Method of Cooling Boil-Off Gas and Apparatus Therefor

Abstract

The present invention is a modification of a typical single mixed refrigerant (SMR) cycle for LNG re-liquefaction in particular, that allows the use of a cost-efficient oil-injected screw compressor in the mixed refrigerant system. In comparison with the typical arrangement, the present innovation allows for reduced complexity, fewer pieces of equipment, and reduced capital cost. There is shown a method of cooling a boil-off gas (BOG) stream from a liquefied gas tank using a single mixed refrigerant (SMR) comprising at least the step of heat exchanging the BOG stream with the SMR in a liquefaction heat exchanger system to provide a cooled BOG stream, wherein the SMR is provided in an SMR recirculating system comprising at least the steps of: (a) compressing the SMR using at least one oil-injected screw compressor to provide a post-compression SMR stream; (b) separating the post-compression SMR stream to provide an oil-based stream and a first SMR vapour stream; (c) passing the first SMR vapour stream into the liquefaction heat exchanger system to cool the first SMR vapour stream and provide a cooled first SMR vapour stream; (d) withdrawing the cooled first SMR vapour stream from the liquefaction heat exchanger system; (e) separating the cooled first SMR vapour stream to provide a liquid-phase SMR stream and an oil-free SMR vapour stream; (f) passing the oil-free SMR vapour stream through the liquefaction heat exchanger system to provide a condensed SMR stream; and (g) expanding the condensed SMR stream to provide an expanded lowest-temperature SMR stream to pass through the liquefaction heat exchanger system for heat exchange against the BOG stream.

Claims

1. A method of cooling a boil-off gas (BOG) stream from a liquefied gas tank using a single mixed refrigerant (SMR) comprising the steps of: heat exchanging the BOG stream with the SMR in a liquefaction heat exchanger system to provide a cooled BOG stream, wherein the SMR is provided in an SMR recirculating system comprising the steps of (a) compressing the SMR using at least one oil-injected screw compressor to provide a post-compression SMR stream; (b) separating the post-compression SMR stream to provide an oil-based stream and a first SMR vapour stream; (c) passing the first SMR vapour stream into the liquefaction heat exchanger system to cool the first SMR vapour stream and provide a cooled first SMR vapour stream; (d) withdrawing the cooled first SMR vapour stream from the liquefaction heat exchanger system; (e) separating the cooled first SMR vapour stream to provide a liquid-phase SMR stream and an oil-free SMR vapour stream; (f) passing the oil-free SMR vapour stream through the liquefaction heat exchanger system to provide a condensed SMR stream; and (g) expanding the condensed SMR stream to provide an expanded lowest-temperature SMR stream to pass through the liquefaction heat exchanger system for heat exchange against the BOG stream.

2. A method as claimed in claim 1 wherein the BOG stream is from one of the following: a liquefied cargo tank in a floating vessel, or a liquefied natural gas (LNG) cargo tank.

3. A method as claimed in claim 1 wherein the liquefaction heat exchanger system comprises a single liquefaction heat exchanger.

4. A method as claimed in claim 3 comprising in step (f) passing the oil-free SMR vapour stream partly through the single liquefaction heat exchanger.

5. A method as claimed in claim 3 comprising in step (f) passing the oil-free SMR vapour stream fully through the single liquefaction heat exchanger.

6. A method as claimed in claim 1 wherein the liquefaction heat exchanger system comprises a multi-unit liquefaction heat exchange two or more heat exchange units, and the BOG stream and the expanded lowest-temperature SMR stream pass through each of the heat exchanger units.

7. A method as claimed in claim 6 further comprising the steps of passing the first SMR vapour stream into a first heat exchange unit, and passing the oil-free SMR vapour stream into a second heat exchanger unit.

8. A method as claimed in claim 6 further comprising the steps of passing the first SMR vapour stream into a first heat exchange unit, and passing the oil-free SMR vapour stream into both a first heat exchange unit and a second heat exchange unit.

9. A method as claimed in claim 6 wherein the multi-unit liquefaction heat exchange comprising two multi-stream heat exchangers.

10. A method as claimed in claim 6 wherein the multi-unit liquefaction heat exchange comprising one multi-stream heat exchanger and a plurality of two-stream heat exchangers.

11. A method as claimed in claim 1 further comprising the step of ambient-cooling the first SMR vapour stream prior to step (c).

12. A method as claimed in claim 1 further comprising the steps of expanding the liquid-phase SMR stream of step (e), and passing the expanded liquid-phase SMR stream into the liquefaction heat exchanger system.

