COMPOSITIONS COMPRISING N-NONANOIC ACID ESTERS OF XYLITAN AND/OR SORBITAN

Abstract

Compositions are made with n-nonanoic acid esters of xylitan and/or sorbitan. A method to produce these compositions is developed. Further formulations are prepared with the compositions, and a method of improved dishwashing with the compositions is developed.

Claims

1. An anhydro sugar alcohol n-nonanoic acid ester composition, comprising: A) an anhydro sugar alcohol, B) an anhydro sugar alcohol mono n-nonanoic ester, and C) an anhydro sugar alcohol di n-nonanoic ester, wherein the anhydro sugar alcohol is at least one selected from the group consisting of sorbitan and xylitan.

2. The anhydro sugar alcohol n-nonanoic acid ester composition as claimed in claim 1, further comprising: D) n anhydro sugar alcohol tri n-nonanoic ester, and/or E) an anhydro sugar alcohol tetra n-nonanoic ester.

3. The anhydro alcohol n-nonanoic acid ester composition as claimed in claim 1, further comprising: F) free n-nonanoic acid.

4. The anhydro sugar alcohol n-nonanoic acid ester composition as claimed in claim 1, wherein the anhydro sugar alcohol n-nonanoic acid ester has an average degree of esterification of 0.7 to 4.0.

5. The anhydro sugar alcohol n-nonanoic acid ester composition as claimed in claim 1, wherein the anhydro sugar alcohol n-nonanoic acid ester has a hydroxyl number of 50 to 600 mg KOH/g.

6. The anhydro sugar alcohol n-nonanoic acid ester composition as claimed in claim 1, wherein the anhydro sugar alcohol n-nonanoic acid ester has an acid value of 0.1 to 40 mg KOH/g.

7. The anhydro sugar alcohol n-nonanoic acid ester composition as claimed in claim 1, wherein the anhydro sugar alcohol n-nonanoic acid ester has a saponification value of 100 to 350 KOH/g.

8. The anhydro sugar alcohol n-nonanoic acid ester composition as claimed in claim 1, wherein the anhydro sugar alcohol n-nonanoic acid ester composition contains sorbitol n-nonanoic esters and/or xylitol n-nonanoic esters and a weight ratio of anhydro sugar alcohols to their corresponding sugar alcohols in the anhydro sugar alcohol n-nonanoic acid ester composition is greater than 60 to 40.

9. A method for the production of an anhydro sugar alcohol n-nonanoic acid ester composition, wherein the anhydro sugar alcohol is at least one selected from the group consisting of sorbitan and xylitan, comprising: I) providing sorbitol and/or xylitol, II) dehydrating the sorbitol and/or xylitol to sorbitan and/or xylitan, III) esterifying the sorbitan and/or xylitan with n-nonanoic acid, and optionally IV) isolating a formed anhydro sugar alcohol n-nonanoic acid ester composition from III).

10. A formulation, comprising the anhydro sugar alcohol n-nonanoic acid ester composition as claimed in claim 1, wherein the formulation comprises from 0.01% by weight to 10% by weight of the anhydro sugar alcohol n-nonanoic acid ester composition based on the total formulation.

11. The formulation according to claim 10, further comprising a surfactant.

12. A method of preventing and/or reducing deposits on dishes, glasses and cutlery from dishwashing processes, comprising: treating dishes, lasses and cutlery with an aqueous composition, comprising the anhydro sugar alcohol n-nonanoic acid ester composition as claimed in claim 1.

14. The anhydro sugar alcohol n-nonanoic acid ester composition as claimed in claim 1, wherein the anhydro sugar alcohol n-nonanoic acid ester has an average degree of esterification of 1.0 to 2.0.

15. The anhydro sugar alcohol n-nonanoic acid ester composition as claimed in claim 1, wherein the anhydro sugar alcohol n-nonanoic acid ester has a hydroxyl number of 100 to 550 mg KOH/g.

16. The anhydro sugar alcohol n-nonanoic acid ester composition as claimed in claim 1, wherein the anhydro sugar alcohol n-nonanoic acid ester has a hydroxyl number of 150 to 500 mg KOH/g.

17. The anhydro sugar alcohol n-nonanoic acid ester composition as claimed in claim 1, wherein the anhydro sugar alcohol n-nonanoic acid ester has an acid value of 0.5 to 30 mg KOH/g.

18. The anhydro sugar alcohol n-nonanoic acid ester composition as claimed in claim 1, wherein the anhydro sugar alcohol n-nonanoic acid ester has an acid value of 1 to 20 mg KOH/g.

19. The anhydro sugar alcohol n-nonanoic acid ester composition as claimed in claim 1, wherein the anhydro sugar alcohol n-nonanoic acid ester has a saponification value of 125 to 300 mg KOH/g.

20. The anhydro sugar alcohol n-nonanoic acid ester composition as claimed in claim 1, wherein the anhydro sugar alcohol n-nonanoic acid ester has a saponification value of 150 to 275 mg KOH/g.

Description

BRIEF DESCRIPTION OF THE FIGURES

[0106] FIG. 1: Cleaning performance results

EXAMPLES

Examples 1a to 1f: Synthesis of n-Nonanoic Acid Esters of Xylitan or Sorbitan (Inventive)

[0107] Xylitol or sorbitol (or aqueous solutions thereof) were initially charged together with n-nonanoic acid and, after the catalyst had been added, the reaction mixture was heated to reaction temperature while stirring at the pressure specified within 1 h, and the water formed was removed continuously until the acid number specified had been attained. Finally, the mixture was filtered through a filter press.

TABLE-US-00001 TABLE 1 Acid Sugar Sugar Pelargonic Pelargonic Pelargonic number of Sugar alcohol alcohol acid acid acid Reaction the product alcohol m [g] n [mol] m/g n [mol] Equiv. Catalyst conditions [mg KOH/g] 1a Xylitol 290.1 1.91 467.6 2.96 1.55 3.7 g H.sub.3PO.sub.4 230? C., 7.9 and 6.6 g 1 atm NaOH 1b Xylitol 290.0 1.91 392.1 2.48 1.30 0.8 g para- 160? C., 5.7 toluenesulfonic 1 atm acid 1c Xylitol 275.0 1.81 486.2 3.07 1.70 19.4 g K.sub.2CO.sub.3 180? C., 7.1 50 mbar 1d Sorbitol 390.5 1.50 368.0 2.33 1.55 2.9 g H.sub.3PO.sub.4 230? C., 8.6 (70% aqueous and 5.0 g 1 atm solution) NaOH 1e Sorbitol 389.7 1.50 308.0 1.95 1.30 0.6 g para- 160? C., 5.6 (70% aqueous toluenesulfonic 1 atm solution) acid 1f Sorbitol 370.2 1.42 382.6 2.42 1.70 15.3 g K.sub.2CO.sub.3 180? C., 6.9 (70% aqueous 50 mbar solution)

Example 1g: Synthesis of a n-Octanoic/n-Decanoic Acid Ester of Sorbitan (Non-Inventive)

[0108] This product was synthesized as an analogue of example 1d by only exchanging the pelargonic acid by a 75:25 (w/w) mixture of caprylic acid and capric acid. The acid number of the product was analyzed to be 13.4 mg KOH/g.

Example 2: Odor Panel

[0109] The products of the examples 1d and 1g were compared in an odor panel test according to the state of the art. A group consisting of 7 experienced testers, which were qualified by a triangle test procedure before, smelled at 30 ml of both products, which were previously stored for 12 hours in a closed 100 ml brown wide neck glass bottle. The odor was evaluated by the 7 testers based on a rating scale from 1 (good) over 2 (acceptable) to 3 (poor).

[0110] As a result of this test, the product of example 1d received an average panel rating of 1.43 and the product of example 1g received an average panel rating of 2.14.

Example 3

[0111] This example demonstrates the cleaning enhancing effect of composition from Example 1f compared to composition described in example 1g when used in formulations of household cleaners.

[0112] Exemplary formulations described in the table 1 have been prepared according to the following protocol. Initially, a measured amount of water was introduced into a glass beaker of a suitable size. Subsequently, further constituents were added at room temperature and under vigorous stirring. The ingredients were added in no specific or uniform sequence as the order of addition to the solution was not critical. Finally, any remaining amount of water was introduced to ensure desired concentration of ingredients. All ingredients were mixed using a magnetic stirrer and pH of the solution was adjusted to 8.0 by addition of citric acid. The mixture was then stirred for 5 minutes to ensure a homogenous solution. The exemplary compositions were easily pourable and stable at room temperature for extended period.

