A Radiation System and Optical Device
20180307146 ยท 2018-10-25
Assignee
Inventors
- Hendrikus Gijsbertus Schimmel (Utrecht, NL)
- Jeroen Marcel Huijbregtse (Breda, NL)
- Maarten Van Kampen (Eindhoven, NL)
- Pieter-Jan Van Zwol (Eindhoven, NL)
Cpc classification
H05G2/00
ELECTRICITY
G03F7/70908
PHYSICS
H05G2/005
ELECTRICITY
G03F7/70925
PHYSICS
International classification
H05G2/00
ELECTRICITY
Abstract
A radiation system comprises a fuel emitter configured to provide fuel to a plasma formation region, a laser arranged to provide a laser beam at the plasma formation region incident on the fuel to generate a radiation emitting plasma, and a reflective or transmissive device (30) arranged to receive radiation emitted by the plasma and to reflect or transmit at least some of the received radiation along a desired path, wherein the reflective or transmissive device comprises a body configured to reflect and/or transmit said at least some of the radiation, and selected secondary electron emission (SEE) material (34) arranged relative to the body such as to emit secondary electrons in response to the received radiation, thereby to clean material from a surface of the device.
32
Claims
1-21. (canceled)
22. A radiation system comprising: a fuel emitter configured to provide fuel to a plasma formation region; a laser arranged to provide a laser beam at the plasma formation region incident on the fuel to generate a radiation emitting plasma; and a reflective or transmissive device arranged to receive radiation emitted by the plasma and to reflect or transmit at least some of the received radiation along a desired path, wherein the reflective or transmissive device comprises: a body configured to reflect and/or transmit the at least some of the radiation; and secondary electron emission (SEE) material arranged relative to the body such as to emit secondary electrons in response to the received radiation, thereby to clean material from a surface of the device.
23. The system of claim 22, wherein: the SEE material comprises an SEE layer that at least partly covers a surface of the body; the body comprises a layered structure that is configured, such that reflection of the at least some of the received radiation by the layered structure causes a standing wave to be formed in the optical device; and the layered structure and the SEE layer are arranged such that in operation a maximum of the standing wave is formed in the SEE layer.
24. The system of claim 23, wherein the layered structure comprises a multi-layer mirror.
25. The system of claim 22, wherein the SEE material comprises a cap layer that at least partly covers a surface of the body
26. The system of claim 22, wherein the SEE material is located at or near an edge of the reflective and/or transmissive device.
27. The system of claim 26, wherein: the body comprises a layered structure configured to reflect the at least some of the received radiation, and at least some of the SEE material located at or near an edge of the reflective and/or transmissive device is beyond a boundary of the layered structure.
28. The system of claim 22, further comprising a further component comprising SEE material positioned adjacent to the reflective and/or transmissive device.
29. The system device of claim 22, wherein: the reflective and/or transmissive optical device is a collector, and the SEE material comprises a coating on a rim of the collector.
30. The system of claim 22, wherein, for received radiation having a wavelength in a range 10 nm to 100 nm, the SEE material has a secondary electron yield (SEY) of greater than 0.01 electron per photon, greater than 0.05 electrons per photon, or greater than 0.1 electrons per photon.
31. The system of claim 22, wherein the SEE material has a band gap energy of greater than 1 eV, greater than 3 eV, or greater than 5 eV.
32. The system of claim 22, wherein the SEE material has an electron affinity less than 4 eV, less than 1 eV, or less than 0 eV.
33. The system of claim 22, wherein the SEE material comprises an insulator or semiconductor.
34. The system of claim 22, wherein the SEE material comprises at least one of diamond, H-terminated diamond, ZrO, ZrN, TiO2, Al2O3, quartz.
35. The system of claim 22, wherein the radiation comprises EUV radiation.
36. The system of claim 22, system comprises an EUV radiation source and the reflective and/or transmissive optical device is a collector of the EUV radiation source.
37. The system of claim 22, wherein the material to be cleaned from material from the surface of the optical device comprises tin.
38. The system of claim 22, further comprising a source of hydrogen for providing hydrogen gas to a surface of the device.
