System and method for use in electron microscopy
10170272 ยท 2019-01-01
Assignee
Inventors
Cpc classification
H01J37/153
ELECTRICITY
H01J2237/2614
ELECTRICITY
International classification
Abstract
An electron beam shaping unit for use in electron beam column and a method for designing thereof is presented. The electron beam shaping unit is configured for affecting electron beams of high density or strong electron-electron repulsion. These 5 beams can always be modeled with multi electron wave function. The electron beam shaping unit comprises a mask unit configured for affecting propagation of electrons therethrough to thereby form a propagating electron beam having, at far field, radial shape as determined by multi-electron non-linear function being an eigen function determined by a multi-electron Hartree-Fock Hamiltonian.
Claims
1. An electron beam shaping unit for use in electron beam column, the electron beam shaping unit is configured for affecting multi electron wave function and comprising a mask unit configured for affecting propagation of electrons therethrough to thereby form at far field thereof a propagating electron beam having radial shape as determined by MENL function being an eigen function determined by a multi-electron Hartree-Fock Hamiltonian.
2. The electron beam shaping unit of claim 1, wherein the mask is configured as a binary mask having a plurality of spaced apart transmitting and blocking regions.
3. The electron beam shaping unit of claim 1, wherein the mask is configured as a phase and amplitude mask having a kinoform surface relief configuration.
4. The electron beam shaping unit of claim 1, wherein the mask is configured to direct the electron beam having MENL wavefunction to a zero or first diffraction order.
5. The electron beam shaping unit of claim 1, wherein the mask is configured to generate electron beam having MENL wavefunction having zero or integer value of orbital angular momentum.
6. The electron beam shaping unit of claim 1, wherein said MENL wavefunction corresponds to a solution of:
7. A method for use in design of an electron beam column, the method comprising: providing data about desired electron beam parameters; determining corresponding parameters for a multi-electron Hamiltonian; determining an eigen function of said multi-electron Hamiltonian corresponding to the desired electron beam parameters; determining a transmission function providing said eigen function and determining structure of a mask having said transmission function when transmitting plane wave electron beam therethrough.
8. The method of claim 7, wherein said multi-electron Hamiltonian being a Hrtree-Fock Hamiltonian.
9. The method of claim 7, wherein said desired electron beam parameters comprise data about electron beam energy and electron density within the beam.
10. The method of claim 7, wherein said desired electron beam parameters comprise data about acceleration voltage of the electrons and data about current on the electron beam column.
11. The method of claim 7, wherein said determining an eigen function comprises determining an MENL wave function having desired parameters in accordance with said electron beam parameters.
12. The method of claim 11, wherein said desired parameters comprise orbital angular momentum value and data about energy of the electron beam.
13. The method of claim 7, wherein said determining a transmission function comprises determining a Fourier transform of the desire wavefunction.
14. The method of claim 13, wherein said determining a transmission function further comprises providing data about hologram plane wave to thereby direct the electron beam to the desire direction.
15. The method of claim 7, wherein said determining structure of a mask comprises thresholding of said transmission function in accordance with a predetermined threshold value such that where the transmission function value exceeds the threshold said mask having full transmission and where the transmission function is below the threshold the mask is configured for blocking transmission.
16. An electron beam shaping unit for use in electron beam column, the beam shaping unit being characterized in the following: (a) said electron beam shaping unit being configured for affecting electron wave function passing; and (b) said electron beam shaping unit being configured to affect said electron wave function passing therethrough to form a substantially not diverging multi-electron wave function.
17. The electron beam shaping unit of claim 16, comprising at least one mask configured as a binary mask and having a plurality of spaced apart transmitting and blocking regions arranged in accordance with one or more MENL functions being an eigen function determined by a multi-electron Hartree-Fock Hamiltonian.
18. The electron beam shaping unit of claim 17, wherein the mask is configured as a phase and amplitude mask having a kinoform surface relief configuration.
19. The electron beam shaping unit of claim 17, wherein the mask is configured to direct the electron beam having MENL wavefunction to a zero or first diffraction order.
20. The electron beam shaping unit of claim 17, wherein the mask is configured to generate electron beam having MENL wavefunction having zero or integer value of orbital angular momentum.
21. The electron beam shaping unit of claim 17, wherein said MENL wavefunction corresponds to a solution of:
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) In order to better understand the subject matter that is disclosed herein and to exemplify how it may be carried out in practice, embodiments will now be described, by way of non-limiting example only, with reference to the accompanying drawings, in which:
(2)
(3)
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(5)
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(7)
(8)
(9)
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(12)
DETAILED DESCRIPTION OF EMBODIMENTS
(13) Reference is made to
(14) The resulting electron beam 500 emerges from the beam column 100 and is directed towards a sample located on a sample holder 20. Electron beam 500 according to the present invention is typically configured as a substantially non diverging beam while supporting greater currents corresponding to single electron beam. More specifically, the electron beam is formed of a main lobe having substantially non diverging shape (width) surrounded by plurality of side lobes as will be described further below. It should however be noted that according to some embodiments, the main lobe may or may not be associated with zero order of diffraction and may actually be associated with a lobe of first diffraction order. The selected lobe of the wave-function generated according to the present invention substantially maintains its structure for a certain propagation distance. Thus the probability that electrons will be detected within the lobe for longer propagation time and distance is increased as compared with the conventional techniques. This is while enabling higher currents corresponding to several electrons traveling within propagation path of the electron beam.
