PU THIN COVERS WITH WATERPROOF AND MOISTURE PERMEABLE FUNCTION

20190061205 ยท 2019-02-28

    Inventors

    Cpc classification

    International classification

    Abstract

    This invention relates to a PU thin covers with waterproof and moisture permeable function, the hydrophilicity of the PEG structure can diffuse the water molecules from the inside of the PU then covers to the outside of the PU thin covers, and then the water molecules at the outer surface of the PU thin covers will be volatilize to achieve the effect of high moisture permeability. Since the PU thin covers containing PEG structure has no perforations, the external water and air cannot directly penetrate into the inside of the PU thin covers to achieve high waterproof effect. Moreover, the PU materials containing PEG structure can use various special manufacturing methods to make the PU thin covers have the best waterproofness, moisture permeability, structural strength, lightness, low cost, low pollution, high environmental value and various functions can be customized.

    Claims

    1. A PU thin covers with waterproof and moisture permeable function at least comprising: a inner cover is provided with a plurality of fine mesh holes; a PU coating is integrally formed on the inner surface and the outer surface of said inner cover by PU material containing a PEG structure, said PU coating may be completely coated on the inner cover or only covered in a part of the inner cover, the inner surface of said PU coating is provided with an rough surface to increase the dry comfort of wearing; said PU material containing PEG structure is added to the oily dilution solvent to form a PU diluent, and then preparing a mold for mounting said inner cover, said mold is provided with a matte surface, and the PU thin covers with waterproof and moisture permeable function is made through at least one dipping process, at least one PU coating forming process in water and at least one drying process; said dipping process is to immerse the mold with the inner cover into the PU diluent, the mesh holes of the inner cover allows the PU diluent to penetrate into the inner surface thereof, so that the inner surface and the outer surface of the inner cover can uniformly coat the PU diluent; said PU coating forming process in water is to place said mold with surface covering PU diluent in water to form the PU coating and to exchange part of the oily dilution solvent of the PU diluent into water, so that the amount of oily dilution solvent volatilized in the drying process can be reduced to effectively reduce the environmental pollution caused by oily dilution solvent.

    2. The PU thin covers with waterproof and moisture permeable function according to claim 1, wherein said inner cover is a braided cover.

    3. The PU thin covers with waterproof and moisture permeable function according to claim 1, wherein said inner cover may be a plastic cover or a rubber cover with a plurality of mesh holes.

    4. The PU thin covers with waterproof and moisture permeable function according to claim 1, wherein a PU film is pre-manufactured on the mold by using said PU diluent before the inner cover is arranged on the mold, and then to arrange the inner coverer on the PU film to increase the thickness of the PU coating on the inner surface of the inner cover.

    5. The PU thin covers with waterproof and moisture permeable function according to claim 4, wherein said inner cover is a braided cover.

    6. The PU thin covers with waterproof and moisture permeable function according to claim 4, wherein said inner cover may be a plastic cover or a rubber cover with a plurality of mesh holes.

    7. A PU thin covers with waterproof and moisture permeable function at least comprising: a inner cover is provided with a plurality of fine mesh holes; a PU coating is integrally formed on the inner surface and the outer surface of said inner cover by PU material containing a PEG structure, said PU coating may be completely coated on the inner cover or only covered in a part of the inner cover, the inner surface of said PU coating is provided with an rough surface 30 to increase the dry comfort of wearing; said PU material containing PEG structure is added to the aqueous dilution solvent to form a PU diluent, and then preparing a mold for mounting said inner cover 2, said mold is provided with a matte surface, and the PU thin covers with waterproof and moisture permeable function is made through at least one dipping process and at least one drying process; said dipping process is to immerse the mold with the inner cover into the PU diluent, the mesh holes of the inner cover allows the PU diluent to penetrate into the inner surface thereof, so that the inner surface and the outer surface of the inner cover can uniformly coat the PU diluent; and then drying the mold to make the PU thin covers with waterproof and moisture permeable function.

    8. The PU thin covers with waterproof and moisture permeable function according to claim 7, wherein said inner cover is a braided cover.

    9. The PU thin covers with waterproof and moisture permeable function according to claim 7, wherein said inner cover may be a plastic cover or a rubber cover with a plurality of mesh holes.

    10. The PU thin covers with waterproof and moisture permeable function according to claim 7, wherein a PU film is pre-manufactured on the mold by using said PU diluent before the inner cover is arranged on the mold, and then to arrange the inner coverer on the PU film to increase the thickness of the PU coating on the inner surface of the inner cover.

