METHOD FOR MANUFACTRING AN OVERMOLDED UNITIZED ELECTRODE ASSEMBLY

Abstract

A process for manufacturing a stepped UEA includes the steps of providing a major diffusion layer, a PEM layer and a minor diffusion layer onto a lower supporting mold; enclosing the major diffusion layer, a PEM layer and a minor diffusion layer in the lower supporting mold and the upper mold; injecting a polymeric material into the mold; permeating the polymeric material into a peripheral edge area of each of the major and minor diffusion layers and molding the polymeric material directly onto the peripheral edge area of the PEM; and removing the overmolded UEA from the upper mold and lower supporting mold.

Claims

1. A method for manufacturing a stepped UEA comprising the steps of: arranging a major diffusion layer, a minor diffusion layer and a PEM layer partially disposed between the major and minor diffusion layers such that the minor diffusion layer only spans the PEM layer outside of a PEM peripheral surface region thereby leaving the PEM peripheral surface region exposed; providing the unitized electrode assembly onto a lower supporting mold; enclosing the major diffusion layer, a PEM layer and a minor diffusion layer in the lower supporting mold and the upper mold, the major diffusion layer, the PEM layer and the minor diffusion layer each include a peripheral edge region; injecting a polymeric material into the mold; molding the polymeric material directly onto the PEM peripheral surface region to create an overmolded UEA; and removing the overmolded UEA from the upper mold and lower supporting mold.

2. The method for manufacturing a stepped UEA as defined in claim 1 wherein the minor diffusion layer has a surface area which is less than each surface area of the major diffusion layer and the PEM thereby exposing the PEM peripheral surface region to the polymeric material being injected into the mold.

3. (canceled)

4. The method for manufacturing a stepped UEA as defined in claim 2 wherein the lower supporting mold supports a peripheral edge region of the major diffusion layer when the polymeric material is injected into the mold.

5. The method for manufacturing a stepped UEA as defined in claim 4 wherein the minor diffusion layer is supported by the PEM and the major diffusion layer when the polymeric material is injected into the mold.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0010] These and other features and advantages of the present disclosure will be apparent from the following detailed description, best mode, claims, and accompanying drawings in which:

[0011] FIG. 1 is a schematic, cross-sectional view of a traditional, overmolded UEA at a molding gate.

[0012] FIG. 2A is a schematic, cross-sectional view of the traditional, overmolded UEA on a second bipolar plate.

[0013] FIG. 2B is a schematic, cross-sectional view of the traditional, fuel cell assembly having an overmolded UEA disposed between a first bipolar plate and a second bipolar plate.

[0014] FIG. 3A is a schematic, cross-sectional view of an example non-limiting overmolded UEA on a second bipolar plate.

[0015] FIG. 3B is a schematic, cross-sectional view of an example, non-limiting fuel cell assembly having an overmolded UEA disposed between a first bipolar plate and a second bipolar plate

[0016] FIG. 4 a schematic, cross-sectional view of an example overmolded UEA disposed within at a molding gate in accordance with the present disclosure.

[0017] FIG. 5 is a flow chart which illustrates an example, non-limiting process for manufacturing the stepped UEA.

[0018] Like reference numerals refer to like parts throughout the description of several views of the drawings.

DETAILED DESCRIPTION

[0019] Reference will now be made in detail to presently preferred compositions, embodiments and methods of the present disclosure, which constitute the best modes of practicing the present disclosure presently known to the inventors. The figures are not necessarily to scale. However, it is to be understood that the disclosed embodiments are merely exemplary of the present disclosure that may be embodied in various and alternative forms. Therefore, specific details disclosed herein are not to be interpreted as limiting, but merely as a representative basis for any aspect of the present disclosure and/or as a representative basis for teaching one skilled in the art to variously employ the present disclosure.

[0020] Except in the examples, or where otherwise expressly indicated, all numerical quantities in this description indicating amounts of material or conditions of reaction and/or use are to be understood as modified by the word about in describing the broadest scope of the present disclosure. Practice within the numerical limits stated is generally preferred. Also, unless expressly stated to the contrary: percent, parts of, and ratio values are by weight; the description of a group or class of materials as suitable or preferred for a given purpose in connection with the present disclosure implies that mixtures of any two or more of the members of the group or class are equally suitable or preferred; the first definition of an acronym or other abbreviation applies to all subsequent uses herein of the same abbreviation and applies mutatis mutandis to normal grammatical variations of the initially defined abbreviation; and, unless expressly stated to the contrary, measurement of a property is determined by the same technique as previously or later referenced for the same property.

[0021] It is also to be understood that this present disclosure is not limited to the specific embodiments and methods described below, as specific components and/or conditions may, of course, vary. Furthermore, the terminology used herein is used only for the purpose of describing particular embodiments of the present disclosure and is not intended to be limiting in any way.

[0022] It must also be noted that, as used in the specification and the appended claims, the singular form a, an, and the comprise plural referents unless the context clearly indicates otherwise. For example, reference to a component in the singular is intended to comprise a plurality of components.

