METHOD AND APPARATUS FOR TREATING COMMERCIAL AND INDUSTRIAL LAUNDRY WASTEWATER
20190001277 ยท 2019-01-03
Assignee
Inventors
Cpc classification
C02F1/006
CHEMISTRY; METALLURGY
B01D65/02
PERFORMING OPERATIONS; TRANSPORTING
C02F11/008
CHEMISTRY; METALLURGY
B01D2317/06
PERFORMING OPERATIONS; TRANSPORTING
B01D69/081
PERFORMING OPERATIONS; TRANSPORTING
C02F1/001
CHEMISTRY; METALLURGY
C02F2201/008
CHEMISTRY; METALLURGY
C02F2103/002
CHEMISTRY; METALLURGY
C02F2301/08
CHEMISTRY; METALLURGY
B01D63/04
PERFORMING OPERATIONS; TRANSPORTING
D06F31/005
TEXTILES; PAPER
International classification
B01D63/04
PERFORMING OPERATIONS; TRANSPORTING
B01D65/02
PERFORMING OPERATIONS; TRANSPORTING
B01D69/12
PERFORMING OPERATIONS; TRANSPORTING
C02F1/68
CHEMISTRY; METALLURGY
Abstract
The present invention relates generally to an effluent treatment device including in one embodiment a skid configuration. The method and apparatus of the present invention can use only two fluid pump units and including individual or multiple membrane modules in a stacked longitudinally arranged configuration. The stacked or in series modules can be either vertical or horizontal forming a column. The membrane modules are contained in large diameter pipes with enough space around each module so that filtered permeate water collects in the pipe and backwash water can flow in the pipe to backwash the modules and contained membranes. The present invention includes one or more hollow fiber ceramic membrane modules which each includes multiple hollow fibers bundled together by end or band caps (e.g., ceramic, epoxy of glass material end caps) to form a complete membrane module. A complete hollow fiber membrane module can comprise multiple symmetric individual hollow fibers between about 2.0 to 4.00 millimeters inside diameter and can be made of aluminium oxide (Al.sub.2O.sub.3) substrate material. The geometry of the individual ceramic fiber walls can be between about 1.0 to 2.0 millimeters in thickness, known as the membrane wall. Such ceramic hollow fibers can have pores including a range of nominal 1 nanometer to 1400 nanometers. The ceramic hollow fibers can comprise selective membranes pores including a range of nominal 1 nanometer to 1400 nanometers which may include individual or multiple separating layers attached to the fiber walls of nominal 1 to 100 nanometers. The separating layers can each be a porous polymeric material. In one embodiment, a skid mounted treatment device is operable to pass water through an individual hollow fiber ceramic membrane module or multiple membrane modules in series known as a membrane loop. Filtration is inside to out flow filtration through the hollow fiber membranes. The apparatus is also operable to pass water through the hollow fiber ceramic filter module or multiple membrane modules in an outside to in flow direction, so as to remove material from the separation layer of the hollow fiber ceramic membrane fibers, a process known as backwashing or back flushing. Contaminant materials (retentate) having been deposited during inside-out filtration of the commercial or industrial laundry effluent is removed with such back flushing.
Claims
1. A method of removing waste from a laundry wastewater stream, comprising the steps of: a) heating the wastewater stream to a temperature of at least 40? Celsius; b) transmitting the waste stream with piping to one or more modules, each module having multiple hollow ceramic fibers, each hollow ceramic fiber having a wall with an exterior and a bore; c) filtering the waste stream to remove waste material from the waste stream by flowing the waste stream from the bore laterally through the wall to the exterior of the wall; d) collecting a permeate fluid stream in step c of cleaned water that has passed through the walls of the hollow ceramic fibers; e) after a time interval, backwashing each hollow ceramic fiber by flowing a backwash fluid from the exterior of the wall, through the wall and into the bore of each hollow ceramic fiber; f) wherein in step e the backwash fluid is cleaner than the wastewater stream; g) wherein in step e, a fluid stream flows longitudinally through the bore of each hollow ceramic fiber and simultaneously with backwashing to generate a retentate stream; and h) transmitting the retentate stream to a collection vessel.
2. The method of claim 1 wherein in step a the temperature is between about 40-90 degrees Celsius.
3. The method of claim 1 wherein in step f the backwash fluid is permeate fluid that was collected in step d.
4. The method of claim 1 wherein in step f the backwash fluid includes clean water.
5. The method of claim 1 wherein the wall of each hollow ceramic fiber is between about 1 and 4 mm thick.
6. The method of claim 1 wherein in step b there are multiple of said one or more modules of hollow ceramic fibers in step b.