[0113] According to the above-described method, three formulations were prepared (table 1): [0114] Reference formulation 1, that was subsequently used as a control formulation to evaluate effect of tested cleaning boosting additives [0115] Reference formulation 2, that contained ingredients of the Reference formulation 1 and a benchmark cleaning booster, composition described in example 1g, [0116] Test formulation 1, that contained ingredients of the Reference formulation 1 and the object of the invention, composition from Example 1f Table 1: Compositions of test formulation 1 and reference formulations evaluated in cleaning performance tests.

TABLE-US-00002 TABLE 1 Compositions of test formulation 1 and reference formulations evaluated in cleaning performance tests. Reference Reference Test formulation formulation formulation 1/% 2/% 1/% Composition from 0.75 example 1g Composition from 0.75 example 1f Rewoferm RL 100 5.00 5.00 5.00 Sodium carbonate 1.00 1.00 1.00 Sodium Citrate 3.00 3.00 3.00 Phenoxyethanol 0.20 0.20 0.20 Citric acid to achieve to achieve to achieve pH 8.0 pH 8.0 pH 8.0 Water to 100 to 100 to 100

[0117] Subsequently, cleaning performance of Test formulation 1 was evaluated against two reference formulations described in table 1. The procedure used for the evaluating the cleaning performance is described in the following test protocol.

[0118] Cleaning performance test was conducted according to the internal test methodology, which was adapted from the recommendation of German Cosmetic, Toiletry, Perfumery and Detergent Association (IKW): IKW Recommendation for the Quality Assessment of the Product Performance of All-Purpose Cleaners 2014 (IKW Test Protocol). The principle of the test was to evaluate the cleaning power of tested formulations by assessing their efficacy in removal of stubborn soil deposited on melamine tiles. White, melamine tiles covered with black, stubborn soil composed of mixture of fat and carbon black (here called Test Monitors) were purchased from Center for Test materials B.V. (available under the name DM-40 Tile). To ensure high reproducibility of the results, all Test Monitors belonged to the same production batch and were conditioned prior to use for 24 hours at 20? C. inside a climatic chamber.

[0119] To evaluate cleaning performance of the prepared formulations, Test Monitors were placed in a TQC Sheen washability tester (model AB5000) and locked in a position. One Test Monitor was placed in the Washability Tester at the time, but it was ensured that for each of the cleaning formulations, the test was conducted at least once at each of the four tracks of the Washability Tester. Subsequently, dry, 9 cm by 4.5 cm sponges were first moistened with tap water, and water excess was wrung out from sponges. Thereafter, 10 g of the test solution was loaded onto the sponge and sponge was attached to the cleaning arm of the Washability Tester. Washability Tester was then actuated and controlled to provide 10 cleaning cycles (so 20 linear strokes) over the Test Monitor. The speed of the strokes for 20 cycles per minute and the test was performed at room temperature. After 10 cleaning cycles were completed, the Test Monitor was removed from the Sheen tester, rinsed with tap water, and allowed to dry. The test was repeated several times to provide 5 replicates for each tested composition.

[0120] The treated Test Monitors were visually evaluated by five panelists who were asked to rate the cleaning efficacy achieved by each of the compositions. Panellists ranked the cleaning efficacy on a scale from 0 to 10, with 0 representing no observed cleaning and 10 representing a complete removal of the stain. For comparative purposes, each of the panelists was provided with a new, soiled Test Monitor that represented no cleaning as well as with a fully cleaned Test Monitor that represented the score of 10. Additionally, the panelists were provided with the evaluation template according to IKW Test Protocol to enable more accurate assessment of cleanness. The scores were summed and averaged for each of the tested composition and the results are reported in table 2.

TABLE-US-00003 TABLE 2 Cleaning performance results for tested compositions (average cleaning score, 0 - no cleaning, 10 - complete cleaning, and photographs of exemplary Test Monitors). Reference Reference Test formulation 1 formulation 2 formulation 1 Average cleaning 4.60 5.84 7.40 score

[0121] As is readily evident from the results reported in the table 2, the composition containing object of invention delivers superior cleaning performance results to both benchmarks. Test formulation 1 by far exceeds cleaning results achieved by Reference formulation 1 that does not contain any cleaning booster as well as it delivers much better cleaning than Reference formulation 2, so composition containing the benchmark cleaning booster.

[0122] FIG. 1 clearly shows the visible result.

Example 4

[0123] This example demonstrates superior properties of composition from Example 1f when compared to benchmark surfactants such as fatty alcohol ethoxylates in terms of fragrance remaining on rinsed dishes.

[0124] The panel test was performed according to the following protocol:

[0125] Initially, two test solutions were prepared. Benchmark Solution contained 0.5 wt. %. of an exemplary fatty alcohol ethoxylate in tap water. Test Solution contained 0.5 wt. %. of composition from Example 1f in tap water. Thereafter, two sets of clean, ceramic plates were used to perform tests. Plates from the first set were immersed in Benchmark Solution and the plates from the second set in Test Solution. Subsequently, plates were allowed to drain and were subjected to a blind test evaluation by a team of 5 panelists. Each of the panelists received two plates, one that had previously been immersed in Benchmark Solution and the second that had been immersed in Test Solution. The panelists were asked to assess the smell of both plates and describe them according to the following methodology: [0126] Smell of the plates was assessed on the scale from ?1 to +1, with ?1 meaning unpleasant, 0neutral, +1pleasant [0127] Panellists were also allowed to share additional comments regarding the recognized smell.

[0128] As the result, 4 out of 5 panelists described the smell of the plates immersed in Benchmark Solution as unpleasant and a further 1 panelist described it as neutral. Moreover, 3 panelists described the smell of the plates immersed in the Test Solution as pleasant and further 2 panelists described it as neutral. In addition, the smell of plates previously immersed in composition from example 1f solution was described as reminding the smell of the coconut by 3 of the panelists, and 4 panelists described the smell of the plates immersed in Benchmark Solution as either artificial or chemical. Such a scent can be considered a common characteristic of fatty alcohol ethoxylate surfactants.

TABLE-US-00004 Composition from Benchmark Solution example 1f solution Panel Person 1 ?1 1 Panel Person 2 0 1 Panel Person 3 ?1 0 Panel Person 4 ?1 0 Panel Person 5 ?1 1

[0129] Moreover, the same test was repeated using this time spoons made from stainless steel. Thereafter, two sets of clean, spoons were used to perform tests. Spoons from the first set were immersed in Benchmark Solution and the spoons from the second set in Composition from Example 1f Solution. Subsequently, the spoons were allowed to drain and were subjected to a blind test evaluation by a team of 5 panelists. Each of the panelists received two spoons, one that had previously been immersed in Benchmark Solution and the second that had been immersed in Composition from Example 1f Solution. The panelists were asked to assess the taste of both spoons and describe them according to the following methodology: [0130] Taste of the spoons s was assessed on the scale from ?1 to +1, with ?1 meaning unpleasant, 0neutral, +1pleasant

[0131] As the result, 3 out of 5 panelists described the taste of the spoons immersed in Benchmark Solution as neutral and a further 2 panelists described it as unpleasant. Moreover, 3 panelists described the taste of the spoons immersed in the Test Solution as neutral and further 2 panelists described it as pleasant.

TABLE-US-00005 Composition from Benchmark Solution example 1f solution Panel Person 1 0 1 Panel Person 2 0 1 Panel Person 3 ?1 0 Panel Person 4 0 0 Panel Person 5 ?1 0

[0132] As evident from the presented example, the object of the invention allows to formulate products with purpose of cleaning or rinsing dishes without the risk of leaving unpleasant scent on the dishes. Instead, the dishes may have a slight scent of coconut that is assessed as pleasant by most panelists.

