1. Patent Search
  2. Details

DYNAMIC RESPONSE COMPONENTS WITH AESTHETIC PROPERTIES

20180371310 · 2018-12-27

    Inventors

    Cpc classification

    International classification

    Abstract

    The composition comprises: (a) a compound of formula (I), (b) a polymeric matrix comprising a crosslinked polymer, the matrix having a viscosity value comprised from 110.sup.3 to 110.sup.12 Pa.Math.s, (c) a redox pair, and (d) a solvent, the compound of formula (I) and the redox pair being embedded in the polymeric matrix; and wherein: R.sub.1 and R.sub.2 are selected from: a (C.sub.1-C.sub.20)alkyl; (C.sub.1-C.sub.20)alkyl substituted; a 2 to 20-member heteroalkyl; a 2 to 20-member heteroalkyl substituted; (C.sub.2-C.sub.20)alkenyl; (C.sub.2-C.sub.20)alkenyl substituted; (C.sub.2-C.sub.20)alkynyl; (C.sub.2-C.sub.20)alkynyl substituted; and a known ring system; R.sub.3 to R.sub.10 are selected from hydrogen; (C.sub.1-C.sub.20)alkyl; (C.sub.1-C.sub.20)alkyl substituted; and nitro; and X is a monocharged anion.

    The present invention also relates to processes for its preparation and to devices comprising it.

    The multichromic composition shows a short switching time and low transmission in the most visible range, which makes it effective in blocking the whole visible radiation in smart windows.

    ##STR00001##

    Claims

    1. A multichromic composition comprising: (a) a compound of formula (I) ##STR00006## (b) a polymeric matrix comprising a crosslinked polymer, the matrix having a viscosity value comprised from 110.sup.3 to 110.sup.12 Pa.Math.s, (c) a redox pair, and (d) a solvent, the compound of formula (I) and the redox pair being embedded in the polymeric matrix; and wherein: one of R.sub.1 and R.sub.2 is a known ring system from 5 to 14 carbon atoms, the system comprising from 1 to 3 rings, where: each one of the rings is saturated, partially unsaturated, or aromatic; the rings are isolated, partially or totally fused, each one of the members forming the known ring system is selected from the group consisting of: CH, CH.sub.2, NH, N, SH, S, and O; and the ring system is optionally substituted by one or more radicals independently selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; and the other is a radical selected from the group consisting of a (C.sub.1-C.sub.20)alkyl; (C.sub.1-C.sub.20)alkyl substituted with one or more (C.sub.1-C.sub.5)alkyl, OH, halogen, phenyl, phenyl substituted with one or more (C.sub.1-C.sub.4)alkyl radicals, phenyl substituted with one or more halogen radicals, benzyl, benzyl substituted with one or more (C.sub.1-C.sub.4)alkyl radicals, or benzyl substituted with one or more halogen radicals; a 2 to 20-member heteroalkyl; a 2 to 20-member heteroalkyl substituted with one or more OH, halogen, phenyl, phenyl substituted with one or more (C.sub.1-C.sub.4)alkyl radicals, phenyl substituted with one or more halogen radicals, benzyl, benzyl substituted with one or more (C.sub.1-C.sub.4)alkyl radicals, or benzyl substituted with one or more halogen radicals; (C.sub.2-C.sub.20)alkenyl; (C.sub.2-C.sub.20)alkenyl substituted with one or more (C.sub.1-C.sub.5)alkyl, OH, halogen, phenyl, phenyl substituted with one or more (C.sub.1-C.sub.4)alkyl radicals, phenyl substituted with one or more halogen radicals, benzyl, benzyl substituted with one or more (C.sub.1-C.sub.4)alkyl radicals, or benzyl substituted with one or more halogen radicals; (C.sub.2-C.sub.20)alkynyl; (C.sub.2-C.sub.20)alkynyl substituted with one or two (C.sub.1-C.sub.5)alkyl, OH, halogen, phenyl, phenyl substituted with one or more (C.sub.1-C.sub.4)alkyl radicals, phenyl substituted with one or more halogen radicals, benzyl, benzyl substituted with one or more (C.sub.1-C.sub.4)alkyl radicals, or benzyl substituted with one or more halogen radicals; and a known ring system from 5 to 14 carbon atoms, the system comprising from 1 to 3 rings, where: each one of the rings is saturated, partially unsaturated, or aromatic; the rings are isolated, partially or totally fused, each one of the members forming the known ring system is selected from the group consisting of: CH, CH.sub.2, NH, N, SH, S, and O; and the ring system is optionally substituted by one or more radicals independently selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; R.sub.3 to R.sub.10 are radicals independently selected from the group consisting of hydrogen; (C.sub.1-C.sub.20)alkyl; (C.sub.1-C.sub.20)alkyl substituted by one or more radicals selected from the group consisting of: halogen, OH, and NO.sub.2; (C.sub.1-C.sub.20)alkoxy; cyano; and nitro; and X is a monocharged anion.

    2. The multichromic composition according to claim 1, wherein R.sub.1 and R.sub.2 are the same and mean a known ring system as defined in claim 1.

    3. The multichromic composition according to claim 2, wherein both R.sub.1 and R.sub.2 are the same and represent a known ring system comprising one aromatic ring optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen.

    4. The multichromic composition according to claim 3, wherein R.sub.1 and R.sub.2 are phenyl radicals optionally substituted with one or more radicals selected from the group consisting of: (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, nitro, cyano, and halogen.

    5. The multichromic composition according to claim 1, wherein R.sub.3 to R.sub.10 are hydrogen.

    6. The multichromic composition according to claim 1, wherein the compound of formula (I) corresponds to: ##STR00007##

    7. The multichromic composition according to claim 1, wherein the crosslinked-polymer is a crosslinked polyvinyl alcohol.

    8. The multichromic composition according to claim 7, wherein the crosslinked polymer is a borate crosslinked polyvinyl alcohol.

    9. The multichromic composition of claim 1 comprising: (a) the compound of formula (Ibis) at a concentration of 3.5 mM, (b) the borate crosslinked polyvinyl alcohol having a viscosity of about 300 Pa.Math.s, (c) a redox pair Fe(CN).sub.6].sup.3/[Fe(CN).sub.6].sup.4 at a concentration of 4 mM; and (d) the solvent is water.

    10. The multichromic composition according to claim 1, which comprises, in addition to the compound of formula (I), one or more further viologens.

    11. The multichromic composition according to claim 10, wherein the further viologen is a compound of formula (III): ##STR00008## wherein R.sub.11 and R.sub.12 are the same or different and are selected from the group consisting of a (C.sub.1-C.sub.20)alkyl; (C.sub.1-C.sub.20)alkyl substituted with one or more (C.sub.1-C.sub.5)alkyl, OH, halogen, phenyl, phenyl substituted with one or more (C.sub.1-C.sub.4)alkyl radicals, phenyl substituted with one or more halogen radicals, benzyl, benzyl substituted with one or more (C.sub.1-C.sub.4)alkyl radicals, or benzyl substituted with one or more halogen radicals; a 2 to 20-member heteroalkyl; a 2 to 20-member heteroalkyl substituted with one or more OH, halogen, phenyl, phenyl substituted with one or more (C.sub.1-C.sub.4)alkyl radicals, phenyl substituted with one or more halogen radicals, benzyl, benzyl substituted with one or more (C.sub.1-C.sub.4)alkyl radicals, or benzyl substituted with one or more halogen radicals; R.sub.13 to R.sub.20 are radicals independently selected from the group consisting of hydrogen; (C.sub.1-C.sub.20)alkyl; (C.sub.1-C.sub.20)alkyl substituted by one or more radicals selected from the group consisting of: halogen, OH, and NO.sub.2; (C.sub.1-C.sub.20)alkoxy; cyano; and nitro; and X is a monocharged anion.

    12. The multichromic composition according to claim 11, wherein the further viologen is a compound of formula (III) wherein R.sub.11 and R.sub.12 are the same.

    13. The multichromic composition according to claim 12, wherein the further viologen is a compound of formula (III) wherein R.sub.11 and R.sub.12 are (C.sub.1-C.sub.20)alkyl.

    14. The multichromic composition according to claim 11, wherein the further viologen is 1,1-diethyl-4,4-bipyridinium dibromide.

    15. A process for preparing a multichromic composition having a viscosity value comprised from 110.sup.3 to 110.sup.12 Pa.Math.s, according to claim 1, the process comprising the steps of: (a1) mixing an appropriate amount of a non-crosslinked polymer solution with an appropriate amount of a solution of a compound of formula (I) as defined above and an appropriate amount of a redox pair solution; and (b1) adding an appropriate amount of polymeric crosslinking agent solution to the resulting mixture of step (al) or, alternatively, (a2) mixing an appropriate amount of non-crosslinked polymer solution with an appropriate amount of crosslinking agent solution; (b2) adding an appropriate amount of compound of formula (I) with an appropriate amount of redox pair; and (c2) mixing the solutions resulting from steps (a2) and (b2) above; or alternatively, (a3) mixing an appropriate amount of non-crosslinked polymer with an appropriate amount of a compound of formula (I) and an appropriate amount of a redox pair, (b3) dissolving the resulting mixture in an appropriate solvent; and (c3) adding an appropriate amount of a polymeric crosslinking agent solution to the resulting solution of step (b3)

    16. The process of claim 15, which comprises a further step of adding one or more additional viologen solution(s).

    17. A device comprising the composition as defined in claim 1 and a substrate.

    18. The device of claim 17, which comprises one or more electrodes over the substrate, the one or more electrodes comprising over the sides, a layer of the composition.

    19. The multichromic composition according to claim 11, wherein the further viologen is a compound of formula (III) wherein R.sub.11 and R.sub.12 are (C.sub.1-C.sub.20)alkyl.

    Description

    BRIEF DESCRIPTION OF THE DRAWINGS

    [0040] FIG. 1 shows the schematic illustration of a three-electrode electrochromic device wherein (1) is the working electrode, (2) is a laser scribing, (3) is a pseudoreference electrode, (4) is the layer of the composition of the invention, (5) is the counter electrode, and (6) is the spacer.

