Method of manufacturing a glass roll

Abstract

A method of manufacturing a glass roll, includes: a forming step (S1) of forming, while conveying a glass film, the glass film by a downdraw method; a temporary rolling step (S3) of rolling the glass film while superposing a protective film on the glass film at a downstream end of a path of the conveying in the forming step (S1), to thereby manufacture a source glass roll; and a main rolling step (S4) of unrolling, while conveying the glass film to a downstream side, the glass film from the source glass roll, and then rerolling the glass film while superposing a protective film on the glass film at a downstream end of a path of the conveying, to thereby manufacture a glass roll. Higher tension in a rolling direction is applied to the glass film in the main rolling step (S4) than in the temporary rolling step (S3).

Claims

1. A method of manufacturing a glass roll, comprising: forming, while conveying a glass film to a downstream side, the glass film by a forming device for carrying out a downdraw method; rolling the glass film while superposing a first protective film on the glass film at a downstream end of a path of the conveying in the forming, to thereby manufacture a source glass roll; unrolling, while conveying the glass film to the downstream side, the glass film from the source glass roll; and rerolling the glass film while superposing a second protective film on the glass film at a downstream end of a path of the conveying in the unrolling to thereby manufacture a glass roll, wherein, in the forming, the glass film at the downstream side of the forming device is conveyed while only a first surface of the glass film is contact-supported, wherein, in the unrolling, the glass film at the downstream side of the source glass roll is conveyed while only the first surface of the glass film is contact-supported, wherein, in the unrolling, a plurality of rollers is arranged on a conveying path from the source glass roll to the glass roll and contact-supports only the first surface of the glass film, the rollers changing a direction of conveying the glass film so that the glass film is bent toward the first surface side thereof, and wherein a wrap angle of the glass film relative to each of the rollers to the glass film is an acute angle, and wherein tension in a rerolling direction to be applied to the glass film in the rerolling is set higher than tension in the rolling direction to be applied to the glass film in the rolling.

2. The method of manufacturing a glass roll according to claim 1, wherein, in the rolling, tension in the rolling direction to be applied to the first protective film is set higher than tension in the rolling direction to be applied to the glass film.

3. The method of manufacturing a glass roll according to claim 1, wherein, in rerolling, tension in the rolling direction to be applied to the glass film is set higher than tension in the rolling direction to be applied to the second protective film.

4. The method of manufacturing a glass roll according to claim 1, wherein, in at least one of the rolling and rerolling, the glass film is rolled and/or rerolled after being cut by laser cutting into pieces each having a predetermined width.

5. The method of manufacturing a glass roll according to claim 1, wherein, in the rolling, an unavailable portion formed at each widthwise end portion of the glass film is cut by laser cutting by the time the glass film is rolled.

6. The method of manufacturing a glass roll according to claim 1, wherein the downdraw method comprises an overflow downdraw method.

7. The method of manufacturing a glass roll according to claim 1, wherein the glass film has a thickness of 1 m or more and 300 m or less.

8. The method of manufacturing a glass roll according to claim 1, wherein, in the rolling, the glass film and the first protective film are rolled while the first protective film is superposed on an outer peripheral surface side of the glass film so that the first protective film is kept to form an outermost layer.

9. The method of manufacturing a glass roll according to claim 1, wherein, in the rerolling, the glass film and the second protective film are rolled while the second protective film is superposed on an outer peripheral surface side of the glass film so that the second protective film is kept to form an outermost layer.

Description

BRIEF DESCRIPTION OF DRAWINGS

(1) FIG. 1 A flow chart illustrating a method of manufacturing a glass roll according to an embodiment of the present invention.

(2) FIG. 2 A diagram illustrating a state of implementation of a forming step, a cutting step, and a temporary rolling step which are included in the method of manufacturing a glass roll according to the embodiment of the present invention.

(3) FIG. 3 A diagram illustrating a state of implementation of a main rolling step which is included in the method of manufacturing a glass roll according to the embodiment of the present invention.