[0023] The term comprising is synonymous with including, having, containing, or characterized by. These terms are inclusive and open-ended and do not exclude additional, unrecited elements or method steps.

[0024] The phrase consisting of excludes any element, step, or ingredient not specified in the claim. When this phrase appears in a clause of the body of a claim, rather than immediately following the preamble, it limits only the element set forth in that clause; other elements are not excluded from the claim as a whole.

[0025] The phrase consisting essentially of limits the scope of a claim to the specified materials or steps, plus those that do not materially affect the basic and novel characteristic(s) of the claimed subject matter.

[0026] The terms comprising, consisting of, and consisting essentially of can be alternatively used. Where one of these three terms is used, the presently disclosed and claimed subject matter can include the use of either of the other two terms.

[0027] Throughout this application, where publications are referenced, the disclosures of these publications in their entireties are hereby incorporated by reference into this application to more fully describe the state of the art to which this present disclosure pertains.

[0028] The following detailed description is merely exemplary in nature and is not intended to limit the present disclosure or the application and uses of the present disclosure. Furthermore, there is no intention to be bound by any theory presented in the preceding background or the following detailed description.

[0029] The present disclosure provides for a stepped overmolded UEA 10 for use in a fuel cell assembly 12. The stepped overmolded UEA 10 is shown in FIG. 3A. The stepped UEA 10 includes a major diffusion layer 20, a minor diffusion layer 22, an overmolded subgasket 34, and a proton exchange membrane layer 24 (PEM 24) disposed between the major diffusion layer 20 and the minor diffusion layer 22. The overmolded subgasket 34 may be directly molded to the peripheral edge region for each of the major diffusion layer 20, the minor diffusion layer 22, and the proton exchange membrane layer 24. The overmolded seal of the present disclosure prevents fluid transfer around the edge of the UEA 10 and effects fluid tight seals to both adjacent flow field plates due to a reduced risk of breakage in the microporous layers/PEM 24. As shown in FIG. 3A, the stepped UEA 10 arrangement is shown where the major diffusion layer 20 and the PEM 24 extend beyond the minor diffusion layer 22. As shown, the major diffusion layer 20, minor diffusion layer 22 and the PEM 24 each include a peripheral edge region shown as elements 26, 28, and 30 respectively in FIGS. 3A and 3B. The major diffusion layer 20 and the minor diffusion layer 22 may each be either an anode or a cathode. However, if the major diffusion layer 20 is an anode then then minor diffusion layer must be a cathode. Similarly, if the major diffusion layer 20 is a cathode, then the minor diffusion layer must be an anode.

[0030] It is understood that the stepped arrangement shown in FIGS. 3A-3B may be implemented along the entire periphery of the gas diffusion layers (major and minor) and the PEM 24. Therefore, it is understood that the proton exchange membrane layer 24 and the major diffusion layer 20 may be equivalently sized or have substantially equivalent surface areas while the surface area 61 of the minor diffusion layer 22 is smaller than that of the major diffusion layer 20. As shown in FIGS. 3A-3B, the end 69 of the minor diffusion layer 22 is disposed inboard of the ends 67 of the major diffusion layer 20 and PEM 24.

[0031] Under this arrangement, a peripheral edge region 28 of the proton exchange membrane layer 24 is exposed such that the polymeric material 32 of the subgasket may be molded directly onto the PEM 24. Moreover, in the molding process, the polymeric material 32 may be directly molded onto and permeate the peripheral edge region of the major diffusion layer 20 and the minor diffusion layer 22. The peripheral edge regions for the major diffusion layer and the minor diffusion layers are respectively shown as elements 30 and 26 where the cross hatching of the subgasket 34 and the various layers 20, 22 intersect. It is further understood that the polymeric material 32 may be directly molded to a peripheral edge region 28 of the proton exchange membrane layer 24 thereby forming the overmolded subgasket 34 for the UEA 10. The overmolded subgasket 34 is therefore configured to provide a barrier 36 between the major diffusion layer 20 and the minor diffusion layer 22 while also sealing the major diffusion layer 20 and the minor diffusion layer 22 from the external environment 38 as shown in FIG. 3B.

[0032] As shown in FIG. 3B, the overmolded subgasket 34 is configured to seal a first bipolar plate 14 to a second bipolar plate 16, and the overmolded subgasket 34 is further configured to seal the proton exchange membrane layer 24 and the major diffusion layer 20 to the second bipolar plate 16. It is further understood that the overmolded subgasket 34 may further define at least one sealing bead 40 proximate to an edge region of the overmolded subgasket 34. FIG. 3A and FIG. 3B show two sealing beads 40 which are disposed between the end 42 of the overmolded seal and the ends 67 of the major diffusion layer 20 and PEM 24. The sealing beads 40 may protrude out from the subgasket surface 69 as shown in FIG. 3A to enable the sealing between the first and second bipolar plates 14, 16 as shown in FIG. 3B.

