LAMINAR FLOW COATING FOR AERODYNAMIC SURFACES
20190062569 ยท 2019-02-28
Assignee
Inventors
Cpc classification
B64C21/10
PERFORMING OPERATIONS; TRANSPORTING
F05D2230/90
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
C09D163/00
CHEMISTRY; METALLURGY
C08L71/00
CHEMISTRY; METALLURGY
C08K3/00
CHEMISTRY; METALLURGY
Y02T50/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C08G2650/48
CHEMISTRY; METALLURGY
C09D163/00
CHEMISTRY; METALLURGY
C08L71/00
CHEMISTRY; METALLURGY
C09D5/1681
CHEMISTRY; METALLURGY
C08K3/042
CHEMISTRY; METALLURGY
C08K3/00
CHEMISTRY; METALLURGY
International classification
C09D163/00
CHEMISTRY; METALLURGY
Abstract
A laminar flow coating for aerodynamic surfaces is provided. The laminar flow coating may comprise a base composition, such as an epoxy composition, a fluoropolyurethane composition, or a polyurethane composition. A filler composition may be dispersed within the base composition. The filler composition may comprise at least one of a nanomaterial composition or a microfiller composition. The filler composition may be doped with a hydrophobic surface modifier prior to being dispersed within the base composition.
Claims
1. A laminar flow coating, comprising: a base composition comprising at least one of an epoxy composition, a fluoropolyurethane composition, or a polyurethane composition; and a filler composition comprising at least one of a nanomaterial composition or a microfiller composition, wherein the filler composition is doped with a hydrophobic surface modifier and is dispersed within the base composition.
2. The laminar flow coating of claim 1, wherein the nanomaterial composition comprises at least one of a graphene nanoplatelet, a graphene nanosheet, a metal oxide particulate, a nanoclay, or a hexagonal boron nitride nanosheet.
3. The laminar flow coating of claim 1, wherein the microfiller composition comprises at least one of a metal oxide, polytetrafluoroethylene (PTFE), fluoroethylene propylene (FEP), polyvinylidene fluoride (PVDF), or fluoroalkoxy polymer.
4. The laminar flow coating of claim 1, wherein the hydrophobic surface modifier comprises an organic molecule or an inorganic molecule containing a hydrolysable unit and a long chain alkane unit that can be at least one of hydrogenated or fluorinated.
5. The laminar flow coating of claim 4, wherein the hydrophobic surface modifier comprises at least one of an organic ligand or an inorganic ligand.
6. The laminar flow coating of claim 5, wherein the organic ligand comprises at least one of dodecylamine, perfluorododecylamine, octylamine, 1H,1H-Perfluorooctylamine, or oleic acid, and wherein the inorganic ligand comprises at least one of a titanate functional agent, a phosphonate functional agent, a silane functional agent, or a perfluorosilane functional agent.
7. The laminar flow coating of claim 1, wherein the filler composition is dispersed within the base composition using at least one of a sonication processing method or a high shear mixing method.
8. A nacelle, comprising: an aerodynamic surface; and a laminar flow coating coupled to the aerodynamic surface, the laminar flow coating comprising: a base composition comprising at least one of an epoxy composition, a fluoropolyurethane composition or a polyurethane composition; and a filler composition comprising at least one of a nanomaterial composition or a microfiller composition, wherein the filler composition is doped with a hydrophobic surface modifier and is dispersed within the base composition.
9. The nacelle of claim 8, wherein the nanomaterial composition comprises at least one of a graphene nanoplatelet, a graphene nanosheet, a metal oxide particulate, a nanoclay, or a hexagonal boron nitride nanosheet.
10. The nacelle of claim 8, wherein the microfiller composition comprises at least one of a metal oxide, polytetrafluoroethylene (PTFE), fluoroethylene propylene (FEP), polyvinylidene fluoride (PVDF), or fluoroalkoxy polymer.
11. The nacelle of claim 8, wherein the hydrophobic surface modifier comprises at least one of an organic ligand or an inorganic ligand.
12. The nacelle of claim 11, wherein the organic ligand comprises at least one of dodecylamine, perfluorododecylamine, octylamine, 1H,1H-Perfluorooctylamine, or oleic acid, and wherein the inorganic ligand comprises at least one of a titanate functional agent, a phosphonate functional agent, a silane functional agent, or a perfluorosilane functional agent.