(4) FIG. 4 A diagram illustrating another state of implementation of the main rolling step which is included in the method of manufacturing a glass roll according to the embodiment of the present invention.

(5) FIG. 5 A diagram illustrating still another state of implementation of the main rolling step which is included in the method of manufacturing a glass roll according to the embodiment of the present invention.

DESCRIPTION OF EMBODIMENTS

(6) Hereinafter, embodiments of the present invention are described with reference to the drawings.

(7) FIG. 1 is a flow chart illustrating a method of manufacturing a glass roll according to a first embodiment of the present invention. The method of manufacturing a glass roll comprises a forming step S1, a cutting step S2, a temporary rolling step (first rolling step) S3, and a main rolling step (second rolling step) S4.

(8) In this embodiment, as illustrated in FIG. 2, the forming step S1 is performed by a forming device 1 for carrying out an overflow downdraw method. The forming device 1 comprises a forming zone 2, an annealing zone 3, and a cooling zone 4 in the stated order from top to bottom. Note that, the forming device 1 may carry out another downdraw method such as a slot downdraw method and a redraw method.

(9) In the forming zone 2, molten glass Gm is fed to a forming body 5 having a wedge-shaped cross-section, and the molten glass Gm overflowing from a top of the forming body 5 to both sides thereof is fused at a lower end portion of the forming body 5 so as to flow downward. In this manner, a plate-like glass film G is formed from the molten glass Gm. The glass film G gradually increases in viscosity as the glass film G moves downward. After its viscosity reaches viscosity high enough to be capable of keeping the shape, strain of the glass film G is removed in the annealing zone 3, and further, the glass film G is cooled to near room temperature in the cooling zone 4.

(10) In the annealing zone 3 and the cooling zone 4, at a plurality of points ranging from an upstream side to a downstream side of a conveying path for the glass film G, a roller group 6 comprising pairs of rollers is arranged, for guiding both widthwise end portions of the glass film G downward. Note that, in this embodiment, rollers, which are arranged in an uppermost portion of the forming zone 2 within the forming device 1, function as cooling rollers for cooling both the widthwise end portions of the glass film G, and also function as driving rollers for drawing the glass film G downward. On the other hand, residual rollers arranged within the forming device 1 function as idle rollers, tension rollers, and the like, for guiding the glass film G downward.

(11) The glass film G formed in this forming step S1 is a long film having a thickness of from 1 to 600 m (preferably, 1 to 300 m, and more preferably, 10 to 200 m). The glass film G is employed for, for example, a flat panel display (FPD) such as a liquid crystal display, a plasma display, and an OLED display, a glass substrate for a device such as a solar cell, a lithium ion battery, a digital signage, a touch panel, and an electronic paper display, a cover glass for an OLED lighting, a glass container for medical supplies, a window glass, and a lightweight laminated window glass.

(12) Further, a width of the glass film G is preferably 100 mm or more, more preferably 300 mm or more, and still more preferably 500 mm or more. Note that, the glass film G is used for a wide variety of devices including a small-screen display such as a mobile phone with a small size and a large-screen display such as a television set with a large size. Thus it is preferred that the width of the glass film G be finally selected as appropriate depending on a size of a substrate of a device to be used.

(13) Further, as a glass composition of the glass film G, there can be used various glass compositions of silicate glass and the like, such as silica glass and borosilicate glass. However, it is preferred to use non-alkali glass. The reason is as follows. When the glass film G contains an alkali component, a so-called too-abundant soda phenomenon occurs so that the glass film is structurally weathered. When the glass film G is curved, there is a risk in that the glass film is prone to break from a portion that is structurally weathered over time. Note that, the non-alkali glass herein comprises glass that does not substantially contain an alkali component, specifically, glass containing an alkali metal oxide of 1,000 ppm or less (preferably, of 500 ppm or less, and more preferably, of 300 ppm or less). Examples of glass satisfying this condition include OA-10G manufactured by Nippon Electric Glass Co., Ltd.

