Ionic liquid, lubricant, and magnetic recording medium

Abstract

A lubricant including: an ionic liquid, which includes a conjugate acid (B.sup.+) and a conjugate base (X.sup.), and is protic, wherein the ionic liquid is represented by the following general formula (1), and wherein the conjugate base is a conjugate base of sulfonic acid, a conjugate base of sulfonimide, or a conjugate base of trisulfonylmethide: ##STR00001##
where R.sup.1 and R.sup.2 each represent a hydrogen atom or R.sup.1 and R.sup.2 form a benzene ring together with carbon atoms to which R.sup.1 and R.sup.2 are bonded, R.sup.3 represents a to straight-chain hydrocarbon group having 10 or more carbon atoms, and R.sup.4 represents a hydrogen atom or a hydrocarbon group in the general formula (1).

Claims

1. An ionic liquid comprising: a conjugate acid (B.sup.+); and a conjugate base (X.sup.), wherein the ionic liquid is represented by the following general formula (1) and is protic, and wherein the conjugate base is represented by the following general formula (3): ##STR00033## where R.sup.1 and R.sup.2 each represent a hydrogen atom or R.sup.1 and R.sup.2 form a benzene ring together with carbon atoms to which R.sup.1 and R.sup.2 are bonded, R.sup.3 represents a straight-chain hydrocarbon group having 10 or more carbon atoms, and R.sup.4 represents a hydrogen atom or a hydrocarbon group in the general formula (1) ##STR00034## where m is an integer of 0 to 2 in the general formula (3).

2. An ionic liquid comprising: a conjugate acid (B.sup.+); and a conjugate base (X.sup.), wherein the ionic liquid is represented by the following general formula (1) and is protic, and wherein the conjugate base is a conjugate base of sulfonic acid, a conjugate base of sulfonimide, or a conjugate base of trisulfonylmethide: ##STR00035## where R.sup.1 and R.sup.2 each represent a hydrogen atom or R.sup.1 and R.sup.2 form a benzene ring together with carbon atoms to which R.sup.1 and R.sup.2 are bonded, R.sup.3 represents a straight-chain hydrocarbon group having 10 or more carbon atoms, and R.sup.4 represents a hydrogen atom in the general formula (1).

3. The ionic liquid according to claim 2, wherein the conjugate base is represented by any one of the following general formulae (2) to (5): ##STR00036## where n is an integer of 0 to 20 in the general formula (2), m is an integer of 0 to 2 in the general formula (3), n is an integer of 0 to 10 in the general formula (4), and n is an integer of 0 to 6 in the general formula (5).

4. A lubricant comprising: the ionic liquid according to claim 1.

5. A lubricant comprising: the ionic liquid according to claim 2.

6. A magnetic recording medium comprising: a non-magnetic support; a magnetic layer on the non-magnetic support; and the lubricant according to claim 4 on the magnetic layer.

7. A magnetic recording medium comprising: a non-magnetic support; a magnetic layer on the non-magnetic support; and the lubricant according to claim 5 on the magnetic layer.

8. An ionic liquid comprising: a conjugate acid (B.sup.+); and a conjugate base (X.sup.), wherein the ionic liquid is represented by the following general formula (Y) and is protic, and wherein the conjugate base is a conjugate base of sulfonic acid, a conjugate base of sulfonimide, or a conjugate base of trisulfonylmethide ##STR00037##

9. The ionic liquid according to claim 8, wherein the conjugate base is represented by any one of the following general formula (2) to (5): ##STR00038## where n is an integer of 0 to 20 in the general formula (2), m is an integer of 0 to 2 in the general formula (3), n is an integer of 0 to 10 in the general formula (4), and n is an integer of 0 to 6 in the general formula (5).

10. A lubricant comprising: the ionic liquid according to claim 9.

11. A magnetic recording medium comprising: a non-magnetic support; a magnetic layer on the non-magnetic support; and the lubricant according to claim 10 on the magnetic layer.

Description

BRIEF DESCRIPTION OF DRAWINGS

(1) FIG. 1 is a cross-sectional view illustrating one example of a hard disk according to one embodiment of the present invention.

(2) FIG. 2 is a cross-sectional view illustrating one example of a magnetic tape according one embodiment of the present invention.

(3) FIG. 3 is a schematic view illustrating heat-assisted magnetic recording.

(4) FIG. 4 is the TG/DTA measurement result of the product of Example 1.

(5) FIG. 5 is the TG/DTA measurement result of the product of Example 2.

(6) FIG. 6 is the TG/DTA measurement result of the product of Example 3.

(7) FIG. 7 is the TG/DTA measurement result of the product of Example 4.

(8) FIG. 8 is the TG/DTA measurement result of the product of Example 5.

(9) FIG. 9 is the TG/DTA measurement result of the product of Comparative Example 2.

(10) FIG. 10 is the TG/DTA measurement result of the product of Comparative Example 3.

DESCRIPTION OF EMBODIMENTS

(11) (Lubricant and Ionic Liquid)

(12) A lubricant of the present invention includes an ionic liquid of the present invention, and may further include other components according to the necessity.

(13) The ionic liquid includes a conjugate acid (B.sup.+) and a conjugate base (X.sup.).

(14) The ionic liquid is protic.

(15) The ionic liquid is represented by the following general formula (1).

(16) The conjugate base is a conjugate base of sulfonic acid, a conjugate base of sulfonimide, or a conjugate base of trisulfonylmethide.

(17) ##STR00008##

(18) In the general formula (1), R.sup.1 and R.sup.2 each represent a hydrogen atom or R.sup.1 and R.sup.2 form a benzene ring together with carbon atoms to which R.sup.1 and R.sup.2 are bonded, R.sup.3 represents a straight-chain hydrocarbon group having 10 or more carbon atoms, and R.sup.4 represents a hydrogen atom or a hydrocarbon group in the general formula (1).

(19) The present inventors conducted extensive studies on an ionic liquid suitably usable in a lubricant and as a result have found that excellent thermal stability can be achieved in a specific imidazole-based ionic liquid using an imidazole derivative having a straight-chain hydrocarbon group having 10 or more carbon atoms. Moreover, the present inventors have found that particularly excellent thermal stability can be achieved when a straight-chain hydrocarbon group having 10 or more carbon atoms is bonded to a carbon atom at position 2 of an imidazole ring (a carbon atom between the two nitrogen atoms and bonded to these nitrogen atoms). The present invention has been completed on the basis of these findings.

(20) The ionic liquid being protic means that the ionic liquid has a proton donor ability, and means, for example, a state where a hydrogen atom is bonded to a cationic atom of the conjugate acid (B.sup.+).

(21) <Conjugate Acid>

(22) The conjugate acid is represented by the following general formula (6):

(23) ##STR00009##
where R.sup.1 and R.sup.2 each represent a hydrogen atom or R.sup.1 and R.sup.2 form a benzene ring together with carbon atoms to which R.sup.1 and R.sup.2 are bonded, R.sup.3 represents a straight-chain hydrocarbon group having 10 or more carbon atoms, and R.sup.4 represents a hydrogen atom or a hydrocarbon group in the general formula (6).

(24) Note that, the conjugate acids in the general formulae (1) and (6) may have other resonance structures (canonical structures). Specifically, the conjugate acids can have resonance structures (canonical structures), in which the nitrogen atom to which R.sup.4 is bonded is positively charged, and a hydrogen atom is bonded to the nitrogen atom. In the present invention, a conjugate acid having such a resonance structure (a canonical structure) is also included in the conjugate acid represented by the general formula (1) and the conjugate acid represented by the general formula (6).

(25) The upper limit of the number of carbon atoms of the straight-chain hydrocarbon group having 10 or more carbon atoms in the R.sup.3 is not particularly limited and may be appropriately selected depending on the intended purpose. The number of carbon atoms is preferably 30 or less, more preferably 25 or less, and particularly preferably 20 or less in view of readily availability of raw materials. Since the hydrocarbon group has a long chain, a coefficient of friction can be reduced, and lubricity is therefore improved.

(26) As long as the hydrocarbon group in the R.sup.3 is in the form of a straight chain, the hydrocarbon group may be a saturated hydrocarbon group, or an unsaturated hydrocarbon group containing double bonds at a part, or an unsaturated branched hydrocarbon group partially containing a branched structure. Among them, the hydrocarbon group is preferably an alkyl group, which is a saturated hydrocarbon group, in view of abrasion resistance. Moreover, the hydrocarbon group is also preferably a straight-chain hydrocarbon group that does not have any branch even partially.

(27) The hydrocarbon group in the R.sup.4 is not particularly limited and may be appropriately selected depending on the intended purpose. It is preferably a straight-chain hydrocarbon group having 10 or more carbon atoms. The straight-chain hydrocarbon group having 10 or more carbon atoms is preferably the hydrocarbon groups described with regard to the R.sup.3.

(28) The conjugate acid is preferably a conjugate acid represented by the following general formula (6-1) or (6-2):

(29) ##STR00010##
where R.sup.3 represents a straight-chain hydrocarbon group having 10 or more carbon atoms and R.sup.4 represents a hydrogen atom or a hydrocarbon group in the general formulae (6-1) and (6-2).
<Conjugate Base (X.sup.)>

(30) The conjugate base (X.sup.) is not particularly limited and may be appropriately selected depending on the intended purpose as long as it is a conjugate base of sulfonic acid, a conjugate base of sulfonimide, or a conjugate base of trisulfonylmethide.

(31) Examples of the conjugate base of sulfonic acid include conjugate bases represented by the following general formula (2).

