PLANT AND METHOD FOR RECOVERING AND TREATING RESIDUES FROM CRUSHING FERROUS SCRAP

Abstract

A plant for recovering and treating residues from crushing scrap is provided. The plant includes a first plant part and a second plant part. The first plant part is provided with crushing and separation means configured to extract ferrous materials, non-ferrous metals and plastic materials from the residues from crushing. The separation means are provided with a granulator system configured to reduce, in dry mode and without pre-screening stages, the residues from crushing into a stream of granular material. The second plant part is provided with means to treat and size the plastic materials configured to transform the plastic materials into additive material to be used, in particular, in iron and steel plants such as blast furnaces, electric arc furnaces or suchlike. The means to treat and size the plastic materials includes a dry system for cutting and/or grinding the plastic materials.

Claims

1.-16. (canceled)

17. Plant for recovering and treating residues from crushing scrap (12) comprising: a first plant part (110) provided with: a granulator system (11), that is a first grinding or crushing system, configured to reduce, in dry mode and without pre-screening stages, the residues from crushing (12) into a stream (F) of granular material; separation means (13, 15, 17, 19) located downstream of the granulator system (11) and configured to extract ferrous materials (14), non-ferrous metals (20) and light or heavy plastic materials (16, 24) from said residues from crushing (12); and a second plant part (210) provided with: means (32, 33) to treat and size the plastic materials (16, 24) configured to transform said plastic materials (16, 24) into additive material to be used, in particular, in iron and steel plants (40) such as blast furnaces, electric arc furnaces or suchlike; said means (32, 33) to treat and size the plastic materials (16, 24) comprising a second dry system for cutting and/or grinding (33) the plastic materials (16, 24); said second plant part (210) comprises a thermomechanical transformation system (32) of the plastic materials (16, 24) and said second cutting and/or grinding system (33) is located downstream of said thermomechanical transformation system (32); the thermomechanical transformation system (32) being able to transform the plastic materials (16, 24) into a series of briquettes or compact cylinders and the second cutting and/or grinding system (33) is able to obtain material in a granular form which is used as additive material, for example to function as fuel or reducing agent (34), to be fed to in the iron and steel plants (40).

18. Plant as in claim 17, further comprising at least a magnetic separation system (13) configured to separate the ferrous materials (14) from said stream (F) of granular material; at least a system of separation by density (15) configured to remove light plastic materials (16) from said stream (F) of granular material; at least an induced current separator system (19) configured to separate non-ferrous metals (20) from the stream (F) of granular material; and at least a screening system (25, 26) configured to extract heavy or hard plastic materials (24) from the stream (F) of granular material.

19. Plant as in claim 18, wherein said first plant part (110) comprises another induced current separator system (28) configured to further separate the non-ferrous metals (20).

20. Plant as in claim 17, wherein said second plant part (210) comprises a separation system (35) to separate the heavy chlorinated plastic materials (36) from the heavy plastic materials not containing chlorine (24).

21. Plant as in claim 17, wherein said additive material functions as a fuel or reducing agent (34).

22. Method for recovering and treating residues from crushing scrap (12) by means of a plant according to claim 17, the method comprising one or more first sequential steps, actuated using dry workings, of crushing and separating the residues from crushing (12), thus by means of a granulator system (11) and separation means (13, 15, 17, 19) able to extract ferrous materials (14), non-ferrous metals (20) and plastic materials (16, 24) from said residues from crushing (12), and second steps of treating and sizing the plastic materials (16, 24) extracted from said residues from crushing (12) able to transform said plastic materials (16, 24) into additive material to be used in iron and steel plants (40) such as blast furnaces, electric arc furnaces or suchlike; said second steps comprising: a second dry system for cutting and/or grinding (33) the plastic materials (16, 24) located downstream of a thermomechanical transformation system (32) of the plastic materials (16, 24); the thermomechanical transformation system (32) being able to transform the plastic materials (16, 24) into a series of briquettes or compact cylinders and the second cutting and/or grinding system (33) being able to obtain material in a granular form which is used as additive material, for example to function as fuel or reducing agent (34), to be fed to in the iron and steel plants (40).