    11. The PU thin covers with waterproof and moisture permeable function according to claim 10, wherein said inner cover is a braided cover.

    12. The PU thin covers with waterproof and moisture permeable function according to claim 10, wherein said inner cover may be a plastic cover or a rubber cover with a plurality of mesh holes.

    Description

    BRIEF DESCRIPTION OF DRAWINGS

    [0014] This invention will be better understood by referring to the accompanying drawings, wherein:

    [0015] FIG. 1 is a three-dimensional view of the first embodiment in the present invention;

    [0016] FIG. 2 is an sectional view of A-A shown in FIG. 1;

    [0017] FIG. 3 is a front view of the second embodiment in the present invention; and

    [0018] FIG. 4 is an sectional view of B-B shown in FIG. 3.

    DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT

    [0019] A preferred first embodiment of the PU thin covers with waterproof and moisture permeable function in the present invention, as shown in FIGS. 1 and 2, which includes at least a cover 1 as main components. The cover 1 is integrally formed from a PU (polyurethane) material containing PEG (polyethylene glycol) structure, it has the material properties of PU such as stretchability, tear resistance, elasticity, etc., and the hydrophilicity of the PEG structure can diffuse the water molecules from the inside of the cover 1 to the outside of the cover 1, and then the water molecules at the outer surface of the cover 1 will be volatilize to achieve the effect of high moisture permeability. Moreover, since the PU cover 1 containing PEG structure has no perforations, the external water and air cannot directly penetrate into the inside of the cover to achieve high waterproof effect.

    [0020] As shown in FIG. 1, said cover 1 is provided with an opening 10, a groove 11 is formed in the opening 10, the shape and the size of the groove 11 may be adjusted according to various requirements for the user to wear. As shown in FIG. 2, the inner surface of the cover 1 is provided with an rough surface (matte) 12 to increase the dry comfort of wearing. Said cover 1 may be a glove, a foot cover, a head cover, a finger sleeve, a joint cover, an arm cover, a leg cover, a condom, a garment, a trousers or other body-worn covers.

    [0021] Said PU material containing PEG structure is diluted with an oily dilution solvent, such as Dimethylformamide (DMF), a mixed solvent containing Dimethylformamide, and the like. Said cover 1 is manufactured by at least one dipping process, at least one cover forming process in water and at least one drying process.

    [0022] Said dipping process is to directly dip the mold with matte surface into the PU diluent, and uniformly covers the PU diluent on the outer surface of the mold. The fine gap of the matte surface of the mold can make the PU located in said fine gap break away from the fine gap due to the shrinkage of the PU material during the drying process of the cover 1, so that the contact area of the mold outer surface with the PU can be effectively reduced and the cover 1 can be more easily demolded (the ultra-thin cover with a thickness of about 0.01 mm can be demoulded smoothly). Said mold will form a rough surface 12 on the inner surface of the cover 1, the rough surface 12 can reduce the contact area between the inner surface of the cover 1 and the user's skin, so that the cover 1 can be worn more dry and comfortable, and the user will not feel uncomfortable even if he/she wears it for a long time (if said mold is provided with a smooth outer surface, the PU thin cover formed on the smooth outer surface will adhere to the mold, so that the PU thin cover product will not easy to demould, and the user will feel sticky and astringent when wearing the PU thin cover product). Said mold may be made of metal, wood, ceramic, or other material that can be made into a mold.

    [0023] Said cover forming process in water is to place said mold with surface covering PU diluent in water to form a cover. Since water can exchange part of the oily dilution solvent of the PU diluent into water, and the PU is incompatible with water, so that the PU can be separate out in water to achieve rapid shaping effect. Moreover, since said cover forming process in water has exchanged a large amount of oily dilution solvent into water, the oily dilution solvent exchanged into the water can be retrieved and reused, and the amount of oily dilution solvent volatilized in the drying process can be reduced to effectively reduce the environmental pollution caused by oily dilution solvent.

    [0024] Said drying process is to dry the mold with the cover 1 in an oven to complete the manufacture of the cover 1. Since the foregoing process has shaped the cover and reduced a large amount of oily dilution solvent in the cover, the drying time of the cover can be reduced, the difficulty of drying can be reduced (don't worry about the continuous flow of PU diluent on the mold during the drying process to result in uneven distribution of the thickness of the PU cover), and the erosion of the outer surface of the cover 1 by the oily dilution solvent can be prevented (because the higher the temperature, the faster the evaporation rate of the oily dilution solvent, the rapid evaporation of a large amount of oily dilution solvent will cause the surface of the cover 1 to form an eroded perforation defects, destroying the waterproof function of the cover).

    [0025] Thus, with the improvement of the foregoing technology, the first embodiment of the PU thin covers in the present invention can achieve high production efficiency, high quality stability, low environmental pollution and low cost.

    [0026] The second embodiment of the PU thin covers with waterproof and moisture permeable function in the present invention, as shown in FIGS. 3 and 4, includes at least an inner cover 2 and a PU coating 3 as main components combined together.

    [0027] Said inner cover 2 is provided with a plurality of fine mesh holes, the inner cover 2 may be a braided cover woven from artificial chemical fiber, natural fiber, metal fiber, ceramic fiber, glass fiber, etc., or the inner cover 2 may be a plastic cover or a rubber cover with a plurality of mesh holes to provide the PU thin covers additional structure strength, rigidity, elasticity, thermal insulation, electrical conductivity or other functions. Said inner cover 2 may be a glove, a foot cover, a head cover, a finger sleeve, a joint cover, an arm cover, a leg cover, a condom, a garment, a trousers or other body-worn covers.

    [0028] Said PU coating 3 is integrally formed on the inner surface and the outer surface of said inner cover 2 by PU (polyurethane) material containing a PEG (polyethylene glycol) structure, said PU coating 3 may be completely coated on the inner cover 2 or only covered in a part of the inner cover 2, depending on the needs of use (the embodiment shown in FIG. 3 only coats the PU coating 3 at the lower position of the inner cover 2). The inner surface of said PU coating 3 is provided with an rough surface (matte) 30 to increase the dry comfort of wearing. Said PU coating 3 has the material properties of PU such as stretchability, tear resistance, elasticity, etc., and the hydrophilicity of the PEG structure can diffuse the water molecules from the inside of the PU coating 3 to the outside of the PU coating 3, and then the water molecules at the outer surface of the PU coating 3 will be volatilize to achieve the effect of high moisture permeability. Moreover, since the PU coating 3 containing PEG structure has no perforations, the external water and air cannot directly penetrate into the inside of the PU coating 3 to achieve high waterproof effect.

    [0029] When manufacturing the second embodiment of the PU thin covers in the present invention, the first step is to add a dilution solvent to said PU material containing PEG structure to form a PU diluent. Said dilution solvent may be an oily dilution solvent (such as DMF (Dimethylformamide), a mixed solvent containing DMF, and the like) or an aqueous dilution solvent (such as pure water or aqueous mixture). Then, preparing a mold for mounting said inner cover 2, said mold is provided with a matte surface. The fine gap of the matte surface of the mold can make the PU located in said fine gap break away from the fine gap due to the shrinkage of the PU material during the drying process of the PU coating 3, so that the contact area of the mold outer surface with the PU can be effectively reduced and the PU coating 3 can be more easily demolded (the ultra-thin cover with a thickness of about 0.01 mm can be demoulded smoothly). Said mold will form a rough surface 30 on the inner surface of the PU coating 3, the rough surface 30 can reduce the contact area between the inner surface of the PU coating 3 and the user's skin, so that the PU thin covers can be worn more dry and comfortable, and the user will not feel uncomfortable even if he/she wears it for a long time (if said mold is provided with a smooth outer surface, the PU thin cover formed on the smooth outer surface will adhere to the mold, so that the PU thin cover product will not easy to demould, and the user will feel sticky and astringent when wearing the PU thin cover product). Said mold may be made of metal, wood, ceramic, or other material that can be made into a mold.

    [0030] The second step is to arrange said inner cover 2 on the mold and dip the mold with the inner cover 2 into the PU diluent. Since the mesh holes of the inner cover 2 allows the PU diluent to penetrate into the inner surface thereof, the inner surface and the outer surface of the inner cover 2 can uniformly coat the PU diluent. In order to increase the thickness of the PU coating 3 on the inner surface of the inner cover 2, a PU film may be pre-manufactured on the mold by using said PU diluent (the thickness of the PU film may be adjusted by at least one PU film process such as at least one dipping process and at least one drying process) before the inner cover 2 is arranged on the mold, and then to arrange the inner coverer 2 on the PU film and dip the mold with the inner cover 2 into the PU diluent, so that the thickness of the PU coating 3 on the inner surface of the inner cover 2 can be adjusted to the desired thickness.

