MRAM REFILL DEVICE STRUCTURE
20240237548 ยท 2024-07-11
Inventors
- Oscar van der Straten (Guilderland Center, NY, US)
- Praneet Adusumilli (Somerset, NJ, US)
- Chih-Chao Yang (Glenmont, NY, US)
Cpc classification
H10B61/00
ELECTRICITY
International classification
H10B61/00
ELECTRICITY
Abstract
Embodiments of present invention provide a method of forming a MRAM structure. The method includes forming a dielectric layer on top of a bottom contact; creating an opening in the dielectric layer, the opening has a slant top edge; filling a bottom portion of the opening to form a bottom electrode; filling a top portion of the opening with a first ferromagnetic material to form a first ferromagnetic layer; forming a stack of blanket layers, including a blanket tunnel barrier layer, a blanket second ferromagnetic layer, and a blanket top electrode layer, on top of the first ferromagnetic layer; patterning the stack of blanket layers into a top portion of a magnetic tunnel junction stack that includes a tunnel barrier layer, a second ferromagnetic layer, and a top electrode; and forming a top contact in contact with the top electrode. A structure formed thereby is also provided.
Claims
1. A magnetoresistive random-access memory (MRAM) structure comprising: a magnetic tunnel junction (MTJ) stack, the MTJ stack, from a bottom to a top thereof, includes a bottom electrode; a first ferromagnetic layer; a tunnel barrier layer; a second ferromagnetic layer; and a top electrode, wherein the first ferromagnetic layer has a top surface and a bottom surface, the top surface being larger than the bottom surface and the bottom surface being directly above the bottom electrode.
2. The MRAM structure of claim 1, wherein a top portion of the MTJ stack includes the top electrode, the second ferromagnetic layer, and the tunnel barrier layer, and the top portion of the MTJ stack has a slant sidewall and is above the first ferromagnetic layer.
3. The MRAM structure of claim 2, wherein the first ferromagnetic layer and the bottom electrode are covered by a first encapsulation layer and the top portion of the MTJ stack is covered by a second encapsulation layer, wherein the first encapsulation layer and the second encapsulation layer are made of different materials.
4. The MRAM structure of claim 3, wherein the first encapsulation layer is made of silicon-aluminum-nitride (SiAlN) or silicon-aluminum-oxynitride (SiAlON), and the second encapsulation layer is made of silicon-nitride (SiN) or silicon-carbonitride (SiCN).
5. The MRAM structure of claim 1, wherein a bottom surface of the tunnel barrier layer has a size equal to or less than a size of the top surface of the first ferromagnetic layer.
6. The MRAM structure of claim 1, wherein the top electrode is made of niobium-carbonitride (NbCN) or titanium-carbonitride (TiCN).
7. The MRAM structure of claim 1, wherein the first ferromagnetic layer is a reference layer, and the second ferromagnetic layer is a free layer.
8. The MRAM structure of claim 7, wherein the reference layer, the tunnel barrier layer, and the free layer form a spindle shape with the tunnel barrier layer at a middle thereof.
9. A semiconductor structure comprising: a magnetic tunnel junction (MTJ) stack, the MTJ stack includes a bottom electrode; a reference layer; a tunnel barrier layer; a free layer; and a top electrode; a first metal level in contact with the bottom electrode of the MTJ stack; and a second metal level in contact with the top electrode of the MTJ stack, wherein the reference layer has a top surface and a bottom surface and a slant sidewall, the top surface being larger than the bottom surface and the bottom surface being directly above the bottom electrode.
10. The semiconductor structure of claim 9, wherein a top portion of the MTJ stack includes the top electrode, the free layer, and the tunnel barrier layer to be above the reference layer; the top portion of the MTJ stack has a slant sidewall; and a top surface of the top portion of the MTJ stack is smaller than a bottom surface of the top portion of the MTJ stack.
11. The semiconductor structure of claim 10, wherein the reference layer and the bottom electrode are covered by a first encapsulation layer and the top portion of the MTJ stack is covered by a second encapsulation layer, and wherein the first encapsulation layer and the second encapsulation layer are made of different materials.
