Colorant including a mixture of pigments

Abstract

A colorant including a mixture of pigments is disclosed. The pigments have a similar coloration but different resistance to corrosion. The mixing ratio is selected to optimize the corrosion resistance against color brightness, and/or acidic corrosion resistance against alkali corrosion resistance of the colorant.

Claims

1. A colorant comprising: a first pigment; and a second pigment, wherein the second pigment comprises a plurality of layers, wherein the plurality of layers include a particular layer, and wherein the particular layer is a reflective ferrochrome (FeCr) layer.

2. The colorant of claim 1, wherein the particular layer includes chromium.

3. The colorant of claim 1, wherein the first pigment includes a plurality of color-shifting interference flakes.

4. The colorant of claim 1, wherein the first pigment includes a dielectric magnesium fluoride (MgF.sub.2) layer.

5. The colorant of claim 1, wherein the first pigment includes a reflective opaque aluminum (Al) layer.

6. The colorant of claim 1, wherein the first pigment includes one or more semi-transparent chromium (Cr) layers.

7. The colorant of claim 1, wherein the particular layer is between two or more other layers of the plurality of layers.

8. The colorant of claim 1, wherein the plurality of layers further include silicon dioxide (SiO.sub.2) dielectric layers.

9. The colorant of claim 1, wherein the first pigment and the second pigment have a chroma of at least 10 units in an L*a*b* color space.

10. The colorant of claim 1, wherein a color difference hue between the first pigment and the second pigment is no more than 30 hue degrees in a polar projection of an L*a*b* color space.

11. A colorant comprising: a pigment, wherein the pigment comprises a plurality of layers, wherein the plurality of layers include a particular layer between two other layers of the plurality of layers, and wherein the particular layer is a reflective ferrochrome (FeCr) layer.

12. The colorant of claim 11, further comprising: another pigment that includes a plurality of chromium (Cr) layers.

13. The colorant of claim 11, further comprising: another pigment that includes an aluminum (Al) layer between four other layers.

14. The colorant of claim 11, further comprising: another pigment that includes a dielectric magnesium fluoride (MgF.sub.2) layer and a chromium (Cr) layer.

15. The colorant of claim 11, where the two other layers include dielectric magnesium fluoride (MgF.sub.2) layers.

16. The colorant of claim 11, where the two other layers include semi-transparent bismuth (Bi) layers.

17. The colorant of claim 11, where the two other layers include semi-transparent iron (Fe) layers.

18. The colorant of claim 11, wherein the pigment is a first pigment, and wherein the colorant is a mixture of the first pigment and a second pigment.

19. The colorant of claim 18, wherein a color difference hue between the first pigment and the second pigment is no more than 30 hue degrees in a polar projection of an L*a*b* color space.

20. The colorant of claim 18, wherein the first pigment exhibits a higher color change E*B in a basic solution than the second pigment, and wherein the second pigment exhibits a higher color change E*A in an acidic solution than the first pigment.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) Exemplary embodiments will now be described in conjunction with the drawings, in which:

(2) FIGS. 1A and 1B are diagrams of a colorant (FIG. 1B) obtained by mixing two different pigments (FIG. 1A);

(3) FIG. 2 is a diagram of a corrosion-induced color change of the two pigments of FIG. 1A and the colorant of FIG. 1B;

(4) FIG. 3 is a three-dimensional view of a color-shifting interference pigment chip of one embodiment of the first pigment of FIG. 1A;

(5) FIG. 4 is a diagram of a base-induced color change of the two color-shifting interference pigments of FIG. 1A and the mixture of these pigments shown in FIG. 1B;

(6) FIG. 5 is a process window diagram for mixing the first and second pigments of FIG. 1A to obtain a colorant of FIG. 1B having an improved alkali resistance, such as the one illustrated by the color change diagram of FIG. 4;

(7) FIG. 6 is a diagram of an acid-induced color change of the two pigments of FIG. 1A and the colorant of FIG. 1B;

(8) FIG. 7 is a combination of the diagrams of FIGS. 4 and 6; and

(9) FIG. 8 is a process window diagram for mixing the first and second pigments of FIG. 1A to obtain a colorant having improved alkali and acidic resistance, such as the one illustrated by the color change diagram of FIG. 7.