7. The method of claim 1 wherein in step b each hollow ceramic fiber has a separating layer with a pore size of between 1 and 1400 nanometers.
8. The method of claim 1 wherein in step b there are between about 200 and 1500 of said hollow ceramic fibers in each said module.
9. The method of claim 1 wherein the removed material in step c includes suspended and dissolved solids.
10. The method of claim 1 wherein the removed material in step c includes dye.
11. The method of claim 1 wherein the removed material in step c includes dissolved organics.
12. The method of claim 1 wherein the removed material in step c includes bacteria and viruses.
13. The method of claim 1 wherein the removed material in step c includes colloids.
14. The method of claim 6 wherein the multiple modules are stacked and aligned in series.
15. The method of claim 1 wherein the waste stream flows at a rate of between 10 and 500 gallons (38-1,893 liters) per minute.
16. The method of claim 1 wherein the permeate fluid stream is transmitted to a washing machine after step d at a temperature of at least 35 degrees Celsius.
17. The method of claim 1 wherein each hollow ceramic fiber in step b has an outside diameter of between about 4 and 6 mm.
18. The method of claim 1 wherein each hollow ceramic fiber in step b has a length of between about 300 and 1000 mm.
19. The method of claim 1 wherein in step b each hollow ceramic fiber includes a ceramic substrate with a pore size of between about 50 and 1400 nanometers.
20. The method of claim 1 wherein in step b each hollow ceramic fiber has a polymeric or metal oxide or graphene oxide coating on the tube wall.
21. The method of claim 1 wherein the filtration of step c has a duration of between about 5 and 120 minutes.
22. The method of claim 1 wherein the backwashing of step e has a duration of between about 10 and 60 seconds.
23. The method of claim 1 further comprising venting the piping and module or modules to reduce the risk of trapped air before the filtration of step c.
24. The method of claim 14 wherein there are multiple loops of stacks of modules.
25. The method of claim 1 wherein the filtration of step c includes transmitting the waste stream through the modules in a first flow direction and after the backwashing of step e transmitting the waste stream through the modules in a second flow direction that is opposite the first flow direction.
26. Laundry wastewater treatment apparatus comprising: a) a piping system having an inflow for receiving a wastewater stream to be treated; b) a heater for enabling heating of the wastewater stream to a temperature of at least 40? Celsius; c) the piping including one or more modules, each module having multiple hollow ceramic fibers, each hollow ceramic fiber having a wall with an exterior and a bore; d) one or more pumps that pump the wastewater stream to the module or modules and laterally through the wall to the exterior of the wall of each hollow ceramic fiber; e) the piping system including a permeate fluid stream of cleaned water that has passed through the walls of the hollow ceramic fibers; f) the piping system having valving that enables a backwashing each hollow ceramic fiber by flowing a backwash fluid with the pump or pumps from the exterior of the wall, through the wall and into the bore of each hollow ceramic fiber; g) wherein the backwash fluid is cleaner than the wastewater stream; h) wherein the pump or pumps transmit a fluid stream that flows longitudinally through the bore of each hollow ceramic fiber and simultaneously with backwashing to generate a retentate stream; and i) a retentate stream collection vessel that receives retentate from the modules.
27. The treatment apparatus of claim 26 wherein the temperature of the wastewater stream is between about 40-90 degrees Celsius.
28. The treatment apparatus of claim 26 wherein backwash fluid is from the permeate fluid that was collected in step d.
29. The treatment apparatus of claim 26 wherein the backwash fluid includes clean water.
30. The treatment apparatus of claim 26 wherein the wall of each hollow ceramic fiber is between about 2 and 4 mm thick.
31. The treatment apparatus of claim 26 wherein there are multiple of said one or more modules of hollow ceramic fibers.
32. The treatment apparatus of claim 26 wherein each hollow ceramic fiber has a porous polymeric separating layer with a pore size of between 1 and 1400 nanometers.
33. The treatment apparatus of claim 26 wherein there are between about 200 and 1500 of said hollow ceramic fibers in each said module.