(15) While operation of the electron beam (e.g. as an electron microscope) the beam is typically focused onto the sample to provide desirably small spot size in nanometric regime and typically with spot size (associated with cross-section of the selected/main lobe) width between 0.1 and 40 nanometer, or generally between 0.1 and 5 nanometer or between 5 and 40 nanometer. Interaction of the electron beam with the sample may result in scattering or transmitted electrons, electromagnetic radiation and/or secondary electrons emitted from the sample. The output radiation 800 may be detected by a detection unit 30 configured for detecting transmitted electrons or other scattered radiation (electrons or electromagnetic radiation) in accordance with the design of the electron microscope.
(16) Thus, the electron beam mask design and the beam shaping resulting therefrom according to the present invention provide an electron beam having a substantially non-diverging cross section for current values corresponding to electron density of plurality of electron. This is contrary to the previously known beam shaping techniques providing Gaussian- or Bessel-shape electron beam, which provide low divergence for single electron but undergo divergence when applied to electron beam carrying more than a single electron at a time.
(17) To this end the beam shaping unit 1000 may include an appropriately made mask configured for affecting electron beam passing therethrough and shaping the electron beam in accordance with multi-electron wave-function (MENL). The mask may be configured as a phase-only mask, phase and amplitude mask, amplitude/intensity only mask as well as binary mask including spaced apart blocking and transmitting regions. For example, the mask may be configured of a metal plate having spaced apart transmitting region (holes in the plate) separated by blocking regions of the mask. Additionally or alternatively, the mask may be configured as kinoform mask carrying a patterned surface (surface relief) configured to apply the desired phase variation. Alternatively or additionally, the beam shaping unit 1000 may be configured with one or more electromagnetic field generators configured to provide the desired shaping as described further below.
(18) Reference is made to
(19) The nonlinear problem defined by the Hertree-Fock Hamiltonian is typically described, and numerical solutions thereof may be obtained numerically. The MENL wavefunction is a well-defined function having functional structure but no simple analytic representation. As described in more details further below, there are many MENL solutions corresponding to different energy levels and to orbital angular momentum of the electron beam. Based on the above determined parameters of beam current and voltage (electron density and energy), as well as orbital angular momentum, a MENL function is selected 5030. As described, the selected function is a solution of the nonlinear problem with selected angular momentum, energy and electron density 5032.
(20) In accordance with the selected MENL wavefunction, a transmission function is determined 5040. The transmission function is typically a Fourier transform of the selected MENL function, and may also include a varying phase determined to shift the desired wave function to the zero of first diffraction orders. Based on the determined transmission function, the mask structure can be designed 5050. The mask structure may be binary, phase mask and or phase and amplitude mask. Typically the mask is designed such that at far field, where evanescent waves are exponentially low, the resulting electron beam assumes the selected MENL wavefunction.
(21) To design the desired electron beam, or generally the cross section of a propagating wave-function, the inventors have developed a novel quantum-based technique for reducing limitations due to electron-electron interaction and allow the use of high density, high resolution e-beams. Shaping techniques of the quantum wave-function of electron beams, show great potential for improving the performance of traditional electron microscopes. However, thus far the existing techniques have been used only for low density e-beams (assuming a single electron), due to the space-charge effect. It should be noted that high intensity electron beams may be used in various additional fields other than microscopy. Such applications include electron accelerators, high-flux electron microscopy with short integration time, electron lithography, high intensity X-ray sources (e.g., FEL) and many more.
(22) Thus, the technique of the invention utilizes shaping of the electron beam wave-function so as to compensate for the repulsion between electrons. This enables the use of beams made up of multiple electrons without compromising on the spatial resolution. Additionally, such beam shaping of the electron beam reduces divergence of the electron beam thereby providing prolonged depth of focus of a dense e-beam.
(23) It should be noted that the use of multi-electron beam, or increased intensity (current) electron beam enables achieving higher signal to noise ratio (SNR) for a given integration time. Alternatively, the use of such increased intensity may be used to decrease the required integration time with respect to the conventional existing method and thereby enable inspection of fast occurring processes. This is while not reducing, and possibly increasing, the spatial resolution provided by the beam-spot of the multi-electron beam with respect to the existing single-electron beam.