39. A reflective and/or transmissive optical device for receiving radiation and reflecting and/or transmitting at least some of the received radiation comprising: a body configured to reflect and/or transmit the at least some of the radiation; and secondary electron emission (SEE) material arranged relative to the body such as to emit secondary electrons in response to the received radiation, the secondary electrons being for cleaning material from a surface of the optical device.
40. A radiation source comprising: a fuel emitter configured to provide fuel to a plasma formation region, where plasma is formed in operation when the fuel is subject to laser radiation; and a reflective and/or transmissive device arranged to receive radiation emitted by the plasma in operation and to reflect or transmit at least some of the received radiation along a desired path, wherein the reflective or transmissive device comprises: a body configured to reflect and/or transmit the at least some of the radiation; and secondary electron emission (SEE) material arranged relative to the body such as to emit secondary electrons in response to the received radiation, thereby to clean material from a surface of the device.
41. A lithographic system comprising: a lithographic apparatus arranged to project a pattern from a patterning device onto a substrate, and a radiation system configured to provide at least some of radiation to the lithographic apparatus, the radiation system comprising: a fuel emitter configured to provide fuel to a plasma formation region; a laser arranged to provide a laser beam at the plasma formation region incident on the fuel to generate a radiation emitting plasma that produces the radiation; and a reflective or transmissive device arranged to receive radiation emitted by the plasma and to reflect or transmit at least some of the received radiation along a desired path, wherein the reflective or transmissive device comprises: a body configured to reflect and/or transmit the at least some of the radiation; and secondary electron emission (SEE) material arranged relative to the body such as to emit secondary electrons in response to the received radiation, thereby to clean material from a surface of the device.
42. A method comprising: providing fuel to a plasma formation region; providing a laser beam at the plasma formation region incident on the fuel to generate a radiation emitting plasma; receiving by a reflective and/or transmissive device radiation emitted by the plasma; reflecting or transmitting along a desired path by a body of the reflective and/or transmissive device at least some of the received radiation; and emitting secondary electrons from the second electron emitting (SEE) material in response to the received radiation thereby to clean material from a surface of the device.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0038] Embodiments of the invention will now be described, by way of example only, with reference to the accompanying schematic drawings, in which:
[0039]
[0040]
[0041]
[0042]
DETAILED DESCRIPTION
[0043]
[0044] The radiation source SO, illumination system IL, and projection system PS may all be constructed and arranged such that they can be isolated from the external environment. A gas at a pressure below atmospheric pressure (e.g. hydrogen) may be provided in the radiation source SO. A vacuum may be provided in illumination system IL and/or the projection system PS. A small amount of gas (e.g. hydrogen) at a pressure well below atmospheric pressure may be provided in the illumination system IL and/or the projection system PS.
[0045] The radiation source SO shown in
[0046] The EUV radiation is collected and focused by a near normal incidence radiation collector 5 (sometimes referred to as a normal incidence radiation collector). The collector 5 may have a multilayer structure which is arranged to reflect EUV radiation (e.g. EUV radiation having a desired wavelength such as 13.5 nm). The collector 5 may have an elliptical configuration, having two ellipse focal points. A first focal point may be at the plasma formation region 4, and a second focal point may be at an intermediate focus 6, as discussed below.
[0047] The laser 1 may be separated from the radiation source SO. Where this is the case, the laser beam 2 may be passed from the laser 1 to the radiation source SO with the aid of a beam delivery system (not shown) comprising, for example, suitable directing mirrors and/or a beam expander, and/or other optics. The laser 1 and the radiation source SO may together be considered to be a radiation system.
[0048] In the embodiment of
[0049] One way of cleaning tin from the surface of the collector and other surfaces is by creating, from the hydrogen gas, hydrogen radicals that can contact the surfaces and react with the tin to form gaseous SnH.sub.4. Alternatively or additionally, gases other than hydrogen, for example CH.sub.4 or HBr or a mixture of H.sub.2 and argon, which in the presence of secondary electrons lead to formation of radicals that can provide a cleaning effect, may be used. Other reactive ions may also be used to clean the tin or other deposits from the surface, for example positive oxygen, hydrogen, nitrogen, fluorine, chlorine or bromine ions or related species. The ions may, for example, be referred to as O<+>, H<+>, N<+>, F<+>, Cl<+>, or Br<+>ions.