12. The semiconductor structure of claim 9, wherein the top electrode is made of niobium-carbonitride (NbCN) or titanium-carbonitride (TiCN).
13. The semiconductor structure of claim 9, wherein the reference layer, the tunnel barrier layer, and the free layer form a spindle shape with the tunnel barrier layer at a middle thereof.
14. The semiconductor structure of claim 9, wherein the tunnel barrier layer has a top surface and a bottom surface, the bottom surface of the tunnel barrier layer being directly above the reference layer; the free layer has a top surface and a bottom surface, the bottom surface of the free layer being directly above the tunnel barrier layer and the top surface of the free layer being smaller than the bottom surface of the free layer; and the top electrode has a top surface and a bottom surface, the bottom surface of the top electrode being directly above the free layer and the top surface of the top electrode being smaller than the bottom surface of the top electrode.
15. A method comprising: forming a dielectric layer on top of a bottom contact; creating an opening in the dielectric layer, the opening has a slant top edge; filling a bottom portion of the opening with a conductive material to form a bottom electrode; filling a top portion of the opening, up to and including the slant top edge, with a first ferromagnetic material to form a first ferromagnetic layer; forming a stack of blanket layers, including a blanket tunnel barrier layer, a blanket second ferromagnetic layer, and a blanket top electrode layer, on top of the first ferromagnetic layer; patterning the stack of blanket layers into a top portion of a magnetic tunnel junction (MTJ) stack that includes a tunnel barrier layer, a second ferromagnetic layer, and a top electrode; and forming a top contact in contact with the top electrode.
16. The method of claim 15, wherein creating the opening in the dielectric layer comprises etching a top edge of the opening in a reactive-ion-etch (RIE) process to create the slant top edge.
17. The method of claim 15, wherein forming the stack of blanket layers includes forming the blanket top electrode layer by depositing a blanket layer of either niobium-carbonitride (NbCN) or titanium-carbonitride (TiCN).
18. The method of claim 15, further comprising lining the opening with a first encapsulation layer of silicon-aluminum-nitride (SiAlN) or silicon-aluminum-oxynitride (SiAlON).
19. The method of claim 15, wherein patterning the stack of blanket layers includes forming the top portion of the MTJ stack to have a slant sidewall with a top surface of the top portion of the MTJ stack being smaller than a bottom surface of the top portion of the MTJ stack, the top surface of the top portion of the MTJ stack is a top surface of the top electrode and the bottom surface of the top portion of the MTJ stack is a bottom surface of the tunnel barrier layer.
20. The method of claim 19, further comprising lining the top portion of the MTJ stack with a second encapsulation layer of silicon-nitride (SiN) or silicon-carbonitride (SiCN).
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0014] The present invention will be understood and appreciated more fully from the following detailed description of embodiments of present invention, taken in conjunction with accompanying drawings of which:
[0015]
[0016]
[0017] It will be appreciated that for simplicity and clarity purpose, elements shown in the drawings have not necessarily been drawn to scale. Further, and if applicable, in various functional block diagrams, two connected devices and/or elements may not necessarily be illustrated as being connected. In some other instances, grouping of certain elements in a functional block diagram may be solely for the purpose of description and may not necessarily imply that they are in a single physical entity, or they are embodied in a single physical entity.
DETAILED DESCRIPTION
[0018] In the below detailed description and the accompanying drawings, it is to be understood that various layers, structures, and regions shown in the drawings are both demonstrative and schematic illustrations thereof that are not drawn to scale. In addition, for the ease of explanation, one or more layers, structures, and regions of a type commonly used to form semiconductor devices or structures may not be explicitly shown in a given illustration or drawing. This does not imply that any layers, structures, and regions not explicitly shown are omitted from the actual semiconductor structures. Furthermore, it is to be understood that the embodiments discussed herein are not limited to the particular materials, features, and processing steps shown and described herein. In particular, with respect to semiconductor processing steps, it is to be emphasized that the descriptions provided herein are not intended to encompass all of the processing steps that may be required to form a functional semiconductor integrated circuit device. Rather, certain processing steps that are commonly used in forming semiconductor devices, such as, for example, wet cleaning and annealing steps, are purposefully not described herein for economy of description.