(14) Further, after the glass film G formed in the forming step S1 as described above is curved in a substantially horizontal direction by a posture changing roller group 7 which comprises a plurality of rollers for supporting the glass film G from below at positions below the forming device 1, the glass film G is conveyed to the cutting step S2 while keeping its posture. Note that, the posture changing roller group 7 may be omitted as appropriate.

(15) In the cutting step S2, an unavailable portion (ear portion) Gx formed at each widthwise end portion of the glass film G in the forming step S1 is cut and removed by a cutting device 8. The unavailable portion Gx is relatively thicker than an available portion Ga formed at a widthwise center portion of the glass film G.

(16) Specifically, the cutting device 8 carries out laser cleaving, and comprises: conveying means 9 for conveying the glass film G, which is formed continuously by the forming device 1, to the downstream side while keeping the glass film G in a substantially horizontal posture; locally heating means 10 for locally heating the glass film G, which is placed on the conveying means 9, through application of a laser beam L from a front surface side of the glass film G; and cooling means 11 for jetting cooling water W from the front surface side of the glass film G onto a heated region heated by the locally heating means 10. When the glass film G is cut by laser cleaving in this manner, without performing post-processing such as polishing, appropriate smoothness can be easily imparted to a cut surface which forms each widthwise end surface of the glass film G. Accordingly, the end surface of the glass film G does not bite into a protective film F1, and hence there is an advantage that it is possible to satisfactorily keep separation property between the glass film G and the protective film F1. There is also another advantage that a chip resulting from micro flaws is less likely to occur in each end surface of the glass film G when the glass film G is rolled. Here, in view of attaining the above-mentioned advantages more reliably, an arithmetic average roughness Ra of each widthwise end surface of the glass film G is preferably 0.1 m or less, and more preferably 0.05 m or less.

(17) In this embodiment, a carbon dioxide laser is used as the locally heating means 10, but alternatively, there may be used means capable of performing another type of localized heating such as heating with a heating wire or hot air blast. Further, the cooling means 11 jets the cooling water W as a refrigerant using an air pressure or the like. In this context, the refrigerant may include a cooling liquid other than the cooling water, a gas such as air or an inert gas, a mixture of a gas and a liquid, a mixture of a solid such as solid carbon dioxide or ice and the gas and/or the liquid, or the like. Note that, the cutting device 8 may carry out breaking and cutting along a scribe line using a diamond cutter, or carry out laser fusing.

(18) The conveying means 9 conveys the glass film G to the downstream side, and thus prior to a region to be cooled by the cooling means 11, a region to be heated by the locally heating means 10 is subjected to scanning performed from one end portion side of the glass film G along a preset cleaving line (boundary portion between the available portion Ga and the unavailable portion Gx) extending in a longitudinal direction of the glass film G. With this, thermal stress is generated through expansion due to a heating action and through contraction due to a cooling action of a refrigerant, and an initial crack (not shown), which is previously formed in a leading end portion of the preset cleaving line, propagates along the preset cleaving line. In this manner, the glass film G is subjected to full-body cleaving continuously.

(19) The cut unavailable portion Gx of the glass film G is bent downward to be separated from the available portion Ga, and then is discarded. On the other hand, the available portion Ga of the glass film G is conveyed to the temporary rolling step S3.

(20) In the temporary rolling step S3, in order that the protective film F1 may be kept to form an outermost layer, the glass film G (specifically, available portion Ga) is rolled by a predetermined length around a roll core 13 while the protective film F1 unrolled from a protective roll 12 is superposed on an outer peripheral surface side of the glass film G, and then the glass film G and the protective film F1 are cut by a cutting device (not shown) in a width direction thereof. Thus, a source glass roll 14 is manufactured. At this time, when tension is excessively applied to the glass film G, excessive tension is applied to a part of the glass film G that is in a softened state near the forming body 5. As a result, a thickness of the glass film G may become unstable, or in some cases, there may arise such a fatal problem that the glass film G breaks below the forming body 5. Accordingly, in the temporary rolling step S3, while tension (for example, tension of from 0 to less than 20 N per unit width (1 m) to the glass film G) is applied to the glass film G along a rolling direction within such a range as to prevent adverse effects on formation of the glass film G, the glass film G is rolled around the roll core 13. Here, in the temporary rolling step S3, it is not necessary to actively apply tension to the glass film G, and hence there may be applied only minimum tension that acts spontaneously when the glass film G is rolled.