13. The nacelle of claim 8, wherein the laminar flow coating comprises a thickness on the aerodynamic surface of about 0.001 inch to about 0.025 inch.
14. The nacelle of claim 8, further comprising an inlet having a leading edge, wherein the aerodynamic surface comprises the leading edge of the inlet.
15. A method, comprising: preparing a base composition, wherein the base composition comprises at least one of an epoxy composition, a fluoropolyurethane composition, or a polyurethane composition; dispersing a filler composition into the base composition to form a laminar flow slurry, wherein the filler composition comprises at least one of a nanomaterial composition or a microfiller composition; at least one of applying the laminar flow slurry on to an aerodynamic surface or preparing a laminar coating film from the laminar flow slurry and applying the laminar coating film on to the aerodynamic surface; and curing at least one of the laminar flow slurry or the laminar coating film to form a laminar flow coating.
16. The method of claim 15, further comprising doping the filler composition with a hydrophobic surface modifier, wherein the hydrophobic surface modifier comprises at least one of an organic ligand or an inorganic ligand, wherein the organic ligand comprises at least one of dodecylamine, perfluorododecylamine, octylamine, 1H,1H-Perfluorooctylamine, or oleic acid, and wherein the inorganic ligand comprises at least one of a titanate functional agent, a phosphonate functional agent, a silane functional agent, or a perfluorosilane functional agent.
17. The method of claim 16, wherein the nanomaterial composition comprises at least one of a graphene nanoplatelet, a graphene nanosheet, a metal oxide particulate, a nanoclay, or a hexagonal boron nitride nanosheet.
18. The method of claim 16, wherein the microfiller composition comprises at least one of a metal oxide, polytetrafluoroethylene (PTFE), fluoroethylene propylene (FEP), polyvinylidene fluoride (PVDF), or fluoroalkoxy polymer.
19. The method of claim 15, wherein the base composition is prepared by mixing a base component and an activator component, and wherein the filler composition is dispersed into the base component prior to the base component being mixed with the activator component.
20. The method of claim 15, wherein the filler composition is mixed into an external solvent prior to being dispersed within the base composition.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0010] The subject matter of the present disclosure is particularly pointed out and distinctly claimed in the concluding portion of the specification. A more complete understanding of the present disclosure, however, may best be obtained by referring to the detailed description and claims when considered in connection with the following illustrative figures. In the following figures, like reference numbers refer to similar elements and steps throughout the figures.
[0011]
[0012]
[0013]
[0014] Elements and steps in the figures are illustrated for simplicity and clarity and have not necessarily been rendered according to any particular sequence. For example, steps that may be performed concurrently or in different order are illustrated in the figures to help to improve understanding of embodiments of the present disclosure.
DETAILED DESCRIPTION
[0015] The detailed description of exemplary embodiments herein makes reference to the accompanying drawings, which show exemplary embodiments by way of illustration. While these exemplary embodiments are described in sufficient detail to enable those skilled in the art to practice the disclosures, it should be understood that other embodiments may be realized and that logical, chemical, and mechanical changes and adaptations in design and construction may be made in accordance with this disclosure and the teachings herein. Thus, the detailed description herein is presented for purposes of illustration only and not of limitation.
[0016] The scope of the disclosure is defined by the appended claims and their legal equivalents rather than by merely the examples described. For example, the steps recited in any of the method or process descriptions may be executed in any order and are not necessarily limited to the order presented. Furthermore, any reference to singular includes plural embodiments, and any reference to more than one component or step may include a singular embodiment or step. Also, any reference to attached, fixed, coupled, connected or the like may include permanent, removable, temporary, partial, full and/or any other possible attachment option. Additionally, any reference to without contact (or similar phrases) may also include reduced contact or minimal contact.
[0017] All ranges may include upper and lower values, and all ranges and ratio limits disclosed herein may be combined. It is to understood that unless specifically stated otherwise, references to a, an, and/or the may include one or more than one and that reference to an item in the singular may also include the item in the plural.
