ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES
20220367820 · 2022-11-17
Assignee
Inventors
- Chun LIN (Yardley, PA, US)
- Zhiqiang Ji (Chalfont, PA, US)
- Ting-Chih WANG (Lawrenceville, NJ, US)
- Pierre-Luc T. Boudreault (Pennington, NJ)
Cpc classification
C09K2211/185
CHEMISTRY; METALLURGY
C09K2211/1029
CHEMISTRY; METALLURGY
International classification
C07F15/00
CHEMISTRY; METALLURGY
C09K11/02
CHEMISTRY; METALLURGY
Abstract
Provided is an OLED having an anode, a cathode and an organic emissive layer disposed between the anode and the cathode. The emissive layer includes a first host; and a first emitter; wherein the first emitter is selected from the following group: (L.sup.1-L.sup.2).sub.nIr(L.sub.A).sub.3−n and (L.sub.B).sub.nIr(L.sup.3-L.sup.4).sub.3−n; wherein (L.sup.1-L.sup.2).sub.nIr(L.sub.A).sub.3−n is
##STR00001##
Claims
1. An organic light emitting device (OLED), comprising: an anode; a cathode; and an organic emissive layer disposed between the anode and the cathode comprising: a first host; and a first emitter; wherein the first emitter is selected from the group consisting of (L.sup.1-1)).sub.nIr(L.sub.A).sub.3−n and (L.sub.B).sub.nIr(L.sup.3-L.sup.4).sub.3−n; wherein (L.sup.1-L.sup.2).sub.nIr(L.sub.A).sub.3−n is ##STR00264## and (L.sub.B).sub.nIr(L.sup.3-L.sup.4).sub.3−n is ##STR00265## wherein each R.sup.S11, R.sup.S32, and R.sup.S13 independently represents zero, mono, or up to a maximum allowed substitution to its associated ring; wherein each L.sup.1-L.sup.2 and L.sup.3-L.sup.4 independently represents an anionic bidentate ligand; wherein n is 1 or 2; wherein each R.sup.S1, R.sup.S2, R.sup.S3, R.sup.S4, R.sup.S5, R.sup.S6, is independently selected from the group consisting of alkyl, cycloalkyl, partially or fully fluorinated variants thereof, partially or fully deuterated variants thereof, and combinations thereof; wherein each R.sup.S11, R.sup.S12, and R.sup.S13 is independently a hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, boryl, and combinations thereof; wherein at least one of R.sup.S11, R.sup.S12, and R.sup.S13 is selected from the group consisting of deuterium, silyl, alkyl, cycloalkyl, partially or fully fluorinated variants thereof, and combinations thereof; wherein any two substituents of R.sup.S1, R.sup.S2, R.sup.S3, R.sup.S4, R.sup.S5, R.sup.S6, R.sup.S11, R.sup.S12, and R.sup.S33 can be joined or fused into a ring; and wherein the first host comprises at least one donor group G.sup.D, and at least one acceptor group G.sup.A.
2. The OLED of claim 1, wherein at least one of R.sup.S11, R.sup.S12, and R.sup.S13 is selected from the group consisting of deuterium, silyl, C1 to C3 alkyl, substituted or unsubstituted cycloalkyl, and a branch substituted or unsubstituted alkyl with the branching occurs at the benzylic position.
3. The OLED of claim 1, wherein the first emitter is ##STR00266##
4. The OLED of claim 1, wherein the first emitter is selected from the group consisting of the following structures having formula (L.sub.B).sub.nIr(L.sup.3-L.sup.4).sub.3−n: ##STR00267## wherein X′ is selected from the group consisting of BR.sub.e, BR.sub.eR.sub.f, NR.sub.e, PR.sub.e, O, S, Se, C═O, S═O, SO.sub.2, CR.sub.eR.sub.f, SiR.sub.eR.sub.f, and GeR.sub.eR.sub.f; wherein each R′, R″, and R.sup.S14 is independently a hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, boryl, and combinations thereof; and wherein any two substituents of R.sub.e, R.sub.f, and R.sup.S14 can be joined or fused into a ring.
5. The OLED of claim 3, wherein the ligand (L.sup.1-L.sup.2) is selected from the group consisting of: ##STR00268## wherein Y.sup.1 to Y.sup.10 are each independently selected from the group consisting of carbon and nitrogen; wherein Y′ is selected from the group consisting of BR.sub.e, BR.sub.eR.sub.f, NR.sub.e, PR.sub.e, O, S, Se, C═O, S═O, SO.sub.2, CR.sub.eR.sub.f, SiR.sub.eR.sub.f, and GeR.sub.eR.sub.f; wherein R.sub.e and R.sub.f are optionally fused or joined to form a ring; wherein R.sub.a, and R.sub.b each independently represent zero, mono, or up to a maximum allowed substitution to its associated ring; wherein each of R.sub.a, R.sub.b, R.sub.e and R.sub.f is independently hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, boryl; and wherein two adjacent substituents of R.sub.a, and R.sub.b are optionally fused or joined to form a ring or form a multidentate ligand.
6. The OLED of claim 3 wherein the ligand (L.sup.1-L.sup.2) is selected from the group consisting of: L.sup.1-L.sup.2-1-i based on Structure 1: ##STR00269## L.sup.1-L.sup.2-2-i based on Structure 2: ##STR00270## L.sup.1-L.sup.2-3-i based on Structure 3: ##STR00271## L.sup.1-L.sup.2-4-i based on Structure 4: ##STR00272## L.sup.1-L.sup.2-5-i based on Structure 5: ##STR00273## L.sup.1-L.sup.2-6-i based on Structure 6: ##STR00274## L.sup.1-L.sup.2-7-i based on Structure 7: ##STR00275## L.sup.1-L.sup.2-8-i based on Structure 8: ##STR00276## L.sup.1-L.sup.2-9-i based on Structure 9: ##STR00277## L.sup.1-L.sup.2-10-i based on Structure 10: ##STR00278## L.sup.1-L.sup.2-11-i based on Structure 11: ##STR00279## L.sup.1-L.sup.2-12-i based on Structure 12: ##STR00280## L.sup.1-L.sup.2-13-i based on Structure 13: ##STR00281## L.sup.1-L.sup.2-14-i based on Structure 14: ##STR00282## and L.sup.1-L.sup.2-15-i based on Structure 15: ##STR00283## L.sup.1-L.sup.2-16-i based on Structure 16: ##STR00284## L.sup.1-L.sup.2-17-i based on Structure 17: ##STR00285## wherein i is an integer from 1 to 810, and for each i, R.sub.E, and G are as defined below: TABLE-US-00007 i R.sub.E G 1 R.sup.1 G.sup.1 2 R.sup.2 G.sup.1 3 R.sup.3 G.sup.1 4 R.sup.4 G.sup.1 5 R.sup.5 G.sup.1 6 R.sup.6 G.sup.1 7 R.sup.7 G.sup.1 8 R.sup.8 G.sup.1 9 R.sup.9 G.sup.1 10 R.sup.10 G.sup.1 11 R.sup.11 G.sup.1 12 R.sup.12 G.sup.1 13 R.sup.13 G.sup.1 14 R.sup.14 G.sup.1 15 R.sup.15 G.sup.1 16 R.sup.16 G.sup.1 17 R.sup.17 G.sup.1 18 R.sup.18 G.sup.1 19 R.sup.19 G.sup.1 20 R.sup.20 G.sup.1 21 R.sup.21 G.sup.1 22 R.sup.22 G.sup.1 23 R.sup.23 G.sup.1 24 R.sup.24 G.sup.1 25 R.sup.25 G.sup.1 26 R.sup.26 G.sup.1 27 R.sup.27 G.sup.1 28 R.sup.28 G.sup.1 29 R.sup.29 G.sup.1 30 R.sup.30 G.sup.1 31 R.sup.31 G.sup.1 32 R.sup.32 G.sup.1 33 R.sup.33 G.sup.1 34 R.sup.34 G.sup.1 35 R.sup.35 G.sup.1 36 R.sup.36 G.sup.1 37 R.sup.37 G.sup.1 38 R.sup.38 G.sup.1 39 R.sup.39 G.sup.1 40 R.sup.40 G.sup.1 41 R.sup.41 G.sup.1 42 R.sup.42 G.sup.1 43 R.sup.43 G.sup.1 44 R.sup.44 G.sup.1 45 R.sup.45 G.sup.1 46 R.sup.1 G.sup.5 47 R.sup.2 G.sup.5 48 R.sup.3 G.sup.5 49 R.sup.4 G.sup.5 50 R.sup.5 G.sup.5 51 R.sup.6 G.sup.5 52 R.sup.7 G.sup.5 53 R.sup.8 G.sup.5 54 R.sup.9 G.sup.5 55 R.sup.10 G.sup.5 56 R.sup.11 G.sup.5 57 R.sup.12 G.sup.5 58 R.sup.13 G.sup.5 59 R.sup.14 G.sup.5 60 R.sup.15 G.sup.5 61 R.sup.16 G.sup.5 62 R.sup.17 G.sup.5 63 R.sup.18 G.sup.5 64 R.sup.19 G.sup.5 65 R.sup.20 G.sup.5 66 R.sup.21 G.sup.5 67 R.sup.22 G.sup.5 68 R.sup.23 G.sup.5 69 R.sup.24 G.sup.5 70 R.sup.25 G.sup.5 71 R.sup.26 G.sup.5 72 R.sup.27 G.sup.5 73 R.sup.28 G.sup.5 74 R.sup.29 G.sup.5 75 R.sup.30 G.sup.5 76 R.sup.31 G.sup.5 77 R.sup.32 G.sup.5 78 R.sup.33 G.sup.5 79 R.sup.34 G.sup.5 80 R.sup.35 G.sup.5 81 R.sup.36 G.sup.5 82 R.sup.37 G.sup.5 83 R.sup.38 G.sup.5 84 R.sup.39 G.sup.5 85 R.sup.40 G.sup.5 86 R.sup.41 G.sup.5 87 R.sup.42 G.sup.5 88 R.sup.43 G.sup.5 89 R.sup.44 G.sup.5 90 R.sup.45 G.sup.5 91 R.sup.1 G.sup.9 92 R.sup.2 G.sup.9 93 R.sup.3 G.sup.9 94 R.sup.4 G.sup.9 95 R.sup.5 G.sup.9 96 R.sup.6 G.sup.9 97 R.sup.7 G.sup.9 98 R.sup.8 G.sup.9 99 R.sup.9 G.sup.9 100 R.sup.10 G.sup.9 101 R.sup.11 G.sup.9 102 R.sup.12 G.sup.9 103 R.sup.13 G.sup.9 104 R.sup.14 G.sup.9 105 R.sup.15 G.sup.9 106 R.sup.16 G.sup.9 107 R.sup.17 G.sup.9 108 R.sup.18 G.sup.9 109 R.sup.19 G.sup.9 110 R.sup.20 G.sup.9 111 R.sup.21 G.sup.9 112 R.sup.22 G.sup.9 113 R.sup.23 G.sup.9 