    [0041] FIG. 2 shows the UV/Vis transmittance spectra of the two-electrode ECD containing composition described in example 5 (without borax for comparative purposes) in off state (dot) and upon applying 1.4 V voltage (solid line) and 1,8 V (dashed line).

    [0042] FIG. 3 shows the UV/Vis transmittance spectra of the two-electrode ECD containing Composition 4h9 in off state (1) and its two colored states upon applying 1.4 V voltage (2) and -1,8 V (3).

    [0043] FIG. 4A) Cyclic voltammogram of composition 4h9 (solid line) and aqueous system (dashed line) in three-electrode ECD configuration. B) UV/Vis transmittance spectra of the three-electrode ECD in bleached state (composition 4h9 (1) and aqueous system described in section 1.13 (2)), upon applying 0.5V (composition 4h9 (3) and aqueous system (4)) and upon applying 0.9 V voltages (composition 4h9 (5) and aqueous system (6)). Continuous lines represent the composition of the invention 4h9, whereas the dashed lines correspond to an aqueous system characterized by not comprising a crosslinked polymer.

    [0044] FIG. 5A) Cyclic voltammetry (CV) of Multi-color three- electrode ECD containing composition 5a and, in the inset, comparison of the multi-color three-electrode ECD containing composition 5a (solid line (1)) with CVs of compositions 4h9 (dash line (2)) and 3g9 (dot line (3)) separately. B) UV/Vis absorbance spectra of multi-color three- electrode ECD obtained for composition 5a after applying a switching voltages of 0 V (1), 0.7 V (2), 0.9 V (3), 1.1 V (4) and 1.7 V (5) respectively.

    [0045] FIG. 6 shows the schematic illustration of the Rainbow-like ECD containing composition 5a provided with zoning design and colors observed in each row of the device while the suitable voltage were being applied.

    [0046] FIG. 7 shows the UV/Vis transmittance spectra of the three-electrode ECD containing Composition 5b in off state (dashed line) and upon applying 1.9 V voltage (solid line).

    [0047] FIG. 8 shows the UV/Vis transmittance spectra of the two-electrode ECD containing composition described in example 6 (for comparative purposes) in off state (dot) and its two colored states upon applying 1.6 V voltage (solid line) and 2,0 V (dashed line).

    DETAILED DESCRIPTION OF THE INVENTION

    [0048] The present invention provides, in a first aspect, a multichromic composition comprising a compound of formula (I), a polymeric matrix, a redox pair, and a solvent, both the compound of formula (I) as well as the redox pair being embedded in the polymeric matrix.

    [0049] In the present invention the term embedded when referred to the compound of formula (I), means that the compound is not bound to the components forming the polymeric matrix (the polymer backbone and the crosslinking moiety), and that it is stabilized in the polymeric matrix.

    [0050] The term alkyl refers to a saturated straight or branched hydrocarbon chain which contains the number of carbon atoms specified in the description or claims. Examples include the group methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl, tert-butyl, n-pentyl, neo-pentyl and n-hexyl.

    [0051] The term (C.sub.2-C.sub.20)alkenyl refers to a saturated straight, or branched alkyl chain which contains from 2 to 20 carbon atoms and that also contains one or more double bonds.

    [0052] The term (C.sub.2-C.sub.20)alkynyl refers to a saturated straight, or branched alkyl chain which contains from 2 to 20 carbon atoms and that also contains one or more triple bonds. Examples include, among others, ethynyl, 1-propynyl, 2-butynyl, 1,3-butadinyl, 4-pentynyl, and 1-hexynyl.

    [0053] The term (C.sub.1-C.sub.6)haloalkyl refers to a group resulting from the replacement of one or more hydrogen atoms from a (C.sub.1-C.sub.6)alkyl group with one or more, preferably from 1 to 6, halogen atoms, which can be the same or different. Examples include, among others, trifluoromethyl, fluoromethyl, 1-chloroethyl, 2-chloroethyl, 1-fluoroethyl, 2-fluoroethyl, 2-bromoethyl, 2-iodoethyl, 2,2,2-trifluoroethyl, pentafluoroethyl, 3-fluoropropyl, 3-chloropropyl, 2,2,3,3-tetrafluoropropyl, 2,2,3,3,3-pentafluoropropyl, heptafluoropropyl, 4-fluorobutyl, and nonafluorobutyl.

    [0054] The term (C.sub.1-C.sub.6)alkoxy refers to an alkyloxy group, or a (C.sub.1-C.sub.6)alkyl-O-radical, having from 1 to 6 carbon atoms, the alkyl moiety having the same meaning as previously defined. Examples include, among others, methoxy, ethoxy, propoxy, isopropoxy, tert-butoxy, pentoxy and hexyloxy.

    [0055] The term known (C.sub.5-C.sub.14)aryl refers to a ring system with 1-3 rings, the ring system having from 5 to 14 carbon atoms and from 1 to 3 rings, where: [0056] each one of the rings is saturated, partially unsaturated, or aromatic; [0057] the rings are isolated, partially or totally fused,

    [0058] each one of the members forming the known ring system being selected from the group consisting of: CH, CH.sub.2, NH, N, SH, S, and O.

    [0059] The term (C.sub.5-C.sub.14)aryloxy refers to an aryl-O-radical, the aryl moiety having the same meaning as previously defined.

    [0060] The term known ring system as used herein refers to a ring system which is chemically feasible and is known in the art and so intends to exclude those ring systems that are not chemically possible.

    [0061] The term (C.sub.2-C.sub.20)heteroalkyl means a 2 to 20-member heteroalkyl represents a known non-polymeric C-heteroalkyl radical consisting of from 2 to 20 members where at least one of the members is O, S, or NH, and the remaining members are selected from CH, C(O), and CH.sub.2.

    [0062] According to the present invention when the ring system is formed by isolated rings means that the ring system is formed by two, three or four rings and said rings are bound via a bond from the atom of one ring to the atom of the other ring. The term isolated also embraces the embodiment in which the ring system has only one ring. Illustrative non-limitative examples of known ring systems consisting of one ring are those derived from: cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, cyclopropenyl, cyclobutenyl, cyclopentenyl, phenyl, and cycloheptenyl.

    [0063] According to the present invention when the ring system has rings totally fused, means that the ring system is formed by two, three or four rings in which two or more atoms are common to two adjoining rings. Illustrative non-limitative examples are 1,2,3,4-tetrahydronaphthyl, 1-naphthyl, 2-naphthyl, anthryl, or phenanthryl,

    [0064] According to the present invention when the ring system is partially fused it means that the ring system is formed by three or four rings, being at least two of said rings totally fused (i.e. two or more atoms being common to the two adjoining rings) and the remaining ring(s) being bound via a bond from the atom of one ring to the atom of one of the fused rings.

    [0065] In one embodiment of the first aspect of the invention, the composition is a multielectrochromic composition. In the present invention electrochromic means that the composition reversibly changes color by applying a particular potential to cause electrochemical redox reactions in the material. In the present invention the term multielectrochromic means that the composition shows more than one color change.

    [0066] In one embodiment of the first aspect of the invention, one of R.sub.1 and R.sub.2 is a known ring system as defined above. In another embodiment of the first aspect of the invention, one of one of R.sub.1 and R.sub.2 is a (C.sub.5-C.sub.4)aryl optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same or different and mean a known ring system as defined above. In another embodiment of the first aspect of the invention, at least one of R.sub.1 and R.sub.2 is a known ring system comprising one aromatic ring optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen. In another embodiment of the first aspect of the invention, both R.sub.1 and R.sub.2 are the same and represent a known ring system comprising one aromatic ring optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen. In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same and represent a known ring system consisting of a single aromatic ring optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen. In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are phenyl radicals optionally substituted with one or more radicals selected from the group consisting of: (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy nitro, cyano, and halogen. In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same and are selected from the group consisting of: phenyl, toluene, ethylbenzene, propylbenzene, cumene, isobutylbenzene, dodecylbenzene, styrene, alpha-methylstyrene, o-Xylene, m-Xylene, p-Xylene, and p-Cymene, the ring being optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen. In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same and are phenyl radicals substituted with one cyano radical.

    [0067] Alternatively, in one embodiment of the first aspect of the invention, one of R.sub.1 or R.sub.2 is a known ring system consisting of two totally fused aromatic rings, wherein each one of the aromatic rings is optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen. In another embodiment of the first aspect of the invention, both R.sub.1 and R.sub.2 are known ring systems consisting of two totally fused aromatic rings, wherein each one of the aromatic rings is optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen. In another embodiment of the first aspect of the invention, both R.sub.1 and R.sub.2 are the same and mean known ring systems consisting of two totally fused aromatic rings, wherein each one of the aromatic rings is optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen. In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same or different and are selected from 1,2,3,4-tetrahydronaphthyl, 1-naphthyl, 2-naphthyl, anthryl, and phenanthryl, said ring system being optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen.

    [0068] In another embodiment of the first aspect of the invention, wherein R.sub.3 to R.sub.10 are hydrogen.

    [0069] In another embodiment of the first aspect of the invention, the compound of formula (I) is one wherein R.sub.1 and R.sub.2 is a known ring system as defined above, and R.sub.3 to R.sub.10 are hydrogen. In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same or different and mean a known ring system as defined above, and R.sub.3 to R.sub.10 are hydrogen. In another embodiment of the first aspect of the invention, at least one of R.sub.1 and R.sub.2 is a known ring system comprising one aromatic ring optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; and R.sub.3 to R.sub.10 are hydrogen. In another embodiment of the first aspect of the invention, both R.sub.1 and R.sub.2 are the same and represent a known ring system comprising one aromatic ring optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; and R.sub.3 to R.sub.10 are hydrogen. In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same and represent a known ring system consisting of a single aromatic ring optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; and R.sub.3 to R.sub.10 are hydrogen. In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are phenyl radicals optionally substituted with one or more radicals selected from the group consisting of: (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; and R.sub.3 to R.sub.10 are hydrogen. In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same and are selected from the group consisting of: phenyl, toluene, ethylbenzene, propylbenzene, cumene, isobutylbenzene, dodecylbenzene, styrene, alpha-methylstyrene, o-Xylene, m-Xylene, p-Xylene, and p-Cymene, the ring being optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; and R.sub.3 to R.sub.10 are hydrogen. In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same and are phenyl radicals substituted with one cyano radical; and R.sub.3 to R.sub.10 are hydrogen.

