Dry cooling system for powerplants
10132568 ยท 2018-11-20
Assignee
Inventors
- Krishna P. Singh (Hobe Sound, FL)
- Vytautas Vincas Maciunas (Cherry Hill, NJ, US)
- Indresh Rampall (Cherry Hill, NJ)
Cpc classification
F28F9/0243
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F28B1/06
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F28B9/06
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F28D1/05366
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F28B1/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
F28B1/06
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F28F9/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F28B9/06
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F28B1/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F28F9/26
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
An indirect dry cooling system suitable for steam condensing applications in a power plant Rankine cycle includes an air blast chiller having a plurality of interconnected modular cooler cells. Each cell includes a blower and tube bundle including inlet headers, outlet headers, and plurality of tubes extending between the headers. In one embodiment, the tube bundles form an A-frame cell construction being structurally self-supporting from a base. Each of the tubes may be finned. Cooling water circulating in a closed flow loop on the tube side between the air blast chiller and turbine steam condenser is cooled by ambient air blown through the tube bundles. The cooled water flows through a second tube bundle in the condenser which condenses steam. The heated cooling water returns through the air blast chiller to complete the cooling water cycle.
Claims
1. A dry cooling system for condensing steam, the system comprising: a condenser arranged to receive exhaust steam from a steam turbine; a condenser tube bundle disposed in the condenser; an air blast chiller fluidly coupled to the condenser tube bundle via a cooling water closed flow loop for circulating cooling water; the air blast chiller comprising a plurality of fluidly interconnected cooling cells each comprising: a pair of first and second inlet bundle section headers fluidly coupled to the closed flow loop; a pair of first and second outlet bundle sections headers fluidly coupled to the closed flow loop; a first tube bundle comprising a plurality of tubes fluidly coupled between the first inlet and outlet bundle section headers; a second tube bundle angularly oriented to the first tube bundle and comprising a plurality of tubes fluidly coupled between the second inlet and outlet bundle section headers; and an air blower arranged to direct ambient cooling air through the first and second tube bundles; wherein hot cooling water from the condenser tube bundle flows through the closed flow loop to each of the first and second inlet bundle section headers, through the first and second tube bundles wherein the cooling water is cooled, the cooled cooling water being collected in the first and second outlet bundle section headers and then flowing through the closed flow loop back to the condenser tube bundle; wherein the plurality of cooling cells are arranged in a horizontally extending row in which first and second inlet bundle section headers are connected in a contiguous series to other first and second inlet bundle section headers respectively, and first and second outlet bundle section headers are connected in a contiguous series to other first and second outlet bundle section headers respectively; wherein the first and second inlet bundle section headers are connected together via mating bolted flanges to adjoining first and second inlet bundle section headers respectively, and first and second outlet bundle section headers are connected together via mating bolted flanges to adjoining first and second outlet bundle section headers respectively.
2. The system according to claim 1, wherein the first and second tube bundles are arranged in a vertically-oriented triangular shape and converge towards a top of the cooling cell.
3. The system according to claim 2, wherein the first and second inlet bundle section headers are supported by a horizontal mounting surface, and the first and second outlet bundle section headers are mechanically coupled together to form a self-supporting A-frame construction.
4. The system according to claim 1, wherein the first inlet bundle section header, first tube bundle, and first outlet bundle section header form a first cooling water flow path, and the second inlet bundle section header, second tube bundle, and second outlet bundle section header form a second cooling water flow path fluidly isolated from the first flow path.
5. The system according to claim 1, wherein the cooling cells are configured and arranged to form a multiple pass heat exchanger in which: cooling water cannot flow directly from one first inlet bundle section header into an adjoining first inlet bundle section header, and cooling water cannot flow directly from one first outlet bundle section header into an adjoining first outlet bundle section header; and cooling water cannot flow directly from one second inlet bundle section header into an adjoining second inlet bundle section header, and cooling water cannot flow directly from one second outlet bundle section header into an adjoining second outlet bundle section header.
6. The system according to claim 1, wherein the tubes include a plurality laterally extending heat transfer fins disposed on opposing sides of the tubes.