DETAILED DESCRIPTION OF THE INVENTION

(10) While the present teachings are described in conjunction with various embodiments and examples, it is not intended that the present teachings be limited to such embodiments. On the contrary, the present teachings encompass various alternatives and equivalents, as will be appreciated by those of skill in the art.

(11) Referring to FIGS. 1A and 1B, an exemplary colorant 10 is obtained by mixing first 11 and second 12 pigments P.sub.1 and P.sub.2 in a vial 19. The first 11 and second 12 pigments P.sub.1 and P.sub.2 have chroma parameters C*.sub.1 and C*.sub.2, respectively. Each of C*.sub.1 and C*.sub.2 is at least 10 unites in L*a*b* color space under illumination by a D65 standard light source using the 10 degree observer function. Although other chroma definitions can be used, the above definition has been selected for certainty of the chroma definition. The chroma parameters C*.sub.1 and C*.sub.2 of at least 15 units are preferable, because they result in brighter pigments. More preferably, the parameters C*.sub.1 and C*.sub.2 are at least 25 units.

(12) According to the invention, the first 11 and second 12 pigments being mixed together are of a same or similar color. Quantitatively, this can be expressed via a color difference hue between the first and second pigments, which is no more than 30 hue degrees, preferably no more than 20 hue degrees and more preferably no more than 15 hue degrees in the polar projection of the aforementioned L*a*b* color space using the same observer function.

(13) The corrosion resistivity of the pigments 11 and 12 can be represented by a color change exhibited when the pigments 11 and 12 are immersed into a standardized corrosive medium, including alkaline acidic solutions, a bleach solution, or water. It is assumed that the first pigment 11 undergoes a corrosion-induced color change E*(P.sub.1) when immersed into a corrosive solution, and the second pigment 12 undergoes a corrosion-induced color change E*(P.sub.2) when immersed into the corrosive solution.

(14) Turning to FIG. 2, the corrosion-induced color change E*(P.sub.2) of the second pigment 12, shown with a bottom solid line 22, is less than the corrosion-induced color change E*(P.sub.1) of the first pigment 11, shown with a top solid line 21. The colorant 10 is a mixture of the pigments 11 (P.sub.1) and 12 (P.sub.2). Since E*(P.sub.2)<E*(P.sub.1), a corrosion-induced color change E*(P.sub.1+P.sub.2) upon immersing the colorant 10 into the corrosive solution will generally be less than E*(P.sub.1), which is the largest E* of the two pigments 11 and 12. The corrosion-induced color change E*(P.sub.1+P.sub.2) of the colorant 10 is shown in FIG. 2 with a dashed line 20 disposed between the solid lines 21 and 22. The rationale to mix the less stable first pigment 11 into the more stable pigment 12 is to meet particular color brightness or vividness characteristics. For example, when chroma C*.sub.1 of the first pigment 11 is higher than the chroma C*.sub.2 of the second pigment 12, the chroma C* of the mixture colorant 10 will be generally higher than the chroma C*.sub.2 of the second pigment 12.

(15) The corrosive solution can include 2% by weight aqueous solution of H.sub.2SO.sub.4, 2% by weight aqueous solution of NaOH, a 1.2% by weight aqueous solution of sodium hypochlorite bleach, or distilled water. The corrosion-induced color change E* is calculated using the formula
E*={square root over ((L*).sup.2+(a*).sup.2+(b*).sup.2)}(1)

(16) wherein L* is the lightness change, and a* and b* are color coordinate changes in the L*a*b* color space, caused by corrosion.