114 R.sup.24 G.sup.9 115 R.sup.25 G.sup.9 116 R.sup.26 G.sup.9 117 R.sup.27 G.sup.9 118 R.sup.28 G.sup.9 119 R.sup.29 G.sup.9 120 R.sup.30 G.sup.9 121 R.sup.31 G.sup.9 122 R.sup.32 G.sup.9 123 R.sup.33 G.sup.9 124 R.sup.34 G.sup.9 125 R.sup.35 G.sup.9 126 R.sup.36 G.sup.9 127 R.sup.37 G.sup.9 128 R.sup.38 G.sup.9 129 R.sup.39 G.sup.9 130 R.sup.40 G.sup.9 131 R.sup.41 G.sup.9 132 R.sup.42 G.sup.9 133 R.sup.43 G.sup.9 134 R.sup.44 G.sup.9 135 R.sup.45 G.sup.9 136 R.sup.1 G.sup.13 137 R.sup.2 G.sup.13 138 R.sup.3 G.sup.13 139 R.sup.4 G.sup.13 140 R.sup.5 G.sup.13 141 R.sup.6 G.sup.13 142 R.sup.7 G.sup.13 143 R.sup.8 G.sup.13 144 R.sup.9 G.sup.13 145 R.sup.10 G.sup.13 146 R.sup.11 G.sup.13 147 R.sup.12 G.sup.13 148 R.sup.13 G.sup.13 149 R.sup.14 G.sup.13 150 R.sup.15 G.sup.13 151 R.sup.16 G.sup.13 152 R.sup.17 G.sup.13 153 R.sup.18 G.sup.13 154 R.sup.19 G.sup.13 155 R.sup.20 G.sup.13 156 R.sup.21 G.sup.13 157 R.sup.22 G.sup.13 158 R.sup.23 G.sup.13 159 R.sup.24 G.sup.13 160 R.sup.25 G.sup.13 161 R.sup.26 G.sup.13 162 R.sup.27 G.sup.13 163 R.sup.28 G.sup.13 164 R.sup.29 G.sup.13 165 R.sup.30 G.sup.13 166 R.sup.31 G.sup.13 167 R.sup.32 G.sup.13 168 R.sup.33 G.sup.13 169 R.sup.34 G.sup.13 170 R.sup.35 G.sup.13 171 R.sup.36 G.sup.13 172 R.sup.37 G.sup.13 173 R.sup.38 G.sup.13 174 R.sup.39 G.sup.13 175 R.sup.40 G.sup.13 176 R.sup.41 G.sup.13 177 R.sup.42 G.sup.13 178 R.sup.43 G.sup.13 179 R.sup.44 G.sup.13 180 R.sup.45 G.sup.13 181 R.sup.1 G.sup.17 182 R.sup.2 G.sup.17 183 R.sup.3 G.sup.17 184 R.sup.4 G.sup.17 185 R.sup.5 G.sup.17 186 R.sup.6 G.sup.17 187 R.sup.7 G.sup.17 188 R.sup.8 G.sup.17 189 R.sup.9 G.sup.17 190 R.sup.10 G.sup.17 191 R.sup.11 G.sup.17 192 R.sup.12 G.sup.17 193 R.sup.13 G.sup.17 194 R.sup.14 G.sup.17 195 R.sup.15 G.sup.17 196 R.sup.16 G.sup.17 197 R.sup.17 G.sup.17 198 R.sup.18 G.sup.17 199 R.sup.19 G.sup.17 200 R.sup.20 G.sup.17 201 R.sup.21 G.sup.17 202 R.sup.22 G.sup.17 203 R.sup.23 G.sup.17 204 R.sup.1 G.sup.2 205 R.sup.2 G.sup.2 206 R.sup.3 G.sup.2 207 R.sup.4 G.sup.2 208 R.sup.5 G.sup.2 209 R.sup.6 G.sup.2 210 R.sup.7 G.sup.2 211 R.sup.8 G.sup.2 212 R.sup.9 G.sup.2 213 R.sup.10 G.sup.2 214 R.sup.11 G.sup.2 215 R.sup.12 G.sup.2 216 R.sup.13 G.sup.2 217 R.sup.14 G.sup.2 218 R.sup.15 G.sup.2 219 R.sup.16 G.sup.2 220 R.sup.17 G.sup.2 221 R.sup.18 G.sup.2 222 R.sup.19 G.sup.2 223 R.sup.20 G.sup.2 224 R.sup.21 G.sup.2 225 R.sup.22 G.sup.2 226 R.sup.23 G.sup.2 227 R.sup.24 G.sup.2 228 R.sup.25 G.sup.2 229 R.sup.26 G.sup.2 230 R.sup.27 G.sup.2 231 R.sup.28 G.sup.2 232 R.sup.29 G.sup.2 233 R.sup.30 G.sup.2 234 R.sup.31 G.sup.2 235 R.sup.32 G.sup.2 236 R.sup.33 G.sup.2 237 R.sup.34 G.sup.2 238 R.sup.35 G.sup.2 239 R.sup.36 G.sup.2 240 R.sup.37 G.sup.2 241 R.sup.38 G.sup.2 242 R.sup.39 G.sup.2 243 R.sup.40 G.sup.2 244 R.sup.41 G.sup.2 245 R.sup.42 G.sup.2 246 R.sup.43 G.sup.2 247 R.sup.44 G.sup.2 248 R.sup.45 G.sup.2 249 R.sup.1 G.sup.6 250 R.sup.2 G.sup.6 251 R.sup.3 G.sup.6 252 R.sup.4 G.sup.6 253 R.sup.5 G.sup.6 254 R.sup.6 G.sup.6 255 R.sup.7 G.sup.6 256 R.sup.8 G.sup.6 257 R.sup.9 G.sup.6 258 R.sup.10 G.sup.6 259 R.sup.11 G.sup.6 260 R.sup.12 G.sup.6 261 R.sup.13 G.sup.6 262 R.sup.14 G.sup.6 263 R.sup.15 G.sup.6 264 R.sup.16 G.sup.6 265 R.sup.17 G.sup.6 266 R.sup.18 G.sup.6 267 R.sup.19 G.sup.6 268 R.sup.20 G.sup.6 269 R.sup.21 G.sup.6 270 R.sup.22 G.sup.6 271 R.sup.23 G.sup.6 272 R.sup.24 G.sup.6 273 R.sup.25 G.sup.6 274 R.sup.26 G.sup.6 275 R.sup.27 G.sup.6 276 R.sup.28 G.sup.6 277 R.sup.29 G.sup.6 278 R.sup.30 G.sup.6 279 R.sup.31 G.sup.6 280 R.sup.32 G.sup.6 281 R.sup.33 G.sup.6 282 R.sup.34 G.sup.6 283 R.sup.35 G.sup.6 284 R.sup.36 G.sup.6 285 R.sup.37 G.sup.6 286 R.sup.38 G.sup.6 287 R.sup.39 G.sup.6 288 R.sup.40 G.sup.6 289 R.sup.41 G.sup.6 290 R.sup.42 G.sup.6 291 R.sup.43 G.sup.6 292 R.sup.44 G.sup.6 293 R.sup.45 G.sup.6 294 R.sup.1 G.sup.10 295 R.sup.2 G.sup.10 296 R.sup.3 G.sup.10 297 R.sup.4 G.sup.10 298 R.sup.5 G.sup.10 299 R.sup.6 G.sup.10 300 R.sup.7 G.sup.10 301 R.sup.8 G.sup.10 302 R.sup.9 G.sup.10 303 R.sup.10 G.sup.10 304 R.sup.11 G.sup.10 305 R.sup.12 G.sup.10 306 R.sup.13 G.sup.10 307 R.sup.14 G.sup.10 308 R.sup.15 G.sup.10 309 R.sup.16 G.sup.10 310 R.sup.17 G.sup.10 311 R.sup.18 G.sup.10 312 R.sup.19 G.sup.10 313 R.sup.20 G.sup.10 314 R.sup.21 G.sup.10 315 R.sup.22 G.sup.10 316 R.sup.23 G.sup.10 317 R.sup.24 G.sup.10 318 R.sup.25 G.sup.10 319 R.sup.26 G.sup.10 320 R.sup.27 G.sup.10 321 R.sup.28 G.sup.10 322 R.sup.29 G.sup.10 323 R.sup.30 G.sup.10 324 R.sup.31 G.sup.10 325 R.sup.32 G.sup.10 326 R.sup.33 G.sup.10 327 R.sup.34 G.sup.10 328 R.sup.35 G.sup.10 329 R.sup.36 G.sup.10 330 R.sup.37 G.sup.10 331 R.sup.38 G.sup.10 332 R.sup.39 G.sup.10 333 R.sup.40 G.sup.10 334 R.sup.41 G.sup.10 335 R.sup.42 G.sup.10 336 R.sup.43 G.sup.10 337 R.sup.44 G.sup.10 338 R.sup.45 G.sup.10 339 R.sup.1 G.sup.14 340 R.sup.2 G.sup.14 341 R.sup.3 G.sup.14 342 R.sup.4 G.sup.14 343 R.sup.5 G.sup.14 344 R.sup.6 G.sup.14 345 R.sup.7 G.sup.14 346 R.sup.8 G.sup.14 347 R.sup.9 G.sup.14 348 R.sup.10 G.sup.14 349 R.sup.11 G.sup.14 350 R.sup.12 G.sup.14 351 R.sup.13 G.sup.14 352 R.sup.14 G.sup.14 353 R.sup.15 G.sup.14 354 R.sup.16 G.sup.14 355 R.sup.17 G.sup.14 356 R.sup.18 G.sup.14 357 R.sup.19 G.sup.14 358 R.sup.20 G.sup.14 359 R.sup.21 G.sup.14 360 R.sup.22 G.sup.14 361 R.sup.23 G.sup.14 362 R.sup.24 G.sup.14 363 R.sup.25 G.sup.14 364 R.sup.26 G.sup.14 365 R.sup.27 G.sup.14 366 R.sup.28 G.sup.14 367 R.sup.29 G.sup.14 368 R.sup.30 G.sup.14 369 R.sup.31 G.sup.14 370 R.sup.32 G.sup.14 371 R.sup.33 G.sup.14 372 R.sup.34 G.sup.14 373 R.sup.35 G.sup.14 374 R.sup.36 G.sup.14 375 R.sup.37 G.sup.14 376 R.sup.38 G.sup.14 377 R.sup.39 G.sup.14 378 R.sup.40 G.sup.14 379 R.sup.41 G.sup.14 380 R.sup.42 G.sup.14 381 R.sup.43 G.sup.14 382 R.sup.44 G.sup.14 383 R.sup.45 G.sup.14 384 R.sup.24 G.sup.17 385 R.sup.25 G.sup.17 386 R.sup.26 G.sup.17 387 R.sup.27 G.sup.17 388 R.sup.28 G.sup.17 389 R.sup.29 G.sup.17 390 R.sup.30 G.sup.17 391 R.sup.31 G.sup.17 392 R.sup.32 G.sup.17 393 R.sup.33 G.sup.17 394 R.sup.34 G.sup.17 395 R.sup.35 G.sup.17 396 R.sup.36 G.sup.17 397 R.sup.37 G.sup.17 398 R.sup.38 G.sup.17 399 R.sup.39 G.sup.17 400 R.sup.40 G.sup.17 401 R.sup.41 G.sup.17 402 R.sup.42 G.sup.17 403 R.sup.43 G.sup.17 404 R.sup.44 G.sup.17 405 R.sup.45 G.sup.17 406 R.sup.23 G.sup.18 407 R.sup.1 G.sup.3 408 R.sup.2 G.sup.3 409 R.sup.3 G.sup.3 410 R.sup.4 G.sup.3 411 R.sup.5 G.sup.3 412 R.sup.6 G.sup.3 413 R.sup.7 G.sup.3 414 R.sup.8 G.sup.3 415 R.sup.9 G.sup.3 416 R.sup.10 G.sup.3 417 R.sup.11 G.sup.3 418 R.sup.12 G.sup.3 419 R.sup.13 G.sup.3 420 R.sup.14 G.sup.3 421 R.sup.15 G.sup.3 422 R.sup.16 G.sup.3 423 R.sup.17 G.sup.3 424 R.sup.18 G.sup.3 425 R.sup.19 G.sup.3 426 R.sup.20 G.sup.3 427 R.sup.21 G.sup.3 428 R.sup.22 G.sup.3 429 R.sup.23 G.sup.3 430 R.sup.24 G.sup.3 431 R.sup.25 G.sup.3 432 R.sup.26 G.sup.3 433 R.sup.27 G.sup.3 434 R.sup.28 G.sup.3 435 R.sup.29 G.sup.3 436 R.sup.30 G.sup.3 437 R.sup.31 G.sup.3 438 R.sup.32 G.sup.3 439 R.sup.33 G.sup.3 440 R.sup.34 G.sup.3 441 R.sup.35 G.sup.3 442 R.sup.36 G.sup.3 443 R.sup.37 G.sup.3 444 R.sup.38 G.sup.3 445 R.sup.39 G.sup.3 446 R.sup.40 G.sup.3 447 R.sup.41 G.sup.3 448 R.sup.42 G.sup.3 449 R.sup.43 G.sup.3 450 R.sup.44 G.sup.3 451 R.sup.45 G.sup.3 452 R.sup.1 G.sup.7 453 R.sup.2 G.sup.7 454 R.sup.3 G.sup.7 455 R.sup.4 G.sup.7 456 R.sup.5 G.sup.7 457 R.sup.6 G.sup.7 458 R.sup.7 G.sup.7 459 R.sup.8 G.sup.7 460 R.sup.9 G.sup.7 461 R.sup.10 G.sup.7 462 R.sup.11 G.sup.7 463 R.sup.12 G.sup.7 464 R.sup.13 G.sup.7 465 R.sup.14 G.sup.7 466 R.sup.15 G.sup.7 467 R.sup.16 G.sup.7 468 R.sup.17 G.sup.7 469 R.sup.18 G.sup.7 470 R.sup.19 G.sup.7 471 R.sup.20 G.sup.7 472 R.sup.21 G.sup.7 473 R.sup.22 G.sup.7 474 R.sup.23 G.sup.7 475 R.sup.24 G.sup.7 476 R.sup.25 G.sup.7 477 R.sup.26 G.sup.7 478 R.sup.27 G.sup.7 479 R.sup.28 G.sup.7 480 R.sup.29 G.sup.7 481 