Diamond cutting elements for drill bits seeded with HCP crystalline material

Abstract

A polycrystalline diamond compact (PDC), which is attached or bonded to a substrate to form a cutter for a drill bit, is comprised of sintered polycrystalline diamond interspersed with a seed material which has a hexagonal close packed (HCP) crystalline structure. A region of the sintered polycrystalline diamond structure, near one or more of its working surfaces, which has been seeded with an HCP seed material prior to sintering, is leached to remove catalyst. Selectively seeding portions or regions of a sintered polycrystalline diamond structure permits differing leach rates to form leached regions with differing distances or depths and geometries.

Claims

1. A cutter for a drill bit comprising a substrate bonded to an integral mass of sintered polycrystalline diamond (PCD) exhibiting diamond-to-diamond bonding, wherein the integral mass of sintered polycrystalline diamond is at least partially interspersed with a hexagonal closed packed (HCP) material and a metal catalyst material used to sinter the integral mass, the HCP seed material having grain sizes greater than 1 micron, and wherein the HCP material and the metal catalyst material are different materials.

2. The cutter of claim 1, wherein a first portion of the integral mass has substantially lesser amount of the metal catalyst than a second portion of the integral mass.

3. The cutter of claim 1, wherein the HCP material is interspersed within at least one first discrete region within the integral mass of sintered PCD adjacent a working surface of the cutter, and wherein the integral mass of sintered PCD has at least one second region not containing the HCP material adjacent to the working surface.

4. The cutter of claim 3, wherein the metal catalyst material has been removed from at least part of the at least one discrete region with the integral mass of sintered PCD containing the HCP material to a first predetermined depth from the working surface, and wherein the metal catalyst material has been removed from at least part of the at least one second region to a second predetermined depth that is less than the first predetermined depth from the working surface.

5. The cutter of claim 1, wherein the HCP material possesses a wurtzite crystalline structure.

6. The cutter of claim 1, wherein the HCP material is chosen from the group consisting essentially of wurtzite boron nitride, wurtzite silicon carbide, and Lonsdaleite.

7. The cutter of claim 1, wherein the HCP material is comprised of wurtzite boron nitride.

8. The drill bit of claim 1, wherein the integral mass of PCD is sintered from diamond crystals grains with a size of 0 to 40 microns.

9. The drill bit of claim 1, wherein the sizes of the grains of the HCP material are less than 60 microns.

10. The drill bit of claim 1, wherein the sizes of the grains of the HCP material are less than 30 microns.

11. The drill bit of claim 1, wherein the sizes of the grains of HCP material are less than 10 microns.

12. The drill bit of claim 1, wherein the proportion of HCP material within the region containing the HCP material is 5% or less by volume.

13. The drill bit of claim 1, wherein the proportions of HCP material within the region containing the HCP material is 0.05% to 2% by volume.

14. The drill bit of claim 1, wherein the proportions of HCP material within the region containing the HCP material is 0.05% to 0.5% by volume.

15. The drill bit of claim 1 wherein integral mass of sintered polycrystalline diamond (PCD) comprises a first discrete region, in which the HCP material has been interspersed in a first concentration, and a second discrete region in which the mixture of the HCP material has been interspersed in a second concentration not equal to the first concentration, and wherein the first and the second discrete regions are adjacent to surfaces of the PCD.

16. The drill bit of claim 1, wherein the integral mass of sintered polycrystalline diamond (PCD) has a plurality of surfaces, at least one of which is a working surface; and wherein the compact has at least one discrete region that is adjacent the working surface that is interspersed with the HCP material, and at least one discrete region that does not contain the HCP material.

17. The drill bit of claim 1, wherein integral mass of sintered polycrystalline diamond (PCD) has a plurality of surfaces, at least one of which is a working surface and at least one of which is a bottom surface; and wherein the PCD is formed with at least a first layer of PCD having grains of a first average size adjacent the working surface, and a second layer nearer the bottom surface having grains of PCD with a larger average size than the first average size.

