System and method for injecting liquid odorant into a natural gas pipeline
10179882 ยท 2019-01-15
Assignee
Inventors
Cpc classification
B01F25/31425
PERFORMING OPERATIONS; TRANSPORTING
C10L2290/58
CHEMISTRY; METALLURGY
Y10T137/2501
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C10L2230/10
CHEMISTRY; METALLURGY
B01F23/21321
PERFORMING OPERATIONS; TRANSPORTING
B05B12/12
PERFORMING OPERATIONS; TRANSPORTING
Y10T137/2529
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B05B15/58
PERFORMING OPERATIONS; TRANSPORTING
F17C2265/027
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B05B1/3053
PERFORMING OPERATIONS; TRANSPORTING
B01F25/31424
PERFORMING OPERATIONS; TRANSPORTING
B05B12/04
PERFORMING OPERATIONS; TRANSPORTING
B05B7/0075
PERFORMING OPERATIONS; TRANSPORTING
International classification
C10L3/00
CHEMISTRY; METALLURGY
B05B12/04
PERFORMING OPERATIONS; TRANSPORTING
B05B7/00
PERFORMING OPERATIONS; TRANSPORTING
B05B12/12
PERFORMING OPERATIONS; TRANSPORTING
B05B1/30
PERFORMING OPERATIONS; TRANSPORTING
Abstract
The invention relates to a system and a method for injecting liquid odorant into a natural gas pipe, the system comprising: a tank containing the odorant in liquid form; a high-pressure pump connected to the tank; a common injection manifold fed with liquid odorant by the high-pressure pump; a plurality of odorant injectors fed with liquid odorant under pressure by the common injection manifold for the purpose of injecting the odorant into the gas pipe so as to cause it to be atomized in the gas pipe; and an electronic injection computer for controlling the injectors and the high-pressure pump.
Claims
1. A system for injecting liquid odorant into a natural gas pipe, the system comprising: a tank containing the odorant in liquid form; a high-pressure pump connected to the tank; a common injection manifold fed with liquid odorant by the high-pressure pump; a plurality of odorant injectors coupled directly to the gas pipe, wherein each of the odorant injectors is fed by the liquid odorant with a respective feed circuit under pressure by the common injection manifold, each of the feed circuits being connected to the common injection manifold such that each of the plurality of odorant injectors injects the odorant directly into the gas pipe and each of the plurality of odorant injectors causes the odorant to be atomized in the gas pipe; and an electronic injection computer that controls the injectors and the high-pressure pump and maintains a pressure difference between the odorant to be injected and the gas in the gas pipe such that an instantaneous atomization of the odorant is caused upon directly injecting the odorant into the gas pipe.
2. A system according to claim 1, further comprising a sensor for measuring the gas flow rate, connected to the electronic injection computer, and serving to measure the flow rate of gas flowing in the natural gas pipe upstream from the injectors.
3. A system according to claim 1, wherein the injectors are electrohydraulic injectors that are each controlled by a respective solenoid valve or are each controlled by a respective piezoelectric actuator.
4. A system according to claim 1, wherein the common injection manifold includes a pressure limiter device.
5. A system according to claim 1, further including a filter interposed between the tank and the high-pressure pump.
6. A system according to claim 1, wherein the injectors are fastened to a common sleeve for mounting in the gas pipe.
7. The system according to claim 1, wherein each of the odorant injectors extends within an internal diameter of the gas pipe.
8. The system according to claim 1, wherein the electronic injection computer controls the injectors and the high-pressure pump and maintains a speed difference between a flow of the gas in the gas pipe and an injection speed of the odorant to sustain the instantaneous atomization of the odorant upon being directly injected into the gas pipe.
9. The system according to claim 1, wherein each of the plurality of odorant injectors is configured to atomize the liquid odorant into the gas pipe by the odorant vaporizing on coming into contact with the natural gas flowing in the gas pipe.
10. The system according to claim 1, wherein each of the plurality of odorant injectors is configured to cause a continuous jet of liquid odorant to transform into a mist of odorant droplets having a diameter between 1 and 10 micrometers.
11. The system according to claim 1, wherein at least two or more of the plurality of odorant injectors are regularly spaced apart angularly from one another over a circumference of the gas pipe such that the odorant is injected uniformly into the gas pipe.
12. The system according to claim 1, wherein the liquid odorant is provided in liquid form at a pressure in the range 200 bars to 2000 bars, and the natural gas flows in the gas pipe at a pressure in the range of one bar to 100 bars.