(21) Further, in this embodiment, in the temporary rolling step S3, higher tension in the rolling direction is applied to the protective film F1 than to the glass film G. Specifically, for example, tension of from 0.8 to 400 N per unit width (1 m) is applied to the protective film F1. The tension to be applied to the protective film F1 is applied, for example, through setting a difference in rotation speed between the source glass roll 14 and the protective roll 12, or through interposing a tension roller 15 as illustrated in the drawing between the source glass roll 14 and the protective roll 12. With this, without applying high tension directly to the glass film G, it is possible to restrain movement of the glass film G by the protective film F1. That is, it is possible to obtain the same effect as that in a case of applying tension directly to the glass film G. Accordingly, it is possible to minimize roll misalignment or separation of the glass film G that occurs in the temporary rolling step S3. Further, the glass film G in a state of the source glass roll 14 is reliably held by the protective film F1, and hence the following situation is less likely to arise: the glass film G in the source glass roll 14 is rolled extremely tightly when the glass film G is unrolled from the source glass roll 14 in the main rolling step S4 described below.

(22) It is preferred that the protective film F1 for the source glass roll 14 have a thickness of from 20 to 1,000 m (more preferably, from 25 to 500 m). Further, it is preferred that the protective film F1 have a width larger than a width of the available portion Ga of the glass film G in order to protect both widthwise end surfaces of the glass film G from various contacts. That is, it is preferred that the protective film F1 extend beyond both widthwise sides of the available portion Ga of the glass film G.

(23) Further, by the time the temporary rolling step S3 is carried out, the temperature of the glass film G sometimes reaches 50 C. or more, and hence it is preferred that the protective film F1 be not transformed, for example, not softened at a temperature of around 100 C.

(24) It is preferred that an elastic film be used for the protective film F1. With this, it is possible to produce the source glass roll 14 free from looseness while applying appropriate tension in the rolling direction to the protective film F1. It is preferred that a tensile elastic modulus of the protective film F1 be from 1 to 5 GPa.

(25) It is preferred that conductivity be imparted to the protective film F1. With this, when the glass film G is taken out of the source glass roll 14, peeling electrification is less likely to occur between the glass film G and the protective film F1, therefore there may be an advantage that the protective film F1 can be easily peeled off from the glass film G. Examples of a method of imparting conductivity to the protective film F1 includes, for example, in a case where the protective film F1 is made of a resin, adding a component for imparting the conductivity, such as polyethylene glycol, into the protective film F1, and in a case where the protective film F1 is made of inserting paper, adding conductive fiber into the inserting paper. Further, it is possible to impart the conductivity into the protective film F1 also by laminating a conductive layer, such as an indium-tin-oxide (ITO) film, on a surface of the protective film F1.

(26) Specifically, as the protective film F1, there can be used a resin film, for example, an organic resin film (synthetic resin film) such as an ionomer film, a polyethylene film, a polypropylene film, a polyvinyl chloride film, a polyvinylidene chloride film, a polyvinyl alcohol film, a polyester film, a polycarbonate film, a polystyrene film, a polyacrylonitrile film, an ethylene vinyl acetate copolymer film, an ethylene-vinyl alcohol copolymer film, an ethylene-methacrylate copolymer film, a polyamide film, a polyimide film, and cellophane. Further, in view of ensuring cushioning performance, as the protective film F1, there can be used a foamed resin film such as an expanded polyethylene resin film, and a composite material obtained by laminating the foamed resin film on the above-mentioned resin films. In addition, in the above-mentioned resin films, there may be dispersed a lubricant such as silica, which yields a satisfactory degree of slip on the glass film G. With this, slipping property of the protective film F1 can absorb a difference in lengths to be rolled between the glass film G and the protective film F1, which results from a slight difference in diameters to be rolled between the glass film G and the protective film F1. Note that, the same applies to a protective film F2 for a glass roll 16 described below.

