METHOD FOR PREPREGGING TACKIFIER FOR CMC ARTICLES

Abstract

A method of creating a tackified prepreg, includes steps of providing a fiber weave having unidirectional fibers and woven sections spaced apart from one another to provide unidirectional fiber sections, applying a tackifier to the fiber weave, arranging layers of the fiber weave onto one another to provide a stack, and wrapping the stack around a form to provide an article having a desired shape.

Claims

1. A method of creating a tackified prepreg, comprising steps of: providing a fiber weave having unidirectional fibers and woven sections spaced apart from one another to provide unidirectional fiber sections; applying a tackifier to the fiber weave; arranging layers of the fiber weave onto one another to provide a stack; and wrapping the stack around a form to provide an article having a desired shape.

2. The method according to claim 1, comprising the step of applying a resin to the article in a mold.

3. The method according to claim 2, wherein the resin is a liquid at room temperature.

4. The method according to claim 3, wherein the resin is a ceramic-based.

5. The method according to claim 4, wherein the tackifier and resin are silicon carbide-based.

6. The method according to claim 1, comprising heating and curing the article.

7. The method according to claim 6, comprising the step of machining the cured article.

8. The method according to claim 7, comprising the step of pyrolyzing the article, including the tackifier and the resin, subsequent to the machining step.

9. A CMC article for a gas turbine engine comprising: a wall having multiple tacks joined to one another, each stack including multiple layers, wherein the layers consist of unidirectional fibers forming a ceramic matrix composite with a resin and a tackifier that are different than one another.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0015] The disclosure can be further understood by reference to the following detailed description when considered in connection with the accompanying drawings wherein:

[0016] FIG. 1 is a flow chart of an example method of manufacturing a CMC article.

[0017] FIG. 2 is a schematic view of a prepregging process.

[0018] FIG. 3 is a side view of the prepregging process shown in FIG. 2.

[0019] FIG. 4 is a schematic view of multiple layers of fiber material kitted into stacks.

[0020] FIG. 5 is an example cross-sectional view of the stacks wrapped about a mandrel providing an article having a desired shape.

[0021] The embodiments, examples and alternatives of the preceding paragraphs, the claims, or the following description and drawings, including any of their various aspects or respective individual features, may be taken independently or in any combination. Features described in connection with one embodiment are applicable to all embodiments, unless such features are incompatible.

DETAILED DESCRIPTION

[0022] Referring to FIG. 1, a method 10 is disclosed of manufacturing ceramic matrix composite (CMC) articles. The method 10 includes prepregging a CMC fiber weave that includes unidirectional fiber sections with a tackifier, as indicated at block 12. Referring to FIG. 2, the fiber weave 28 includes unidirectional fibers 30 woven with cross fibers 32 to provide spaced apart woven sections 34. Unidirectional fiber sections 38 are provided between the woven sections 34. The woven sections 34 provide stability to the unidirectional fibers 30 during the prepregging process to hold the unidirectional fibers 30 in alignment with one another during the tackifying process. The fiber weave 28 is fed through rollers, for example, first and second rollers 42, 44 with the unidirectional fibers 30 oriented in a same direction as a feed direction F of the rollers 42, 44.

[0023] Referring to FIG. 3, the tackifier 40 may be applied to the fiber weave 28 in a bath. The second rollers 44 are arranged with respect to one another to provide a desired thickness 46 of the tackified fiber weave. Once the fiber weave 28 has been tackified, the unidirectional fibers 30 in the unidirectional sections 38 may be separated from the woven sections 34 at cut lines 36 shown in FIG. 2 (block 14 in FIG. 1). The unidirectional fibers 30 are sufficiently adhered to one another with the tackifier, such that they can be handled and trimmed without falling apart or frying the tow.

[0024] In one example, the tackifier is a pre-ceramic polymer material, for example, a silicon carbide. The tackifier is melt processable polymer solid at room temperature, for example, an amorphous solid that readily flows at moderate temperatures. In order to not compromise the integrity of the CMC, a tackifier was chosen that has the same chemical backbone as the matrix that material used, polycarbosilane. Upon pyrolyzing of the tackifier it is incorporated into the matrix of the CMC. The tackifier can also be loaded with filler particles to aid in processing in addition to altering desired CMC properties.

[0025] The degree of tack that is provided by the tackifier enables the layers of the unidirectional fibers 38 to be kitted and stuck to one another to produce stacks 50, as shown in FIG. 4 (block 16 in FIG. 1). The layers 48 are sufficiently sticky such that the layers will stick to one another at room temperature using hand pressure only or low levels of heat.

[0026] The tackifier process will provide the fabric/fiber to which it is applied with the appropriate handling characteristics that allow the fabric to be cut, handled and kitted while maintaining edge, ply integrity and fiber alignment. The fabric/fiber can then be utilized in RTM processing of complex shapes while maintaining handling characteristics. This process is suitable for the processing of unidirectional fiber tows.

[0027] Returning to FIG. 1, block 18, the stacks 50 are wrapped about a form 52, such as a mandrel shown in FIG. 5, to provide an article 54 having a desired shape. With continuing reference to FIG. 1, the article is arranged into a mold and a pre-ceramic polymer resin is injected into the mold. The resin and tackifier are different than one another. In one example, the resin is a liquid at room temperature. In one example, the tackifier has a greater carbon content than the resin.

[0028] The article is heated within the mold, as indicated at block 20. The article is allowed to cool and cure, enabling the resin and tackifier to set and the article to sufficiently take its shape for subsequent handling, as indicated at block 22. The article then may be machined to a finished shape, as indicated at block 24. Finally, the article may be arranged in a fixture to maintain its shape and heated to high temperatures, for example, 1000-1600 C., to pyrolized the article including the tackifier and resin, to form a crystalline ceramic matrix composite. The CMC article includes multiple stacks, each having multiple layers. The layers consist of unidirectional fibers that form a ceramic matrix composite with the resin and the tackifier.

[0029] It should also be understood that although a particular component arrangement is disclosed in the illustrated embodiment, other arrangements will benefit herefrom. Although particular step sequences are shown, described, and claimed, it should be understood that steps may be performed in any order, separated or combined unless otherwise indicated and will still benefit from the present invention.

[0030] Although the different examples have specific components shown in the illustrations, embodiments of this invention are not limited to those particular combinations. It is possible to use some of the components or features from one of the examples in combination with features or components from another one of the examples.

[0031] Although example embodiments have been disclosed, a worker of ordinary skill in this art would recognize that certain modifications would come within the scope of the claims. For that and other reasons, the following claims should be studied to determine their true scope and content.