R.sup.30 G.sup.7 482 R.sup.31 G.sup.7 483 R.sup.32 G.sup.7 484 R.sup.33 G.sup.7 485 R.sup.34 G.sup.7 486 R.sup.35 G.sup.7 487 R.sup.36 G.sup.7 488 R.sup.37 G.sup.7 489 R.sup.38 G.sup.7 490 R.sup.39 G.sup.7 491 R.sup.40 G.sup.7 492 R.sup.41 G.sup.7 493 R.sup.42 G.sup.7 494 R.sup.43 G.sup.7 495 R.sup.44 G.sup.7 496 R.sup.45 G.sup.7 497 R.sup.1 G.sup.11 498 R.sup.2 G.sup.11 499 R.sup.3 G.sup.11 500 R.sup.4 G.sup.11 501 R.sup.5 G.sup.11 502 R.sup.6 G.sup.11 503 R.sup.7 G.sup.11 504 R.sup.8 G.sup.11 505 R.sup.9 G.sup.11 506 R.sup.10 G.sup.11 507 R.sup.11 G.sup.11 508 R.sup.12 G.sup.11 509 R.sup.13 G.sup.11 510 R.sup.14 G.sup.11 511 R.sup.15 G.sup.11 512 R.sup.16 G.sup.11 513 R.sup.17 G.sup.11 514 R.sup.18 G.sup.11 515 R.sup.19 G.sup.11 516 R.sup.20 G.sup.11 517 R.sup.21 G.sup.11 518 R.sup.22 G.sup.11 519 R.sup.23 G.sup.11 520 R.sup.24 G.sup.11 521 R.sup.25 G.sup.11 522 R.sup.26 G.sup.11 523 R.sup.27 G.sup.11 524 R.sup.28 G.sup.11 525 R.sup.29 G.sup.11 526 R.sup.30 G.sup.11 527 R.sup.31 G.sup.11 528 R.sup.32 G.sup.11 529 R.sup.33 G.sup.11 530 R.sup.34 G.sup.11 531 R.sup.35 G.sup.11 532 R.sup.36 G.sup.11 533 R.sup.37 G.sup.11 534 R.sup.38 G.sup.11 535 R.sup.39 G.sup.11 536 R.sup.40 G.sup.11 537 R.sup.41 G.sup.11 538 R.sup.42 G.sup.11 539 R.sup.43 G.sup.11 540 R.sup.44 G.sup.11 541 R.sup.45 G.sup.11 542 R.sup.1 G.sup.15 543 R.sup.2 G.sup.15 544 R.sup.3 G.sup.15 545 R.sup.4 G.sup.15 546 R.sup.5 G.sup.15 547 R.sup.6 G.sup.15 548 R.sup.7 G.sup.15 549 R.sup.8 G.sup.15 550 R.sup.9 G.sup.15 551 R.sup.10 G.sup.15 552 R.sup.11 G.sup.15 553 R.sup.12 G.sup.15 554 R.sup.13 G.sup.15 555 R.sup.14 G.sup.15 556 R.sup.15 G.sup.15 557 R.sup.16 G.sup.15 558 R.sup.17 G.sup.15 559 R.sup.18 G.sup.15 560 R.sup.19 G.sup.15 561 R.sup.20 G.sup.15 562 R.sup.21 G.sup.15 563 R.sup.22 G.sup.15 564 R.sup.23 G.sup.15 565 R.sup.24 G.sup.15 566 R.sup.25 G.sup.15 567 R.sup.26 G.sup.15 568 R.sup.27 G.sup.15 569 R.sup.28 G.sup.15 570 R.sup.29 G.sup.15 571 R.sup.30 G.sup.15 572 R.sup.31 G.sup.15 573 R.sup.32 G.sup.15 574 R.sup.33 G.sup.15 575 R.sup.34 G.sup.15 576 R.sup.35 G.sup.15 577 R.sup.36 G.sup.15 578 R.sup.37 G.sup.15 579 R.sup.38 G.sup.15 580 R.sup.39 G.sup.15 581 R.sup.40 G.sup.15 582 R.sup.41 G.sup.15 583 R.sup.42 G.sup.15 584 R.sup.43 G.sup.15 585 R.sup.44 G.sup.15 586 R.sup.45 G.sup.15 587 R.sup.1 G.sup.18 588 R.sup.2 G.sup.18 589 R.sup.3 G.sup.18 590 R.sup.4 G.sup.18 591 R.sup.5 G.sup.18 592 R.sup.6 G.sup.18 593 R.sup.7 G.sup.18 594 R.sup.8 G.sup.18 595 R.sup.9 G.sup.18 596 R.sup.10 G.sup.18 597 R.sup.11 G.sup.18 598 R.sup.12 G.sup.18 599 R.sup.13 G.sup.18 600 R.sup.14 G.sup.18 601 R.sup.15 G.sup.18 602 R.sup.16 G.sup.18 603 R.sup.17 G.sup.18 604 R.sup.18 G.sup.18 605 R.sup.19 G.sup.18 606 R.sup.20 G.sup.18 607 R.sup.21 G.sup.18 608 R.sup.22 G.sup.18 609 R.sup.1 G.sup.4 610 R.sup.2 G.sup.4 611 R.sup.3 G.sup.4 612 R.sup.4 G.sup.4 613 R.sup.5 G.sup.4 614 R.sup.6 G.sup.4 615 R.sup.7 G.sup.4 616 R.sup.8 G.sup.4 617 R.sup.9 G.sup.4 618 R.sup.10 G.sup.4 619 R.sup.11 G.sup.4 620 R.sup.12 G.sup.4 621 R.sup.13 G.sup.4 622 R.sup.14 G.sup.4 623 R.sup.15 G.sup.4 624 R.sup.16 G.sup.4 625 R.sup.17 G.sup.4 626 R.sup.18 G.sup.4 627 R.sup.19 G.sup.4 628 R.sup.20 G.sup.4 629 R.sup.21 G.sup.4 630 R.sup.22 G.sup.4 631 R.sup.23 G.sup.4 632 R.sup.24 G.sup.4 633 R.sup.25 G.sup.4 634 R.sup.26 G.sup.4 635 R.sup.27 G.sup.4 636 R.sup.28 G.sup.4 637 R.sup.29 G.sup.4 638 R.sup.30 G.sup.4 639 R.sup.31 G.sup.4 640 R.sup.32 G.sup.4 641 R.sup.33 G.sup.4 642 R.sup.34 G.sup.4 643 R.sup.35 G.sup.4 644 R.sup.36 G.sup.4 645 R.sup.37 G.sup.4 646 R.sup.38 G.sup.4 647 R.sup.39 G.sup.4 648 R.sup.40 G.sup.4 649 R.sup.41 G.sup.4 650 R.sup.42 G.sup.4 651 R.sup.43 G.sup.4 652 R.sup.44 G.sup.4 653 R.sup.45 G.sup.4 654 R.sup.1 G.sup.8 655 R.sup.2 G.sup.8 656 R.sup.3 G.sup.8 657 R.sup.4 G.sup.8 658 R.sup.5 G.sup.8 659 R.sup.6 G.sup.8 660 R.sup.7 G.sup.8 661 R.sup.8 G.sup.8 662 R.sup.9 G.sup.8 663 R.sup.10 G.sup.8 664 R.sup.11 G.sup.8 665 R.sup.12 G.sup.8 666 R.sup.13 G.sup.8 667 R.sup.14 G.sup.8 668 R.sup.15 G.sup.8 669 R.sup.16 G.sup.8 670 R.sup.17 G.sup.8 671 R.sup.18 G.sup.8 672 R.sup.19 G.sup.8 673 R.sup.20 G.sup.8 674 R.sup.21 G.sup.8 675 R.sup.22 G.sup.8 676 R.sup.23 G.sup.8 677 R.sup.24 G.sup.8 678 R.sup.25 G.sup.8 679 R.sup.26 G.sup.8 680 R.sup.27 G.sup.8 681 R.sup.28 G.sup.8 682 R.sup.29 G.sup.8 683 R.sup.30 G.sup.8 684 R.sup.31 G.sup.8 685 R.sup.32 G.sup.8 686 R.sup.33 G.sup.8 687 R.sup.34 G.sup.8 688 R.sup.35 G.sup.8 689 R.sup.36 G.sup.8 690 R.sup.37 G.sup.8 691 R.sup.38 G.sup.8 692 R.sup.39 G.sup.8 693 R.sup.40 G.sup.8 694 R.sup.41 G.sup.8 695 R.sup.42 G.sup.8 696 R.sup.43 G.sup.8 697 R.sup.44 G.sup.8 698 R.sup.45 G.sup.8 699 R.sup.1 G.sup.12 700 R.sup.2 G.sup.12 701 R.sup.3 G.sup.12 702 R.sup.4 G.sup.12 703 R.sup.5 G.sup.12 704 R.sup.6 G.sup.12 705 R.sup.7 G.sup.12 706 R.sup.8 G.sup.12 707 R.sup.9 G.sup.12 708 R.sup.10 G.sup.12 709 R.sup.11 G.sup.12 710 R.sup.12 G.sup.12 711 R.sup.13 G.sup.12 712 R.sup.14 G.sup.12 713 R.sup.15 G.sup.12 714 R.sup.16 G.sup.12 715 R.sup.17 G.sup.12 716 R.sup.18 G.sup.12 717 R.sup.19 G.sup.12 718 R.sup.20 G.sup.12 719 R.sup.21 G.sup.12 720 R.sup.22 G.sup.12 721 R.sup.23 G.sup.12 722 R.sup.24 G.sup.12 723 R.sup.25 G.sup.12 724 R.sup.26 G.sup.12 725 R.sup.27 G.sup.12 726 R.sup.28 G.sup.12 727 R.sup.29 G.sup.12 728 R.sup.30 G.sup.12 729 R.sup.31 G.sup.12 730 R.sup.32 G.sup.12 731 R.sup.33 G.sup.12 732 R.sup.34 G.sup.12 733 R.sup.35 G.sup.12 734 R.sup.36 G.sup.12 735 R.sup.37 G.sup.12 736 R.sup.38 G.sup.12 737 R.sup.39 G.sup.12 738 R.sup.40 G.sup.12 739 R.sup.41 G.sup.12 740 R.sup.42 G.sup.12 741 R.sup.43 G.sup.12 742 R.sup.44 G.sup.12 743 R.sup.45 G.sup.12 744 R.sup.1 G.sup.16 745 R.sup.2 G.sup.16 746 R.sup.3 G.sup.16 747 R.sup.4 G.sup.16 748 R.sup.5 G.sup.16 749 R.sup.6 G.sup.16 750 R.sup.7 G.sup.16 751 R.sup.8 G.sup.16 752 R.sup.9 G.sup.16 753 R.sup.10 G.sup.16 754 R.sup.11 G.sup.16 755 R.sup.12 G.sup.16 756 R.sup.13 G.sup.16 757 R.sup.14 G.sup.16 758 R.sup.15 G.sup.16 759 R.sup.16 G.sup.16 760 R.sup.17 G.sup.16 761 R.sup.18 G.sup.16 762 R.sup.19 G.sup.16 763 R.sup.20 G.sup.16 764 R.sup.21 G.sup.16 765 R.sup.22 G.sup.16 766 R.sup.23 G.sup.16 767 R.sup.24 G.sup.16 768 R.sup.25 G.sup.16 769 R.sup.26 G.sup.16 770 R.sup.27 G.sup.16 771 R.sup.28 G.sup.16 772 R.sup.29 G.sup.16 773 R.sup.30 G.sup.16 774 R.sup.31 G.sup.16 775 R.sup.32 G.sup.16 776 R.sup.33 G.sup.16 777 R.sup.34 G.sup.16 778 R.sup.35 G.sup.16 779 R.sup.36 G.sup.16 780 R.sup.37 G.sup.16 781 R.sup.38 G.sup.16 782 R.sup.39 G.sup.16 783 R.sup.40 G.sup.16 784 R.sup.41 G.sup.16 785 R.sup.42 G.sup.16 786 R.sup.43 G.sup.16 787 R.sup.44 G.sup.16 788 R.sup.45 G.sup.16 789 R.sup.24 G.sup.18 790 R.sup.25 G.sup.18 791 R.sup.26 G.sup.18 792 R.sup.27 G.sup.18 793 R.sup.28 G.sup.18 794 R.sup.29 G.sup.18 795 R.sup.30 G.sup.18 796 R.sup.31 G.sup.18 797 R.sup.32 G.sup.18 798 R.sup.33 G.sup.18 799 R.sup.34 G.sup.18 800 R.sup.35 G.sup.18 801 R.sup.36 G.sup.18 802 R.sup.37 G.sup.18 803 R.sup.38 G.sup.18 804 R.sup.39 G.sup.18 805 R.sup.40 G.sup.18 806 R.sup.41 G.sup.18 807 R.sup.42 G.sup.18 808 R.sup.43 G.sup.18 809 R.sup.44 G.sup.18 810 R.sup.45 G.sup.18 wherein R.sup.1 to R.sup.45 have the following structures: ##STR00286## ##STR00287## ##STR00288## and wherein G.sup.1 to G.sup.18 have the following structures ##STR00289## ##STR00290## ##STR00291## ##STR00292##
