SEPARATOR PLATE AND ELECTROCHEMICAL CELL
20230058717 · 2023-02-23
Inventors
- Rainer GLUECK (Dornstadt-Tomerdingen, DE)
- Thomas KINDER (Staig, DE)
- Horst GEHRING (Orsenhausen, DE)
- Thomas Stoehr (Laupheim, DE)
Cpc classification
Y02E60/50
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01M8/0267
ELECTRICITY
H01M8/0258
ELECTRICITY
H01M8/188
ELECTRICITY
International classification
H01M8/0258
ELECTRICITY
Abstract
A separator plate for an electrochemical system, comprising a first and a second metal layer arranged with flat sides adjacent to each other. The first and the second metal layer each having at least one through-opening for supplying and/or discharging a fluid. Circumferential edges of the through-openings are formed at least in part by a half-bead. An open edge of the half-bead is angled so as to form a collar.
Claims
1. A separator plate for an electrochemical system, comprising: a first and a second metal layer which are arranged with a respective one of their flat sides adjacent to each other, wherein the first and the second metal layer each have at least one through-opening for supplying and/or discharging a fluid, said through-openings being arranged in pairs at least substantially coaxially with respect to their axial direction of passage and form a passage opening for the fluid to pass through the separator plate, wherein the circumferential edges of the through-openings of a respective pair of through-openings have a half-bead which at least in part forms the circumferential edge of the respective through-opening and projects out of the layer plane of the respective metal layer in a direction away from the adjacent metal layer, wherein the open edge of the half-bead of each of the metal layers is angled in the direction of the layer plane of the respective metal layer so as to form a collar.
2. The separator plate according to claim 1, wherein for at least one of the through-openings, a sealing bead which extends around the respective through-opening is arranged on the side of the half-bead remote from the respective through-opening.
3. The separator plate according to claim 2, wherein for at least one of the through-openings, the sealing bead has along its course, at least in a first portion, at least one passage which in cross-section extends through the sealing bead from one side of the sealing bead to the opposite side of the sealing bead, wherein the collar is formed only in portions adjacent to the passage and/or adjacent to the first portion.
4. The separator plate according to claim 1, wherein the outer circumferential edge of the first metal layer and the outer circumferential edge of the second metal layer each have a half-bead which at least in part forms the respective circumferential edge and projects out of the layer plane of the respective metal layer in a direction away from the adjacent metal layer, wherein the open edge of this half-bead of each of the metal layers is angled in the direction of the layer plane of the respective metal layer so as to form a collar.
5. The separator plate for an electrochemical system, comprising: a first and a second metal layer which are arranged with a respective one of their flat sides adjacent to each other, wherein the outer circumferential edge of the first metal layer and the outer circumferential edge of the second metal layer each have a half-bead which at least in part forms the respective circumferential edge and projects out of the layer plane of the respective metal layer in a direction away from the adjacent metal layer, wherein the open edge of the half-bead of each of the metal layers is angled in the direction of the layer plane of the respective metal layer so as to form a collar.
6. The separator plate according to claim 1, wherein the first and the second metal layer enclose between them a cooling region for guiding a cooling medium along a flat side of the metal layers.
7. The separator plate according to claim 1, wherein the first and the second metal layer each have, on the flat side thereof remote from the adjacent metal layer, channel structures for forming a flow field for a fluid.
8. The separator plate according to claim 1, wherein for at least one of the through-openings and/or for the outer circumferential edges, the collar of the first metal layer and the collar of the second metal layer are arranged along at least part of the respective circumferential edge in an adjacent and overlapping manner.
9. The separator plate according to claim 1, wherein for at least one of the through-openings and/or for the outer circumferential edges, the collar of the first and/or the second metal layer projects at least in part beyond the layer plane of the respective metal layer.
10. The separator plate according to claim 1, wherein for at least one of the through-openings and/or for the outer circumferential edges, the flank of the half-bead of the first and/or the second metal layer extends over more than 50% of its length outside of the first portion, at an angle α to the layer plane of the respective metal layer, where 20°≤α≤80°.
11. The separator plate according to claim 1, wherein for at least one of the through-openings and/or for the outer circumferential edges, the collar of the first and/or the second metal layer extends over more than 50% of its length, outside of the first portion, at an angle β to the layer plane of the respective metal layer, where 70°≤β≤130°.
