Amidoxime Functionalized Polymers Loaded with Alkyl Amines, Methods of Making, And CO2 Capture Using Same

Abstract

A novel adsorbent and contactor material based on polymer functionalized with amidoxime and alkylamines moieties. Methods of making the material are also described. The material can be easily processed into any desired sorbent geometry such as solid fibers, electrospun fibers, hollow fibers, monoliths, etc. The adsorbent exhibits a very high affinity toward acidic gases such CO.sub.2 and can be used in direct air capture, power plant-based CO.sub.2 capture, and industrial CO.sub.2 capture applications. The material can also serve as a contactor that accommodates other adsorbents within its structure.

Claims

1. A sorbent material, comprising: a polymer comprising an amidoxime moiety; and an alkyl amine disposed on a surface of the polymer.

2. The sorbent of claim 1 wherein the amidoxime moiety is covalently bonded to the polymer. This can be represented by the chemical formula R.sup.1C(═N(OH))NR.sup.2R.sup.3, where R.sup.1 is a monomer moiety and the R.sup.1C(═N(OH))NR.sup.2R.sup.3 unit repeats in the polymer.

3. The sorbent of any of the above claims wherein the polymer is a microporous polymer and comprising the alkyl amine disposed on surfaces within pores in the polymer.

4. The sorbent of any of the above claims comprising sorbent fillers.

5. The sorbent of claim 4 wherein the sorbent fillers are selected from: porous silica, porous carbon, porous cage materials, metal organic frameworks, porous organic polymers, and combinations thereof. These are classes of known sorbent materials; porous cage materials may include, for example, compounds such as cyclodextrins.

6. The sorbent of any of the above claims characterizable by an IR spectrum with a broad peak around 3300-3600 and peaks within ±3 wavenumbers of 2240 and 1604 cm.sup.-1.

7. The sorbent of any of the above claims in the form of fibers.

8. The sorbent of claim 7 where the fibers comprise solid fibers, hollow fibers, or electrospun fibers.

9. The sorbent of any of the above claims in the form of a powder.

10. The sorbent of any of claims 1 - 8 in the form of a solid continuous structure having a dimension in at least one direction of at least 1 cm, or at least 5 cm.

any of the above claims comprising at least 3 wt% or at least 5 wt%, or from 5 to 15 wt% CO.sub.2.

12. The sorbent of any of the above claims characterizable by a CO.sub.2 uptake of at least 30 cm.sup.3/g sorbent at 400 mbar CO.sub.2 at 298 K.

13. The sorbent of any of the above claims characterizable by a CO.sub.2 uptake of 30 ±30% (i.e., 21 to 39 \) cm.sup.3/g sorbent at 400 mbar CO.sub.2 at 298 K.

14. The sorbent of any of the above claims comprising the repeating unit R.sup.1C(═N(OH))NR.sup.2R.sup.3, where R.sup.1 is a monomer, R.sup.2 is H, CH.sub.3, or CH.sub.2CH.sub.3, and R.sup.3 is H, CH.sub.3, or CH.sub.2CH.sub.3.

15. The sorbent of claim 14 wherein R.sup.2 is H, and R.sup.3 is H.

16. A method of sorbing a molecular species, comprising: contacting the sorbent material of any of the above claims with a fluid composition comprising the molecular species at a first set of conditions wherein at least a portion of the molecular species in the fluid composition is adsorbed by the sorbent material at the first set of conditions to form the sorbent material with sorbed molecular species.

17. The method of claim 16 further comprising exposing the sorbent material with sorbed component to a second set of conditions; wherein the first set of conditions comprise a first temperature and a first pressure and the second set of conditions comprise a second temperature and second pressure; wherein at least one of the second temperature and second pressure are different than at least one of the second temperature and second pressure; and wherein at least a portion of the molecular species is desorbed from the sorbent at the second set of conditions.

18. The method of any of claims 16 - 17 wherein the fluid composition comprises CO.sub.2 and N.sub.2 and the sorbent material has a CO.sub.2/N.sub.2 selectivity of at least 100, preferably at least 500 or in the range of 200 to 1000.

19-24. (canceled)

25. A method of making a sorbent material, comprising: reacting a polymer having a R.sup.1—C═N (cyano) moiety with HONR.sup.2R.sup.3 to form a polymer with an amidoxime moiety and reacting the polymer with an amidoxime moiety with an alkyl amine.

26. (canceled)

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0009] FIG. 1. Reaction scheme of PIM-1-AO-DETA synthesized by PIM-1 and DETA.

[0010] FIG. 2. (A) CO2 adsorption isotherms of PIM-1, PIM-1-AO, PIM-1-AO-DETA and PIM-1-AO-PEI. (B) CO.sub.2 adsorption cyclability test at 0.15 bar and 298 K, desorption at 348 K under vacuum. (C) CO.sub.2 isosteric heats of adsorption for PIM-1, PIM-1-AO, and PIM-1-AO-DETA.

