Dyeing composition comprising a fatty substance, a non-ionic guar gum, an amphoteric surfactant and a non-ionic or anionic surfactant, and an oxidizing agent, dyeing process and suitable device

Abstract

The subject of the present invention is a composition for dyeing human keratin fibers such as the hair, comprising: (a) at least one oxidation dye precursor; (b) at least one first amphoteric or zwitterionic surfactant; (c) at least one second non-ionic or anionic surfactant; (d) one or more fatty substances; (e) at least one cationic polymer; (f) at least one non-ionic guar gum; (g) at least one oxidizing agent other than atmospheric oxygen. The present invention also relates to a process for dying human keratin fibers, in which this composition is applied to said fibers, and also to a suitable multicompartment device.

Claims

1. A composition for dyeing keratin fibers, comprising: at least one oxidation dye precursor; at least one amphoteric or zwitterionic surfactant; at least one non-ionic or anionic surfactant; at least one fatty substance chosen from liquid petroleum jelly, C.sub.6-C.sub.16 alkanes, polydecenes, liquid fatty acid or fatty alcohol esters, or mixtures thereof; at least one cationic polymer; at least one non-ionic guar gum, wherein the at least one non-ionic guar gum is unmodified, or is modified with C.sub.1-C.sub.6 hydroxyalkyl groups, optionally comprising groups comprising at least one C.sub.6-C.sub.30 fatty chain; and at least one oxidizing agent other than atmospheric oxygen, wherein the weight ratio of the amount of amphoteric and/or zwitterionic surfactant to the amount of non-ionic and/or anionic surfactant ranges from 0.1 to 10 (0.1:10).

2. The composition according to claim 1, wherein the at least one oxidation dye precursor is chosen from oxidation bases or salts thereof.

3. The composition according to claim 1, wherein the at least one oxidation dye precursor is chosen from couplers or the addition salts of these couplers with an acid.

4. The composition according to claim 1, wherein the at least one amphoteric or zwitterionic surfactant is chosen from derivatives of optionally quaternized aliphatic secondary or tertiary amines, wherein the aliphatic group is a linear or branched chain comprising from 8 to 22 carbon atoms, said amine derivatives containing at least one anionic group.

5. The composition according to claim 4, wherein the at least one amphoteric or zwitterionic surfactant is chosen from: (C.sub.8-C.sub.20)alkylbetaines, (C.sub.8-C.sub.20)alkylsulfobetaines, (C.sub.8-C.sub.20)alkylam ido(C.sub.3-C.sub.8)alkylbetaines, (C.sub.8-C.sub.20)alkylam ido(C.sub.6-C.sub.8)alkylsulfobetaines, the compounds of formula (B1):
R.sub.aC(O)NHCH.sub.2CH.sub.2N.sup.+(R.sub.b)(R.sub.c)CH.sub.2C(O)O.sup., M.sup.+, X.sup.(B1) wherein: R.sub.a is chosen from a C.sub.10-C.sub.30 alkyl or alkenyl group derived from an acid R.sub.aCOOH, heptyl, nonyl or undecyl group; R.sub.b is a -hydroxyethyl group; and R.sub.c is a carboxymethyl group; M.sup.+ is chosen from a cationic counterion derived from an alkali metal or alkaline-earth metal or an ammonium ion or an ion derived from an organic amine, and X.sup. is chosen from an organic or inorganic anionic counterion chosen from halides, acetates, phosphates, nitrates, (C.sub.1-C.sub.4)alkyl sulfates, (C.sub.1-C.sub.4)alkyl- or (C.sub.1-C.sub.4)alkylarylsulfonates; or alternatively M.sup.+ and X.sup. are absent, the compounds of formula (B2):
R.sub.aC(O)NHCH.sub.2CH.sub.2N(B)(B)(B2) wherein: B is the group CH.sub.2CH.sub.2OX; B is the group (CH.sub.2).sub.zY, with z equal to the integer 1 or 2; X is chosen from the groups CH.sub.2C(O)OH, CH.sub.2C(O)OZ, CH.sub.2CH.sub.2C(O)OH, CH.sub.2CH.sub.2C(O)OZ, or a hydrogen atom; Y is chosen from the groups C(O)OH, C(O)OZ, CH.sub.2CH(OH)SO.sub.3H and CH.sub.2CH(OH)SO.sub.3Z; Z is chosen from a cationic counterion derived from an alkali metal or alkaline-earth metal, an ammonium ion or an ion derived from an organic amine; and R.sub.a represents a C.sub.10-C.sub.30 alkyl or alkenyl group of an acid R.sub.aC(O)OH, an alkyl group, or an unsaturated C.sub.17 group, and the compounds of formula (B2):
R.sub.aNHCH(Y)(CH.sub.2)nC(O)NH(CH.sub.2)nN(R.sub.d)(R.sub.e)(B2) wherein: Y is chosen from the groups C(O)OH, C(O)OZ, CH.sub.2CH(OH)SO.sub.3H, CH.sub.2CH(OH)SO.sub.3Z; R.sub.d and R.sub.e, independently of each other, are chosen from C.sub.1-C.sub.4 alkyl or hydroxyalkyl radical; Z is chosen from a cationic counterion derived from an alkali metal or alkaline-earth metal, an ammonium ion or an ion derived from an organic amine; R.sub.a is chosen from a C.sub.10-C.sub.30 alkyl or alkenyl group of an acid R.sub.aC(O)OH; and n and n, independently of each other, are integers ranging from 1 to 3.

