Reactor for hydrothermal carbonization with optimized mixture of sludge and steam
10151480 ยท 2018-12-11
Assignee
Inventors
Cpc classification
F23G7/001
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B01F23/2323
PERFORMING OPERATIONS; TRANSPORTING
B01F23/23351
PERFORMING OPERATIONS; TRANSPORTING
Y02W10/40
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y02W10/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B01F23/2334
PERFORMING OPERATIONS; TRANSPORTING
B01J2219/00123
PERFORMING OPERATIONS; TRANSPORTING
B01F23/23362
PERFORMING OPERATIONS; TRANSPORTING
B01F23/23341
PERFORMING OPERATIONS; TRANSPORTING
F23G5/0276
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
C10L2290/54
CHEMISTRY; METALLURGY
International classification
F23G7/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F23G5/027
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F23G5/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B01J19/00
PERFORMING OPERATIONS; TRANSPORTING
Abstract
Disclosed is a reactor for treating, particularly by hydrothermal carbonization, sludge containing organic matter, including, with: a vessel (100) including an inner chamber arranged to receive the sludge and to form a path of travel for the sludge adapted to allow for circulation of the sludge, a sludge inlet (1) arranged to introduce the sludge into a sludge introduction area of the inner chamber, a sludge outlet (11) arranged to discharge at least part of the sludge contained in the inner chamber, and a steam inlet (3) arranged to inject steam in a steam injection zone of the inner chamber along a steam injection direction, the steam injection direction being different from a sludge circulation direction in the steam injection zone along the circulation path, the steam injection zone being separated from the sludge introduction zone.
Claims
1. A reactor for treating sludge containing organic matter, particularly by hydrothermal carbonization, including: a vessel (100) comprising an inner chamber arranged to receive the sludge and to form a circulation path for the sludge adapted to allow the sludge to circulate, a sludge inlet (1) arranged to introduce the sludge into a sludge introduction area of the inner chamber, a sludge outlet (11) arranged to discharge at least part of the sludge contained in the inner chamber, and a steam inlet (3) arranged to inject steam in a steam injection zone of the inner chamber along a steam injection direction, the steam injection direction being different from a sludge circulation direction in the steam injection zone along the circulation path, the steam injection zone being separated from the sludge introduction zone, wherein the circulation path comprises at least a closed loop; and said reactor further comprising, in an upper portion of the inner chamber, a degassing volume (8) arranged to collect gaseous effluents contained in the sludge, the reactor further comprising at least one vent (10) arranged to discharge these gaseous effluents.
2. The reactor according to claim 1, wherein the inner chamber is of vertical dimension L, and wherein the steam injection zone is separated from the sludge introduction zone by a distance greater than L/12.
3. The reactor of claim 2, wherein the steam injection zone is separated from the sludge introduction zone by a distance greater than L/8.
4. The reactor of claim 2, wherein the steam injection zone is separated from the sludge introduction zone by a distance greater than L/4.
5. The reactor according to claim 2, wherein the steam injection direction is against the sludge circulation direction (2) in the steam injection zone.
6. The reactor according to claim 2, further comprising a circulator (6) arranged to circulate the sludge in the inner chamber along the circulation path.
7. The reactor according to claim 1, wherein the steam injection direction is against the sludge circulation direction (2) in the steam injection zone.
8. The reactor according to claim 7, further comprising a circulator (6) arranged to circulate the sludge in the inner chamber along the circulation path.
9. The reactor according to claim 1, further comprising a circulator (6) arranged to circulate the sludge in the inner chamber along the circulation path.
10. The reactor according to claim 9, wherein the inner chamber comprises an inner space (2b) located inside the tube (101) and an outer space (4b) located outside the tube (101), the reactor being arranged: so that the steam injection zone is located in a lower region of the inner space (2b) of the tube (101), the lower region comprising a first end of the tube (101), so that the circulator (6) is located, at least in part, in an upper region of the inner space (2b) of the tube (101), the upper region comprising a second end of the tube (101) opposite the first end, and so that the sludge introduction zone is located between the lower region and the upper region of the inner space (2b) of the tube (101).