7. The OLED of claim 3, wherein the ligand L.sub.A is selected from the group consisting of: L.sub.A1-k based on Structure A1: ##STR00293## L.sub.A2-k based on Structure A2: ##STR00294## L.sub.A3-k based on Structure A3: ##STR00295## L.sub.A4-k based on Structure A4: ##STR00296## L.sub.A5-k based on Structure A5: ##STR00297## and L.sub.A6-k based on Structure A6: ##STR00298## wherein k is an integer from 1 to 600, and for each k, R.sub.D, R.sub.F, and R.sub.G are as defined below: TABLE-US-00008 k R.sup.D R.sup.F R.sup.G 1 R.sup.D1 R.sup.D1 R.sup.D1 2 R.sup.D2 R.sup.D2 R.sup.D2 3 R.sup.D3 R.sup.D3 R.sup.D3 4 R.sup.D4 R.sup.D4 R.sup.D4 5 R.sup.D5 R.sup.D5 R.sup.D5 6 R.sup.D6 R.sup.D6 R.sup.D6 7 R.sup.D7 R.sup.D7 R.sup.D7 8 R.sup.D8 R.sup.D8 R.sup.D8 9 R.sup.D9 R.sup.D9 R.sup.D9 10 R.sup.D10 R.sup.D10 R.sup.D10 11 R.sup.D11 R.sup.D11 R.sup.D11 12 R.sup.D12 R.sup.D12 R.sup.D12 13 R.sup.D13 R.sup.D13 R.sup.D13 14 R.sup.D14 R.sup.D14 R.sup.D14 15 R.sup.D15 R.sup.D15 R.sup.D15 16 R.sup.D16 R.sup.D16 R.sup.D16 17 R.sup.D17 R.sup.D17 R.sup.D17 18 R.sup.D18 R.sup.D18 R.sup.D18 19 R.sup.D19 R.sup.D19 R.sup.D19 20 R.sup.D20 R.sup.D20 R.sup.D20 21 R.sup.D21 R.sup.D21 R.sup.D21 22 R.sup.D22 R.sup.D22 R.sup.D22 23 R.sup.D23 R.sup.D23 R.sup.D23 24 R.sup.D1 R.sup.D2 R.sup.D2 25 R.sup.D1 R.sup.D3 R.sup.D3 26 R.sup.D1 R.sup.D4 R.sup.D4 27 R.sup.D1 R.sup.D5 R.sup.D5 28 R.sup.D1 R.sup.D6 R.sup.D6 29 R.sup.D1 R.sup.D7 R.sup.D7 30 R.sup.D1 R.sup.D8 R.sup.D8 31 R.sup.D1 R.sup.D9 R.sup.D9 32 R.sup.D1 R.sup.D10 R.sup.D10 33 R.sup.D1 R.sup.D11 R.sup.D11 34 R.sup.D1 R.sup.D12 R.sup.D12 35 R.sup.D1 R.sup.D13 R.sup.D13 36 R.sup.D1 R.sup.D14 R.sup.D14 37 R.sup.D1 R.sup.D15 R.sup.D15 38 R.sup.D1 R.sup.D16 R.sup.D16 39 R.sup.D1 R.sup.D17 R.sup.D17 40 R.sup.D1 R.sup.D18 R.sup.D18 41 R.sup.D1 R.sup.D19 R.sup.D19 42 R.sup.D1 R.sup.D20 R.sup.D20 43 R.sup.D1 R.sup.D21 R.sup.D21 44 R.sup.D1 R.sup.D22 R.sup.D22 45 R.sup.D1 R.sup.D23 R.sup.D23 46 R.sup.D1 R.sup.D2 R.sup.D3 47 R.sup.D1 R.sup.D2 R.sup.D4 48 R.sup.D1 R.sup.D2 R.sup.D5 49 R.sup.D1 R.sup.D2 R.sup.D6 50 R.sup.D1 R.sup.D2 R.sup.D7 51 R.sup.D1 R.sup.D2 R.sup.D8 52 R.sup.D1 R.sup.D2 R.sup.D9 53 R.sup.D1 R.sup.D2 R.sup.D10 54 R.sup.D1 R.sup.D2 R.sup.D11 55 R.sup.D1 R.sup.D2 R.sup.D12 56 R.sup.D1 R.sup.D2 R.sup.D13 57 R.sup.D1 R.sup.D2 R.sup.D14 58 R.sup.D1 R.sup.D2 R.sup.D15 59 R.sup.D1 R.sup.D2 R.sup.D16 60 R.sup.D1 R.sup.D2 R.sup.D17 61 R.sup.D1 R.sup.D2 R.sup.D18 62 R.sup.D1 R.sup.D2 R.sup.D19 63 R.sup.D1 R.sup.D2 R.sup.D20 64 R.sup.D1 R.sup.D2 R.sup.D21 65 R.sup.D1 R.sup.D2 R.sup.D22 66 R.sup.D1 R.sup.D2 R.sup.D23 67 R.sup.D1 R.sup.D3 R.sup.D4 68 R.sup.D1 R.sup.D3 R.sup.D5 69 R.sup.D1 R.sup.D3 R.sup.D6 70 R.sup.D1 R.sup.D3 R.sup.D7 71 R.sup.D1 R.sup.D3 R.sup.D8 72 R.sup.D1 R.sup.D3 R.sup.D9 73 R.sup.D1 R.sup.D3 R.sup.D10 74 R.sup.D1 R.sup.D3 R.sup.D11 75 R.sup.D1 R.sup.D3 R.sup.D12 76 R.sup.D1 R.sup.D3 R.sup.D13 77 R.sup.D1 R.sup.D3 R.sup.D14 78 R.sup.D1 R.sup.D3 R.sup.D15 79 R.sup.D1 R.sup.D3 R.sup.D16 80 R.sup.D1 R.sup.D3 R.sup.D17 81 R.sup.D1 R.sup.D3 R.sup.D18 82 R.sup.D1 R.sup.D3 R.sup.D19 83 R.sup.D1 R.sup.D3 R.sup.D20 84 R.sup.D1 R.sup.D3 R.sup.D21 85 R.sup.D1 R.sup.D3 R.sup.D22 86 R.sup.D1 R.sup.D3 R.sup.D23 87 R.sup.D1 R.sup.D4 R.sup.D5 88 R.sup.D1 R.sup.D4 R.sup.D6 89 R.sup.D1 R.sup.D4 R.sup.D7 90 R.sup.D1 R.sup.D4 R.sup.D8 91 R.sup.D1 R.sup.D4 R.sup.D9 92 R.sup.D1 R.sup.D4 R.sup.D10 93 R.sup.D1 R.sup.D4 R.sup.D11 94 R.sup.D1 R.sup.D4 R.sup.D12 95 R.sup.D1 R.sup.D4 R.sup.D13 96 R.sup.D1 R.sup.D4 R.sup.D14 97 R.sup.D1 R.sup.D4 R.sup.D15 98 R.sup.D1 R.sup.D4 R.sup.D16 99 R.sup.D1 R.sup.D4 R.sup.D17 100 R.sup.D1 R.sup.D4 R.sup.D18 101 R.sup.D1 R.sup.D4 R.sup.D19 102 R.sup.D1 R.sup.D4 R.sup.D20 103 R.sup.D1 R.sup.D4 R.sup.D21 104 R.sup.D1 R.sup.D4 R.sup.D22 105 R.sup.D1 R.sup.D4 R.sup.D23 106 R.sup.D1 R.sup.D5 R.sup.D6 107 R.sup.D1 R.sup.D5 R.sup.D7 108 R.sup.D1 R.sup.D5 R.sup.D8 109 R.sup.D1 R.sup.D5 R.sup.D9 110 R.sup.D1 R.sup.D5 R.sup.D10 111 R.sup.D1 R.sup.D5 R.sup.D11 112 R.sup.D1 R.sup.D5 R.sup.D12 113 R.sup.D1 R.sup.D5 R.sup.D13 114 R.sup.D1 R.sup.D5 R.sup.D14 115 R.sup.D1 R.sup.D5 R.sup.D15 116 R.sup.D1 R.sup.D5 R.sup.D16 117 R.sup.D1 R.sup.D5 R.sup.D17 118 R.sup.D1 R.sup.D5 R.sup.D18 119 R.sup.D1 R.sup.D5 R.sup.D19 120 R.sup.D1 R.sup.D5 R.sup.D20 121 R.sup.D1 R.sup.D5 R.sup.D21 122 R.sup.D1 R.sup.D5 R.sup.D22 123 R.sup.D1 R.sup.D5 R.sup.D23 124 R.sup.D1 R.sup.D6 R.sup.D7 125 R.sup.D1 R.sup.D6 R.sup.D8 126 R.sup.D1 R.sup.D6 R.sup.D9 127 R.sup.D1 R.sup.D6 R.sup.D10 128 R.sup.D1 R.sup.D6 R.sup.D11 129 R.sup.D1 R.sup.D6 R.sup.D12 130 R.sup.D1 R.sup.D6 R.sup.D13 131 R.sup.D1 R.sup.D6 R.sup.D14 132 R.sup.D1 R.sup.D6 R.sup.D15 133 R.sup.D1 R.sup.D6 R.sup.D16 134 R.sup.D1 R.sup.D6 R.sup.D17 135 R.sup.D1 R.sup.D6 R.sup.D18 136 R.sup.D1 R.sup.D6 R.sup.D19 137 R.sup.D1 R.sup.D6 R.sup.D20 138 R.sup.D1 R.sup.D6 R.sup.D21 139 R.sup.D1 R.sup.D6 R.sup.D22 140 R.sup.D1 R.sup.D6 R.sup.D23 141 R.sup.D1 R.sup.D7 R.sup.D8 142 R.sup.D1 R.sup.D7 R.sup.D9 143 R.sup.D1 R.sup.D7 R.sup.D10 144 R.sup.D1 R.sup.D7 R.sup.D11 145 R.sup.D1 R.sup.D7 R.sup.D12 146 R.sup.D1 R.sup.D7 R.sup.D13 147 R.sup.D1 R.sup.D7 R.sup.D14 148 R.sup.D1 R.sup.D7 R.sup.D15 149 R.sup.D1 R.sup.D7 R.sup.D16 150 R.sup.D1 R.sup.D7 R.sup.D17 151 R.sup.D1 R.sup.D7 R.sup.D18 152 R.sup.D1 R.sup.D7 R.sup.D19 153 R.sup.D1 R.sup.D7 R.sup.D20 154 R.sup.D1 R.sup.D7 R.sup.D21 155 R.sup.D1 R.sup.D7 R.sup.D22 156 R.sup.D1 R.sup.D7 R.sup.D23 157 R.sup.D1 R.sup.D8 R.sup.D9 158 R.sup.D1 R.sup.D8 R.sup.D10 159 R.sup.D1 R.sup.D8 R.sup.D11 160 R.sup.D1 R.sup.D8 R.sup.D12 161 R.sup.D1 R.sup.D8 R.sup.D13 162 R.sup.D1 R.sup.D8 R.sup.D14 163 R.sup.D1 R.sup.D8 R.sup.D15 164 R.sup.D1 R.sup.D8 R.sup.D16 165 R.sup.D1 R.sup.D8 R.sup.D17 166 R.sup.D1 R.sup.D8 R.sup.D18 167 R.sup.D1 R.sup.D8 R.sup.D19 168 R.sup.D1 R.sup.D8 R.sup.D20 169 R.sup.D1 R.sup.D8 R.sup.D21 170 R.sup.D1 R.sup.D8 R.sup.D22 171 R.sup.D1 R.sup.D8 R.sup.D23 172 R.sup.D1 R.sup.D9 R.sup.D10 173 R.sup.D1 R.sup.D9 R.sup.D11 174 R.sup.D1 R.sup.D9 R.sup.D12 175 R.sup.D1 R.sup.D9 R.sup.D13 176 R.sup.D1 R.sup.D9 R.sup.D14 177 R.sup.D1 R.sup.D9 R.sup.D15 178 R.sup.D1 R.sup.D9 R.sup.D16 179 R.sup.D1 R.sup.D9 R.sup.D17 180 R.sup.D1 R.sup.D9 R.sup.D18 181 R.sup.D1 R.sup.D9 R.sup.D19 182 R.sup.D1 R.sup.D9 R.sup.D20 183 R.sup.D1 R.sup.D9 R.sup.D21 184 R.sup.D1 R.sup.D9 R.sup.D22 185 R.sup.D1 R.sup.D9 R.sup.D23 186 R.sup.D1 R.sup.D10 R.sup.D11 187 R.sup.D1 R.sup.D10 R.sup.D12 188 R.sup.D1 R.sup.D10 R.sup.D13 189 R.sup.D1 R.sup.D10 R.sup.D14 190 R.sup.D1 R.sup.D10 R.sup.D15 191 R.sup.D1 R.sup.D10 R.sup.D16 192 R.sup.D1 R.sup.D10 R.sup.D17 193 R.sup.D1 R.sup.D10 R.sup.D18 194 R.sup.D1 R.sup.D10 R.sup.D19 195 R.sup.D1 R.sup.D10 R.sup.D20 196 R.sup.D1 R.sup.D10 R.sup.D21 197 R.sup.D1 R.sup.D10 R.sup.D22 198 R.sup.D1 R.sup.D10 R.sup.D23 199 R.sup.D1 R.sup.D11 R.sup.D12 200 R.sup.D1 R.sup.D11 R.sup.D13 201 R.sup.D1 R.sup.D11 R.sup.D14 202 R.sup.D1 R.sup.D11 R.sup.D15 203 R.sup.D1 R.sup.D11 R.sup.D16 204 R.sup.D1 R.sup.D11 R.sup.D17 205 R.sup.D1 R.sup.D11 R.sup.D18 206 R.sup.D1 R.sup.D11 R.sup.D19 207 R.sup.D1 R.sup.D11 R.sup.D20 208 R.sup.D1 R.sup.D11 R.sup.D21 209 R.sup.D1 R.sup.D11 R.sup.D22 210 R.sup.D1 R.sup.D11 R.sup.D23 211 R.sup.D1 R.sup.D12 R.sup.D13 212 R.sup.D1 R.sup.D12 R.sup.D14 213 R.sup.D1 R.sup.D12 R.sup.D15 214 R.sup.D1 R.sup.D12 R.sup.D16 215 R.sup.D1 R.sup.D12 R.sup.D17 216 R.sup.D1 R.sup.D12 R.sup.D18 217 R.sup.D1 R.sup.D12 R.sup.D19 218 R.sup.D1 R.sup.D12 R.sup.D20 219 R.sup.D1 R.sup.D12 R.sup.D21 220 R.sup.D1 R.sup.D12 R.sup.D22 221 R.sup.D1 R.sup.D12 R.sup.D23 222 R.sup.D1 R.sup.D13 R.sup.D14 223 R.sup.D1 R.sup.D13 R.sup.D15 224 R.sup.D1 R.sup.D13 R.sup.D16 225 R.sup.D1 R.sup.D13 R.sup.D17 226 R.sup.D1 R.sup.D13 R.sup.D18 227 R.sup.D1 R.sup.D13 R.sup.D19 228 R.sup.D1 R.sup.D13 R.sup.D20 229 R.sup.D1 R.sup.D13 R.sup.D21 230 R.sup.D1 R.sup.D13 R.sup.D22 231 R.sup.D1 R.sup.D13 R.sup.D23 232 R.sup.D1 R.sup.D14 R.sup.D15 233 R.sup.D1 R.sup.D14 R.sup.D16 234 R.sup.D1 R.sup.D14 R.sup.D17 235 R.sup.D1 R.sup.D14 R.sup.D18 236 R.sup.D1 R.sup.D14 R.sup.D19 237 R.sup.D1 R.sup.D14 R.sup.D20 238 R.sup.D1 R.sup.D14 R.sup.D21 239 R.sup.D1 R.sup.D14 R.sup.D22 240 R.sup.D1 R.sup.D14 R.sup.D23 241 R.sup.D1 R.sup.D15 R.sup.D16 242 R.sup.D1 R.sup.D15 R.sup.D17 243 R.sup.D1 R.sup.D15 R.sup.D18 244 R.sup.D1 R.sup.D15 R.sup.D19 245 R.sup.D1 R.sup.D15 R.sup.D20 246 R.sup.D1 R.sup.D15 