Example Formulations

[0133]

TABLE-US-00006 Recipes 1a, 1b, 1c and 1d: Shower cream 1a 1b 1c 1d Water to 100.0% to 100.0% to 100.0% to 100.0% Composition from Example 1a 1.5% Composition from Example 1c 1.5% Composition from Example 1d 1.5% Composition from Example 1f 1.5% Sodium Laureth Sulfate (Texapon NSO. BASF. 28%) 25.0% 25.0% 25.0% 25.0% Coco-Glucoside (Plantacare 818 UP. BASF. 51%) 8.0% 8.0% 8.0% 8.0% Cocamidopropyl Betaine (TEGO? Betain F 50. Evonik. 8.0% 8.0% 8.0% 8.0% 38%) PEG-18 Glyceryl Oleate/Cocoate (ANTIL? 171. Evonik) 1.5% 1.5% 1.5% 1.5% Sorbitan Sesquicaprylate (ANTIL? Soft SC. Evonik) 0.8% 0.8% 0.8% 0.8% Glyceryl Oleate (TEGIN? O V. Evonik) 0.8% 0.8% 0.8% 0.8% Perfume Spicy Herbs (IFF) 0.2% 0.2% 0.2% 0.2% Polyglyceryl-4 Caprate (TEGOSOFT? PC 41. Evonik) 0.6% 0.6% 0.6% 0.6% Helianthus Annuus Seed Oil (AEC Sunflower Oil. A & E 0.2% 0.2% 0.2% 0.2% Connock. Perfumery & Cosmetics Ltd.) Linalool (Lipofresh. Lipo Chemicals. Inc.) 0.1% 0.1% 0.1% 0.1% Coumarin (Rhodiascent extra pure. Solvay Rhodia) 0.1% 0.1% 0.1% 0.1% Glycerol (Glycerol EP. vegetable. Spiga Nord) 0.4% 0.4% 0.4% 0.4% Hydroxypropyl Methylcellulose (TEGOCEL? HPM 50. 0.2% 0.2% 0.2% 0.2% Evonik) Glycol Distearate (TEGIN? G 1100 Pellets. Evonik) 0.4% 0.4% 0.4% 0.4% Sodium Chloride 0.5% 0.5% 0.5% 0.5% Hydroxypropyl Guar Hydroxypropyltrimonium Chloride 0.2% 0.2% 0.2% 0.2% (Jaguar C-162. Solvay Rhodia) dermofeel TOCO 70 non GMO 0.1% 0.1% 0.1% 0.1% Disodium EDTA (Dissolvine NA-2-P. AkzoNobel) 0.1% 0.1% 0.1% 0.1% Preservative q.s. q.s. q.s. q.s. Citric Acid to pH 5.2 to pH 5.2 to pH 5.2 to pH 5.2

TABLE-US-00007 Recipes 2a, 2b, 2c and 2d: Body shampoo 2a 2b 2c 2d Phase Composition from Example 1a 0.5% A Composition from Example 1c 0.5% Composition from Example 1d 0.5% Composition from Example 1f 0.5% Lavandula Angustifolia (Lavender) Oil (AEC 0.2% 0.2% 0.2% 0.2% Lavender Oil. A&E Connock Ltd.) Perfume 0.1% 0.1% 0.1% 0.1% Phase Sodium Cocoamphoacetate (REWOTERIC? AM 10.0% 10.0% 10.0% 10.0% B C. Evonik. 32%) Phase Water to 100.0% to 100.0% to 100.0% to 100.0% C Xanthan Gum (Keltrol CG-SFT. CP Kelco) 1.2% 1.2% 1.2% 1.2% Phase Sodium Lauroyl Methyl Isethionate (Iselux. 4.5% 4.5% 4.5% 4.5% D Innospec Active Chemicals) Capryl/Capramidopropyl Betaine (TEGO? 4.5% 4.5% 4.5% 4.5% Betaine 810. Evonik. 38%) Citric Acid 1.2% 1.2% 1.2% 1.2% Phase Water 10.0% 10.0% 10.0% 10.0% E Polyquaternium-7 (Merquat 550. Nalco) 0.4% 0.4% 0.4% 0.4% Preservative q.s. q.s. q.s. Body cream

TABLE-US-00008 Recipes 3a, 3b, 3c and 3d: Shampoo 3a 3b 3c 3d Phase Composition from Example 1a 3.5% A Composition from Example 1c 3.5% Composition from Example 1d 3.5% Composition from Example 1f 3.5% Isopropyl Myristate (TEGOSOFT? M. 0.2% 0.2% 0.2% 0.2% Evonik) Perfume 0.1% 0.1% 0.1% 0.1% Phase Water to 100.0% to 100.0% to 100.0% to 100.0% B Phase Sodium Lauryl Sulfate (Texapon LS 35. 28.0% 28.0% 28.0% 28.0% C BASF. 30%) Phase Cocamidopropyl Betaine (TEGO? 9.0% 9.0% 9.0% 9.0% D Betain F 50. Evonik. 38%) Phase Cocamide MEA (REWOMID? C 212. 2.0% 2.0% 2.0% 2.0% E Evonik) Xanthan Gum (Keltrol CG-SFT. CP 0.3% 0.3% 0.3% 0.3% Kelco) Water 10.0% 10.0% 10.0% 10.0% Phase Water 10.0% 10.0% 10.0% 10.0% F Polyquaternium-10 (Polymer JR 400. 0.2% 0.2% 0.2% 0.2% Amerchol) Phase Citric Acid to pH 5.0 to pH 5.0 to pH 5.0 to pH 5.0 G Phase Preservative q.s. q.s. q.s. Body H cream

TABLE-US-00009 Recipes 4a, 4b, 4c and 4d: Shampoo Recipes 4a 4b 4c 4d Water to 100.0% to 100.0% to 100.0% to 100.0% Composition from Example 1a 2.5% 2.5% Composition from Example 1c 1.5% 1.5% Composition from Example 1d 2.5% 2.5% Composition from Example 1f 1.5% 1.5% Cocamidopropyl Betaine (TEGO? Betain F 50. 22.0% 22.0% 22.0% 22.0% Evonik. 38%) Lauryl Glucoside (Plantacare 1200 UP. BASF. 50%) 6.0% 6.0% 6.0% 6.0% Sodium Cocoyl Glutamate (Plantapon ACG HC. 1.5% 1.5% 1.5% 1.5% BASF) Sodium Cocoyl Glycinate (Hostapon SG. Clariant) 0.8% 0.8% 0.8% 0.8% Zinc Pyrithione (Microcare ZP. Thor) 0.1% 0.1% 0.1% 0.1% PEG-120 Methyl Glucose Dioleate (ANTIL? 120 0.4% 0.4% 0.4% 0.4% Plus. Evonik) Sodium Chloride 0.5% 0.5% 0.5% 0.5% Isostearamide MIPA; Glyceryl Laurate (ANTIL? SPA 0.5% 0.5% 0.5% 0.5% 80. Evonik) Xanthan Gum (Keltrol CG-SFT. CP Kelco) 0.3% 0.3% 0.3% 0.3% Hydroxypropyl Guar Hydroxypropyltrimonium 0.3% 0.3% 0.3% 0.3% Chloride (Jaguar C-162. Solvay Rhodia) Quaternium-80 (ABIL? Quat 3272. Evonik) 0.4% 0.4% 0.4% 0.4% Palmitamidopropyltrimonium Chloride (VARISOFT? 0.4% 0.4% 0.4% 0.4% PATC. Evonik) Argania Spinosa Oil (Argan Oil. DSM Nutritional 0.1% 0.1% 0.1% 0.1% Products Ltd.) Glycerol (Glycerol EP. vegetable. Spiga Nord) 0.6% 0.6% 0.6% 0.6% Tetrasodium EDTA (Versene 100. The Dow 0.1% 0.1% 0.1% 0.1% Chemical Company) Caffeine (Merck KGaA/EMD Chemicals. Inc.) 0.1% 0.1% 0.1% 0.1% Hydrolyzed Wheat Protein (Gluadin WLM. BASF) 0.1% 0.1% 0.1% 0.1% Limonene (Dipentene No. 122. Hercules Inc.) 0.1% 0.1% 0.1% 0.1% Citric Acid to pH 5.5 to pH 5.5 to pH 5.5 to pH 5.5 Sodium Phytate; Aqua; Alcohol (dermofeel? PA-3; 0.1% 0.1% 0.1% Evonik Dr. Straetmans GmbH (PA-3) Perfume 0.2% Preservative q.s. Aqua; Sodium Levulinate; Sodium Benzoate 1.2% 1.2% 1.2% (Verstatil? BL non GMO; Evonik Dr. Straetmans GmbH)

