DEVICE AND METHOD FOR SEPARATING AIR BY CRYOGENIC DISTILLATION

Abstract

Method for separating air by cryogenic distillation, wherein at least part of the air to be distilled is boosted in an air booster, compressed air is allowed to expand in at least one expansion turbine and, if the pressure drop between two points of the booster passes under a threshold and/or a flow of the booster passes under a minimum flow of the booster, part of the air boosted in the booster is allowed to expand without having been cooled between the booster and the expansion turbine and the boosted expanded air is sent upstream or downstream of the at least one turbine, without having been cooled in the heat exchanger, after having been boosted.

Claims

1. A device for separating air by cryogenic distillation comprising: an air compressor configured to compress all the air to be distilled; an air booster configured to boost at least part of the air to be distilled; an expansion turbine for receiving compressed air originating from the compressor and optionally from the air booster; a system of cryogenic distillation columns comprising at least one column; a heat exchanger; means for sending air from the compressor to the heat exchanger, which has two ends; means for bleeding cooled air at an intermediate point of the heat exchanger between the two ends and for sending cooled air to the booster; means for sending boosted air from the booster to the heat exchanger; means for sending air cooled in the heat exchanger to the turbine; means for sending air allowed to expand in the turbine to the system of columns; means for extracting an oxygen enriched flow and a nitrogen enriched flow from the system of columns, said means being connected to the heat exchanger; means for allowing the boosted air in the booster to expand; an absence of cooling means between the discharge of the booster and the means for allowing the boosted air to expand means for sending air, boosted in the booster and allowed to expand by the expansion means, upstream or downstream of the turbine, without having been cooled in the heat exchanger after having been boosted, means for detecting the pressure drop or the flow between two points of the booster, means for opening the expansion means for sending the boosted air upstream or downstream of the turbine, without passing through the heat exchanger, only if the pressure drop or the flow of the booster exceeds a threshold indicating that pumping is imminent.

2. The device according to claim 1, wherein the booster is connected to the inlet of the turbine so that the boosted air can be allowed to at least partly expand in the turbine.

3. A method for separating air by cryogenic distillation, the method comprising the steps of: compressing all air to be distilled in an air compressor; boosting at least part of the air to be distilled that is compressed in the air compressor in an air booster; expanding compressed air originating from the air compressor in at least one expansion turbine; separating compressed air cooled in a heat exchanger in a system of cryogenic distillation columns comprising at least one column; withdrawing cooled air from an intermediate point of the heat exchanger between the two ends thereof in order to be sent to the booster; sending boosted air from the booster to the heat exchanger; sending air cooled in the heat exchanger to the turbine; sending air allowed to expand in the turbine to the system of columns; and extracting an oxygen enriched flow and a nitrogen enriched flow from the system of columns and heating the oxygen enriched flow and the nitrogen enriched flow; wherein: i) if the pressure drop between two points of the booster is under a threshold indicating that the pumping point is imminent; or ii) if a flow of the booster is under a minimum flow of the booster indicating that the pumping point is imminent, part of the air boosted in the booster is allowed to expand without having been cooled between the booster and the expansion turbine; the boosted expanded air is sent upstream or downstream of the at least one turbine, without having been cooled in the heat exchanger, after having been boosted; and in the event of case ii), the flow in the booster is increased in order to exit the pumping zone.

4. The method according to claim 3, wherein if the pressure drop between the two points is above the threshold and/or a flow of the booster is above the minimum flow of the booster, all the air is sent from the booster to the heat exchanger in order to be cooled.

5. The method according to claim 3, wherein, if the pressure drop between the two points of the booster passes under the threshold and/or a flow of the booster passes under the minimum flow of the booster, none of the boosted air is sent upstream of the booster.

6. The method according to claim 3, wherein boosted and expanded air is allowed to expand in the turbine if the pressure drop between the two points of the booster passes under the threshold and/or a flow of the booster passes under the minimum flow of the booster and preferably no air flow originating from the booster is allowed to expand in the turbine if the pressure drop between the two points of the booster is above the threshold and/or a flow of the booster rises above the minimum flow.

7. The method according to claim 3, wherein, if the pressure drop between the two points of the booster passes under the threshold and/or a flow of the booster passes under the minimum flow, the boosted air is allowed to expand to the pressure of a column of the system of columns, is mixed with the air originating from the turbine and is sent to the column.

8. The method according to claim 3, wherein, if the pressure drop between the two points of the booster is above the threshold, all the boosted air is sent to cool in the heat exchanger.

9. The method according to claim 3, wherein the boosted expanded air sent to the turbine is sent to a turbine coupled to the booster from which the air originates.

10. The method according to claim 3, wherein the boosted expanded air sent to the turbine is sent to a turbine receiving all the air that it allows to expand from the booster.