R.sup.D21 247 R.sup.D1 R.sup.D15 R.sup.D22 248 R.sup.D1 R.sup.D15 R.sup.D23 249 R.sup.D1 R.sup.D16 R.sup.D17 250 R.sup.D1 R.sup.D16 R.sup.D18 251 R.sup.D1 R.sup.D16 R.sup.D19 252 R.sup.D1 R.sup.D16 R.sup.D20 253 R.sup.D1 R.sup.D16 R.sup.D21 254 R.sup.D1 R.sup.D16 R.sup.D22 255 R.sup.D1 R.sup.D16 R.sup.D23 256 R.sup.D1 R.sup.D17 R.sup.D18 257 R.sup.D1 R.sup.D17 R.sup.D19 258 R.sup.D1 R.sup.D17 R.sup.D20 259 R.sup.D1 R.sup.D17 R.sup.D21 260 R.sup.D1 R.sup.D17 R.sup.D22 261 R.sup.D1 R.sup.D17 R.sup.D23 262 R.sup.D1 R.sup.D18 R.sup.D19 263 R.sup.D1 R.sup.D18 R.sup.D20 264 R.sup.D1 R.sup.D18 R.sup.D21 265 R.sup.D1 R.sup.D18 R.sup.D22 266 R.sup.D1 R.sup.D18 R.sup.D23 267 R.sup.D1 R.sup.D19 R.sup.D20 268 R.sup.D1 R.sup.D19 R.sup.D21 269 R.sup.D1 R.sup.D19 R.sup.D22 270 R.sup.D1 R.sup.D19 R.sup.D23 271 R.sup.D1 R.sup.D20 R.sup.D21 272 R.sup.D1 R.sup.D20 R.sup.D22 273 R.sup.D1 R.sup.D20 R.sup.D23 274 R.sup.D1 R.sup.D21 R.sup.D22 275 R.sup.D1 R.sup.D21 R.sup.D23 276 R.sup.D1 R.sup.D22 R.sup.D23 277 R.sup.D2 R.sup.D2 R.sup.D2 278 R.sup.D2 R.sup.D3 R.sup.D3 279 R.sup.D2 R.sup.D4 R.sup.D4 280 R.sup.D2 R.sup.D5 R.sup.D5 281 R.sup.D2 R.sup.D6 R.sup.D6 282 R.sup.D2 R.sup.D7 R.sup.D7 283 R.sup.D2 R.sup.D8 R.sup.D8 284 R.sup.D2 R.sup.D9 R.sup.D9 285 R.sup.D2 R.sup.D10 R.sup.D10 286 R.sup.D2 R.sup.D11 R.sup.D11 287 R.sup.D2 R.sup.D12 R.sup.D12 288 R.sup.D2 R.sup.D13 R.sup.D13 289 R.sup.D2 R.sup.D14 R.sup.D14 290 R.sup.D2 R.sup.D15 R.sup.D15 291 R.sup.D2 R.sup.D16 R.sup.D16 292 R.sup.D2 R.sup.D17 R.sup.D17 293 R.sup.D2 R.sup.D18 R.sup.D18 294 R.sup.D2 R.sup.D19 R.sup.D19 295 R.sup.D2 R.sup.D20 R.sup.D20 296 R.sup.D2 R.sup.D21 R.sup.D21 297 R.sup.D2 R.sup.D22 R.sup.D22 298 R.sup.D2 R.sup.D23 R.sup.D23 299 R.sup.D2 R.sup.D2 R.sup.D3 300 R.sup.D2 R.sup.D2 R.sup.D4 301 R.sup.D2 R.sup.D2 R.sup.D5 302 R.sup.D2 R.sup.D2 R.sup.D6 303 R.sup.D2 R.sup.D2 R.sup.D7 304 R.sup.D2 R.sup.D2 R.sup.D8 305 R.sup.D2 R.sup.D2 R.sup.D9 306 R.sup.D2 R.sup.D2 R.sup.D10 307 R.sup.D2 R.sup.D2 R.sup.D11 308 R.sup.D2 R.sup.D2 R.sup.D12 309 R.sup.D2 R.sup.D2 R.sup.D13 310 R.sup.D2 R.sup.D2 R.sup.D14 311 R.sup.D2 R.sup.D2 R.sup.D15 312 R.sup.D2 R.sup.D2 R.sup.D16 313 R.sup.D2 R.sup.D2 R.sup.D17 314 R.sup.D2 R.sup.D2 R.sup.D18 315 R.sup.D2 R.sup.D2 R.sup.D19 316 R.sup.D2 R.sup.D2 R.sup.D20 317 R.sup.D2 R.sup.D2 R.sup.D21 318 R.sup.D2 R.sup.D2 R.sup.D22 319 R.sup.D2 R.sup.D2 R.sup.D23 320 R.sup.D2 R.sup.D3 R.sup.D4 321 R.sup.D2 R.sup.D3 R.sup.D5 322 R.sup.D2 R.sup.D3 R.sup.D6 323 R.sup.D2 R.sup.D3 R.sup.D7 324 R.sup.D2 R.sup.D3 R.sup.D8 325 R.sup.D2 R.sup.D3 R.sup.D9 326 R.sup.D2 R.sup.D3 R.sup.D10 327 R.sup.D2 R.sup.D3 R.sup.D11 328 R.sup.D2 R.sup.D3 R.sup.D12 329 R.sup.D2 R.sup.D3 R.sup.D13 330 R.sup.D2 R.sup.D3 R.sup.D14 331 R.sup.D2 R.sup.D3 R.sup.D15 332 R.sup.D2 R.sup.D3 R.sup.D16 333 R.sup.D2 R.sup.D3 R.sup.D17 334 R.sup.D2 R.sup.D3 R.sup.D18 335 R.sup.D2 R.sup.D3 R.sup.D19 336 R.sup.D2 R.sup.D3 R.sup.D20 337 R.sup.D2 R.sup.D3 R.sup.D21 338 R.sup.D2 R.sup.D3 R.sup.D22 339 R.sup.D2 R.sup.D3 R.sup.D23 340 R.sup.D2 R.sup.D4 R.sup.D5 341 R.sup.D2 R.sup.D4 R.sup.D6 342 R.sup.D2 R.sup.D4 R.sup.D7 343 R.sup.D2 R.sup.D4 R.sup.D8 344 R.sup.D2 R.sup.D4 R.sup.D9 345 R.sup.D2 R.sup.D4 R.sup.D10 346 R.sup.D2 R.sup.D4 R.sup.D11 347 R.sup.D2 R.sup.D4 R.sup.D12 348 R.sup.D2 R.sup.D4 R.sup.D13 349 R.sup.D2 R.sup.D4 R.sup.D14 350 R.sup.D2 R.sup.D4 R.sup.D15 351 R.sup.D2 R.sup.D4 R.sup.D16 352 R.sup.D2 R.sup.D4 R.sup.D17 353 R.sup.D2 R.sup.D4 R.sup.D18 354 R.sup.D2 R.sup.D4 R.sup.D19 355 R.sup.D2 R.sup.D4 R.sup.D20 356 R.sup.D2 R.sup.D4 R.sup.D21 357 R.sup.D2 R.sup.D4 R.sup.D22 358 R.sup.D2 R.sup.D4 R.sup.D23 359 R.sup.D2 R.sup.D5 R.sup.D6 360 R.sup.D2 R.sup.D5 R.sup.D7 361 R.sup.D2 R.sup.D5 R.sup.D8 362 R.sup.D2 R.sup.D5 R.sup.D9 363 R.sup.D2 R.sup.D5 R.sup.D10 364 R.sup.D2 R.sup.D5 R.sup.D11 365 R.sup.D2 R.sup.D5 R.sup.D12 366 R.sup.D2 R.sup.D5 R.sup.D13 367 R.sup.D2 R.sup.D5 R.sup.D14 368 R.sup.D2 R.sup.D5 R.sup.D15 369 R.sup.D2 R.sup.D5 R.sup.D16 370 R.sup.D2 R.sup.D5 R.sup.D17 371 R.sup.D2 R.sup.D5 R.sup.D18 372 R.sup.D2 R.sup.D5 R.sup.D19 373 R.sup.D2 R.sup.D5 R.sup.D20 374 R.sup.D2 R.sup.D5 R.sup.D21 375 R.sup.D2 R.sup.D5 R.sup.D22 376 R.sup.D2 R.sup.D5 R.sup.D23 377 R.sup.D2 R.sup.D6 R.sup.D7 378 R.sup.D2 R.sup.D6 R.sup.D8 379 R.sup.D2 R.sup.D6 R.sup.D9 380 R.sup.D2 R.sup.D6 R.sup.D10 381 R.sup.D2 R.sup.D6 R.sup.D11 382 R.sup.D2 R.sup.D6 R.sup.D12 383 R.sup.D2 R.sup.D6 R.sup.D13 384 R.sup.D2 R.sup.D6 R.sup.D14 385 R.sup.D2 R.sup.D6 R.sup.D15 386 R.sup.D2 R.sup.D6 R.sup.D16 387 R.sup.D2 R.sup.D6 R.sup.D17 388 R.sup.D2 R.sup.D6 R.sup.D18 389 R.sup.D2 R.sup.D6 R.sup.D19 390 R.sup.D2 R.sup.D6 R.sup.D20 391 R.sup.D2 R.sup.D6 R.sup.D21 392 R.sup.D2 R.sup.D6 R.sup.D22 393 R.sup.D2 R.sup.D6 R.sup.D23 394 R.sup.D2 R.sup.D7 R.sup.D8 395 R.sup.D2 R.sup.D7 R.sup.D9 396 R.sup.D2 R.sup.D7 R.sup.D10 397 R.sup.D2 R.sup.D7 R.sup.D11 398 R.sup.D2 R.sup.D7 R.sup.D12 399 R.sup.D2 R.sup.D7 R.sup.D13 400 R.sup.D2 R.sup.D7 R.sup.D14 401 R.sup.D2 R.sup.D7 R.sup.D15 402 R.sup.D2 R.sup.D7 R.sup.D16 403 R.sup.D2 R.sup.D7 R.sup.D17 404 R.sup.D2 R.sup.D7 R.sup.D18 405 R.sup.D2 R.sup.D7 R.sup.D19 406 R.sup.D2 R.sup.D7 R.sup.D20 407 R.sup.D2 R.sup.D7 R.sup.D21 408 R.sup.D2 R.sup.D7 R.sup.D22 409 R.sup.D2 R.sup.D7 R.sup.D23 410 R.sup.D2 R.sup.D8 R.sup.D9 411 R.sup.D2 R.sup.D8 R.sup.D10 412 R.sup.D2 R.sup.D8 R.sup.D11 413 R.sup.D2 R.sup.D8 R.sup.D12 414 R.sup.D2 R.sup.D8 R.sup.D13 415 R.sup.D2 R.sup.D8 R.sup.D14 416 R.sup.D2 R.sup.D8 R.sup.D15 417 R.sup.D2 R.sup.D8 R.sup.D16 418 R.sup.D2 R.sup.D8 R.sup.D17 419 R.sup.D2 R.sup.D8 R.sup.D18 420 R.sup.D2 R.sup.D8 R.sup.D19 421 R.sup.D2 R.sup.D8 R.sup.D20 422 R.sup.D2 R.sup.D8 R.sup.D21 423 R.sup.D2 R.sup.D8 R.sup.D22 424 R.sup.D2 R.sup.D8 R.sup.D23 425 R.sup.D2 R.sup.D9 R.sup.D10 426 R.sup.D2 R.sup.D9 R.sup.D11 427 R.sup.D2 R.sup.D9 R.sup.D12 428 R.sup.D2 R.sup.D9 R.sup.D13 429 R.sup.D2 R.sup.D9 R.sup.D14 430 R.sup.D2 R.sup.D9 R.sup.D15 431 R.sup.D2 R.sup.D9 R.sup.D16 432 R.sup.D2 R.sup.D9 R.sup.D17 433 R.sup.D2 R.sup.D9 R.sup.D18 434 R.sup.D2 R.sup.D9 R.sup.D19 435 R.sup.D2 R.sup.D9 R.sup.D20 436 R.sup.D2 R.sup.D9 R.sup.D21 437 R.sup.D2 R.sup.D9 R.sup.D22 438 R.sup.D2 R.sup.D9 R.sup.D23 439 R.sup.D2 R.sup.D10 R.sup.D11 440 R.sup.D2 R.sup.D10 R.sup.D12 441 R.sup.D2 R.sup.D10 R.sup.D13 442 R.sup.D2 R.sup.D10 R.sup.D14 443 R.sup.D2 R.sup.D10 R.sup.D15 444 R.sup.D2 R.sup.D10 R.sup.D16 445 R.sup.D2 R.sup.D10 R.sup.D17 446 R.sup.D2 R.sup.D10 R.sup.D18 447 R.sup.D2 R.sup.D10 R.sup.D19 448 R.sup.D2 R.sup.D10 R.sup.D20 449 R.sup.D2 R.sup.D10 R.sup.D21 450 R.sup.D2 R.sup.D10 R.sup.D22 451 R.sup.D2 R.sup.D10 R.sup.D23 452 R.sup.D2 R.sup.D11 R.sup.D12 453 R.sup.D2 R.sup.D11 R.sup.D13 454 R.sup.D2 R.sup.D11 R.sup.D14 455 R.sup.D2 R.sup.D11 R.sup.D15 456 R.sup.D2 R.sup.D11 R.sup.D16 457 R.sup.D2 R.sup.D11 R.sup.D17 458 R.sup.D2 R.sup.D11 R.sup.D18 459 R.sup.D2 R.sup.D11 R.sup.D19 460 R.sup.D2 R.sup.D11 R.sup.D20 461 R.sup.D2 R.sup.D11 R.sup.D21 462 R.sup.D2 R.sup.D11 R.sup.D22 463 R.sup.D2 R.sup.D11 R.sup.D23 464 R.sup.D2 R.sup.D12 R.sup.D13 465 R.sup.D2 R.sup.D12 R.sup.D14 466 R.sup.D2 R.sup.D12 R.sup.D15 467 R.sup.D2 R.sup.D12 R.sup.D16 468 R.sup.D2 R.sup.D12 R.sup.D17 469 R.sup.D2 R.sup.D12 R.sup.D18 470 R.sup.D2 R.sup.D12 R.sup.D19 471 R.sup.D2 R.sup.D12 R.sup.D20 472 R.sup.D2 R.sup.D12 R.sup.D21 473 R.sup.D2 R.sup.D12 R.sup.D22 474 R.sup.D2 R.sup.D12 R.sup.D23 475 R.sup.D2 R.sup.D13 R.sup.D14 476 R.sup.D2 R.sup.D13 R.sup.D15 477 R.sup.D2 R.sup.D13 R.sup.D16 478 R.sup.D2 R.sup.D13 R.sup.D17 479 R.sup.D2 R.sup.D13 R.sup.D18 480 R.sup.D2 R.sup.D13 R.sup.D19 481 R.sup.D2 R.sup.D13 R.sup.D20 482 R.sup.D2 R.sup.D13 R.sup.D21 483 R.sup.D2 R.sup.D13 R.sup.D22 484 R.sup.D2 R.sup.D13 R.sup.D23 485 R.sup.D2 R.sup.D14 R.sup.D15 486 R.sup.D2 R.sup.D14 R.sup.D16 487 R.sup.D2 R.sup.D14 R.sup.D17 488 R.sup.D2 R.sup.D14 R.sup.D18 489 