11. The reactor according to claim 1, further comprising at least one orifice (9) arranged to inject the acid to the vessel (100).
12. The reactor according to claim 1, wherein the vessel (100) comprises a wall (101) arranged to separate two parts of the circulation path having opposing sludge circulation directions (2, 4).
13. The reactor according to claim 12, wherein the wall (101) forms a tube.
14. The reactor according to claim 1, further comprising a hydrocyclone (400) arranged to selectively eliminate heavy particles contained in the sludge circulating in the vessel (100).
15. A reactor for treating sludge containing organic matter, particularly by hydrothermal carbonization, including: a vessel (100) comprising an inner chamber arranged to receive the sludge and to form a circulation path for the sludge adapted to allow the sludge to circulate, a sludge inlet (1) arranged to introduce the sludge into a sludge introduction area of the inner chamber, a sludge outlet (11) arranged to discharge at least part of the sludge contained in the inner chamber, and a steam inlet (3) arranged to inject steam in a steam injection zone of the inner chamber along a steam injection direction, the steam injection direction being different from a sludge circulation direction in the steam injection zone along the circulation path, the steam injection zone being separated from the sludge introduction zone, wherein the circulation path comprises at least a closed loop, and wherein the vessel (100) comprises an inner jacketing (101) arranged to delimit the circulation path so as to constitute: an ascending channel (4b) in an annular passage between an internal face of the inner chamber and jacketing (101), a descending channel (2b) in a cylindrical conduit formed by the jacketing (101), an upper transverse section (21) arranged to allow sludge to circulate from the ascending channel (4b) to the descending channel (2b), a lower transverse section (22) arranged to allow sludge to circulate from the descending channel (2b) to the ascending channel (4b).
16. The reactor according to claim 15, further comprising, in an upper portion of the inner chamber, a degassing volume (8) arranged to collect gaseous effluents contained in the sludge, the reactor further comprising at least one vent (10) arranged to discharge these gaseous effluents.
17. A reactor for treating sludge containing organic matter, particularly by hydrothermal carbonization, including: a vessel (100) comprising an inner chamber arranged to receive the sludge and to form a circulation path for the sludge adapted to allow the sludge to circulate, a sludge inlet (1) arranged to introduce the sludge into a sludge introduction area of the inner chamber, a sludge outlet (11) arranged to discharge at least part of the sludge contained in the inner chamber, and a steam inlet (3) arranged to inject steam in a steam injection zone of the inner chamber along a steam injection direction, the steam injection direction being different from a sludge circulation direction in the steam injection zone along the circulation path, the steam injection zone being separated from the sludge introduction zone, wherein the circulation path comprises at least a closed loop, said reactor further comprising a circulator (6) arranged to circulate the sludge in the inner chamber along the circulation path, and wherein the circulation path is defined by: a first tube defining an ascending path (4bc), a second tube defining a descending path (2bc), a first transverse conduit (5) arranged so that the first and the second tubes emerge, at their upper portions, in this first transverse conduit (5), the reactor comprising, in an upper portion of the first transverse conduit (5), a degassing volume (8) arranged to collect effluent gaseous contained in the sludge, and a second transverse conduit (12) arranged so that the first and the second tubes emerge, at their lower portions, in this second transverse conduit (12).
18. The reactor according to claim 17, wherein the circulator (6) is arranged to generate the circulation of sludge in the second transverse conduit (12).
19. The reactor according to claim 17, further comprising, in an upper portion of the inner chamber, a degassing volume (8) arranged to collect gaseous effluents contained in the sludge, the reactor further comprising at least one vent (10) arranged to discharge these gaseous effluents.