13. A method as claimed in claim 12 further comprising the step of combining the expanded liquid-phase SMR stream with the expanded lowest-temperature SMR stream in the liquefaction heat exchanger system.

14. A method as claimed in claim 12 wherein the liquefaction heat exchanger system comprises a multi-unit liquefaction heat exchanger system, and further comprising the step of combining the expanded liquid-phase SMR stream with the expanded lowest-temperature SMR stream between two units of the multi-unit liquefaction heat exchanger system.

15. A method as claimed in claim 10 further comprising the step of combining the expanded liquid-phase SMR stream with the expanded lowest-temperature SMR stream after the liquefaction heat exchanger system

16. A method as claimed in claim 1 wherein step (g) provides a post-cooling vapour SMR stream for recirculation or reuse as part of the SMR recirculating system.

17. A method as claimed in claim 1 wherein expansion of the condensed SMR stream is able to provide an expanded lowest-temperature SMR stream having a temperature below the oil-solidification temperature of the oil in the at least one oil-injected screw compressor compressing the SMR.

18. A method as claimed in claim 1 wherein the first SMR vapour stream of step (b) does not undergo any external refrigerant cooling prior to step (e).

19. A method as claimed in claim 1 wherein the BOG stream does not undergo any external refrigerant cooling prior to passing through the liquefaction heat exchanger.

20. A method as claimed in claim 1 wherein the liquefaction heat exchanger system comprises one or more plate-fin heat exchangers.

21. A method as claimed in claim 1 wherein the expanded lowest-temperature SMR stream provides the cooling of the first SMR vapour stream.

22. An SMR recirculating system for use with a method of cooling a boil-off gas (BOG) stream from a liquefied gas tank using a single mixed refrigerant (SMR) comprising the steps of heat exchanging the BOG stream with the SMR in a liquefaction heat exchanger system to provide a cooled BOG stream, wherein the SMR is provided in an SMR recirculating system comprising the steps of (a) compressing the SMR using at least one oil-injected screw compressor to provide a post-compression SMR stream; (b) separating the post-compression SMR stream to provide an oil-based stream and a first SMR vapour stream; (c) passing the first SMR vapour stream into the liquefaction heat exchanger system cool the first SMR vapour stream and provide a cooled first SMR vapour stream; (d) withdrawing the cooled first SMR vapour stream from the liquefaction heat exchanger system; (e) separating the cooled first SMR vapour stream to provide a liquid-phase SMR stream and an oil-free SMR vapour stream; (f) passing the oil-free SMR vapour stream through the liquefaction heat exchanger system to provide a condensed SMR stream; and (g) expanding the condensed SMR stream to provide an expanded lowest-temperature SMR stream to pass through the liquefaction heat exchanger system for heat exchange against the BOG stream.

23. An SMR recirculating system as claimed in claim 22 for use in cooling the BOG stream from one of the following: a liquefied gas cargo tank in a floating vessel, or a liquefied natural gas (LNG) cargo tank.

24-25. (canceled)

26. An SMR recirculating system as claimed in claim 22 further comprising providing the sub-ambient refrigerant cooling duty for cooling a boil-off gas stream from a liquefied gas tank.

27. An apparatus for cooling a boil-off gas (BOG) stream from a liquefied gas tank comprising a single mixed refrigerant (SMR) recirculating system as defined in claim 22 and a liquefaction heat exchanger system for heat exchange against the BOG stream.

Description

[0091] Embodiments and an example of the present invention will now be described by way of example only and with reference to the accompanying schematic drawings in which:

[0092] FIG. 1 is a schematic view of a prior art method of cooling a BOG stream using a prior art SMR system;

[0093] FIG. 2 is a schematic view of a method of cooling a BOG stream using an SMR system according to a general embodiment of the present invention;

[0094] FIG. 3 is a schematic view of a method of cooling a BOG stream using an SMR system according to a first embodiment of the present invention;

[0095] FIG. 4 is a schematic view of a method of cooling a BOG stream using an SMR system according to a second embodiment of the present invention;

[0096] FIG. 5 is a schematic view of a method of cooling a BOG stream using an SMR system according to a third embodiment of the present invention;

[0097] FIG. 6 is a schematic view of a method of cooling a BOG stream using an SMR system according to a fourth embodiment of the present invention;

[0098] FIG. 7 is a schematic view of a method of cooling a BOG stream using an SMR system according to a fifth embodiment of the present invention;

[0099] FIG. 8 is a schematic view of a method of cooling a BOG stream using an SMR system according to a sixth embodiment of the present invention; and

[0100] FIG. 9 is a schematic view of a method of cooling a BOG stream using an SMR system according to a seventh embodiment of the present invention

[0101] Where relevant, the same reference numerals are used in different Figures to represent the same or similar feature.