18. A drill bit comprising a body with a cutting face, the cutting face having disposed thereon a plurality of cutters, each of the plurality of cutters comprising a substrate bonded to an integral mass of sintered polycrystalline diamond (PCD) exhibiting diamond-to-diamond bonding, wherein the integral mass of sintered polycrystalline diamond is at least partially interspersed with a hexagonal closed packed (HCP) material and a metal catalyst material used to sinter the integral mass, the HCP material having grain sizes greater than 1 micron and wherein the HCP material and the metal catalyst material are different materials.

19. The drill bit of claim 18, wherein a first portion of the integral mass has substantially lesser amount of the metal catalyst than a second portion of the integral mass.

20. The drill bit of claim 18, wherein the HCP material is interspersed within at least one discrete region within the integral mass of sintered PCD adjacent a working surface of the cutter, and wherein the integral mass of sintered PCD has at least one region not containing the HCP material.

21. The drill bit of claim 20, wherein metal catalyst material has been removed from at least part of the at least one discrete region with the integral mass of sintered PCD containing the HCP material to a predetermined depth from the working surface.

22. The drill bit of claim 18, wherein the HCP material possesses a wurtzite crystalline structure.

23. The drill bit of claim 18, wherein the HCP material is chosen from the group consisting essentially of wurtzite boron nitride, wurtzite silicon carbide, and Lonsdaleite.

24. The drill bit of claim 18, wherein the HCP material is comprised of wurtzite boron nitride.

25. The drill bit of claim 18, wherein the integral mass of PCD is made up of diamond crystals between 0 and 40 microns.

26. The drill bit of claim 18, wherein the cutter is leached at least at specific, predetermined locations and pathways corresponding to where the HCP material is located.

27. The drill bit of claim 18, wherein the sizes of the grains of the HCP material are less than 60 microns.

28. The drill bit of claim 18, wherein the sizes of the grains of the HCP material are less than 0 to 30 microns.

29. The drill bit of claim 18, wherein the sizes of the grains of the HCP material are less than 10 microns.

30. The drill bit of claim 18, wherein the proportions of the HCP material within the region containing the HCP material is 5% or less by volume.

31. The drill bit of claim 18, wherein the proportions of the HCP material within the region containing the HCP material is 0.05% to 2% by volume.

32. The drill bit of claim 18, wherein the proportions of the HCP material within the region containing the HCP material is 0.05% to 0.5% by volume.

33. The drill bit of claim 18, wherein the integral mass of sintered polycrystalline diamond (PCD) has a plurality of surfaces, at least one of which is a working surface; and wherein the compact has at least one discrete region that is adjacent the working surface that is interspersed with HCP material, and at least one discrete region that does not contain HCP material.

34. The drill bit of claim 18, wherein integral mass of sintered polycrystalline diamond (PCD) has a plurality of surfaces, at least one of which is a working surface and at least one of which is a bottom surface; and wherein the PCD is formed at least a first layer of PCD having grains of a first average size adjacent the working surface, and a second layer nearer the bottom surface having grains of PCD with a larger average size than the first average size.

35. A drill bit comprising a body with a cutting face, the cutting face having disposed thereon a plurality of cutters, each of the plurality of cutters comprising a substrate bonded to an integral mass of sintered polycrystalline diamond (PCD) exhibiting diamond-to-diamond bonding, wherein the integral mass of sintered polycrystalline diamond is at least partially interspersed with a hexagonal closed packed (HCP) material and a metal catalyst material used to sinter the integral mass, wherein the integral mass of sintered polycrystalline diamond (PCD) comprises a first discrete region in which the HCP material has been interspersed in a first concentration, and a second discrete region in which the HCP material has been interspersed in a second concentration not equal to the first concentration, and wherein the first and the second discrete regions are adjacent to surfaces of the PCD, and wherein the HCP material and the metal catalyst material are different materials.