7. The system according to claim 6, wherein the tubes have an oblong cross sectional shape.
8. The system according to claim 1, further comprising an inlet manifold of the cooling water closed flow loop fluidly coupled to the first and second inlet bundle section headers at a first end of the first and second inlet bundle section headers, and a second end of the first and second inlet bundle section headers fluidly coupled to an outlet manifold of the cooling water closed flow loop.
9. A dry cooling system for condensing steam, the system comprising: a condenser arranged to receive exhaust steam from a steam turbine; a condenser tube bundle disposed in the condenser; an air blast chiller fluidly coupled to the condenser tube bundle via a cooling water closed flow loop for circulating cooling water; the air blast chiller comprising a plurality of fluidly interconnected cooling cells each comprising: a pair of first and second inlet bundle section headers fluidly coupled to the closed flow loop; a pair of first and second outlet bundle sections headers fluidly coupled to the closed flow loop; a first tube bundle comprising a plurality of tubes fluidly coupled between the first inlet and outlet bundle section headers; a second tube bundle angularly oriented to the first tube bundle and comprising a plurality of tubes fluidly coupled between the second inlet and outlet bundle section headers; and an air blower arranged to direct ambient cooling air through the first and second tube bundles; wherein hot cooling water from the condenser tube bundle flows through the closed flow loop to each of the first and second inlet bundle section headers, through the first and second tube bundles wherein the cooling water is cooled, the cooled cooling water being collected in the first and second outlet bundle section headers and then flowing through the closed flow loop back to the condenser tube bundle; wherein the plurality of cooling cells are arranged in a horizontally extending row in which first and second inlet bundle section headers are connected in a contiguous series to other first and second inlet bundle section headers respectively, and first and second outlet bundle section headers are connected in a contiguous series to other first and second outlet bundle section headers respectively; wherein the cooling cells are arranged in pairs in which the first and second inlet bundle section headers of a first cell are fluidly isolated from the first and second inlet bundle section headers of a second cell respectively, and the first and second outlet bundle section headers of the first cell fluidly communicate with the first and second outlet bundle section headers of a second cell respectively.
10. The system according to claim 9, wherein the first and second inlet bundle section headers of each pair of cooling cells are in fluid communication with the first and second inlet bundle section headers of an adjoining pair of cooling cells, and the first and second outlet bundle section headers of each pair of cooling cells are not in fluid communication with the first and second inlet bundle section headers of an adjoining pair of cooling cells.
11. An air blast chiller for condensing steam, the air blast chiller comprising: a plurality of fluidly coupled cooling cells arranged in a contiguous row of adjoining fluidly interconnected cooling cells, each cooling cell comprising: a first half section including a first inlet header, a first outlet header, and a first tube bundle comprising a plurality of linearly spaced apart finned tubes fluidly coupled between the first inlet and outlet headers; and a second half section including a second inlet header, a second outlet header, and a second tube bundle comprising a plurality of linearly spaced apart finned tubes fluidly coupled between the second inlet and outlet headers; the first half section arranged at an acute angle to the second half section wherein the first and second outlet headers are disposed proximately to each other, and the first and second inlet headers are disposed distally to each other forming a triangular configuration; and a blower arranged and operable to flow ambient cooling air through the first and second tube bundles; wherein at least some of the cooling cells are arranged in a pair in which the inlet headers of a first and second cooling cell are mechanically coupled together via joints which includes a flow partition plate that prevents cooling water from flowing directly from the inlet headers of the first cooling cell into corresponding inlet headers of the second cooling cell.
12. The air blast chiller according to claim 11, wherein the first and second outlet headers are disposed laterally adjacent to each other and mechanically coupled together to form a self-supporting integrated construction.
13. The air blast chiller according to claim 11, wherein the outlet headers of the first and second cooling cells are mechanically coupled together via joints configured to allow cooling water to flow directly from the outlet headers of the first cooling cell into corresponding outlet headers of the second cooling cell.
14. The air blast chiller according to claim 11, wherein a first pair of cooling cells is fluidly coupled to an adjoining second pair of cooling cells in which inlet headers of the first pair are fluidly isolated from inlet headers of the second pair, and outlet headers of the first pair are fluidly coupled to the outlet headers of the second pair.