[0050] In operation, hydrogen or other radicals may be generated from the hydrogen or other gas by a number of mechanisms including dissociation through UV radiation, collisions between H.sub.2 or other molecules and fast inert gas ions, and secondary electron generation at the collector surface. As discussed further below, it is a feature of certain embodiments that secondary electron generation is enhanced, which may lead to increased production of hydrogen or other radicals and thus increased or more effective cleaning of surfaces.
[0051] Returning to consideration of the radiation produced by the source, radiation that is reflected by the collector 5 forms a radiation beam B. The radiation beam B is focused at point 6 to form an image of the plasma formation region 4, which acts as a virtual radiation source for the illumination system IL. The point 6 at which the radiation beam B is focused may be referred to as the intermediate focus. The radiation source SO is arranged such that the intermediate focus 6 is located at or near to an opening 8 in an enclosing structure 9 of the radiation source.
[0052] The radiation beam B passes from the radiation source SO into the illumination system IL, which is configured to condition the radiation beam. The illumination system IL may include a facetted field mirror device 10 and a facetted pupil mirror device 11. The faceted field mirror device 10 and faceted pupil mirror device 11 together provide the radiation beam B with a desired cross-sectional shape and a desired angular distribution. The radiation beam B passes from the illumination system IL and is incident upon the patterning device MA held by the support structure MT. The patterning device MA reflects and patterns the radiation beam B. The illumination system IL may include other mirrors or devices in addition to or instead of the faceted field mirror device 10 and faceted pupil mirror device 11.
[0053] Following reflection from the patterning device MA the patterned radiation beam B enters the projection system PS. The projection system comprises a plurality of mirrors which are configured to project the radiation beam B onto a substrate W held by the substrate table WT. The projection system PS may apply a reduction factor to the radiation beam, forming an image with features that are smaller than corresponding features on the patterning device MA. A reduction factor of 4 may for example be applied. Although the projection system PS has two mirrors in
[0054] The radiation sources SO shown in
[0055]
[0056] The cap region 34 of the embodiment of
[0057] In operation, reflection of the EUV radiation incident on the collector 5 by the various layers of the multi-layer minor structure 30 causes a standing wave to be formed in the collector 5. This is illustrated schematically in
[0058] The reflection of the EUV radiation by the layers 31, 32 having thickness d1 and d2 respectively, can be understood using Bragg's law, m=2p.sin, where is the angle of incidence between the layers and the received radiation, m is an integer representing the order of the Bragg diffraction peak, and p is the periodicity of the multi-layer structure (e.g. the thickness of one pair of alternating layers, p=d1+d2). The reflection causes generation of the standing wave 40 in the collector 5.
[0059] In the embodiment of
[0060] The relative thicknesses of the different repeating layers, for example the Mo and Si layers can also be different in different embodiments, and the thicknesses of the Mo layers may be different to the thicknesses of the Si layers. In some embodiments the multi-layer structure may comprise more than two repeating layers.
[0061] It is a feature of the embodiment of
[0062] According to embodiments, various parameters may be selected or varied to ensure that an anti-node of the standing wave is present in the cap layer, for example a) materials of the multilayer and the order of materials in the multilayer, b) thickness of the cap layer, or c) thickness of the final layer of the stack before the cap layer. Further buffer layers may also be included to alter the position of the anti-node and ensure it falls in the cap layer in some embodiments. The thickness of the cap layer may be optimised in some embodiments, for example to ensure that it is sufficiently thick to ensure sufficient SEE and not too thick to reduce reflectivity beyond an acceptable level.
[0063] As well as ensuring that the anti-node of the standing wave is present in the cap layer of SEE material, suitable choice of the material for the cap layer can also ensure that the secondary electron yield is increased. In some embodiments, a desirable level of secondary electron yield may be obtained by choice of material alone. In such embodiments, the stack of layers may be arranged to provide a node rather than an anti-node of the standing wave in the cap layer, thereby to provide optimized reflectivity, as sufficient level of secondary electron yield may in that case be obtained by choice of material alone.
[0064] In the embodiment of
[0065] Although hydrogen-terminated diamond is a particularly suitable material for use as the SEE material, other materials may be used in alternative embodiments. For example, materials that have a high band gap energy or a low or negative electron affinity may provide a high secondary electron yield, which may make them suitable for use as the SEE material.