12. The separator plate according to claim 1, wherein for at least one of the through-openings and/or for the outer circumferential edges, the collar of the first and/or the second metal layer along the circumferential edge of the through-opening and/or along the outer circumferential edge forms at least in part the boundary of the fluid-guiding through-opening and/or of the outer circumferential edge.
13. The separator plate according to claim 1, wherein for at least one of the through-openings and/or for the outer circumferential edges, the collar of the respective metal layer has one or more slots starting from the layer edge surrounding the through-opening or the outer circumferential edge in the first and/or second metal layer.
14. The separator plate according to claim 13, wherein for at least one of the through-openings and/or for the outer circumferential edges, the slots extend substantially perpendicular to the layer edge.
15. The separator plate according to claim 13, wherein for at least one of the through-openings and/or for the outer circumferential edges, the slots have a length that is less than or equal to the width of the respective collar.
16. The separator plate according to claim 13, wherein for at least one of the through-openings and/or for the outer circumferential edges, the slots are arranged along the circumferential edge.
17. The separator plate according to claim 1, wherein for at least one of the through-openings and/or for the outer circumferential edges, at least in part or all the way round, the ends of the collars of substantially coaxially arranged through-openings and/or of the outer circumferential edges of the first and the second metal layer overlap one another so as to form at least one overlap region and/or are arranged offset from one another in a direction perpendicular to the layer plane of the first and/or the second layer.
18. The separator plate according to claim 1, wherein for at least one of the through-openings and/or for the outer circumferential edges, the collars of the first metal layer and the second metal layer are not arranged relative to one another in a form-fitting manner.
19. The separator plate according to claim 1, wherein for through-openings arranged substantially coaxial to one another and/or for the outer circumferential edges, the flank of the half-bead of the first metal layer and the flank of the half-bead of the second metal layer are arranged at different positions perpendicular to the bead running direction, which extends along the respective circumferential edge of the through-opening and/or along the outer circumferential edge.
20. An electrochemical system comprising a plurality of separator plates claim 1, wherein the plurality of separator plates are stacked perpendicular to the layer plane of the first and/or to the layer plane of the second metal layer.
Description
BRIEF DESCRIPTION OF THE FIGURES
[0032]
[0033]
[0034]
[0035]
[0036]
[0037]
[0038]
[0039]
DETAILED DESCRIPTION
[0040]
[0041] Each MEA 10 contains at least one membrane, for example an electrolyte membrane. Furthermore, a gas diffusion layer (GDL) may be arranged on one or both surfaces of the MEA. Adjacent separator sub-plates, which are not separated from one another by an MEA, form a separator plate according to the present disclosure with the two separator sub-plates as a first and second metal layer, which separator plate separates two electrochemically active fields from one another.
[0042] In alternative embodiments, the system 1 may also be designed as an electrolyzer, as an electrochemical compressor or as a redox flow battery. Separator plates may likewise be used in these electrochemical systems. The structure of these separator plates may then correspond to the structure of the separator plates 2 explained in detail here, although the media guided on and/or through the separator plates in the case of an electrolyzer, an electrochemical compressor or a redox flow battery may differ in each case from the media used for a fuel cell system.
[0043] The z-axis 7, together with an x-axis 8 and a y-axis 9, spans a right-handed Cartesian coordinate system. The separator plates 2 each define a plate plane, wherein the plate planes of the separator plates or of the layers 2a, 2b thereof are each oriented parallel to the x-y plane and thus perpendicular to the stacking direction or to the z-axis 7. The end plate 4 usually has a plurality of media ports 5, via which media can be fed to the system 1 and via which media can be discharged from the system 1. Said media that can be fed to the system 1 and discharged from the system 1 may comprise for example fuels such as molecular hydrogen or methanol, reaction gases such as air or oxygen, reaction products such as water vapor or depleted fuels, or coolants such as water and/or glycol.