15. The air blast chiller according to claim 14, wherein the first and second pairs of cooling cells form a 4-pass cooling water flow arrangement.
16. The air blast chiller according to claim 11, wherein the cooling cells each have an A frame configuration with the first and second inlet headers forming a bottom of the cell and the first and second outlet headers forming a top apex of the cell.
17. The air blast chiller according to claim 11, wherein the cooling cells each have a V frame configuration with the first and second inlet headers forming a top of the cell and the first and second outlet headers forming a bottom apex of the cell.
18. A method for condensing steam, the method comprising: providing the air blast chiller according to claim 11; receiving hot cooling water from a steam condenser in the first and second inlet headers of a first cooling cell; flowing the cooling water through the first and second tube bundles in a first direction, wherein the cooling water is cooled a first time; collecting the cooling water in the first and second outlet headers of the first cooling cell; transferring the cooling water to the first and second outlet headers of a second cooling cell; flowing the cooling water through the first and second tube bundles of the second cooling cell in a second first direction opposite the first direction, wherein the cooling water is cooled a second time; collecting the cooling water in the first and second inlet headers of the second cooling cell; and transferring the cooling water to the first and second inlet headers of a third cooling cell.
19. An air blast chiller for condensing steam, the air blast chiller comprising: a plurality of fluidly coupled cooling cells arranged in a contiguous row of adjoining fluidly interconnected cooling cells, each cooling cell comprising: a first half section including a first inlet header, a first outlet header, and a first tube bundle comprising a plurality of linearly spaced apart finned tubes fluidly coupled between the first inlet and outlet headers; and a second half section including a second inlet header, a second outlet header, and a second tube bundle comprising a plurality of linearly spaced apart finned tubes fluidly coupled between the second inlet and outlet headers; the first half section arranged at an acute angle to the second half section wherein the first and second outlet headers are disposed proximately to each other, and the first and second inlet headers are disposed distally to each other forming a triangular configuration; and a blower arranged and operable to flow ambient cooling air through the first and second tube bundles; wherein at least one cooling cell has a double A-frame construction comprising: a third half section including a third inlet header, a third outlet header, and a third tube bundle comprising a plurality of linearly spaced apart finned tubes fluidly coupled between the third inlet and outlet headers; and a fourth half section including a fourth inlet header, a fourth outlet header, and a fourth tube bundle comprising a plurality of linearly spaced apart finned tubes fluidly coupled between the fourth inlet and outlet headers; the third half section arranged at an acute angle to the fourth half section wherein the third and fourth outlet headers are disposed proximately to each other, and the third and fourth inlet headers are disposed distally to each other forming a second triangular configuration; the blower being located centrally between second and third half sections.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The features of the preferred embodiments will be described with reference to the following drawings where like elements are labeled similarly, and in which:
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(18) All drawings are schematic and not necessarily to scale. A reference herein to a figure number herein that may include multiple figures of the same number with different alphabetic suffixes shall be construed as a general reference to all those figures unless specifically noted otherwise.
DETAILED DESCRIPTION
(19) The features and benefits of the invention are illustrated and described herein by reference to exemplary (example) embodiments. This description of exemplary embodiments is intended to be read in connection with the accompanying drawings, which are to be considered part of the entire written description. Accordingly, the disclosure expressly should not be limited to such exemplary embodiments illustrating some possible non-limiting combination of features that may exist alone or in other combinations of features.
(20) In the description of embodiments disclosed herein, any reference to direction or orientation is merely intended for convenience of description and is not intended in any way to limit the scope of the present invention. Relative terms such as lower, upper, horizontal, vertical,, above, below, up, down, top and bottom as well as derivative thereof (e.g., horizontally, downwardly, upwardly, etc.) should be construed to refer to the orientation as then described or as shown in the drawing under discussion. These relative terms are for convenience of description only and do not require that the apparatus be constructed or operated in a particular orientation. Terms such as attached, affixed, connected, coupled, interconnected, and similar refer to a relationship wherein structures are secured or attached to one another either directly or indirectly through intervening structures, as well as both movable or rigid attachments or relationships, unless expressly described otherwise.