[0066] In the case of selection of material for use in the collector, there are also other considerations that may be taken into account. For example, materials that have good hydrogen radical cleaning properties may be particularly useful. The properties of interest may include low H radical recombination coefficient (chance that a hydrogen radical impinging on a surface of the material reacts to form H.sub.2). Materials having low values of Sn redeposition coefficient may also be useful. Sn redeposition may be present when a reaction from SnHx (x=1,2,3 or 4) to Sn+Hx occurs, and it may be that materials having a low H radical recombination coefficient will also have a low Sn redeposition coefficient. Insulators or wide bandgap semiconductors may be used in some embodiments, as at least some such insulators or wide bandgap semiconductors may have suitable values of H radical recombination coefficient, low values of Sn redeposition coefficient, and high SEY values.
[0067] The semiconductor materials may be doped semiconductor materials in some embodiments as, without wishing to be bound by theory, doping may play a role in the escape process of the secondary electrons from the surface and doping may also result in an increase in electrical conductivity, which may be beneficial in relation to the resupply of electrons to the material following escape of electrons from the surface.
[0068] Other considerations are also be taken into account in selecting materials for use as the cap material for the collector in some embodiments. For example, it can be important that the cap layer stops oxidation of the multi-layer stack 31, 32 and/or stops oxygen reaching the multi-layer stack 31, 32, has stable values of reflectivity, and be resistant to hydrogen, hydrogen radicals, and EUV radiation.
[0069] In some embodiments, the SEE material may comprise at least one of diamond, H-terminated diamond, ZrO, ZrN, TiO2, Al.sub.2O.sub.3, or quartz, each of which can provide suitable values of SEY whilst also having suitable thermal, mechanical and chemical properties for use as the cap layer.
[0070] A further embodiment in which SEE material is used in a collector of an EUV source to provide for cleaning by way of secondary electron effects is illustrated schematically in
[0071] In the embodiment of
[0072] The provision of further SEE material at or near the perimeter of the collector can be particularly useful as it has been found for some EUV sources that tin deposits can be particularly extensive or persistent near the perimeter of the collector.
[0073] The further SEE material may be in the form of a coating applied to a rim of the collector. The further SEE material 50 may be deposited or otherwise installed beyond the boundary of the multi-layer minor structure of the collector in some embodiments and may, for example, be deposited directly on an underlying substrate of the collector, for example substrate 33. The substrate 33 may, for example, comprise stainless steel. Alternatively or additionally, in some embodiments, the further SEE material may form part of a further component that is separate from but adjacent to the edge of the collector 5. In some embodiments a collector cone (not shown) is provided, where the cone comprises a structure, for example a cone-shaped piece of metal, configured to guide hydrogen or other gas flow to the plasma formation region in operation. The further SEE material may be provided on at least part of the surface of the collector cone in some embodiments.
[0074] The same or similar criteria may be applied in selecting the material to be used as the further SEE material 50, as those described above in relation to the selection of SEE material for the cap layer 5. However, some factors may be less important as the further material 5 may not need to perform the additional function of protecting the multi-layer minor 31, 32.
[0075] In some embodiments, insulators or semiconductors with low electron affinities may be used as the further SEE material 50. In some embodiments, the further SEE material 50 comprises diamond, H-terminated diamond, ZrO, ZrN, TiO2, Al.sub.2O.sub.3, or quartz.
[0076] It will also be understood that while the discussion here is primarily in terms of cleaning a collector of accumulated tin or other debris, tin or other debris may also accumulate on other surfaces within the source collector module such as metrology ports and the creation of hydrogen radicals due to emission of secondary electrons may also serve to clean these surfaces.