13. The system according to claim 12, each of the odorant injectors includes an injection hole through which the liquid odorant is injected into the gas pipe, and a diameter of each of the injection holes is within a range of 0.1 mm to 0.2 mm.
14. The system according to claim 1, wherein each of the odorant injectors includes an injection hole through which the liquid odorant is injected into the gas pipe, and a diameter of each of the injection holes is within a range of 0.1 mm to 0.2 mm.
15. A method of injecting liquid odorant into a natural gas pipe, the method comprising: using a high-pressure pump to feed a common injection manifold with liquid odorant coming from a tank, said common injection manifold being connected to a plurality of odorant injectors coupled directly to a gas pipe; feeding each of the odorant injectors with the liquid odorant with a respective feed circuit under pressure by the common injection manifold, each of the feed circuits being connected to the common injection manifold; injecting the odorant, by each of the plurality of odorant injectors, directly into the gas pipe, wherein each of the plurality of odorant injectors causes the odorant to be atomized in the gas pipe; and controlling the injectors and the high-pressure pump using an electronic injection computer and maintaining a pressure difference between the odorant to be injected and the gas in the gas pipe such that an instantaneous atomization of the odorant is caused upon directly injecting the odorant into the gas pipe.
16. A method according to claim 15, wherein the common injection manifold is fed with liquid odorant at a pressure lying in the range 200 bars to 2000 bars, and the gas pipe is fed with natural gas at a pressure lying in the range of one bar to 100 bars.
17. A method according to claim 15, wherein the odorant is tetrahydrothiophene.
18. The method according to claim 15, wherein each of the odorant injectors extends within an internal diameter of the gas pipe.
19. The method according to claim 15, further comprising controlling the injectors and the high-pressure pump with the electronic injection computer and maintaining a speed difference between a flow of the gas in the gas pipe and an injection speed of the odorant such that the instantaneous atomization of the odorant is sustained upon directly injecting the odorant into the gas pipe.
20. The method according to claim 15, wherein each of the plurality of odorant injectors is configured to atomize the liquid odorant into the gas pipe by the odorant vaporizing on coming into contact with the natural gas flowing in the gas pipe.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) Other characteristics and advantages of the present invention appear from the following description made with reference to the accompanying drawings, which show an embodiment having no limiting character. In the figures:
(2)
(3)
(4)
(5)
DETAILED DESCRIPTION OF THE INVENTION
(6)
(7) The injection system 10 comprises in particular a tank 14 containing the odorant, which is present in liquid form. The liquid odorant is typically tetrahydrothiophene or thiophane (commonly designated by the acronym THT). Alternatively, it may be made up of tert-butyl mercaptan (designated by the acronym TBM) or of a mixture of these chemicals with each other or with other chemicals.
(8) The tank 14 is connected to a high-pressure pump 16 with a filter 18 being interposed between these elements. The high-pressure pump is dimensioned so as to be capable of delivering the maximum needed flow rate at a pressure lying in the range 200 bars to 2000 bars, approximately.
(9) The high-pressure pump 16 feeds a common injection manifold 20 continuously with liquid odorant under pressure. By way of example, this high-pressure pump 16 is a rotary pump known to the person skilled in the art.
(10) The common injection manifold 20 is a hydraulic accumulator that constitutes a reserve of liquid odorant under high pressure. This manifold distributes the liquid odorant to a plurality of injectors 100 (there being four in this example) in uniform manner, i.e. the manifold feeds each of the injectors at the same pressure and with the same quantity of liquid odorant.
(11) The injectors 100 serve to atomize the liquid odorant into the gas pipe 12 by the odorant vaporizing on coming into contact with the natural gas flowing in the gas pipe.
(12) More precisely, the injectors 100 serve to inject a jet of liquid odorant into the gas pipe 12 that becomes transformed into an atomized spray, i.e. into a cloud of odorant droplets (having a diameter of the order of a few micrometers) thereby enhancing mixing of the odorant in the flow of natural gas.
(13) More precisely, at the outlet from each injector, the jet of liquid odorant disintegrates immediately because of the very great difference in speed between the injected liquid and the natural gas flowing in the gas pipe (the odorant is said to be atomized).
(14) As shown in
(15) Furthermore, the injectors 100 may be regularly spaced apart angularly from one another over the entire circumference of the sleeve 22, so as to enable odorant to be injected as uniformly as possible.