TABLE-US-00010 Recipes 5a, 5b, 5c and 5d: Liquid Soap 5a 5b 5c 5d Water to 100% to 100% to 100% to 100% Glycerol (Glycerol EP. vegetable. Spiga Nord) 4.0% 4.0% 4.0% 4.0% Alcohol 4.0% 4.0% 4.0% 4.0% Sodium Coco-Sulfate (Texapon HC G. BASF) 3.0% 3.0% 3.0% 3.0% Lauryl Glucoside (Plantacare 1200 UP. BASF. 50%) 6.0% 6.0% 6.0% 6.0% Composition from Example 1a 0.1% Composition from Example 1c 0.1% Composition from Example 1d 0.1% Composition from Example 1f 0.1% Xanthan Gum (Keltrol CG-SFT. CP Kelco) 1.5% 1.5% 1.5% 1.5% Mangifera Indica (Mango) Fruit Extract (Mango 0.5% 0.5% 0.5% 0.5% Extract. Draco Natural Products) Limonene (Dipentene No. 122. Hercules Inc.) 0.1% 0.1% 0.1% 0.1% Linalool (Lipofresh. Lipo Chemicals. Inc.) 0.1% 0.1% 0.1% 0.1% Citric Acid to pH 4.9 to pH 4.9 to pH 4.9 to pH 4.9 Preservative q.s. q.s. q.s. q.s. Dyes Body q.s. q.s. q.s. cream

TABLE-US-00011 Recipes 6a, 6b, 6c and 6d: Cream Soap 6a 6b 6c 6d Water to 100% to 100% to 100% to 100% Propylene Glycol (Euxyl K 320. Sch?lke & Mayr 2.0% 2.0% 2.0% 2.0% GmbH) Coco-Glucoside (Plantacare 818 UP. BASF. 51%) 10.0% 10.0% 10.0% 10.0% Glycerol (Glycerol EP. vegetable. Spiga Nord) 5.0% 5.0% 5.0% 5.0% Composition from Example 1a 2.5% Composition from Example 1c 2.5% Composition from Example 1d 2.5% Composition from Example 1f 2.5% Disodium Cocoyl Glutamate (Planatpon ACG LC. 2.5% 2.5% 2.5% 2.5% BASF) Xanthan Gum (Keltrol CG-SFT. CP Kelco) 1.2% 1.2% 1.2% 1.2% Stearic Acid (Pristerene 4922. Croda Europe. Ltd.) 1.2% 1.2% 1.2% 1.2% Citric Acid to pH 5.5 to pH 5.5 to pH 5.5 to pH 5.5 Olea Europaea Fruit Oil (Cropure Olive. Croda 0.2% 0.2% 0.2% 0.2% Europe. Ltd.) Glyceryl Oleate (TEGIN ? O V. Evonik) 1.0% 1.0% 1.0% 1.0% Sodium Cocoyl Glutamate (Plantapon ACG HC. 0.8% 0.8% 0.8% 0.8% BASF) Tetrasodium EDTA (Versene 100. The Dow 0.2% 0.2% 0.2% 0.2% Chemical Company) Perfume 0.1% 0.1% 0.1% 0.1% Preservative q.s. q.s. q.s. q.s. Dyes q.s. q.s. q.s. Body cream

TABLE-US-00012 Recipes 7a, 7b, 7c and 7d: Oil Bath 7a 7b 7c 7d Water to 100.0% to 100.0% to 100.0% to 100.0% Glycine Soja Oil (Cropure Soybean. Croda Europe. 20.0% 20.0% 20.0% 20.0% Ltd.) Composition from Example 1a 12.0% Composition from Example 1c 12.0% Composition from Example 1d 12.0% Composition from Example 1f 12.0% Polyglyceryl-3 Palmitate (Dermofeel? PP. Evonik 4.5% 4.5% 4.5% 4.5% Dr. Straetmans) Glyceryl Caprylate (Dermosoft? GMCY. Evonik Dr. 3.0% 3.0% 3.0% 3.0% Straetmans) Simmondsia Chinensis Seed Oil (AEC Jojoba Oil 1.2% 1.2% 1.2% 1.2% Refined. A & E Connock. Perfumery & Cosmetics Ltd.) Prunus Amygdalus Dulcis (Sweet Almond) Oil 1.0% 1.0% 1.0% 1.0% (Cropure Almond. Croda Europe. Ltd.) Triticum Vulgare Germ Oil (Cropure Wheatgerm. 0.5% 0.5% 0.5% 0.5% Croda Europe. Ltd.) Tocopherol (Euxyl K 700. Sch?lke & Mayr GmbH) 0.2% 0.2% 0.2% 0.2% Limonene (Dipentene No. 122. Hercules Inc.) 0.1% 0.1% 0.1% 0.1% Citral 0.1% 0.1% 0.1% 0.1% Preservative q.s. q.s. q.s. q.s. Dyes q.s. q.s. q.s. q.s.

TABLE-US-00013 Recipes 8a, 8b, 8c and 8d: Micellar Water for make-up removal 8a 8b 8c 8d Water to 100.0% to 100.0% to 100.0% to 100.0% Perfume 0.1% 0.1% 0.1% 0.1% Composition from Example 1a 2.0% Composition from Example 1c 2.0% Composition from Example 1d 2.0% Composition from Example 1f 2.0% Capryl/Capramidopropyl Betaine (TEGO? Betain 1.3% 1.3% 1.3% 1.3% 810. Evonik. 38%) Polyglyceryl-6 Caprylate; Polyglyceryl-3 Cocoate; 1.0% 1.0% 1.0% 1.0% Polyglyceryl-4 Caprate; Polyglyceryl-6 Ricinoleate (TEGO? Solve 61. Evonik) Betaine (TEGO? Natural Betaine. Evonik) 2.0% 2.0% 2.0% 2.0% Glycerol (Glycerol EP. vegetable. Spiga Nord) 1.0% 1.0% 1.0% 1.0% Preservative q.s. q.s. q.s. q.s.

TABLE-US-00014 Recipes 9a, 9b, 9c and 9d: Solution for wet wipes Recipe 9a 9b 9c 9d Composition from Example 1a 3.5% Composition from Example 1c 3.5% Composition from Example 1d 3.5% Composition from Example 1f 3.5% Aloe Barbadensis Leaf Extract (Aloe-Con UP 40. 0.2% 0.2% 0.2% 0.2% Florida Food Products Inc.) Isopropyl Myristate (TEGOSOFT? M. Evonik) 0.2% 0.2% 0.2% 0.2% Disodium Cocoamphodiacetate (REWOTERIC? 1.5% 1.5% 1.5% 1.5% AM 2 C NM. Evonik. 39%) Perfume 0.2% 0.2% 0.2% 0.2% Propylene Glycol (Euxyl K 320. Sch?lke & Mayr 2.5% 2.5% 2.5% 2.5% GmbH) Hydrolyzed Silk (Crosilk 10000. Croda Inc.) 0.2% 0.2% 0.2% 0.2% Caprylyl/Capryl Glucoside (Plantacare 810 UP. 1.0% 1.0% 1.0% 1.0% BASF) Water to 100.0% to 100.0% to 100.0% to 100.0% Citric Acid to pH 5.0 to pH 5.0 to pH 5.0 to pH 5.0 Phenoxyethanol (S&M Phenoxyethanol. Sch?lke & 0.5% 0.5% 0.5% 0.5% Mayr GmbH) Dehydroacetic Acid (Unisept DHA (Universal 0.1% 0.1% 0.1% 0.1% Preserv-A-Chem. Inc.) Sodium Benzoate (Euxyl K 712. Sch?lke & Mayr 0.4% 0.4% 0.4% 0.4% GmbH) Salicylic Acid (Salicylic acid nat.; Evonik Dr. 0.5% 0.5% 0.5% 0.5% Straetmans GmbH)