(32) Examples of the conjugate base of sulfonamide include conjugate bases represented by the following general formula (3) and conjugate bases represented by the following general formula (4).

(33) Examples of the conjugate base of trisulfonylmethide include conjugate bases represented by the following general formula (5).

(34) Among them, conjugate bases represented by the following general formulae (2) to (5) are particularly preferable.

(35) ##STR00011##

(36) In the general formula (2), n is an integer of 0 to 20. In the general formula (3), m is an integer of 0 to 2. In the general formula (4), n is an integer of 0 to 10. In the general formula (5), n is an integer of 0 to 6.

(37) n in the general formula (2) is preferably an integer of 1 to 10.

(38) m in the general formula (3) is preferably 1 or 2.

(39) n in the general formula (4) is preferably an integer of 0 to 6.

(40) n in the general formula (5) is preferably an integer of 0 to 4.

(41) A synthesis method of the ionic liquid is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include a synthesis method of mixing equimolar amounts of an alkali metal salt of sulfonic acid or sulfoimide corresponding to the conjugate base and a nitric acid salt of a base corresponding to the conjugate acid, and a synthesis method of mixing equimolar amounts of sulfonic acid corresponding to the conjugate base and a base corresponding to the conjugate acid.

(42) The protic ionic liquids are synthesized more easily than aprotic ionic liquids because the protic ionic liquids have no need to make a nitrogen atom quaternized and can be obtained simply via an acid-base reaction. However, in order to reduce its dissociation to increase thermal stability, it is necessary to use an acid having a low pKa. Specifically, the acid preferably used has a pKa in dichloroethane of less than 10. Examples thereof include acids represented by the following general formula (2-1), acids represented by the following general formula (3-1), and acids represented by the following general formula (4-1).

(43) ##STR00012##

(44) In the general formula (2-1), n is an integer of 0 to 20. In the general formula (3-1), m is an integer of 0 to 2. In the general formula (4-1), n is an integer of 0 to 10.

(45) n in the general formula (2-1) is preferably an integer of 1 to 10.

(46) m in the general formula (3-1) is preferably an integer of 1 or 2.

(47) n in the general formula (4-1) is preferably an integer of 0 to 6.

(48) The ionic liquid may be used alone as the lubricant, or the ionic liquid may be used in combination with a conventional lubricant. Examples of the conventional lubricant include long-chain carboxylic acid, long-chain carboxylic acid ester, perfluoroalkyl carboxylic acid ester, perfluoroalkyl carboxylate, perfluoroalkyl perfluoroalkylcarboxylate, and a perfluoropolyether derivative.

(49) Moreover, an extreme pressure agent may be used in combination at a blending ratio of about 30:70 to 70:30 in a mass ratio in order to maintain a lubricating effect under severe conditions. The extreme pressure agent reacts with a surface of a metal with friction heat generated when the lubricant is partially in contact with the metal in a boundary lubrication region, and forms a coating film of a reaction product. As a result, friction and abrasion are prevented. As the extreme pressure agent, for example, any of a phosphorus-based extreme pressure agent, a sulfur-based extreme pressure agent, a halogen-based extreme pressure agent, an organic metal-based extreme pressure agent, or a complex extreme pressure agent can be used.

(50) Moreover, an anti-rust agent may be optionally used in combination. The anti-rust agent may be any anti-rust agent typically used for this kind of magnetic recording media. Examples of the anti-rust agent include phenols, naphthols, quinones, heterocyclic compounds containing a nitrogen atom, heterocyclic compounds containing an oxygen atom, and heterocyclic compounds containing a sulfur atom. Moreover, the anti-rust agent may be mixed with the lubricant. Alternatively, the anti-rust agent and the lubricant may be deposited as two or more layers by forming a magnetic layer on a non-magnetic support, and applying an anti-rust agent layer on the upper part of the magnetic layer, followed by applying a lubricant layer.

(51) As a solvent of the lubricant, for example, a single use or a combination of alcoholic solvents, such as isopropyl alcohol (IPA), and ethanol, can be used. For example, a mixture of a hydrocarbon-based solvent, such as normal-hexane, and a fluorine-based solvent can be used.

(52) (Magnetic Recording Medium)

(53) A magnetic recording medium of the present invention includes a non-magnetic support, a magnetic layer, and the lubricant of the present invention, and may further include other members according to the necessity.

(54) The magnetic layer is formed on the non-magnetic support.

(55) The lubricant is formed on the magnetic layer.

(56) The lubricant can be applied for so-called a thin film-metal-type magnetic recording medium, in which a magnetic layer formed on a non-magnetic support by a method, such as vapor deposition and sputtering. Moreover, the lubricant can be also applied for a magnetic recording medium having a structure, in which a base layer is disposed between a non-magnetic support and a magnetic layer. Examples of such a magnetic recording medium include a magnetic disk, and a magnetic tape.

(57) FIG. 1 is a cross-sectional view illustrating one example of a hard disk. The hard disk has a structure, in which a substrate 11, a base layer 12, a magnetic layer 13, a protective carbon layer 14, and a lubricant layer 15 are sequentially laminated.

(58) Moreover, FIG. 2 is a cross-sectional view illustrating one example of a magnetic tape. The magnetic tape has a structure, in which a back-coating layer 25, a substrate 21, a magnetic layer 22, a protective carbon layer 23, and a lubricant layer 24 are sequentially laminated.

(59) In the magnetic disk illustrated in FIG. 1, each of the substrate 11 and the base layer 12 corresponds to the non-magnetic support. In the magnetic tape illustrated in FIG. 2, the substrate 21 corresponds to the non-magnetic support. In the case where a rigid substrate, such as an Al alloy plate, and a glass plate, is used as the non-magnetic support, a surface of the substrate may be made hard by forming an oxidized film, such as anodizing or a NiP coating on the surface of the substrate.

(60) Each of the magnetic layers 13 and 22 is formed as a continuous film by a method, such as plating, sputtering, vacuum deposition, and plasma CVD. Examples of the magnetic layers 13 and 22 include: longitudinal magnetic recording metal magnetic films formed of metals (e.g., Fe, Co, and Ni), CoNi-based alloys, CoPt-based alloys, CoNiPt-based alloys, FeCo-based alloys, FeNi-based alloys, FeCoNi-based alloys, FeNiB-based alloys, FeCoB-based alloys, or FeCoNiB-based alloys; and perpendicular magnetic recording metal magnetic thin films, such as CoCr-based alloy thin films, and CoO-based thin films.

(61) In the case where a longitudinal magnetic recording metal magnetic thin film is formed, particularly, a non-magnetic material, such as Bi, Sb, Pb, Sn, Ga, In, Ge, Si, and Tl, is formed as a base layer 12 on a non-magnetic support in advance, and a metal magnetic material is deposited through vapor deposition or sputtering in a perpendicular direction to diffuse the non-magnetic material into the magnetic metal thin film, to thereby improve a coercive force as well as eliminating orientation to assure in-plane isotropy.

(62) Moreover, a hard protective layer 14 or 23, such as a carbon film, a diamond-formed carbon film, a chromium oxide film, and SiO.sub.2 film, may be formed on a surface of the magnetic layer 13 or 22.

(63) Examples of a method for applying the above-mentioned lubricant to such a metal thin film magnetic recording medium include a method for top-coating a surface of the magnetic layer 13 or 22, or a surface of the protective layer 14 or 23 with the lubricant, as illustrated in FIGS. 1 and 2. A coating amount of the lubricant is preferably from 0.1 mg/m.sup.2 to 100 mg/m.sup.2, and more preferably from 0.2 mg/m.sup.2 to 3 mg/m.sup.2.

(64) As illustrated in FIG. 2, moreover, a metal thin film magnetic tape may optionally have a back-coating layer 25, other than a metal magnetic thin film, which is the magnetic layer 22.

(65) The back-coating layer 25 is formed by adding a carbon-based powder for imparting conductivity, or an inorganic pigment for controlling a surface roughness to a resin binder, and applying the resin binder mixture. In the present embodiment, the above-described lubricant may be internally added to the back-coating layer 25, or applied to the back-coating layer 25 as top coating.

(66) Moreover, the above-described lubricant may be internally added to both the magnetic layer 22 and the back-coating layer 25, or applied to both the magnetic layer 22 and the back-coating layer 25 as top coating.

(67) As another embodiment, moreover, the lubricant can be applied for a so-called coating-type magnetic recording medium, in which a magnetic coating film is formed as a magnetic layer by applying a magnetic coating material onto a surface of a non-magnetic support. In the coating-type magnetic recording medium, the non-magnetic support, a magnetic powder constituting the magnetic coating film, and the resin binder for use can be selected from any of those known in the art.

(68) Examples of the non-magnetic support include: polymer substrates formed of polymer materials, such as polyesters, polyolefins, cellulose derivatives, vinyl-based resins, polyimides, polyamides, and polycarbonate; metal substrates formed of aluminium alloys, or titanium alloys; ceramic substrates formed of alumina glass; and glass substrates. Moreover, a shape of the non-magnetic support is not particularly limited and may be any form, such as a tape, a sheet, and a drum. Furthermore, the non-magnetic support may be subjected to a surface treatment to form fine irregularities in order to control surface properties of the non-magnetic support.

(69) Examples of the magnetic powder include: ferromagnetic iron oxide-based particles, such as -Fe.sub.2O.sub.3, cobalt-coated -Fe.sub.2O.sub.3; ferromagnetic chromium dioxide; ferromagnetic metal-based particles formed of a metal, such as Fe, Co, and Ni, or an alloy containing any of the above-listed metals; and hexagonal ferrite particles in the form of hexagonal plates.