36. The drill bit of claim 35, wherein the metal catalyst material has been removed from at least part of the first discrete region to a first predetermined depth from the working surface, and wherein the metal catalyst material has been removed from at least part of the second discrete region to a second predetermined depth that is less than the first predetermined depth from the working surface.

37. The drill bit of claim 35, wherein the HCP material possesses a wurtzite crystalline structure.

38. The drill bit of claim 35, wherein the HCP material is chosen from the group consisting essentially of wurtzite boron nitride, wurtzite silicon carbide, and Lonsdaleite.

39. The drill bit of claim 35, wherein the HCP material is comprised of wurtzite boron nitride.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 is a perspective view of a PDC drag bit.

(2) FIGS. 2A, 2B and 2C are perspective, side and top views, respectively, of a representative PDC cutter suitable for the drag bit of FIG. 1.

(3) FIGS. 3A, 3B and 3C are cross-sections through four different examples of the PDC cutter of FIGS. 2A-2C, that has been seeded with HCP material in discrete regions within its diamond structure and then leached to partially or completely remove catalyst from at least the seeded region.

(4) FIG. 4 is a cross section of an embodiment of the PDC cutter of FIGS. 2A-2C with HCP seed material interspersed throughout the diamond layer.

DETAILED DESCRIPTION OF EXEMPLARY EMBODIMENTS

(5) In the following description, like numbers refer to like elements.

(6) FIG. 1 illustrates an example 100 of a PDC drag bit. However, it is intended to be a representative example of drag bits and, in general, drill bits for drilling oil and gas wells. It is designed to be rotated around its central axis 102. It is comprised of a bit body 104 connected to a shank 106 having a tapered threaded coupling 108 for connecting the bit to a drill string and a bit breaker surface 111 for cooperating with a wrench to tighten and loosen the coupling to the drill string. The exterior surface of the body intended to face generally in the direction of boring is referred to as the face of the bit. The face generally lies in a plane perpendicular to the central axis 102 of the bit. The body is not limited to any particular material. It can be, for example, made of steel or a matrix material such as powdered tungsten carbide cemented by metal binder.

(7) Disposed on the bit face are a plurality of raised blades, each designated 110, that rise from the face of the bit. Each blade extends generally in a radial direction, outwardly to the periphery of the cutting face. In this example, there are six blades substantially equally spaced around the central axis and each blade, in this embodiment, sweeps or curves backwardly in the direction of rotation indicated by arrow 115.

(8) On each blade is mounted a plurality of discrete cutting elements, or cutters, 112. Each discrete cutting element is disposed within a recess or pocket. In a drag bit the cutters are placed along the forward (in the direction of intended rotation) side of the blades, with their working surfaces facing generally in the forward direction for shearing the earth formation when the bit is rotated about its central axis. In this example, the cutters are arrayed along blades to form a structure cutting or gouging the formation and then pushing the resulting debris into the drilling fluid which exits the drill bit through the nozzles 117. The drilling fluid in turn transports the debris or cuttings uphole to the surface.

(9) In this example of a drag bit, all of the cutters 112 are PDC cutters. However, in other embodiments, not all of the cutters need to be PDC cutters. The PDC cutters in this example have a working surface made primarily of super hard, polycrystalline diamond, or the like, supported by a substrate that forms a mounting stud for placement in a pocket formed in the blade. Each of the PDC cutters is fabricated discretely and then mountedby brazing, press fitting, or otherwise into pockets formed on bit. However, the PDC layer and substrate are typically used in the cylindrical form in which they are made. This example of a drill bit includes gauge pads 114. In some applications, the gauge pads of drill bits such as bit 100 can include an insert of thermally stable, sintered polycrystalline diamond (TSP).