[0102] FIG. 1 is a prior art arrangement described hereinabove, which requires an external refrigerant circuit and apparatus based on cascade 13 to achieve reliquefaction of the compressed BOG using an SMR recirculating system and an oil-injected screw compressor 2.

[0103] FIG. 2 shows a method of cooling a boil-off gas stream from a liquefied gas tank according to a general embodiment of the present invention, using a single mixed refrigerant (SMR), and comprising at least the step of heat exchanging the BOG stream with the SMR in a liquefaction heat exchanger system to provide a cooled BOG stream, and wherein the SMR is provided in an SMR recirculating system according to another embodiment of the present invention.

[0104] In more detail, FIG. 2 shows a BOG stream 70 provided from one or more LNG cargo tanks (not shown) and already compressed in a compressor (also not shown).

[0105] The BOG stream 70 is optionally ambient cooled in a first ambient heat exchanger 60, using a readily available cooling medium (e.g. seawater, freshwater, engine room cooling water, air). This optionally cooled (and compressed) BOG stream 71 is then passed into a liquefaction heat exchanger system 40.

[0106] The liquefaction heat exchanger system 40 may comprise any form or arrangement of one or more heat exchangers able to allow heat exchange between two or more streams, optionally between multiple streams, and optionally having at least one stream running countercurrently to one or more other streams in a part or portion of the system, in particular between the BOG stream and one of the refrigerant. Any arrangement of more than one heat exchanger may be in series or in parallel or a combination of in series and in parallel, and the heat exchangers may be separate or conjoined or contiguous, optionally in a single cooled unit or box, and optionally in the form of one or more stages of providing the required heat exchange with the BOG stream to liquefy the BOG stream.

[0107] Liquefaction heat exchanger systems comprising more than one heat exchanger generally have a one section, unit or stage being warmer than another section, unit or stage, in the sense of the average temperature therein.

[0108] Some variants of suitable liquefaction heat exchanger systems arc discussed and shown hereinafter. The skilled man can recognise other variants, and the invention is not limited thereby.

[0109] In the general liquefaction heat exchanger system 40 shown in FIG. 2, the cooled (and compressed) BOG stream 71 is condensed by colder streams discussed hereinafter, generated in the SMR recirculating system 200. The condensed BOG stream leaves the exchanger system 40 via pipeline 73, and can be returned back to the LNG cargo tanks.

[0110] In the SMR system 200, an initial stream of SMR refrigerant gas 74 from a refrigerant receiver 51 is sent to an oil-injected screw compressor 52. Oil-injected screw compressors are well known in the art, and not further described herein. Oil-injected screw compressors are well proven in industry and are cost effective, especially for small scale or small volume compression, but are known to have the disadvantage that some, possibly even microscopic amounts, of the oil can become entrained in the gas passing through the compressor, and thus become a part of the gas discharge therefrom.

[0111] In FIG. 2, compressing the initial SMR stream 74 using the one oil-injected screw compressor 52 provides a post-compression SMR stream 75, which enters a first oil separator 53, optionally having a filter, which separates the post-compression SMR stream 75 to provide an oil-based stream 76 and a first SMR vapour stream 79. Most of the oil is removed in the separator 53 typically by gravity and/or filtration. The recovered oil-based stream 76 is drained into a pipeline where pressure differences or an optional oil pump 54 passes the oil to stream 77, and an oil cooler 55 cools the oil, which is then re-injected as stream 78 into compressor 52.

[0112] The first SMR vapour stream 79 is mostly oil-free, but does contain some degree of oil carryover. The first SMR vapour stream 79 is cooled in a second ambient heat exchanger 56 using a readily available cooling medium (e.g. seawater, freshwater, engine room cooling water, air) to provide a cooler first vapour stream 80. Depending on the composition and pressure of the refrigerant, as well as on the temperature achieved in the second ambient heat exchanger 56, some condensation of the SMR may start to occur.

[0113] The cooler first vapour stream 80 passes into the liquefaction heat exchanger system 40, where the refrigerant is cooled and at least partially condensed. The temperature to which it is cooled is higher than the solidification temperature of the oil. The cooled first SMR vapour stream 81 is withdrawn from an intermediate temperature along the liquefaction heat exchanger system 40, and enters a vapour-liquid separator 58. In the separator 58, a liquid-phase SMR stream 82, generally comprising liquid and any residual oil amount, can be drained via pipeline 82.