(17) In a preferred embodiment of the invention, the first 11 and second 12 pigments include color-shifting pigments, which are formed from a multilayer thin film structure broken down into small flakes. The multilayer film structure includes an absorber layer or layers, a dielectric layer or layers, and optionally a reflector layer, in varying layer orders. The coatings can be formed to have a symmetrical multilayer thin film structure, such as absorber/dielectric/reflector/dielectric/absorber; or absorber/dielectric/absorber. Coatings can also be formed to have an asymmetrical multilayer thin film structure, such as absorber/dielectric/reflector. Color-shifting multilayer interference pigments are particularly advantageous in this invention, because for these pigments, the color can be decoupled, from the material system used, allowing one to vary the materials of the dielectric, semi-transparent, and reflective layers to fulfill certain corrosion resistance criteria, while varying thicknesses of these materials to match to each other colors of individual pigments.

(18) By way of a non-limiting illustrative example shown in FIG. 3 with further reference to FIGS. 1A and 1B, the first pigment 11 can include a plurality of color-shifting interference flakes 30 (FIG. 3) including in sequence a top semi-transparent chromium (Cr) layer 31, a top dielectric magnesium fluoride (MgF.sub.2) layer 32, a reflective opaque aluminum (Al) layer 33, a bottom dielectric magnesium fluoride (MgF.sub.2) layer 34, and a bottom semi-transparent chromium (Cr) layer 35. Of course, the terms top and bottom are relative, since the flakes 30 can have any orientation when suspended within the first pigment 11. The thicknesses of the first and second chromium 31, 35 and MgF.sub.2 layers 32, 24 are selected to make the pigment 11 have blue-greenish color. The second pigment 12 includes the same basic structure of the flakes 30, only the dielectric layers 32, 34 are made of silicon dioxide (SiO.sub.2), and the center reflector layer 33 includes chromium which is effectively opaque. The first 11 and second 12 pigments of this composition have chroma of at least 10 units in L*a*b* color space under illumination by a D65 standard light source using the 10 degree observer function, as measured using a standard d/8 integrating sphere geometry. The color difference hue between the first 11 and second 12 pigments is no more than 30 hue degrees in the polar projection of the L*a*b* color space at the above illumination/observation conditions.

(19) Table 1 below shows results of testing of color degradation of the first 11 and second 12 pigments upon immersion into 2% by weight aqueous solution of NaOH. The values of C* were measured before the immersion. hue.sub.11-12 is a difference of hue between the pigments 11 and 12.

(20) TABLE-US-00001 TABLE 1 Sample Pigment E*.sub.B C* hue.sub.11-12 Pigment 11: green-to-blue Cr/MgF.sub.2/Al/MgF.sub.2/Cr 27.04 60.70 Pigment 12: green-to-blue Cr/SiO.sub.2/Cr/SiO.sub.2/Cr 4.05 52.30 50:50 mixture of Pigments 11 and 12 12.47 56.05 6.06

(21) Mixing together the color-shifting interference pigments 11 and 12 of Table 1 at different ratios allows one to optimize the color brightness (chroma) performance of the resulting colorant 10, as well as bring the base-induced color change E*.sub.B(P.sub.1+P.sub.2) of the colorant 10 below a pre-defined level. Referring to FIG. 5, chroma C* and the base-induced color change E*.sub.B of the colorant 10 are plotted as a function of P.sub.2/P.sub.1 mixing ratio. A top solid line 51 represents chroma C*(P.sub.2/P.sub.1) dependence, and a bottom solid line 52 represents the base-induced color change E*.sub.B(P.sub.1+P.sub.2). In this example, the mixing ratio P.sub.2/P.sub.1 is selected to simultaneously fulfill two criteria: to have the chroma C* above a threshold value C*.sub.0, and to have the base-induced color change E*.sub.B below a threshold value E*.sub.0.

