Torrefaction/gassification system
10221371 ยท 2019-03-05
Assignee
Inventors
Cpc classification
C10L5/447
CHEMISTRY; METALLURGY
Y10T29/49716
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y02E50/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y02E50/30
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
Abstract
A modified dryer operates on a different principle from that used by the prior torrefaction plants. The subject invention utilizes thermal conduction to torrefy the biomass in a vibratory reactor in which a heated solid unperforated plate is sealed in the reactor to separate the biomass above from the gas used to heat the plate below. This permits using inert flue gas to heat the reactor which in turn permits the use of a cool air damping system to prevent thermal runaway. Also syngas evolved from the process is utilized to power a gas engine, the exhaust output of which is recirculated to heat the reactor plate. When the gas engine is coupled to an electric generator, waste energy is recovered for use in other parts of the plant or exported elsewhere.
Claims
1. A method for modifying a vibratory dryer to provide a vibrating torrefaction reactor comprising the steps of: in a vibrating dryer having a multiplicity of conduits from the inside of the dryer to the outside of the dryer, sealing off all but a small predetermined number of conduits, providing the dryer with an unperforated solid plate from one side of the dryer to the other for supporting a biomass to be torrefied on top of the plate, the solid plate being inclined, non-planar and having a plurality of waffle-shaped ridges thereby providing more surface area to transfer energy while not impeding the conveyance of biomass; and, introducing a hot gas underneath the unperforated solid plate, conductively transferring heat through the plate from the hot gas to the biomass, whereby convective heating roasts the biomass in a torrefaction process.
2. The method of claim 1, and further including an exit conduit for removal of syngas from the reactor.
3. The method of claim 2, and further including duct work coupled to the exit conduit and a flexible heat resistant gland between the exit conduit and associated duct work, whereby the vibratory motion of the reactor against the duct work is accommodated by the gland, such that the reactor has only one syngas port at which leakage can occur.
4. The method of claim 2, further comprising ducting the syngas directly to a gas engine for immediate combustion and introducing an exhaust from the gas engine beneath the plate to provide the hot gas, wherein the hot gas is non-volatile, thereby eliminating the exposure of syngas or other volatile gas to the reactor.
5. The method of claim 4 and further including mechanically coupling an electrical generator to the gas engine for the production of electricity thereby increasing the efficiency of a torrefaction reactor such that the overall energy efficiency of the torrefaction process exceeds 80%.
6. The method of claim 1 further comprising: injecting cold air along with the hot gas into the reactor to regulate the temperature of the reactor, wherein the plate extends from one end of the reactor to the other to form a bottom plenum, wherein the plate is impermeable, the solid plate preventing syngas that evolves in the torrefaction process from being exposed to oxygen.
7. The method of claim 6, wherein the reactor includes a gas engine and wherein the hot gas is from an exhaust of the gas engine.
8. The method of claim 7, wherein and further including an electric generator coupled to the gas engine with the electrical generator provided with a current sensor, wherein the conduit that channels the syngas to the gas engine includes a pressure transducer and wherein the injection of the hot gas into the reactor includes an inlet conduit having an thermocouple sensor and further including a damper assembly for the injection of the cold air controlled by the output of the current sensor, the pressure transducer and the thermocouple sensor.
9. The method of claim 8, wherein the syngas evolving from the reactor is cooled before being used as a fuel for the gas engine.
10. The method of claim 9, wherein as a result of the cooling of the syngas, tar is removed.
11. The method of claim 1 further comprising the steps of: blocking off all exit ports of the dryer with the exception of an exit port utilized to bleed off syngas in the torrefaction process: and, providing a flexible gasketed conduit for the syngas from the torrefaction process, whereby the number of conduits that need to be gasketed is reduced over the original number of conduits.
12. A method for torrefying a biomass, comprising the steps of providing a reactor that is fabricated with a solid plate wherein the solid plate is non-planar and unperforated, thereby providing more surface area to transfer energy; introducing the biomass onto the solid plate; heating the solid plate from underneath with hot inert gas such that heat from the hot inert gas is conductively transferred to the biomass through the heating of the solid plate, generating a syngas by-product.
13. The method of claim 12, and further including a gas engine and a conduit for the evolving syngas coupled between the reactor and the gas engine.
14. The method of claim 13, and further including using the exhaust from the gas engine to heat the solid plate, thereby providing a heat exchanger.