R.sup.D2 R.sup.D14 R.sup.D19 490 R.sup.D2 R.sup.D14 R.sup.D20 491 R.sup.D2 R.sup.D14 R.sup.D21 492 R.sup.D2 R.sup.D14 R.sup.D22 493 R.sup.D2 R.sup.D14 R.sup.D23 494 R.sup.D2 R.sup.D15 R.sup.D16 495 R.sup.D2 R.sup.D15 R.sup.D17 496 R.sup.D2 R.sup.D15 R.sup.D18 497 R.sup.D2 R.sup.D15 R.sup.D19 498 R.sup.D2 R.sup.D15 R.sup.D20 499 R.sup.D2 R.sup.D15 R.sup.D21 500 R.sup.D2 R.sup.D15 R.sup.D22 501 R.sup.D2 R.sup.D15 R.sup.D23 502 R.sup.D2 R.sup.D16 R.sup.D17 503 R.sup.D2 R.sup.D16 R.sup.D18 504 R.sup.D2 R.sup.D16 R.sup.D19 505 R.sup.D2 R.sup.D16 R.sup.D20 506 R.sup.D2 R.sup.D16 R.sup.D21 507 R.sup.D2 R.sup.D16 R.sup.D22 508 R.sup.D2 R.sup.D16 R.sup.D23 509 R.sup.D2 R.sup.D17 R.sup.D18 510 R.sup.D2 R.sup.D17 R.sup.D19 511 R.sup.D2 R.sup.D17 R.sup.D20 512 R.sup.D2 R.sup.D17 R.sup.D21 513 R.sup.D2 R.sup.D17 R.sup.D22 514 R.sup.D2 R.sup.D17 R.sup.D23 515 R.sup.D2 R.sup.D18 R.sup.D19 516 R.sup.D2 R.sup.D18 R.sup.D20 517 R.sup.D2 R.sup.D18 R.sup.D21 518 R.sup.D2 R.sup.D18 R.sup.D22 519 R.sup.D2 R.sup.D18 R.sup.D23 520 R.sup.D2 R.sup.D19 R.sup.D20 521 R.sup.D2 R.sup.D19 R.sup.D21 522 R.sup.D2 R.sup.D19 R.sup.D22 523 R.sup.D2 R.sup.D19 R.sup.D23 524 R.sup.D2 R.sup.D20 R.sup.D21 525 R.sup.D2 R.sup.D20 R.sup.D22 526 R.sup.D2 R.sup.D20 R.sup.D23 527 R.sup.D2 R.sup.D21 R.sup.D22 528 R.sup.D2 R.sup.D21 R.sup.D23 529 R.sup.D2 R.sup.D22 R.sup.D23 530 R.sup.D19 R.sup.D2 R.sup.D2 531 R.sup.D19 R.sup.D3 R.sup.D3 532 R.sup.D19 R.sup.D4 R.sup.D4 533 R.sup.D19 R.sup.D5 R.sup.D5 534 R.sup.D19 R.sup.D6 R.sup.D6 535 R.sup.D19 R.sup.D7 R.sup.D7 536 R.sup.D19 R.sup.D8 R.sup.D8 537 R.sup.D19 R.sup.D9 R.sup.D9 538 R.sup.D19 R.sup.D10 R.sup.D10 539 R.sup.D19 R.sup.D11 R.sup.D11 540 R.sup.D19 R.sup.D12 R.sup.D12 541 R.sup.D19 R.sup.D13 R.sup.D13 542 R.sup.D19 R.sup.D14 R.sup.D14 543 R.sup.D19 R.sup.D15 R.sup.D15 544 R.sup.D19 R.sup.D16 R.sup.D16 545 R.sup.D19 R.sup.D17 R.sup.D17 546 R.sup.D19 R.sup.D18 R.sup.D18 547 R.sup.D19 R.sup.D19 R.sup.D19 548 R.sup.D19 R.sup.D20 R.sup.D20 549 R.sup.D19 R.sup.D21 R.sup.D21 550 R.sup.D19 R.sup.D22 R.sup.D22 551 R.sup.D19 R.sup.D23 R.sup.D23 552 R.sup.D19 R.sup.D2 R.sup.D3 553 R.sup.D19 R.sup.D2 R.sup.D4 554 R.sup.D19 R.sup.D2 R.sup.D5 555 R.sup.D19 R.sup.D2 R.sup.D6 556 R.sup.D19 R.sup.D2 R.sup.D7 557 R.sup.D19 R.sup.D2 R.sup.D8 558 R.sup.D19 R.sup.D2 R.sup.D9 559 R.sup.D19 R.sup.D2 R.sup.D10 560 R.sup.D19 R.sup.D2 R.sup.D11 561 R.sup.D19 R.sup.D2 R.sup.D12 562 R.sup.D19 R.sup.D2 R.sup.D13 563 R.sup.D19 R.sup.D2 R.sup.D14 564 R.sup.D19 R.sup.D2 R.sup.D15 565 R.sup.D19 R.sup.D2 R.sup.D16 566 R.sup.D19 R.sup.D2 R.sup.D17 567 R.sup.D19 R.sup.D2 R.sup.D18 568 R.sup.D19 R.sup.D2 R.sup.D19 569 R.sup.D19 R.sup.D2 R.sup.D20 570 R.sup.D19 R.sup.D2 R.sup.D21 571 R.sup.D19 R.sup.D2 R.sup.D22 572 R.sup.D19 R.sup.D2 R.sup.D23 573 R.sup.D19 R.sup.D3 R.sup.D4 574 R.sup.D19 R.sup.D3 R.sup.D5 575 R.sup.D19 R.sup.D3 R.sup.D6 576 R.sup.D19 R.sup.D3 R.sup.D7 577 R.sup.D19 R.sup.D3 R.sup.D8 578 R.sup.D19 R.sup.D3 R.sup.D9 579 R.sup.D19 R.sup.D3 R.sup.D10 580 R.sup.D19 R.sup.D3 R.sup.D11 581 R.sup.D19 R.sup.D3 R.sup.D12 582 R.sup.D19 R.sup.D3 R.sup.D13 583 R.sup.D19 R.sup.D3 R.sup.D14 584 R.sup.D19 R.sup.D3 R.sup.D15 585 R.sup.D19 R.sup.D3 R.sup.D16 586 R.sup.D19 R.sup.D3 R.sup.D17 587 R.sup.D19 R.sup.D3 R.sup.D18 588 R.sup.D19 R.sup.D3 R.sup.D19 589 R.sup.D19 R.sup.D3 R.sup.D20 590 R.sup.D19 R.sup.D3 R.sup.D21 591 R.sup.D19 R.sup.D3 R.sup.D22 592 R.sup.D19 R.sup.D3 R.sup.D23 593 R.sup.D19 R.sup.D4 R.sup.D5 594 R.sup.D19 R.sup.D4 R.sup.D6 595 R.sup.D19 R.sup.D4 R.sup.D7 596 R.sup.D19 R.sup.D4 R.sup.D8 597 R.sup.D19 R.sup.D4 R.sup.D9 598 R.sup.D19 R.sup.D4 R.sup.D10 599 R.sup.D19 R.sup.D4 R.sup.D11 600 R.sup.D19 R.sup.D4 R.sup.D12 wherein R.sup.D1 to R.sup.D23 have the following structures: ##STR00299## ##STR00300##
8. The OLED of claim 7, wherein the first emitter is selected from the group consisting of: (L.sup.1-L.sup.2-1-1).sub.2Ir(L.sub.A1-1) to (L.sup.1-L.sup.2-17-810).sub.2Ir(L.sub.A6-600) based on the general formula of (L.sup.1-L.sup.2-m-i).sub.2Ir(L.sub.An-k), wherein m is an integer from 1 to 17, i is an integer from 1 to 810, n is an integer from 1 to 6, and k is an integer from 1 to 600.
9. The OLED of claim 4, wherein at least one of R.sup.S11, R.sup.S12, and R.sup.S13 is selected from the group consisting of: ##STR00301## ##STR00302## ##STR00303## ##STR00304## ##STR00305## ##STR00306## ##STR00307##
10. The OLED of claim 4, wherein the first emitter is selected from the group consisting of: ##STR00308## ##STR00309## wherein when there is more than one R.sup.S11 or R.sup.S13, each R.sup.S11 and R.sup.S13 can be same or different.
11. The OLED of claim 4, wherein the ligand L.sub.B is selected from the group consisting of: L.sub.B1-h based on Structure B1: ##STR00310## L.sub.B2-h based on Structure B2: ##STR00311## L.sub.B3-h based on Structure B3: ##STR00312## L.sub.B4-h based on Structure B4: ##STR00313## L.sub.B5-h based on Structure B5: ##STR00314## wherein h is an integer from 1 to 1170, and for each h, R.sup.H, and G are defined as below: TABLE-US-00009 h R.sup.H G h R.sup.H G h R.sup.H G h R.sup.H G 1 R.sup.H1 G.sup.1 261 R.sup.H1 G.sup.2 521 R.sup.H1 G.sup.3 781 R.sup.H1 G.sup.4 2 R.sup.H2 G.sup.1 262 R.sup.H2 G.sup.2 522 R.sup.H2 G.sup.3 782 R.sup.H2 G.sup.4 3 R.sup.H3 G.sup.1 263 R.sup.H3 G.sup.2 523 R.sup.H3 G.sup.3 783 R.sup.H3 G.sup.4 4 R.sup.H4 G.sup.1 264 R.sup.H4 G.sup.2 524 R.sup.H4 G.sup.3 784 R.sup.H4 G.sup.4 5 R.sup.H5 G.sup.1 265 R.sup.H5 G.sup.2 525 R.sup.H5 G.sup.3 785 R.sup.H5 G.sup.4 6 R.sup.H6 G.sup.1 266 R.sup.H6 G.sup.2 526 R.sup.H6 G.sup.3 786 R.sup.H6 G.sup.4 7 R.sup.H7 G.sup.1 267 R.sup.H7 G.sup.2 527 R.sup.H7 G.sup.3 787 R.sup.H7 G.sup.4 8 R.sup.H8 G.sup.1 268 R.sup.H8 G.sup.2 528 R.sup.H8 G.sup.3 788 R.sup.H8 G.sup.4 9 R.sup.H9 G.sup.1 269 R.sup.H9 G.sup.2 529 R.sup.H9 G.sup.3 789 R.sup.H9 G.sup.4 10 R.sup.H10 G.sup.1 270 R.sup.H10 G.sup.2 530 R.sup.H10 G.sup.3 790 R.sup.H10 G.sup.4 11 R.sup.H11 G.sup.1 271 R.sup.H11 G.sup.2 531 R.sup.H11 G.sup.3 791 R.sup.H11 G.sup.4 12 R.sup.H12 G.sup.1 272 R.sup.H12 G.sup.2 532 R.sup.H12 G.sup.3 792 R.sup.H12 G.sup.4 13 R.sup.H11 G.sup.1 273 R.sup.H13 G.sup.2 533 R.sup.H13 G.sup.3 793 R.sup.H13 G.sup.4 14 R.sup.H14 G.sup.1 274 R.sup.H14 G.sup.2 534 R.sup.H14 G.sup.3 794 R.sup.H14 G.sup.4 15 R.sup.H15 G.sup.1 275 R.sup.H15 G.sup.2 535 R.sup.H15 G.sup.3 795 R.sup.H15 G.sup.4 16 R.sup.H16 G.sup.1 276 R.sup.H16 G.sup.2 536 R.sup.H16 G.sup.3 796 R.sup.H16 G.sup.4 17 R.sup.H17 G.sup.1 277 R.sup.H17 G.sup.2 537 R.sup.H17 G.sup.3 797 R.sup.H17 G.sup.4 18 R.sup.H18 G.sup.1 278 R.sup.H18 G.sup.2 538 R.sup.H18 G.sup.3 798 R.sup.H18 G.sup.4 19 R.sup.H19 G.sup.1 279 R.sup.H19 G.sup.2 539 R.sup.H19 G.sup.3 799 R.sup.H19 G.sup.4 20 R.sup.H20 G.sup.1 280 R.sup.H20 G.sup.2 540 R.sup.H20 G.sup.3 800 R.sup.H20 G.sup.4 21 R.sup.H21 G.sup.1 281 R.sup.H21 G.sup.2 541 R.sup.H21 G.sup.3 801 R.sup.H21 G.sup.4 22 R.sup.H22 G.sup.1 282 R.sup.H22 G.sup.2 542 R.sup.H22 G.sup.3 802 R.sup.H22 G.sup.4 23 R.sup.H23 G.sup.1 283 R.sup.H23 G.sup.2 543 R.sup.H23 G.sup.3 803 R.sup.H23 G.sup.4 24 R.sup.H24 G.sup.1 284 R.sup.H24 G.sup.2 544 R.sup.H24 G.sup.3 804 R.sup.H24 G.sup.4 25 R.sup.H25 G.sup.1 285 R.sup.H25 G.sup.2 545 R.sup.H25 G.sup.3 805 R.sup.H25 G.sup.4 26 R.sup.H26 G.sup.1 286 R.sup.H26 G.sup.2 546 R.sup.H26 G.sup.3 806 R.sup.H26 G.sup.4 27 R.sup.H27 G.sup.1 287 R.sup.H27 G.sup.2 547 R.sup.H27 G.sup.3 807 R.sup.H27 G.sup.4 28 R.sup.H28 G.sup.1 288 R.sup.H28 G.sup.2 548 R.sup.H28 G.sup.3 808 R.sup.H28 G.sup.4 29 R.sup.H29 G.sup.1 289 R.sup.H29 G.sup.2 549 R.sup.H29 G.sup.3 809 R.sup.H29 G.sup.4 30 R.sup.H30 G.sup.1 290 R.sup.H30 G.sup.2 550 R.sup.H30 G.sup.3 810 R.sup.H30 G.sup.4 31 R.sup.H31 G.sup.1 291 R.sup.H31 G.sup.2 551 R.sup.H31 G.sup.3 811 R.sup.H31 G.sup.4 32 R.sup.H32 G.sup.1 292 R.sup.H32 G.sup.2 552 R.sup.H32 G.sup.3 812 