(70) Examples of the resin binder include: polymers, such as vinyl chloride, vinyl acetate, vinyl alcohol, vinylidene chloride, acrylic acid ester, methacrylic acid ester, styrene, butadiene, and acrylonitrile; copolymers combining two or more selected from the above-listed polymers; polyurethane resins; polyester resins; and epoxy resins. In order to improve dispersibility of the magnetic powder, a hydrophilic polar group, such as a carboxylic acid group, a carboxyl group, and a phosphoric acid group, may be introduced into any of the above-listed binders.

(71) Other than the magnetic powder and the resin binder, additives, such as a dispersing agent, an abrasive, an antistatic agent, and an anti-rust agent, may be added to the magnetic coating film.

(72) As a method for retaining the above-described lubricant in the coating-type magnetic recording medium, there are a method where the lubricant is internally added to the magnetic layer constituting the magnetic coating film formed on the non-magnetic support, a method where the lubricant is applied on a surface of the magnetic layer as top coating, and a combination of the above-listed methods. In the case where the lubricant is internally added into the magnetic coating film, the lubricant is added in an amount of from 0.2 parts by mass to 20 parts by mass relative to 100 parts by mass of the resin binder.

(73) In the case where a surface of the magnetic layer is top-coated with the lubricant, moreover, a coating amount of the lubricant is preferably from 0.1 mg/m.sup.2 to 100 mg/m.sup.2, and more preferably from 0.2 mg/m.sup.2 to 3 mg/m.sup.2. As a deposition method in the case where the lubricant is applied as top coating, the ionic liquid is dissolved in a solvent, and the obtained solution may be applied or sprayed, or a magnetic recording medium may be dipped in the solution.

(74) Since the lubricant of the present invention is used, in the present embodiment, an excellent lubricating effect is exhibited to reduce a coefficient of friction, and high thermal stability can be achieved. Moreover, the lubricating effect is not impaired even under severe conditions, such as high temperatures, low temperatures, high humidity, and low humidity.

(75) Accordingly, the magnetic recording medium, to which the lubricant of the present embodiment is applied, exhibits excellent running performances, abrasion resistance, and durability because of a lubricating effect, and can further improve thermal stability.

EXAMPLES

(76) Specific examples of the present invention are explained below. In the examples, ionic liquids were synthesized, and lubricants including the ionic liquids were produced. Then, magnetic disks and magnetic tapes were produced using the lubricants and durability of each disk and durability of each tape were evaluated. Production of a magnetic disk, a durability test of the disk, production of a magnetic tape, and a durability test of the tape were performed in the following manner.

(77) Note that, the present invention is not limited to these examples.

(78) <Production of Magnetic Disk>

(79) A magnetic thin film was formed on a glass substrate to produce a magnetic disk as illustrated in FIG. 1, for example, according to International Patent Publication No. WO2005/068589. Specifically, a chemically reinforced glass disk, which was formed of aluminium silicate glass and had an outer diameter of 65 mm, an inner diameter of 20 mm, and a disk thickness of 0.635 mm, was prepared, and a surface of the glass disk was polished so that Rmax of the surface was to be 4.8 nm, and Ra of the surface was to be 0.43 nm. The glass substrate was subjected to ultrasonic cleaning for 5 minutes each in pure water and in isopropyl alcohol (IPA) having the purity of 99.9% or greater, and the washed glass substrate was left to stand in saturated IPA steam for 1.5 minutes, followed by drying. The resultant glass substrate was provided as a substrate 11.

(80) On the substrate 11, a NiAl alloy (Ni: 50 mol %, Al: 50 mol %) thin film in the thickness of 30 nm as a seed layer, a CrMo alloy (Cr: 80 mol %, Mo: 20 mol %) thin film in the thickness of 8 nm as a base layer 12, and a CoCrPtB alloy (Co: 62 mol %, Cr: 20 mol %, Pt: 12 mol %, B: 6 mol %) thin film in the thickness of 15 nm as a magnetic layer 13 were sequentially formed by DC magnetron sputtering.

(81) Subsequently, a 5 nm-thick protective carbon layer 14 formed of amorphous diamond-like carbon was formed by plasma CVD, and the resultant disk sample was subjected to ultrasonic cleaning for 10 minutes in isopropyl alcohol (IPA) having the purity of 99.9% or greater inside a cleaner to remove impurities on a surface of the disk, followed by drying. Thereafter, an IPA solution of an ionic liquid was applied on a surface of the disk by dip coating in the environment of 25 C. and 50% in relative humidity (RH), to form about 1 nm of a lubricant layer 15.

(82) <Disk Durability Test>

(83) A CSS durability test was performed by means of a commercially available strain-gauge-type disk friction-abrasion tester in the following manner. A hard disk was mounted on a rotatable spindle with tightening torque of 14.7 Ncm. Thereafter, a head slider was attached on the hard disk in a manner that a center of an air bearing surface at the inner circumference side of the head slider relative to the hard disk was 17.5 mm from a center of the hard disk. The head used for the measurement was an IBM3370-type inline head, a material of the slider was Al.sub.2O.sub.3TiC, and the head load was 63.7 mN. In the test, the maximum value of friction force was monitored per CSS (contact, start, and stop) in the environment of 100 in cleanliness, 25 C., and 60% RH. The number of times when a coefficient of friction was greater than 1.0 was determined as a result of the CSS durability test. When a result of the CSS durability test was greater than 50,000, the result was represented as >50,000. Moreover, a CSS durability test was similarly performed after performing a heating test for 3 minutes at a temperature of 300 C., in order to study heat resistance.

(84) <Production of Magnetic Tape>

(85) A magnetic tape having a cross-sectional structure as illustrated in FIG. 2 was produced. First, Co was deposited on a substrate 21 formed of a 5 m-thick MICTRON (aromatic polyamide) film available from TORAY INDUSTRIES, INC. by oblique deposition to form a magnetic layer 22 formed of a ferromagnetic metal thin film having a film thickness 100 nm. Next, a protective layer 23 formed of a 10 nm-thick diamond-like carbon was formed on a surface of the ferromagnetic metal thin film by plasma CVD, followed by cutting the resultant into a strip having a width of 6 mm. An ionic liquid dissolved in IPA was applied onto the magnetic layer 22 in a manner that a film thickness of the ionic liquid solution was about 1 nm. In this manner, a lubricant layer 24 is formed on the magnetic layer to thereby produce a sample tape.

(86) <Tape Durability Test>

(87) Each sample tape was subjected to a measurement of still durability in an environment having a temperature of 5 C. and in an environment having a temperature of 40 C. and 30% RH, and measurements of a coefficient of friction and shuttle durability in an environment having a temperature of 5 C. and in an environment having a temperature of 40 C. and 90% RH. The still durability was evaluated by a decay time of an output in a paused state decayed by 3 dB. The shuttle resistant was evaluated by the number of shuttles taken until an output was reduced by 3 dB when repeated shuttle run was performed for 2 minutes per time. Moreover, a durability test was similarly performed after performing a heating test for 10 minutes at a temperature of 100 C., in order to study heat resistance.

(88) <FTIR>

(89) The measurement of FTIR was performed by means of FT/IR-460 available from JASCO Corporation according to a transmission method using KBr plates or KBr pellets. The resolution of the measurement was 4 cm.sup.1.

(90) <TG/DTA>

(91) In the TG/DTA measurement, the measurement was performed by means of EXSTAR6000 available from Seiko Instruments Inc. at a temperature range of from 30 C. to 600 C. at a heating rate of 10 C./min with introducing air at a flow rate of 200 mL/min.

(92) <NMR>

(93) The .sup.1H-NMR spectrum was measured by means of Varian Mercury Plus 300 nuclear magnetic resonance spectrometer (available from Varian, Inc.). A chemical shift of .sup.1H-NMR was represented with ppm comparing with an internal standard (CDCl.sub.3 at 7.24 ppm). Splitting patterns were presented by denoting a singlet as s, a doublet as d, a triplet as t, a quartet as q, a multiplet as m, and a broad peak as br.

(94) The .sup.13C-NMR spectrum was measured by means of Varian Gemini-300 (125 MHz) nuclear magnetic resonance spectrometer (available from Varian, Inc.), and a chemical shift of .sup.13C-NMR was represented with ppm comparing with an internal standard (CDCl.sub.3 at 77.0 ppm).

Example 1

Synthesis of nonafluorobutanesulfonic acid-2-heptadecylimidazole salt

(95) Nonafluorobutanesulfonic acid-2-heptadecylimidazole salt was synthesized according to the following scheme.

(96) ##STR00013##

(97) The starting material, 2-heptadecylimidazole was purchased from SHIKOKU CHEMICALS CORPORATION and was used after recrystallization with ethanol. By increasing the purity from 93% to 98.5% through recrystallization, the resultant ionic liquid is improved in thermal stability. Thus, 2-heptadecylimidazole, which is used below as a synthesis material, was purified through recrystallization before use.

(98) 5.10 g of 2-heptadecylimidazole was dissolved in 100 mL of ethanol. To the resultant solution, 5.00 g of nonafluorobutanesulfonic acid was gradually added dropwise. After completion of the dropwise addition, the mixture was stirred for 30 minutes and then refluxed under heating for 1 hour. The solvent was removed. Then, the resultant was recrystallized from a solvent mixture of ethanol/n-hexane to obtain colorless nonafluorobutanesulfonic acid-2-heptadecylimidazole salt. The yield was 95%.