15. A method for modifying a vibratory dryer to provide a vibrating torrefaction reactor comprising the steps of: sealing off all but a small predetermined number of conduits in a vibrating dryer having a multiplicity of conduits from the inside of the dryer to the outside of the dryer, providing the dryer with an unperforated solid plate from one side of the dryer to the other for supporting a biomass to be torrefied on top of the plate, the unperforated solid plate being inclined, non-planar and having a plurality of waffle-shaped ridges thereby providing more surface area to transfer energy while not impeding the conveyance of biomass; introducing a hot gas underneath the unperforated solid plate, conductively transferring heat through the plate from the hot gas to the biomass, whereby convective heating roasts the biomass in a torrefaction process; maintaining one of the conduits from the multiplicity of conduits as an exit conduit for removal of syngas from the reactor; ducting the syngas directly to a gas engine for immediate combustion; introducing an exhaust from the gas engine beneath the plate to provide the hot gas, wherein the hot gas is non-volatile, thereby eliminating the exposure of syngas or other volatile gas to the reactor.
16. The method of claim 15, wherein the waffle-shaped ridges further comprise a plurality of protuberances for a conductive transfer of heat from non-volatile flue gas in the bottom plenum to the top plenum which contains biomass and volatile syngas.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) These and other features of the subject invention will be better understood in connection with the Detailed Description, in conjunction with the Drawings, of which:
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DETAILED DESCRIPTION
Prior Art
(10) Referring now to
(11) Referring to
(12) Here it can be seen that the vibration of reactor 10 is accommodated through glands or flexible joints 24 which, inter alia, must be capable of porting the hot syngas at 300 C. out of the reactor and be able to port heated syngas into the bottom of the reactor.
(13) It is noted that the vibratory dryer is modified in this prior art installation in which the commercial dryer is used to migrate material through the dryer with no moving parts. In essence for this prior art installation there were very few changes necessary to convert the vibratory dryer to a torrefaction reactor. The first physical change made is that a modified perforated plate is used within the dryer to support the biomass which incorporates wood chips that for instance tend to turn to dust. The dust as it will be appreciated will fall through the holes in the perforated plate as originally supplied.
(14) How this prior art reactor works is shown in
(15) The torrefaction process starts with providing heated gas 56 beneath perforated plate 40 such that it passes through orifices 58 in plate 40 and then passes as illustrated at 60 through the wood chip biomass to roast or torrefy the wood chips such that what exits screw conveyor 50 in one embodiment is biocoal or briquettes due to the roasting or torrefaction process. The efficiency of the torrefaction process is defined by the energy output from the process in the form of biocoal divided by the energy input to the process in the form of biomass, typically wood. The net energy lost in the process is in the form of syngas evolved which functionally is lost from the process as radiated or exhausted heat.
(16) In order to capture and utilize waste heat from the process, syngas 54 is piped through the aforementioned conduits 12 and manifold 14 to a blower 62 such that the evolving 300 C. syngas is forced out of the blower and into a heat exchanger 64. The ideal heat for the convective heating shown in
(17) Here it can be seen that off center weights 70 rotating as illustrated by arrows 72 cause reactor 10 to vibrate so as to move the biomass from screw conveyor 44 to screw conveyor 50.
(18) Referring now to
(19) Here it can be seen through the thickness of arrows 74 and 76 that the flow rate from the burner is significantly less than the massive flow rate output of 62 which may be for instance as low as 250 C. As illustrated at manifold 32 a heated low volume syngas output at 500 C. is mixed with the high volume output from fan 62 such that the temperature of the syngas from the blower is heat augmented using the output of burner 66.
(20) As mentioned above, the physical change to the commercial carrier vibratory dryer includes the utilization of a modified perforated plate in which the apertures in the plate are sized to minimize the amount of dust that can fall through the holes when hot gases are moving upwardly through the apertures in the plate. In one embodiment, not shown, small covers are placed over the holes such that the dust is not allowed to fall back down through the holes.
(21) The second change for the commercial vibratory dryer is that the dryer is no longer drying materials, i.e. removing moisture, other than wood but is now heated to a temperature which will roast the wood chips and is much like putting wood into a frying pan, with the wood giving off flammable gases such as methane, hydrogen, acetic acid and carbon monoxide.
(22) The end result is that instead of using a unit which circulates air in a drying process, in a torrefaction application what is actually generated is recirculated syngas. It will be appreciated that synthetic gas or syngas is a low BTU gas that can be generated for instance from landfill gas and more particularly from wood or from coal. Syngas is used instead of methane which has a heat value of 1,000 BTU per cubic foot because of its ready availability and low cost. Specifically the range for syngas is on the order of 200 to 400 BTU such that what is utilized in the torrefaction process is a low BTU synthetic gas.