[0114] Thereafter, the pressure of the liquid-phase SMR stream 82 can be reduced by a flash valve 59, resulting in some vaporisation and an associated reduction in temperature. The SMR system 200 is designed such that this lower temperature is still above the solidification temperature of the oil. The expanded, or at least partly vaporised, liquid-phase SMR stream 83 can be sent into the heat exchanger system 40, where it provides some cooling to warmer streams, while itself being vaporised.

[0115] In the separator 58, an oil-free (or essentially oil-free) SMR vapour stream 84 is also sent into the heat exchanger system 40. In FIG. 2, the oil-free SMR vapour stream 84 enters the heat exchanger system 40 at an intermediate temperature, optionally at a similar temperature to that at the withdrawal of the cooled first SMR vapour stream 81. In the heat exchanger system 40, this oil-free SMR vapour stream 84 is cooled until it partly or wholly condenses, leaving the heat exchanger system 40 as a condensed SMR stream 85. Thereafter, the pressure is reduced via throttling valve 61, leading to partial vaporisation and temperature reduction to provide the expanded lowest-temperature SMR stream 86. The expanded lowest-temperature SMR stream 86 is the coolest SMR refrigerant stream in the SMR system 200, having a temperature below the oil-solidification temperature of the oil in the oil-injected screw compressor 52.

[0116] The expanded lowest-temperature SMR stream 86 is sent back into heat exchanger system 40, where it vaporises as it heats up, and in doing so, cools the warmer streams in the heat exchanger system 40 to provide the majority of the cooling duty. The SMR refrigerant stream 86 can merge with the expanded liquid-phase SMR stream 83 to form a single stream which leaves the heat exchanger system 40 as a post-cooling vapour stream 89, to be returned to refrigerant receiver 51.

[0117] In this way, the requirement in prior art arrangement in FIG. 1 for an external refrigerant cascade is removed, such that the condensation of mixed refrigerant at a temperature above oil solidification takes place by cooling within the liquefaction heat exchanger system. This represents a reduction in capital expenditure, and in overall plant size. The partial condensation necessary to remove compressor oil from the portion of refrigerant gas exposed to the lowest temperatures in the system is achieved without an external refrigerant cascade loop, having shifted that duty to the SMR recirculating system only.

[0118] FIG. 3 shows a more-detailed SMR recirculating system 101 being a first variation example of the SMR recirculating system 200 shown in FIG. 2. The first SMR recirculating system 101 comprises a single multi-stream liquefaction heat exchanger 57, (typically a brazed aluminium plate-fin heat exchanger), where the cooled (and compressed) BOG stream 71 is condensed by the colder streams discussed herein before in the SMR recirculating system 200.

[0119] FIG. 4 shows a second variation example SMR recirculating system 102 of the SMR recirculating system 200 shown in FIG. 2, wherein the liquefaction heat exchanger system now comprises two heat exchangers, being the first and second multi-stream heat exchange units 64 and 62. In FIG. 4, there is a mixing of cold streams externally of the heat exchange units 64 and 62. That is, the expanded lowest-temperature SMR stream or coldest refrigerant stream 86 is sent into the second unit 62, where it starts to vaporise as it heats up, and in doing so, cools the warmer streams in the second unit 62, and then exits as a part-warmer SMR stream 87 prior to merging with the expanded liquid-phase SMR stream 83 to form a combined stream 88, which then passes into the first unit 64 to cool the warmer streams in the first unit 64, and leaving the first unit 64 as a post-cooling vapour stream 89, to be returned to refrigerant receiver 51. Meanwhile, the cooled BOG from the first unit 64 passes as stream 72 into the second cooler unit 62.

[0120] The first and second heat exchange units 64 and 62 may be contiguous or separate.

[0121] FIG. 5 shows a third variation example SMR recirculating system 103, being a further variation of the SMR recirculating system 102 shown in FIG. 4. In FIG. 5, the liquefaction heat exchanger system comprises first and second multi-stream heat exchange units 63 and 62. Compared with FIG. 4, the expanded liquid-phase SMR stream 83 and part-warmer SMR stream 88 are kept separate in first unit 63. The first and second warmer SMR streams 90 and 91 provided by the liquefaction heat exchanger system are combined in the vapour phase after they leave the first unit 63 to form a combined post-cooling vapour stream 89, to be returned to refrigerant receiver 51.