(10) FIGS. 2A-2C illustrate examples of a PDC cutter 200. It is comprised of a substrate 202, to which is attached a layer of sintered polycrystalline diamond (PCD) 204. This layer is sometimes also called a diamond table. Note that the cutter is not drawn to scale and intended to be representative of cutters generally that have a polycrystalline diamond structure attached to a substrate, and in particular the one or more of the PDC cutters 112 on the drill bit 100 of FIG. 1. Although frequently cylindrical in shape, PDC cutters in general are not limited to a particular shape, size or geometry, or to a single layer of PCD. In this example, an edge between top surface 206 and side surface 208 of the diamond layer 204 is beveled to form a beveled edge 210. The top surface and the beveled surface are, in this example, each a working surface for contacting and cutting through the formation. A portion of the side surface, particularly nearer the top, may also come into contact with the formation or debris. Not all of the cutters on a bit must be of the same size, configuration, or shape. In addition to being sintered with different sizes and shapes, PDC cutters can be cut, ground, or milled to change their shapes. Furthermore, the cutter could have multiple discrete PCD structures. Other examples of possible cutter shapes might pre-flatted gauge cutters, pointed or scribe cutters, chisel-shaped cutters, and dome inserts.

(11) Referring now also, in addition to FIGS. 2A to 2C, to FIGS. 3A to 3C and 4, the diamond structure comprising the diamond layer 204 has at least one, discrete region or area within it interspersed with grains of a crystalline seed material. An example of such crystalline seed is material having a hexagonal close pack (HCP) structure. Examples of such HCP crystalline seed material include materials with having a wurtzite crystal structure, including for example wurtzite boron nitride (BNw), wurtzite silicon carbide, and Lonsdaleite (hexagonal diamond).

(12) The diamond structure is formed by mixing small or fine grains of synthetic or natural diamond, referred to within the industry as diamond grit, with grains of HCP seed material (with or without additional materials) according to a predetermined proportion to obtain a desired concentration. A compact is then formed either entirely of the mixture or, alternately, the compact is formed with the mixture discrete regions or volumes within the compactcontaining the mixture and the remaining portion of the compact (or at least one other region of the compact) comprising PCD grains (with any additional material) but not the HCP seed material. The formed compact is then sintered under high pressure and high temperature in the presence of a catalyst, such as cobalt, a cobalt alloy, or any group VIII metal or alloy. The catalyst may be infiltrated into the compact by forming the compact on a substrate of tungsten carbide that is cemented with the catalyst, and then sintering. The result is a sintered PCD structure with at least one region containing HCP seed material dispersed throughout the region in the same proportion as the mixture.

(13) The HCP seed material may have a grain size of between 0 and 60 microns in one embodiment, between 0 and 30 microns, and between 0 and 10 microns in another embodiment. The grains of PCD in the mixture may be within the range of 0 to 40 microns, and may be as small as nano particle size. The proportion or concentration of HCP seed material within the mixture, and thus within the region seeded with the HCP seed material, is in one embodiment 5% or less by volume. In another embodiment it is in the range 0.05% to 2% by volume and in a further embodiment, in the range of 0.05% to 0.5% by volume.

(14) The PCD may be layered within the compact according to grain size. For example, a layer next to a working layer will be comprised of finer grains (i.e. grains smaller than a predetermined grain size) and a layer further away, perhaps a base layer next to the substrate, with grain larger than the predetermined size. The HCP seed material can be mixed with only the finer grain diamond grit mix to form a first region or layer next to a working surface, or with multiple layers of diamond grit mix.

(15) Alternately, mixtures having different concentrations or proportions of HCP seed material within the diamond layer may form a plurality of different regions or layers in the diamond structure, with or without having HCP seed material in the remaining structure of the PCD layer.

(16) In another, alternate example, the HCP material is replaced with a crystalline seed material (other than diamond) having a zinc blend crystalline structure, which is a type of face centered cubic (FCC) structure. Examples of such material include cubic boron nitride.