(22) The chroma line 51 shows that as the ratio P.sub.2/P.sub.1 increases, the chroma C* decreases. This is because the chromium reflective layer 33 of the chips 30 of the second pigment 12 is not as reflective as the corresponding aluminum reflective layer 33 of the first pigment 11. A shaded area 53 above the threshold chroma value C*.sub.0 denotes a range of acceptable mixing ratios P.sub.2/P.sub.1, at which chroma C*>C*.sub.0.

(23) The color change line 52 shows that as the mixing ratio P.sub.2/P.sub.1 increases, the color change also decreases. This is because the chromium reflective layer 33 of the chips 30 of the second pigment 12 is more stable in basic (alkali) solutions than the corresponding aluminum reflective layer of the first pigment 11. A shaded area 54 below the threshold color change value E*.sub.0 denotes a range of acceptable mixing ratios P.sub.2/P.sub.1, at which chroma E*.sub.B<E*.sub.0.

(24) Together, the shaded areas 53 and 54 define a process window 55 having a range 56 of acceptable mixing ratios P.sub.2/P.sub.1, which satisfy the conditions C*>C*.sub.0 and E*.sub.B<E*.sub.0 simultaneously. It has been found that a range of mixing ratios P.sub.2/P.sub.1 varying between 25:75 and 75:25 by weight can provide practically useful results.

(25) Turning to FIG. 6, acid-induced color change of the first pigment 11 E*.sub.A(P.sub.1) is shown with a bottom dotted line 61, and the acid-induced color change of the second pigment 12 E*.sub.A(P.sub.2) is shown with a top dotted line 62. The acid-induced color change E*.sub.A(P.sub.1+P.sub.2) upon immersing the colorant 10 into the 2% by weight aqueous solution of H.sub.2SO.sub.4 is less than E*.sub.A(P.sub.2). The acid-induced color change E*.sub.A(P.sub.1+P.sub.2) is shown with a dotted-dashed line 60. In a preferred embodiment of the invention, the two pigments 11 and 12 are selected so that while the first pigment 11 corrodes more in basic solutions than in acidic solutions, that is, E*.sub.B(P.sub.1)>E*.sub.A(P.sub.1), the second pigment 12 corrodes more in acidic solutions than in basic solutions, that is, E*.sub.A(P.sub.2)>E*.sub.B(P.sub.2).

(26) Referring to FIG. 7, the E*.sub.B(P.sub.1)>E*.sub.A(P.sub.1) and E*.sub.A(P.sub.2)>E*.sub.B(P.sub.2) conditions are illustrated by means of a corrosion-induced color change diagram. FIG. 7 is a combination of FIG. 4 showing the condition E*.sub.B(P.sub.1)>E*.sub.A(P.sub.1), and FIG. 6 showing the condition E*.sub.A(P.sub.2)>E*.sub.B(P.sub.2). Table 2 below includes results of corrosion-induced color degradation E* testing for the material systems of the first 11 and second 12 pigments satisfying the E* relationships represented by FIG. 7. In Table 2 below, the first 11 and second 12 pigments are color-shifting interference pigments including pigment flakes similar to the flake 30 shown in FIG. 3. The first pigment 11 includes the semi-transparent chromium (Cr) layers 31 and 35, the dielectric magnesium fluoride (MgF.sub.2) layers 32 and 34, and the reflective aluminum (Al) layer 33. The second pigment 12 includes the semi-transparent bismuth (Bi) layers 31 and 35, the dielectric magnesium fluoride (MgF.sub.2) layers 32 and 34, and the reflective ferrochrome (FeCr) layer 33. The first 11 and second 12 pigments of this composition have chroma of at least 10 units in L*a*b* color space under illumination by a D65 standard light source using the 10 degrees observer function, as measured using a d/8 integrating sphere geometry. The color difference E* between the first 11 and second 12 pigments is no more than 30 hue degrees in the polar projection of the L*a*b* color space at the above illumination/observation conditions. The values of C* were measured before the immersion. hue.sub.11-12 is a difference of hue between the pigments 11 and 12.