TABLE-US-00015 Recipes 10a, 10b, 10c and 10d: Antiperspirant deodorant 10a 10b 10c 10d Phase Composition from Example 1a 4.0% A Composition from Example 1c 4.0% Composition from Example 1d 4.0% Composition from Example 1f 4.0% Dicaprylyl Ether (Cetiol OE. BASF) 0.3% 0.3% 0.3% 0.3% Geraniol (Nerol 800. International Flavors 0.1% 0.1% 0.1% 0.1% & Fragrances Inc.) Linalool (Lipofresh. Lipo Chemicals. Inc.) 0.1% 0.1% 0.1% 0.1% Perfume 0.1% 0.1% 0.1% 0.1% Phase Propylene Glycol (Euxyl K 320. Sch?lke & 1.0% 1.0% 1.0% 1.0% B Mayr GmbH) Butylene Glycol (Oxea Corparation) 0.2% 0.2% 0.2% 0.2% Water 5.0% 5.0% 5.0% 5.0% Palmitamidopropyltrimonium Chloride 1.0% 1.0% 1.0% 1.0% (VARISOFT? PATC. Evonik) Phase Water 50.0% 50.0% 50.0% 50.0% C Hydroxethyl Ethylcellulose (Structure Cel 0.8% 0.8% 0.8% 0.8% 4400 E. AkzoNobel) Sodium Hydroxide (10% in water) 0.3% 0.3% 0.3% 0.3% Phase Aluminium Chlorohydrate (Locron L. 15.0% 15.0% 15.0% 15.0% D Clariant) Phase Preservative q.s. q.s. q.s. q.s. E Water to 100.0% to 100.0% to 100.0% to 100.0%

TABLE-US-00016 Recipes 11a, 11b, 11c and 11d: Mouthwash 11a 11b 11c 11d Composition from Example 1a 0.4% Composition from Example 1c 0.4% Composition from Example 1d 0.4% Composition from Example 1f 0.4% Glycolipids (Rheance One. Evonik) 0.2% 0.2% 0.2% 0.2% Flavor 0.2% 0.2% 0.2% 0.2% Water to 100.0% to 100.0% to 100.0% to 100.0% Sorbitol (Karion FP Liquid. Merck) 3.0% 3.0% 3.0% 3.0% Preservative q.s. q.s. q.s. q.s. Dyes q.s. q.s. q.s. q.s.

TABLE-US-00017 Recipes 12a, 12b, 12c and 12d: Toothpaste 12a 12b 12c 12d A Sorbitol (Karion FP Liquid. Merck) 50.0% 50.0% 50.0% 50.0% Water to 100.0% to 100.0% to 100.0% to 100.0% Sodium Carboxymethylcelluslose (Blanose 1.2% 1.2% 1.2% 1.2% 7MXF. Ashland) B Sodium Saccharine (Sigma Aldrich) 0.1% 0.1% 0.1% 0.1% Sodium Fluoride (Sigma Aldrich) 0.1% 0.1% 0.1% 0.1% C Titanium Dioxide (Caesar & Loretz) 0.4% 0.4% 0.4% 0.4% Hydrated Silica (Zeodent? 113. Evonik) 14.0% 14.0% 14.0% 14.0% Hydrated Silica (Zeodent? 165. Evonik) 8.0% 8.0% 8.0% 8.0% D Flavor oil 1.0% 1.0% 1.0% 1.0% E Glyceryl Caprylate (dermosoft? GMCY. 0.3% 0.3% 0.3% 0.3% Evonik) Composition from Example 1a 3.5% Composition from Example 1c 3.5% Composition from Example 1d 3.5% Composition from Example 1f 3.5%

TABLE-US-00018 Recipes 13a, 13b, 13c and 13d: Kitchen Cleaning Spray Ingredient 13a 13b 13c 13d REWOTERIC? AM V 0.5% 0.5% 0.5% 0.5% Composition from Example 1a 1.0% Composition from Example 1c 1.0% Composition from Example 1d 1.0% Composition from Example 1f 1.0% TOMAKLEEN? G-14 2.0% 2.0% 2.0% 2.0% Water (Dye. Perfume) 89.5% 89.5% 89.5% 89.5% Chelating Agent. GLDA 3.0% 3.0% 3.0% 3.0% Triethanolamine 4.0% 4.0% 4.0% 4.0%

TABLE-US-00019 Recipes 14a, 14b, 14c and 14d: Extra Mild Dish Wash Foam Ingredient 14a 14b 14c 14d C10-16 Alkylpolyglucoside. 50% 10.0% 10.0% 10.0% 10.0% Xanthan Gum 0.1% 0.1% 0.1% 0.1% Glycerin 2.0% 2.0% 2.0% 2.0% Water 76.9% 76.9% 76.9% 76.9% Composition from Example 1a 1.0% Composition from Example 1c 1.0% Composition from Example 1d 1.0% Composition from Example 1f 1.0% REWOFERM? SL ONE 2.0% 2.0% 2.0% 2.0% REWOPOL? SB CS 50 5.0% 5.0% 5.0% 5.0% TEGO? Betain C 60 3.0% 3.0% 3.0% 3.0% Preservative qs. qs. qs. qs.

TABLE-US-00020 Recipes 15a, 15b, 15c and 15d: Automatic Rinse Aid for Direct Use 1 Ingredient 15a 15b 15c 15d TEGOTENS? EC 11 5.0% 5.0% 5.0% 5.0% Composition from Example 1a 5.0% Composition from Example 1c 5.0% Composition from Example 1d 5.0% Composition from Example 1f 5.0% Citric acid monohydrate 5.0% 5.0% 5.0% 5.0% Water (Dye. Perfume) 85.0% 85.0% 85.0% 85.0%

TABLE-US-00021 Recipes 16a, 16b, 16c and 16d: Automatic Rinse Aid for Direct Use 2 Ingredient 16a 16b 16c 16d Citric acid monohydrate 5.0% 5.0% 5.0% 5.0% Sodium Cumene Sulfonate. 92% 1.5% 1.5% 1.5% 1.5% Water (Dye. Perfume) 83.5% 83.5% 83.5% 83.5% TEGOTENS? EC 11 6.0% 6.0% 6.0% 6.0% Composition from Example 1a 4.0% Composition from Example 1c 4.0% Composition from Example 1d 4.0% Composition from Example 1f 4.0%

TABLE-US-00022 Recipes 17a, 17b, 17c and 17d: Automatic Rinse Aid for Direct Use 3 Ingredient 17a 17b 17c 17d Citric acid monohydrate 5.0% 5.0% 5.0% 5.0% Sodium Cumene Sulfonate. 92% 1.5% 1.5% 1.5% 1.5% Water (Dye. Perfume) 83.5% 83.5% 83.5% 83.5% TEGOTENS? EC 11 7.0% 7.0% 7.0% 7.0% Composition from Example 1a 3.0% Composition from Example 1c 3.0% Composition from Example 1d 3.0% Composition from Example 1f 3.0%

TABLE-US-00023 Recipes 18a, 18b, 18c and 18d: Glass Cleaner With Optimized Antifogging Efficiency Ingredient 18a 18b 18c 18d REWOPOL? TS 35 1.0% 1.0% 1.0% 1.0% Composition from Example 1a 0.2% Composition from Example 1c 0.2% Composition from Example 1d 0.2% Composition from Example 1f 0.2% Isopropanol 15.0% 15.0% 15.0% 15.0% Chelating Agent. M 2.0% 2.0% 2.0% 2.0% Water (Dye. Perfume) 81.8% 81.8% 81.8% 81.8%

TABLE-US-00024 Recipes 19a, 19b, 19c and 19d: Oven Cleanser for Smoking Chamber Ingredient 19a 19b 19c 19d Water 77.6% 77.6% 77.6% 77.6% Trilon A liquid 8.0% 8.0% 8.0% 8.0% Sodium carbonate 6.0% 6.0% 6.0% 6.0% REWOTERIC? AM KSF 40 5.0% 5.0% 5.0% 5.0% Laureth-6 1.2% 1.2% 1.2% 1.2% Composition from Example 1a 1.2% Composition from Example 1c 1.2% Composition from Example 1d 1.2% Composition from Example 1f 1.2% DOWANOL DPnB 1.0% 1.0% 1.0% 1.0%

TABLE-US-00025 Recipes 20a, 20b, 20c and 20d: All Purpose Cleanser (Microemulsion) Ingredient 20a 20b 20c 20d Water 73.0% 73.0% 73.0% 73.0% TEGOTENS? AM VSF 6.0% 6.0% 6.0% 6.0% Composition from Example 1a 2.0% Composition from Example 1c 2.0% Composition from Example 1d 2.0% Composition from Example 1f 2.0% REWOPOL? D 510 NC 5.0% 5.0% 5.0% 5.0% Undeceth-6 3.0% 3.0% 3.0% 3.0% Potassium hydroxide. 50% 5.0% 5.0% 5.0% 5.0% Chelating Agent. MGDA 6.0% 6.0% 6.0% 6.0%