[0018] As used herein, aft refers to the direction associated with the tail (e.g., the back end) of an aircraft, or generally, to the direction of exhaust of the gas turbine. As used herein, forward refers to the direction associated with the nose (e.g., the front end) of an aircraft, or generally, to the direction of flight or motion.
[0019] Referring to
[0020] In various embodiments, nacelle 10 may comprise a leading edge 13. Leading edge 13 may define a portion of nacelle 10 extending in an aft direction from inlet 12 towards fan cowl 14. In that respect, leading edge 13 may define an aerodynamic surface of nacelle 10 wherein an increase in natural laminar flow may lead to an increase in fuel efficiency in a gas turbine engine.
[0021] In various embodiments, aerodynamic surfaces of an aircraft, such as leading edge 13 of nacelle 10 and portions of inlet 12 and/or fan cowl 14 aft of leading edge 13, contours of aircraft wings, an empennage of a tail, or the like, may be exposed to insect impact and residue during flight. Insect residue build-up comprising heights as low as 0.003 inch (0.0762 mm) may disrupt the natural laminar flow over the aerodynamic surfaces leading to a loss in fuel efficiency. Therefore, the aerodynamic surfaces, including leading edge 13 of nacelle 10 and/or portions of inlet 12 and/or fan cowl 14 aft of leading edge 13, may comprise a laminar flow coating 100 configured to provide a barrier against insect residue adhesion. In various embodiments, laminar flow coating 100 may also be applied to any other suitable surface of nacelle 10, or an aircraft, such as inlet 12, fan cowl 14, and thrust reverser 16. In that regard, laminar flow coating 100 may provide a low surface energy coating (e.g., exhibited by the filler materials) that can at least partially mitigate insect residue adhesion on leading edge 13 while also surviving weather conditions during flight (e.g., rain erosion, hail erosion, etc.). For example, laminar flow coating 100 may provide a low surface energy coating due at least partially to the inherent energy absorbing nature of base composition 110 (e.g., polyurethane materials, as discussed further herein). It should be appreciated that while this disclosure is described in the context of aerodynamic surfaces on an aircraft, and more specifically to leading edge 13 of nacelle 10, the systems and methods described herein may be implemented in various other contexts (e.g., other aerodynamic surfaces in an automobile, boat, wind turbine, or the like wherein use of laminar flow coating 100 may be desired).
[0022] With reference to
[0023] In various embodiments, laminar flow coating 100 may comprise a base composition 110 and a filler composition 120. Base composition 110 may comprise any suitable host composition, such as, for example, a low surface energy, high solids matrix coating. For example, base composition 110 may comprise an epoxy coating, a fluoropolyurethane coating, a polyurethane coating, or any other suitable coating or composition. The fluoropolyurethane coating and/or the polyurethane coating may each comprise various sub-compositions. For example, the fluoropolyurethane coating may comprise a fluoropolyurethane base component and a fluoropolyurethane activator component. The fluoropolyurethane base component may first be agitated or stirred to ensure that solids are uniformly dispersed, prior to the fluoropolyurethane activator component being added and mixed. As a further example, the polyurethane coating may comprise a polyurethane base component, a polyurethane activator component, and a polyurethane thinner component. The polyurethane base component may first be agitated or stirred to ensure that solids are uniformly dispersed, prior to the polyurethane activator component being added and mixed. The polyurethane thinner component may be added to achieve a desired viscosity in base composition 110.