[0077] The cleaning of the surfaces of debris via secondary electron effects has been described in relation to the cleaning of tin debris based on decomposition and/or ionisation of hydrogen by the secondary electrons, where decomposition of hydrogen may refer to generating of neutral H radicals, and ionisation of hydrogen may refer to generating charged H.sup.+, H.sup.2+ or H.sup.3+ etc. In alternative embodiments other types of debris may be cleaned, for example carbon debris or other materials that can form volatile compounds in operation of a radiation source or other apparatus. Other type of gas atoms or molecules may be ionised and/or decomposed by the secondary electrons to provide the cleaning effect. For example, SEE effects may be used to activate gases other than hydrogen, for example CH.sub.4 or HBr or a mixture of H.sub.2 and argon, which in the presence of secondary electrons may lead to formation of radicals that can provide a cleaning effect. Other reactive ions may also be used to clean the tin or other deposits from the surface, for example positive oxygen, hydrogen, nitrogen, fluorine, chlorine or bromine ions or related species. The ions may be referred to as O<+>, H<+>, N<+>, F<+>, Cl<+>, or Br<+>ions.
[0078] It will be understood that while the discussion here is primarily in terms of cleaning a collector that includes a multilayer mirror of accumulated tin or other debris, in alternative embodiments the surface of any other suitable reflective or transmissive device may be cleaned using secondary electron effects, for example but not limited to any other suitable reflective or transmissive device forming part of or associated with a radiation source.
[0079] In an embodiment, the invention may form part of a mask inspection apparatus. The mask inspection apparatus may use EUV radiation to illuminate a mask and use an imaging sensor to monitor radiation reflected from the mask. Images received by the imaging sensor are used to determine whether or not defects are present in the mask. The mask inspection apparatus may include optics (e.g. mirrors) configured to receive EUV radiation from an EUV radiation source and form it into a radiation beam to be directed at a mask. The mask inspection apparatus may further include optics (e.g. mirrors) configured to collect EUV radiation reflected from the mask and form an image of the mask at the imaging sensor. The mask inspection apparatus may include a processor configured to analyse the image of the mask at the imaging sensor, and to determine from that analysis whether any defects are present on the mask. The processor may further be configured to determine whether a detected mask defect will cause an unacceptable defect in images projected onto a substrate when the mask is used by a lithographic apparatus.
[0080] In an embodiment, the invention may form part of a metrology apparatus. The metrology apparatus may be used to measure alignment of a projected pattern formed in resist on a substrate relative to a pattern already present on the substrate. This measurement of relative alignment may be referred to as overlay. The metrology apparatus may for example be located immediately adjacent to a lithographic apparatus and may be used to measure the overlay before the substrate (and the resist) has been processed.
[0081] Although specific reference may be made in this text to embodiments of the invention in the context of a lithographic apparatus, embodiments of the invention may be used in other apparatus. Embodiments of the invention may form part of a mask inspection apparatus, a metrology apparatus, or any apparatus that measures or processes an object such as a wafer (or other substrate) or mask (or other patterning device). These apparatus may be generally referred to as lithographic tools. Such a lithographic tool may use vacuum conditions or ambient (non-vacuum) conditions.
[0082] The term EUV radiation may be considered to encompass electromagnetic radiation having a wavelength within the range of 4-20 nm, for example within the range of 13-14 nm. EUV radiation may have a wavelength of less than 10 nm, for example within the range of 4-10 nm such as 6.7 nm or 6.8 nm.
[0083] Although
[0084] Although specific reference may be made in this text to the use of lithographic apparatus in the manufacture of ICs, it should be understood that the lithographic apparatus described herein may have other applications. Possible other applications include the manufacture of integrated optical systems, guidance and detection patterns for magnetic domain memories, flat-panel displays, liquid-crystal displays (LCDs), thin-film magnetic heads, etc.
[0085] Although specific reference may have been made above to the use of embodiments of the invention in the context of optical lithography, it will be appreciated that the invention may be used in other applications, for example imprint lithography, and where the context allows, is not limited to optical lithography. In imprint lithography a topography in a patterning device defines the pattern created on a substrate. The topography of the patterning device may be pressed into a layer of resist supplied to the substrate whereupon the resist is cured by applying electromagnetic radiation, heat, pressure or a combination thereof. The patterning device is moved out of the resist leaving a pattern in it after the resist is cured.
[0086] While specific embodiments of the invention have been described above, it will be appreciated that the invention may be practiced otherwise than as described. The descriptions above are intended to be illustrative, not limiting. Thus it will be apparent to one skilled in the art that modifications may be made to the invention as described without departing from the scope of the claims set out below.