[0033] In yet another aspect of the present disclosure a fuel cell assembly 12 is provided which includes a first bipolar plate 14, a second bipolar plate 16, and a stepped UEA 10 having an overmolded subgasket 34 disposed between the first bipolar plate 14 and the second bipolar plate 16. The fuel cell assembly 12 is shown in FIG. 3B. As shown, the fuel cell assembly 12 includes a stepped UEA 10 which further comprises a major diffusion layer 20, a minor diffusion layer 22, and a proton exchange membrane layer 24 disposed between the major diffusion layer 20 and the minor diffusion layer 22. It is understood that the minor diffusion layer 22 has a surface area 61 which is less than each surface 61 of the major diffusion layer 20 and the proton exchange membrane layer 24. The major diffusion layer 20 and the proton exchange membrane layer 24 may have surface areas 61 which are substantially equivalent in size.

[0034] As shown, a peripheral edge region 28 of the proton exchange membrane layer 24 is exposed such that the polymeric material 32 of the overmolded subgasket 34 may be directly molded onto the peripheral edge region 28 of the PEM 24. The stepped UEA 10 arrangement shown in FIG. 3B may be generally provided along the entire periphery 63 of the UEA 10. Therefore, it is understood that the proton exchange membrane layer 24 and the major diffusion layer 20 may be substantially equivalently sized having a substantially equivalent surface area 61. However, as shown, the minor diffusion layer 22 may have a surface area 61 which is smaller than the major diffusion layer 20 and the PEM 24. Under this fuel cell assembly 12 arrangement, the polymeric material 32 is molded to and permeates a peripheral edge region 30, 26 of the major diffusion layer 20 and the minor diffusion layer 22. It is further understood that the polymeric material 32 may be molded directly onto the peripheral edge region 28 of the proton exchange membrane layer 24 as shown in FIG. 3B.

[0035] Accordingly, the polymeric material 32 molded to the peripheral edge regions 30, 26, 28 of the major diffusion layer 20, the minor diffusion layer 22, and the proton exchange membrane layer 24 forms the overmolded subgasket 34 for the UEA 10. The overmolded subgasket 34 is configured to provide a barrier 36 between the major diffusion layer 20 and the minor diffusion layer 22 while also sealing the major diffusion layer 20 and the minor diffusion layer 22 from an external environment 38. As shown in FIG. 3B, it is further understood that the overmolded subgasket 34 is configured to seal the first bipolar plate 14 to the second bipolar plate 16, and the overmolded subgasket 34 is further configured to seal the proton exchange membrane layer 24 and the major diffusion layer 20 to the second bipolar plate 16. Moreover, as shown in FIG. 3B, the fuel cell assembly 12 further includes an overmolded subgasket 34 which defines at least one sealing bead 40 proximate to an edge region of the overmolded subgasket 34.

[0036] With reference to FIG. 5, the process 58 for manufacturing the overmolded subgasket 34 is shown in the form of a flow chart. The process 58 includes the steps of providing 60 a major diffusion layer 20, a PEM 24 layer and a minor diffusion layer 22 onto a lower supporting mold 50; enclosing 62 the major diffusion layer 20, a PEM 24 layer and a minor diffusion layer 22 in the lower supporting mold 50 and the upper mold 52; injecting a polymeric material 32 into the mold 55 (formed by the upper mold 52 and lower supporting mold 50); permeating 64 the polymeric material 32 into a peripheral edge region of each of the major and minor diffusion layers 20, 22 and molding 66 the polymeric material 32 directly onto the peripheral edge region 28 of the PEM 24 to create an overmolded UEA; and removing 68 the overmolded UEA 10 from the upper mold 52 and lower supporting mold 50. It is understood that the major diffusion layer, the PEM layer and the minor diffusion layer each include a peripheral edge region.

[0037] In the aforementioned process, it is understood that the minor diffusion layer 22 has a surface area 61 which is less than each surface layer 61 of the major diffusion layer 20 and the minor diffusion layer 22 which enables the peripheral edge region 28 of the PEM 24 to be exposed polymeric material 32. Moreover, it is understood that the lower supporting mold 50 supports the peripheral edge regions 30, 28 of the major diffusion layer 20 and the PEM 24 layer during the molding process thereby reducing the risk of breakage or leaks in the layers. The minor diffusion layer 22 as shown in FIG. 4 is supported by the PEM 24 and the major diffusion layer 20 thereby reducing the risk of any breakage or leaks in the minor diffusion layer 22 during the molding process.

[0038] While at least one exemplary embodiment has been presented in the foregoing detailed description, it should be appreciated that a vast number of variations exist. It should also be appreciated that the exemplary embodiment or exemplary embodiments are only examples, and are not intended to limit the scope, applicability, or configuration of the disclosure in any way. Rather, the foregoing detailed description will provide those skilled in the art with a convenient road map for implementing the exemplary embodiment or exemplary embodiments. It should be understood that various changes can be made in the function and arrangement of elements without departing from the scope of the disclosure as set forth in the appended claims and the legal equivalents thereof.