6. The composition according to claim 1, wherein the at least one non-ionic or anionic surfactant is non-ionic and chosen from the following, alone or as mixtures: oxyalkylenated (C.sub.8-C.sub.24)alkylphenols; saturated or unsaturated, linear or branched, oxyalkylenated or glycerolated C.sub.8-C.sub.30 alcohols; saturated or unsaturated, linear or branched, oxyalkylenated C.sub.8-C.sub.30 amides; esters of saturated or unsaturated, linear or branched, C.sub.8-C.sub.30 acids and of polyethylene glycols; esters of saturated or unsaturated, linear or branched, C.sub.8-C.sub.30 acids and of sorbitol; fatty acid esters of sucrose; (C.sub.8-C.sub.30)alkylpolyglycosides, (C.sub.8-C.sub.30)alkenylpolyglycosides, optionally oxyalkylenated (0 to 10 oxyalkylene units) and comprising 1 to 15 glucose units, (C.sub.8-C.sub.30)alkylglucoside esters; oxyethylenated and saturated or unsaturated vegetable oils; condensates of ethylene oxide and/or of propylene oxide, inter alia, alone or as mixtures; N(C.sub.8-C.sub.30)alkylglucamine derivatives and N(C.sub.8-C.sub.30)acyl-methylglucamine derivatives; aldobionamides; amine oxides; or oxyethylenated and/or oxypropylenated silicones.

7. The composition according to claims 1, comprising anionic surfactants chosen from alkyl sulfates, alkyl ether sulfates, alkylamido ether sulfates, alkylaryl polyether sulfates, monoglyceride sulfates, alkyl sulfonates, alkylamide sulfonates, alkylaryl sulfonates, alpha-olefin sulfonates, paraffin sulfonates, alkyl sulfosuccinates, alkyl ether sulfosuccinates, alkylamide sulfosuccinates, alkyl sulfoacetates, acyl sarcosinates, acyl glutamates, alkyl sulfosuccinamates, acyl isethionates and N-acyl taurates; salts of alkyl monoesters of polyglycoside-polycarboxylic acids, acyl lactylates, salts of D-galactoside uronic acids, salts of alkyl ether carboxylic acids, salts of alkylaryl ether carboxylic acids, salts of alkylamido ether carboxylic acids, and the corresponding non-salified forms of these compounds, the alkyl and acyl groups of all these compounds comprising from 6 to 40 carbon atoms, and the aryl group denoting a phenyl group.

8. The composition according to claim 1, comprising at least one non-ionic surfactant and at least one anionic surfactant.

9. The composition according to claim 1, wherein the at least one fatty substance is present in an amount ranging from about 10% to about 70% by weight, relative to the total weight of the composition.

10. The composition according to claim 1, wherein the at least one cationic polymer has a charge density of at least 1 meq/g.