(27) TABLE-US-00002 TABLE 2 Sample Pigment E*.sub.B E*.sub.A C* hue.sub.11-12 Pigment 11: Cr/MgF.sub.2/Al/MgF.sub.2/Cr 27.04 1.79 60.70 Pigment 12: Bi/MgF.sub.2/FeCr/MgF.sub.2/Bi 4.71 30.12 37.25 50:50 mixture of Pigments 11 and 12 20.94 12.47 51.76 18.15

(28) Table 3 below illustrates corrosion performance of another material system. In Table 3, the first pigment 11 is the same as in Table 2. The second pigment 12 includes the semi-transparent iron (Fe) layers 31 and 35, the dielectric magnesium fluoride (MgF.sub.2) layers 32 and 34, and the reflective ferrochrome (FeCr) layer 33. The first 11 and second 12 pigments of this composition have chroma of at least 10 units in L*a*b* color space under illumination by a D65 standard light source using the 10 degrees observer function, as measured using a d/8 integrating sphere geometry. The color difference between the first 11 and second 12 pigments is no more than 30 hue degrees in the polar projection of the L*a*b* color space at the above illumination/observation conditions.

(29) TABLE-US-00003 TABLE 3 Sample Pigment E*.sub.B E*.sub.A C* hue.sub.11-12 Pigment 11: Cr/MgF.sub.2/Al/MgF.sub.2/Cr 27.04 1.79 60.70 Pigment 12: Fe/MgF.sub.2/FeCr/MgF.sub.2/Fe 0.99 37.30 37.54 50:50 mixture of Pigments 11 and 12 14.30 7.35 49.53 27.12

(30) The positive-slope solid line 81 shows that as the ratio P.sub.2/P.sub.1 increases, the acid-induced color change E*.sub.A(P.sub.2/P.sub.1) of the mixture colorant 10 increases. This is because bismuth (Bi) is more sensitive to acids than to bases. A shaded area 83 below the threshold value E*.sub.A0 denotes a range of acceptable mixing ratios P.sub.2/P.sub.1, at which chroma E*.sub.A(P.sub.2/P.sub.1)<E*.sub.A0.

(31) The negative-slope solid line 82 shows that as the ratio P.sub.2/P.sub.1 increases, the base-induced color change E*.sub.B(P.sub.2/P.sub.1) of the mixture colorant 10 decreases. This is because aluminum (Al) is more sensitive to bases than to acids. A shaded area 84 below the threshold value E*.sub.B0 denotes a range of acceptable mixing ratios P.sub.2/P.sub.1, at which chroma E*.sub.B(P.sub.2/P.sub.1)<E*.sub.B0.

(32) Together, the shaded areas 83 and 84 define a process window 83 having a range 86 of acceptable mixing ratios P.sub.2/P.sub.1, which satisfy the conditions E*.sub.A(P.sub.2/P.sub.1)<E*.sub.A0 and E*.sub.B(P.sub.2/P.sub.1)<E*.sub.B0 simultaneously.

(33) In accordance with a further embodiment of the invention, three or more pigments can be mixed together, for example, a third pigment P.sub.3 having the semi-transparent chromium (Cr) layers 31 and 35, the dielectric silicon dioxide (SiO.sub.2) layers 32 and 34, and the reflective chromium (Al) layer 33, can be added to the first 11 and second 12 pigments of Table 3 above. The third pigment P.sub.3 based only on chromium and silicon dioxide is quite stable in both acidic and alkaline solutions but has a relatively low chroma. Accordingly, if the chroma specification permits, the third pigment P.sub.3 added to the first and second pigments of Table 3, can further increase the corrosion resistance of the colorant 10, albeit at a slight drop of chroma C* of the colorant 10. To improve the corrosion resistance of the colorant 10, the corrosion-induced color change E*(P.sub.3) of the third pigment P.sub.3 upon immersion into the corrosive solution should satisfy the condition E*(P.sub.3)<E*(P.sub.2). The chroma C*.sub.3 of the third pigment P.sub.3 should be at least 10 units in L*a*b* color space trader illumination by a D65 standard light source using a 10 degree observer function, and a color difference between the first P.sub.1, second P.sub.2, and third P.sub.3 pigments is no more than 30 hue degrees in a polar projection of the L*a*b* color space. The three-component colorants 10 can include at least 25% of individual pigments P.sub.1, P.sub.2, and P.sub.3 by weight.