Safety
(23) a) Reducing Number of Conduits
(24) In the above prior art torrefaction process there is a considerable safety concern because syngas has replaced air in the dryer and the temperature of the dryer in the torrefaction process is on the order of 300 C. as opposed to for instance 60 C. for commercial drying. At these higher temperatures with syngas one creates a massive safety risk such that any leak is going to involve a flammable hot gas that is looking for oxygen.
(25) It is noted that the prior art reactor is intended to be a closed system in which the leakage of oxygen into the reactor is specifically to be avoided. In practice upon starting up of the system a small amount of oxygen is consumed in regular combustion. For the first 10 to 15 minutes the wood that is on top of the perforated plate is actually combusting. Once all of the oxygen is consumed one is creating more and more syngas and this is done in an oxygen-free environment thereafter recirculation of the syngas is ultimately used to produce heat to drive the process.
(26) In the prior art reactors of
(27) Originally the flexible connections were made out of fabric but the fabric could not handle the temperatures and would eventually rupture and result in leaks. Thereafter the glands were made in the form of a convoluted stainless steel expansion bellows system which partially mitigated the problem and were able to handle the high temperatures. However, the vibration in and of itself loosened these glands and with as many as 15 of these metal connections if any one of them leaks it puts syngas into the facility and is an ever present risk. Also because syngas is predominantly carbon monoxide, health and safety of the employees in such a plant are also a significant risk.
(28) Thus, the plugging of most of the holes for the prior art conduits significantly reduces the possibility of fire or explosion due to the fact that only one syngas joint or flange need be addressed for maintenance purposes. Note also that whatever syngas is utilized exists only within the reactor and that the utilization of an external recirculating blower and external heat exchanger is eliminated, thereby eliminating the flammable syngas recirculation loop of the prior art system shown in
(29) Significant modifications to the standard vibratory dryer first and foremost include closing all but one of the ducts that are used to recirculate the syngas. This can be seen in
(30) b) Conductive Heating and the Use of a Solid Torrefaction Plate
(31) It will be seen that rather than using convective heating, in the subject application a solid plate 100 is utilized to support biomass 42 which comes in from screw conveyer 44 and exits from that screw conveyer 50. Here the hot inert gas is illustrated at 102 to impinge upon the lower surface of plate 100 where it heats the plate to 500 C. It will be appreciated that biomass 42 is roasted in very much the same way as using a frying pan in which the biomass is cooked on top of plate 100. Note that convective elements within the top portion of the reactor itself facilitate internal convention much like a convection oven but without the need to remove or recirculate the syngas from the reactor.
(32) What will also be appreciated is that plate 100 is sealed to the ends 104 and 106 of chamber 10, thereby to divide chamber 10 into a lower chamber or plenum 110 and an upper chamber or plenum 112. The result is that while inert gas from gas engine 88 is utilized to heat plate 100, the only portion of the reactor at which flammable gas exists is above plate 100 and with the utilization of only one conduit 80 the leakage associated with the vibration is minimized.
(33) It is noted that the feedstock, namely the wood chips input, exist at approximately 20 C., whereas the torrefied material exits at a relatively hot 300 C. due to the torrefaction that takes place above plate 100. This material is subsequently cooled back to 20 C. by the outlet screw to stop the torrefaction process.
(34) c) Thermal Runaway
(35) As will be discussed more completely hereinafter, thermal runaway is controlled by the ingress of cold air 114 using a cold air blower 116 and a damper and valve assembly 118 such that the non-volatile exhaust gas from engine 88 may be cooled through the ingestion of cold air from outside. It is noted that since only the upper chamber contains flammable gas and since the exhaust output from the gas engine includes nitrogen, CO.sub.2 and O.sub.2, the control of the heat applied to plate 100 can be rapidly controlled through this cold air damper system.
(36) As will be discussed, a control unit or module 120 controls damper assembly 118 through the output of a thermal couple sensor 122 at conduit 92, a pressure transducer 124 which measures the pressure in conduit 80, and a current sensor 126 which senses the energy removed from the reactor by the gas engine in terms of the current and the kilowatt-hours generated. It will be seen that a balancing of the temperature, pressure and electric current output can effectively modulate the temperature of the incoming gas at 94 so as to stabilize the temperature of the gas applied to the bottom of plate 100.