11. The composition according to claim 1, wherein the at least one cationic polymer is chosen from the following polymers, alone or as mixtures: (1) Homopolymers or copolymers derived from acrylic or methacrylic esters or amides and comprising at least one of the units of formula (I), (II), (III) or (IV) below: ##STR00024## wherein: R.sub.3, which may be identical or different, is a hydrogen atom or a CH.sub.3 radical; A, which may be identical or different, are chosen from a linear or branched C.sub.1-C.sub.6 alkyl group or a hydroxyalkyl group, the alkyl of which is C.sub.1-C.sub.4; R.sub.4, R.sub.5 and R.sub.6, which may be identical or different, are chosen from a C.sub.1-C.sub.18 alkyl group or a benzyl radical; R.sub.1 and R.sub.2, which may be identical or different, are chosen from hydrogen or a C.sub.1-C.sub.6 alkyl group; (2) Cationic cellulose derivatives; (3) Cationic guar gums; (4) Polymers consisting of piperazinyl units and of linear or branched divalent alkyl or hydroxyalkyl radicals, optionally interrupted with oxygen, sulfur or nitrogen atoms or with aromatic or heterocyclic rings, and also the oxidation and/or quaternization products of these polymers; (5) Water-soluble polyam inoam ides which are optionally crosslinked; (6) Polymers obtained by reaction of a polyalkylene polyamine containing two primary amine groups and at least one secondary amine group with a dicarboxylic acid; (7) Cyclopolymers of alkyldiallylamine or of dialkyldiallylammonium, in the form of homopolymers or copolymers containing, as main constituent of the chain, units corresponding to formula (V) or (VI): ##STR00025## wherein k and t are equal to integers 0 or 1, the sum k+t being equal to 1; R.sub.9 is a hydrogen atom or a methyl radical; R.sub.7 and R.sub.8, independently of each other, are chosen from a C.sub.1-C.sub.8 alkyl group, a hydroxyalkyl group in which the alkyl group is C.sub.1-C.sub.5, or an amidoalkyl group in which the alkyl is C.sub.1-C.sub.4; R.sub.7 and R.sub.8, together with the nitrogen atom to which they are attached, can also be chosen from a heterocyclic group; Y.sup. is an organic or inorganic anion; (8) The diquaternary ammonium polymers containing repeating units corresponding to the formula: ##STR00026## wherein: R.sub.10, R.sub.11, R.sub.12 and R.sub.13, which may be identical or different, are chosen from linear, branched or cyclic, saturated, unsaturated or aromatic, C.sub.1-C.sub.20 hydrocarbon-based radicals, linear or branched hydroxyalkyl radicals in which the alkyl part is C.sub.1-C.sub.4, or linear or branched C.sub.1-C.sub.6 alkyl radicals, substituted with a nitrile, ester, acyl or amide group or a group COOR.sub.14-D or CONH13 R.sub.14-D with R.sub.14 representing an alkyl radical and D a quaternary ammonium group, or form, together or separately, with the nitrogen atoms to which they are attached, heterocycles optionally containing a second heteroatom other than nitrogen; A.sub.1 and B.sub.1 are chosen from linear or branched, saturated or unsaturated, C.sub.2-C.sub.20 radicals, optionally substituted or interrupted with one or more aromatic rings, oxygen or sulfur atoms or groups bearing at least one of these atoms; X.sup. is an organic or inorganic anion; A.sub.1, R.sub.10 and R.sub.12 can form, with the two nitrogen atoms to which they are attached, a piperazine ring; in addition, if A.sub.1 is chosen from a linear or branched, saturated or unsaturated alkylene or hydroxyalkylene radical, B.sub.1 can also be chosen from a (CH.sub.2).sub.nCO-D-OC(CH.sub.2).sub.n group in which n is between 1 and 100, and D is chosen from a glycol, bis-secondary diamine, bis-primary diamine or ureylene residue; (9) Polyquaternary ammonium polymers consisting of repeating units of formula (IX): ##STR00027## wherein p is an integer ranging from 1 to 6, D may be zero or may be a (CH.sub.2).sub.rCOgroup in which r is an integer equal to 4 or 7, and X.sup. is an organic or inorganic anion; (10) Quaternary polymers of vinylpyrrolidone and of vinylimidazole; or (11) Polyamines.