    [0070] In another embodiment of the first aspect of the invention, the monocharged anion is selected from the group consisting of: Cl.sup., Br.sup., I.sup., NO.sub.3.sup., NO.sub.2.sup., PF.sub.6.sup., BF.sub.4.sup., ClO.sub.4.sup., CN.sup., SCN.sup., HSO.sub.4.sup., (FSO.sub.2).sub.2N.sup., (CF.sub.3SO.sub.2).sub.2N.sup., (C.sub.2F.sub.6SO.sub.2).sub.2N.sup.31 , (CF.sub.3SO.sub.2).sub.3C.sup., CF.sub.3SO.sub.3.sup., CF.sub.3COO.sup., AsF.sub.6.sup., CH.sub.3SO.sub.3.sup., CH.sub.3COO.sup., (CN).sub.2N.sup., (CN).sub.3C.sup., and aromatic sulfonate. In another embodiment of the first aspect of the invention, the monocharged anion is halogen. In another embodiment of the first aspect of the invention the monocharged anion is Cl.sup..

    [0071] In another embodiment of the first aspect of the invention, the compound of formula (I) is one wherein R.sub.1 and R.sub.2 is a known ring system as defined above, R.sub.3 to R.sub.10 are hydrogen; and X is halogen. In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same or different and mean a known ring system as defined above, R.sub.3 to R.sub.10 are hydrogen, and X is halogen. In another embodiment of the first aspect of the invention, at least one of R.sub.1 and R.sub.2 is a known ring system comprising one aromatic ring optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; R.sub.3 to R.sub.10 are hydrogen; and X is halogen. In another embodiment of the first aspect of the invention, both R.sub.1 and R.sub.2 are the same and represent a known ring system comprising one aromatic ring optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; R.sub.3 to R.sub.10 are hydrogen; and X is halogen. In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same and represent a known ring system consisting of a single aromatic ring optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; R.sub.3 to R.sub.10 are hydrogen; and X is halogen. In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are phenyl radicals optionally substituted with one or more radicals selected from the group consisting of: (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; R.sub.3 to R.sub.10 are hydrogen; and X is halogen. In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same and are selected from the group consisting of: phenyl, toluene, ethylbenzene, propylbenzene, cumene, isobutylbenzene, dodecylbenzene, styrene, alpha-methylstyrene, o-Xylene, m-Xylene, p-Xylene, and p-Cymene, the ring being optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; R.sub.3 to R.sub.10 are hydrogen; and X is halogen. In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same and are phenyl radicals substituted with one cyano radical; R.sub.3 to R.sub.10 are hydrogen; and X is halogen.

    [0072] In another embodiment of the first aspect of the invention, the compound of formula (I) corresponds to:

    ##STR00003##

    [0073] In another embodiment of the first aspect of the invention, the compound of formula (I) is at a concentration comprised from 0.15 to 30 mM. In another embodiment of the first aspect of the invention, the compound of formula (I) is at a concentration comprised from 0.25 to 25 mM. In another embodiment of the first aspect of the invention, the compound of formula (I) is at a concentration comprised from 0.25 to 10 mM. In another embodiment of the first aspect of the invention, the compound of formula (I) is at a concentration comprised from 0.25 a 4. In another embodiment of the first aspect of the invention, the compound of formula (I) is at a concentration of 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1.0, 2.0, 3.0, 4.0, 5.0, 6.0, 7.0, 8.0, 9.0, 10.0, 11.0, 12.0, 13.0, 14.0, 15.0, 16.0, 17.0, 18.0, 19.0, 20.0, 21.0, 22.0, 23.0, 24.0, 25.0, 26.0, 27.0, 28.0, 29.0, or 30.0 mM. In another embodiment of the first aspect of the invention, the compound of formula (I) is at a concentration of 3.5 mM.

    [0074] The term polymer refers to a macromolecule composed of many repeated subunits, known as monomers. Polymers, both natural and synthetic, are created via polymerization of many monomers. The polymer is composed of polymer chains, said chains being typically linear or branched.

    [0075] In the present invention the term crosslinked polymer is used in a wide sense, and refers to any type of covalent polymer network, dynamic or reversible covalent polymer networks or supramolecular polymer networks. Illustrative non-limitative examples of covalent bonds, useful in linking polymer chains, are: ether (C(O)), thioether (S(O)), ester (OC(O)), amide (C(O)NH), disulfide urethane (NC(S)S), thiourethane (NC(O)S), and borate (OBO) bonds. The crosslink between two polymeric chains can be performed by chemical reactions that are initiated by heat, pressure, change in pH, or radiation. For example, mixing of an unpolymerized or partially polymerized resin with specific chemicals called crosslinking reagents results in a chemical reaction that forms crosslinks. Crosslinkings are selected on the basis of their chemical reactivities (i.e., specificity for particular function groups) and other chemical properties that affect their behavior in different applications: [0076] (a) Chemical specificity refers to the reactive target(s) of the crosslinking's reactive ends. A general consideration is whether the reagent has the same or different reactive groups at either end; [0077] (b) Spacer arm length refers to the molecular span of a crosslinking (i.e., the distance between conjugated molecules). A related consideration is whether the arm is cleavable (i.e., whether the linkage can be reversed or broken when desired); and [0078] (c) Spontaneously reactive or photoreactive groups in a crosslinking affect whether it react as soon as it is added to a sample or can be activated at a specific time by exposure to UV light.

    [0079] In one embodiment, the crosslinking agent is a boron compound selected from the group consisting of: boric acid; boric anhydride; borate (C.sub.1-C.sub.4)alkyl ester; (C.sub.1-C.sub.4)alkyl; (C.sub.5-C.sub.6)aryl boronic acids and their (C.sub.1-C.sub.4)alkyl esters; and a metallic borate, the metal being selected from K, Na, Li, Ca and Mg. In another embodiment, the crosslinking is a metallic borate. In another embodiment, the crosslinking agent is borax (Na.sub.2B.sub.4O.sub.7.10H.sub.2O).

    [0080] In another embodiment of the first aspect of the invention, the crosslinked polymer is selected from the group consisting of a crosslinked polyvinyl alcohol, a crosslinked polyhydroxyalkylacrylate, a crosslinked polyhydroxyalkyl methacrylate, a crosslinked polysaccharide, and a crosslinked polyalkylenglycol, and a combination thereof. In another embodiment, the crosslinked polymer is a crosslinked polyvinyl alcohol.

    [0081] In another embodiment of the first aspect of the invention, the compound of formula (I) is one wherein R.sub.1 and R.sub.2 is a known ring system as defined above, R.sub.3 to R.sub.10 are hydrogen, and the polymeric matrix comprises a crosslinked polyvinyl alcohol. In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same or different and mean a known ring system as defined above, R.sub.3 to R.sub.10 are hydrogen, and the polymeric matrix comprises a crosslinked polyvinyl alcohol. In another embodiment of the first aspect of the invention, at least one of R.sub.1 and R.sub.2 is a known ring system comprising one aromatic ring optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.10)aryloxy, nitro, cyano, and halogen; R.sub.3 to R.sub.10 are hydrogen; and the polymeric matrix comprises a crosslinked polyvinyl alcohol. In another embodiment of the first aspect of the invention, both R.sub.1 and R.sub.2 are the same and represent a known ring system comprising one aromatic ring optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; R.sub.3 to R.sub.10 are hydrogen; and the polymeric matrix comprises a crosslinked polyvinyl alcohol. In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same and represent a known ring system consisting of a single aromatic ring optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; R.sub.3 to R.sub.10 are hydrogen; and the polymeric matrix comprises a crosslinked polyvinyl alcohol. In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are phenyl radicals optionally substituted with one or more radicals selected from the group consisting of: (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; R.sub.3 to R.sub.10 are hydrogen; and the polymeric matrix comprises a crosslinked polyvinyl alcohol. In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same and are selected from the group consisting of: phenyl, toluene, ethylbenzene, propylbenzene, cumene, isobutylbenzene, dodecylbenzene, styrene, alpha-methylstyrene, o-Xylene, m-Xylene, p-Xylene, and p-Cymene, the ring being optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; R.sub.3 to R.sub.10 are hydrogen; and the polymeric matrix comprises a crosslinked polyvinyl alcohol. In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same and are phenyl radicals substituted with one cyano radical; R.sub.3 to R.sub.10 are hydrogen; and the polymeric matrix comprises a crosslinked polyvinyl alcohol.