(24) To this end, the technique of the present invention is based on the inventors' understanding of the following. It is known that the quantum state of the electron-beam is formally anti-symmetric to exchange between electrons (due to Pauli's Exclusion Principle). Even relativistic electrons (such as accelerated electrons in an electron beam for use in electron microscopy) can still be described with Schrdinger's Equation, with a modified mass. The electron beam wave-function can be described based on Hartree-Fock approximation in cylindrical coordinates as:
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As can be seen, the resulting approximation is a non-linear equation including interaction between electrons. Defining the effective potential
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where a.sub.0 is the Bohr radius
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and rearranging, leads to:
(30)
(31) Here, n is the density of electron per unit length in z, which depends linearly on the e-beam current. More specifically,
(32)
the electron density corresponds to the beam current and the accelerating potential, where the accelerating potential also corresponds to the eigen value of the wavefunction E providing
(33)
(34) The nonlinear set of equations is solved numerically based on predetermined initial conditions, to provide a set of functions providing suitable cross sectional structure of the non-diverging electron beam. In this connection the following should be noted. Being a result of a set of nonlinear differential equations, the family of resulting multi-electron radial functions does not have an analytical formulation. However, similar to other well-known functions, e.g. Bessel functions etc., the resulting eigen-function of equation 4 are well described function defined on the domain of real non-negative numbers and providing a measure for the amplitude of the multi-electron wavefunction at the corresponding radial distance from central axis of the beam. The function family .sub.E() provide that integral of .sub.E() is finite and corresponds to the number of electrons N propagating simultaneously within the beam. To enhance understanding, functions selected from the function family .sub.E() characterized as corresponding to eigen-function of equation 3 and 4 and specific wave function selected therefore are referred herein as multi-electron nonlinear (MENL) function.
2.sub.N,E()d1(equation 5)
Further in accordance with the formulation of equation 4 above, electronic wave function having such cross-section part of the function propagated while substantially not diverging and thus allowing the use of multi-electron focused electron beam.
(35) In this connection, reference is made to
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(38) Reference is made to
(39) Thus, the technique of the invention is based on the inventors' understanding that an electron beam having radial structure according to MENL function having suitable energy and orbital angular momentum provides a substantially non diverging beam for a predetermined propagation distance, which greatly exceeds that of the conventionally known Bessel shaped electron beam. To this end the technique of the invention generally includes selecting an appropriate MENL function having suitable electron density and angular momentum; determining a mask structure such that transmitting plane wave electron beam through the mask will result in an electron beam shaped according to the selected MENL function.
(40) According to some embodiments of the invention, the mask may be configured to direct electrons transmitted therethrough by diffraction into a plurality of diffraction orders. This may be used to provide higher ratio of the electron beam intensity within the desired beam shape and reducing noise factors. In a similar manner, the mask configuration according to the present invention may be designed to direct electron beam into several diffraction orders, where the desired MENL electron beam is directed to the zero or first order of diffraction. In this connection, reference is made to
(41) The mask structure is determined based on well-known wave propagation theory to provide transmission of electrons therethrough and direct the electrons to form the desired MENL beam structure at far field. In this connection the term far field should be understood as relating to a distance from the mask where evanescent waves are exponentially small and the detected data corresponds to the propagating waves. Thus according to some embodiments of the invention, the mask structure may be determined in accordance with a Fourier transform of the desired MENL function.
(42) The non-diffracting wavefunction (the solutions of Eqs. 4) can be generated by passing the electron beam (or generally plane wave beam of any charged particle) through a binary holographic mask, or through a phase mask configured to imprint the actual phase distribution of the shape-invariant wavefunction, which shapes the electron wavepacket directly. Generally, to design the holographic mask a transmission function of the mask is determine in accordance with the desired MENL function:
T.sub.holographic mask=|{()e.sup.il}+e.sup.ik.sup.
where ()e.sup.il is the radial and angular parts of the selected MENL function being a solution of equation 4 above; the symbol stands for Fourier transform; and e.sup.ik.sup.
(43)
The threshold may be selected in accordance with material properties of the mask and desired electron beam intensity (current). As described above, two such mask designs are exemplified in
(44) Additional mask configurations are exemplified in
(45)
(46) Typically a kinoform mask may be used to provide the desired phase variation. For example a thin plate of silicon nitride, having pseudo binary surface relief as shown may provide phase variation while keep the probability distribution (amplitude) constant along the cross section in the near field. The desired beam shape will be generated while propagating of the electron beam.
(47) Thus, the present invention provides a technique for designing a mask and beam shaping unit for use in an electron microscope or electron beam column. The mask is configured for generating an electron beam providing non-divergent high resolution multi-electron beam. The technique of the invention relies on the inventors' understanding that such a multi-electron beam needs to be tailored while taking into account the interaction between electrons. The beam shaping according to the present invention compensates for both space charge effects and diffraction, affecting the wave-function of the electron beam. The technique of the invention may be applied in various different applications in electron microscopy, lithography, accelerators and many more.