(99) The assignment of the FTIR spectrum of the product is depicted below.

(100) The symmetric stretching vibrations of SO.sub.2 were observed at 1,135 cm.sup.1, asymmetric stretching vibrations of SO.sub.2 bonds were observed at 1,356 cm.sup.1, symmetric stretching vibrations of CF were observed at 1,238 cm.sup.1, symmetric stretching vibrations of a CN bond were observed at 1,471 cm.sup.1, symmetric stretching vibrations of CH.sub.2 were observed at 2,850 cm.sup.1, asymmetric stretching vibrations of CH.sub.2 were observed at 2,918 cm.sup.1, and stretching vibrations of a NH bond were observed at 3,160 cm.sup.1.

(101) Moreover, peaks of the protons (.sup.1H)NMR and carbons (.sup.13C)NMR of the product in deuterated chloroform are presented below.

(102) ##STR00014##

(103) TABLE-US-00002 TABLE 2 Chemical shift/ppm CDCl.sub.3 11.150 2H, br s 7.130 2H, s 2.943 2H, t/10 Hz 1.710-1.809 2H, m 1.160-1.340 28H, m 0.847 3H, t/9 Hz

(104) ##STR00015##

(105) It could be confirmed from the above that nonafluorobutanesulfonic acid-2-heptadecylimidazole salt was synthesized.

(106) The TG/DTA measurement was performed. The TG/DTA measurement result is presented in FIG. 4. The main exothermic peak temperature due to the weight loss was extremely high, i.e., 471.6 C. Moreover, it was suggested that it was a decomposition reaction of the compound because the weight loss was exothermic. The exothermic temperature was improved by 60 C. or more compared to a perfluorooctanesulfonic acid octadecyl ammonium salt of Comparative Example 1. Also, 5% weight loss temperature, 10% weight loss temperature, and 20% weight loss temperature were improved by about 10 C. to about 40 C.

Example 2

Synthesis of nonafluorobutanesulfonic acid-1-octadecyl-2-heptadecylimidazole salt

(107) Nonafluorobutanesulfonic acid-1-octadecyl-2-heptadecylimidazole salt was synthesized according to the following scheme.

(108) ##STR00016##

(109) First, 1-octadecyl-2-heptadecylimidazole was synthesized.

(110) 9.18 g of 2-heptadecylimidazole purified in the same manner as in Example 1, 9.99 g of octadecyl bromide, and 1.68 g of potassium hydroxide were added to a mixture of 100 mL of acetonitrile and 100 mL of toluene, and the resultant mixture was refluxed under heating for 3 hours. The reaction solution was filtrated to remove the salt formed. The solvent was removed with an evaporator. Unreacted raw materials were separated through column chromatography using a solvent of n-hexane/ethyl acetate (=9/1), to thereby obtain 14.5 g of the target compound, 1-octadecyl-2-heptadecylimidazole with a gas chromatographic purity of 98% or higher.

(111) 4.45 g of the obtained 1-octadecyl-2-heptadecylimidazole was dissolved in ethanol. To the resultant solution, a solution prepared by dissolving 2.40 g of nonafluorobutanesulfonic acid in ethanol was gradually added dropwise. After completion of the dropwise addition, the mixture was stirred for 30 minutes and then refluxed under heating for 1 hour. The solvent was removed. Then, the resultant was recrystallized from a solvent mixture of ethanol/n-hexane to obtain 6.43 g of colorless nonafluorobutanesulfonic acid-1-octadecyl-2-heptadecylimidazole salt. The yield was 94%.

(112) The assignment of the FTIR spectrum of the product is depicted below.

(113) The symmetric stretching vibrations of SO.sub.2 were observed at 1,135 cm.sup.1, symmetric stretching vibrations of CF were observed at 1,279 cm.sup.1, asymmetric stretching vibrations of SO.sub.2 bonds were observed at 1,357 cm.sup.1, symmetric stretching vibrations of a CN bond were observed at 1,472 cm.sup.1, symmetric stretching vibrations of CH.sub.2 were observed at 2,851 cm.sup.1, asymmetric stretching vibrations of CH.sub.2 were observed at 2,918 cm.sup.1, and stretching vibrations of a NH bond were observed at 3,152 cm.sup.1.

(114) Moreover, peaks of the protons (.sup.1H)NMR and carbons (.sup.13C)NMR of the product in deuterated chloroform are presented below.

(115) ##STR00017##

(116) TABLE-US-00003 TABLE 3 Chemical shift/ppm CDCl.sub.3 13.285 1H, br s 7.255 1H, t/2 Hz 7.139 1H, t/2 Hz 4.003 2H, t/10 Hz 3.739 (unknown) 1H, m 2.908 2H, t/10 Hz 1.702-1.817 4H, m 1.171-1.307 58H, m 0.848 6H, t/9 Hz

(117) ##STR00018##

(118) It could be confirmed from the above that nonafluorobutanesulfonic acid-1-octadecyl-2-heptadecylimidazole salt was synthesized.

(119) The TG/DTA measurement was performed. The TG/DTA measurement result is presented in FIG. 5. The main exothermic peak temperature due to the weight loss was extremely high, i.e., 451.4 C. Moreover, it was suggested that it was a decomposition reaction of the compound because the weight loss was exothermic. The exothermic temperature was improved by about 65 C. compared to the perfluorooctanesulfonic acid octadecyl ammonium salt of Comparative Example 1. Also, 5% weight loss temperature, 10% weight loss temperature, and 20% weight loss temperature were improved by about 35 C. to about 55 C. Moreover, its thermal stability was much higher than those of Z-DOL and Z-Tetraol used in magnetic recording media.

Example 3

Synthesis of hexafluorocyclopropane-1,3-disulfonimide-2-heptadecylimidazole salt

(120) Hexafluorocyclopropane-1,3-disulfonimide-2-heptadecylimidazole salt was synthesized according to the following scheme.

(121) ##STR00019##

(122) 5.10 g of 2-heptadecylimidazole purified in the same manner as in Example 1 was dissolved in 100 mL of ethanol. To the resultant solution, a solution prepared by dissolving 4.84 g of hexafluorocyclopropane-1,3-disulfonimide in ethanol was gradually added dropwise. After completion of the dropwise addition, the mixture was stirred for 30 minutes and then refluxed under heating for 1 hour. The solvent was removed. Then, the resultant was recrystallized from a solvent mixture of ethanol/n-hexane to obtain colorless hexafluorocyclopropane-1,3-disulfonimide-2-heptadecylimidazole salt. The yield was 71%.

(123) The assignment of the FTIR spectrum of the product is depicted below.

(124) The symmetric stretching vibrations of SO.sub.2 were observed at 1,080 cm.sup.1, symmetric stretching vibrations of CF.sub.2 were observed at 1,171 cm.sup.1 and 1,225 cm.sup.1, asymmetric stretching vibrations of SO.sub.2 bonds were observed at 1,361 cm.sup.1, symmetric stretching vibrations of a CN bond were observed at 1,469 cm.sup.1, symmetric stretching vibrations of CH.sub.2 were observed at 2,851 cm.sup.1, asymmetric stretching vibrations of CH.sub.2 were observed at 2,919 cm.sup.1, symmetric stretching vibrations of CCH were observed at 3,028 cm.sup.1, and stretching vibrations of a NH bond were observed at 3,302 cm.sup.1 and 3,171 cm.sup.1.

(125) Moreover, peaks of the protons (.sup.1H)NMR and carbons (.sup.13C)NMR of the product in deuterated chloroform are presented below.

(126) ##STR00020##

(127) TABLE-US-00004 TABLE 4 Chemical shift(PMR)/ppm CD.sub.3OD 7.376 2H, s 4.960 2H, br s 2.948 2H, t/10 Hz 1.749-1.797 2H, m 1.220-1.349 28H, m 0.885 3H, t/10 Hz

(128) ##STR00021##

(129) It could be confirmed from the above that hexafluorocyclopropane-1,3-disulfonimide-2-heptadecylimidazole salt was synthesized.

(130) The TG/DTA measurement was performed. The TG/DTA measurement result is presented in FIG. 6. The main exothermic peak temperature due to the weight loss was extremely high, i.e., 475.8 C. Moreover, it was suggested that it was a decomposition reaction of the compound because the weight loss was exothermic. The exothermic temperature was improved by 85 C. or higher compared to the perfluorooctanesulfonic acid octadecyl ammonium salt of Comparative Example 1. Also, 5% weight loss temperature, 10% weight loss temperature, and 20% weight loss temperature were improved by about 25 C. to about 55 C.

Example 4

Synthesis of hexafluorocyclopropane-1,3-disulfonimide-1-octadecyl-2-heptadecylimidazole salt

(131) Hexafluorocyclopropane-1,3-disulfonimide-1-octadecyl-2-heptadecylimidazole salt was synthesized according to the following scheme.

(132) ##STR00022##

(133) 3.46 g of 1-octadecyl-2-heptadecylimidazole synthesized in Example 2 was dissolved in ethanol. To the resultant solution, a solution prepared by dissolving 1.82 g of hexafluorocyclopropane-1,3-disulfonimide in ethanol was gradually added dropwise. After completion of the dropwise addition, the mixture was stirred for 30 minutes and then refluxed under heating for 1 hour. The solvent was removed. Then, the resultant was recrystallized from a solvent mixture of ethanol/n-hexane to obtain 5.05 g of colorless hexafluorocyclopropane-1,3-disulfonimide-1-octadecyl-2-heptadecylimidazole salt. The yield was 96%.