11. The method according to claim 3, wherein the turbine receives air from the booster only in the event that the pressure drop between the two points of the booster is below the threshold.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0030] These and other features, aspects, and advantages of the present invention will become better understood with regard to the following description, claims, and accompanying drawings. It is to be noted, however, that the drawings illustrate only several embodiments of the invention and are therefore not to be considered limiting of the invention's scope as it can admit to other equally effective embodiments.

[0031] The invention will be described in further detail with reference to the figure, which shows a device for separating air by cryogenic distillation according to the invention.

DETAILED DESCRIPTION OF THE INVENTION

[0032] The device comprises a system of columns comprising a column operating at a first pressure K1 and a column operating at a second pressure K2 below the second pressure. The columns are thermally connected through a bottom reboiler of the second column heated by nitrogen from the top of the first column. Nitrogen and oxygen enriched reflux flows, not shown, are sent from the column K1 to the column K2. Liquid oxygen 31 is extracted from the bottom of the second column K2 and gaseous nitrogen 33 is extracted from the top of the second column. Liquid nitrogen LIN is sent from the top of the second column in certain phases in order to help to keep the method cold. An oxygen rich fluid is sent to the exchanger E to be heated, for example, liquid oxygen 31 can vaporise in the heat exchanger E. A nitrogen rich fluid is sent to the exchanger E to be heated.

[0033] The device comprises a first air expansion turbine T1, a second air expansion turbine T2, a first air booster C1 coupled to the first turbine and a second air booster C2 coupled to the second turbine.

[0034] Compressed air 1 at a pressure P and originating from another compressor (not shown) is divided into two fractions, a first fraction 3 of which is sent to the heat exchanger

[0035] E without having been compressed at a pressure above the pressure P. A second fraction 5 is sent to the first booster C1, where it is compressed at a pressure above the pressure (P) of the first fraction 3. The outlet of the first booster C1 is connected to the inlet of said booster by a duct 25 through a valve V8.

[0036] According to a first variation, the first fraction 3 is cooled in the heat exchanger E to an intermediate temperature thereof and, having not been compressed in the first booster, is sent to the first and the second turbines through the open valve CL3 and the open valves V5, V13, V4, V19.

[0037] The second fraction 5 cools in the heat exchanger E to an intermediate temperature thereof, after having been compressed in the first booster C1. It is subsequently sent to the second booster C2.

[0038] During normal operation, expanded air originating from the first and second turbines is sent to the first column K1 in order to be separated through the valves V6, V15, V11 and the duct 13. The second fraction 5 is compressed in the second booster C2, passes through the open valve CL1 and is subsequently cooled in the heat exchanger before being sent in liquid form to the first column K1 through the valve V9. The valves V2 and V3 are closed.

[0039] If the booster C1 approaches its pumping point, part of the boosted air is taken, after cooling in a cooler downstream of the booster, is allowed to expand by the valve V8 and is sent to the suction side of the booster C1.

[0040] If the booster C2, supplied with air 19 originating from an intermediate point of the heat exchanger E, approaches its pumping point, none of the air boosted in the booster C2 is sent to the suction side of the booster C2. The booster C2 does not have any coolant downstream of the booster. If the flow boosted in C2 passes under a threshold indicating that the pumping point is imminent, part of the boosted air is sent via the duct 23, is allowed to expand in the valve V3 and reaches the suction side of the turbine T2 in order to be allowed to expand therein and to be sent to distillation.

[0041] The detection threshold of the imminence of the pumping point is defined by defining a pressure drop threshold between two points of the booster, which threshold must not be exceeded. As long as the pressure drop remains below the threshold, all the boosted air is sent to the heat exchanger in order to be liquefied therein.

[0042] Once the pressure drop has reached the threshold, the valve is opened that allows the air to pass to the turbine.

[0043] The remainder of the boosted air is returned to the heat exchanger E through the valve CL1 and is at least partly liquefied in the exchanger, before being allowed to expand in the valve V9 and being sent to the column K1.

[0044] Alternatively, the part of the air sent to the inlet of the turbine T2 can be sent to the outlet thereof arriving in the duct 17. In this case, the air expansion valve will allow this part of the air to expand to a pressure that is slightly above the pressure of the column K1.

[0045] It is also possible for the part of the air to be sent to the inlet or the outlet of the turbine T1 instead of to the turbine T2. The air even can be sent to the two turbines T1, T2, to the inlets of the two turbines, to the outlets of the two turbines or to the inlet of one turbine and to the outlet of the other turbine.

[0046] According to a second variation, the first fraction 3 is discharged from a heat exchanger at an intermediate temperature thereof and, having not been compressed in the first booster, is sent to the second booster C2.

[0047] The second fraction 5 cools in the heat exchanger to an intermediate temperature thereof, after having been compressed in the first booster C1. It is subsequently sent to the first and the second turbines.

[0048] Again, in this case, if the booster C2, supplied with air 19 originating from an intermediate point of the heat exchanger E, approaches its pumping point, none of the air boosted in the booster C2 is sent to the suction side of the booster C2. The booster C2 does not have any coolant downstream of the booster.

[0049] If the flow boosted in C2 passes under a threshold indicating that the pumping point is imminent, part of the boosted air is sent via the duct 23, is allowed to expand in the valve V3 and reaches the suction side of the turbine T2, without passing through the exchanger E, in order to be allowed to expand in the turbine T2 and to be sent to distillation.

[0050] The detection threshold of the imminence of the pumping point is defined by defining a pressure drop threshold between two points of the booster, which threshold must not be exceeded. This pressure difference is equivalent to the minimum flow of air in the booster, which minimum flow must not be passed under. As long as the pressure drop remains above the threshold, all the boosted air is sent to the heat exchanger in order to be liquefied therein.

[0051] Once the pressure drop passes under the threshold, the valve is opened that allows the air to pass towards the turbine.

[0052] It is also possible to trigger opening of the valve if the air flow in the booster passes under a threshold.

[0053] The remainder of the boosted air is returned to the heat exchanger E through the valve CL1 and at least partly liquefies in the exchanger, before being allowed to expand in the valve V9 and being sent to the column K1.

[0054] Alternatively, the part of the air sent to the inlet of the turbine T2 can be sent to the outlet thereof arriving in the duct 17. In this case, the air expansion valve will allow this part of the air to expand to a pressure slightly above the pressure of the column K1.

[0055] It is also possible for the part of the air to be sent to the inlet or the outlet of the turbine T1 instead of to the turbine T2. The air even can be sent to the two turbines T1, T2, to the inlets of the two turbines, to the outlets of the two turbines or to the inlet of one turbine and to the outlet of the other turbine.

[0056] An oxygen rich fluid is sent to the exchanger E to be heated, for example, liquid oxygen 31 can vaporise in the heat exchanger E. A nitrogen rich fluid is sent to the exchanger E to be heated.

[0057] The invention is also applicable to the case where the device only comprises a single air turbine coupled to a cold booster.

[0058] In this case, in normal operation the air is sent from the cold booster to the heat exchanger. The air then can directly enter the system of columns after being allowed to expand or otherwise can be at least partly sent to the single turbine.

[0059] In the event that part of the boosted air liquefies in the heat exchanger and is allowed to expand in a valve V9 upstream of the system of columns, when the air flow boosted in the booster C1 passes under a threshold indicating that pumping is imminent, the flow of liquid passing through the valve V9 can be increased. This valve will then be designed with respect to this operating case.

[0060] It is understood that the device can comprise a single cold booster and a single turbine, which may or may not receive air from the cold booster outside a pumping risk period.

[0061] This invention is applicable to any method using a cold air booster in a device for separating air by cryogenic distillation. For example, it is applicable to the following methods: FR2943408, WO05064252, EP2831525, JP2015114083, JP54162678, EP1055894, EP2600090, JP2005221199, EP2963370, EP2963369, FR2913670, FR3033397, EP2458311, EP1782011, EP1711765, FR2895068, EP2489968, DE102011121314, EP1014020, FR2985305, DE102006027650, FR2861841, FR3010778, EP644388 and FR2721383.

[0062] The inlet temperature of the air booster preferably is between 0 C. and 180 C., even between 60 C. and 180 C.

[0063] While the invention has been described in conjunction with specific embodiments thereof, it is evident that many alternatives, modifications, and variations will be apparent to those skilled in the art in light of the foregoing description. Accordingly, it is intended to embrace all such alternatives, modifications, and variations as fall within the spirit and broad scope of the appended claims. The present invention may suitably comprise, consist or consist essentially of the elements disclosed and may be practiced in the absence of an element not disclosed. Furthermore, if there is language referring to order, such as first and second, it should be understood in an exemplary sense and not in a limiting sense. For example, it can be recognized by those skilled in the art that certain steps can be combined into a single step.

[0064] The singular forms a, an and the include plural referents, unless the context clearly dictates otherwise.

[0065] Comprising in a claim is an open transitional term which means the subsequently identified claim elements are a nonexclusive listing (i.e., anything else may be additionally included and remain within the scope of comprising). Comprising as used herein may be replaced by the more limited transitional terms consisting essentially of and consisting of unless otherwise indicated herein.

[0066] Providing in a claim is defined to mean furnishing, supplying, making available, or preparing something. The step may be performed by any actor in the absence of express language in the claim to the contrary.

[0067] Optional or optionally means that the subsequently described event or circumstances may or may not occur. The description includes instances where the event or circumstance occurs and instances where it does not occur.

[0068] Ranges may be expressed herein as from about one particular value, and/or to about another particular value. When such a range is expressed, it is to be understood that another embodiment is from the one particular value and/or to the other particular value, along with all combinations within said range.

[0069] All references identified herein are each hereby incorporated by reference into this application in their entireties, as well as for the specific information for which each is cited.