34. The treatment apparatus of claim 26 wherein the retentate includes suspended and dissolved solids.
35. The treatment apparatus of claim 26 wherein the retentate includes dye.
36. The treatment apparatus of claim 26 wherein the retentate includes dissolved organics.
37. The treatment apparatus of claim 26 wherein the retentate includes bacteria and viruses.
38. The treatment apparatus of claim 26 wherein the retentate includes colloids.
39. The treatment apparatus of claim 31 wherein the multiple modules are stacked and aligned in series.
40. The treatment apparatus of claim 26 wherein the wastewater stream flows at a rate of between 10 and 500 gallons (38-1,893 liters) per minute.
41. The treatment apparatus of claim 26 further comprising a washing machine and wherein the permeate fluid stream flows to the washing machine with a flow line at a temperature of at least 35 degrees Celsius.
42. The treatment apparatus of claim 26 wherein each hollow ceramic fiber has an outside diameter of between about 4 and 6 mm.
43. The treatment apparatus of claim 26 wherein each hollow ceramic fiber has a length of between about 300 and 1000 mm.
44. The treatment apparatus of claim 26 wherein each hollow ceramic fiber includes a ceramic substrate with a pore size of between about 50 and 1400 nanometers.
45. The treatment apparatus of claim 26 wherein each hollow ceramic fiber has a porous polymeric coating on the hollow ceramic fiber wall.
46. The treatment apparatus of claim 26 wherein there are multiple loops of stacks of modules.
47. The treatment apparatus of claim 26 further comprising a skid or base and wherein all or part of the piping system is mounted on the skid or base.
48. The treatment apparatus of claim 26 further comprising a skid or base and wherein all or part of the pumps is mounted on the skid or base.
49. The treatment apparatus of claim 26 further comprising a skid or base and wherein all or part of the modules is mounted on the skid or base.
50. The treatment apparatus of claim 47 wherein the piping system includes permeate and retentate flow lines supported upon the skid or base.
51. (canceled)
Description
BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS
[0116] For a further understanding of the nature, objects, and advantages of the present invention, reference should be had to the following detailed description, read in conjunction with the following drawings, wherein like reference numerals denote like elements and wherein:
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DETAILED DESCRIPTION OF THE INVENTION
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[0139] Feed tank or vessel 14 receives flow from sump 15 and screen 13 via flow lines 16, 17. Feed tank 14 transmits the wastewater stream 12 to the various pump, valve and treatment module components that can be skid mounted on skid or base or frame 62 (see
[0140] The method of the present invention intermittently alternates fluid to a left hand side membrane loop conduit 39 then to the right hand side membrane loop conduit 40 via a 180 degree elbow 94. In between the left hand conduit filtration (see
[0141] In one embodiment, the method includes heating the wastewater stream or effluent held in a feed tank 14 by way of a valve 21 (e.g., actuated control valve) and heater or steam injector line 20. Feed tank 14 can have a level control and overflow line 19. Steam or heater 20 may be operable to heat the wastewater or effluent in tank 14 to about 40 degrees centigrade or more. The heater 20 may be operable to heat the effluent to about 50 degrees centigrade or more. The heater 20 may be operable to heat the effluent to within a temperature range of about 50 to 80 degrees centigrade. The heater 20 may be operable to heat the effluent to about 60 degrees centigrade or more.
[0142] Once effluent 12 is at a temperature of between about 50 and 80 degrees centigrade, the feed pump 22 is enabled to a set point of between about 1-10 bar. Pump 22 receives flow from feed tank 14 via line 23 with valve 24. Pump 22 pumps to line 26 which is an inlet conduit. From pump 22, flow goes to pump 25 (circulation pump) and through valve 35 or 36 to the filtration modules 44 or 45. There are two (left and right) conduits 39, 40 each with multiple modules 44 or 45. Each module 44 or 45 is preferably contained in a stainless steel conduit or pipe 39 or 40 that enables filtered water to be collected after filtration through each hollow fiber ceramic membrane 46. The stainless steel conduit or pipe 39, 40 also preferably contains fluid used for backwash in an out to in flow path (seen in
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[0144] Pump 22 supplies the wastewater 12 to circulation pump 25 via line 26 and valve 27. Tee fitting 32 connects line 26 and 33. Pump 25 discharges into line 31 and tee fitting 34 which provides selective transmission of fluid to either line 37 or 38 depending upon the open or closed state of valves 35, 36.
[0145] A circulation is enabled during filtration by transmitting the wastewater 12 in a first direction through lines 39, 40 and modules 44, 45 and back to circulation pump 25 via flow line 33.