    [0082] In another embodiment of the first aspect of the invention, the compound of formula (I) is one wherein R.sub.1 and R.sub.2 is a known ring system as defined above, R.sub.3 to R.sub.10 are hydrogen; X is halogen; and the polymeric matrix comprises a crosslinked polyvinyl alcohol. In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same or different and mean a known ring system as defined above, R.sub.3 to R.sub.10 are hydrogen, X is halogen; and the polymeric matrix comprises a crosslinked polyvinyl alcohol. In another embodiment of the first aspect of the invention, at least one of R.sub.1 and R.sub.2 is a known ring system comprising one aromatic ring optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; R.sub.3 to R.sub.10 are hydrogen; X is halogen; and the polymeric matrix comprises a crosslinked polyvinyl alcohol. In another embodiment of the first aspect of the invention, both R.sub.1 and R.sub.2 are the same and represent a known ring system comprising one aromatic ring optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.10)aryloxy, nitro, cyano, and halogen; R.sub.3 to R.sub.10 are hydrogen; X is halogen; and the polymeric matrix comprises a crosslinked polyvinyl alcohol. In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same and represent a known ring system consisting of a single aromatic ring optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; R.sub.3 to R.sub.10 are hydrogen; X is halogen; and the polymeric matrix comprises a crosslinked polyvinyl alcohol. In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are phenyl radicals optionally substituted with one or more radicals selected from the group consisting of: (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, nitro, cyano, and halogen; R.sub.3 to R.sub.10 are hydrogen; X is halogen; and the polymeric matrix comprises a crosslinked polyvinyl alcohol. In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same and are selected from the group consisting of: phenyl, toluene, ethylbenzene, propylbenzene, cumene, isobutylbenzene, dodecylbenzene, styrene, alpha-methylstyrene, o-Xylene, m-Xylene, p-Xylene, and p-Cymene, the ring being optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; R.sub.3 to R.sub.10 are hydrogen; X is halogen; and the polymeric matrix comprises a crosslinked polyvinyl alcohol. In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same and are phenyl radicals substituted with one cyano radical; R.sub.3 to R.sub.10 are hydrogen; X is halogen; and the polymeric matrix comprises a crosslinked polyvinyl alcohol.

    [0083] In the present invention, the term polyvinyl alcohol is to be understood as composing mainly of 1,3-diol linkages [CH.sub.2CH(OH)CH.sub.2CH(OH)], although a low percent of 1,2-diols [CH.sub.2CH(OH)CH(OH)CH.sub.2] occur, depending on the conditions for the polymerization of the vinyl ester precursor.

    [0084] In another embodiment of the first aspect of the invention, the crosslinked polymer is a borate crosslinked polyvinyl alcohol. The borate crosslinked polyvinyl alcohol has been previously characterized by McLaughlin M. et al., (The Gelation of Poly(Vinyl Alcohol) with Na.sub.2B.sub.4O.sub.7.10H.sub.2O: Killing Slime, 1997, J. Chem. Educ. 47, 97-99)and has the structure (II):

    ##STR00004##

    [0085] In another embodiment of the first aspect of the invention, the compound of formula (I) is one wherein R.sub.1 and R.sub.2 is a known ring system as defined above, R.sub.3 to R.sub.10 are hydrogen, and the polymeric matrix comprises a borate crosslinked polyvinyl alcohol comprising units of formula (II). In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same or different and mean a known ring system as defined above, R.sub.3 to R.sub.10 are hydrogen, and the polymeric matrix comprises a borate crosslinked polyvinyl alcohol comprising units of formula (II). In another embodiment of the first aspect of the invention, at least one of R.sub.1 and R.sub.2 is a known ring system comprising one aromatic ring optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; R.sub.3 to R.sub.10 are hydrogen; and the polymeric matrix comprises a borate crosslinked polyvinyl alcohol comprising units of formula (II). In another embodiment of the first aspect of the invention, both R.sub.1 and R.sub.2 are the same and represent a known ring system comprising one aromatic ring optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; R.sub.3 to R.sub.10 are hydrogen; and the polymeric matrix comprises a borate crosslinked polyvinyl alcohol comprising units of formula (II). In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same and represent a known ring system consisting of a single aromatic ring optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; R.sub.3 to R10 are hydrogen; and the polymeric matrix comprises a borate crosslinked polyvinyl alcohol comprising units of formula (II). In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are phenyl radicals optionally substituted with one or more radicals selected from the group consisting of: (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; R.sub.3 to R.sub.10 are hydrogen; and the polymeric matrix comprises a borate crosslinked polyvinyl alcohol comprising units of formula (II). In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same and are selected from the group consisting of: phenyl, toluene, ethylbenzene, propylbenzene, cumene, isobutylbenzene, dodecylbenzene, styrene, alpha-methylstyrene, o-Xylene, m-Xylene, p-Xylene, and p-Cymene, the ring being optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; R.sub.3 to R.sub.10 are hydrogen; and the polymeric matrix comprises a borate crosslinked polyvinyl alcohol comprising units of formula (II). In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same and are phenyl radicals substituted with one cyano radical; R.sub.3 to R.sub.10 are hydrogen; and the polymeric matrix comprises a borate crosslinked polyvinyl alcohol comprising units of formula (II).

    [0086] In another embodiment of the first aspect of the invention, the compound of formula (I) is one wherein R.sub.1 and R.sub.2 is a known ring system as defined above, R.sub.3 to R.sub.10 are hydrogen; X is halogen; and the polymeric matrix comprises a borate crosslinked polyvinyl alcohol comprising units of formula (II). In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same or different and mean a known ring system as defined above, R.sub.3 to R.sub.10 are hydrogen, X is halogen; and the polymeric matrix comprises a borate crosslinked polyvinyl alcohol comprising units of formula (II). In another embodiment of the first aspect of the invention, at least one of R.sub.1 and R.sub.2 is a known ring system comprising one aromatic ring optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; R.sub.3 to R.sub.10 are hydrogen; X is halogen; and the polymeric matrix comprises a borate crosslinked polyvinyl alcohol comprising units of formula (II). In another embodiment of the first aspect of the invention, both R.sub.1 and R.sub.2 are the same and represent a known ring system comprising one aromatic ring optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; R.sub.3 to R.sub.10 are hydrogen; X is halogen; and the polymeric matrix comprises a borate crosslinked polyvinyl alcohol comprising units of formula (II). In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same and represent a known ring system consisting of a single aromatic ring optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; R.sub.3 to R.sub.10 are hydrogen; X is halogen; and the polymeric matrix comprises a borate crosslinked polyvinyl alcohol comprising units of formula (II). In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are phenyl radicals optionally substituted with one or more radicals selected from the group consisting of: (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; R.sub.3 to R.sub.10 are hydrogen; X is halogen; and the polymeric matrix comprises a borate crosslinked polyvinyl alcohol comprising units of formula (II). In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same and are selected from the group consisting of: phenyl, toluene, ethylbenzene, propylbenzene, cumene, isobutylbenzene, dodecylbenzene, styrene, alpha-methylstyrene, o-Xylene, m-Xylene, p-Xylene, and p-Cymene, the ring being optionally substituted with one or more radicals selected from the group consisting of (C.sub.1-C.sub.6)alkyl, (C.sub.1-C.sub.6)haloalkyl, (C.sub.1-C.sub.6)alkoxy, (C.sub.5-C.sub.14)aryloxy, nitro, cyano, and halogen; R.sub.3 to R.sub.10 are hydrogen; X is halogen; and the polymeric matrix comprises a borate crosslinked polyvinyl alcohol comprising units of formula (II). In another embodiment of the first aspect of the invention, R.sub.1 and R.sub.2 are the same and are phenyl radicals substituted with one cyano radical; R.sub.3 to R.sub.10 are hydrogen; X is halogen; and the polymeric matrix comprises a borate crosslinked polyvinyl alcohol comprising units of formula (II).

    [0087] The viscosity of the polymeric matrix is measured with a controlled stress rheometer, in particular TA instruments AR.sub.2000ex, using a 40 mm plate-plate geometry. The flow procedure with a shear rate (s-1) from 0.00001 to 1 was monitored at a constant temperature of 25 C. In one embodiment, the viscosity of the polymeric matrix, forming part of any of the compositions provided above or below as embodiments, is higher than 110.sup.3 and equal or lower than 110.sup.12 Pa.Math.s. In another embodiment, the viscosity of the polymeric matrix, forming part of any of the compositions provided above or below, is comprised from 1-10.sup.2 to 1-10.sup.6 Pa.Math.s. In another embodiment, the viscosity of the polymeric matrix, forming part of any of the compositions provided above or below, is comprised from 1-10.sup.2 to 5-10.sup.5 Pa.Math.s. In one embodiment, the viscosity of the polymeric matrix, forming part of any of the compositions provided above or below as embodiments, is comprised from 1-10.sup.2 to 5-10.sup.2 Pa.Math.s. In another embodiment, the viscosity of the polymeric matrix is comprised from 1-10.sup.1 to 4-10.sup.2 Pa.Math.s. In another embodiment, the viscosity of the polymeric matrix is about 300 Pa.Math.s. In another embodiment, the viscosity of the polymeric matrix is about 5-10.sup.5 Pa.Math.s.

    [0088] In the present invention, the expression redox pair is to be understood as an electron mediator which consists of an oxidizing and/or reducing agent which are involved in the redox reaction suffered by the compound of formula (I). Thus, in the reaction, the reducing agent loses electrons, which are accepted by the compound of formula (I), and the oxidizing agent gains electrons from the compound of formula (I). Illustrative non-limitative examples of redox pair includes Fe.sup.3+/Fe.sup.2+, Mn.sup.4+/Mn.sup.2+, Sn.sup.4+/Sn.sup.2+, Cu.sup.2+/Cu.sup.+, Ni.sup.3+/Ni.sup.2+, Mn.sup.3+/Mn.sup.2+, Cr.sup.4+/Cr.sup.3+, and Co.sup.3+/Co.sup.2+, 5,10-Dihydro-5,10-dimethylphenazine, N,N,N,N-tetramethyl-p-phenylene-diamine, N,N,N,N-tetraphenyl-p-phenylene-diamine, bis-3,3-diethyl-2,2-benzothiazole azine, tetrathiafulvalene, ferrocene, and hydroquinone, among others. In one embodiment, the redox pair is Fe(CN).sub.6].sup.3/[Fe(CN).sub.6].sup.4. This redox couple is reversible and entails no making or breaking of FeC bonds:


    [Fe(CN).sub.6].sup.3+e.sup..fwdarw.[Fe(CN).sub.6].sup.4

    [0089] In another embodiment of the first aspect of the invention, the redox pair is at a concentration comprised from 0.1 to 20 mM. In another embodiment of the first aspect of the invention, the redox pair is at a concentration comprised from 0.2 to 10 mM. In another embodiment of the first aspect of the invention, the redox pair is at a concentration comprised from 0.2 to 5. In another embodiment of the first aspect of the invention, the redox pair is at a concentration of 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1.0, 2.0, 3.0, 4.0, 5.0, 6.0, 7.0, 8.0, 9.0, 10.0, 11.0, 12.0, 13.0, 14.0, 15.0, 16.0, 17.0, 18.0, 19.0 or 20.0. In another embodiment of the first aspect of the invention, the redox pair is at a concentration of 4 mM.