[0019] It is to be understood that the terms about or substantially as used herein with regard to thicknesses, widths, percentages, ranges, etc., are meant to denote being close or approximate to, but not exactly. For example, the term about or substantially as used herein implies that a small margin of error may be present such as, by way of example only, 1% or less than the stated amount. Likewise, the terms on, over, or on top of that are used herein to describe a positional relationship between two layers or structures are intended to be broadly construed and should not be interpreted as precluding the presence of one or more intervening layers or structures.
[0020] To provide spatial context to different structural orientations of the semiconductor structures shown in the drawings, XYZ Cartesian coordinates may be provided in some of the drawings. The terms vertical or vertical direction or vertical height as used herein denote a Z-direction of the Cartesian coordinates shown in the drawings, and the terms horizontal or horizontal direction or lateral direction as used herein denote an X-direction and/or a Y-direction of the Cartesian coordinates shown in the drawings.
[0021] Moreover, although various reference numerals may be used across different drawings, the same or similar reference numbers are used throughout the drawings to denote the same or similar features, elements, or structures, and thus detailed explanations of the same or similar features, elements, or structures may not be repeated for each of the drawings for economy of description. Labelling for the same or similar elements in some drawings may be omitted as well in order not to overcrowd the drawings.
[0022]
[0023] More particularly, embodiments of present invention provide forming a MRAM structure 10 (see
[0024] Embodiments of present invention may further provide forming a conductive cap 201 on top of the bottom contact 101 with the conductive cap 201 embedded or surrounded by a dielectric material layer 110. In forming the above structure, one embodiment of present invention may include first depositing a layer of conductive material on top of the supporting structure, and then patterning the layer of conductive material into the conductive cap 201. After the patterning, a dielectric material may be deposited to surround the conductive cap 201 and the dielectric material may subsequently be planarized through a chemical-mechanic-polishing (CMP) process to form the dielectric material layer 110. Alternatively, another embodiment of present invention may include first depositing the dielectric material layer 110 on top of the supporting structure and then patterning the dielectric material layer 110 to create an opening directly above and exposing the bottom contact 101. Subsequently the opening may be filled with a conductive material, followed by a CMP process, to form the conductive cap 201. In addition to the above embodiments, other known or future developed methods and/or processes may be used as well to form the conductive cap 201 and the surrounding dielectric material layer 110.
[0025]
[0026]
[0027]
[0028]
[0029]
[0030]
[0031]
[0032]
[0033]
[0034]
[0035] As is demonstratively illustrated in
[0036] In one embodiment, the first ferromagnetic layer 401 may be a layer of cobalt (Co), iron (Fe), and boron (B) based material (CoFeB) such as, for example, an alloy of Co, Fe, and B. However, embodiments of present invention are not limited in this aspect and the first ferromagnetic layer 401 may include other suitable materials such as, for example, an alloy of Co and Fe (CoFe) or an alloy of nickel (Ni) and Fe (NiFe). Moreover, the first ferromagnetic layer 401 may be a reference layer to include a Co-based synthetic anti-ferromagnetic layer. The first ferromagnetic layer 401 may have a thickness ranging from about 2 nm to about 30 nm.
[0037]
[0038] Similar to the first ferromagnetic layer 401, in one embodiment, the blanket second ferromagnetic layer 600 may be a layer of cobalt (Co), iron (Fe), and boron (B) based material (CoFeB) such as, for example, an alloy of Co, Fe, and B. However, embodiments of present invention are not limited in this aspect and the blanket second ferromagnetic layer 600 may be of other suitable materials such as, for example, an alloy of Co and Fe (CoFe) or an alloy of nickel (Ni) and Fe (NiFe). The blanket second ferromagnetic layer 600 may be formed to have a thickness ranging from about 2 nm to about 30 nm.
[0039] On the other hand, the blanket tunnel barrier layer 500 may be a layer of magnesium-oxide (MgO) or other suitable materials such as, for example, aluminum-oxide (Al.sub.2O.sub.3) and/or titanium-oxide (TiO.sub.2) and may be formed to have a thickness ranging from about 0.6 nm to about 1.2 nm.