System Details
(37) It will be appreciated that all of the syngas evolving from the subject process is leaving the reactor through a single pipe as shown in
(38) While a gas engine has been described other types of syngas fired heating units may be utilized such as a gas turbine, burner or a boiler. However because a gas engine also provides a rotary output to drive an electric generator as illustrated by dotted line 128 the electrical energy generated may be used by the plant to power the vibrating motors and other plant equipment as well as sell the unused electricity to the grid.
(39) Referring back to
(40) It is noted that the hot flue gas from the gas engine is ducted to the bottom plenum 110 with one pipe and while there is some oxygen left over in the combustion flue gas from the gas engine, the output from the gas engine is predominantly nitrogen and carbon dioxide which is non-volatile and basically inert. This inert gas is completely safe as far as employees are concerned and as the utilization of this inert flue gas limits the possibility of explosion. It will be appreciated that the output gas from the engine is around 500 C., whereas the syngas is around 300 to 400 C. It is this differential temperature that is utilized in the drive heat transfer. If there is insufficient heat transfer from the plate to the biomass one can actually introduce a fan into the upper plenum or chamber to stir up the evolving syngas very much like a convection oven to help with transfer. However in most instances this is not necessary.
(41) In summary, the subject system utilizes conduction to transfer heat from the exhaust gas in the lower plenum to the upper plenum and then into the biomass itself. It is noted that gas engines are utilized because they can run on low energy fuels such as syngas at high efficiency as well as across a wide variety of load. These gas engines are readily available especially from engine manufacturers supplying landfill companies and are particularly appropriate for use in the subject system because the exit temperature of the gas is exactly that which is necessary to heat the reactor. The gas engine is also very efficient in producing electricity making it a good additional profit center.
Thermal Efficiency
(42) It is noted that prior torrefaction plants have exhibited an average 50-60% thermal efficiency in part because the amount of evolved syngas cannot be adequately controlled and the excess heat generated is lost. Those that use boilers to extract heat to make steam might have a 66-67% thermal efficiency. However using a syngas fueled gas engine and electrical generator raises the overall thermal efficiency to as high as 80%.
(43) In operation one does not initially have syngas. To start up the reactor one first starts up the engine utilizing natural gas to fire and idle the gas engine. Very little natural gas is utilized to initially power the gas engine and in point of fact the gas engine only idles when starting on natural gas. Once heated the reactor is actively made inert with steam and inert nitrogen so that no combustion happens in the reactor. Biomass is introduced slowly at first until syngas is evolved. Then the engine power increases allowing for biomass input to increase and the process slowly ramps up.
(44) It will be appreciated that for torrefied wood ideally 20 percent of the input wood energy is turned into syngas and subsequently heat and the rest of the energy comes out as biocoal. This biocoal is a brown to black product.
(45) The problem with respect to thermal runaway is that when wood is torrefied at 250 C. to 300 C. about 40 percent of the thermal energy within the wood when torrefying wood is volatile at these temperatures and managing the process so that only 20% is evolved is an exacting control issue requiring razor sharp response time and also the ability to both add and remove heat from the process. One wants to utilize only 20 percent of the heat, because anything more would be wasted. If one cannot soak up the remaining 20 percent of the torrefaction heat generated, the process tends to want to run away. This is because the process wants everything that is volatile at 340 C. to exit the wood. This in turn makes most torrefaction processes very inefficient.
Efficiency and Thermal Runaway
(46) It is also this inability to utilize the heat that is generated in the process which causes thermal runaway that leads to high reactor temperatures, fires and a large number of other safety concerns. Thus what is required in the torrefaction process is roasting the wood such that only 20 percent of the input heat is used to cook the wood. It will be appreciated that the increased heat over the 20 percent produces more volatiles and the process tends to run away with no safety features built in to prevent thermal runaway in the prior torrefaction processes.
(47) Referring now to
(48) Thus the air damper system shown in
(49) It will be noted that combustion in a gas engine is relatively stable from the exhaust temperature standpoint, known for a given load although the volume of exhaust also changes making load indication a valuable control signal. Thus this design is inherently more stable than the prior designs, with the advantage of the gas engine being that the gas engines are about 40 percent thermally efficient across a wide variety of loads. In short these engines are exceptional thermal conversion machines. They are much better for instance than boiler steam power plants which are typically about 20% thermally efficient. Thus of the 40 percent volatiles syngas energy available if one takes 20 percent, or roughly half, for the roasting process and one converts the other 20 percent, the excess half, that naturally occurs into electrical energy, instead of contributing to thermal runaway this system actually produces electrical energy that removes this 20 percent heat overage, thus to stabilize the torrefaction process by pulling exactly the right amount of energy out.
(50) One simple way to explain this is that 40 percent of the energy in the wood wants to become volatile at torrefaction temperatures and the intent is to use the entire 40 percent by bleeding off 20 percent to run an electric generator. This is in contrast to the prior torrefaction processes that are trying to operate on a knife edge to control the energies associated with the volatiles component. Thus, by taking out 20 percent of the energy associated with the volatiles one can stabilize the entire system. Note that the amount of energy taken out is adjustable in terms of the load on the generator and temperature of the reactor.
(51) It might be thought that thermal control could be exercised simply by running a generator from the syngas fueled gas engine. The reason this is a problem is because the generator usually has a fixed maximum capacity of, for instance 560 kilowatts, and one runs the risk of actually running out of capacity in the generator. If one wants to run the generator flat out all the time one can reach the maximum capacity of the generator which in turn limits the amount of energy that can be withdrawn from the system. Thus, the maximum capacity of the generator limits the amount of energy that can be taken out. This problem is solved by the subject air damping system that permits the operators to set the maximum capacity of the generator without having to take into account the maximum capacity of the generator.
(52) If the reactor starts producing more gas than the engine can handle one has two options. One can start putting in less wood but when wood first comes in and then leaves the reactor it takes about 30 minutes to show any change. The alternative is to inject the aforementioned cold dilution air.
(53) In one embodiment, the aforementioned pressure transducer 124 is used as a sensing mechanism to turn on the cold air. That along with the temperature thermocouple and a current sensor on the electrical generation system completes the feedback control for the damper. Of course in the event of a massive thermal runaway which is not accommodated by the above, one can utilize a stop button which simply turns the entire wood supply process off and immediately cools the reactor with the dilution damper blower in short order.
(54) Note that the thermocouple sensor on conduit 92 provides the primarily feedback loop to make sure that one actually has not opened the cold air damper too much. When the damper first opens it is using a current feedback loop to set for instance the temperature target at 500 C. If for instance the output gas from the generator is 600 C., in order to control the process wants to inject cool air. However one certainly does not want to go to ambient temperature. That would be too far. It is noted that the current sensor measures generator capacity such that no damping happens unless the generator is at full capacity. It is noted that if the current sensor is not at maximum, any more gas produced will just load up the engine to consume more of the gas. Once the generator has hit maximum capacity the pressure transducer reports that the system can tolerate some additional pressure to build up as a buffer in this type of system. However pressure in pipe 80 has a safety limit and again is utilized for safety purposes to make sure the pressure is not exceeded. It is noted that even when using a single pipe one does not want to operate that pipe at very high pressure because it will create a leak which will be a health and fire safety concern. One can regulate the pressure to a certain predetermined maximum utilizing the subject damper which modulates the temperature. This occurs by opening up the air which will lower the exhaust temperature a little bit and will keep the reactor from producing more syngas, with these two operating back and forth to naturally moderate the system.
(55) It is noted that the cool air damper system works because the gas from the engine is non-volatile and one can simply cool it or not with direct dilution, as opposed to a heat exchanger, and nothing untoward happens. However one cannot mix cold air with syngas as it would combust or potentially explode.
(56) In summary, syngas is generated from the reactor and is used to produce heat to roast the wood in a torrefaction process. The process in one embodiment uses a gas engine to extract energy as both electricity and heat from the syngas.
(57) It is noted that one can also remove heat either using a boiler to make steam or one can simply combust the syngas in an oxidizer. The problem with the oxidizer is that it simply produces far more heat than the process needs. Note that the use of an oxidizer is generally counter-indicated because it is a low pressure device and operates on ambient combustion with the required duct work being on the order of 24 to 30 inches diameter. On the other hand a gas engine is essentially an air pump and one can combust gas at fairly substantial pressures both on the intake side and the compressed out exhaust side. This means that one can utilize 12-18 inch exhaust pipes which are much smaller.
(58) Referring now to
(59) While the present invention has been described in connection with the preferred embodiments of the various figures, it is to be understood that other similar embodiments may be used or modifications or additions may be made to the described embodiment for performing the same function of the present invention without deviating therefrom. Therefore, the present invention should not be limited to any single embodiment, but rather construed in breadth and scope in accordance with the recitation of the appended claims.