    [0090] In another embodiment of the first aspect of the invention, the composition comprises: (a) the compound of formula (Ibis), (b) the borate crosslinked polyvinyl alcohol comprising units of formula (II), and (c) the redox pair Fe.sup.2+/Fe.sup.3+. In another embodiment of the first aspect of the invention, the composition comprises: (a) the compound of formula (Ibis) at a concentration of 3.5 mM, (b) the borate crosslinked polyvinyl alcohol comprising units of formula (II), wherein the polymeric matrix has a viscosity comprised from 1-10.sup.2 to 5-10.sup.2 Pa.Math.s, and (c) the redox pair Fe(CN).sub.6].sup.3/[Fe(CN).sub.6].sup.4 at a concentration of 4 mM. In another embodiment of the first aspect of the invention, the composition comprises: (a) the compound of formula (Ibis), (b) the borate crosslinked polyvinyl alcohol comprising units of formula (II), and (c) the redox pair Fe(CN).sub.6].sup.3/[Fe(CN).sub.6].sup.4. In another embodiment of the first aspect of the invention, the composition comprises: (a) the compound of formula (Ibis) at a concentration of 3.5 mM, (b) the borate crosslinked polyvinyl alcohol comprising units of formula (II), wherein the polymeric matrix has a viscosity about 300 Pa.Math.s, and (c) the redox pair Fe(CN).sub.6].sup.3/[Fe(CN).sub.6].sup.4 at a concentration of 4 mM.

    [0091] In another embodiment, the solvent is selected from the group consisting of ethyleneglycol, dimethyl sulfoxide (DMSO), and water. In another embodiment, the solvent is water.

    [0092] In another embodiment of the first aspect of the invention, the composition comprises: (a) the compound of formula (Ibis), (b) a borate crosslinked polyvinyl alcohol, (c) the redox pair Fe(CN)6P.sup./[Fe(CN).sub.6].sup.4, and (d) the solvent is water. In another embodiment of the first aspect of the invention, the composition comprises: (a) the compound of formula (Ibis) at a concentration of 3.5 mM, (b) a borate crosslinked polyvinyl alcohol, wherein the polymeric matrix has a viscosity comprised from 1-10.sup.2 to 5-10.sup.2 Pa.Math.s, (c) the redox pair Fe(CN).sub.6].sup.3/[Fe(CN).sub.6].sup.4 at a concentration of 4 mM, and (d) the solvent is water. In another embodiment of the first aspect of the invention, the composition comprises: (a) the compound of formula (Ibis) at a concentration of 3.5 mM, (b) a borate crosslinked polyvinyl alcohol having a viscosity about 300 Pa.Math.s, (c) the redox pair Fe(CN).sub.6].sup.3/[Fe(CN).sub.6].sup.4 at a concentration of 4 mM; and (d) the solvent is water.

    [0093] In another embodiment of the first aspect of the invention, the composition comprises: (a) the compound of formula (Ibis), (b) the borate crosslinked polyvinyl alcohol comprising units of formula (II), (c) the redox pair Fe(CN).sub.6].sup.3/[Fe(CN).sub.6].sup.4, and (d) the solvent is water. In another embodiment of the first aspect of the invention, the composition comprises: (a) the compound of formula (Ibis) at a concentration of 3.5 mM, (b) the borate crosslinked polyvinyl alcohol comprising units of formula (II), wherein the polymeric matrix has a viscosity comprised from 1-10.sup.2 to 5-10.sup.2 Pa.Math.s, (c) the redox pair Fe(CN).sub.6].sup.3/[Fe(CN).sub.6].sup.4 at a concentration of 4 mM, and (d) the solvent is water. In another embodiment of the first aspect of the invention, the composition comprises: (a) the compound of formula (Ibis) at a concentration of 3.5 mM, (b) the borate crosslinked polyvinyl alcohol comprising units of formula (II), wherein the polymeric matrix has a viscosity about 300 Pa.Math.s, (c) the redox pair Fe(CN).sub.6].sup.3/[Fe(CN).sub.6].sup.4 at a concentration of 4 mM; and (d) the solvent is water.

    [0094] In another embodiment of the first aspect of the invention, the multichromic composition comprises one or more further viologens, in addition to the compound of formula (I).

    [0095] In the present invention, the term viologen encompasses 1,1-disubstituted-4,4-bipyridilium salts having the ability to change color reversibly many times upon reduction and oxidation. The compounds of formula (I) are viologens, as having this ability.

    [0096] In one embodiment, the multichromic composition comprises one additional viologen.

    [0097] In another embodiment, optionally in combination with any of the embodiments provided above or below, the further viologen is a compound of formula (III):

    ##STR00005##

    [0098] wherein

    [0099] R.sub.11 and R.sub.12 are the same or different and are selected from the group consisting of a (C.sub.1-C.sub.20)alkyl, (C.sub.1-C.sub.20)alkyl substituted with one or more (C.sub.1-C.sub.5)alkyl, OH, halogen, phenyl, phenyl substituted with one or more (C.sub.1-C.sub.4)alkyl radicals, phenyl substituted with one or more halogen radicals, benzyl, benzyl substituted with one or more (C.sub.1-C.sub.4)alkyl radicals, or benzyl substituted with one or more halogen radicals; a 2 to 20-member heteroalkyl; a 2 to 20-member heteroalkyl substituted with one or more OH, halogen, phenyl, phenyl substituted with one or more (C.sub.1-C.sub.4)alkyl radicals, phenyl substituted with one or more halogen radicals, benzyl, benzyl substituted with one or more (C.sub.1-C.sub.4)alkyl radicals, or benzyl substituted with one or more halogen radicals;

    [0100] R.sub.13 to R.sub.20 are radicals independently selected from the group consisting of hydrogen; (C.sub.1-C.sub.20)alkyl, (C.sub.1-C.sub.20)alkyl substituted by one or more radicals selected from the group consisting of: halogen, OH, and NO.sub.2; (C.sub.1-C.sub.20)alkoxy; cyano; and nitro; and

    [0101] X is a monocharged anion.

    [0102] In another embodiment, optionally in combination with any of the embodiments provided above or below, the further viologen is a compound of formula (III) wherein R.sub.11 and R.sub.12 are the same.

    [0103] In another embodiment, optionally in combination with any of the embodiments provided above or below, the further viologen is a compound of formula (III) wherein R.sub.11 and R.sub.12 are (C.sub.1-C.sub.20)alkyl.

    [0104] In another embodiment, optionally in combination with any of the embodiments provided above or below, the further viologen is a compound of formula (III) wherein R.sub.11 and R.sub.12 are the same and represent (C.sub.1-C.sub.20)alkyl. In another embodiment, optionally in combination with any of the embodiments provided above or below, R.sub.11 and R.sub.12 are the same and represent (C.sub.1-C.sub.10)alkyl. In another embodiment, optionally in combination with any of the embodiments provided above or below, the further viologen is a compound of formula (III) wherein R.sub.11 and R.sub.12 are the same and represent (C.sub.1-C.sub.5)alkyl.

    [0105] In another embodiment, optionally in combination with any of the embodiments provided above or below, the further viologen is a compound of formula (III) wherein R.sub.13 to R.sub.20 are the same. In another embodiment, optionally in combination with any of the embodiments provided above or below, the further viologen is a compound of formula (III) wherein R.sub.13 to R.sub.20 are the same and represent H.

    [0106] In one embodiment, the additional viologen is selected from 1,1-diethyl-4,4-bipyridinium dibromide, 1,1-diethyl-4,4-bipyridinium diperchlorate, 1,1-dimethyl-4,4-bipyridinium dichloride hydrate, 1,1-dipropyl-4,4-bipyridinium dibromide, 1,1-dibutyl-4,4-bipyridinium dibromide.

    [0107] Alternatively, in another embodiment, the further viologen can be 1,1-dibenzyl-4,4-bipyridinium dibromide.

    [0108] In another embodiment, the one or more additional viologen(s) are at a concentration comprised from 0.5 to 40 mM. In another embodiment, the additional viologen is at a concentration of 20 mM. In another embodiment, the one additional viologen is 1,1-diethyl-4,4-bipyridinium dibromide at a concentration in the range of 0.5 to 30 mM. In another embodiment, the one additional viologen is 1,1-diethyl-4,4-bipyridinium dibromide at a concentration in the range of 2.5 to 25 mM. In another embodiment, the one additional viologen is 1,1-diethyl-4,4-bipyridinium dibromide at a concentration of 20 mM.

    [0109] It is the first time that a formulation containing two viologens provides five well-defined colorations. As it is shown below, the resulting devices showed multi-electrochromic behavior including colorless, green, pink-violet, orange and purple, involving just a single EC layer sandwiched between two electrodes. The easy design involves just applying a layer of the composition of the first aspect of the invention, containing two-viologens in a single layer sandwiched between different electrodes on a common patterned substrate. This allows the fabrication of rainbow-like electrochromic devices in which the color of each area can be adjusted independently over time between different colors under suitable applied potentials, bringing us closer to rainbow-like windows.

    [0110] In a second aspect, the present invention provides a process for preparing the multichromic composition as defined in the first aspect of the invention.

    [0111] All the embodiments mentioned above regarding the compound of formula (I) and the redox pair are also embodiments of the process of the second aspect of the invention.

    [0112] In the present invention, the term non-crosslinked polymer is a polymer wherein the polymeric chains are not bound. Illustrative non-limitative examples of non-crosslinked polymer are a non-crosslinked polyvinyl alcohol, a non-crosslinked polyhydroxyalkylacrylate, a non-crosslinked polyhydroxyalkyl methacrylate, a non-crosslinked polysaccharide, and a non-crosslinked polyalkylenglycol, and a combination thereof. In another embodiment, the non-crosslinked polymer is a non-crosslinked polyvinyl alcohol.