(134) The assignment of the FTIR spectrum of the product is depicted below.

(135) The symmetric stretching vibrations of SO.sub.2 were observed at 1,086 cm.sup.1, symmetric stretching vibrations of CF.sub.2 were observed at 1,164 cm.sup.1, asymmetric stretching vibrations of SO.sub.2 bonds were observed at 1,364 cm.sup.1, symmetric stretching vibrations of a CN bond were observed at 1,469 cm.sup.1, symmetric stretching vibrations of CH.sub.2 were observed at 2,851 cm.sup.1, asymmetric stretching vibrations of CH.sub.2 were observed at 2,920 cm.sup.1, and stretching vibrations of a NH bond were observed at 3,162 cm.sup.1 and 3,289 cm.sup.1.

(136) Moreover, peaks of the protons (.sup.1H)NMR and carbons (.sup.13C)NMR of the product in deuterated chloroform are presented below.

(137) ##STR00023##

(138) TABLE-US-00005 TABLE 5 Chemical shift/ppm CDCl.sub.3 11.820 1H, br s 7.274 1H, t/2 Hz 7.126 1H, t/2 Hz 4.007 2H, t/10 Hz 2.913 2H, t/10 Hz 1.652-1.833 4H, m 1.182-1.323 58H, m 0.853 6H, t/9 Hz

(139) ##STR00024##

(140) It could be confirmed from the above that hexafluorocyclopropane-1,3-disulfonimide-1-octadecyl-2-heptadecylimidazole salt was synthesized.

(141) The TG/DTA measurement was performed. The TG/DTA measurement result is presented in FIG. 7. The main exothermic peak temperature due to the weight loss was extremely high, i.e., 465.6 C. Moreover, it was suggested that it was a decomposition reaction of the compound because the weight loss was exothermic. The exothermic temperature was improved by about 59 C. compared to the perfluorooctanesulfonic acid octadecyl ammonium salt of Comparative Example 1. Also, 10% weight loss temperature and 20% weight loss temperature were improved by about 20 C. to about 55 C. Moreover, its thermal stability was much higher than those of Z-DOL and Z-Tetraol used in magnetic recording media.

Example 5

Synthesis of tris(trifluoromethylsulfonyl)methide-2-heptadecylimidazole salt

(142) Tris(trifluoromethylsulfonyl)methide-2-heptadecylimidazole salt was synthesized according to the following scheme.

(143) ##STR00025##

(144) 18.8 g of 2-heptadecylimidazole purified in the same manner as in Example 1 was dissolved in 100 mL of ethanol. To the resultant solution, a solution prepared by diluting 6.33 g of 65% by mass concentrated sulfuric acid (d=1.40) with ethanol was added. The resultant mixture was confirmed to be neutralized with litmus paper. The solvent was removed. The resultant was recrystallized from a solvent mixture of n-hexane/ethanol to obtain 2-heptadecylimidazole nitrate.

(145) To the 2-heptadecylimidazole nitrate, a solution prepared by dissolving an equimolar of tris(trifluoromethylsulfonyl)methide potassium salt (7.15 g) in ethanol was gradually added. After completion of the dropwise addition, the mixture was stirred for 30 minutes and then refluxed under heating for 1 hour. The solvent was removed therefrom and then water was added thereto. The resultant mixture was extracted with diethyl ether. The organic layer was washed with water several times and then dried with magnesium sulfate anhydrate. The solvent was removed to obtain 10.2 g of colorless liquid tris(trifluoromethylsulfonyl)methide-2-heptadecylimidazole salt. The yield was 89%.

(146) The assignment of the FTIR spectrum of the product is depicted below.

(147) The symmetric stretching vibrations of SO.sub.2 were observed at 1,126 cm.sup.1, symmetric stretching vibrations of CF.sub.3 were observed at 1,200 cm.sup.1, asymmetric stretching vibrations of SO.sub.2 bonds were observed at 1,373 cm.sup.1, symmetric stretching vibrations of a CN bond were observed at 1,467 cm.sup.1, symmetric stretching vibrations of CH.sub.2 were observed at 2,855 cm.sup.1, asymmetric stretching vibrations of CH.sub.2 were observed at 2,925 cm.sup.1, and stretching vibrations of a NH bond were observed at 3,303 cm.sup.1.

(148) Moreover, peaks of the protons (.sup.1H)NMR and carbons (.sup.13C)NMR of the product in deuterated chloroform are presented below.

(149) ##STR00026##

(150) TABLE-US-00006 TABLE 6 Chemical shift(PMR)/ppm CDCl.sub.3 11.187 2H, br s 7.178 2H, s 2.938 2H, t/10 Hz 1.670-1.742 2H, m 1.180-1.320 28H, m 0.848 3H, t/10 Hz

(151) ##STR00027##

(152) It could be confirmed from the above that tris(trifluoromethylsulfonyl)methide-2-heptadecylimidazole salt was synthesized.

(153) The TG/DTA measurement was performed. The TG/DTA measurement result is presented in FIG. 8. The main exothermic peak temperature due to the weight loss was extremely high, i.e., 410.0 C. Moreover, it was suggested that it was a decomposition reaction of the compound because the weight loss was exothermic. The exothermic temperature was improved by about 25 C. compared to the perfluorooctanesulfonic acid octadecyl ammonium salt of Comparative Example 1. Also, 5% weight loss temperature, 10% weight loss temperature, and 20% weight loss temperature were improved by 40 C. or higher.

Comparative Example 1

Perfluorooctanesulfonic acid octadecyl ammonium salt

(154) Perfluorooctanesulfonic acid octadecyl ammonium salt (C.sub.8F.sub.17SO.sub.3.sup.H.sub.3N.sup.+C.sub.18H.sub.37) was synthesized with reference to non-patent literature (Novel ionic liquid lubricants for magnetic thin film media, Hirofumi Kondo et al., IEEE Trans. Magn., 2013, Vol. 49, issue 7, pp. 3756-3759).

Comparative Example 2

Synthesis of 2-heptadecylimidazole nitrate

(155) 2-Heptadecylimidazole nitrate was synthesized according to the following scheme.

(156) ##STR00028##

(157) 18.8 g of 2-heptadecylimidazole purified in the same manner as in Example 1 was dissolved in 100 mL of ethanol. To the resultant solution, a solution prepared by diluting 6.33 g of 65% by mass concentrated sulfuric acid (d=1.40) with ethanol was added. The resultant mixture was confirmed to be neutralized with litmus paper. The solvent was removed. The resultant was recrystallized from a solvent mixture of n-hexane/ethanol to obtain 2-heptadecylimidazole nitrate.

(158) The assignment of the FTIR spectrum of the product is depicted below.

(159) The symmetric stretching vibrations of NO were observed at 1,385 cm.sup.1, asymmetric bending vibrations of CH.sub.2 were observed at 1,458 cm.sup.1, symmetric stretching vibrations of a CN bond were observed at 1,473 cm.sup.1 and 1,620 cm.sup.1, symmetric stretching vibrations of CH.sub.2 were observed at 2,852 cm.sup.1, asymmetric stretching vibrations of CH.sub.2 were observed at 2,914 cm.sup.1, and stretching vibrations of a NH bond were observed at 3,174 cm.sup.1.

(160) Moreover, peaks of the protons (.sup.1H)NMR and carbons (.sup.13C)NMR of the product in deuterated chloroform are presented below.

(161) ##STR00029##

(162) TABLE-US-00007 TABLE 7 Chemical shift(PMR)/ppm CD.sub.3OD 7.410 2H, s 4.877 2H, br s 2.956 2H, t/8 Hz 1.776 2H, quintet 1.240-1.400 28H, m 0.890 3H, t/7 Hz

(163) ##STR00030##

(164) It could be confirmed from the above that 2-heptadecylimidazole nitrate was synthesized.

(165) The TG/DTA measurement was performed. The TG/DTA measurement result is presented in FIG. 9. The main exothermic peak temperature due to the weight loss was 304.2 C. Also, 5% weight loss temperature, 10% weight loss temperature, and 20% weight loss temperature were considerably low; i.e., 162.7 C., 191.3 C., and 256.2 C., respectively. Its thermal stability was not good compared with those of Z-DOL and Z-Tetraol used in magnetic recording media. In this manner, thermal resistance is not greatly improved by use of an inorganic acid such as nitric acid even though it is a strong acid as a Bronsted acid.

Comparative Example 3

Synthesis of 2-heptadecylimidazoletetrafluoroboric acid salt

(166) An aqueous solution of 2.06 g of potassium tetrafluoroborate was added to a solution prepared by dissolving 6.05 g of the 2-heptadecylimidazole nitrate synthesized in Comparative Example 2 in ethanol, followed by refluxing for 2 hours. After completion of the reaction, the reaction mixture was returned to normal temperature and ethanol was removed. Then, the resultant was cooled and the precipitates were separated through filtration, followed by recrystallization from a solvent mixture of n-hexane/ethanol, to obtain 5.70 g of colorless crystals. The yield was 88%.

(167) The assignment of the FTIR spectrum of the product is depicted below.

(168) The asymmetric bending vibrations of CH.sub.2 were observed at 1,422 cm.sup.1, symmetric stretching vibrations of a CN bond were observed at 1,469 cm.sup.1, symmetric stretching vibrations of CH.sub.2 were observed at 2,848 cm.sup.1, asymmetric stretching vibrations of CH.sub.2 were observed at 2,922 cm.sup.1, and stretching vibrations of a NH bond were observed at 3,109 cm.sup.1 and 3,157 cm.sup.1.