(27) Note that, regarding the above-mentioned matters relating to the protective film F1, the same applies to the protective film F2 for the glass roll 16 described below.

(28) The source glass roll 14 manufactured in the temporary rolling step S3 as described above is conveyed to the main rolling step S4, and then is rerolled.

(29) In the main rolling step S4, as illustrated in FIG. 3, with use of a roll-to-roll apparatus, the glass film G (specifically, available portion Ga) unrolled from the source glass roll 14 is rerolled, and thus the glass roll 16 as a product is manufactured.

(30) Specifically, in this embodiment, after the glass film G unrolled from the source glass roll 14 at an unrolling position P1 is guided on a roundabout route in a substantially circumferential manner by a roller group 17 comprising a plurality of rollers, the glass film G is rerolled around a roll core 18 at a rolling position P2. Thus, the glass roll 16 is manufactured. When the glass film G is guided in this manner, appropriate tension is easily applied to the glass film G also between the respective rollers of the roller group 17.

(31) At this time, at the unrolling position P1, the protective film F1 is peeled off from the glass film G, and the peeled-off protective film F1 is rolled into a protective roll 19. On the other hand, at the rolling position P2, in order that the protective film F2 may be kept to form an outermost layer, the glass film G is rolled around the roll core 18 while the protective film F2 unrolled from another protective roll 20 is superposed on the outer peripheral surface side of the glass film G. Then, after the glass film G is rolled by a predetermined length around the roll core 18 while the protective film F2 is superposed on the glass film G, the protective film F2 (or the glass film G and the protective film F2) is cut by the cutting device (not shown) in the width direction thereof. Thus, the glass roll 16 is manufactured. In this embodiment, the protective film F2 is the same type as the protective film F1 used in the temporary rolling step S3.

(32) Further, in the main rolling step S4, as illustrated in FIG. 1, tension b in the rolling direction to be applied to the glass film G is set higher than tension a to be applied to the glass film G in the temporary rolling step S3. Specifically, for example, tension of from 10 to 500 N per unit width (1 m) is applied to the glass film G. The tension to be applied to the glass film G is applied, for example, through setting a difference in rotation speed between the source glass roll 14 and the glass roll 16. Thus, even if roll misalignment or separation occurs in the glass film G which is included in the source glass roll 14 manufactured in the temporary rolling step S3, it is possible to apply satisfactory tension to the glass film G in the main rolling step S4, and to reroll the glass film G while straightening the roll misalignment or the like.

(33) Note that, in the main rolling step S4, higher tension in the rolling direction may be applied to the glass film G than to the protective film F2. Specifically, for example, it is preferred that tension of from 0.8 to 400 N per unit width (1 m) be applied to the protective film F2. The tension to be applied to the protective film F2 is applied, for example, through setting a difference in rotation speed between the glass roll 16 and the protective roll 20, or through interposing a tension roller 21 as illustrated in the drawings between the glass roll 16 and the protective roll 20. In this case, a magnitude relation between the tension in the rolling direction to be applied to the protective film F2 in the main rolling step S4 and the tension in the rolling direction to be applied to the protective film F1 in the temporary rolling step S3 is not particularly limited to the above. It is possible to set the magnitude relation as appropriate in consideration of various conditions (tension to the protective film F1<tension to the protective film F2, tension to the protective film F1=tension to the protective film F2, tension to the protective film F1>tension to the protective film F2).