    [0113] In the present invention, the expression amount of a solution when referred to the solution of non-crosslinked polymer, pair redox, crosslinking agent or the compound of formula (I) means the volume of the solution.

    [0114] In another embodiment of the process of the second aspect of the invention, the mixture of the non-crosslinked polymer solution with the crosslinking agent solution is performed ata volume ratio comprised from 10:1 to 2:1. In another embodiment, the volume ratio is 4:1.

    [0115] In the present invention, the expression volume ratio means the volume of the mixture resulting from step (a1) with respect to the volume of the crosslinking agent, said volumes being expressed in the same units.

    [0116] In another embodiment of the second aspect of the invention, the process comprises a further step of mixing the resulting mixture of step (b1) or (c2) or (c3) with one or more additional viologens. In another embodiment of the second aspect of the invention, the process comprises a further step of mixing the resulting mixture of step (b1) or (c2) or (c3) with one or more additional viologens, wherein the further one or more viologen(s) form(s) part of a composition further comprising a crosslinked polymer and a redox pair, both as defined in any of the above embodiments. In another embodiment of the second aspect of the invention, the one or more additional viologens form(s) part of a composition further comprising a borate crosslinked polymer comprising units of formula (II) and a redox pair Fe(CN).sub.6].sup.3/[Fe(CN).sub.6].sup.4.

    [0117] The composition comprising the one or more further viologen(s) can be prepared by routine procedures but also following the steps (a1) to (b1) or alternatively (a2) to (c2) or alternatively (a3) to (c3) disclosed above for the process of the second aspect of the invention.

    [0118] In one embodiment of the process of the second aspect of the invention, the non-crosslinked polymer is a polyvinyl alcohol and the crosslinking agent is borax. In another embodiment, the non-crosslinked polymer is a polyvinyl alcohol, the crosslinking agent is borax, and the molar ratio polyvinyl alcohol:borax is comprised from 87:1 to 17:1. In another embodiment, the non-crosslinked polymer is a polyvinyl alcohol, the crosslinking agent is borax, and the molar ratio polyvinyl alcohol:borax is comprised from 70:1 to 30:1. In another embodiment, the non-crosslinked polymer is a polyvinyl alcohol, the crosslinking agent is borax, and the molar ratio polyvinyl alcohol:borax is comprised from 50:1 to 30:1. In another embodiment, the non-crosslinked polymer is a polyvinyl alcohol, the crosslinking agent is borax, and the molar ratio polyvinyl alcohol:borax is comprised from 40:1 to 30:1. In another embodiment, the non-crosslinked polymer is a polyvinyl alcohol, the crosslinking agent is borax, and the molar ratio polyvinyl alcohol:borax is about 34:1.

    [0119] In the present invention, the expression molar ratio means the number of moles of polyvinyl alcohol polymer with respect to the number of moles of borax.

    [0120] In a fourth aspect, the present invention provides a device comprising the composition of the invention and a substrate. The device can be an electrochromic device, a photochromic device, or a thermochromic device, among others, depending on the external stimuli responsible for the color change (current, light or heat, respectively).

    [0121] In the present invention the expression substrate means an inert support which does not negatively affect the external stimuli (either electrical current, heat, light, among others) applied on the device nor the color change produced in response to the stimuli. Illustrative non-limitative examples of substrates are glass, plastic, or metal, among others.

    [0122] In another embodiment of the fourth aspect of the invention, the device comprises a layer made of the composition as defined in the first aspect of the invention.

    [0123] In another embodiment of the fourth aspect of the invention, the device is an electrochromic device and comprises the composition of the invention and two substrates, the two substrates being positioned in such a way that it is allowed the transversal transmission of the current through the substrates.

    [0124] In another embodiment of the fourth aspect of the invention, the device is an electrochromic device and comprises a layer made of the composition of the invention sandwiched between two substrates, each one of the substrates comprising one or more electrodes, wherein at least one of the substrates is transparent.

    [0125] The electrode included in the substrate can be any material containing a conducting surface, electrically conducting thin layers, such as indium tin oxide (ITO), fluorine doped tin oxide (FTO), and/or doped zinc oxide oxides (TCOs), among others.

    [0126] In another embodiment of the fourth aspect of the invention, the substrate comprises one or more electrodes, the one or more electrodes comprising on at least one of their sides, a layer of the composition of the first aspect of the invention. Thus generating what the inventors referred as a rainbow-like device, wherein each one of the electrodes shows an independent color behavior. There are well-known methods for manufacturing this kind of devices. An illustrative non-limitative way is provided below, in the section of Examples.

    [0127] In another embodiment of the fourth aspect of the invention, the device is a two electrode electrochromic device wherein the composition layer is sandwiched between two electrodes. In the case of quasi-solid formulations, the electrochromic compositions were spread on the conducting side of one of the substrates provided with a spacer and then covered with the conducting side of the other substrate. The electrodes were clamped together. In the case of liquid compositions such as aqueous liquid system and composition comprising non-crosslinked PVA-4% employed for comparison, the electrochromic device was prepared in a sandwich-type structure as follows: A spacer was placed between the conducting sides of the substrates and the electrodes were clamped together. The electrochromic formulations were introduced by surface capillarity.

    [0128] In another embodiment of the fourth aspect of the invention, the device is a three-electrode electrochromic device. The parts comprised in this kind of devices are schematically illustrated in FIG. 1. Briefly, it comprises a working electrode, a scribing, a pseudoreference electrode, a layer of the composition of the invention, a counter electrode, and a spacer (such as a double-side adhesive). The parts forming this type of device are commercially available, and the skilled person, using the general knowledge, can select the more appropriate electrodes and spacers. An illustrative non-limitative way is provided below, in the section of Examples. The three-electrode electrochromic device was prepared in a sandwich-type structure as follows: one of the substrates was electrically insulated into two sections. A metal and/or ionic salt ink was employed to draw a layer on one of these conducting sections which was employed as pseudoreference electrode after being cured (RE). The other section of the same substrate was employed as a working electrode (WE) while new substrate (without any treatment) provided with a spacer was used as counter electrode (CE).

    [0129] The quasi-solid electrochromic compositions were spread on the conducting side of one of the substrates and then covered with the conducting side of the other substrate. The electrodes were clamped together. In the case of aqueous liquid system employed for comparison, the electrochromic device was prepared in a sandwich-type structure as follows: One of the substrates was electrically insulated into two sections. A metal and/or ionic salt ink was employed to draw a layer on one of these conducting sections which was employed as pseudoreference electrode after being cured (RE). The other section of the same substrate was employed as a working electrode (WE) while new substrate (without any treatment) provided with a spacer was used as counter electrode (CE). The electrodes were clamped together and the electrochromic formulations were introduced by surface capillarity.

    EXAMPLES

    [0130] Materials

    [0131] Polyvinyl alcohol (PVA, Mw 61000), sodium tetraborate (borax, 99.5%), 4,4-bipyridyl (98%), 2,4-dinitrochlorobenzene (99%), p-cyanoaniline (98%), potassium ferrocyanide (98.5%), potassium ferricyanide (99%) and 1,1-diethyl-4,4-bipyridinium dibromide (ethyl viologen dibromide, EtViol, 99%), were purchased from Sigma-Aldrich and used without further purification. Required solvents such as acetonitrile, chloroform, acetone, ethanol, methanol and diethyl ether, were purchased from Scharlab and used as received. Fluorine-doped tin oxide (FTO) coated glass substrates (TEC, Rs 6-8 sq.sup.1) and Tin-doped indium oxide glass substrates (ITO Sol 30/1.1, Rs 25-35 sq.sup.1) were supplied by Solems and cleaned with warm acetone prior to use.

    [0132] Synthesis of 1,1-bis-(p-cyanophenyI)-4,4-bipyridilium dichloride (p-cyanophenylviologen dichloride, p-CV).

    [0133] It was synthesized according to previously reported procedures (G. D. Short, Disubstituted Bipyridylium Salts Patent GB1310813) but replacing the solvent by water. Finally, the product was further purified by double recrystallization from methanol and ether, followed by drying in vacuo .sup.1H NMR (500 MHz, DMSO-d6, ): 9.77 and 9.18 (d of d, 4H and 4H, Ar H), 8.35 and 8.23 (d of d, 4H and 4H, bipyridine); IR (bulk ATR): v=3091 (CH), 2227 (CN), 1629, 1603 (CC, CN), 830 cm.sup.1 (o-phenylene H).

    [0134] Methods

    [0135] UV/Vis transmission/absorption spectra were measured with a Jasco V-570 spectrophotometer. The spectra were registered using a films holder accessory for solid samples, while the devices were connected to Biologic MPG potentiostat-galvanostat as a direct current source. Before recording the spectra measurement of the ECDs (%T or Abs as a function of the wavelength), the devices were exposed to the same voltage during 40 seconds with the aim of reaching the maximum colored state before starting the measurement.

    [0136] Fourier transform infrared (FT-IR) spectra was recorded on a 4100LE FTIR from Jasco. The IR spectra was obtained using Attenuated Total Reflectance (ATR) technique on the pure solid.

    [0137] Viscosity measurements were carried out in a TA instruments AR.sub.2000ex rheometer using a 40 mm plate-plate geometry. The flow procedure with a shear rate(s.sup.1) from 0.00001 to 1 was monitored at a constant temperature of 25 C.

    [0138] Color coordinates of the devices were determined using CIE 1976 L*a*b color space as quantitative scale to define th2e color, where L* represents the lightness of the color (L*=0 yields black and L*=100 indicates diffuse white), a* axis corresponds to the position between green and red (with green at negative a* values and red at positive a* values) and b* indicates the position between blue and yellow (with blue at negative b* values and yellow at positive b* values). Color coordinates were obtained using both spectrophotometric and colorimetric method. The colorimetric measurements were carried out with a spectroradiometer Konika Minolta CS-1000 A, while the spectrophotometric measurements were determined using the same spectrophotometer mentioned above following the method developed by R. J. Mortimer (R. J. Mortimer et al., Quantification of colour stimuli through the calculation of CIE chromaticity coordinates and luminance data for application to in situ colorimetry studies of electrochromic materials, 2013, Displays, 32, 35-44).