(21) As used throughout, any ranges disclosed herein are used as shorthand for describing each and every value that is within the range. Any value within the range can be selected as the terminus of the range.
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(23) The steam side of the plant equipment further includes a water-cooled surface condenser 23 which receives exhaust steam from the low pressure section of the turbine 22. A heat exchanger tube bundle assembly 24 comprising a tube bundle 32 having a plurality of heat transfer tubes 26 is mounted in the condenser below the neck in any suitable orientation. The tubes extend substantially from one side the condenser shell 31 to an opposite side. In one non-limiting embodiment, the bundle may be oriented horizontally. The tube bundle assembly 24 further comprises a cooling water inlet nozzle 28 and an outlet nozzle 27 fluidly and physically coupled to an exposed head 29 of the tube bundle assembly positioned outside the condenser shell 31. The head 29 forms an interior channel or flow plenum for receiving and discharging cooling water.
(24) Any type, metallic material, and configuration of tubes 26 suitable for the heat transfer application may be used such as U-bend tubes as illustrated or straight tubes with a return header provided on a distal end of the tube bundle opposite from the head 29. The tube bundle 32 extends internally inside and through the shell 31 of the condenser 23. A two-pass tube arrangement is provided by the U-shaped tubes in which cooling water traverses the width of the condenser shell 31 from side to side twice. Other numbers of passes may be used depending on the heat transfer duty sufficient to condense the steam. The condensed steam is collected in a hotwell in the bottom of the condenser 23 from which a feedwater pump 25 takes suction for returning the feedwater to the steam generator for heating and conversion into steam again, thereby completing the steam cycle water flow loop.
(25) The cooling system 30 includes an air-cooled heat exchanger in the form of an air blast chiller (ABC) 40. In one embodiment, the cooling system 30 defines a cooling water closed flow loop 43 formed by a cooling water pump 66 and flow conduits comprising a cold fluid flow conduit 41 (or cold leg) which receives cooled cooling water discharged by the air blast chiller for condensing steam and a hot fluid flow conduit 42 (or hot leg) which transports heated cooling water from the condenser 23 heated by the steam to the chiller for cooling, thereby completing the cooling cycle flow loop 43. It bears noting that the cooling water flowing inside the closed flow loop 43 is physically and fluidly isolated from the steam flowing through condenser 23. Flow conduits 41, 42 may be formed by piping of suitable diameter and material appropriate for the service conditions encountered.
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(27) Referring to
(28) The pairs of inlet and outlet headers 48, 47 may each be considered tube bundle section headers disposed at opposing ends of the tube arrays. In one arrangement, the inlet headers 48 may be bottom headers disposed at the bottom 50 of the air blast chiller closest to the ground or other flat horizontal support surface, and the outlet headers 47 may be top headers disposed at the top 51 of the chiller spaced above and distally to the support surface, or vice versa. An inlet manifold 46 fluidly couples the inlet headers 48 to the hot fluid flow conduit 42 receiving heated water from the condenser 23, and an outlet manifold 45 fluidly couples outlet headers 47 to the cold fluid flow conduit 41 returning cooled cooling water to the condenser. Manifold 46 bifurcates and distributes the heated cooling water flow to each inlet header 48. Manifold 45 collects and combines the cooled cooling water flow from each outlet header 47. A motorized fan or blower 44 is provided which draws ambient cooling air from the environment and discharges/blows the air upwards through the tube bundles 49 for cooling the cooling water. The headers 47 and 48 may each be considered section headers formed of individual sections of flow conduit such as piping which are physically coupled together.