[0011] FIG. 3. Fiber sorbents processed from a phase inversion method.

DETAILED DESCRIPTION OF THE INVENTION

[0012] In the general case, the polymer can be any polymer comprising an amidoxime moiety. The amidoxime moiety should be on a surface of the polymer such that the alkyl amine can be attracted to the polymer via hydrogen bonding. Preferred polymers include POPs and PIMs (see below). In some preferred embodiments the polymer has a number average molecular weight in the range of 20 to 150 kg/mol. In some preferred embodiments the polymer has a porosity of at least 10 vol%, or at least 20 vol%, or at least 50 vol%. In some embodiments, the polymer has at least 30 vol% of pores in a size range of 0.6 to 1.2 nm; or at least 50 vol% of pores in a size range of 0.6 to 1.2 nm; or 70 vol% of pores in a size range of 0.6 to 1.2 nm.

[0013] Polymer precursors to the inventive sorbent material typically comprise a cyano (CN) group that reacts to form the amidoxime moiety. One preferred PIM can be formed by the reaction of 3,3,3',3'-tetramethyl-1,1'-spirobisindane-5,5',6,6'-tetrol (TTSBI) and 1,3-dicyanotetrafluorobenzene (DCTB).

[0014] Porous sorbents are one class of material being studied for use in carbon dioxide (CO2) capture applications. In the last decade, a new class of porous materials, porous organic polymers (POPs) have emerged, including porous aromatic frameworks (PAFs), porous polymeric networks (PPNs), benzimidazole linked polymers (BILPs) and hyper crosslinked polymers (HPCs). In general, POPs have been reported as high surface area materials with a highly stable polymer structure resulting from the covalent bonding between the monomers. However, the CO.sub.2 uptake capacity of most POPs is not able to exceed twenty (20) cubic centimeters per gram (cc/g) (at 0.15 bar CO.sub.2 and 298 Kelvin (K)), as the interaction between CO.sub.2 and POPs is primarily due to physisorption. Although there have been several efforts to append primary amines to POPs through either amine-impregnation or grafting methods, drawbacks such as harsh synthesis, poor scalability, and poor processability have been a hurdle for POPs as a breakthrough for CO.sub.2 capture.

[0015] Polymers with intrinsic microporosity (PIMs) are POPs that can be synthesized inexpensively and under mild reaction conditions. In contrast to most POPs, PIMs can be processed into thin films and fibers. Consequently, studies on PIMs have focused on gas separation membrane applications in which they feature exceptionally high permeability and moderate selectivity for several different light gas pairs. Although PIM-based membranes have been among the best performing gas separation materials, little is known about PIMs as solid sorbents for CO.sub.2 capture or other gas separations. While PIMs possess the high surface area and permanent microporosity desired for a sorbent, they also suffer from low CO2 adsorption capacity (less than 10 cc/g at 0.15 bar and 298 K) due to relatively large (greater than 1 nm) non-polar micropores as well as some mesopores.

[0016] The amidoxime moiety has the formula —C(═N(OH))NR.sup.2R.sup.3. R.sup.2 and R.sup.3 can be the same or different and are selected from H, alkyls or substituted alkyls (including alkenes or alkynes); preferably methyl, ethyl, propyl or butyl; most preferably R.sup.2 and R.sup.3 are H. The hydroxyl hydrogen may be shared with an amino group on the alkyl amine.

[0017] The alkyl amine comprises an amine (-NHR) moiety that is part of a larger molecule comprising at least one carbon. Preferably the alkyl amine has a molecular weight of between 31 and 300 daltons, or 31 and 200 daltons. Preferably, the alkyl amine comprises between 2 and 5 amine groups. Examples of alkyl amines include: diethylenetriamine (DETA), tetraethylenepentamine (TEPA), tetraethylenepentamine-acrylonitrile (TEPAN), ethylenediamine, ethylamine, aniline, benzylamine, piperidine, pyrrole, diethanolamine (DEA), monoethanolamine (MEA), triethylenetetramine (TETA), 2-amino-2-methyl-1-propanol (AMP), and 2-(isopropylamino)ethanol (IPAE).

[0018] The invention discloses a sorbent functionalized with amidoxime and alkylamines. The invention discloses a unique synthesis protocol which can be applied not only to the utilized polymer (PIM-1), but also a library of other polymers and even other non-polymeric materials to create a new sorbent. The method is cost efficient and scalable.

[0019] The invented sorbent can possess very high CO.sub.2 capture performance compared to other polymeric sorbents. To our knowledge, the CO.sub.2 uptake capacity is the highest ever recorded in any PIM based porous polymeric sorbent and amidoxime functionalized sorbents (polymers and others). The invented sorbent can be processed into any sorbent geometries including fiber, monolith, flat sheet, pellets, etc.