    [0139] The spectroelectrochemistry study was carried out with the same potentiostat-galvanostat mentioned above.

    [0140] Manufacture of Two-Electrode Electrochromic Devices

    [0141] The electrochromic device was prepared as follows: A 220 m double-side adhesive tape was placed on FTO-coated side and the electrochromic compositions were sandwiched between two FTO-coated glass substrates. The electrodes were clipped using paper clip clamps.

    [0142] In the case of aqueous liquid system employed for comparison, the electrochromic formulations were introduced in the previously assembled device by surface capillarity.

    [0143] Manufacture of Three-Electrode Electrochromic Device

    [0144] The electrochromic device was prepared as follows: 5 cm2.5 cm ITO coated glass substrate was electrically insulated by laser scribing into two sections having an approximate active area of 5 cm2 cm and 5 cm0.5 cm. Ag ink purchased from Acheson (Electrodag PF-410) was employed to draw a layer on the 5 cm0.5 cm section which was employed as pseudoreference electrode after being dried at 90 C. (RE). The other wider section of the same substrate was employed as a working electrode (WE) while new ITO-coated glass substrate (without any laser treatment) was used as counter electrode (CE). FIG. 1 shows a schematic view of the three-electrode electrochromic device configuration. A 220 m double-side adhesive tape was placed on ITO-coated side of the counter electrode and the electrochromic compositions were sandwiched between two ITO-coated glass substrates. The electrodes were clipped using paper clip clamps.

    [0145] Manufacture of a Rainbow-Like Electrochromic Device

    [0146] The electrochromic device was prepared as follows: 5 cm5 cm ITO coated glass substrate was electrically insulated by laser scribing into four different sections having all of them an approximate active area of 5 cm1 cm. Each section was employed as stand-alone working electrode (WE) for rainbow-like electrochromic device. Similarly laser scribing substrate was employed as counter electrode (CE). A 220 m double-side adhesive tape was placed on ITO-coated side of the counter electrode and the electrochromic compositions were sandwiched between two ITO-coated glass substrates. The electrodes were clipped using paper clip clamps.

    Example 1

    Preparation of the Compositions of the Invention 4a-i

    [0147] This series of nine electrochromic compositions were fabricated by varying concentrations of p-cyanophenylviologen dichloride from 0.25 to 4.0 mmolL.sup.1 while keeping the concentration of ferro/ferricyanide potassium pair at a constant value of 0.4 mmolL.sup.1. These compositions were prepared as follows: to a previously prepared 4 wt % solution of PVA, aqueous solutions containing appropriate amounts of p-cyanophenylviologen dichloride and a 1:1 mixture of potassium ferrocyanide and potassium ferricyanide were added. The resulting mixtures were stirred until homogeneous solution was obtained. Then, each of these solutions were mixed with a 4 wt % borax aqueous solution in a 4:1 volume ratio by vigorous stirring with a spatula, until the formation of a gel. The composition was left to settle on its own until completely bubble-free material was obtained. The final concentrations of viologen for Composition 4a, Composition 4b, Composition 4c, Composition 4d, Composition 4e, Composition 4f, Composition 4g, Composition 4h and Composition 4i were 0.25, 0.5, 1.0, 1.5, 2.0, 2.5, 3.0, 3.5 and 4.0 mmolL.sup.1, respectively. All the compositions had a viscosity value of about 300 Pa.Math.s.

    [0148] All the compositions were prepared using water as solvent.

    Example 2

    Preparation of the Compositions of the Invention 4h1-10

    [0149] This series of ten electrochromic compositions were fabricated by varying concentrations of ferro/ferricyanide potassium pair from 0.2 to 5.0 mmolL.sup.1 while keeping the concentration of p-cyanophenylviologen dichloride at a constant value of 3.5 mmolL.sup.1. These compositions were prepared as described above for the preparation of compositions 4a-i. The final concentrations of ferro/ferricyanide potassium pair for Composition 4h1, Composition 4h2, Composition 4h3, Composition 4h4, Composition 4h5, Composition 4h6, Composition 4h7, Composition 4h8, Composition 4h9 and Composition 4h10 were 0.2, 0.4, 0.6, 0.8, 1.0, 1.5, 2.0, 3.0, 4.0 and 5.0 mmolL-1 respectively. All the compositions had a viscosity value of about 300 Pa.Math.s.

    [0150] All the compositions were prepared using water as solvent.

    Example 3

    Preparation of the Composition of the Invention 3g9

    [0151] This electrochromic composition was prepared keeping the final concentration of ethyl viologen dibromide at 20 mmolL.sup.1 and the concentration of the ferro/ferricyanide potassium pair at 6 mmolL.sup.1 value. This composition was prepared following the protocol as described above for the preparation of Compositions 4a-i. The resulting composition had a viscosity value of about 300 Pa.Math.s.

    [0152] All the compositions were prepared using water as solvent.

    Example 4

    Preparation of the Compositions of the Invention 5a and 5b

    [0153] These electrochromic compositions were fabricated by mixing a weight ratio of the Composition 3g9:Composition 4h9 (both obtained as described above) of 2:1 and 1:1 respectively, followed by vigorous stirring with spatula. The composition was left to settle on its own until completely bubble-free material was obtained.

    [0154] The term weight ratio means the amount of composition 3g9 vs the amount of composition 4h9, both amounts being expressed in the same units.

    Example 5

    Preparation of an Aqueous Composition Comprising Non-Crosslinked PVA-4% (for Comparative Purposes)

    [0155] A previously prepared 4 wt % solution of non-crosslinked PVA, was mixed with an aqueous solution containing required ammounts of p-cyanophenylviologen dichloride and a 1:1 mixture of potassium ferrocyanide and potassium ferricyanide to obtain a final concentrations of 3.5 and 4 mM respectively. The resulting mixture was stirred until homogeneous solution was obtained. The viscosity of the resulting composition was 9-10.sup.3 Pa.Math.s.

    Example 6

    Preparation of a Composition of the Invention Comprising Crosslinked PVA-Borax 15%

    [0156] A previously prepared 15 wt % solution of PVA, was mixed with an aqueous solution containing required ammounts of p-cyanophenylviologen dichloride and a 1:1 mixture of potassium ferrocyanide and potassium ferricyanide to obtain a final concentrations of 3.5 and 4 mM respectively. The resulting mixture was stirred until homogeneous solution was obtained. Then, the resulting solution was mixed with a 15 wt % borax aqueous solution in a 4:1 volume ratio by stirring with a spatula, until the cross-linking occurs. The viscosity of the resulting composition was 5-10.sup.5 Pa.Math.s.

    Example 7

    Preparation of an Aqueous Composition (for Comparative Purposes)

    [0157] Appropriate amounts of p-cyanophenylviologen dichloride and 1:1 mixture of potassium ferrocyanide and potassium ferricyanide were dissolved in water to obtain a final concentrations of 3.5 mM of p cyanophenylviologen dichloride and 4 mM concentration of potassium ferrocyanide and potassium ferricyanide. No polymer was added to the mixture.

    [0158] The resulting mixture was stirred at room temperature until homogeneous solution was obtained. The viscosity of the resulting composition was 1-10.sup.3 Pa.Math.s.

    Example 8

    Electrochromism of a Two-Electrode Electrochromic Device with the Aqueous Composition of Example 7(for Comparative Purposes)

    [0159] Two-electrode electrochromic device comprising the composition of the example 7 was prepared following the same protocol as disclosed above. FIG. 2 corresponds to the UV/Vis transmittance spectra of the device under different potentials (i.e. 0, 1.4 and 1.8 V) respectively. From the results obtained, it could be concluded that when the external voltage was set at 1.4 V the ECD containing Composition PVA-4% exhibited two strong absorption bands (i.e. transmittance valleys in FIG. 2) at around 420 and 600 nm, characteristic of the green materials that absorb both the blue and red regions of the electromagnetic spectrum. Although some decrease of the transmittance for wavelengths around 500 nm was detected when once more cathodic potential of 1.8 V was applied, the transmittance spectrum is still typical of green materials, indicating no red coloration. This finding is opposite to the detected for borax containing formulations (e.g. example 9 below) indicating that borax-based reticulation is crucial to reach the red color.

    Example 9

    Multichromism of a Two-Electrode Device with the Composition of the Invention 4h9

    [0160] FIG. 3 shows UV/vis transmittance spectra.

    [0161] Interestingly, in addition to the green color such as p-CV can provide and observed upon applying 1.4V voltage, red coloration occurred as a result of applying more cathodic potential of 1,8V.

    [0162] It is remarkable that the non-water soluble composition comprising a di-reduced specie viologen compound of formula (I), such as p-CV, showing good electrochemical reversibility and cyclability as well as shorts switching time for the colored and bleached steps.

    Example 10

    Multichromism Comparison between a Three-Electrode Device Comprising the Composition of the Invention 4h9 and a Three-Eletrode Device Comprising the Aqueous Composition of Example 7

    [0163] The three-electrode electrochromic device comprising the composition of the invention 4h9 was prepared following the protocol disclosed above.

    [0164] For comparative purposes, a further three-electrode electrochromic device was manufacture using the aqueous system of Example 7 following the same protocol as disclosed above.