23. Method as in claim 22, further comprising the following sequential steps: crushing the residues from crushing (12) of the scrap so as to obtain a stream (F) of granular material; extracting the ferrous materials (14) from said stream (F) of granular material by means of magnetic separation; extracting from the stream (F) of granular material light plastic materials (16) by means of separation by density; extracting non-ferrous metals (20) from said stream (F) of granular material by means of induced currents; and extracting heavy or hard plastic materials (24) by means of one or more screening steps.

24. Method as in claim 22, further comprising at least a step of thermomechanical treatment of the plastic materials (16, 24).

25. Method as in claim 22, wherein the plastic materials (16, 24) are subjected to a cutting and/or grinding step so as to obtain briquettes or cylinders to feed into said iron and steel plants (40).

26. Method as in claim 22, wherein said non-ferrous metals (20) are treated by means of another induced current separation step, so as to separate the main constituent components (29, 30).

27. Method as in claim 23, wherein, downstream of the separation step of the light plastic materials (16) and upstream of the separation step of the non-ferrous metals (20), the method comprises a step of screening the stream (F) of said granular material.

28. Method as in claim 23, wherein downstream of the separation step of the non-ferrous metals (20), the method comprises another separation step by density of the light plastic materials (16).

29. Method as in claim 23, further comprising a final multiple screening step and subsequent separation stage by size/density by means of which it is possible to obtain clean fragments of a homogeneous size (P1, P2, P3, P4) of heavy or hard plastic materials (24).

30. Method as in claim 23, further comprising a step of separating the heavy chlorinated plastic materials (36) from the remaining heavy plastic materials which do not contain chlorine (24).

Description

BRIEF DESCRIPTION OF THE DRAWING

[0037] These and other characteristics of the present invention will become apparent from the following description of some forms of embodiment, given as a non-restrictive example with reference to the attached drawing wherein:

[0038] FIG. 1 is a block diagram showing the plant and method for recovering and treating residues from crushing scrap according to the present invention.

DETAILED DESCRIPTION OF SOME FORMS OF EMBODIMENT

[0039] With reference to FIG. 1 of the attached drawing, a plant for recovering and treating residues from crushing ferrous scrap according to the present invention is shown schematically with the reference number 10. The plant 10 substantially comprises a first plant part 110 for separating residues from crushing scrap, for example ASR material 12, into its main components, and a second plant part 210 for the preparation and sizing of the plastic materials to be sent to an iron and steel plant 40 such as a blast furnace, electric arc furnace or suchlike Although hereafter in the description we shall refer to the specific application of an electric arc furnace 40, the same considerations can also refer in general to iron and steel plants.

[0040] The first plant part 110 regarding the separation and sorting of materials substantially comprises a single treatment line.

[0041] As the first element in said treatment line, a crushing or granulator system is provided, represented symbolically by block 11. Preferably, in the first plant part 110 a single crushing or granulator system 11 is provided. The granulator system 11 can be for example a mill with a vertical rotor and rotary star cams, by means of which all the ASR material 12 is crushed, without any prior screening, to a size that optimizes the recovery of the different fractions. The size of the granulated material can be comprised between 0 and 30 mm, preferably between 0 and 20 mm. The function of the granulator system 11 is therefore to reduce the size of the material, both through a mechanism that disintegrates the materials, which implies separating the different constituents of a composite material, such as metal cables, and also by granulating the fractions of metal and hard plastics.

[0042] During this first step of size reduction, as a consequence of the reciprocal friction mechanisms between the materials, the latter heat up, promoting the reduction in residual humidity. Therefore, a stream F of mixed granular material, with a size and density suitable for the subsequent treatments, comes out from the granulator system 11.