TABLE-US-00026 Recipes 21a, 21b, 21c and 21d: Low Foaming Hard Surface Degreaser Ingredient 21a 21b 21c 21d C9-11 FATTY ALCOHOL 2.0% 2.0% 2.0% 2.0% ETHOXYLATE - 8 MOLES OF EO Composition from Example 1a 1.0% Composition from Example 1c 1.0% Composition from Example 1d 1.0% Composition from Example 1f 1.0% TEGOTENS? G 826 C 4.0% 4.0% 4.0% 4.0% Chelating Agent. MGDA 7.5% 7.5% 7.5% 7.5% Water (Dye. Perfume) 85.5% 85.5% 85.5% 85.5%

TABLE-US-00027 Recipes 22a, 22b, 22c and 22d: Low Foaming Hard Surface Degreaser (101630-23) Ingredient 22a 22b 22c 22d C9-11 FATTY ALCOHOL 2.0% 2.0% 2.0% 2.0% ETHOXYLATE - 8 MOLES OF EO Composition from Example 1a 1.0% Composition from Example 1c 1.0% Composition from Example 1d 1.0% Composition from Example 1f 1.0% TEGOTENS? G 826 C 4.0% 4.0% 4.0% 4.0% Chelating Agent. MGDA 7.5% 7.5% 7.5% 7.5% Water (Dye. Perfume) 85.5% 85.5% 85.5% 85.5%

TABLE-US-00028 Recipes 23a, 23b, 23c and 23d: Foaming Hard Surface Degreaser 1 Ingredient 23a 23b 23c 23d C9-11 FATTY ALCOHOL 2.0% 2.0% 2.0% 2.0% ETHOXYLATE - 8 MOLES OF EO TEGOTENS? AM VSF 6.0% 6.0% 6.0% 6.0% Composition from Example 1a 1.0% Composition from Example 1c 1.0% Composition from Example 1d 1.0% Composition from Example 1f 1.0% Chelating Agent. MGDA 7.5% 7.5% 7.5% 7.5% Water (Dye. Perfume) 83.5% 83.5% 83.5% 83.5%

TABLE-US-00029 Recipes 24a, 24b, 24c and 24d: Foaming Hard Surface Degreaser 2 Ingredient 24a 24b 24c 24d C9-11 FATTY ALCOHOL 3.0% 3.0% 3.0% 3.0% ETHOXYLATE - 8 MOLES OF EO REWOTERIC? AM KSF 40 2.5% 2.5% 2.5% 2.5% Composition from Example 1a 1.0% Composition from Example 1c 1.0% Composition from Example 1d 1.0% Composition from Example 1f 1.0% Chelating Agent. MGDA 10.0% 10.0% 10.0% 10.0% Water (Dye. Perfume) 83.5% 83.5% 83.5% 83.5%

TABLE-US-00030 Recipes 25a, 25b, 25c and 25d: Low Foaming Hard Surface Degreaser Ingredient 25a 25b 25c 25d Composition from Example 1a 1.0% Composition from Example 1c 1.0% Composition from Example 1d 1.0% Composition from Example 1f 1.0% C8-10 Alkylpolyglucosid 4.0% 4.0% 4.0% 4.0% Sodium C13-17 Alkane Sulfonate. 2.0% 2.0% 2.0% 2.0% 30% Chelating Agent. MGDA 7.5% 7.5% 7.5% 7.5% Water (Dye. Perfume) 85.5% 85.5% 85.5% 85.5%

TABLE-US-00031 Recipes 26a, 26b, 26c and 26d: Hard Surface Degreaser From Renewable Surfactants Ingredient 26a 26b 26c 26d Water 89.3% 89.3% 89.3% 89.3% Chelating Agent. MGDA 4.0% 4.0% 4.0% 4.0% Sodium carbonate 3.0% 3.0% 3.0% 3.0% TEGOTENS? AM VSF 2.4% 2.4% 2.4% 2.4% Laureth-6 0.6% 0.6% 0.6% 0.6% Composition from Example 1a 0.4% Composition from Example 1c 0.4% Composition from Example 1d 0.4% Composition from Example 1f 0.4% TEGO? Polish Additiv Q 70 0.3% 0.3% 0.3% 0.3%

TABLE-US-00032 Recipes 27a, 27b, 27c and 27d: Highly Efficient Floor Cleanser Ingredient 27a 27b 27c 27d Water 89.3% 89.3% 89.3% 89.3% Chelating Agent. MGDA 4.0% 4.0% 4.0% 4.0% Sodium carbonate 3.0% 3.0% 3.0% 3.0% TEGOTENS? AM VSF 2.4% 2.4% 2.4% 2.4% Laureth-6 0.6% 0.6% 0.6% 0.6% Composition from Example 1a 0.4% Composition from Example 1c 0.4% Composition from Example 1d 0.4% Composition from Example 1f 0.4% TEGO? Polish Additiv Q 70 0.3% 0.3% 0.3% 0.3%

TABLE-US-00033 Recipes 28a, 28b, 28c and 28d: Super Natural Wash Lotion for Textile Face Masks Ingredient 28a 28b 28c 28d Xanthan Gum 0.1% 0.1% 0.1% 0.1% Glycerin 2.0% 2.0% 2.0% 2.0% Water 76.9% 76.9% 76.9% 76.9% Composition from Example 1a 1.0% Composition from Example 1c 1.0% Composition from Example 1d 1.0% Composition from Example 1f 1.0% REWOFERM? SL ONE 2.0% 2.0% 2.0% 2.0% REWOPOL? SB CS 50 5.0% 5.0% 5.0% 5.0% C8-10 Alkylpolyglucosid 10.0% 10.0% 10.0% 10.0% TEGO? Betain C 60 3.0% 3.0% 3.0% 3.0% Preservative qs. qs. qs. qs.

TABLE-US-00034 Recipes 29a, 29b, 29c and 29d: Highly Effective Presoaker Ingredient 29a 29b 29c 29d Water 77.5% 77.5% 77.5% 77.5% Chelating Agent. Mgda 8.0% 8.0% 8.0% 8.0% Sodium metasilicate 2.0% 2.0% 2.0% 2.0% Sodium gluconate 2.0% 2.0% 2.0% 2.0% Sodium carbonate 2.0% 2.0% 2.0% 2.0% TEGOTENS? AM VSF 6.5% 6.5% 6.5% 6.5% Undeceth-6 0.6% 0.6% 0.6% 0.6% Composition from Example 1a 0.4% Composition from Example 1c 0.4% Composition from Example 1d 0.4% Composition from Example 1f 0.4% DOWANOL DPnB 1.0% 1.0% 1.0% 1.0%

TABLE-US-00035 Recipes 30a, 30b, 30c and 30d: Presoaker (Basic Formula) Ingredient 30a 30b 30c 30d Water 82.6% 82.6% 82.6% 82.6% Trilon A 92 3.0% 3.0% 3.0% 3.0% Sodium metasilicate 2.0% 2.0% 2.0% 2.0% Sodium carbonate 2.0% 2.0% 2.0% 2.0% Bayhibit AM 1.0% 1.0% 1.0% 1.0% REWOTERIC? AM KSF 40 4.0% 4.0% 4.0% 4.0% C9-11 FATTY ALCOHOL 1.2% 1.2% 1.2% 1.2% ETHOXYLATE - 8 MOLES OF EO Composition from Example 1a 1.2% Composition from Example 1c 1.2% Composition from Example 1d 1.2% Composition from Example 1f 1.2% DOWANOL DPnB 3.0% 3.0% 3.0% 3.0%

TABLE-US-00036 Recipes 31a, 31b, 31c and 31d: Good Dispersing Presoaker Ingredient 31a 31b 31c 31d Water 80.0% 80.0% 80.0% 80.0% Trilon A 92 3.0% 3.0% 3.0% 3.0% Sodium metasilicate 2.0% 2.0% 2.0% 2.0% Sodium carbonate 2.0% 2.0% 2.0% 2.0% Sequion 10 Na 430 2.0% 2.0% 2.0% 2.0% TEGOTENS? 475 5.0% 5.0% 5.0% 5.0% C9-11 FATTY ALCOHOL 1.5% 1.5% 1.5% 1.5% ETHOXYLATE - 7 MOLES OF EO Composition from Example 1a 1.5% Composition from Example 1c 1.5% Composition from Example 1d 1.5% Composition from Example 1f 1.5% DOWANOL PnB 3.0% 3.0% 3.0% 3.0%