    [0165] FIG. 4a shows the cyclic voltammetry of three-electrode ECDs containing the Composition 4h9 as well as a water solution containing the same amount of viologen and redox pair, but not the crosslinked polymer. In the potential range from 1.10 to 1.45 V, three well-defined peaks can be distinguished on the cathodic sweep of the scan of both systems. The first reduction peak (0.2 V) was assigned to the reduction of ferricyanide ion, the second reduction peak (0.5 V) was correlated with the green radical-cation (p-CV+.) formed by one-electron reduction of the dication (p-CV2+), while the third reduction peak (0.9 V) was related to the di-reduced form (p-CVO) obtained by one-electron reduction of the radical-cation. FIG. 4b corresponds to the UV/Vis transmittance spectra of devices under different potentials (i.e. 0, 0.5 and 0.9 V) respectively. From the results obtained, it could be concluded that the ECD containing Composition 4h9 exhibited green coloration when the external voltage was set at 0.5 V, and the color turned into the red upon applying external voltage of 0.9 V. By comparing the UVNis transmittance spectra (FIG. 4b), different absorption features were observed in the case of Composition 4h9. When the applied potential was set at 0.5 V, the ECD exhibited two strong absorption bands (i.e. transmittance valleys in FIG. 4b) at around 420 and 600 nm, characteristic of the green materials that absorb both the blue and red regions of the electromagnetic spectrum. Once more cathodic potential of 0.9 V was applied, the transmittance is quenched (indicating very significant absorption) around 500 nm and the ECD color turned into the red. After the potential was set again to 0 V, the ECD turned back to its original colorless form, showing reversible response.

    [0166] Nevertheless, in the case of aqueous liquid system, the results revealed that upon applying a switching voltage of 0.9V, the device showed mainly dark green coloration and the corresponding transmittance profiles (FIG. 4b). The electrochromic properties and color coordinates (D65) CIE L*a*b are summarized in Table 1.The results from the aqueous liquid-based ECD show that even though the applied potential is sufficiently negative for di-reduction to occur, the red coloration is not observed. This can be attributed to the comproportionation mechanism which is more likely to happen in the aqueous liquid system.

    [0167] With the data provided above, it can be concluded that the viscosity of the composition seems to avoid the di-reduced species and the dications to meet, preventing the comproportionation process and consequently the red coloration of the di-reduced species is observed upon applying suitable voltage of 0.9 V. These results revealed that the presence of the crosslinked polymer matrix at such values of viscosity acts as a stabilizer enabling dual electrochromic behavior, while greatly simplifies the ECDs manufacturing

    TABLE-US-00001 TABLE 1 Compo- Potential sition (V) % T.sup.(a) t.sub.c(s).sup.(b) t.sub.b(s).sup.(c) (cm.sup.2 C.sup.1).sup.(d) L*.sup.(e) a*.sup.(e) b*.sup.(e) L*.sup.(f) a*.sup.(f) b*.sup.(f) 4h9 1.4 61 16 8 78 62 44 27 21 27 16 1.8 58 14 4 83 29 38 15 6 9 2 Aqueous 2.2 62 8 10 179 28 16 8 5 3 3 system 2.4 62 9 15 166 29 17 10 12 1 1 .sup.a)Optical contrast: (% T.sub.b % T.sub.c) being T.sub.b = transmittance at bleached state and T.sub.c = transmittance at colored state. .sup.b),c)Switching times: time required for 90% of the total transmittance change to occur at the maximum contrast wavelength for the colored (t.sub.c) and bleached steps (t.sub.b). .sup.d)Color efficiency: [(OD = log (T.sub.c/T.sub.b))/(Q/A)] being A = device area and Q = injected/ejected charge. .sup.e),f)Color coordinates obtained by spectrophotometric method (.sup.(e)) and colorimetric method (.sup.(f)).

    Example 11

    Preparation of the Composition of the Invention 1g8

    [0168] This electrochromic composition was prepared keeping the final concentration of 1-ethyl-1-(p-cyanophenyl)-4,4-bipyridinium dibromide (Et-pCNVio) at 20 mmolL-1 and the concentration of the ferro/ferricyanide potassium pair at 5 mmolL-1 value. This composition was prepared following the protocol as described above for the preparation of Compositions 4a-i. The resulting composition had a viscosity value of about 300 Pa.Math.s.

    Example 12

    Preparation of the Composition of the Invention 2g8

    [0169] This electrochromic composition was prepared keeping the final concentration 1-benzyl-1-(p-cyanophenyl)-4,4-bipyridinium dibromide (Bn-pCNVio) at 20 mmolL-1 and the concentration of the ferro/ferricyanide potassium pair at 5 mmolL-1 value. This composition was prepared following the protocol as described above for the preparation of Compositions 4a-i. The resulting composition had a viscosity value of about 300 Pa.Math.s.

    Example 13

    Preparation of the Composition of the Invention 5c

    [0170] This electrochromic compositions was fabricated by mixing a weight ratio of the Composition 3g9:Composition 1g8 (both obtained as described above) of 2:1, followed by vigorous stirring with spatula. The composition was left to settle on its own until completely bubble-free material was obtained. The term weight ratio means the amount of composition 3g9 vs the amount of composition 1g8, both amounts being expressed in the same units.

    Example 14

    Preparation of the Composition of the Invention 5d

    [0171] This electrochromic compositions was fabricated by mixing a weight ratio of the Composition 3g9:Composition 2g8 (both obtained as described above) of 2:1, followed by vigorous stirring with spatula. The composition was left to settle on its own until completely bubble-free material was obtained. The term weight ratio means the amount of composition 3g9 vs the amount of composition 2g8, both amounts being expressed in the same units.

    Example 15

    Multichromism of a Three-Electrode Device Comprising the Composition of the Invention 5a

    [0172] A three-electrode device was manufactured with the composition 5a, following the protocol provided above, and the absorbance spectrum, applying different potentials, is provided in FIG. 5.

    [0173] In the potential range from 0 to 1.7 V (FIG: 5A), five well-defined features were observed during the cathodic sweep. As shown in the inset, there is good agreement between these features and the sum of those detected in devices based on the single-compositions 4h9 and 3g9 separately. The first reduction peak (0.2 V) is assigned to the uncolored redox process of ferricyanide ion, while the second peak (0.6 V) and the third (0.8 V) are correlated with first and second reduction of the p-CV respectively. The fourth and fifth peak observed (1.2 and 1.6 V) seem to be related to the radical-cation of the EtVio (EtVio+.) formed by one-electron reduction of the dication (EtVio2+) and the di-reduced form (EtVio0) obtained by one-electron reduction of the radical-cation, respectively.

    [0174] As no significant overlap in the redox potentials of the p-CV and EtVio was detected in the CV of the Composition 5a-based ECD, the latter is expected to behave as a multi-electrochromic device. The multi-electrochromic behavior encompassing five different colorations: colorless (0 V), green (0.7 V), pink-violet (0.9 V), orange (1.1 V) and purple (1.7 V) was visually confirmed. The absorbance spectrum (FIG. 5b) of the three-electrode ECD after applying a switching voltage of 0.7 V was characteristic of green materials with two absorption bands at around 420 and 600 nm. As more cathodic potential of 0.9 V was applied the ECD exhibited broader band with it maximum located at 520 nm which is in good agreement with the observed violet coloration. For a more negative potential of 1.1 V the absorption band showed hypsochromic shift to give a maximum absorption band at 460 nm characteristic of orange materials. Once more cathodic potential of 1.7 V was set, ECD exhibited strong absorption band at around 520 and new band grew up from 415 to 380 nm where the spectra ends. Table 2 summarizes the color coordinates determined by spectrophotometric method.

    TABLE-US-00002 TABLE 2 Color coordinates (D65) xyY(1931) and L*a*b (1976) of Composition 5a Color Corordinates Color Coordinates xyY (1931) L*a*b* (1976) Potential x y Y L* a* b* Off 0.316 0.335 77.492 91 1 3 0.5 V 0.316 0.375 63.391 84 17 15 0.7 V 0.305 0.388 41.052 70 23 15 0.9 V 0.367 0.289 23.656 56 32 4 1.1 V 0.402 0.363 29.247 61 17 21 1.3 V 0.434 8.339 18.985 51 30 17 1.5 V 0.444 0.309 11.098 40 35 9 1.7 V 0.402 0.245 6.356 30 40 8

    [0175] It is noted that the reproducibility and the electrochemical reversibility of Composition 5a was assessed by measuring color coordinates of three ECDs at each potential and, evolution of CV upon cycling. On the basis of the results, Composition 5a system provides highly reproducible and electrochemical reversibility multi-ECDs with well-defined colorations. Therefore, multi-electrochromic compositions may contribute an interesting accomplishment that addresses the shortcomings explained above and frequently present in multi-EC systems such as the device complexity or not distinct enough coloration in their different redox states, among others.

    Example 16

    Multichromism of a Rainbow-Like Device Comprising the Composition of the Invention 5a

    [0176] The fabrication process of Rainbow-like ECDs was very easy, as it has been disclosed above, being only necessary to sandwich the Composition 5a between two ITO-coated glass substrates previously zoned in rows by laser scribing.

    [0177] Applying a voltage in the range from 0.7 to 1.7 V, it was found that each row exhibited multi-electrochromic behavior enabling adjustment of their color independently and changing over time under suitable applied potentials according to the needs. FIG. 6 shows a schematic representation of the resulting device.

    Example 17

    Multichromism of a device comprising the composition of the invention 5b

    [0178] The three-electrode electrochromic device comprising the composition of the invention 5b was prepared following the protocol disclosed above. The resulting electrochromic device showed very low transmission in most of the visible range when the applied potential was set at 1.9 V (FIG. 7). The very low transmission is comparable to that previously reported by using other approaches such as double layered working electrode and counter electrodes, or through two working electrodes and two counter electrodes.

    [0179] Therefore, multi-EC composition-based devices appear also to be very promising for effective blocking of the whole visible radiation in smart windows.

    REFERENCES CITED IN THE APPLICATION

    [0180] GB1310813;

    [0181] R. J. Mortimer et al., Quantification of colour stimuli through the calculation of CIE chromaticity coordinates and luminance data for application to in situ colorimetry studies of electrochromic materials, Displays 2013, 32, 35-44; and

    [0182] McLaughlin M. et al., The Gelation of Poly(Vinyl Alcohol) with Na.sub.2B.sub.4O.sub.7.10H.sub.2O: Killing Slime, 1997, J. Chem. Educ. 47, 97-99.