    [0031] When the PU diluent is diluted with an oily dilution solvent, the third step is to place said mold in water to form the PU coating 3. Since water can exchange part of the oily dilution solvent of the PU diluent into water, and the PU is incompatible with water, so that the PU can be separate out in water to achieve rapid shaping effect. It should be noted that since the inner cover 2 with mesh holes is not a flat surface, the overall distribution of the PU coating 3 is not uniform (the PU coating 3 located at the mesh holes of the inner cover 2 has the most thickest thickness), so that it will result in inconsistent volatilization rate of the oily dilution solvent of the PU coating 3. If said mold is directly fed into the oven for drying, the PU coating 3 will generate solvent vapor erosion and perforations at the mesh hole position of the inner cover 2, thereby causing the PU coating 3 to form defects and reduce the waterproof effect thereof. Therefore, when the PU diluent is diluted with an oily dilution solvent, it have to use this process, the advantage of the PU coating 3 forming in water is that the PU coating 3 can be quickly shaped and a large amount of oily dilution solvent can be exchanged Into water; moreover, the oily dilution solvent exchanged into the water can be retrieved and reused, and the amount of oily dilution solvent volatilized in the drying process can be reduced to effectively reduce the environmental pollution caused by oily dilution solvent.

    [0032] It is important to note that when the PU diluent is diluted with an aqueous dilution solvent, the PU coating 3 cannot be formed in water because the water will dissolve and disperse the PU diluent. Moreover, the aqueous dilution solvent will not cause the problem of solvent vapor erosion and perforation during the drying process, so the PU coating 3 can be formed by directly drying in an oven.

    [0033] The fourth step is to feed the mold into the oven and dry the excess moisture and the residual solvent to complete the PU thin covers. If it is necessary to increase the thickness of the PU coating 3 on the outer surface of the inner cover 2 to get better tensile strength (tear strength) and waterproof function, the manufacturer may repeat the foregoing second step to the fourth step to achieve the purpose.

    [0034] Said PU materials may be added with various additives to increase the functionality, production efficiency, comfort and commercial value of the PU thin covers, depending on the demand. For example, the addition of silicon oil to the PU material can make the PU thin covers have a slippery feel, assist the PU demould and anti-sticking effect; the addition of silica powder to the PU material can make the PU thin covers have the functions of dry hand, anti-sticking and surface extinction; the addition of hardening agent containing isocyanate group (NCO) to PU material can further strengthen the physical properties and mechanical strength of the PU thin covers; the addition of titanium dioxide to the PU material can make the PU thin covers have the functions of antistatic (electrical conductivity) and dyed white, and the PU thin covers can directly perform the touch operation of the electronic product; the addition of the antibacterial agent to the PU material can inhibit the growth of bacteria and mold; the addition of coloring agent to the PU material can make the PU thin covers have various color changes.

    [0035] It is worth mentioning that the PU thin covers in the present invention can be adjusted in thickness through a plurality of identical processes according to the use requirements, and the PU thin covers can be made to have a minimum thickness of about 0.01 mm. The moisture permeability of the PU thin covers will not be greatly reduced by the increase of the thickness, and the moisture permeability can reach the level of JIS L1099 B1 test method 15000 (g/m2/24 hr) or more, so that the effect of the thickness on the moisture permeability can be reduced, and the sweat from the skin can be quickly discharged out of the PU thin covers to keep the skin dry. The water resistance of the PU thin covers can reach the level of JIS L1092B test method 10000 (mm-H2O) or more, and various functional inner cover can be arranged according to requirements, so that the PU thin covers can be applied to various industries (such as industrial, commercial, agricultural, aquaculture, medical, beauty, catering or special work) or special needs (such as toughness, steel, elasticity, heat insulation, electrical conductivity, etc.). The PU thin covers also has the anti-solvent property, which allows the user to achieve the effect of blocking the external harmful solvent erosion when worn, and avoids the skin directly being exposed to the harmful solvent. Evidently this invention has tangible benefits and tallies with progressiveness and novelty demanded by patent laws.

    [0036] While the preferred embodiments of this invention have been described above, it will be recognized and understood that various modifications may be made therein and appended claims are intended to cover all such modifications that may fall within the spirit and scope of the invention.