(169) Moreover, peaks of the protons (.sup.1H)NMR and carbons (.sup.13C)NMR of the product in deuterated chloroform are presented below.

(170) ##STR00031##

(171) TABLE-US-00008 TABLE 8 Chemical shift(PMR)/ppm CDCl.sub.3 13.96 2H, s 7.182 2H, t 1.8 Hz 4.330 1H, br s 3.019 2H, t 7.5 Hz 1.796 2H, quintet, 7.5 Hz 1.130-1.350 28H, m 0.840 3H, t 7.2 Hz

(172) ##STR00032##

(173) The TG/DTA measurement was performed. The TG/DTA measurement result is presented in FIG. 10. The main exothermic peak temperature due to the weight loss was 317.3 C. Also, 5% weight loss temperature, 10% weight loss temperature, and 20% weight loss temperature were considerably low; i.e., 162.6 C., 192.6 C., and 267.7 C., respectively. Its thermal stability was not good compared with those of Z-DOL and Z-Tetraol used in magnetic recording media. In this manner, thermal resistance is not greatly improved by use of an inorganic acid such as tetrafluoroboric acid even though it is a strong acid as a Bronsted acid.

(174) The synthesized ionic liquids are collectively presented in the following Table 9.

(175) The ionic liquids synthesized in Examples 1 to 5 are referred to as Ionic Liquids 1 to 5. The exothermic peak temperatures, endothermic peak temperatures, 5% weight loss temperatures, 10% weight loss temperatures, and 20% weight loss temperatures are also presented.

(176) Comparative Example 1 was a perfluorooctanesulfonic acid octadecyl ammonium salt (C.sub.8F.sub.17SO.sub.3.sup.H.sub.3N.sup.+C.sub.18H.sub.37).

(177) Comparative Example 4 was Fomblin Z-DOL.

(178) Comparative Example 5 was Z-Tetraol (ZTMD).

(179) TABLE-US-00009 TABLE 9 5% weight 10% weight 20% weight Endothermic peak Exothermic peak Names Compounds loss temp./ C. loss temp./ C. loss temp./ C. temperature/ C. temperature/ C. Ionic Nonafluorobutanesulfonic 365.35 390.5 414.28 60.6 386.0, Liquid 1 acid-2-heptadecylimidazole 401.3, (Ex. 1) salt 416.7, 471.6 Ionic Nonafluorobutanesulfonic 338.19 365.86 390.13 72.3 390.1, Liquid 2 acid-1-octadecyl- 411.7, (Ex. 2) 2-heptadecylimidazole 432.9, salt 451.4 Ionic Hexafluorocyclopropane- 353.36 384.94 413.45 109.0 426.1, Liquid 3 1,3-disulfonimide- 434.5, (Ex. 3) 2-heptadecylimidazole 475.8 salt Ionic Hexafluorocyclopropane- 303.7 366.4 404.99 79.7 295.58, Liquid 4 1,3-disulfonimide- 405.0, (Ex. 4) 1-octadecyl-2- 465.6 heptadecylimidazole salt Ionic Tris(trifluoromethyl- 370.3 388.69 403.42 410.0, Liquid 5 sulfonyl)methide- 442.94 (Ex. 5) 2-heptadecylimidazole salt Comp. Perfluorooctanesulfonic 328 343.4 358.4 87.6, 386.3, Ionic acid octadecyl 121.1, 404.1 Liquid 1 ammonium salt 194.4 (Comp. Ex. 1) Comp. 2-Heptadecylimidazole 162.66 191.25 256.16 94.2 162.05, Ionic nitrate 304.2, Liquid 2 407.93, (Comp. 493.6 Ex. 2) Comp. 2-Heptadecylimidazole- 162.6 192.6 267.7 94.4 163.3, Ionic tetrafluoroboric acid 317.3, Liquid 3 salt 375.4, (Comp. 503.0, Ex. 3) 551.6 Comp. Z-DOL 178 197 222 190-260 355.1 Lubricant (evaporated) 1 (Comp. Ex. 4) Comp. Z-Tetraol 243 261 282 260-300 371.0, Lubricant (evaporated) 344.6 12 (Comp. Ex. 5)

(180) Next, durability in magnetic discs was studied by using Ionic Liquids 1 to 5, Comparative Ionic Liquids 1 to 3, Z-DOL, and Z-Tetraol.

Example 6

(181) The above-described magnetic disk was produced using a lubricant including nonafluorobutanesulfonic acid-2-heptadecylimidazole salt, which is a protic ionic liquid in Example 1. As presented in Table 10, the CSS measurement of the magnetic disk was greater than 50,000 times, and the CSS measurement of the magnetic disk after the heating test was also greater than 50,000 times. Therefore, the magnetic disk exhibited excellent durability.

Example 7

(182) The above-described magnetic disk was produced using a lubricant including nonafluorobutanesulfonic acid-1-octadecyl-2-heptadecylimidazole salt, which is a protic ionic liquid in Example 2. As presented in Table 10, the CSS measurement of the magnetic disk was greater than 50,000 times, and the CSS measurement of the magnetic disk after the heating test was also greater than 50,000 times. Therefore, the magnetic disk exhibited excellent durability.

Example 8

(183) The above-described magnetic disk was produced using a lubricant including hexafluorocyclopropane-1,3-disulfonimide-2-heptadecylimidazole salt, which is a protic ionic liquid in Example 3. As presented in Table 10, the CSS measurement of the magnetic disk was greater than 50,000 times, and the CSS measurement of the magnetic disk after the heating test was also greater than 50,000 times. Therefore, the magnetic disk exhibited excellent durability.

Example 9

(184) The above-described magnetic disk was produced using a lubricant including hexafluorocyclopropane-1,3-disulfonimide-1-octadecyl-2-heptadecylimidazole salt, which is a protic ionic liquid in Example 4. As presented in Table 10, the CSS measurement of the magnetic disk was greater than 50,000 times, and the CSS measurement of the magnetic disk after the heating test was also greater than 50,000 times. Therefore, the magnetic disk exhibited excellent durability.

Example 10

(185) The above-described magnetic disk was produced using a lubricant including tris(trifluoromethylsulfonyl)methide-2-heptadecylimidazole salt, which is a protic ionic liquid in Example 5. As presented in Table 10, the CSS measurement of the magnetic disk was greater than 50,000 times, and the CSS measurement of the magnetic disk after the heating test was also greater than 50,000 times. Therefore, the magnetic disk exhibited excellent durability.

Comparative Example 6

(186) The above-described magnetic disk was produced using a lubricant including perfluorooctane sulfonic acid octadecyl ammonium salt (C.sub.8F.sub.17SO.sub.3.sup.H.sub.3N.sup.+C.sub.18H.sub.37) of [Comparative Example 1] presented in Table 9. As presented in Table 10, the durability of the magnetic disc measured by the CSS was greater than 50,000 times, and even after the heating test, was also greater than 50,000 times. There was no significant difference in properties of the disk compared to Examples.

Comparative Example 7

(187) The above-described magnetic disk was produced using a lubricant including 2-heptadecylimidazole nitrate of [Comparative Example 2] presented in Table 9. As presented in Table 10, the durability of the magnetic disc measured by the CSS was 33,000 times, and after the heating test, was 6,000 times. There was a significant difference in properties of the disk compared to Examples. Compared to Examples, the magnetic disk lacked thermal resistance, and therefore the durability was particularly deteriorated after the heating.

Comparative Example 8

(188) The above-described magnetic disk was produced using a lubricant including 2-heptadecylimidazoletetrafluoroboric acid salt of [Comparative Example 3] presented in Table 9. As presented in Table 10, the durability of the magnetic disc measured by the CSS was 31,000 times, and after the heating test, was 7,000 times. There was a significant difference in properties of the disk compared to Examples. Compared to Examples, the magnetic disk lacked thermal resistance, and therefore the durability was particularly deteriorated after the heating.

Comparative Example 9

(189) The above-described magnetic disk was produced using a lubricant including Z-DOL of [Comparative Example 4] presented in Table 9. As presented in Table 10, the durability of the magnetic disk measured by the CSS measurement was greater than 50,000 times, but after the heating test, the CSS durability started to deteriorate at 12,000 times. Compared to Examples, the magnetic disk lacked thermal resistance, and therefore it was considered that the durability was deteriorated after the heating.

Comparative Example 10

(190) The above-described magnetic disk was produced using a lubricant including Z-Tetraol of [Comparative Example 5] presented in Table 9. As presented in Table 10, the durability of the magnetic disk measured by the CSS measurement was greater than 50,000 times, but after the heating test, the CSS durability started to deteriorate at 36,000 times. Regarding the thermal resistance, the durability was improved compared with Z-DOL, but the magnetic disk lacked thermal resistance compared to Examples. It was therefore considered that the durability was deteriorated after the heating.

(191) TABLE-US-00010 TABLE 10 CSS durability after CSS durability heating Ex. 6 25 C., >50,000 25 C., >50,000 60% RH 60% RH Ex. 7 25 C., >50,000 25 C., >50,000 60% RH 60% RH Ex. 8 25 C., >50,000 25 C., >50,000 60% RH 60% RH Ex. 9 25 C., >50,000 25 C., >50,000 60% RH 60% RH Ex. 10 25 C., >50,000 25 C., >50,000 60% RH 60% RH Comp. 25 C., >50,000 25 C., >50,000 Ex. 6 60% RH 60% RH Comp. 25 C., 33,000 25 C., 6,000 Ex. 7 60% RH 60% RH Comp. 25 C., 31,000 25 C., 7,000 Ex. 8 60% RH 60% RH Comp. 25 C., >50,000 25 C., 12,000 Ex. 9 60% RH 60% RH Comp. 25 C., >50,000 25 C., 36,000 Ex. 10 60% RH 60% RH

(192) As is clear from the descriptions above, the lubricant of the present invention including the ionic liquid of the present invention could maintain excellent lubricity even under the high temperature storage conditions, and moreover could maintain the CSS lubricity over a long period.