[0043] Downstream of the granulator system 11 a magnetic separation system 13 is provided, able to separate the fraction of ferrous materials 14 from the rest of the stream F of granular material. The magnetic separation system 13 can be any known system, for example a magnetic system with a belt or drum.

[0044] Downstream of the magnetic separation system 13 a separation by density system 15 is provided, for example using a jet of air, which, after the step of magnetic separation using the magnetic separation system 13, or even already in the shredding step, is used to remove light plastic materials 16, possibly also in the form of fibers, from the stream F of granular material.

[0045] By means of the magnetic separation system 13 and the separation by density system 15, a first stage of density/size separation is implemented, to remove most of the light plastic materials 16, also in the form of fibers, which have already been disintegrated. The heavier fraction exiting from the granulator system 11 and the magnetic separation system 13 is sent to a first screening device 17.

[0046] According to a possible solution, material with unsuitable sizes, for example more than 20 mm, can be recirculated to the granulator system 11, line 18, while material with suitable sizes, for example less than 20 mm, is sent to an induced current separation system 19. The purpose of the induced current separation system 19 is to separate components or fractions of non-ferrous metals 20 from the main current of ASR material being treated. The induced current separation system 19 is able to produce a clean expelled fraction, for example aluminum, based on the settings of the machine, and a remaining mixed fraction which includes plastic mixed material and copper.

[0047] After the induced current separation system 19 the plant 10 according to the present invention can provide another separation by density system 21, for example using a stream of air by means of which it is possible to separate from the main stream of material another fraction of light plastic materials 16, line 22, or a fraction of plastic materials classifiable as heavy or hard, hereafter referred to as heavy or hard plastic materials 24, line 23. The main fraction exiting from the separation by density system 21 consists mainly of heavy plastic materials and non-ferrous metals.

[0048] Downstream of the separation by density system 21 a multi-stage screening system 26 is provided, by means of which a plurality of fractions of materials is obtained. For example at least three fractions of materials having a homogeneous size, each of which is subjected to a stage of separation according to size/density on a mechanic/pneumatic sorting system 25, able to remove the lightest fraction with respect to the remaining stream.

[0049] According to the solution shown in FIG. 1, the multi-stage screening system 26 allows to separate four fractions from each other, respectively F1, F2, F3 and F4, each of which is sent to a respective stage of separation according to size/density on a mechanic/pneumatic sorting system 25.

[0050] Depending on the settings of the machines and on the type of material, one or more fractions of non-ferrous metals and one or two fractions of plastic material, more or less light, will be obtained at exit from the mechanic/pneumatic sorting system 25; in any case, at exit from this last separation stage, three different fractions are recovered. Thanks to this combination of treatments of screening, size/density separation, together with the induced current separation system, it is possible to obtain a series of clean fractions of heavy or hard plastic materials P1, P2, P3, P4. The combination of heavy or hard plastic materials obtained in the first plant part 110 is symbolized by block 24 described above. From the mechanic/pneumatic sorting system 25 and separation by size/density, it is also possible to separate another quantity of non-ferrous metals, line 27.

[0051] From the process or method performed by the first plant part 110 just described, at least four fractions of materials are obtained: a fraction of light plastic materials 16, mainly comprising fibers and polyurethanes; a fraction of heavy or hard plastic materials 24; a fraction of ferrous materials 14; and one or more fractions of non-ferrous metals 20, for example aluminum and copper.

[0052] To increase the purity of the fraction or fractions of non-ferrous metals 20, for example to divide the copper from the aluminum, it is possible to provide another induced current separation system 28, by means of which a separation is obtained of the main constituent components, for example a fraction of aluminum 29 and a fraction of copper 30.