(16) An electronic injection computer 24 is electrically connected to the injectors 100 and to the high-pressure pump 16 in order to control them (via electrical connections 26 in
(17) For this purpose, the injectors 100 are electrohydraulic injectors controlled by solenoid valves or controlled by piezoelectric actuators, thereby enabling the duration of injection and the exact quantity of odorant to be injected to be controlled electronically.
(18)
(19) In known manner, the injector 100 is made up of two portions, namely a bottom portion 102 that constitutes the injector proper (often referred to as the nozzle), and a top portion 104 that constitutes the electrical control device of the injector.
(20) Such an injector operates as follows. At rest, the injector is in a closed position as shown in
(21) When the injector begins to open, the solenoid valve 106 is powered under the control of electrical pulses from the electronic injection computer 24. Its magnetic core compresses the return spring 108, which raises the ball 110 off its seat and thus allows leakage to take place towards the return circuit 124 (
(22) When the injector is closed, the solenoid valve 106 ceases to be activated, so the return spring 108 pushes the magnetic core and drives the ball 110 against its seat in order to close the leaks. Pressure between the control chamber 112 and the pressure chamber 114 becomes balanced once again. The return spring 108 pushes the needle against its sealing bearing surface so as to shut the injection hole(s) 122.
(23) Thus, the injector 100 operates like a solenoid valve, opening and closing very quickly in order to inject into the gas pipe the exact quantity of odorant that is set by the electronic injection computer 24. In particular, the flow rate of odorant injected by each injector depends on the pressure in the common injection manifold 20, on the length of time the needle 120 of the injector is open, and on the diameter of the injection hole(s) 122.
(24) At the outlet from the injectors 100, the odorant in liquid form presents a pressure lying in the range 200 bars to 2000 bars, while the natural gas typically flows in the gas pipe 12 at a pressure lying in the range one bar to 100 bars. This large pressure difference, together with a small diameter for the injection hole(s) 122 of the injectors (typically in the range 0.1 millimeters (mm) to 0.2 mm), leads to a large difference in speed between the flow of natural gas in the gas pipe and the injection flow of odorant leaving the injectors. This speed difference leads to the odorant being atomized almost instantaneously on being injected into the gas pipe.
(25) It should be observed that the injectors may be controlled by a piezoelectric actuator instead of a solenoid valve. Such a piezoelectric actuator is typically made up of a plurality of layers of quartz having the property of deforming on receiving an electrical pulse coming from the electronic injection computer. This enables injectors to be controlled particularly fast.
(26) In order to ensure accurate control over the flow rate of odorant injected into the gas pipe 12, the electronic injection computer 24 receives information about the operation of the high-pressure pump 16 and of the common injection manifold 20 via electrical connections 28.
(27) Likewise, it is advantageous to make provision for a sensor 30 to measure the gas flow rate in the gas pipe 12 upstream from odorant injection. By way of example, the sensor 30 may be an orifice plate, well known to the person skilled in the art for measuring a gas flow rate.
(28) Such a sensor 30 is electrically connected via a connection 32 to the electronic injection computer 16 in order to inform it in real time about the flow rate of gas flowing in the gas pipe upstream from the injectors 100. The electronic injection computer can thus control accurately the quantities of odorant that are injected as a function of the gas flow rate in the gas pipe, and can adjust these quantities, in particular if the flow rate drops.
(29) In another advantageous provision, the common injection manifold 20 includes a pressure limiter device 34. The function of the pressure limiter device is to control the pressure in the common injection manifold and to return the excess flow of odorant to the tank 14 via a controlled leak (connected to the return circuit 124).
(30)
(31) In this variant embodiment, the injection system 10 has a main gas pipe 12 that is split into a plurality of secondary pipes 12a (there being three of them in this example). Each secondary gas pipe 12a has its own liquid odorant injection module 200 (each module has a high-pressure pump, a common injection manifold, and an electronic injection computer, not shown in
(32) Each injection module 200 is connected to the same liquid odorant tank (not shown in figure) and to a plurality of injectors 100 leading into the corresponding secondary gas pipe. Upstream from the injectors, a sensor 30 is provided in each secondary gas pipe 12a for measuring the gas flow rate (e.g. an orifice plate).
(33) Such a system makes it possible to enlarge the range over which odorization is effective by allowing natural gas to flow through and be odorized in a plurality of secondary gas pipes as a function of the flow rate of natural gas through the system. In addition, since the injection modules 200 are independent of one another, they can take over from one another, when necessary.