(193) Next, examples where Ionic Liquids 1 to 5, Comparative Ionic Liquids 1 to 3, Z-DOL, and Z-Tetraol were applied for magnetic tapes are described.

Example 11

(194) The above-described magnetic tape was produced using a lubricant including Ionic Liquid 1. As presented in Table 11, a coefficient of friction of the magnetic tape after 100 times of the shuttle running was 0.18 in the environment having a temperature of 5 C., and 0.20 in the environment having a temperature of 40 C. and relative humidity of 90%. Moreover, the still durability test was greater than 60 min in the environment having a temperature of 5 C., and greater than 60 min in the environment having a temperature of 40 C. and relative humidity of 30%. Moreover, the shuttle durability test was greater than 200 times in the environment having a temperature of 5 C., and greater than 200 times in the environment having a temperature of 40 C. and relative humidity of 90%. Moreover, a coefficient of friction of the magnetic tape after 100 times of the shuttle running after the heating test was 0.19 in the environment having a temperature of 5 C., and 0.21 in the environment having a temperature of 40 C. and relative humidity of 90%. Also, the still durability test after the heating test was greater than 60 min in the environment having a temperature of 5 C., and greater than 60 min in the environment having a temperature of 40 C. and relative humidity of 30%. Moreover, the shuttle durability test after the heating test was greater than 200 times in the environment having a temperature of 5 C., and greater than 200 times in the environment having a temperature of 40 C. and relative humidity of 90%. It was found from the results above that the magnetic tape, to which Ionic Liquid 1 had been applied, had excellent abrasion properties, still durability, and shuttle durability.

Example 12

(195) The above-described magnetic tape was produced using a lubricant including Ionic Liquid 2. As presented in Table 11, a coefficient of friction of the magnetic tape after 100 times of the shuttle running was 0.20 in the environment having a temperature of 5 C., and 0.22 in the environment having a temperature of 40 C. and relative humidity of 90%. Moreover, the still durability test was greater than 60 min in the environment having a temperature of 5 C., and greater than 60 min in the environment having a temperature of 40 C. and relative humidity of 30%.

(196) Moreover, the shuttle durability test was greater than 200 times in the environment having a temperature of 5 C., and greater than 200 times in the environment having a temperature of 40 C. and relative humidity of 90%. Moreover, a coefficient of friction of the magnetic tape after 100 times of the shuttle running after the heating test was 0.21 in the environment having a temperature of 5 C., and 0.23 in the environment having a temperature of 40 C. and relative humidity of 90%. The still durability test after the heating test was greater than 60 min in the environment having a temperature of 5 C., and greater than 60 min in the environment having a temperature of 40 C. and relative humidity of 30%. Moreover, the shuttle durability test after the heating test was greater than 200 times in the environment having a temperature of 5 C., and greater than 200 times in the environment having a temperature of 40 C. and relative humidity of 90%. It was found from the results above that the magnetic tape, to which Ionic Liquid 2 had been applied, had excellent abrasion properties, still durability, and shuttle durability.

Example 13

(197) The above-described magnetic tape was produced using a lubricant including Ionic Liquid 3. As presented in Table 11, a coefficient of friction of the magnetic tape after 100 times of the shuttle running was 0.17 in the environment having a temperature of 5 C., and 0.19 in the environment having a temperature of 40 C. and relative humidity of 90%. Moreover, the still durability test was greater than 60 min in the environment having a temperature of 5 C., and greater than 60 min in the environment having a temperature of 40 C. and relative humidity of 30%. Moreover, the shuttle durability test was greater than 200 times in the environment having a temperature of 5 C., and greater than 200 times in the environment having a temperature of 40 C. and relative humidity of 90%. Moreover, a coefficient of friction of the magnetic tape after 100 times of the shuttle running after the heating test was 0.18 in the environment having a temperature of 5 C., and 0.19 in the environment having a temperature of 40 C. and relative humidity of 90%. Also, the still durability test after the heating test was greater than 60 min in the environment having a temperature of 5 C., and greater than 60 min in the environment having a temperature of 40 C. and relative humidity of 30%. Moreover, the shuttle durability test after the heating test was greater than 200 times in the environment having a temperature of 5 C., and greater than 200 times in the environment having a temperature of 40 C. and relative humidity of 90%. It was found from the results above that the magnetic tape, to which Ionic Liquid 3 had been applied, had excellent abrasion properties, still durability, and shuttle durability.

Example 14

(198) The above-described magnetic tape was produced using a lubricant including Ionic Liquid 4. As presented in Table 11, a coefficient of friction of the magnetic tape after 100 times of the shuttle running was 0.20 in the environment having a temperature of 5 C., and 0.22 in the environment having a temperature of 40 C. and relative humidity of 90%. Moreover, the still durability test was greater than 60 min in the environment having a temperature of 5 C., and greater than 60 min in the environment having a temperature of 40 C. and relative humidity of 30%. Moreover, the shuttle durability test was greater than 200 times in the environment having a temperature of 5 C., and greater than 200 times in the environment having a temperature of 40 C. and relative humidity of 90%. Moreover, a coefficient of friction of the magnetic tape after 100 times of the shuttle running after the heating test was 0.22 in the environment having a temperature of 5 C., and 0.23 in the environment having a temperature of 40 C. and relative humidity of 90%. Also, the still durability test after the heating test was greater than 60 min in the environment having a temperature of 5 C., and greater than 60 min in the environment having a temperature of 40 C. and relative humidity of 30%. Moreover, the shuttle durability test after the heating test was greater than 200 times in the environment having a temperature of 5 C., and greater than 200 times in the environment having a temperature of 40 C. and relative humidity of 90%. It was found from the results above that the magnetic tape, to which Ionic Liquid 4 had been applied, had excellent abrasion properties, still durability, and shuttle durability.

Example 15

(199) The above-described magnetic tape was produced using a lubricant including Ionic Liquid 5. As presented in Table 11, a coefficient of friction of the magnetic tape after 100 times of the shuttle running was 0.18 in the environment having a temperature of 5 C., and 0.19 in the environment having a temperature of 40 C. and relative humidity of 90%. Moreover, the still durability test was greater than 60 min in the environment having a temperature of 5 C., and greater than 60 min in the environment having a temperature of 40 C. and relative humidity of 30%. Moreover, the shuttle durability test was greater than 200 times in the environment having a temperature of 5 C., and greater than 200 times in the environment having a temperature of 40 C. and relative humidity of 90%. Moreover, a coefficient of friction of the magnetic tape after 100 times of the shuttle running after the heating test was 0.18 in the environment having a temperature of 5 C., and 0.20 in the environment having a temperature of 40 C. and relative humidity of 90%. Also, the still durability test after the heating test was greater than 60 min in the environment having a temperature of 5 C., and greater than 60 min in the environment having a temperature of 40 C. and relative humidity of 30%. Moreover, the shuttle durability test after the heating test was greater than 200 times in the environment having a temperature of 5 C., and greater than 200 times in the environment having a temperature of 40 C. and relative humidity of 90%. It was found from the results above that the magnetic tape, to which Ionic Liquid 5 had been applied, had excellent abrasion properties, still durability, and shuttle durability.

Comparative Example 11

(200) The above-described magnetic tape was produced using a lubricant including Comparative Ionic Liquid 1. As presented in Table 12, a coefficient of friction of the magnetic tape after 100 times of the shuttle running was 0.20 in the environment having a temperature of 5 C., and 0.23 in the environment having a temperature of 40 C. and relative humidity of 90%. Moreover, the still durability test was greater than 60 min in the environment having a temperature of 5 C., and greater than 60 min in the environment having a temperature of 40 C. and relative humidity of 30%. Moreover, the shuttle durability test was greater than 200 times in the environment having a temperature of 5 C., and greater than 200 times in the environment having a temperature of 40 C. and relative humidity of 90%. However, a coefficient of friction of the magnetic tape after 100 times of the shuttle running after the heating test was 0.23 in the environment having a temperature of 5 C., and increased to 0.26 in the environment having a temperature of 40 C. and relative humidity of 90%. The still durability test after the heating test was greater than 60 min in the environment having a temperature of 5 C., and greater than 60 min in the environment having a temperature of 40 C. and relative humidity of 30%. Moreover, the shuttle durability test after the heating test was greater than 200 times in the environment having a temperature of 5 C., and greater than 200 times in the environment having a temperature of 40 C. and relative humidity of 90%. It was found from the results above that the magnetic tape, to which Comparative Ionic Liquid 1 had been applied, had still durability and shuttle durability, but the coefficient of friction increased after the heating test.

