METHOD FOR PRODUCING A MATERIAL WEB, USE THEREOF AS A REINFORCING PLY FOR AN ELASTOMER ITEM, AND VEHICLE PNEUMATIC TIRES

Abstract

The invention is directed to a vehicle pneumatic tire wherein strengthening plies are provided with steel cords running parallel to one another. The belt plies can be used, as isolated electrically conductive plates, for supplying electricity to electrical consumers such as sensors and actuators installed in the tire. Adjacent belt plies can be connected by puncture sensors to be able to identify damage to the belt caused by metallic parts penetrating from the outside, such as nails, on the basis of a change in the electrical resistance.

Claims

1-15. (canceled)

16. A pneumatic vehicle tire comprising a belt strengthening ply, wherein the belt ply comprises: an upper plate comprising a rubber mixture web; a lower plate comprising a second rubber mixture web positioned directly below the upper plate; a strengthening member web embedded between the upper plate and the lower plate, wherein the strengthening member web comprises a multiplicity of strengthening members that are positioned parallel to each other; and a multiplicity of filaments positioned on top of and at least substantially transverse to the strengthening members, wherein the multiplicity of filaments are comprised of a non-conductive textile carrier and an electrically conductive coating that coats each filament, wherein the belt strengthening ply is an isolated electrically conductive plate.

17. The pneumatic vehicle tire of claim 16, further comprising a woven or knit fabric material placed in contact with the strengthening member web and comprising the multiplicity of filaments.

18. The pneumatic vehicle tire of claim 17, wherein the woven or knit fabric comprising the multiplicity of filaments is substantially as wide as the strengthening member web.

19. The pneumatic vehicle tire of claim 16, wherein each of the multiplicity of filaments has a length of from 2 cm to 10 cm.

20. The pneumatic vehicle tire of claim 17, wherein the multiplicity of filaments are positioned or woven into the woven or knit fabric in a random arrangement such that successive filaments are in each case only partially positioned on identical individual strengthening members.

21. The pneumatic vehicle tire of claim 16, wherein the strengthening members are steel cords present at a density of from 2 to 120 per decimeter width of the belt ply.

22. The pneumatic vehicle tire of claim 16, wherein the filaments are randomly present above and below the multiplicity of strengthening members.

23. The pneumatic vehicle tire of claim 16, wherein the electrically conductive coating comprises an elastomer and electrically conductive particles.

24. The pneumatic vehicle tire of claim 23, wherein the electrically conductive particles are graphite particles, carbon black particles, or carbon nanotubes.

25. The pneumatic vehicle tire of claim 23, wherein the electrically conductive coating further comprises an adhesion promoter and carbon black particles.

26. The pneumatic vehicle tire of claim 25, wherein the adhesion promoter is a resorcinol-formaldehyde latex (RFL) comprising carbon black particles.

27. The pneumatic vehicle tire of claim 16, wherein the non-conductive textile carrier is a monofilament, a yarn, or a cord.

28. The pneumatic vehicle tire of claim 16, wherein the non-conductive textile carrier is rayon, polyester, polyamide, and/or aramid.

29. The pneumatic vehicle tire of claim 16, wherein the pneumatic vehicle tire comprises at least two belt strengthening plies.

30. A method for producing a pneumatic vehicle tire electrically conductive belt strengthening ply, which comprises: providing an upper plate comprising a rubber mixture web; providing a lower plate comprising a second rubber mixture web; providing a strengthening member web comprising a multiplicity of steel strengthening members that are positioned parallel to each other; providing a multiplicity of filaments each comprising a non-conductive textile carrier and an electrically conductive coating; positioning the upper plate on top of the strengthening member; positioning the strengthening member web on top of the lower plate; leading under tension the positioned upper plate, strengthening member web, and lower plate through a roll gap of a roll calender; applying the multiplicity of filaments to the strengthening member web before leading the upper plate, strengthening member web, and lower plate through the roll gap; and calendaring the upper plate, strengthening member web with filaments, and lower plate thereby joining together the upper plate with the strengthening member and the lower plate, wherein the multiplicity of filaments contact at least some of the strengthening members at least substantially transversely with respect to the parallel strengthening members.

31. The method of claim 30, further comprising providing a woven or knit fabric comprising the multiplicity of filaments, and further comprising positioning the woven or knit fabric above or below the strengthening member web before leading the upper plate, strengthening member web, and lower plate through the roll gap of the roll calender.

32. The method of claim 31, wherein the woven or knit fabric at least has a width substantially corresponding to a width of the strengthening member web.

33. The method of claim 31, which further comprises: leading the strengthening member web over a creel before leading the upper plate, strengthening member web, and lower plate through the roll gap of the roll calender to alternately lift individual strengthening members of the strengthening member web, and placing the filaments between the alternately lifted and non-lifted strengthening members.

34. The method of claim 31, wherein the electrically conductive coating of the filaments comprises or is composed of an elastomer, optionally a resorcinol-formaldehyde latex (RFL), and electrically conductive particles, selected from one or more of carbon black particles, graphite particles, and carbon nanotubes.

35. The method of claim 34, which further comprises: dipping an uncut filament into a suspension comprising RFL and carbon black particles, wherein the suspension comprises from 10% to 70% by weight of carbon black particles; and then cutting the uncut filament, thereby producing the multiplicity of filaments.