[0044]
[0045] The bipolar plate 2 is formed of two separator sub-plates or layers 2a, 2b which are joined together in a materially bonded manner, of which in each case only the first separator sub-plate 2a facing towards the viewer is visible in
[0046] The separator sub-plates 2a, 2b typically have through-openings which are aligned with one another and form through-openings 11a-c of the separator plate 2. When a plurality of separator plates of the same type as the separator plate 2 are stacked, the through-openings 11a-c form lines which extend through the stack 6 in the stacking direction 7 (see
[0047] In order to seal off the through-openings 11a-c with respect to the interior of the stack 6 and with respect to the surrounding environment, the first separator sub-plates 2a each have sealing arrangements in the form of sealing beads 12a-c, which are respectively arranged around the through-openings 11a-c and in each case completely surround the through-openings 11a-c. On the rear side of the separator plates 2, facing away from the viewer of
[0048] In an electrochemically active region 18, the first separator sub-plates 2a have, on the front side thereof facing towards the viewer of
[0049] The sealing beads 12a-12c have passages 13a-13c, of which the passages 13a are formed both on the underside of the upper separator sub-plate 2a and on the upper side of the lower separator sub-plate 2b, while the passages 13b are formed in the upper separator sub-plate 2a and the passages 13c are formed in the lower separator sub-plate 2b. By way of example, the passages 13a enable coolant to pass between the through-opening 12a and the distribution or collection region 60, so that the coolant enters the distribution or collection region 60 between the separator plates 2a, 2b and is guided out therefrom.
[0050] Furthermore, the passages 13b enable hydrogen to pass between the through-opening 12b and the distribution or collection region on the upper side of the upper separator sub-plate 2a; these passages 13b are characterized by perforations facing towards the distribution or collection region and extending at an angle to the plate plane. By way of example, hydrogen thus flows through the passages 13b from the through-opening 12b to the distribution or collection region on the upper side of the upper separator sub-plate 2a, or in the opposite direction.
[0051] The passages 13c enable air, for example, to pass between the through-opening 12c and the distribution or collection region, so that air enters the distribution or collection region on the underside of the lower separator sub-plate 2b and is guided out therefrom. The associated perforations are not visible here.
[0052] The first separator sub-plates 2a each also have a further sealing arrangement in the form of a perimeter bead 12d, which extends around the flow field 17 of the active region 18 and also around the distribution or collection region 60 and the through-openings 11b, 11c and seals these off with respect to the through-opening 11a, that is to say with respect to the coolant circuit, and with respect to the environment surrounding the system 1. The second separator sub-plates 2b each comprise corresponding perimeter beads 12d. The structures of the active region 18, the distributing or collecting structures of the distribution or collection region 60 and the sealing beads 12a-d are each formed in one piece with the separator sub-plates 2a and are integrally formed in the separator sub-plates 2a, for example in an embossing, hydroforming or deep-drawing process. The same applies to the corresponding distributing structures and sealing beads of the second separator sub-plates 2b. Each sealing bead 12a-12d may have in cross-section at least one bead top and two bead flanks, but a substantially angular arrangement between these elements is not necessary; a curved transition may also be provided.
[0053] While the sealing beads 12a-12c take a substantially round course, the perimeter bead 12d has various portions of different shape. For instance, the course of the perimeter bead 12d may comprise at least two wavy portions.
[0054] The two through-openings 11b or the lines through the plate stack of the system 1 that are formed by the through-openings 11b are each fluidically connected to one another via passages 13b in the sealing beads 12b, via the distributing structures of the distribution or collection region 60 and via the flow field 17 in the active region 18 of the first separator sub-plates 2a facing towards the viewer of
[0055] In contrast, the through-openings 11a or the lines through the plate stack of the system 1 that are formed by the through-openings 11a are each fluidically connected to one another via a cavity 19 which is surrounded or enclosed by the separator sub-plates 2a, 2b. This cavity 19 serves in each case to guide a coolant through the separator plate 2, such as for cooling the electrochemically active region 18 of the separator plate 2. The coolant thus serves primarily to cool the electrochemically active region 18 of the separator plate 2. The coolant flows through the cavity 19 from an inlet opening 11a towards an outlet opening 11a. Mixtures of water and antifreeze are often used as coolants. However, other coolants are also conceivable. For guidance of the coolant or cooling medium, second structures are present on the inner side of the separator plate 2. Said second structures are not visible in
[0056] The separator plate according to the present disclosure comprises two metal layers, which correspond to directly adjacent separator sub-plates 2a and 2b of different separator plates in
[0057] The inventive design of edge regions around through-openings or at outer edges of separator plates will be presented below. With regard to the technical explanation, it is irrelevant whether the edge region is an edge region of through-openings or an outer edge region.
[0058] The individual metal layers are therefore denoted by reference signs 20a, 20b, 20c and 20d, wherein 20a and 20b form a separator plate according to the present disclosure and 20c and 20d form a separator plate according to the present disclosure. Sealing beads are denoted by reference signs 21a, 21b, 21c and 21d, the half-beads according to the present disclosure are denoted by reference signs 22a, 22b, 22c and 22d, the rims at the circumferential edge or outer edge are denoted by reference signs 23a, 23b, 23c and 23d, and the collars are denoted by reference signs 24a, 24b, 24c and 24d. In general, therefore, the metal layers are denoted by reference sign 20 in addition to reference signs 2a and 2b from
[0059]
[0060]
[0061]
[0062] The collars 24a and 24b overlap as seen in the layer plane Ea, Eb of the layers 20a and 20b or of the MEA 10. This offset between the two collars 24a and 24b in the cross-section of the layers 20a and 20b is created by arranging the half-bead 22a with its bead foot closer to an adjacent sealing bead 21a than the half-bead 22b to an adjacent sealing bead 21b extending symmetrically to the sealing bead 21a. However, the bead top of the half-beads 22a and 22b is of equal length in the radial direction around the exterior 30.
[0063] The collar 24b, which extends into the interior space of the half-bead 20a and is radially further away from the region 30 than the collar 24a, is wider than the collar 24a in the example of
[0064] Embodiments of collars 24a and 24b each may have a width which ensures that their free ends overlap even in the compressed state, even when the half-beads gape open, in order to ensure a sufficient distance of the collar 24a from the MEA 10 even under compression. To this end, the collars 24a and 24b are wider in total than the distance between the bead tops of the half-beads 22a and 22b, for instance at least 20% wider. Furthermore, as a result of the collars 24a, 24b, the through-openings have defined outer walls at least over large portions along their course, which lead to low turbulence and thus low pressure losses of the media guided in the through-openings.
[0065] The collars 24a, 24b, 24c and 24d are schematically shown in
[0066] The edges of the layers 20c and 20d are also designed in a manner corresponding to the edges of the layers 20a and 20b.
[0067]
[0068]
[0069] Furthermore, the collars 24a and 24b do not extend at a right angle to the adjacent bead tops of the half-beads 22a and 22b in the respective same layer 20a and 20b, respectively, but instead extend at an enclosed angle between the bead top and the collar of more than 90°.
[0070] The preceding three embodiments each show half-beads and collars with sharp rims; this is a simplification for the sake of the drawing. In actual fact, all the rims are rounded or formed with a radius that is set during the shaping. Furthermore, all the exemplary embodiments are shown with a straight or flat bead roof; in actual fact, use can also be made of bead tops that are rounded or domed in cross-section.
[0071]
[0072] For clarity, the MEA 10 below the layer 20a and above the layer 20b has not been shown. The design of the edges of the layers 20a and 20b around the opening 30 corresponds to that in
[0073]
[0074]
[0075]
[0076]
[0077]
[0078] Embodiments of the collars (for example 24a, 24b, 24c and 24d) only have to be arranged along part of the circumferential edge of the through-opening or along part of the outer edge of the respective metal layer. In addition, it is possible that adjacent, mutually facing collars of adjacent layers only overlap in part.
[0079]
[0080] It will be appreciated that the configurations and routines disclosed herein are exemplary in nature, and that these specific embodiments are not to be considered in a limiting sense, because numerous variations are possible. Moreover, unless explicitly stated to the contrary, the terms “first,” “second,” “third,” and the like are not intended to denote any order, position, quantity, or importance, but rather are used merely as labels to distinguish one element from another. The subject matter of the present disclosure includes all novel and non-obvious combinations and sub-combinations of the various systems and configurations, and other features, functions, and/or properties disclosed herein.
[0081] As used herein, the term “approximately” or “substantially” is construed to mean plus or minus five percent of the range unless otherwise specified.
[0082] The following claims particularly point out certain combinations and sub-combinations regarded as novel and non-obvious. These claims may refer to “an” element or “a first” element or the equivalent thereof. Such claims should be understood to include incorporation of one or more such elements, neither requiring nor excluding two or more such elements. Other combinations and sub-combinations of the disclosed features, functions, elements, and/or properties may be claimed through amendment of the present claims or through presentation of new claims in this or a related application. Such claims, whether broader, narrower, equal, or different in scope to the original claims, also are regarded as included within the subject matter of the present disclosure.