12. The composition according to claim 11, wherein the at least one cationic polymer is chosen from the polymers (1), (7), (8) and (9), alone or as mixtures.

13. The composition according to claim 1, wherein the at least one cationic polymer is present in an amount ranging from about 0.01% to about 10% by weight, relative to the weight of the composition.

14. The composition according to claim 1, wherein the at least one non-ionic guar gum is present in an amount ranging from about 0.001% to about 10% by weight, relative to the total weight of the composition.

15. The composition according to claim 1, wherein the at least one oxidizing agent other than atmospheric oxygen is hydrogen peroxide.

16. A process for dyeing keratin fibers, comprising: (a) preparing the dye composition by mixing: a first composition free of an oxidizing agent other than atmospheric oxygen, comprising at least one oxidation dye precursor; and a second composition comprising at least one oxidizing agent other than atmospheric oxygen, wherein at least one of the first or second compositions comprises at least one fatty substance, at least one cationic polymer, at least one first amphoteric or zwitterionic surfactant, at least one non-ionic or anionic surfactant and at least one non-ionic guar gum, wherein the at least one non-ionic guar gum is unmodified, or is modified with C.sub.1-C.sub.6 hydroxyalkyl groups, optionally comprising groups comprising at least one C.sub.6-C.sub.30 fatty chain, further wherein the weight ratio of the amount of amphoteric and/or zwitterionic surfactant to the amount of non-ionic and/or anionic surfactant ranges from 0.1 to 10 (0.1:10); and (b) applying said dye composition to said keratin fibers.

17. The process according to claim 16, wherein the second composition comprising at least one oxidizing agent comprises at least one cationic polymer.

18. The process according to claim 16, wherein the fatty substance is present in at least 10% the mixture of the first composition and of the second composition, relative to the weight of the mixture.

19. A device for mixing and using a composition for dyeing keratin fibers, comprising: a first compartment containing a composition free of oxidizing agent other than atmospheric oxygen, comprising at least one oxidation dye precursor; and a second compartment containing an oxidizing composition; wherein at least one of the compositions comprises at least one fatty substance, at least one cationic polymer, at least one amphoteric or zwitterionic surfactant, at least one non-ionic or anionic surfactant and at least one non-ionic guar gum, wherein the at least one non-ionic guar gum is unmodified, or is modified with C.sub.1-C.sub.6 hydroxyalkyl groups, optionally comprising groups comprising at least one C.sub.6-C.sub.30 fatty chain; and wherein the composition in the first compartment and the composition in the second compartment are mixed before use.

Description

EXAMPLE

(1) The following compositions are prepared (the amounts are expressed in g % of active material):

(2) Composition 1:

(3) TABLE-US-00001 Resorcinol 0.5 Ethanolamine 5 Sodium laureth sulfate comprising 2.2 OE 1.75 Hydroxypropyl guar 1 Ascorbic acid 0.5 N,N-Bis(2-hydroxyethyl)-p-phenylenediamine sulfate 0.073 m-Aminophenol 0.18 EDTA 0.2 2-Methylresorcinol 0.1 PEG-40 hydrogenated castor oil 1 2,4-Diaminophenoxyethanol hydrochloride 0.019 Cocobetaine 3 Sodium chloride 0.65 Sodium metabisulfite 0.5 Mineral oil 60 2,5-Toluenediamine 0.6732 Water q.s. for 100
Composition 2:

(4) TABLE-US-00002 Tocopherol 0.1 Sodium stannate 0.04 Pentasodium pentetate 0.06 Polyquaternium-6 0.2 Glycerol 0.5 Cetearyl alcohol 6 Hexadimethrine chloride 0.15 Hydrogen peroxide 6 Tetrasodium pyrophosphate 0.03 Mineral oil 20 PEG-4 Rapeseedamide 1.19 Steareth-20 5 Phosphoric acid q.s. for pH 2.2 Water q.s. for 100
Application Method:

(5) The two compositions are mixed together at the time of use in the following proportions: 10 g of composition 1 with 15 g of composition 2.