Comparative Example 12

(201) The above-described magnetic tape was produced using a lubricant including Comparative Ionic Liquid 2. As presented in Table 12, a coefficient of friction of the magnetic tape after 100 times of the shuttle running was 0.27 in the environment having a temperature of 5 C., and 0.31 in the environment having a temperature of 40 C. and relative humidity of 90%. Moreover, the still durability test was 15 min in the environment having a temperature of 5 C., and 42 min in the environment having a temperature of 40 C. and relative humidity of 30%. Moreover, the shuttle durability test was greater than 200 times in the environment having a temperature of 5 C., and greater than 200 times in the environment having a temperature of 40 C. and relative humidity of 90%. Furthermore, a coefficient of friction of the magnetic tape after 100 times of the shuttle running after the heating test was 0.32 in the environment having a temperature of 5 C., and 0.40 in the environment having a temperature of 40 C. and relative humidity of 90%. The still durability test after the heating test was 10 min in the environment having a temperature of 5 C., and 15 min in the environment having a temperature of 40 C. and relative humidity of 30%. Moreover, the shuttle durability test after the heating test was 43 times in the environment having a temperature of 5 C., and 45 times in the environment having a temperature of 40 C. and relative humidity of 90%. From the results above, the magnetic tape, to which the compound of Comparative Ionic Liquid 2 had been applied, had poor still durability and had a significant deterioration in shuttle durability after the heating test, and the specifications of magnetic tapes were not satisfied.

Comparative Example 13

(202) The above-described magnetic tape was produced using a lubricant including Comparative Ionic Liquid 3. As presented in Table 12, a coefficient of friction of the magnetic tape after 100 times of the shuttle running was 0.26 in the environment having a temperature of 5 C., and 0.30 in the environment having a temperature of 40 C. and relative humidity of 90%. Moreover, the still durability test was 20 min in the environment having a temperature of 5 C., and 41 min in the environment having a temperature of 40 C. and relative humidity of 30%. Moreover, the shuttle durability test was greater than 200 times in the environment having a temperature of 5 C., and greater than 200 times in the environment having a temperature of 40 C. and relative humidity of 90%. Furthermore, a coefficient of friction of the magnetic tape after 100 times of the shuttle running after the heating test was 0.31 in the environment having a temperature of 5 C., and 0.40 in the environment having a temperature of 40 C. and relative humidity of 90%. The still durability test after the heating test was 13 min in the environment having a temperature of 5 C., and 19 min in the environment having a temperature of 40 C. and relative humidity of 30%. Moreover, the shuttle durability test after the heating test was 50 times in the environment having a temperature of 5 C., and 46 times in the environment having a temperature of 40 C. and relative humidity of 90%. From the results above, the magnetic tape, to which the compound of Comparative Ionic Liquid 3 had been applied, had poor still durability and had a significant deterioration in shuttle durability after the heating test, and the specifications of magnetic tapes were not satisfied.

Comparative Example 14

(203) The above-described magnetic tape was produced using Z-DOL. As presented in Table 12, a coefficient of friction of the magnetic tape after 100 times of the shuttle running was 0.25 in the environment having a temperature of 5 C., and 0.30 in the environment having a temperature of 40 C. and relative humidity of 90%. Moreover, the still durability test was 12 min in the environment having a temperature of 5 C., and 48 min in the environment having a temperature of 40 C. and relative humidity of 30%. Moreover, the shuttle durability test was 59 times in the environment having a temperature of 5 C., and 124 times in the environment having a temperature of 40 C. and relative humidity of 90%. Moreover, a coefficient of friction of the magnetic tape after 100 times of the shuttle running after the heating test was 0.32 in the environment having a temperature of 5 C., and 0.35 in the environment having a temperature of 40 C. and relative humidity of 90%. The still durability test after the heating test was 12 min in the environment having a temperature of 5 C., and 15 min in the environment having a temperature of 40 C. and relative humidity of 30%. Moreover, the shuttle durability test after the heating was 46 times in the environment having a temperature of 5 C., and 58 times in the environment having a temperature of 40 C. and relative humidity of 90%. From the results above, the magnetic tape, to which Z-DOL had been applied, had poor still durability and had a significant deterioration in shuttle durability after the heating test, and the specifications of magnetic tapes were not satisfied.

Comparative Example 15

(204) The above-described magnetic tape was produced using Z-Tetraol. As presented in Table 12, a coefficient of friction of the magnetic tape after 100 times of the shuttle running was 0.22 in the environment having a temperature of 5 C., and 0.26 in the environment having a temperature of 40 C. and relative humidity of 90%. Moreover, the still durability test was 25 min in the environment having a temperature of 5 C., and 35 min in the environment having a temperature of 40 C. and relative humidity of 30%. Moreover, the shuttle durability test was 65 times in the environment having a temperature of 5 C., and 156 times in the environment having a temperature of 40 C. and relative humidity of 90%. Moreover, a coefficient of friction of the magnetic tape after 100 times of the shuttle running after the heating test was 0.28 in the environment having a temperature of 5 C., and 0.32 in the environment having a temperature of 40 C. and relative humidity of 90%. The still durability test after the heating test was 23 min in the environment having a temperature of 5 C., and 31 min in the environment having a temperature of 40 C. and relative humidity of 30%. Moreover, the shuttle durability test after the heating was 55 times in the environment having a temperature of 5 C., and 126 times in the environment having a temperature of 40 C. and relative humidity of 90%. From the results above, the magnetic tape, to which Z-Tetraol had been applied, had poor still durability and had a significant deterioration in shuttle durability after the heating test, and the specifications of magnetic tapes were not satisfied.

(205) TABLE-US-00011 TABLE 11 Coefficient Still Coefficient Shuttle of friction Still Shuttle durability of friction durability after 100 durability/ durability/ after heating/ after 100 after heating/ running min times min running times Ex. 11 5 C. 0.18 5 C. >60 5 C. >200 5 C. 0.19 5 C. >60 5 C. >200 40 C., 0.20 40 C., >60 40 C., >200 40 C., 0.21 40 C., >60 40 C., >200 90% RH 30% RH 90% RH 90% RH 30% RH 90% RH Ex. 12 5 C. 0.20 5 C. >60 5 C. >200 5 C. 0.21 5 C. >60 5 C. >200 40 C., 0.22 40 C., >60 40 C., >200 40 C., 0.23 40 C., >60 40 C., >200 90% RH 30% RH 90% RH 90% RH 30% RH 90% RH Ex. 13 5 C. 0.17 5 C. >60 5 C. >200 5 C. 0.18 5 C. >60 5 C. >200 40 C., 0.19 40 C., >60 40 C., >200 40 C., 0.19 40 C., >60 40 C., >200 90% RH 30% RH 90% RH 90% RH 30% RH 90% RH Ex. 14 5 C. 0.20 5 C. >60 5 C. >200 5 C. 0.22 5 C. >60 5 C. >200 40 C., 0.22 40 C., >60 40 C., >200 40 C., 0.23 40 C., >60 40 C., >200 90% RH 30% RH 90% RH 90% RH 30% RH 90% RH Ex. 15 5 C. 0.18 5 C. >60 5 C. >200 5 C. 0.18 5 C. >60 5 C. >200 40 C., 0.19 40 C., >60 40 C., >200 40 C., 0.20 40 C., >60 40 C., >200 90% RH 30% RH 90% RH 90% RH 30% RH 90% RH

(206) TABLE-US-00012 TABLE 12 Coefficient Still Coefficient Shuttle of friction Still Shuttle durability of friction durability after 100 durability/ durability/ after heating/ after 100 after heating/ running min times min running times Comp. 5 C. 0.20 5 C. >60 5 C. >200 5 C. 0.23 5 C. >60 5 C. >200 Ex. 11 40 C., 0.23 40 C., >60 40 C., >200 40 C., 0.26 40 C., >60 40 C., >200 90% RH 30% RH 90% RH 90% RH 30% RH 90% RH Comp. 5 C. 0.27 5 C. 15 5 C. >200 5 C. 0.32 5 C. 10 5 C. 43 Ex. 12 40 C., 0.31 40 C., 42 40 C., >200 40 C., 0.40 40 C., 15 40 C., 45 90% RH 30% RH 90% RH 90% RH 30% RH 90% RH Comp. 5 C. 0.26 5 C. 20 5 C. >200 5 C. 0.31 5 C. 13 5 C. 50 Ex. 13 40 C., 0.30 40 C., 41 40 C., >200 40 C., 0.40 40 C., 19 40 C., 46 90% RH 30% RH 90% RH 90% RH 30% RH 90% RH Comp. 5 C. 0.25 5 C. 12 5 C. 59 5 C. 0.32 5 C. 12 5 C. 46 Ex. 14 40 C., 0.30 40 C., 48 40 C., 124 40 C., 0.35 40 C., 15 40 C., 58 90% RH 30% RH 90% RH 90% RH 30% RH 90% RH Comp. 5 C. 0.22 5 C. 25 5 C. 65 5 C. 0.28 5 C. 23 5 C. 55 Ex. 15 40 C., 0.26 40 C., 35 40 C., 156 40 C., 0.32 40 C., 31 40 C., 126 90% RH 30% RH 90% RH 90% RH 30% RH 90% RH

(207) It was also evident from the results above that the magnetic tape, to which the lubricant of the present invention including the ionic liquid of the present invention had been applied, exhibited excellent abrasion resistance, still durability, and shuttle durability. In case of Z-DOL or Z-Tetraol as Comparative Example, however, deterioration in the durability was significant similarly to the case of the above-described disk. In case of the lubricant including perfluorooctane sulfonic octadecyl ammonium salt, moreover, the magnetic tape had excellent durability, but the coefficient of friction slightly increased after the heating.

REFERENCE SIGNS LIST

(208) 1 laser light 2 near-field light 3 recording head (PMR element) 4 reproducing head (TMR element) 11 substrate 12 base layer 13 magnetic layer 14 protective carbon layer 15 lubricant layer 21 substrate 22 magnetic layer 23 protective carbon layer 24 lubricant layer 25 back-coating layer