[0146] Retentate line 41 enables transmission of retentate to feed tank 14 via valves 42, 43. Part of the retentate stream of line 41 can be discarded to drain or sewer 49 via drain line 47 and valve 48. Permeate flow lines 50, 51, 52 transmit cleaned fluid from modules 44, 45 to permeate tank 57. Line 52 has valve 88. Permeate lines 50, 51 connect to line 52 at tee fittings 54, 55. Permeate tank 57 can be used for backwashing (
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[0148] The filtration of
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[0150] Channels 79 of membranes 46 are open ended so that wastewater 12 enters channel 79 at a first end 81 then exits channel 79 at a second end 82. Membrane 46 can have a generally cylindrically shaped wall 84 surrounding channel 79. Wall 84 has inner surface 83 with a separating layer of porous polymeric material or porous ceramic material.
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[0154] The present invention can optionally use cleaning in place. Cleaning in place can include the external injection from clean in place dosing tank 28 and pump 29 and via line 30 into the commercial or industrial laundry effluent treatment device of an alkali or acidic solution into the feed tank 14, mixed with clean water being city or permeate water. Clean in place is operable to preserve, maintain or restore the clean fluid permeation flow through the ceramic hollow fiber wall 84, being either individual or multiple hollow fiber membranes 46, which preferably includes nominal 220 to 1500 individual ceramic hollow fibers 46 preferably made of a substrate such as an aluminium oxide (Al.sub.2O.sub.3) substrate material. Selective pore sizes of the aluminium oxide substrate material (Al.sub.2O.sub.3) can be about 50 to 1400 nanometers, also but not limited to selective pore sizes of the aluminium oxide substrate material (Al.sub.2O.sub.3) being nominal 50 to 1400 nanometers, including nominal 1 to 100 nanometers ceramic or porous polymeric coating or multiple separate porous ceramic or polymeric coatings, acting as a separation layer attached to the membrane fiber wall at 83. In one embodiment, each hollow ceramic fiber 46 can have a polymeric or metal oxide or graphene oxide coating on the tube wall 84. In one embodiment, each hollow ceramic fiber can have a polymeric or metal oxide or graphene oxide coating on the tube wall. The metal oxide can preferably be, for example, aluminium oxide, zirconia oxide or titanium oxide. In
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[0159] The treatment equipment 10 shown in the drawings should be completely vented of air before filtration of
[0160] The following is a list of parts and materials suitable for use in the present invention:
PARTS LIST
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TABLE-US-00002 PART NUMBER DESCRIPTION 10 wastewater treatment apparatus 11 commercial laundry 12 commercial/industrial laundry effluent/wastewater 13 pretreatment screen/filter/vibrating screen 14 feed tank/vessel 15 sump/effluent sump 16 flow line 17 flow line 18 pump 19 overflow line 20 steam/steam inlet/steam flow line/heater 21 valve 22 feed pump 23 flow line 24 valve 25 circulation pump 26 flow line 27 valve 28 clean in place dosing device 29 pump 30 flow line 31 flow line 32 tee fitting 33 flow line 34 tee fitting 35 valve 36 valve 37 flow line 38 flow line 39 left conduit/membrane loop conduit 40 right conduit/membrane loop conduit 41 retentate line 42 valve 43 valve 44 module of ceramic hollow fiber membranes (left) 45 module of ceramic hollow fiber membranes (right) 46 hollow fiber ceramic membrane 47 drain line 48 valve 49 sewer 50 permeate flow line 51 permeate flow line 52 permeate flow line 53 valve 54 tee fitting 55 tee fitting 56 valve 57 clean water tank/permeate tank 58 flow line 59 pH adjustment device 60 pump 61 flow line 62 skid mounted treatment unit 63 flow line 64 permeate pump 65 flow line 66 backwash flow line 67 valve 68 valve 69 tee fitting 70 flow line 71 valve 72 band/cap 73 band/cap 74 end portion/end 75 end portion/end 76 arrow 77 arrow 78 arrow 79 channel 80 outer surface 81 end 82 end 83 inner surface 84 wall 85 arrow 86 arrow 87 bundle of fibers 88 valve 89 arrow 90 arrow 91 arrow 92 arrow 93 vertical section 94 180 degree elbow 95 control panel 96 flow outlet 98 line 99 valve 100 valve 101 flow line
[0162] All measurements disclosed herein are at standard temperature and pressure, at sea level on Earth, unless indicated otherwise. All materials used or intended to be used in a human being are biocompatible, unless indicated otherwise.
[0163] The foregoing embodiments are presented by way of example only; the scope of the present invention is to be limited only by the following claims.