Description

BRIEF DESCRIPTION OF THE DRAWING

[0022] The invention will now be described with reference to the single FIGURE of the drawing (FIG. 1) which shows a method stage during the production of a material web for a reinforcement ply.

DESCRIPTION OF THE PREFERRED EMBODIMENTS OF THE INVENTION

[0023] The material web 1 produced in accordance with the method according to the invention comprises a multiplicity of strengthening members 2 which run parallel to one another and which are composed of steel, in particular steel cords of conventional construction, which are embedded into a rubber mixture. If the material web 1 is used for producing a belt ply in a belt assembly of a pneumatic vehicle tire, the number of strengthening members 2 per decimeter width of the belt ply amounts to for example 90 to 120. In belt plies, the strengthening members 2 normally run at a certain angle with respect to the circumferential direction of the pneumatic vehicle tire, such that the material web 1 is trimmed correspondingly. The rubber mixture in which the strengthening members 2 are embedded is referred to as rubberizing mixture and, as shown in FIG. 1, is produced from two rubber mixture plates, an upper plate 3 and a lower plate 4, which are rubber mixture webs produced by calendering. The upper plate 3 and the lower plate 4 are led through the roll gap of a roll calender 5, wherein the strengthening members 2 running parallel to one another are led, under tension, through the roll gap between the upper plate 3 and the lower plate 4. Downstream of the roll calender 5, which is illustrated in this case by way of example with two calender rolls 6, the material web 1 composed of strengthening members 2 that have been rubberized on both sides exits the roll calender 5.

[0024] Before entering the roll gap, the strengthening members 2 running parallel to one another form a strengthening member web 2a, onto which electrically conductive filaments 7 are placed substantially transversely with respect to the longitudinal extent of the strengthening members 2. The electrically conductive filaments 7 may be of substantially equal length, or may have different lengths in the range of a few centimeters, in particular from 2 cm to 10 cm. The filaments 7 are placed on such that successive filaments 7 in a direction of extent of the strengthening member web 2a are in each case as far as possible only partially positioned on the same strengthening members 2. Here, the filaments 7 do not need to be placed on rectilinearly, but rather may be placed on in a somewhat random arrangement. The filaments 7 may be placed on without or with points of contact with one another. By means of the multiplicity of filaments 7, contact is produced between different sets of strengthening members 2 by filaments 7 over the length of the strengthening member web 2a.

[0025] In a further configuration variant that is not illustrated, a woven fabric or knit composed of electrically conductive filaments is supplied together with the strengthening member web, between the upper plate 3 and lower plate 4, to the roll gap of the roll calender 5.

[0026] Alternatively, individual electrically conductive filaments may be woven into the strengthening members 2 transversely with respect to the direction of extent of the strengthening member web 2a. For this purpose, the strengthening member web 2a may be led over a creel which serves to alternately lift some strengthening members, such that the electrically conductive filaments can be placed, for example fired in, between the lifted and the non-lifted strengthening members 2.

[0027] In a preferred embodiment of the invention, the electrically conductive filaments 7 are composed in each case of a carrier filament composed of an electrically non-conductive material, which has an outer coating or shell is composed of an electrically conductive, preferably elastomeric material. The electrically conductive coating of the carrier filaments may also be composed of electrically conductive particles, for example graphite powder or carbon nanotubes. The carrier filaments may for example be composed of rayon, polyester, polyamide or aramid and may be a monofilament, a yarn or a cord composed of multiple yarns. The electrically conductive coating is based, for example, on a suspension comprising latex or another elastomer and including electrically conductive particles, for example carbon black particles or graphite powder, which ensures the electrical conductivity of the coating. This coating can be produced by using, for example, a conventional adhesion promoter comprising carbon black particles, which is liquid to such an extent that the carrier filament composed of textile material can be coated by means of a dipping operation. Use may for example be made of an RFL dip (resorcinol-formaldehyde latex dip) incorporating carbon black particles, in particular N 339 particles or N 121 particles. The proportion of electrically conductive particles in the suspension is for example 10% by weight to 70% by weight, in particular 30% by weight to 50% by weight. The filament produced as endless filament and provided with an electrically conductive coating is cut into correspondingly shorter filaments 7.

[0028] During the calendering process in the roll calender 5, the coating of the filaments 7 is embedded into the rubber material of the upper plate 3 and of the lower plate 4, such that electrically conductive passages are formed in the rubber material, which passages in each case connect a number of strengthening members 2 to one another in electrically conductive fashion. During the subsequent vulcanization of the elastomer article, for example of the pneumatic vehicle tire, the passages are retained. The carrier filaments may readily be damaged or destroyed during the further processing of the material web 1; the mechanical strength thereof is not of significance. Any ends of the filaments 7 that protrude at the lateral edges of the calendered material web 1 can be cut off.

[0029] It is understood that the foregoing description is that of the preferred embodiments of the invention and that various changes and modifications may be made thereto without departing from the spirit and scope of the invention as defined in the appended claims.

LIST OF REFERENCE NUMERALS

[0030] 1 . . . Material web

[0031] 2 . . . Strengthening member

[0032] 2a . . . Strengthening member web

[0033] 3 . . . Upper plate

[0034] 4 . . . Lower plate

[0035] 5 . . . Roll calender

[0036] 6 . . . Calender roll

[0037] 7 . . . Filaments