R.sup.H32 G.sup.4 33 R.sup.H33 G.sup.1 293 R.sup.H33 G.sup.2 553 R.sup.H33 G.sup.3 813 R.sup.H33 G.sup.4 34 R.sup.H34 G.sup.1 294 R.sup.H34 G.sup.2 554 R.sup.H34 G.sup.3 814 R.sup.H34 G.sup.4 35 R.sup.H35 G.sup.1 295 R.sup.H35 G.sup.2 555 R.sup.H35 G.sup.3 815 R.sup.H35 G.sup.4 36 R.sup.H36 G.sup.1 296 R.sup.H36 G.sup.2 556 R.sup.H36 G.sup.3 816 R.sup.H36 G.sup.4 37 R.sup.H37 G.sup.1 297 R.sup.H37 G.sup.2 557 R.sup.H37 G.sup.3 817 R.sup.H37 G.sup.4 38 R.sup.H38 G.sup.1 298 R.sup.H38 G.sup.2 558 R.sup.H38 G.sup.3 818 R.sup.H38 G.sup.4 39 R.sup.H39 G.sup.1 299 R.sup.H39 G.sup.2 559 R.sup.H39 G.sup.3 819 R.sup.H39 G.sup.4 40 R.sup.H40 G.sup.1 300 R.sup.H40 G.sup.2 560 R.sup.H40 G.sup.3 820 R.sup.H40 G.sup.4 41 R.sup.H41 G.sup.1 301 R.sup.H41 G.sup.2 561 R.sup.H41 G.sup.3 821 R.sup.H41 G.sup.4 42 R.sup.H42 G.sup.1 302 R.sup.H42 G.sup.2 562 R.sup.H42 G.sup.3 822 R.sup.H42 G.sup.4 43 R.sup.H43 G.sup.1 303 R.sup.H43 G.sup.2 563 R.sup.H43 G.sup.3 823 R.sup.H43 G.sup.4 44 R.sup.H44 G.sup.1 304 R.sup.H44 G.sup.2 564 R.sup.H44 G.sup.3 824 R.sup.H44 G.sup.4 45 R.sup.H45 G.sup.1 305 R.sup.H45 G.sup.2 565 R.sup.H45 G.sup.3 825 R.sup.H45 G.sup.4 46 R.sup.H46 G.sup.1 306 R.sup.H46 G.sup.2 566 R.sup.H46 G.sup.3 826 R.sup.H46 G.sup.4 47 R.sup.H47 G.sup.1 307 R.sup.H47 G.sup.2 567 R.sup.H47 G.sup.3 827 R.sup.H47 G.sup.4 48 R.sup.H48 G.sup.1 308 R.sup.H48 G.sup.2 568 R.sup.H48 G.sup.3 828 R.sup.H48 G.sup.4 49 R.sup.H49 G.sup.1 309 R.sup.H49 G.sup.2 569 R.sup.H49 G.sup.3 829 R.sup.H49 G.sup.4 50 R.sup.H50 G.sup.1 310 R.sup.H50 G.sup.2 570 R.sup.H50 G.sup.3 830 R.sup.H50 G.sup.4 51 R.sup.H51 G.sup.1 311 R.sup.H51 G.sup.2 571 R.sup.H51 G.sup.3 831 R.sup.H51 G.sup.4 52 R.sup.H52 G.sup.1 312 R.sup.H52 G.sup.2 572 R.sup.H52 G.sup.3 832 R.sup.H52 G.sup.4 53 R.sup.H55 G.sup.1 313 R.sup.H53 G.sup.2 573 R.sup.H53 G.sup.3 833 R.sup.H55 G.sup.4 54 R.sup.H54 G.sup.1 314 R.sup.H54 G.sup.2 574 R.sup.H54 G.sup.3 834 R.sup.H54 G.sup.4 55 R.sup.H55 G.sup.1 315 R.sup.H55 G.sup.2 575 R.sup.H55 G.sup.3 835 R.sup.H55 G.sup.4 56 R.sup.H56 G.sup.1 316 R.sup.H56 G.sup.2 576 R.sup.H56 G.sup.3 836 R.sup.H56 G.sup.4 57 R.sup.H57 G.sup.1 317 R.sup.H57 G.sup.2 577 R.sup.H57 G.sup.3 837 R.sup.H57 G.sup.4 58 R.sup.H58 G.sup.1 318 R.sup.H58 G.sup.2 578 R.sup.H58 G.sup.3 838 R.sup.H58 G.sup.4 59 R.sup.H59 G.sup.1 319 R.sup.H59 G.sup.2 579 R.sup.H59 G.sup.3 839 R.sup.H59 G.sup.4 60 R.sup.H60 G.sup.1 320 R.sup.H60 G.sup.2 580 R.sup.H60 G.sup.3 840 R.sup.H60 G.sup.4 61 R.sup.H61 G.sup.1 321 R.sup.H61 G.sup.2 581 R.sup.H61 G.sup.3 841 R.sup.H61 G.sup.4 62 R.sup.H62 G.sup.1 322 R.sup.H62 G.sup.2 582 R.sup.H62 G.sup.3 842 R.sup.H62 G.sup.4 63 R.sup.H63 G.sup.1 323 R.sup.H63 G.sup.2 583 R.sup.H63 G.sup.3 843 R.sup.H63 G.sup.4 64 R.sup.H64 G.sup.1 324 R.sup.H64 G.sup.2 584 R.sup.H64 G.sup.3 844 R.sup.H64 G.sup.4 65 R.sup.H65 G.sup.1 325 R.sup.H65 G.sup.2 585 R.sup.H65 G.sup.3 845 R.sup.H65 G.sup.4 66 R.sup.H1 G.sup.5 326 R.sup.H1 G.sup.6 586 R.sup.H1 G.sup.7 846 R.sup.H1 G.sup.8 67 R.sup.H2 G.sup.5 327 R.sup.H2 G.sup.6 587 R.sup.H2 G.sup.7 847 R.sup.H2 G.sup.8 68 R.sup.H3 G.sup.5 328 R.sup.H3 G.sup.6 588 R.sup.H3 G.sup.7 848 R.sup.H3 G.sup.8 69 R.sup.H4 G.sup.5 329 R.sup.H4 G.sup.6 589 R.sup.H4 G.sup.7 849 R.sup.H4 G.sup.8 70 R.sup.H5 G.sup.5 330 R.sup.H5 G.sup.6 590 R.sup.H5 G.sup.7 850 R.sup.H5 G.sup.8 71 R.sup.H6 G.sup.5 331 R.sup.H6 G.sup.6 591 R.sup.H6 G.sup.7 851 R.sup.H6 G.sup.8 72 R.sup.H7 G.sup.5 332 R.sup.H7 G.sup.6 592 R.sup.H7 G.sup.7 852 R.sup.H7 G.sup.8 73 R.sup.H8 G.sup.5 333 R.sup.H8 G.sup.6 593 R.sup.H8 G.sup.7 853 R.sup.H8 G.sup.8 74 R.sup.H9 G.sup.5 334 R.sup.H9 G.sup.6 594 R.sup.H9 G.sup.7 854 R.sup.H9 G.sup.8 75 R.sup.H10 G.sup.5 335 R.sup.H10 G.sup.6 595 R.sup.H10 G.sup.7 855 R.sup.H10 G.sup.8 76 R.sup.H11 G.sup.5 336 R.sup.H11 G.sup.6 596 R.sup.H11 G.sup.7 856 R.sup.H11 G.sup.8 77 R.sup.H12 G.sup.5 337 R.sup.H12 G.sup.6 597 R.sup.H12 G.sup.7 857 R.sup.H12 G.sup.8 78 R.sup.H13 G.sup.5 338 R.sup.H13 G.sup.6 598 R.sup.H13 G.sup.7 858 R.sup.H13 G.sup.8 79 R.sup.H14 G.sup.5 339 R.sup.H14 G.sup.6 599 R.sup.H14 G.sup.7 859 R.sup.H14 G.sup.8 80 R.sup.H15 G.sup.5 340 R.sup.H15 G.sup.6 600 R.sup.H15 G.sup.7 860 R.sup.H15 G.sup.8 81 R.sup.H16 G.sup.5 341 R.sup.H16 G.sup.6 601 R.sup.H16 G.sup.7 861 R.sup.H16 G.sup.8 82 R.sup.H17 G.sup.5 342 R.sup.H17 G.sup.6 602 R.sup.H17 G.sup.7 862 R.sup.H17 G.sup.8 83 R.sup.H18 G.sup.5 343 R.sup.H18 G.sup.6 603 R.sup.H18 G.sup.7 863 R.sup.H18 G.sup.8 84 R.sup.H19 G.sup.5 344 R.sup.H19 G.sup.6 604 R.sup.H19 G.sup.7 864 R.sup.H19 G.sup.8 85 R.sup.H20 G.sup.5 345 R.sup.H20 G.sup.6 605 R.sup.H20 G.sup.7 865 R.sup.H20 G.sup.8 86 R.sup.H21 G.sup.5 346 R.sup.H21 G.sup.6 606 R.sup.H21 G.sup.7 866 R.sup.H21 G.sup.8 87 R.sup.H22 G.sup.5 347 R.sup.H22 G.sup.6 607 R.sup.H22 G.sup.7 867 R.sup.H22 G.sup.8 88 R.sup.H23 G.sup.5 348 R.sup.H23 G.sup.6 608 R.sup.H23 G.sup.7 868 R.sup.H23 G.sup.8 89 R.sup.H24 G.sup.5 349 R.sup.H24 G.sup.6 609 R.sup.H24 G.sup.7 869 R.sup.H24 G.sup.8 90 R.sup.H25 G.sup.5 350 R.sup.H25 G.sup.6 610 R.sup.H25 G.sup.7 870 R.sup.H25 G.sup.8 91 R.sup.H26 G.sup.5 351 R.sup.H26 G.sup.6 611 R.sup.H26 G.sup.7 871 R.sup.H26 G.sup.8 92 R.sup.H27 G.sup.5 352 R.sup.H27 G.sup.6 612 R.sup.H27 G.sup.7 872 R.sup.H27 G.sup.8 93 R.sup.H28 G.sup.5 353 R.sup.H28 G.sup.6 613 R.sup.H28 G.sup.7 873 R.sup.H28 G.sup.8 94 R.sup.H29 G.sup.5 354 R.sup.H29 G.sup.6 614 R.sup.H29 G.sup.7 874 R.sup.H29 G.sup.8 95 R.sup.H30 G.sup.5 355 R.sup.H30 G.sup.6 615 R.sup.H30 G.sup.7 875 R.sup.H30 G.sup.8 96 R.sup.H31 G.sup.5 356 R.sup.H31 G.sup.6 616 R.sup.H31 G.sup.7 876 R.sup.H31 G.sup.8 97 R.sup.H32 G.sup.5 357 R.sup.H32 G.sup.6 617 R.sup.H32 G.sup.7 877 R.sup.H32 G.sup.8 98 R.sup.H33 G.sup.5 358 R.sup.H33 G.sup.6 618 R.sup.H33 G.sup.7 878 R.sup.H33 G.sup.8 99 R.sup.H34 G.sup.5 359 R.sup.H34 G.sup.6 619 R.sup.H34 G.sup.7 879 R.sup.H34 G.sup.8 100 R.sup.H35 G.sup.5 360 R.sup.H35 G.sup.6 620 R.sup.H35 G.sup.7 880 R.sup.H35 G.sup.8 101 R.sup.H36 G.sup.5 361 R.sup.H36 G.sup.6 621 R.sup.H36 G.sup.7 881 R.sup.H36 G.sup.8 102 R.sup.H37 G.sup.5 362 R.sup.H37 G.sup.6 622 R.sup.H37 G.sup.7 882 R.sup.H37 G.sup.8 103 R.sup.H38 G.sup.5 363 R.sup.H38 G.sup.6 623 R.sup.H38 G.sup.7 883 R.sup.H38 G.sup.8 104 R.sup.H39 G.sup.5 364 R.sup.H39 G.sup.6 624 R.sup.H39 G.sup.7 884 R.sup.H39 G.sup.8 105 R.sup.H40 G.sup.5 365 R.sup.H40 G.sup.6 625 R.sup.H40 G.sup.7 885 R.sup.H40 G.sup.8 106 R.sup.H41 G.sup.5 366 R.sup.H41 G.sup.6 626 R.sup.H41 G.sup.7 886 R.sup.H41 G.sup.8 107 R.sup.H42 G.sup.5 367 R.sup.H42 G.sup.6 627 R.sup.H42 G.sup.7 887 R.sup.H42 G.sup.8 108 R.sup.H43 G.sup.5 368 R.sup.H43 G.sup.6 628 R.sup.H43 G.sup.7 888 R.sup.H43 G.sup.8 109 R.sup.H44 G.sup.5 369 R.sup.H44 G.sup.6 629 R.sup.H44 G.sup.7 889 R.sup.H44 G.sup.8 110 R.sup.H45 G.sup.5 370 R.sup.H45 G.sup.6 630 R.sup.H45 G.sup.7 890 R.sup.H45 G.sup.8 111 R.sup.H46 G.sup.5 371 R.sup.H46 G.sup.6 631 R.sup.H46 G.sup.7 891 R.sup.H46 G.sup.8 112 R.sup.H47 G.sup.5 372 R.sup.H47 G.sup.6 632 R.sup.H47 G.sup.7 892 R.sup.H47 G.sup.8 113 R.sup.H48 G.sup.5 373 R.sup.H48 G.sup.6 633 R.sup.H48 G.sup.7 893 R.sup.H48 G.sup.8 114 R.sup.H49 G.sup.5 374 R.sup.H49 G.sup.6 634 R.sup.H49 G.sup.7 894 R.sup.H49 G.sup.8 115 R.sup.H50 G.sup.5 375 R.sup.H50 G.sup.6 635 R.sup.H50 G.sup.7 895 R.sup.H50 G.sup.8 116 R.sup.H51 G.sup.5 376 R.sup.H51 G.sup.6 636 R.sup.H51 G.sup.7 896 R.sup.H51 G.sup.8 117 R.sup.H52 G.sup.5 377 R.sup.H52 G.sup.6 637 R.sup.H52 G.sup.7 897 R.sup.H52 G.sup.8 118 R.sup.H53 G.sup.5 378 R.sup.H53 G.sup.6 638 R.sup.H53 G.sup.7 898 R.sup.H53 G.sup.8 119 R.sup.H54 G.sup.5 379 R.sup.H54 G.sup.6 639 R.sup.H54 G.sup.7 899 R.sup.H54 G.sup.8 120 R.sup.H55 G.sup.5 380 R.sup.H55 G.sup.6 640 R.sup.H55 G.sup.7 900 R.sup.H55 G.sup.8 121 R.sup.H56 G.sup.5 381 R.sup.H56 G.sup.6 641 R.sup.H56 G.sup.7 901 R.sup.H56 G.sup.8 122 R.sup.H57 G.sup.5 382 R.sup.H57 G.sup.6 642 R.sup.H57 G.sup.7 902 R.sup.H57 