(29) Each cooling cell 54 of the air blast chiller 40 in one non-limiting embodiment may have a self-supporting triangular or A-frame construction and configuration with a broader bottom base or bottom 50 of the frame than top 51. The A-frame profile of a single cooling unit or cell may comprise two closely spaced proximate parallel outlet headers 47 at the apex of the A-frame and two laterally spaced apart and separated parallel inlet headers 48 at the bottom of the frame disposed distally to each other. The top and bottom headers 47, 48 are parallel to each other. The top outlet headers 47 in one configuration may be laterally spaced apart and closely adjacent as illustrated so that the top headers may be mechanically/structurally fastened together by any suitable fastening method (e.g. tie-plates, struts, etc.) to create a strong truss-like connection at the top. The bottom headers 48 are supported on a steel (or concrete) base frame 52 structure that may also support the blower 44, its motors, gear box and other ancillaries. This construction formed a self-supporting construction. Identical A-frame bundles or cells may be arrayed in a row, each fastened to its contiguous adjoining one via joints 53 located at the ends of each header both at the top and at the bottom. Joints 53 may comprise bolted piping flanges, welded piping connections, or a combination thereof. In one embodiment, bolted flanges are preferred.
(30) Each cooling cell 54 of the air blast chiller 40 may be considered to comprise a first half section 55 including a first inlet header 48, a first outlet header 47, and a first tube bundle 49 comprising a plurality of linearly spaced apart heat transfer tubes 57 extending and fluidly coupled between the first inlet and outlet headers. A second half section 56 includes a second inlet header 48, a second outlet header 47, and a second tube bundle 49 also comprising a plurality of linearly spaced apart tubes 57 extending and fluidly coupled between the second inlet and outlet headers. In the A-frame construction, the first half section 55 is arranged angularly at an included acute angle A1 to the second half section 56. In one embodiment, angle A1 may be between 0 and 90 degrees, and in one non-limiting example may be about 60 degrees. Other angles may be used.
(31) It will be appreciated that the first inlet bundle section header, first tube bundle, and first outlet bundle section header form a first cooling water flow circuit or path through the air blast chiller, and the second inlet bundle section header, second tube bundle, and second outlet bundle section header form a second cooling water flow circuit or path through the air blast chiller which is fluidly isolated from the first flow circuit or path in the cooling cell 54. Accordingly, the half sections 55 and 56 are fluidly isolated.
(32) Advantageously, the air blast chiller half sections 55 and 56, each having a substantially flat profile when fabricated in the shop, allows the air blast chiller 44 to be shipped in multiple half section units to the installation site and then field assembled for form the A-frame. Multiple flat individual half sections 55, 56 each having a substantially flat profile comprised of an inlet header 48, tube bundle 49, and outlet header 47 may be horizontally or vertically stacked on a flat bed truck or rail car for shipment. This beneficially facilitates transportation and maneuvering the half sections to the specific erection location on site which in the case of retrofit installations may have serious space and access constrictions. The pair of top headers 47 may then be mechanically coupled together at the site in the manner described herein to erect the A-frame construction. It bears noting that in conventional air cooled condenser designs, this is not possible since brazing or welding of the tube bundles to the tube sheets of a single outlet header must typically be performed in the fabrication shop controlled environment conditions for leak proof joints. Accordingly, the A-frame arrangement must be shop fabricated and the cooler shipped to the installation site already in V-shaped condition, thereby making transport cumbersome and requiring larger field erection equipment. In addition, regional and local traffic laws governing the truck transport of oversize loads often requires additional and costly measures such as a flag vehicle and/or police escort to accompany the transport vehicle.
(33) In alternative embodiments, it will be appreciated that the two cooling water outlet headers 47 may be replaced by a single outlet header having a longitudinally-extending vertical flow separation plate therein which maintains the flow isolation between the first and second cooling water flow circuits or paths. The separate cooling water flow paths whether created by either of the foregoing first and second half section arrangements helps maintain the desired high tubeside cooling water flow velocities with minimal friction loss in comparison to a single outlet header (not including the longitudinal flow separation plate) that allows the tube outlet flows to comingle instead of remaining isolated.