(34) Further, in the main rolling step S4, as illustrated in FIG. 3, the glass film G is conveyed while only one surface of the glass film G is contact-supported, and the glass film G is rolled so that the contact-supported surface is situated on an inner peripheral surface side of the glass roll 16. Thus, even when the micro flaws occur in the contact-supported surface of the glass film G, the glass film G is rolled so that the contact-supported surface is situated on the inner peripheral surface side of the glass roll 16. In the glass roll 16, only compressive stress is applied to the inner peripheral surface of the glass film G. Accordingly, even when the micro flaws occur in the contact-supported surface, a force to propagate the micro flaws is less likely to act. In other words, on the outer peripheral surface of the glass film G on which the force to propagate the micro flaws acts, a non-contact surface having substantially no micro flaws is situated, and hence breakage of the glass film G can be reliably reduced. Note that, in this embodiment, also in the temporary rolling step S3, only one surface of the glass film G is contact-supported, and the contact-supported surface of the glass film G is set to the same side as the contact-supported surface of the glass film G supported in the main rolling step S4.

(35) Note that, the present invention is not limited to the above-mentioned first embodiment, and can be implemented in various modes. For example, as illustrated in FIG. 4, also in the main rolling step S4, the cutting step may be carried out. Specifically, the glass film G (specifically, available portion Ga) unrolled from the source glass roll 14 is cut in the width direction thereof to be divided into a plurality of (two in the illustrated example) glass films G each having a desired width. Then, each of the glass films G is rolled around the roll core 18 while superposing the protective film F2 on each of the glass films G. In this manner, a plurality of glass rolls 16 may be manufactured at the same time.

(36) Further, in the above-mentioned embodiment, description is made of a case where a surface of the glass film G situated on the inner peripheral surface side in a state of the source glass roll 14 is conveyed as the contact-supported surface of the glass film G. However, as illustrated in FIG. 4, a surface of the glass film G situated on the outer peripheral surface side in the state of the source glass roll 14 may be conveyed as the contact-supported surface of the glass film G. Further, in the above-mentioned embodiment, description is made of a case where the glass film G is rolled so that the contact-supported surface is situated on the inner peripheral surface side of the glass roll 16. However, the glass film G may be rolled so that the contact-supported surface is situated on the outer peripheral surface side of the glass roll 16.

(37) In addition, in the above-mentioned embodiment, description is made of a case where the glass film G unrolled from the source glass roll 14 is rolled in the main rolling step S4 after being guided on the roundabout route in the substantially circumferential manner. However, as illustrated in FIG. 5, the glass film G unrolled from the source glass roll 14 may be rolled after being guided in a straight manner.

(38) Further, in the above-mentioned embodiment, description is made of a case where the main rolling step S4 is carried out only one time after the temporary rolling step S3. However, after the main rolling step S4, a step of further rerolling the glass film G may be carried out one or a plurality of times.

(39) Next, description is made of a method of manufacturing a glass roll according to a second embodiment of the present invention. Note that, the second embodiment can be implemented in the same mode as that illustrated in FIG. 1, but is different from the first embodiment in that the temporary rolling step S3 is carried out as a main rolling step of manufacturing a glass roll as an end product.

(40) Specifically, in the second embodiment, as illustrated in FIG. 1, the glass film G is formed by a downdraw method, and the protective film F1 is superposed on the outer peripheral side of the formed glass film G. Then, while higher tension in the rolling direction is applied to the protective film F1 than to the glass film G, the protective film F1 and the glass film G are rolled. In this manner, a glass roll as an end product is manufactured. Further, while the glass roll thus manufactured remains rolled, higher tension in the rolling direction is applied to the protective film F1 than to the glass film G.

(41) Here, tension to be applied to the protective film F1 and tension to be applied to the glass film G are the same as the tension described in the temporary rolling step S3 described in the first embodiment (for example, tension of from 0 to less than 20 N per unit width (1 m) to the glass film G, and tension of from 0.8 to 400 N per unit width (1 m) to the protective film F1).

INDUSTRIAL APPLICABILITY

(42) The present invention can be preferably used for a glass substrate used for a flat panel display, such as a liquid crystal display or an OLED display, for a glass substrate used for a device such as a solar cell, and for cover glass for an OLED lighting.

REFERENCE SIGNS LIST

(43) 1 forming device 2 forming zone 3 annealing zone 4 cooling zone 5 forming body 7 posture changing roller group 8 cutting device 9 conveying means 10 locally heating means 11 cooling means 14 source glass roll 16 glass roll F1, F2 protective film G glass film