[0024] In various embodiments, filler composition 120 may be dispersed within base composition 110 prior to the laminar flow slurry (or the laminar coating film, as discussed further herein) being applied to leading edge 13. Filler composition 120 may be configured to reinforce base composition 110 and to at least partially lower the surface energy in laminar flow coating 100. In that respect, filler composition 120 may comprise nanomaterials and/or microfillers. For example, filler composition 120 may comprise a nanomaterial such as graphene nanoplatelets, graphene nanosheets, metal oxide nanoparticles (e.g., aluminum oxide (Al.sub.2O.sub.3) particulate, silicon dioxide (SiO.sub.2) particulate, titanium dioxide (TiO.sub.2) particulate, or the like, in powder form), nanoclays (e.g., montmorillonite), hexagonal boron nitride nanosheets, or the like. The graphene nanosheets may have a mean diameter of about 1 m (3.937e-5 inch) to about 25 m (9.843e-4 inch) and may have a thickness of 1-12 atomic layers. The graphene nanosheets may be dispersed in dimethyl sulfoxide (DMSO) (C.sub.2H.sub.6OS; Chemical Abstracts Service Registry Number 67-68-5), an alcohol, dimethylformamide ((CH.sub.3).sub.2NCH; Chemical Abstracts Service Registry Number 68-12-2), toluene (C.sub.6H.sub.5CH.sub.3; Chemical Abstracts Service Registry Number 108-88-3), n-methyl-2-pyrrolidone (NMP) (C.sub.5H.sub.9NO; Chemical Abstracts Service Registry Number 872-50-4), or the like, and may be at least partially oxygenized (containing about 0.1% oxygen to about 15% oxygen (wherein about as used in this context refers only to +/0.05%)). In various embodiments, the aluminum oxide may comprise a mean particle size of about 40 nanometers (nm) (1.5748e-6 inch) to about 50 nm (1.9685e-6 inch). In various embodiments, the silicon dioxide may comprise a mean particle size of about 10 nm (3.937e-7 inch) to about 20 nm (7.874e-7 inch). In various embodiments, the titanium dioxide may comprise a mean particle size of about 21 nm (8.2677e-7 inch). In various embodiments, the nanoclay may comprise a mean diameter of less than 25 m (9.843e-4 inch), and may have a thickness of 1 to 20 atomic layers. In various embodiments, the hexagonal boron nitride nanosheets may comprise a mean diameter of about 1 m (3.937e-5 inch) to about 13 m (5.118e-4 inch), and may have a thickness of 5-20 atomic layers. About as used in the above context refers only to +/0.5 nm (1.9685e-8 inch).
[0025] As a further example, filler composition 120 may comprise a microfiller composition. The microfiller composition may comprise a metal oxide (e.g., silicon dioxide (SiO.sub.2), aluminum oxide (Al.sub.2O.sub.3), or the like), a fluorinated polymer composition (e.g., polytetrafluoroethylene (PTFE) ((C.sub.2F.sub.4).sub.n), polyvinylidene fluoride (PVDF) ((C.sub.2H.sub.2F.sub.2).sub.n), fluoroethylene propylene (FEP), fluoroalkoxy polymer, or the like), and/or the like. The silicon dioxide may comprise a particle size of about 0.5 micrometers (m) (1.9685e-5 inch) to about 10 m (0.0003937 inch). The aluminum oxide may comprise a particle size of about 1 m (3.937e-5 inch) to about 50 m (0.00197 inch). The PTFE may comprise a particle size of about 1 m (3.937e-5 inch). About as used in the above context refers only to +/0.05 m (1.9685e-6 inch).
[0026] In various embodiments, filler composition 120 may be dispersed into base composition 110 based on a filler loading level. The filler loading level may comprise a percent of filler composition 120 in laminar flow coating 100, with respect to a percent of solid materials in base composition 110 (e.g., a polyurethane base composition may comprise, for example, 36% solid polyurethane, on a weight basis). In that regard, the filler loading level may comprise about 0% to about 10%, about 10% to about 15%, or about 15% to about 20% (wherein about as used in this context refers only to +/1%).
[0027] In various embodiments, filler composition 120 may be dispersed into base composition 110 to form the laminar flow slurry. For example, filler composition 120 may be dispersed directly into base composition 110. Filler composition 120 may be mixed into base composition 110 using sonication, high shear mixing, a combination of sonication and high shear mixing, or any other suitable mixing or processing method. During a sonication processing method, ultrasonic frequencies may be applied to agitate particles in a solution. For example, filler composition 120 mixed into base composition 110 may undergo the sonication processing method for about 20 minutes to about 180 minutes at an ultrasonic frequency of about 20 kHz to about 40 kHz. In response to using a high shear mixing processing method, filler composition 120 may be mixed into base composition 110 for about 5 minutes to about 20 minutes at a frequency of rotation of about 5,000 RPM to about 10,000 RPM. In that respect, filler composition 120 may be mixed into the base component (e.g., the epoxy base component, the fluoropolyurethane base component, or the polyurethane base component) or the thinner component (e.g., the polyurethane thinner component) of base composition 110.
