Fluid distribution in a fluidized bed reactor

Abstract

A fluid distribution cap (301) for a fluidized bed reactor, comprising a tunnel shaped structure having two opposing walls for attaching to a fluid distribution plate (103), and at least one opening at an end of the tunnel shaped structure. The tunnel shaped structure has an inner surface (302) and an outer surface (303), wherein the inner surface (302) has a curved cross section, and wherein the outer surface (303) has a substantially V-shaped cross section. A fluid distribution plate (103) for a fluidized bed reactor, comprising a plate having a plurality of fluid vent holes (113), a plurality of fluid distribution caps (301), wherein for each fluid vent hole (113) a fluid distribution cap (301) is mounted over said hole (113). At least two mutually neighboring fluid distribution caps (301) are positioned with an opening of a first of the two neighboring fluid distribution caps facing a side of the second of the two neighboring fluid distribution caps. A fluidized bed reactor having a fluid distribution plate (103) and a fluid distribution cap (301).

Claims

1. A fluid distribution cap for a fluidized bed reactor or a fluidized bed reactor used in a polymerization process, comprising a tunnel shaped structure having two opposing walls for attaching to a fluid distribution plate; and at least one opening at an end of the tunnel shaped structure, wherein the tunnel shaped structure has two openings at opposing ends of the structure; the tunnel shaped structure having an inner surface and an outer surface, wherein the inner surface has a curved cross section, and wherein the outer surface has a substantially V-shaped cross section.

2. The fluid distribution cap according to claim 1, wherein the inner surface has a substantially semicircular cross section.

3. The fluid distribution cap according to claim 1, wherein the tunnel shaped structure is a one-piece object.

4. The fluid distribution cap according to claim 1, wherein the structure comprises an angle profile forming the V-shaped outer surface and a pipe segment forming the curved inner surface, the pipe segment attached to an inner part of the angle profile.

5. The fluid distribution cap according to claim 4, wherein the pipe segment is substantially a half pipe.

6. The fluid distribution cap according to claim 4, having a filler at each end of the structure for closing a clearance between the angle profile and the pipe segment.

7. A fluid distribution plate for a fluidized bed reactor or a fluidized bed reactor used in a polymerization process, comprising a plate having a plurality of fluid vent holes; a plurality of fluid distribution caps in accordance with claim 1; wherein for each fluid vent hole a fluid distribution cap is mounted over said hole; wherein at least two mutually neighboring fluid distribution caps are positioned with an opening of a first of the two neighboring fluid distribution caps facing a side of the second of the two neighboring fluid distribution caps.

8. A fluidized bed reactor having a fluid distribution cap comprising a tunnel shaped structure having two opposing walls for attaching to a fluid distribution plate; and at least one opening at an end of the tunnel shaped structure, wherein the tunnel shaped structure has two openings at opposing ends of the structure; the tunnel shaped structure having an inner surface and an outer surface, wherein the inner surface has a curved cross section, and wherein the outer surface has a substantially V-shaped cross section; or having a fluid distribution plate comprising a plate having a plurality of fluid vent holes; a plurality of the fluid distribution caps, wherein for each fluid vent hole a fluid distribution cap is mounted over said hole; wherein at least two mutually neighboring fluid distribution caps are positioned with an opening of a first of the two neighboring fluid distribution caps facing a side of the second of the two neighboring fluid distribution caps.

9. A polymerization process, comprising performing the process of polymerization with a fluid distribution cap comprising a tunnel shaped structure having two opposing walls for attaching to a fluid distribution plate; and at least one opening at an end of the tunnel shaped structure, wherein the tunnel shaped structure has two openings at opposing ends of the structure; the tunnel shaped structure having an inner surface and an outer surface, wherein the inner surface has a curved cross section, and wherein the outer surface has a substantially V-shaped cross section; or performing the process of polymerization with a fluid distribution plate comprising a plate having a plurality of fluid vent holes; a plurality of the fluid distribution caps, wherein, for each fluid vent hole a fluid distribution cap is mounted over said hole; wherein, at least two mutually neighboring fluid distribution caps are positioned with an opening of a first of the two neighboring fluid distribution caps facing a side of the second of the two neighboring fluid distribution caps.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 shows a schematic diagram of an exemplary fluidized bed reactor according to the state of the art.

(2) FIG. 2a shows a fluid distribution cap according to the state of the art.

(3) FIG. 2b shows an alternative fluid distribution cap according to the state of the art.

(4) FIG. 3a shows a fluid distribution cap according to an embodiment of the invention.