(34) A method of manufacture of the colorant 10 of the invention includes a first step of providing the first 11 (P.sub.1) and second 12 (P.sub.2) pigments, and a second step of mixing the pigments 11 and 12 together to obtain the colorant 10. The pigments 11 and 12 each have chroma C*.sub.1 and C*.sub.2, respectively, of at least 10 units in L*a*b* color space as explained above. The first pigment 11 undergoes a corrosion-induced color change E*(P.sub.1) upon immersion into a corrosive solution, and the second pigment 12 undergoes a corrosion-induced color change E*(P.sub.2) upon immersion into the corrosive solution, wherein E*(P.sub.2)<E*(P.sub.1). Upon mixing, the colorant 10 has E*(P.sub.1+P.sub.2)<E*(P.sub.1) as explained above. The proportion of the first 11 and second 12 pigments in the colorant 10 is preferably between 25:75 and 75:25.

(35) The corrosion-induced color changes of the first 11 and second 12 pigments and the colorant 10 include base-induced color changes E*.sub.B(P.sub.1), E*.sub.B(P.sub.2), and E*.sub.B(P.sub.1+P.sub.2), respectively, upon immersion into the 2% by weight aqueous solution of NaOH; and E*.sub.A(P.sub.1), E*.sub.A(P.sub.2), and E*.sub.A(P.sub.1+P.sub.2), respectively, upon immersion into the 2% by weight aqueous solution of H.sub.2SO.sub.4. In one embodiment, E*.sub.A(P.sub.1)<E*.sub.B(P.sub.1) and E*.sub.A(P.sub.2)>E*.sub.B(P.sub.2), while E*.sub.A(P.sub.2)>E*.sub.A(P.sub.1). This interrelationship between acidic and alkali induced color changes E* of the ingredients result in acid-induced color change E*.sub.A(P.sub.1+P.sub.2) of the colorant 10 upon immersion into the 2% by weight aqueous solution of H.sub.2SO.sub.4 satisfying the condition E*.sub.A(P.sub.1+P.sub.2)<E*.sub.A(P.sub.2), that is, the acidic resistance of the mixture colorant 10 improves as compared to that of the second pigment 12; and the alkali resistance of the mixture colorant 10 improves in comparison with that of the first pigment 11. The proportion of the first 11 and second 12 pigments in the colorant 10 is preferably between 25:75 and 75:25.

(36) As noted above, the first 11 and second 12 pigments preferably include color-shifting interference pigments. For certainty, tire conditions of chroma C*.sub.1 and C*.sub.2 of at least 10 units in color space under illumination by a D65 standard light source using the 10 degree observer function, and the color difference between, the first 11 and second 12 pigments of no more than 30 hue degrees in the polar projection of the L*a*b* color space color space is fulfilled as measured using a d/8 integrating sphere geometry.

(37) The chips or flakes 30 of the color-shifting interference pigments 11 and 12 can include, by means of example and without limitation, chromium (Cr), bismuth (Bi), iron (Fe), and ferrochrome (FeCr) outer semi-transparent layers 31 and 35, for providing different acid and/or alkali resistance. It is preferable that the first pigment 11 includes chromium (Cr) in the outer semi-transparent layers 31 and 35, and the second pigment 12 includes bismuth (Bi) or iron (Fe) in the outer semi-transparent layers 31 and 35. The reflective metal 33 can include aluminum (Al), chromium (Cr), ferrochrome (FeCr), and other materials.