Description
DESCRIPTION OF FIGURES AND EMBODIMENTS
(1) Other advantages and features of the invention will emerge on reading the detailed description of implementations and embodiments which follow, given only by way of non-limiting example and with reference to the accompanying drawings:
(2)
(3)
(4)
(5)
(6) As the embodiments described below are in no way limiting, variants of the invention can notably be considered comprising only a selection of the described features, isolated from the other features described (even if this selection is isolated within a sentence comprising these other features), if this selection of features is sufficient to attribute a technical advantage or to differentiate the invention in relation to the state of the art. This selection comprises at least one feature, preferably functional without structural details, or with only a part of the structural details if only this part is sufficient to attribute a technical advantage or to differentiate the invention in relation to the state of the art.
(7) In this description of embodiments and variants, the steam is water vapor by default.
(8) In this description, the expression circulation of sludge, a mixture or a liquid in the reactor refers to any movement of this sludge, this mixture or this liquid in the reactor.
(9) In this description, the expression circulation path refers to the path along which this movement takes place in the reactor.
(10) The reactor according to the invention is typically adapted to treat sludge containing organic matter by hydrothermal carbonization.
(11)
(12) It should be noted that the steam inlet 3 is not flush on an internal face of the inner chamber of the vessel 100, but emerges in the core of the inner chamber of the vessel 100, so that the steam inlet 3 is surrounded by the sludge+steam mixture in the inner chamber of the vessel 100.
(13) In this embodiment, the expression circulation of sludge typically refers to a relative displacement of the sludge defining an average speed of travel Vd of the sludge within the vessel 100 of typically 0.1 to 3 m/s, an average injection speed Ve of the sludge through the sludge inlet 1 of typically 0.005 to 0.1 m/s, or a Vd/Ve ratio of typically 5 to 100.
(14) In the example of
(15) The inner chamber is of vertical dimension L, the vertical being defined by Earth's gravity. In the reactor of
(16) Here, the vertical dimension L corresponds to the height of the inner chamber of the vessel 100 measured along said vertical direction, and connecting a horizontal plane passing through the lowest point of the lower surface 108 (concave as seen from the inside of the vessel) to a horizontal plane passing through the highest point of the upper surface 109 (concave as seen from the inside of the vessel).
(17) As illustrated in
(18) Furthermore, the steam injection direction is against the sludge circulation direction (preferably opposite) in the steam injection zone.
(19) In this description, the expression against the circulation direction means that for an average sludge circulation direction in the steam injection zone in a main direction (vertically downwards in the case of
(20) It can be seen in
(21) In the embodiment of
(22) Intensive mixing takes place between the steam, which tends to rise up towards the top of the vessel 100 and the sludge with weak rheological properties, close to water, which tends to descend toward the bottom of the vessel 100. This mixing breaks up any lumps of sludge that are not yet liquefied. Furthermore, this mixing intensifies the condensation of the steam which rapidly provides its heat to the ambient environment.
(23) The vessel 100 of the reactor of
(24) In the example described, sludge is introduced via a branch connection 1 emerging into the descending channel 2b. For this purpose, a sludge inlet conduit passes through the wall of the vessel 100 and the inner jacketing 101 to emerge in the descending channel 2b.
(25) The reactor of
(26) According to variants not represented, the circulator 6 can include: an agitator with one or more blades, and/or a screw, and/or a pump, and/or a sludge recirculation loop, and/or a bubbler.
(27) The circulator 6 is preferably arranged in an upper portion of the descending channel 2b, below the upper transverse section 21 and above the sludge introduction zone.
(28) In other words, the vessel 100 of
(29) In this example, the wall 101 forms a tube, the inner chamber of the vessel 100 comprising an inner space (descending channel 2b) inside the tube 101 and an outer space (ascending channel 4b) outside the tube. The tube 101 corresponds to the inner jacketing 101 previously described.