(5) FIG. 3b shows a fluid distribution cap according to an embodiment of the invention.

(6) FIG. 4a shows a cross section of a fluid distribution cap according to an embodiment of the invention.

(7) FIG. 4b shows a cross section of a fluid distribution cap according to an embodiment of the invention.

(8) FIG. 5 shows an arrangement of fluid distribution caps according to an embodiment of the invention on a fluid distribution plate

DETAILED DESCRIPTION OF EMBODIMENTS

(9) FIG. 1 shows a schematic diagram of an exemplary system 100 with a fluidized bed reactor 101 which can be used in a process for polymerization according to the state of the art. The fluid fluidized bed reactor 101 has a fluidized bed 102 wherein the process of polymerization is performed. The fluidized bed reactor 101 can have a product outlet 108 from where the polymer can be extracted from the system 100. Reactants and/or inerts for use in the fluidized bed reactor can be supplied via fluid supply 112 to the system 100. Via fluid inlet 106, the fluid enters the fluidized bed reactor 101. In an upward flow indicated by the upward pointing arrows through vent holes 113 in the fluidized bed reactor the fluid passes from a lower end of the fluidized bed reactor 101 to an upper part having the fluidized bed 102. Fluid distribution caps 104 prevent fluidized bed material from passing through the fluid distribution plate 103 when the fluidized bed reactor is in rest. Further reactants may be added to the fluidized bed reactor 101 via supplementary inlet 107. Fluid escaping from fluidized bed 102 is captured in fluid outlet 105, and via fluid return 111 returned to the fluid inlet 106 of the system 100. The fluid in the system is compressed and circulated through the system using a cycle gas compressor 110. In heat exchange 109 any surplus heat can be exchanged with the environment.

(10) FIG. 2a shows an example of a fluid distribution cap in the shape of a pipe segment 201a according to the state of the art. The fluid distribution cap 201a is attached to a fluid distribution plate 103 at the edges of the pipe segment sidewalls 204a. The pipe segment shaped fluid distribution cap 201a is placed over vent hole 113 allowing a fluid outflow 202 from underneath the pipe segment 201a.

(11) Horizontal components 205 of the fluid outflow 202 from another fluid distribution cap 204a causes a scattered upward flow of the fluid, i.e. flow in various upward directions due to the curved outer surface of the distribution cap 201a. Due to the relative steep angle of the side walls 201a of the pipe segment shaped fluid distribution cap 201a, the outside edges 203a of the fluid distribution cap 201a may form a stagnant zone where fluid flow is low. In such a stagnant zone, the fluid may clog, thereby contaminating the fluid distribution plate 103.

(12) FIG. 2b shows a fluid distribution cap having an angle profile shape 201b according to the state of the art. The fluid distribution cap side walls 204b are flat and are connected at a substantially rectangular shaped apex. Fluid outflow 207 is performed from the fluid vent hole 113 in a similar way as the pipe segment shaped fluid distribution cap of FIG. 2a. However the inner curved surface of the pipe segment shaped fluid distribution cap 201a allows a better outflow 202. The angle profile shaped fluid distribution cap 201b may have stagnant zones near the edges at the inside of the angle profile shaped fluid distribution cap side walls 203b. The stagnant zone may cause clogging of the fluid carrying fines passing through the vent hole 113 and eventually cause plugging.

(13) The angle profile shaped fluid distribution cap 201b has improved deflection of a horizontal component 208 of the outflow of neighboring fluid distribution caps 201b caused by the flat fluid distribution cap side wall 204b which is placed substantially at an angle of 45 degrees with respect to the fluid distribution plate 103. The deflected fluid flow 209 is substantially upward as shown in FIG. 2b.

(14) FIG. 3a shows a tunnel shaped fluid distribution cap 301 having an inner surface with a curved cross section and an outer surface with a V-shaped cross section. The tunnel shaped fluid distribution cap 301 can be made from a combination of a pipe segment shaped inner element 302 as in FIG. 2a and an angled profile shaped outer element 303 as in FIG. 2b. The tunnel shaped fluid distribution cap 301 is placed over a vent hole 113 allowing fluid outflow 202 at both ends of the tunnel shaped pipe segment 302. The curved inner surface of the pipe segment shaped inner element 302 allows efficient outflow 202 of the fluid, while the V-shaped outer surface, i.e. flat sides 305a, 305b (which is referred to in FIG. 2b as 204b) of the angled profile outer element 303 allow the efficient upward deflection 209 of fluid outflows 306 from neighboring fluid distribution caps 301, as shown in FIG. 3b and similar to outflows 205 or 202 described in FIG. 2a.