[0040]
[0041]
[0042]
[0043] In one embodiment, the low-angle IBE process may form the top portion 511 of the MTJ stack 510 to have a slant sidewall 520. The top portion 511 of the MTJ stack 510 may have a top surface, that is the top surface of the top electrode 701, that has a substantially same size as a size of the hard mask 711. The top portion 511 of the MTJ stack 510 also has a bottom surface, that is the bottom surface of the tunnel barrier layer 501, that is equal to or less than a size of the top surface of the first ferromagnetic layer 401. In other words, the top portion 511 of the
[0044] MTJ stack 510 includes the tunnel barrier layer 501 that has a top surface and a bottom surface with the bottom surface of the tunnel barrier layer 501 being directly above the first ferromagnetic layer 401; the second ferromagnetic layer 601 has a top surface and a bottom surface with the bottom surface of the second ferromagnetic layer 601 being directly above the tunnel barrier layer 501 and the top surface of the second ferromagnetic layer 601 being smaller than the bottom surface of the second ferromagnetic layer 601; and the top electrode 701 has a top surface and a bottom surface with the bottom surface of the top electrode 701 being directly above the second ferromagnetic layer 601 and the top surface of the top electrode 701 being smaller than the bottom surface of the top electrode 701.
[0045]
[0046]
[0047]
[0048] In one embodiment, the second encapsulation layer 721 may overlap with the first encapsulation layer 321 at the slant sidewall 520 of the top portion 511 of the MTJ stack 510 and the slant sidewall 410 of the first ferromagnetic layer 401. In another embodiment, the second encapsulation layer 721 and the first encapsulation layer 321 may be different in material. For example, the first encapsulation layer 321 may be made of SiAlN and the second encapsulation layer 721 may be made of SiN.
[0049]
[0050]
[0051]
[0052] It is to be understood that the exemplary methods discussed herein may be readily incorporated with other semiconductor processing flows, semiconductor devices, and integrated circuits with various analog and digital circuitry or mixed-signal circuitry. In particular, integrated circuit dies can be fabricated with various devices such as field-effect transistors, bipolar transistors, metal-oxide-semiconductor transistors, diodes, capacitors, inductors, etc. An integrated circuit in accordance with the present invention can be employed in applications, hardware, and/or electronic systems. Suitable hardware and systems for implementing the invention may include, but are not limited to, personal computers, communication networks, electronic commerce systems, portable communications devices (e.g., cell phones), solid-state media storage devices, functional circuitry, etc. Systems and hardware incorporating such integrated circuits are considered part of the embodiments described herein. Given the teachings of the invention provided herein, one of ordinary skill in the art will be able to contemplate other implementations and applications of the techniques of the invention.
[0053] Accordingly, at least portions of one or more of the semiconductor structures described herein may be implemented in integrated circuits. The resulting integrated circuit chips may be distributed by the fabricator in raw wafer form (that is, as a single wafer that has multiple unpackaged chips), as a bare die, or in a packaged form. In the latter case the chip may be mounted in a single chip package (such as a plastic carrier, with leads that are affixed to a motherboard or other high-level carrier) or in a multichip package (such as a ceramic carrier that has surface interconnections and/or buried interconnections). In any case the chip may then be integrated with other chips, discrete circuit elements, and/or other signal processing devices as part of either an intermediate product, such as a motherboard, or an end product. The end product may be any product that includes integrated circuit chips, ranging from toys and other low-end applications to advanced computer products having a display, a keyboard or other input device, and a central processor.
[0054] The descriptions of various embodiments of present invention have been presented for the purposes of illustration and they are not intended to be exhaustive and present invention are not limited to the embodiments disclosed. The terminology used herein was chosen to best explain the principles of the embodiments, practical application or technical improvement over technologies found in the marketplace, and to enable others of ordinary skill in the art to understand the embodiments disclosed herein. Many modifications, substitutions, changes, and equivalents will now occur to those of ordinary skill in the art. Such changes, modification, and/or alternative embodiments may be made without departing from the spirit of present invention and are hereby all contemplated and considered within the scope of present invention. It is, therefore, to be understood that the appended claims are intended to cover all such modifications and changes as fall within the spirit of the invention.