(30) In this first embodiment, the reactor is arranged: so that the steam injection zone is located in a lower region of the inner space 2b of the tube 101, the lower region comprising a first end of the tube (toward the bottom in
(31) The circulation path thus comprises at least a closed loop which, in the example of
(32) Ideally, if the flow lines of sludge circulating in the reactor are considered, these flow lines form at least a closed loop with a bifurcation possible toward the sludge outlet 11.
(33) The reactor comprises, in an upper portion of the inner chamber, above the upper transverse section 21, a degassing volume 8 arranged to collect gaseous effluents contained in the sludge, the reactor further comprising at least one vent 10 arranged to discharge these gaseous effluents.
(34) This degassing volume 8 is defined, in
(35) The delimitation of the degassing volume 8 and the sludge contained in the vessel 100 by the level N results from the fact that the reactor is pressurized and that the gaseous effluents collected in degassing volume 8 push the sludge downward.
(36) The sludge contained in the vessel 100 of the reactor typically circulates continuously to perform multiple cycles (or passages along the same circulation path) before discharge through the sludge outlet 11.
(37) To illustrate an implementation of the reactor, an incoming flow of sludge is introduced into the descending channel 2b, between the blades of the circulator 6 and the steam injection 3 nozzles 3a, 3b, 3c, 3d. Between these two sludge introduction and steam injection zones, the mixture, consisting of the sludge and the steam, is subjected to strong turbulence as the steam and the sludge are circulating against one another. This turbulence increases the interactions between steam and sludge, which allows the mixture to homogenize. The sludge can contain fibers, which are highly disaggregated in this zone with the steam, before reaching the circulator 6 while following the circulation path via the descending channel 2b, the lower transverse section 22, the ascending channel 4b, then the upper transverse section 21. This thereby reduces problems caused by fibers being wound around the blades of circulator 6.
(38) Furthermore, with such implementation, mineral parts and aggregates contained in the sludge tend to settle in the bottom of the inner chamber of the vessel 100 by gravity (on an internal face of the lower surface 108), which reduces the interactions of these mineral parts and aggregates with blades of the circulator 6.
(39) The size of the inner jacketing 101 is designed in such a way that the average circulation speed of the sludge in the ascending channel 4b is of the same order of magnitude as in the descending channel 2b. The ratios of the sludge circulation speeds between the ascending channel 4b and the descending channel 2b are in the order of 0.5 to 5. Typically the speeds in the ascending channel 2b are 0.1-3 m/s, typically 0.5-1.5 m/s.
(40) In a mode of implementation, cold sludge is injected into the descending channel 2b with a low injection speed relative to the circulation speed, typically in the order of 0.005 to 0.1 m/s. Due to the shear phenomenon of the sludge by the steam, the cold sludge introduced is rapidly driven into circulation; it is uniformly mixed and its temperature thus increases relatively rapidly.
(41) Owing to the circulator 6, the sludge, uniformly mixed through its interactions with the injected steam, is conveyed into the ascending channel 4b where it continues to be uniformly mixed.
(42) The sludge-steam mixture then arrives in the upper transverse section 21 then calms down in terms of turbulence. Non-condensable gas bubbles separate from the sludge in this upper transverse section 21, and then rise in the degassing volume 8 without returning downward. The gas thus produced by the separation of the bubbles is regularly removed through the vent 10, typically through a valve (not represented) controlled by a pressure regulator (not represented).
(43) The sludge then returns to the descending channel 2b through the circulator 6. At this stage, the sludge is liquefied; the majority of the lumps being reduced so that they no longer interfere with the operation of the circulator 6. Carbonization reactions can then take place for several sludge circulation cycles between the descending 2b and ascending 4b channels successively (i.e. in the closed loop).
(44) An anti-vortex system, such as blades 7, can be installed above the circulator 6 to prevent preferential flow paths and vortex type swirling from forming in the descending channel 2b of the reactor.