(34) The tube bundles 49 in one embodiment may be shop manufactured straight tube bundles each comprised closely spaced apart parallel tubes 57 aligned in a linear row. Tubes 57 may have an obround or rectangular cross section and are brazed or welded at opposite ends to a tubesheet 60 of a header manifold 61 which is turn is fixedly attached to an to an inlet or outlet header 47, 48. Tubesheet 60 may be flat in one embodiment. The manifold 61 forms a transition of the flat tubesheet to the arcuately curved sidewalls of the headers 47, 48. Manifold 61 may be a generally rectilinear box-like configuration in one embodiment as illustrated with a bell shape in side view (reference
(35) Because of the stiffness of the rectangular tubes 57, the A-frame geometry is sufficiently self-supporting and rigid to meet the governing structural requirements (snow, wind & earthquake) at most sites. However, braces 63 and/or guy wires, frequently used to strengthen tall columns against winds and earthquakes, may be used to suitably brace the A-frame if required.
(36) The design of the air blast chiller 40 as outlined above involves virtually no welding during site construction and erection. The erection of the chiller at the site is essentially a set of rigging, handling, and fastening steps that require no welding in one embodiment when bolted flanged joints 53 are employed, thus significantly reducing the cooling cell assembly time. Furthermore, because every tube bundle and inlet/outlet header assembly (i.e. half section) is installed by fastening, any damaged bundle (e.g. tornado, storm, or seismic damage) can be easily removed and replaced without affecting structurally sound bundle assemblies. Each cooling cell 54 in some constructions may be transported as a unit to the operating site and assembled to adjoining cells via connecting the bolted flanges of outlet and inlet headers 47, 48 described herein.
(37) The headers, manifolds, tubes, flow conduits, and structural supports in one embodiment may preferably be made of an appropriate metallic material suitable for the service conditions.
(38) In one embodiment, each A-frame cooling cell 54 may be served by a single blower 44 which supplies cooling air to the tube bundles 49. Thus a cell is composed of two multi-pass heat exchangers working in parallel which are cooled by blower 44. In other embodiments shown in
(39) Referring to
(40) In some implementations shown in
(41) As depicted in
(42) The ability to create multi-pass flow patterns provides considerable flexibility in the arrangement and configuration of the array. Advantageously, the tubeside multi-pass flow arrangement maximizes the amount of heat that may be extracted from the ambient cooling air delivered by the blower 44. In some embodiments, using limited quantities of conditioning water introduced as a fine mist spray in the inlet bell of the blower 44 during abnormally hottest hours in the summer would, in most cases, ameliorate the condenser pressure rise driving it to a plant's design basis value. Other methods of cooling augmentation during unusually high ambient temperature such as use of chilled water from another source such as a cooling tower or other can be used.
(43) Various modifications of the air blast chiller 40 described herein may be made in various embodiments and implementation. For example, the two outlet header 47 configuration at the top 51 of the A-frame while preferred to maintain high tubeside flow velocities may nonetheless may be replaced with a single outlet header in some less preferred but acceptable embodiments dependent on the expected service conditions.
(44) In some embodiments contemplated, the tube bundles 49 of the cooling cell 54 may be instead be arranged in a V shape (see, e.g.
(45) In another geometric variation, the single A-shape of a cooling cell 54 may be replaced by a double-A frame configuration as shown in
(46) The adoption of any of the above variations will be dictated by the site specific conditions, among them local wind patterns, earthquake resistance demands, size limitations of the air blast chiller, etc. The foregoing approaches provide significant design flexibility especially for retrofit air blast chiller installations.
(47) While the foregoing description and drawings represent preferred or exemplary embodiments of the present invention, it will be understood that various additions, modifications and substitutions may be made therein without departing from the spirit and scope and range of equivalents of the accompanying claims. In particular, it will be clear to those skilled in the art that the present invention may be embodied in other forms, structures, arrangements, proportions, sizes, and with other elements, materials, and components, without departing from the spirit or essential characteristics thereof. In addition, numerous variations in the methods/processes as applicable described herein may be made without departing from the spirit of the invention. One skilled in the art will further appreciate that the invention may be used with many modifications of structure, arrangement, proportions, sizes, materials, and components and otherwise, used in the practice of the invention, which are particularly adapted to specific environments and operative requirements without departing from the principles of the present invention. The presently disclosed embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being defined by the appended claims and equivalents thereof, and not limited to the foregoing description or embodiments. Rather, the appended claims should be construed broadly, to include other variants and embodiments of the invention, which may be made by those skilled in the art without departing from the scope and range of equivalents of the invention.