[0020] Amidoxime functionalization can be incorporated into a wide variety of polymer types. The amidoxime functionality, surface area and pore size properties can be easily adjusted for CO2 sorption and other applications. Other applications of the sorption media include: rare earth elements capture; precious and/or toxic metal capture; membrane based gas and liquid separation; gas storage; solid state energy storage; and gas sensor applications. The invention includes use of the sorbent material in any of these applications.

[0021] The sorbent or sorbent precursor is processible in a molten or dissolved state. The sorbent can be converted into several sorbent geometries such as fibers (FIG. 3). A difference between this invention and prior best performing sorbents such as zeolites, silica and MOFs is the advantage of not having a need for an additional processing material (polymers, etc.) in the system. The inventive sorbent is preferably soluble in organic solvents including DMF, NMP, DMSO and DMAc. In the sorbent literature, it has been increasingly suggested that the fiber form of the sorbents can decrease the carbon capture cost significantly as the pressure drop problem is less encountered in the fiber forms compared to powder sorbents. The maximum sorbent loading is usually below 50 wt% (of the actual sorbent), so the CO.sub.2 uptake performance is curbed by at least 50% as the processing materials are mostly a non-sorbent. This invention offers a solution to this challenge by creating a processible sorbent material that consists chiefly (>50 mass%) or entirely of the sorbent material. In preferred embodiments of the invention, the sorbent material comprises 10 wt% or less, or 5 wt% or less, of polymers other than the functionalized polymer. In other embodiments, the sorbent material can be combined with a material such as polyphosphazene.

[0022] The synthesis comprises a three-step sorbent preparation method (FIG. 1). In the first step, the CN-functionalized polymer is provided or synthesized. In the second step, the polymer is functionalized with amidoxime groups by using a hydroxylamine reagent. This step can be effected using a low-temperature reaction method and low cost reagents. The use of a nonsolvent (methanol) in the reaction is important in this second step as the nucleophilic attack of the hydroxylamine reagent can be controlled. The controlled reaction provides precise adjustability over the amidoxime functionalities. In the third step, the amidoxime functionalized polymer (such as PIM-1-AO) is treated with alkylamines such as DETA. The proposed sorbent preparation method provides a scalable and cost-efficient material synthesis.

[0023] The invention is designed on the effective use of amidoxime groups in a sorbent media. The amidoxime groups can strongly interact with the host amine molecules. The strong interaction between the amidoxime and amine groups immobilizes the amine molecules within the sorbent, thus the major problems associated with amine based sorbent can be eliminated. For example; amine leaching, which is often encountered with sorbents, is limited in this invention given the unique design of the sorbent. Another attribute of the use of amidoxime in the sorbent is enabling molecular amine utilization which offers great sorbent attributes such as fast kinetics and low temperature CO.sub.2. Most of the amine based sorbents depend on polymeric amines such as polyethylenimine (PEI). These polymeric amines provide high CO.sub.2 uptake capacity. However, the amines also bring deficiencies to the impregnating sorbent including worsen mass and heat transfer character. CO.sub.2 transport (adsorption and desorption) in bulk polymeric amines is relatively slow. Our sorbent design provides molecular amines in the sorbent which can interact strongly with amidoxime functional groups.

[0024] The invention is experimentally proven and characterized by common sorbent instruments including surface area analyzer, FT-IR, TGA and elemental analysis. The chemical structure was confirmed by IR absorption for —OH, nitrile, and N—H with a broad peak around 3300-3600 and peaks at 2240, 1604 cm-1, respectively. The amine content in the sorbent was quantified by TGA and elemental analysis. The amine presence in the sorbent was also evinced by CO.sub.2 adsorption and desorption isotherms. Accordingly, a large hysteresis, observed between the isotherms, addresses the chemisorption nature of the sorbent due to the incorporated alkylamines. Typically, the amine content in the characterized sorbents is below 15 wt%, which is drastically lower than the usual amine (40-80 wt%) reported in sorbents. The low amine content contributes to the desired sorbent properties such as fast kinetics and low cost sorbent regeneration.

[0025] The invention was tested with two different (commercial) gas adsorption analyzers. Very high CO2 uptake performance (10 wt% CO.sub.2 at 0.15 bar and 298 K) was recorded (FIG. 2A). Moreover, the CO2 uptake capacity was cyclable after several regeneration steps (FIG. 2B). The CO2/N2 selectivity was found to be also very high (>500). The heats of adsorption for CO.sub.2 were calculated from the CO.sub.2 isotherms and the results revealed that the sorbent is a chemisorbent (FIG. 2C).