(45) The reactor of
(46) The discharge of carbonized sludge, i.e. its extraction from the inner chamber of the vessel 100 via the sludge outlet 11, preferably takes place in the lower part of the reactor, in the lower transverse section 22, for example at the bottom of the vessel 100 via a branch connection passing through the lower surface 108. This configuration allows non-carbonizable materials such as sand to be drained and eliminated. These solids are preferentially extracted from the reactor while the liquid organic content of the sludge continues to flow along the circulation path.
(47) It should be noted that in case of failure of the circulator 6, the injection of steam via the steam inlet 3 allows the sludge to be mixed in the descending channel 2b and natural circulation to take place.
(48)
(49) In this second embodiment, the sludge is introduced at the bottom of the ascending channel 4bb.
(50) The descending channel 2bb is no longer located in the inner space 4bb of the tube 101 as in the solution shown in
(51) The ascending channel 4bb is thus located inside the jacketing 101. Both of these descending 2bb and ascending 4bb channels are connected, as in the solution described in
(52) Steam is injected via a branch connection emerging in the ascending channel 4bb in the inner space of the jacketing 101.
(53) Sludge is introduced into the ascending channel 4bb, in the inner space of the tube 101.
(54) In this second embodiment of
(55) The reactor also comprises an anti-vortex system 7, this time installed below the circulator 6, i.e. upstream from the circulator 6 relative to the circulation direction 4 of the sludge, similarly to the embodiment of the
(56) All other configurations, for example the arrangement of the sludge inlet 1 and/or the steam inlet 3 to introduce sludge and/or to inject steam into the ascending channel 4b (embodiment of
(57)
(58) Similarly to the embodiments of
(59) Furthermore, the circulator 6, e.g. a centrifugal pump, is arranged in this example, to generate the circulation of sludge in the second transverse conduit 12.
(60) In this third embodiment, the steam inlet 3 is arranged to inject the steam in the lower part of the descending path 2bc, against the direction of sludge flow in the reactor.
(61) The sludge inlet 1 is arranged to introduce the cold sludge via a branch connection in the lower part of the ascending path 4bc to allow sludge to travel a maximum period of time before arriving at the circulator 6 and extraction from the reactor through the sludge outlet 11.
(62) The first transverse conduit 5, in which the sludge flows at lower speed, allows incondensables to be degassing toward the degassing volume 8, then toward a discharge connection 10.
(63) In this third embodiment, acid can be injected, by a branch connection 9, into the ascending path 4bc (as illustrated in
(64) A discharge connection 11 is located in the second transverse conduit 12 to form the sludge outlet, preferably upstream from the circulator 6 (relative to the circulation of sludge), so that the discharge of the mineral particles contained in the sludge is given priority, by gravity or by means of a hydrocyclone 400 as shown in
(65) A back-up branch connection 11b is fitted on the lower part of the ascending path 4bc to evacuate any accumulation of heavy particles at this location. This back-up branch connection 11b is opened periodically in order to discharge the accumulated particulates.
(66) Sludge can be alternatively introduced into the descending path 2bc (not represented). In this case, the circulator 6 is preferentially located in the ascending path 4bc (not represented).
(67) Any other configuration of the respective positions of the circulator 6 and the sludge inlet 1 is possible but does not confer any substantial benefits in relation to the embodiments described here.
(68) It should be noted that if the circulator 6 consists of a centrifugal type pump that can accept solids, sludge can also be injected directly upstream from the circulator 6 in order to be ground therein for better homogenization (not represented). However, this method would necessarily involve a pretreatment of the sludge prior to its introduction into the reactor to ensure that no fibers wrap around the circulator 6.
(69)
(70) Such a hydrocyclone 400 is arranged to selectively eliminate heavy particles (heavy sands) contained in the sludge. The centrifugation principle, known to those skilled in the art, allows heavy sands to be eliminated while allowing the light liquefied material to continue its path while circulating in the reactor.
(71) The presence of a hydrocyclone 400, as illustrated in
(72) Of course, the invention is not limited to the examples described here and numerous modifications can be made to these examples within departing from the scope of the invention. For example, the hydrocyclone of