TABLE-US-00037 Recipes 32a, 32b, 32c and 32d: Cost Efficient Presoaker Ingredient 32a 32b 32c 32d Water 80.5% 80.5% 80.5% 80.5% Chelating Agent. M 8.0% 8.0% 8.0% 8.0% Sodium carbonate 6.0% 6.0% 6.0% 6.0% TEGOTENS? AM VSF 3.5% 3.5% 3.5% 3.5% Laureth-6 0.6% 0.6% 0.6% 0.6% Composition from Example 1a 0.4% Composition from Example 1c 0.4% Composition from Example 1d 0.4% Composition from Example 1f 0.4% DOWANOL DPnB 1.0% 1.0% 1.0% 1.0%

TABLE-US-00038 Recipes 33a, 33b, 33c and 33d: Rinse Aid to minimize remaining water Ingredient 33a 33b 33c 33d REWOPAL? MPG 40 6.0% 6.0% 6.0% 6.0% Butyl Cellusolve (BG) 14.0% 14.0% 14.0% 14.0% Composition from Example 1a 3.0% Composition from Example 1c 3.0% Composition from Example 1d 3.0% Composition from Example 1f 3.0% REWOQUAT? CR 3099 10.0% 10.0% 10.0% 10.0% TEGOSOFT? OP 5.0% 5.0% 5.0% 5.0% Water 62.0% 62.0% 62.0% 62.0%

TABLE-US-00039 Recipes 34a, 34b, 34c and 34d: Rinse Aid with Optimal Oil Content Ingredient 34a 34b 34c 34d DOWANOL DPnB 8.6% 8.6% 8.6% 8.6% REWOPAL? MPG 40 6.2% 6.2% 6.2% 6.2% REWOQUAT? CR 3099 10.0% 10.0% 10.0% 10.0% REWOCARE? DOC 4.0% 4.0% 4.0% 4.0% TEGOSOFT? OP 3.0% 3.0% 3.0% 3.0% Composition from Example 1a 1.0% Composition from Example 1c 1.0% Composition from Example 1d 1.0% Composition from Example 1f 1.0% Water 66.8% 66.8% 66.8% 66.8% TEGOPREN? 6923 0.4% 0.4% 0.4% 0.4%

TABLE-US-00040 Recipes 35a, 35b, 35c and 35d: Low Foaming All Purpose Cleaner Ingredient 35a 35b 35c 35d Water 82.0% 82.0% 82.0% 82.0% Trilon A 92 3.0% 3.0% 3.0% 3.0% Sodium metasilicate 2.0% 2.0% 2.0% 2.0% Sodium carbonate 2.0% 2.0% 2.0% 2.0% Sequion 10 Na 430 2.0% 2.0% 2.0% 2.0% TEGOTENS? 475 5.0% 5.0% 5.0% 5.0% C9-11 FATTY ALCOHOL 1.5% 1.5% 1.5% 1.5% ETHOXYLATE - 7 MOLES OF EO Composition from Example 1a 1.5% Composition from Example 1c 1.5% Composition from Example 1d 1.5% Composition from Example 1f 1.5% DOWANOL PnB 1.0% 1.0% 1.0% 1.0%

TABLE-US-00041 Recipes 36a, 36b, 36c and 36d: Low Foaming Alkaline Cleanser Ingredient 36a 36b 36c 36d Water 85.5% 85.5% 85.5% 85.5% Chelating Agent. M 4.0% 4.0% 4.0% 4.0% Sodium carbonate 6.0% 6.0% 6.0% 6.0% TEGOTENS? AM VSF 3.5% 3.5% 3.5% 3.5% Laureth-6 0.6% 0.6% 0.6% 0.6% Composition from Example 1a 0.4% Composition from Example 1c 0.4% Composition from Example 1d 0.4% Composition from Example 1f 0.4%

TABLE-US-00042 Recipes 37a, 37b, 37c and 37d: Low Foaming Alkaline Cleaner Ingredient 37a 37b 37c 37d Water 85.35% 85.35% 85.35% 85.35% TOMAKLEEN G-14 0.75% 0.75% 0.75% 0.75% TEGOTENS? AM VSF 3.5% 3.5% 3.5% 3.5% Composition from Example 1a 0.4% Composition from Example 1c 0.4% Composition from Example 1d 0.4% Composition from Example 1f 0.4% Sodium carbonate 6.0% 6.0% 6.0% 6.0% MGDA-Na3 (40%) 4.0% 4.0% 4.0% 4.0%

TABLE-US-00043 Recipes 38a, 38b, 38c and 38d: Alkaline Cleanser (Automatic Wash) Ingredient 38a 38b 38c 38d Water 59.0% 59.0% 59.0% 59.0% Tetra Potassium Pyrophosphate 15.0% 15.0% 15.0% 15.0% (TKPP) Trilon A liquid 5.0% 5.0% 5.0% 5.0% KOH. 45% 4.0% 4.0% 4.0% 4.0% Sequion 10 Na 430 10.0% 10.0% 10.0% 10.0% Sodium metasilicate 6.0% 6.0% 6.0% 6.0% Composition from Example 1a 1.0% Composition from Example 1c 1.0% Composition from Example 1d 1.0% Composition from Example 1f 1.0%

TABLE-US-00044 Recipes 39a, 39b, 39c and 39d: Metal Cleaner Ingredient 39a 39b 39c 39d Water 82.0% 82.0% 82.0% 82.0% TOMAKLEEN? G-14 12.0% 12.0% 12.0% 12.0% REWOTERIC? AM V 1.5% 1.5% 1.5% 1.5% Composition from Example 1a 3.0% Composition from Example 1c 3.0% Composition from Example 1d 3.0% Composition from Example 1f 3.0% Triethanolamine 1.5% 1.5% 1.5% 1.5%

TABLE-US-00045 Recipes 40a, 40b, 40c and 40d: Metal Cleanser Ingredient 40a 40b 40c 40d Water (Dye. Perfume) 82.0% 82.0% 82.0% 82.0% Triethanolamine 1.5% 1.5% 1.5% 1.5% DOWANOL PnP 6.0% 6.0% 6.0% 6.0% REWOTERIC? AM V 1.5% 1.5% 1.5% 1.5% Composition from Example 1a 3.0% Composition from Example 1c 3.0% Composition from Example 1d 3.0% Composition from Example 1f 3.0% C8-10 Fatty alcohol5 EO 6.0% 6.0% 6.0% 6.0%

TABLE-US-00046 Recipes 41a, 41b, 41c and 41d: Cost Efficient Facade Cleanser Ingredient 41a 41b 41c 41d Water 86.6% 86.6% 86.6% 86.6% Chelating Agent. MGDA 4.0% 4.0% 4.0% 4.0% Sodium carbonate 6.0% 6.0% 6.0% 6.0% TEGOTENS? AM VSF 2.4% 2.4% 2.4% 2.4% Laureth-6 0.6% 0.6% 0.6% 0.6% Composition from Example 1a 0.4% Composition from Example 1c 0.4% Composition from Example 1d 0.4% Composition from Example 1f 0.4%

TABLE-US-00047 Recipes 42a, 42b, 42c and 42d: Anti- dust Glass and Window Cleaner 1 Ingredient 42a 42b 42c 42d Water ad. 100 ad. 100 ad. 100 ad. 100 Ethanol 15% 15% 15% 15% Rewoferm RL 100 .sup.2% .sup.2% .sup.2% .sup.2% Rewocare 755 0.5% 0.5% 0.5% 0.5% Composition from Example 1a 0.1% Composition from Example 1c 0.1% Composition from Example 1d 0.1% Composition from Example 1f 0.1% 2-Phenoxyethanol 0.1% 0.1% 0.1% 0.1% pH Wert (adjust to) 8 8 8 8

TABLE-US-00048 Recipes 43a, 32b, 43c and 43d: Anti- dust Glass and Window Cleaner 2 Ingredient 43a 43b 43c 43d Water ad. 100 ad. 100 ad. 100 ad. 100 Ethanol 15% 15% 15% 15% Rewoferm RL 100 Rewocare 755 0.5% 0.5% 0.5% 0.5% Composition from Example 1a 0.1% Composition from Example 1c 0.1% Composition from Example 1d 0.1% Composition from Example 1f 0.1% Rewoferm SL one .sup.1% .sup.1% .sup.1% .sup.1% Tegotens AM VSF .sup.1% .sup.1% .sup.1% .sup.1% 2-Phenoxyethanol 0.1% 0.1% 0.1% 0.1% pH Wert (adjust to) 8.00 8.00 8.00 8.00

TABLE-US-00049 Recipes 44: Anti-dust Glass and Window Cleaner 3 Ingredient 44 Water ad. 100 Ethanol 3% Composition from Example 1f 0.1%.sup. Rewoferm SL one 1% Tegotens DO 40 1% Tegopren 5840 0.05% 2-Phenoxyethanol 0.1%.sup. pH Wert (adjust to) 6.0-7.0

TABLE-US-00050 Recipes 45, 46, 47: All-purpose Cleaner concentrate Ingredient 45 46 47 Water ad. 100 ad. 100 ad. 100 Ethanol .sup.3% 3% .sup.5% Rewoferm RL 100 .sup.2% Tego Betain Powder MB 1% Rewocare 755 0.5% 0.5%.sup. Rewopol SB DO 75 .sup.3% 1.5% Rewoferm SL ONE .sup.1% 1% Composition from Example 1e 0.2% 0.5%.sup. 0.5% Tegotens AM VSF 3% 2-Phenoxyethanol 0.1% 0.1%.sup. 0.1% pH Wert (adjust to) 8 8 8

TABLE-US-00051 Recipes 48, 49, 50: All-purpose Cleaner Cleaner Trigger spray Ingredient 48 49 50 Water ad. 100 ad. 100 ad. 100 Ethanol 3% .sup.3% .sup.3% Rewoferm RL 100 .sup.3% 1.5% Tego Betain Powder MB .sup.1% Rewocare 755 0.5% Rewoferm SL one 2% Composition from Example 1e 0.2%.sup. 0.5% 0.5% Tegotens AM VSF 1% 2-Phenoxyethanol 0.1%.sup. 0.1% 0.1% pH Wert (adjust to) 8.00 8.00 8.00

TABLE-US-00052 Recipes 51, 52, 53: Floor Cleaner Ingredient 51 52 53 Water 93% 93% 80% Rewoferm SL one 1% Rewoferm RL 100 .sup.1% .sup.1% Composition from Example 1e 0.5% 0.5% 0.5%.sup. Tego PP 1027 0.5% 0.5% Tego Betain Powder MB .sup.1% .sup.1% 1% Tegotens AM VSF 3% Tomadol 91-6 .sup.4% .sup.4% 4% Rewocare 755 0.5%.sup. 2-Phenoxyethanol 0.1% 0.1% 0.1%.sup. pH Wert (adjust to) 8.00 9.00 8.00

TABLE-US-00053 Recipes 54, 55, 56: Automatic Dish Rinse Aid Ingredient 54 55 56 Water ad. 100 ad. 100 ad. 100 Composition from Example 1e 3% 3% 3% Citric acid monohydrate 5% 5% 5% Tomadol 91-6 5% 5% Tomadol 91-8 3% Tomadol 1-5 1.5%.sup. pH (adjust to) 4 4 4

TABLE-US-00054 Recipes 57, 58, 59: Bathroom Cleaner Ingredient 57 58 59 Water ad. 100 ad. 100 ad. 100 Rewoferm RL 100 1.5% Tego Betain Powder MB 1.5% 1.5% 1.5% Rewocare 755 0.5% 0.5% Rewopol SB DO 75 1.5% Rewoferm SL one .sup.1% 0.5% 0.5% Composition from Example 1e 0.5% 0.5% 0.5% Tegotens AM VSF .sup.3% 1.5% Rewoteric AM V 1.5% Tego PP 1027 0.5% GLDA 0.25 2-Phenoxyethanol 0.1% 0.1% 0.1% pH Wert (adjust to) 5.5 5.5 5.5

TABLE-US-00055 Recipes 60, 61, 62: Handdishwash Liquid Ingredient 60 61 62 Water ad. 100 ad. 100 ad. 100 Texapon 70 15% 5% TEGO Betain C 60 4.8% 3% 3% REWOFERM SL One 5.4% 2% 2% Composition from Example 1e 0.5% 1% 1% C10-16 APG, 50% 10% 10% NaCl 1.25% Xanthan Gum 0.3%.sup. 0.3%.sup. Glycerin 2% 2% Rewopol SB CS 50 5% Preservative q.s. q.s. q.s. pH Wert 5.5 5.5 5.5

TABLE-US-00056 Recipes 63, 64, 65: Cleaner for Plastic furniture and interieur Ingredient 63 64 65 Water ad. 100 ad. 100 ad. 100 GLDA .sup.3% 0.5% 0.5% Composition from Example 1e 0.5% 0.5% .sup.1% Tego Betain C 60 1.5% Tomakleen 91-6 1.5% Rewoquat Q 70 0.5% Rewopol CC 40 B MB .sup.4% Tegotens DO 40 3.5% Tegopren 6922 1.2% 1.2% pH Wert (adjust to) 9 9 9

TABLE-US-00057 Recipes 66, 67, 68: Grill and Oven Cleaner Ingredient 66 67 68 Water ad. 100 ad. 100 ad. 100 MGDA 5% 5% 5% Sodium Carbonate 5% 5% 5% Rewoteric AM KSF 40 MB 5% Tomadol 91-6 1.5%.sup. 1.5%.sup. Composition from Example 1e 1.2%.sup. 1.5%.sup. 1.5%.sup. Dowanol DPnB 1% 1% 1% Rewoquat CQ 200 5% 5% Tomakleen G-14 6% pH (adjust to) 12 12 12

TABLE-US-00058 Recipes 69, 70, 71: Cleaner for Food&Beverage Fatsolve Ingredient 69 70 71 Water ad. 100 ad. 100 ad. 100 Rewoquat CQ 200 20% 12% 12% Rewoteric AM KSF 40 MB 10% Composition from Example 1e 5% 5% 3% MGDA 5% 5% Sodium Carbonate 3% 3% Tomadol 91-8 5% Tomadol 1-5 3% 2% pH Wert (adjust to) 12 12 12

TABLE-US-00059 Recipes 72, 73, 74: Car Shampoo Ingredient 72 73 74 Water ad. 100 ad. 100 ad. 100 Tomakleen G-14 5% 5% Rewoteric AM KSF 40 MB 5% Composition from Example 1e 2% 2% 1.5%.sup. MGDA 3% 2% 3% Sodium Carbonate 1% 2% Sodium laurylethersulfate, 28% 10% Tomadol 91-6 3% Rewocare 755 0.5%.sup. 0.5%.sup. Tego Betain C 60 2% 3% Rewoferm RL 100 5% pH Wert (adjust to) 9 10 9

TABLE-US-00060 Recipes 72, 73, 74: Car Rinse Ingredient 72 73 74 Water ad. 100 ad. 100 ad. 100 Carspray 90 MB 20% Rewopol MPG 40 5% 5% Composition from Example 1e 0.5% 0.5%.sup. 1% Rewoquat CR 3099 15% Tegopren 6922 20% Isopropanol 2% 2% 2% pH Wert (adjust to) 8 8 8

TABLE-US-00061 Recipe 75, Automatic Dish Wash Powder Ingredient 75 Sodium carbonate 42.0% Sodium sulphate 20.0% Sodium citrate 15.0% Sodium percarbonate 10.0% Polymer 3.0% Phosphonate (HEDP) 2.5% Sodium metasilicate 2.0% Tomakleen G-14 1.0% Composition from Example 1e 1.0% TAED 2.0% Protease 1.0% Amylase 0.5%

TABLE-US-00062 Recipe 76, Automatic Dish Wash Gel Ingredient 76 Water .sup.65% Tetrasodium Glutamare diacetate/GLDA .sup.16% Glycerol 9.0% Polyacrylate polymer 2.0% Protease 1.0% Formic acid 0.2% PPG-1 C6-10 Pareth-20 2.0% Amylase 0.50% Xanthan Gum 0.50% Composition from Example 1e 0.25% Perfumes 0.20% Zinc acetate dihydrate 0.10% Calcium Chloride 0.10% Limonen 0.050% Colorant 0.050% CIT/MIT 0.050%