(15) Also shown in FIG. 3b, a clearance between the angle profile shaped outer element 303 and pipe segment shaped inner element 302 can be filled with a filler 304. Alternatively, the clearance 304 can be covered with an appropriate cover such that the clearance between the pipe segment 302 and the angle profile 303 is sealed off from the fluid flow across the distribution plate 1203, thereby preventing clogging and plugging of the clearance.

(16) The pipe segment shaped inner element 302 and the angle profile shaped outer element 303 can be made from metal and be welded together to the fluid distribution plate 103. It can also be contemplated to manufacture the tunnel shaped distribution cap in a one-piece fashion, for example by casting metal in a mold or by injection molding. Other heat resistant materials may also apply. Likewise, filler materials may comprise metal, e.g. carbon steel.

(17) The pipe segment shape of the inner elements 302 of FIGS. 3a and 3b can be semi-circular with a central axis in the plane of the distribution plate 103 or even underneath the plane of the distribution plate 103. Alternative configurations are contemplated in FIGS. 4a and 4b, wherein the central axis of the pipe segment 302 and cross-section A-A lies above the distribution plate 103. The position of the central axis is indicated by center point 402. FIG. 4a shows a fluid distribution cap 301 having a hoof shaped inner element 302 and an angle profile shaped outer element 303. The hatched section 304 indicates the filler or cover between the inner element 302 and the outer element 303. The hoof shaped cross section 401a of the inner element 302 need not be regular, but may have partially straight walls extending upwards from fluid distribution plate 103 and arch over to an opposite side of the vent hole 113 as shown in FIG. 4a.

(18) In FIG. 4b the inner element 302 is shown having a circular cross section 401b with a central axis at location 402. The edges of the cross-section of the circular inner element 302 can be aligned and connected to edges of the vent hole 113. Other variations of the inner element shape can be contemplated by the skilled person.

(19) FIG. 5 shows a fluid distribution cap arrangement 500 having a fluid distribution plate 103 with a plurality of fluid distribution caps 301 in accordance with FIGS. 3a and/or 3b. The fluid distribution caps 301 are arranged over corresponding vent holes 113 in the fluid distribution plate 103 in mutually perpendicular directions of their tunnel shaped structure. In FIG. 5 it is shown that horizontal components 306 of fluid outflows from neighboring fluid distribution caps 301 deflect upwards 209 contributing to an improved performance when applied in for example the fluidized bed reactor 101 shown in FIG. 1.

(20) The fluid distribution caps 301 described above and shown in FIGS. 3a-5 have two openings at opposite ends of the fluid distribution cap 301 to allow fluid outflow. A skilled person may contemplate fluid distribution caps 301 having a single opening e.g. for example one opening of the fluid distribution cap 301 as described is closed. Moreover, fluid distribution caps having more than one outflow opening such as Y-shaped fluid distribution caps having three openings or X-shaped fluid distribution caps having four openings may be considered for lower pressure drop in the fluid outflow.

(21) The above described embodiments are given by way of example only. Variations or alterations to the embodiments can be made without limiting the scope of protection as laid down in the claims as set out below.

REFERENCE NUMERALS

(22) 100 system

(23) 101 fluidized bed reactor

(24) 102 fluidized bed

(25) 103 fluid distribution plate

(26) 104 fluid distribution cap

(27) 105 fluid outlet

(28) 106 fluid inlet

(29) 107 supplementary inlet

(30) 108 product outlet

(31) 109 fluid heat exchanger

(32) 110 cycle gas compressor

(33) 111 fluid return

(34) 112 fluid supply

(35) 113 fluid vent holes

(36) 201a pipe segment cap

(37) 201b angle profile cap

(38) 202 pipe segment fluid outflow

(39) 203a stagnant zone

(40) 203b stagnant zone

(41) 204a pipe segment side wall

(42) 204b angle profile side wall

(43) 205 neighboring pipe segment outflow

(44) 206 scattered upward flow

(45) 207 angle profile fluid outflow

(46) 208 neighboring angle profile outflow

(47) 209 upward deflected fluid flow

(48) 301 tunnel shaped fluid distribution cap

(49) 302 inner element

(50) 303 outer element

(51) 304 filler or cover

(52) 305a, 305b flat side wall

(53) 306 neighboring tunnel shaped fluid distribution cap outflow

(54) 401a hoof cross section

(55) 401b circular cross section

(56) 402 central axis location

(57) 500 fluid distribution cap arrangement