[0122] FIG. 6 shows a fourth variation example SMR recirculating system 104, being another variation of the SMR recirculating system 102 shown in FIG. 4. In FIG. 6, the liquefaction heat exchanger system comprises first and second multi-stream heat exchange units 63A and 62. Compared with FIG. 4, the oil-free SMR vapour stream 95 provided by the vapour-liquid separator 58 now passes into the warmer first unit 63A to provide an intermediate stream 92, prior to passage through the cooler second unit 62 (to exit as a condensed SMR stream 85).

[0123] FIG. 7 shows a fifth variation example SMR recirculating system 105, being a combination of the third SMR recirculating system 103 shown in FIG. 5 and the fourth SMR recirculating system 104 shown in FIG. 6. In FIG. 7, the liquefaction heat exchanger system comprises first and second multi-stream heat exchange units 65 and 62, and the oil-free SMR vapour stream 95 provided by the vapour-liquid separator 58 now passes into the first warmer unit 65 (to provide an intermediate stream 92, prior to passage through the second cooler unit 62 to exit as a condensed SMR stream 85), and the expanded liquid-phase SMR stream 83 and part-warmer SMR stream 88 are kept separate in first unit 65. The first and second warmer SMR streams 93 and 94 provided by the liquefaction heat exchanger system are combined in the vapour phase after they leave the first unit 65 to form a combined post-cooling vapour stream 89, to be returned to refrigerant receiver 51.

[0124] FIG. 8 shows a sixth variation example SMR recirculating system 106, being a combination of the first SMR recirculating system 101 shown in FIG. 3 and the fourth SMR recirculating system 104 shown in FIG. 6. In FIG. 8, the liquefaction heat exchanger system comprises a single multi-stream liquefaction heat exchanger 66, and the oil-free SMR vapour stream 95 provided by the vapour-liquid separator 58 now passes fully through the heat exchanger 66 (to provide a condensed SMR stream 85), whilst the expanded liquid-phase SMR stream 83 merges with the refrigerant stream 86 at an intermediate location within the heat exchanger 66 to form a single stream which leaves the heat exchanger 66 as a post-cooling vapour stream 89, to be returned to refrigerant receiver 51.

[0125] FIG. 9 shows a seventh SMR variation example recirculation system 107, being a variant of the SMR recirculating system 104 shown in FIG. 6, wherein the first multi-stream heat exchange unit 63A in the liquefaction heat exchanger system is replaced by a series of two-stream heat exchangers. The series of two-stream heat exchangers still provide the same first and warmer stage or section of the liquefaction heat exchanger system, now using a series of distinct heat exchangers suitably arranged to work together.

[0126] In FIG. 9, the cooler first vapour stream 80 passes into a first two-stream heat exchanger 96 against a stream discussed hereinafter, to provide the cooled first SMR vapour stream 81 in the same manner as before, to pass into the vapour-liquid separator 58. From the separator 58, a liquid-phase SMR stream 82 is expanded by a flash valve 59 to provide an at least partly vaporised, liquid-phase SMR stream 83.

[0127] The separator 58 also provides the oil-free SMR vapour stream 95, which passes into a second two-stream heat exchanger 97 to provide an intermediate stream 92 prior to its passage into the same second unit 62 as discussed and shown in FIG. 6.

[0128] Meanwhile, the cooled and compressed BOG stream 71 passes into a third two-stream heat exchanger 98 to provide a cooler BOG stream 72 to pass into the second cooler unit 62.

[0129] The second unit 62 in FIG. 9 provides the condensed BOG stream 73 in the same manner as described above, and a part-warmer SMR stream 87, which merges with the expanded liquid-phase SMR stream 83 to form a combined stream 88, which is then divided into part-streams 99A and 99B. Part-stream 99A passes into the second heat exchanger 97, and part-stream 99B passes into the third heat exchanger 98. Their exit streams combine to form a combined stream 100 which then passes into the first heat exchanger 96 to exit as the post-cooling vapour stream 89.

[0130] Where the liquefaction heat exchanger system comprises multiple heat exchanger units, the present invention is not limited by the relative positioning of the first and second units, which may be contiguous or separate.

[0131] It is possible that the composition and/or ratio of components in the SMR can be varied to achieve best effect for each arrangement of the present invention. It is also possible that the SMR composition is different in each of the examples shown in FIGS. 3-9.

[0132] The present invention is a modification of a typical single mixed refrigerant (SMR) cycle for LNG re-liquefaction in particular, that allows the use of a cost-efficient oil-injected screw compressor in the mixed refrigerant system. In comparison with the typical arrangement, the present innovation allows for reduced complexity, fewer pieces of equipment, and reduced capital cost.