[0028] In various embodiments, filler composition 120 may also be mixed into an external solvent before the solvent is added into base composition 110. For example, the external solvent may comprise n-methylpyrrolidone (C.sub.5H.sub.9NO; Chemical Abstracts Service Registry Number 872-50-4), dimethyl sulfoxide ((CH.sub.3).sub.2SO), isopropanol, ethanol, water, N,N-dimethylformamide (HCON(CH.sub.3).sub.2; Chemical Abstracts Service Registry Number 68-12-2), toluene (Chemical Abstracts Service Registry Number 108-88-3), and/or any suitable combination thereof. In that respect, filler composition 120 may be mixed into the external solvent, and the solvent/filler composition mixture may then be dispersed into base composition 110. For example, the solvent/filler composition mixture may be added to the base component (e.g., the epoxy base component, the fluoropolyurethane base component, or the polyurethane base component) or the thinner component (e.g., the polyurethane thinner component) of base composition 110.
[0029] In various embodiments, filler composition 120 may also be doped with a hydrophobic surface modifier. For example, filler composition 120 may be doped prior to being dispersed into base composition 110. In that respect, the hydrophobic surface modifier may be configured to bond with the particles in filler composition 120 to further reduce the surface energy in filler composition 120. Moreover, doping filler composition 120 with the hydrophobic surface modifier may also aid in creating a strong covalent bond between base composition 110 and filler composition 120 to further enhance weather erosion resistance.
[0030] In various embodiments, filler composition 120 may comprise any suitable hydrophobic surface modifier. For example, filler composition 120 may comprise an organic molecule or an inorganic molecule containing a hydrolysable unit (e.g., methoxy, ethoxy, amine, halogen, carboxylic acid, or the like), and a long chain alkane unit (C.sub.nH.sub.2n+2, where 20<n>8) that can be hydrogenated, fluorinated, or a combination thereof. For example, filler composition 120 may include organic ligands and/or inorganic ligands. The organic ligands may comprise any suitable hydrogenated or fluorinated alkane unit (e.g., linear, branched, or a combination thereof) that contains a long chain alkane unit (C.sub.nH.sub.2n+2, wherein 20<n>8) and a hydrolysable unit (e.g., methoxy, ethoxy, amine, halogen, carboxylic acid, or the like). For example, the organic ligand may comprise dodecylamine (C.sub.12H.sub.27N; Chemical Abstracts Service Registry Number 124-22-1), perfluorododecylamine (C.sub.12H.sub.4F.sub.23N), octylamine (C.sub.8H.sub.19N; Chemical Abstracts Service Registry Number 111-86-4), 1H,1H-Perfluorooctylamine (C.sub.8H.sub.4F.sub.15N), oleic acid (C.sub.18H.sub.34O.sub.2; Chemical Abstracts Service Registry Number 112-80-1), and/or any other suitable organic ligand.
[0031] The inorganic ligands may comprise, for example, titanate functional agents, phosphonate functional agents, silane functional agents, or perfluorosilane functional agents. For example, the silane functional agents may comprise functional units such as epoxides, amines, or the like that are useful based on the filler composition 120. The silane functional agent may comprise, for example, (3-Glycidoxypropyl)trimethoxysilane (C.sub.9H.sub.20O.sub.5Si; Chemical Abstracts Service Registry Number 2530-83-8), [3-(2-Aminoethylamino)propyl]trimethoxysilane (C.sub.8H.sub.22N.sub.2O.sub.3Si; Chemical Abstracts Service Registry Number 1760-24-3), or (3-Aminopropyl)triethoxysilane (C.sub.9H.sub.23NO.sub.3Si; Chemical Abstracts Service Registry Number 919-30-2). The perfluorosilane functional agent may comprise any suitable fluorinated silane (whether linear, branched, or a combination thereof), such as, for example a fluorinated silane having a short alkyl chain (e.g., C.sub.nF.sub.2n+2, wherein n=<4) (e.g., Trichloro(3,3,3-trifluoropropyl)silane (C.sub.6H.sub.13CL.sub.3F.sub.3O.sub.3Si; Chemical Abstracts Service Registry Number 429-60-7)), or a fluorinated silane having a long alkyl chain (e.g., C.sub.nF.sub.2n+2, wherein n=8-20) (e.g., 1H, 1H, 2H, 2H-Perfluorooctyltriethoxysilane (C.sub.14H.sub.19F.sub.13O.sub.3Si; Chemical Abstracts Service Registry Number 51851-37-7)). The perfluorosilane functional agent may contain one, two, or three hydrolysable units comprising of methoxy (OCH.sub.3), ethoxy (OCH.sub.2CH.sub.3), or halide such as chloride (Cl), or any combination thereof.