(17) It is believed that PCD seeded with an HCP crystalline seed material, particularly BNw, as described above results in a sintered polycrystalline diamond structure with faster leaching times. Furthermore, it is believed a PDC cutter with diamond layer that is formed according to the method described above with HCP seed material, and in particular with BNw as a seed material, performs better than the same PDC cutter with diamond structure formed without HCP seed material due to increased fracture toughness and abrasion resistance.

(18) In the different embodiments of PDC cutter 200 shown in FIGS. 3A to 3C, the regions or portion of the sintered PCD diamond layer or structure 204 in which an HCP seed material (the seeded regions) is interspersed is generally indicated by stippling, and the depth to which the diamond layer is partially leached is indicated by dashed line 300. In each of the examples the seeded region is adjacent the top surface 206 and the beveled peripheral edge surface 210, each of which is a working surface.

(19) In the embodiment of FIG. 3A, the region of seeding 302 extends across the entire top surface of diamond layer 204, and down a portion of its sides. It extends downwardly from the top surface 206 to a uniform depth 304 as measured from the top surface and is less than the thickness of the PCD layer. As indicated by the dashed line 300 the diamond layer is leached to the depth 304, the leaching removing a substantial percentage of the metal catalyst remaining in the diamond layer after sintering as compared to unleached regions.

(20) The seeded region 306 of the embodiment of FIG. 3B also extends, like the embodiment of FIG. 3A, across the full face of the diamond layer 204. The region extends a distance 308 down the side surface 208 that is approximately the same distance as the seeded region 302 is from the top surface of the embodiment of FIG. 3A, as shown by depth 304. However, unlike the embodiment of FIG. 3A, the seeded region extends a depth from the top surface that is approximately the distance 308, which is substantially less than the depth 304 of FIG. 3A. Because the rate of leaching is relatively faster in the seeded region 306 than the unseeded regions of the diamond layer, the leaching pattern, indicated by line 300, can be made substantially coincident with the seeded region's boundary.

(21) The embodiment of FIG. 3C has an annular shaped seeded region 310 that extends inwardly from the periphery of top surface 206, shown as 208 of FIG. 3C, by a distance 312 (which is less than the radius of the top surface) and to a depth 314 as measured from the top surface 206. This embodiment is leached to a depth indicated by a dashed line 300. Because the leaching rate is faster for the seeded region 310, leach depth 314 in the seeded region 310 is greater than the leach depth 316 in an unseeded region under the portion of top surface 206, shown as region 318.

(22) In the embodiment of FIG. 4 the entire diamond layer 204 is seeded with HCP crystalline material. For diamond mixes of 0-10 microns, particularly if the pressing pressures are very higher, the resultant PCD tends to be very dense. This increased density leads to considerable increases in leaching times. It is believed that this is due to the PCD microstructure having relatively little interstitial space, thus inhibiting the access of the leaching acid to the group VIII metal catalyst. For instance, if the PCD layer is comprised of diamond grit with grain sizes of 0-10 microns, pressed at elevated pressure, the practical limitation in leach depth will be of the order of 250 microns. This is due to the degradation of the sealing materials used to prevent the acid from contact the substrate. If nano particles are used in the diamond grit, this practical leaching depth will reduce further as the diamond density increases further, such that the benefits of leaching become negligible. The addition of the HCP seeding material makes it practical to leach fine grained diamond feed PCD, with grain sizes less than 20 microns, to depths well in excess of 500 microns, and in some embodiments in excess of 1200 microns.

(23) The foregoing description is of exemplary and preferred embodiments. The invention, as defined by the appended claims, is not limited to the described embodiments. Alterations and modifications to the disclosed embodiments may be made without departing from the invention. The meaning of the terms used in this specification are, unless expressly stated otherwise, intended to have ordinary and customary meaning and are not intended to be limited to the details of the illustrated or described structures or embodiments.