(38) The dielectric layers of the flakes 30 of the color-shifting interferometric pigments 11 and 12 can include layers having a high index of refraction, defined herein as greater than about 1.8 or 1.9, as well as those have a low index of refraction, which is defined herein as about 1.65 or less. Each of the dielectric layers 32, 34 (FIG. 3) can be formed of a single material or with a variety of material combinations and configurations. For example, the dielectric layers 32, 34 can be formed of only a low index material or only a high index material, a mixture or multiple sub-layers of two or more low index materials, a mixture or multiple sub-layers of two or more high index materials, or a mixture or multiple sub-layers of low index and high index materials. In addition, the dielectric layers can be formed partially or entirely of high/low dielectric optical stacks, which are discussed in further detail below. When a dielectric layer is formed partially with a dielectric optical stack, the remaining portion of the dielectric layer can be formed with a single material or various material combinations and configurations as described above.

(39) Examples of suitable high refractive index materials for the dielectric layers 32, 34 include zinc sulfide (ZnS), zinc oxide (ZnO), zirconium oxide (ZrO.sub.2), titanium dioxide (TiO.sub.2) diamond-like carbon, indium oxide (In.sub.2O.sub.3), indium-tin-oxide (ITO), tantalum pentoxide (Ta.sub.2O.sub.5), ceric oxide (CeO.sub.2), yttrium oxide (Y.sub.2O.sub.3), europium oxide (Eu.sub.2O.sub.3), iron oxides such as (II)diiron(III) oxide (Fe.sub.3O.sub.4) and ferric oxide (Fe.sub.2O.sub.3), hafnium nitride (HfN), hafnium carbide (HfC), hafnium oxide (HfO2), lanthanum oxide (La.sub.2O.sub.3), magnesium oxide (MgO), neodymium oxide (Nd.sub.2O.sub.3), praseodymium oxide (Pr.sub.6O.sub.11), samarium oxide (Sm.sub.2O.sub.3), antimony trioxide (Sb.sub.2O.sub.3), silicon monoxide (SiO), selenium trioxide (Se.sub.2O.sub.3), tin oxide (SnO.sub.2), tungsten trioxide (WO.sub.3), combinations thereof, and the like.

(40) Examples of suitable low refractive index materials for the dielectric layers 32, 34 include silicon dioxide (SiO.sub.2), aluminum oxide (Al.sub.2O.sub.3), metal fluorides such as magnesium fluoride (MgF.sub.2), aluminum fluoride (AlF.sub.3), cerium fluoride (CeF.sub.3), lanthanum fluoride (LaF.sub.3), sodium aluminum fluorides (e.g., Na.sub.3AlF.sub.6 or Na.sub.5Al.sub.3F.sub.14), neodymium fluoride (NdF.sub.3), samarium fluoride (SmF.sub.3), barium fluoride (BaF.sub.2), calcium fluoride (CaF.sub.2), lithium fluoride (LiF), combinations thereof, or any other low index material having an index of refraction of about 1.65 or less. For example, organic monomers and polymers can be utilized as low index materials, including dienes or alkenes such as acrylates (e.g., methacrylate), perfluoroalkenes, polytetrafluoroethylene (Teflon), fluorinated ethylene propylene (FEP), combinations thereof and the like.

(41) The foregoing description of one or more embodiments of the invention has been presented for the purposes of illustration and description. It is not intended to be exhaustive or to limit the invention to the precise form disclosed. Many modifications and variations are possible in light of the above teaching. It is intended that the scope of the invention be limited not by this detailed description, but rather by the claims appended hereto. For instance, the invention is not limited to color-shifting interference pigments. Other pigments such as interference pigments, lamellar pigments, mica pigments, metallic flake pigments, and organic pigments exhibiting different alkali and/or acidic and/or bleach and/or water resistance can be used as well.