[0032] In various embodiments, and with reference to
[0033] Method 301 may comprise doping the filler composition with a hydrophobic surface modifier (step 306). For example, the filler composition may be doped with the hydrophobic surface modifier prior to the filler composition being dispersed into the base composition (e.g., prior to the formation of the laminar flow slurry in step 304). In that respect, the filler composition may be chemically altered by the hydrophobic surface modifier to reinforce the filler composition particles and reduce surface energy. The hydrophobic surface modifier may be any of the hydrophobic surface modifiers discussed herein, such as an organic ligand, a silane functional agent, or a perfluorosilane functional agent.
[0034] In various embodiments, method 301 may comprise applying the laminar flow slurry to an aerodynamic surface (step 308). In that regard, the laminar flow slurry may be applied to an aerodynamic surface of an aircraft, such as leading edge 13 of nacelle 10, with brief reference to
[0035] Method 301 may comprise curing the laminar flow slurry to form a laminar flow coating (step 310). For example, the slurry may be left to dry and cure for a period of about one day to about three days, about three days to about five days, or about five days to about seven days, or any other suitable amount of time. In other words, drying the laminar flow slurry forms the laminar flow coating. In various embodiments, in response to the laminar flow slurry first being prepared into the laminar coating film prior to being applied to the aerodynamic surface, the laminar coating film may be cured to form the laminar flow coating. For example, the laminar coating film may be left to dry and cure for a period of about one day to about three days, about three days to about five days, or about five days to about seven days, or any other suitable amount of time. In other words, drying the laminar coating film forms the laminar flow coating.
[0036] Benefits, other advantages, and solutions to problems have been described herein with regard to specific embodiments. Furthermore, the connecting lines shown in the various figures contained herein are intended to represent exemplary functional relationships and/or physical couplings between the various elements. It should be noted that many alternative or additional functional relationships or physical connections may be present in a practical system. However, the benefits, advantages, solutions to problems, and any elements that may cause any benefit, advantage, or solution to occur or become more pronounced are not to be construed as critical, required, or essential features or elements of the disclosures. The scope of the disclosures is accordingly to be limited by nothing other than the appended claims and their legal equivalents, in which reference to an element in the singular is not intended to mean one and only one unless explicitly so stated, but rather one or more. Moreover, where a phrase similar to at least one of A, B, or C is used in the claims, it is intended that the phrase be interpreted to mean that A alone may be present in an embodiment, B alone may be present in an embodiment, C alone may be present in an embodiment, or that any combination of the elements A, B and C may be present in a single embodiment; for example, A and B, A and C, B and C, or A and B and C.
[0037] Systems, methods and apparatus are provided herein. In the detailed description herein, references to various embodiments, one embodiment, an embodiment, an example embodiment, etc., indicate that the embodiment described may include a particular feature, structure, or characteristic, but every embodiment may not necessarily include the particular feature, structure, or characteristic. Moreover, such phrases are not necessarily referring to the same embodiment. Further, when a particular feature, structure, or characteristic is described in connection with an embodiment, it is submitted that it is within the knowledge of one skilled in the art to affect such feature, structure, or characteristic in connection with other embodiments whether or not explicitly described. After reading the description, it will be apparent to one skilled in the relevant art(s) how to implement the disclosure in alternative embodiments.
[0038] Furthermore, no element, component, or method step in the present disclosure is intended to be dedicated to the public regardless of whether the element, component, or method step is explicitly recited in the claims. No claim element is intended to invoke 35 U.S.C. 112(f) unless the element is expressly recited using the phrase means for. As used herein, the terms comprises, comprising, or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus.