Filling material, a sealing structure and a method of making the sealing structure
10119054 ยท 2018-11-06
Inventors
Cpc classification
B22F7/08
PERFORMING OPERATIONS; TRANSPORTING
B22F1/103
PERFORMING OPERATIONS; TRANSPORTING
B22D45/00
PERFORMING OPERATIONS; TRANSPORTING
C09K3/1006
CHEMISTRY; METALLURGY
B22F1/102
PERFORMING OPERATIONS; TRANSPORTING
B22F3/24
PERFORMING OPERATIONS; TRANSPORTING
International classification
F16J9/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B22D45/00
PERFORMING OPERATIONS; TRANSPORTING
B22F1/00
PERFORMING OPERATIONS; TRANSPORTING
B22F7/08
PERFORMING OPERATIONS; TRANSPORTING
C09K3/10
CHEMISTRY; METALLURGY
Abstract
A liquid epoxy resin, a powdered metal and a hardening agent are provided as a filling material (S) and poured into an insert hole (82). The filling material (S) is in a liquid state under a normal temperature so as to make the filling material (S) handle easily in the filling work. The filling material (S) is hardened at a clearance between a bushing tool (12) and the insert hole (82). The filling material (S) is placed between the bushing tool (12) and the insert hole (82) to enhance a heat-conductivity therebetween. By heat treating a metallic mold die 80, it is possible to char the epoxy resin. This makes it possible to deposit the powdered metal (copper or the like) over an entire area of the clearance so as to highly enhance the heat-conductivity.
Claims
1. A method of making a sealing structure for a filling material in which said filling material is provided on a device body having an insert hole, a bottom portion of which has a semi-spherical end portion, said device body further having a bushing tool in a cylindrical configuration to form a sealing space between an outer surface of said bushing tool and an inner surface of said insert hole, said filling material having a liquid epoxy resin, a powdered metal and a hardening agent in which said epoxy resin is hardened by said hardening agent, or said epoxy resin is hardened by said hardening agent and concurrently said epoxy resin being charred by a heat treatment after hardened; said method comprising steps of: providing said filling material into said insert hole; inserting said bushing tool into said insert hole, said bushing tool having an outer diameter corresponding to an inner diameter of said insert hole, and having a leading end which has a semi-spherical end portion corresponding to said semi-spherical end portion of said insert hole; pushing said bushing tool into said insert hole by a predetermined amount as a tight-fitting engagement procedure and hardening said epoxy resin to tightly provide said epoxy resin at said sealing space between said bushing tool and said insert hole; and further heat treating said device body, so that said filling material is solidified at said sealing space to produce said powdered metal with said epoxy resin charred with said powdered metal isolated from oxygen in the atmosphere.
2. The method of making the sealing structure for the filling material method according to claim 1, wherein said hardening agent is de-natured polyamine.
3. The method of making the sealing structure for the filling material method according to claim 1, wherein an noncombustible agent is contained.
4. The method of making the sealing structure for the filling material method according to claim 1, wherein said noncombustible agent is a phosphorous-based substance or a halogen-based substance.
5. The method of making the sealing structure for the filling material method according to claim 1, wherein said powdered metal has grains, size of which is more than 1 m in diameter.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) A preferred form of the present invention are illustrated in the accompanying drawings in which:
(2)
(3)
(4)
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DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS
(8) In the following description of the depicted embodiments to carry out the invention, described are a filling material, a sealing structure and a method of making the sealing structure.
(9) Referring to
(10) The epoxy resin categorically represents aromatic epoxy resin, aliphatic epoxy resin, alicyclic epoxy resin and the like (referred merely to as epoxy resin hereinafter). More specific, bisphenol A type epoxy resin or bisphenol AD type epoxy resin is preferable, and more preferable is bisphenol F type epoxy resin with a lower viscosity.
(11) The epoxy resin has a harden-shrinkage ratio lower than that of metals (zinc, tin, lead or the like) which has low melting points, and having an adherence force stronger than a polyester resin. The harden-shrinkage ratio (solidification ratio) of the epoxy resin is 0.1%, while the metals (e.g., soldering metals) having low melting points are around 1-2%. The adherence force of the epoxy resin is 20 mPa-40 mPa and the adherence force of the polyurethane and the polyester resin are 10 mPa-20 mPa. Namely, the epoxy resin has the adherence force approximately twice as strong as that of the polyurethane.
(12) The epoxy resin, according to the present invention, the filling material has the epoxy resin as a main ingredient and having powdered metal in addition to a liquid or powdered hardening agent. The epoxy resin is used to act as a binder for the powdered metals. The powdered metals are represented by stainless steel, iron, copper or zinc. Among the powdered metals, zinc is preferable as an anti-rust agent, and copper is preferable as a high heat-conductivity agent.
(13) In general, zinc is ionized and oxidated earlier than iron to form an anti-rust film which prevents zinc from being eroded. From the ionized point of view, the powdered zinc has the anti-rust effect for copper and iron and having a heat-conductivity higher than iron and stainless steel. As for the powdered zinc which is oxidizable and combustible, it is necessary to isolate the powdered zinc from oxygen in the atmosphere. For this purpose, the powdered zinc is mixed within the epoxy resin to coat the surface of the powdered zinc with the epoxy resin. It is to be noted that a hardening agent may be added to the epoxy resin while mixing the powdered zinc with the epoxy resin.
(14) Since the thermo-grease has approx. 8.2 W/m.Math.K at heat-conductivity, it is preferable to use stainless steel (24 W/m.Math.K), iron (84 W/m.Math.K), zinc (383 W/m.Math.K) and copper (403 W/m.Math.K), each of which has the heat-conductivity higher than the thermo-grease. As for the weight percentage of the powdered metal and the epoxy resin, it is preferable that the powdered metal contains more than 85-95% by weight and that the epoxy resin contains less than 15-5%.
(15) The powdered metal contains a grain size greater than 1 m in diameter. When applied to a metallic mold die 80 as described hereinafter in detail, it is preferable to render the powdered metals to have the grain size more than e.g., 4 m-100 m in diameter, considering a size of the clearance (e.g, 0.1-0.5 mm in width) between the bushing tool 12 and a cooling hole 82 (insert hole). More preferably, the powdered metals have the grain size of 4 m-50 m in diameter. It is possible to mix the powdered metal having two types of grain sizes (e.g., 40 m and 4 m).
(16) In this situation, the grains (4 m) fill up the intergranular space of the grain size (40 m). The powdered metal may be one selected from powdered stainless steel, powdered iron, powdered copper or powdered zinc. Otherwise, the powdered metal may be a powdery mixture compound appropriately combined among the powdered stainless steel, powdered iron, powdered copper and powdered zinc.
(17) It is preferable to render the hardening agent to have de-natured polyamine such as, for example, de-natured polyamide-amine, de-nature aliphatic polyamine and de-nature alicyclic polyamine. The liquid de-natured polyamine renders the epoxy resin to have a lower viscosity and harden the epoxy resin under the normal temperature.
(18) As a mixing ratio of hardening agent (e.g., de-natured polyamine), it is preferable that the hardening agent may have 3-10% by weight against the filling material S and the powdered metal. The hardening process advances against the epoxy resin by reacting the active hydrogen to the epoxy base to form secondary amine which reacts to the epoxy base.
(19) In order to render the hardening agent to the bridged polymer, it is necessary for the hardening agent to have more than three active hydrogen atoms and three amino bases in a single molecule. Namely, the epoxy resin has one compound having two or more epoxy bases and another compound (polyamide, polyamine) having two or more active hydrogen atoms (NH.sub.2, NH, CONH) which are combined each other to form a stereo-structure (three-dimensional mesh structure) through the addition polymerization reaction. It is to be noted that the polyamine has a hardening speed changing depending on the blending quantity, types of the polyamine and types of the epoxy resin.
(20) The filling material S contains a noncombustible agent for fear that the epoxy resin would not be hardened. As the noncombustible agent, preferably prepared is a phosphorous-based substance or a halogen-based substance. Preferably, the noncombustible agent may have 0.5-1.0% by weight against the epoxy resin and the powdered metal.
(21) The halogen-based substances which contain a toxic compound are represented by bromic-based (e.g., pentabromo-phenylether), fluoro-based and chloric-based substances. The phosphorous-based substances (inorganic noncombustible substances) which contain a non-toxic compound are preferably represented by antimony trioxide, aluminum hydroxide and magnesium hydroxide.
(22) Sealing Structure with the Use of Filling Material
(23) As for a sealing structure used for cooling the metallic mold die 80 and a method of making the sealing structure, the sealing structure is especially employed to a metal die cooling mechanism 10 for the metallic mold die 80.
(24) As shown in
(25) At an upper side of the cooling hole 82, a female-thread portion 83 is provided. An axial bore 82A is provided consecutively to the female-thread portion 83 to form the cooling hole 82 as a whole. The cooling hole 82 has an inner diameter indentical to an inner diameter of the axial bore 82A. At the bottom of the axial bore 82A (cooling hole 82), a semi-spherical end portion 82B is formed.
(26) Rather than the cooling hole 82 has a bore diameter identical to the outer diameter of the bushing tool 12, the cooling hole 82 has a bore diameter corresponding to the outer diameter of the bushing tool 12. The cooling hole 82 has a bore diameter slightly greater than the outer diameter of the bushing tool 12, so that the bushing tool 12 can be inserted into the cooling hole 82. The cooling hole 82 has an inner surface undulated as tool marks in a concave and convex fashion caused by the boring operation.
(27) By inserting the bushing tool 12 into the cooling hole 82, a clearance 14 is formed between an inner surface of the cooling hole 82 and an outer surface of the bushing tool 12 as shown in
(28) Cooling Mechanism for Metallic Mold Die
(29) As shown in
(30) Structure for Bushing Tool
(31) As shown in
(32) As shown in
(33) As shown in
(34) As also shown in
(35) The flange portion 18 has a hexagonal wrench hole 18A, to which the Allen wrench (a.k.a. a hexagonal wrench, but not shown) is applied. The wrench hole 18A lies in registration with the male-threaded portion 20. Below the wrench hole 18A, the flange portion 18 has a female-threaded portion 18B to be in communication with the wrench hole 18A.
(36) The female-threaded portion 18B is adapted to mesh with a male-threaded portion 34A which is provided on an outer surface of the coupler pipe 24 as shown in
(37) The bushing tool 12 is integrally formed by a high-tension steel metal sheet such as, for example, a mild steel metal by means of the pressing procedure. It is noted that the bushing tool 12 16 may be formed by means of a boring procedure or swaging procedure, in lieu of the pressing procedure.
(38) Structure for Lock Nut
(39) A lock nut 22 is provided to mesh with the female-threaded portion 83 of the cooling hole 82, so as to prevent the male-threaded portion 20 from being inadvertently loosened. The lock nut 22 has a hexagonal wrench hole 22A formed similar to the wrench hole 18A of the flange portion 18.
(40) For this reason, it is possible to concurrently secure the lock nut 22 and the bushing tool 12 by putting the hexagonal wrench into the wrench holes 18A, 22A at the same time.
(41) Structure for Coupler Pipe
(42) As shown in
(43) A drainage connector 32 is to guide the heat-exchanged drain water toward an exhaust basin (not shown). Connected to the drainage connector 32 is a watershoot pipe 34. To the supply connector 28, a water-communicating pipe (not shown) is connected which comes from a water source (e. g., faucet of waterworks). The coupler pipe 24 extends the supply pipe 30 to a proximity of a semi-spherical bottom end portion 16C of the bushing tool 12 as shown in
(44) Into the wrench holes 18A, 22A, a columnar support pipe 26 is inserted to be held upright as shown in
(45) To an outer surface of the watershoot pipe 34, a male thread portion 34A is formed. The support pipe 26 is formed into a circular cylinder, so that the support pipe 26 is inserted into and extended through the wrench holes 18A, 22A.
(46) Method of Making Sealing Structure
(47) As for the method of making the sealing structure for cooling the metallic mold die (method of assembling the sealing structure in concrete terms). In this method, a filling step is provided to supply the filling material S into the cooling hole 82 (refer to
(48) Filling Step
(49) In the filling step, a predeterminately calculated quantity (e.g., 35 gram) of the filling material S is supplied to the cooling hole 82. The calculated quantity of the filling material S is such that the filling material S reaches near an uppermost end of the female-thread portion 83 when the bushing tool 12 is pushed into the cooling hole 82.
(50) The filling material S is liquid under the normal temperature which makes it possible to handle the filling material S with ease at the filling operation. Namely, the filling step can be done with a simplified procedure only to flow the filling material S into the cooling hole 82.
(51) Inserting Step
(52) At the inserting step, the bushing tool 12 is inserted into the cooling hole 82 as shown at the phantom line in
(53) With the use of the hexagonal wrench or the like, the male-threaded portion 20 is secured to the female-threaded portion 83. The lock nut 22 is further tightened to the bushing tool 12 until the lock nut 22 comes its upper surface to be in flush with the cavity surface 81B of the metallic mold die 80.
(54) In this situation, a remnant space (distance L2) is established between a lowermost end of the semi-spherical end portion 12C of the bushing tool 12 and a lowermost end of the semi-spherical end portion 82B of the cooling hole 82.
(55) At the time of establishing the remnant space, the filling material S pushes the air voids in the proximity of the female-threaded portion 83 of the cooling hole 82. Since the powdered metals mixed with the filling material S has the grain size of 4 m-50 m which is smaller than the clearance between the bushing tool 12 and the cooling hole 82, it is possible for the powdered metal to flow through the clearance.
(56) Pushing Step
(57) At the pushing step (tight-fitting engagement step), the bushing tool 12 is pushed deeper into the cooling hole 82 by the predetermined quantity (corresponding to the distance L2). The lock nut 22 moves lower than the cavity surface 81B by the amount of the distance L2 so as to completely attach the bushing tool 12 to the metallic mold die 80.
(58) Under the ambient temperature (approx. 15 C.-40 C.), the epoxy resin in the filling material S is hardened if set for approx. 2-24 hours. Although it is possible to harden the epoxy resin at less than 15 C. if taken a longer time, it is preferable to keep the epoxy resin under the ambient temperature (approx. 15 C.-40 C.) as far as possible. After hardening the epoxy resin, the filling material S is solidified within the sealing clearance between the bushing tool 12 and the cooling hole 82.
(59) Such is the structure that it is needless to determine the clearance (e.g., 0.1 mm-0.5 mm) to be e.g., 0.01 mm-0.09 mm which is more precise than the former clearance. Namely, the filling material S is liquid so that the filling material S fills the clearance in accordance with the shape of the clearance. This permits a latitude in precision errors against the bushing tool 12 and the cooling hole 82, thereby rendering it easy to maintain and control the products with a high assembling efficiency.
(60) According to the sealing structure, the filling material S is provided so that the bushing tool 12 pushes up the filling material S (i.e., deaeration) to fill up the clearance between the bushing tool 12 and the cooling hole 82, thereby preventing the air voids from occurring in the filling material S so as to enhance the heat-conductivity therebetween.
(61) With the powdered metals mixed with the hardened or charred epoxy resin, it is possible to completely plug the the annular clearance between the bushing tool 12 and the cooling hole 82.
(62) This makes it possible to separate the bushing tool 12 from the inner surface of the cooling hole 82. This means to make the bushing tool 12 in contact with the inner surface of the cooling hole 82 by way of the the powdered metal mixed with the hardened or charred epoxy resin. This makes it possible to prevent the cooling refrigerant from leaking to the cooling hole 82, thereby enhancing the heat-conductivity therebetween so as to readily adjust the temperature of the metallic mold die 80.
(63) Heat Treatment Step
(64) After the end of the pushing step, a heat treating step is provided to heat the metallic mold die 80 so as to char the hardened epoxy resin. The heat treating step is done when the bushing tool 12 is in the state as shown in
(65) When heated to approx. 300 C., the epoxy resin releases gaseous components (oxygen, hydrogen or the like) outside from their intermolecular space, and the carbon component is concurrently burned. Considering that the metallic mold die 80 is heated during process in which metallic mold die 80 casts the products, the heat treating step may be provided depending on necessity.
(66) Although the epoxy resin is liable to burn at 200 C., the hardened epoxy resin remains unburned until it reaches more than 200 C. The epoxy resin mixed with the powdered metal to serve as the binder, burns to be charred at the heat treatment step.
(67) This permits the powdered metal (copper or zinc powder) to plug the clearance to deposit on an entire region of the inner surface of the cooling hole 82 and the outer surface of the bushing tool 12, thereby enhancing the heat-conductivity therebetween so as to readily adjust the temperature of the metallic mold die 80.
(68) Temperature-rise Experimental Test Result
(69)
(70) When only the cooling hole 82 is provided devoid of both the bushing tool 12 and the filling material S, a maximum heat-conductivity is obtained as observed at a triangular denotation . When using the commercial thermo-grease and the bushing tool 12 made of the stainless steel, the conventional heat-conductivity is obtained as observed at a square denotation . When providing the bushing tool 12 and the filling material S in addition to the cooling hole 82, an enhanced heat-conductivity is obtained as observed at a circular denotation .circle-solid.. Comparing the detonation .circle-solid. with other counterparts, the heat-conductivity approaches near the maximum value when using the filling material S than when using the commercial thermo-grease.
(71) With the filling material S separating the bushing tool 12 from the inner wall of the cooling hole 82, it is possible for the filling material S to prevent the bushing tool 12 from being directly in contact with the inner wall of the cooling hole 82. This makes it possible to avoid the cooling refrigerant from leaking off the bushing tool 12 to the cooling hole 82 even when the die cracks occur on the metallic mold die 80.
(72) After assembling the bushing tool 12, the coupler pipe 24 is installed to the bushing tool 12 at a water-communicating step, so as to finish the assemble of the metal die cooling mechanism 10 for the metallic mold die 80.
(73) The coupler pipe 24 is installed by inserting the supply pipe 30 into the cooling hole 82 and setting the support pipe 26 into the wrench holes 18A, 22A as shown in
(74) Thereafter, the coupler pipe 24 bring the male-threaded portion 34A with the female-threaded portion 18B of the bushing tool 12. With the male-threaded portion 34A meshed with the female-threaded portion 18B, it is possible to prevent the water-leakage from the support pipe 26.
(75) In order to complete a water-communicating conduit, the supply connector 28 is attached to the spigot of the waterworks (not shown) through a communication pipe (not shown), and the drainage connector 32 is led to a catchment basin through a communication pipe (not shown).
(76) The tapwater from the waterworks is continuously supplied to the bushing tool 12 through the supply connector 28 and the supply pipe 30, and drained to the catchment basin through the watershoot pipe 34 and the drainage connector 32 as shown at arrows in
(77) During the process in which the tapwater is supplied as the cooling refrigerant to the bushing tool 12, the tapwater cools the metallic mold die 80 through the bushing tool 12 when the molten-metal is supplied to a cavity of the metallic mold die 80. The refrigerant water which is heat exchanged with the metallic mold die 80 is drained outside through the watershoot pipe 34.
(78) Although the powdered metal mixed with the charred epoxy resin remains between the bushing tool 12 and the cooling hole 82, it is possible to wash away the powdered metal with the use of a wire brush or the like at the time when rectifying strains occurred in the metallic die mold 80.
(79) This makes it possible to readily remove the powdered metal from the clearance, so as to user-friendly mitigate the laboring force especially when exchanging the bushing tool 12, in contrast to the prior art structure in which the molten metal is placed between the bushing tool and the molten-metal cooling pin.
(80) The device body also includes a central processing unit (CPU) of a super computer, a capacity of which is such as to require one floor of a building to accommodate. Namely, the bushing tool 12 is applicable to the central processing unit (CPU) which serves as the device body.
(81) In the meanwhile, the bushing tool 12 is also employed not only to cool the device body but also to pre-heat the device body. By way of example, a certain quantity of hot water (e.g., 100 C.) may be circulated within the bushing tool 12 after starting to use the metallic mold die 80 or after the metallic mold die 80 is exchanged.
(82) The metallic mold die 80 categorically includes a molten-metal cooling pin (equivalent to the prior art outer cylinder) which comes in direct contact with the molten metal.
(83) The cooling pin has a cooling path and constitutes a part of the metal die when used to the die-casting procedure. The bushing tool 12 may be inserted into the cooling path of the cooling pin.
(84) The metallic mold die includes a molten-metal supplying device placed on a stationary side of the metallic mold die and a sub-flowing device placed on a movable side of the metallic mold die. Namely, the bushing tool 12 may be inserted into a cooling passage provided on the metallic mold die or the sub-flowing device.
(85)
(86) Such is the structure that it is possible to equally transfer the cooling heat from the bushing tool 12 to the metallic mold die 80 through the filling material S. Upon hardening the epoxy resin, the metallic wire 12E comes in integral with the epoxy resin, while the metallic wire 12E comes in integral with the charred epoxy resin upon heat treating the epoxy resin. This makes it possible for the metallic wire 12E to contribute to the heat-conductivity between the bushing tool 12 and the metallic mold die 80.
(87) It is to be noted that metallic sire 12E may be made of gold, silver, steel copper, aluminum, stainless steel or felt.
(88) Modification Forms
(89) When the bushing tool 12 is completely installed within the cooling hole 82 (at the completely tightened position), the lock nut 22 may be in flush with the cavity surface 81B of the metallic mold die 80. The male-threaded portion 20 may be provisionally welded to the female-threaded portion 83 to prevent the male-threaded portion from being inadvertently loosened. Instead of the bushing tool 12, a pin, a sleeve or a casing may be employed as the inserting member.
(90) While several illustrative embodiments of the invention have been shown and described, numerous variations and alternate embodiments will occur to those skilled in the art. Such variations and alternate embodiments are contemplated, and can be made without departing from the spirit and scope of the invention as defined in the appended claims.