(6) The resulting mixture is easily applied to locks of dark chestnut hair in a proportion of 10 g of mixture for 1 g of hair, for 30 minutes at ambient temperature (20 C.).

(7) The hair is then easily rinsed, then washed with a standard shampoo and dried.

(8) A light chestnut colour is obtained.

(9) Compositions 3 and 3:

(10) TABLE-US-00003 3 3 p-Aminophenol 0.188 0.46 Ethanolamine 5 5 Sodium laureth sulfate comprising 2.2 1.75 1.75 OE Hydroxypropyl guar 1 1 Ascorbic acid 0.5 0.5 1-Hyroxyethyl-4,5-diaminopyrazole 1.58 sulfate 2,3-Diamino-6,7-dihydro-1H,5H- 0.8 pyrazolo(1,2-a)pyrazol-1-one dimethane sulfonate 4-amino-2-hydroxytoluene 1.3 0.81 EDTA 0.2 0.2 1-Methyl-2-hydroxy-beta- 0.4 hydroxyethylaminobenzene PEG-40 hydrogenated castor oil 1 1 5-Amino-6-chloro-o-cresol 0.28 Cocobetaine 3 3 Sodium chloride 0.65 0.65 Sodium metabisulfite 0.5 0.5 Mineral oil 60 60 2,5-Toluenediamine 0.4653 0.26 Water q.s. for 100 q.s. for 100
Composition 4:

(11) TABLE-US-00004 Tocopherol 0.1 Sodium stannate 0.04 Pentasodium pentetate 0.06 Polyquaternium-6 0.2 Glycerol 0.5 Cetearyl alcohol 6 Hexadimethrine chloride 0.15 Hydrogen peroxide 6 Tetrasodium pyrophosphate 0.03 Mineral oil 20 PEG-4 Rapeseedamide 1.19 Steareth-20 5 Phosphoric acid q.s. for pH 2.2 Water q.s. for 100
Application Method:

(12) The two compositions 3 or 3 are mixed at the time of use with composition 4 in the following proportions: 10 g of composition 3 or 3 with 15 g of composition 4.

(13) The resulting mixture is easily applied to locks of dark chestnut hair in a proportion of 10 g of mixture for 1 g of hair, for 30 minutes at ambient temperature (20 C.).

(14) The hair is then easily rinsed, then washed with a standard shampoo and dried.

(15) A deep red light chestnut colour is obtained with the mixture of composition 3 and of composition 4, and a coppery-red light chestnut colour is obtained with the mixture of composition 3 and of composition 4.

(16) Composition 5:

(17) TABLE-US-00005 Ingredients Content Resorcinol 0.5 Ethanolamine 2.8 Sodium laureth sulfate comprising 2 OE 1.75 Hydroxypropyl guar 2.25 Ascorbic acid 0.5 N,N-Bis(2-hydroxyethyl)-p-phenylenediamine sulfate 0.07 m-Aminophenol 0.18 EDTA 0.2 2-Methylresorcinol 0.1 PEG-40 hydrogenated castor oil 1 2,4-Diaminophenoxyethanol hydrochloride 0.02 Cocobetaine 3 Sodium chloride 0.65 Sodium metabisulfite 0.5 Mineral oil (liquid paraffin) 60 2,5-Toluenediamine 0.7 Water q.s. for 100
Composition 6:

(18) TABLE-US-00006 Ingredients Content Caprylyl/capryl glucoside 1.8 Tetrasodium etidronate 0.06 Sodium salicylate 0.035 Glycerol 4 Hydrogen peroxide 6 Tetrasodium pyrophosphate 0.04 Phosphoric acid q.s. for pH 2.2 Water q.s.
Application Method:

(19) The two compositions are mixed together at the time of use, for example in a shaker, in the following proportions: 9 g of composition 5 with 12 g of composition 6.

(20) The resulting foam is creamy. It is applied to locks of gray hair comprising 90% white hairs, in a proportion of 10 g of mixture for 1 g of hair, for 30 minutes at ambient temperature (20 C.).

(21) The hair is then rinsed, washed with a standard shampoo and dried. A strong light chestnut colour is obtained.