[0053] As symbolized by the arrows shown, the fraction of aluminum 29, the fraction of copper 30, the fraction of ferrous materials 14 and the fraction of non-ferrous metals 20 which have not been subjected to further treatment by the induced current separation system 28, can be introduced directly onto the market, block 31. The light plastic materials 16 and heavy or hard plastic materials 24 are subjected to other treatments in order to improve the dimensional and transport characteristics, see second plant part 210, and especially in order to make them suitable for use as additive material, usable for example as fuel or reducing agent, in iron and steel plants such as electric arc furnaces 40, blast furnaces or suchlike.

[0054] The fraction of light plastic materials 16 can be voluminous and hence difficult to transport and manage. Using a thermomechanical transformation system 32, the fraction of light plastic and fiber materials 16 is transformed into a series of briquettes or compact cylinders, which have high density and good mechanical characteristics.

[0055] The thermomechanical transformation system 32, merely by way of example, can comprise an extruder of a known type, provided for example with two screws able to compress the plastic material. The compression of the plastic material causes an increase in temperature by friction and pressure only, until the portion of thermoplastic materials present in the fraction of light plastic materials 16 softens. Using this system, it is therefore not necessary to supply heat, since it is the pressure and friction between the plastic materials that generate an increase in temperature, which can be varied by modifying the stream of material, so as to adjust it according to needs and to the material.

[0056] Optionally, during the extrusion step, binding additives can be added, such as thermoplastic materials, carbon, sawdust and other biomasses.

[0057] Depending on the use of the plastic briquettes or cylinders obtained during the previous steps, it is possible to provide a cutting and/or grinding system 33, located downstream of the thermomechanical transformation system 32 and able to obtain material in a granular form, line 38, which is used as additive material, for example to function as fuel or reducing agent 34, to be fed to the furnace 40. Preferably, a single crushing system is provided in the second plant part 210, that is, the cutting and/or grinding system 33. The cutting and/or grinding system 33 can comprise, for example, a shearing mill, of a known type and with a functioning based on a rotating cylinder equipped with blades and a grid that allows the material with a determinate size to exit.

[0058] Merely by way of example, it can be provided that the material exiting from the cutting and/or grinding system 33 has a size comprised between 2 and 6 mm or any other size suitable for its subsequent introduction into the furnace 40. Alternatively, the cylinders or briquettes obtained by the thermomechanical transformation system 32 can be used directly as additive material, to function for example as fuel or reducing agent 34, line 39.

[0059] The fraction of heavy or hard plastic materials 24 can also be sent to the grinding process, for example in the same cutting and/or grinding system 33 described above, so as to obtain a more homogeneous fraction in size.

[0060] In any case it can be provided that the fraction of heavy or hard plastics 24 is used as it is, without any further treatments, as a fuel or reducing agent.

[0061] Optionally to what has been described, moreover, in the second plant part 210, a separation system 35 can be provided to separate the chlorinated heavy plastic materials 36 from the rest, so as to reduce the percentage of chlorine in the heavy or hard plastic materials 24. From this separation process, therefore, a fraction of heavy plastic materials not containing chlorine 24 and a fraction of chlorinated heavy plastic materials 36 are obtained. The heavy plastic materials not containing chlorine 24 can also be sent to the thermomechanical transformation system 32.

[0062] The separation system 35 can be either an optical or mechanical type.

[0063] As can be seen, the heavy or hard plastic materials 24, heavy plastic materials not containing chlorine 24 or the additive material, to function for example as fuel or reducing agent 34 in granular form, can be introduced directly onto the fuel or reducing agent market, block 37.

[0064] As we said at the beginning of the description, the additive material, to function for example as fuel or reducing agent 34 obtained from light plastic materials and heavy plastic materials, can advantageously be used to at least partly replace the carbon in a furnace 40, for example an electric arc furnace 40. If granulated plastic material is used, line 38, as additive material to function for example as fuel or reducing agent 34, the granulated material can be injected pneumatically under the slag using a pneumatic lance. Alternatively, as we said, it is possible to feed the briquettes or cylinders produced directly to the furnace 40, line 39. In this case the briquettes will be loaded inside the basket that feeds the furnace.

[0065] The Table below compares the chemical composition of carbon typically used in an electric arc furnace (EAF), that is, Metallurgic coke, and its ashes, with the composition of the additive material, to function for example as fuel or reducing agent 34 (called RPF, Recycled Plastic Fuel) and its ashes.

TABLE-US-00001 RPF* Metallurgical coke Elemental analysis Carbon (total) % 51.17 78 Hydrogen % 6.65 1.1 Nitrogen % 1.66 1.21 Chlorine % 1.28 Sulphur % 0.08 0.28 Chemical analysis of ash Aluminum % 11.9 32.1 Calcium as CaO % 17.9 0.71 Copper % 4.6 Iron Fe.sub.2O.sub.3 % 16.3 1.6 Potassium as K.sub.2O % 0.57 0.29 Magnesium MgO % 5.3 0.17 Sodium as Na.sub.2O % 3.8 0.19 Phosphorous as P.sub.2O.sub.5 % 0.78 0.68 Silicon as SiO.sub.2 % 37.6 61.1 Titanium % 1.16 1 Gross calorific value [MJ/kg] 23.74 28-31 *averaged data obtained by experimentation. They should be understood as a reference and not as a precise value.

[0066] In the furnace 40, for example an electric arc furnace, the advantages of adding polymers are not connected only to an economic saving in the at least partial replacement of carbon with a recovered material which is cheaper than carbon. If managed correctly, the injection of the polymer fraction allows to obtain very foamy slag, able to shield the arc and thus to reduce energy consumption and the problems of noise in the plant.

[0067] In applications in furnaces 40, for example electric arc furnaces, some potentially negative characteristics of the plastic fractions are easily managed. The presence of residues of ferrous metals is positive, the presence of metals such as copper and aluminum can easily be managed through the percentage of carbon replacement, hence by dilution.

[0068] Another advantageous possibility is to continuously monitor the quality parameters of the steel and slag so as to manage the stream of fuel or reducing agent, RPF (Recycled plastic fuel), indicated in block 34, which can be fed so as not to affect the quality of the steel.

[0069] The presence of chlorine in the plastics is the most critical aspect of the fuel produced. When used inside the electric arc furnace EAF, since it is possible and preferable to provide systems to abate persistent organic pollutants (dioxins, that is, PCDD, PCDF, and PCB: polychlorinated dibenzodioxins, polychlorinated dibenzofurans, polychlorinated biphenyls) and other dangerous elements inside the fume treatment system, the presence of chlorine is not discriminating. A system that is effective in drastically abating dioxins is to inject lignite, active carbons or mineral oxides or to use catalytic filters in fume treatment systems, upstream of the filtration stage.

[0070] Compared with other technologies using ASR material, therefore, the present method and the present plant advantageously produce a waste fraction that has to be sent to the dump below 5% in weight of the total: all the fractions are used inside the market or become RPF fuel.

[0071] Compared with other technologies to partly replace carbon in the electric arc furnace, the present method and the present plant produce a fraction of plastic materials that is clean of metals, thanks especially to the passes made in the first plant part 110.

[0072] Compared with other technologies to partly replace carbon in the electric arc furnace, the present method and the present plant produce a fraction that can be injected pneumatically under the slag, allowing better control of the quantity added, a better use of the material compared with loading in a basket, and prevents the possibility of being sucked into the fumes plant before it has carried out its function.

[0073] The light or heavy plastic materials, treated as described above, in granular or briquette form, can be used as fuel and at least partly to replace carbon, also in blast furnaces as well as in electric arc furnaces.

[0074] It is clear that modifications and/or additions of parts may be made to the method and plant as described heretofore, without departing from the field and scope of the present invention.

[0075] It is also clear that, although the present invention has been described with reference to some specific examples, a person of skill in the art shall certainly be able to achieve many other equivalent forms of plant, having the characteristics as set forth in the claims and hence all coining within the field of protection defined thereby.