G.sup.8 123 R.sup.H58 G.sup.5 383 R.sup.H58 G.sup.6 643 R.sup.H58 G.sup.7 903 R.sup.H58 G.sup.8 124 R.sup.H59 G.sup.5 384 R.sup.H59 G.sup.6 644 R.sup.H59 G.sup.7 904 R.sup.H59 G.sup.8 125 R.sup.H60 G.sup.5 385 R.sup.H60 G.sup.6 645 R.sup.H60 G.sup.7 905 R.sup.H60 G.sup.8 126 R.sup.H61 G.sup.5 386 R.sup.H61 G.sup.6 646 R.sup.H61 G.sup.7 906 R.sup.H61 G.sup.8 127 R.sup.H62 G.sup.5 387 R.sup.H62 G.sup.6 647 R.sup.H62 G.sup.7 907 R.sup.H62 G.sup.8 128 R.sup.H63 G.sup.5 388 R.sup.H63 G.sup.6 648 R.sup.H63 G.sup.7 908 R.sup.H63 G.sup.8 129 R.sup.H64 G.sup.5 389 R.sup.H64 G.sup.6 649 R.sup.H64 G.sup.7 909 R.sup.H64 G.sup.8 130 R.sup.H65 G.sup.5 390 R.sup.H65 G.sup.6 650 R.sup.H65 G.sup.7 910 R.sup.H65 G.sup.8 131 R.sup.H1 G.sup.9 391 R.sup.H1 G.sup.10 651 R.sup.H1 G.sup.11 911 R.sup.H1 G.sup.12 132 R.sup.H2 G.sup.9 392 R.sup.H2 G.sup.10 652 R.sup.H2 G.sup.11 912 R.sup.H2 G.sup.12 133 R.sup.H3 G.sup.9 393 R.sup.H3 G.sup.10 653 R.sup.H3 G.sup.11 913 R.sup.H3 G.sup.12 134 R.sup.H4 G.sup.9 394 R.sup.H4 G.sup.10 654 R.sup.H4 G.sup.11 914 R.sup.H4 G.sup.12 135 R.sup.H5 G.sup.9 395 R.sup.H5 G.sup.10 655 R.sup.H5 G.sup.11 915 R.sup.H5 G.sup.12 136 R.sup.H6 G.sup.9 396 R.sup.H6 G.sup.10 656 R.sup.H6 G.sup.11 916 R.sup.H6 G.sup.12 137 R.sup.H7 G.sup.9 397 R.sup.H7 G.sup.10 657 R.sup.H7 G.sup.11 917 R.sup.H7 G.sup.12 138 R.sup.H8 G.sup.9 398 R.sup.H8 G.sup.10 658 R.sup.H8 G.sup.11 918 R.sup.H8 G.sup.12 139 R.sup.H9 G.sup.9 399 R.sup.H9 G.sup.10 659 R.sup.H9 G.sup.11 919 R.sup.H9 G.sup.12 140 R.sup.H10 G.sup.9 400 R.sup.H10 G.sup.10 660 R.sup.H10 G.sup.11 920 R.sup.H10 G.sup.12 141 R.sup.H11 G.sup.9 401 R.sup.H11 G.sup.10 661 R.sup.H11 G.sup.11 921 R.sup.H11 G.sup.12 142 R.sup.H12 G.sup.9 402 R.sup.H12 G.sup.10 662 R.sup.H12 G.sup.11 922 R.sup.H12 G.sup.12 143 R.sup.H13 G.sup.9 403 R.sup.H13 G.sup.10 663 R.sup.H13 G.sup.11 923 R.sup.H13 G.sup.12 144 R.sup.H14 G.sup.9 404 R.sup.H14 G.sup.10 664 R.sup.H14 G.sup.11 924 R.sup.H14 G.sup.12 145 R.sup.H15 G.sup.9 405 R.sup.H15 G.sup.10 665 R.sup.H15 G.sup.11 925 R.sup.H15 G.sup.12 146 R.sup.H16 G.sup.9 406 R.sup.H16 G.sup.10 666 R.sup.H16 G.sup.11 926 R.sup.H16 G.sup.12 147 R.sup.H17 G.sup.9 407 R.sup.H17 G.sup.10 667 R.sup.H17 G.sup.11 927 R.sup.H17 G.sup.12 148 R.sup.H18 G.sup.9 408 R.sup.H18 G.sup.10 668 R.sup.H18 G.sup.11 928 R.sup.H18 G.sup.12 149 R.sup.H19 G.sup.9 409 R.sup.H19 G.sup.10 669 R.sup.H19 G.sup.11 929 R.sup.H19 G.sup.12 150 R.sup.H20 G.sup.9 410 R.sup.H20 G.sup.10 670 R.sup.H20 G.sup.11 930 R.sup.H20 G.sup.12 151 R.sup.H21 G.sup.9 411 R.sup.H21 G.sup.10 671 R.sup.H21 G.sup.11 931 R.sup.H21 G.sup.12 152 R.sup.H22 G.sup.9 412 R.sup.H22 G.sup.10 672 R.sup.H22 G.sup.11 932 R.sup.H22 G.sup.12 153 R.sup.H23 G.sup.9 413 R.sup.H23 G.sup.10 673 R.sup.H23 G.sup.11 933 R.sup.H23 G.sup.12 154 R.sup.H24 G.sup.9 414 R.sup.H24 G.sup.10 674 R.sup.H24 G.sup.11 934 R.sup.H24 G.sup.12 155 R.sup.H25 G.sup.9 415 R.sup.H25 G.sup.10 675 R.sup.H25 G.sup.11 935 R.sup.H25 G.sup.12 156 R.sup.H26 G.sup.9 416 R.sup.H26 G.sup.10 676 R.sup.H26 G.sup.11 936 R.sup.H26 G.sup.12 157 R.sup.H27 G.sup.9 417 R.sup.H27 G.sup.10 677 R.sup.H27 G.sup.11 937 R.sup.H27 G.sup.12 158 R.sup.H28 G.sup.9 418 R.sup.H28 G.sup.10 678 R.sup.H28 G.sup.11 938 R.sup.H28 G.sup.12 159 R.sup.H29 G.sup.9 419 R.sup.H29 G.sup.10 679 R.sup.H29 G.sup.11 939 R.sup.H29 G.sup.12 160 R.sup.H30 G.sup.9 420 R.sup.H30 G.sup.10 680 R.sup.H30 G.sup.11 940 R.sup.H30 G.sup.12 161 R.sup.H31 G.sup.9 421 R.sup.H31 G.sup.10 681 R.sup.H31 G.sup.11 941 R.sup.H31 G.sup.12 162 R.sup.H32 G.sup.9 422 R.sup.H32 G.sup.10 682 R.sup.H32 G.sup.11 942 R.sup.H32 G.sup.12 163 R.sup.H33 G.sup.9 423 R.sup.H33 G.sup.10 683 R.sup.H33 G.sup.11 943 R.sup.H33 G.sup.12 164 R.sup.H34 G.sup.9 424 R.sup.H34 G.sup.10 684 R.sup.H34 G.sup.11 944 R.sup.H34 G.sup.12 165 R.sup.H35 G.sup.9 425 R.sup.H35 G.sup.10 685 R.sup.H35 G.sup.11 945 R.sup.H35 G.sup.12 166 R.sup.H36 G.sup.9 426 R.sup.H36 G.sup.10 686 R.sup.H36 G.sup.11 946 R.sup.H36 G.sup.12 167 R.sup.H37 G.sup.9 427 R.sup.H37 G.sup.10 687 R.sup.H37 G.sup.11 947 R.sup.H37 G.sup.12 168 R.sup.H38 G.sup.9 428 R.sup.H38 G.sup.10 688 R.sup.H38 G.sup.11 948 R.sup.H38 G.sup.12 169 R.sup.H39 G.sup.9 429 R.sup.H39 G.sup.10 689 R.sup.H39 G.sup.11 949 R.sup.H39 G.sup.12 170 R.sup.H40 G.sup.9 430 R.sup.H40 G.sup.10 690 R.sup.H40 G.sup.11 950 R.sup.H40 G.sup.12 171 R.sup.H41 G.sup.9 431 R.sup.H41 G.sup.10 691 R.sup.H41 G.sup.11 951 R.sup.H41 G.sup.12 172 R.sup.H42 G.sup.9 432 R.sup.H42 G.sup.10 692 R.sup.H42 G.sup.11 952 R.sup.H42 G.sup.12 173 R.sup.H43 G.sup.9 433 R.sup.H43 G.sup.10 693 R.sup.H43 G.sup.11 953 R.sup.H43 G.sup.12 174 R.sup.H44 G.sup.9 434 R.sup.H44 G.sup.10 694 R.sup.H44 G.sup.11 954 R.sup.H44 G.sup.12 175 R.sup.H45 G.sup.9 435 R.sup.H45 G.sup.10 695 R.sup.H45 G.sup.11 955 R.sup.H45 G.sup.12 176 R.sup.H46 G.sup.9 436 R.sup.H46 G.sup.10 696 R.sup.H46 G.sup.11 956 R.sup.H46 G.sup.12 177 R.sup.H47 G.sup.9 437 R.sup.H47 G.sup.10 697 R.sup.H47 G.sup.11 957 R.sup.H47 G.sup.12 178 R.sup.H48 G.sup.9 438 R.sup.H48 G.sup.10 698 R.sup.H48 G.sup.11 958 R.sup.H48 G.sup.12 179 R.sup.H49 G.sup.9 439 R.sup.H49 G.sup.10 699 R.sup.H49 G.sup.11 959 R.sup.H49 G.sup.12 180 R.sup.H50 G.sup.9 440 R.sup.H50 G.sup.10 700 R.sup.H50 G.sup.11 960 R.sup.H50 G.sup.12 181 R.sup.H51 G.sup.9 441 R.sup.H51 G.sup.10 701 R.sup.H51 G.sup.11 961 R.sup.H51 G.sup.12 182 R.sup.H52 G.sup.9 442 R.sup.H52 G.sup.10 702 R.sup.H52 G.sup.11 962 R.sup.H52 G.sup.12 183 R.sup.H53 G.sup.9 443 R.sup.H53 G.sup.10 703 R.sup.H53 G.sup.11 963 R.sup.H53 G.sup.12 184 R.sup.H54 G.sup.9 444 R.sup.H54 G.sup.10 704 R.sup.H54 G.sup.11 964 R.sup.H54 G.sup.12 185 R.sup.H55 G.sup.9 445 R.sup.H55 G.sup.10 705 R.sup.H55 G.sup.11 965 R.sup.H55 G.sup.12 186 R.sup.H56 G.sup.9 446 R.sup.H56 G.sup.10 706 R.sup.H56 G.sup.11 966 R.sup.H56 G.sup.12 187 R.sup.H57 G.sup.9 447 R.sup.H57 G.sup.10 707 R.sup.H57 G.sup.11 967 R.sup.H57 G.sup.12 188 R.sup.H58 G.sup.9 448 R.sup.H58 G.sup.10 708 R.sup.H58 G.sup.11 968 R.sup.H58 G.sup.12 189 R.sup.H59 G.sup.9 449 R.sup.H59 G.sup.10 709 R.sup.H59 G.sup.11 969 R.sup.H59 G.sup.12 190 R.sup.H60 G.sup.9 450 R.sup.H60 G.sup.10 710 R.sup.H60 G.sup.11 970 R.sup.H60 G.sup.12 191 R.sup.H61 G.sup.9 451 R.sup.H61 G.sup.10 711 R.sup.H61 G.sup.11 971 R.sup.H61 G.sup.12 192 R.sup.H62 G.sup.9 452 R.sup.H62 G.sup.10 712 R.sup.H62 G.sup.11 972 R.sup.H62 G.sup.12 193 R.sup.H63 G.sup.9 453 R.sup.H63 G.sup.10 713 R.sup.H63 G.sup.11 973 R.sup.H63 G.sup.12 194 R.sup.H64 G.sup.9 454 R.sup.H64 G.sup.10 714 R.sup.H64 G.sup.11 974 R.sup.H64 G.sup.12 195 R.sup.H65 G.sup.9 455 R.sup.H65 G.sup.10 715 R.sup.H65 G.sup.11 975 R.sup.H65 G.sup.12 196 R.sup.H1 G.sup.13 456 R.sup.H1 G.sup.14 716 R.sup.H1 G.sup.15 976 R.sup.H1 G.sup.16 197 R.sup.H2 G.sup.13 457 R.sup.H2 G.sup.14 717 R.sup.H2 G.sup.15 977 R.sup.H2 G.sup.16 198 R.sup.H3 G.sup.13 458 R.sup.H3 G.sup.14 718 R.sup.H3 G.sup.15 978 R.sup.H3 G.sup.16 199 R.sup.H4 G.sup.13 459 R.sup.H4 G.sup.14 719 R.sup.H4 G.sup.15 979 R.sup.H4 G.sup.16 200 R.sup.H5 G.sup.13 460 R.sup.H5 G.sup.14 720 R.sup.H5 G.sup.15 980 R.sup.H5 G.sup.16 201 R.sup.H6 G.sup.13 461 R.sup.H6 G.sup.14 721 R.sup.H6 G.sup.15 981 R.sup.H6 G.sup.16 202 R.sup.H7 G.sup.13 462 R.sup.H7 G.sup.14 722 R.sup.H7 G.sup.15 982 R.sup.H7 G.sup.16 203 R.sup.H8 G.sup.13 463 R.sup.H8 G.sup.14 723 R.sup.H8 G.sup.15 983 R.sup.H8 G.sup.16 204 R.sup.H9 G.sup.13 464 R.sup.H9 G.sup.14 724 R.sup.H9 G.sup.15 984 R.sup.H9 G.sup.16 205 R.sup.H10 G.sup.13 465 R.sup.H10 G.sup.14 725 R.sup.H10 G.sup.15 985 R.sup.H10 G.sup.16 206 R.sup.H11 G.sup.13 466 R.sup.H11 G.sup.14 726 R.sup.H11 G.sup.15 986 R.sup.H11 G.sup.16 207 R.sup.H12 G.sup.13 467 R.sup.H12 G.sup.14 727 R.sup.H12 G.sup.15 987 R.sup.H12 G.sup.16 208 R.sup.H13 G.sup.13 468 R.sup.H13 G.sup.14 728 R.sup.H13 G.sup.15 988 R.sup.H13 G.sup.16 209 R.sup.H14 G.sup.13 469 R.sup.H14 G.sup.14 729 R.sup.H14 G.sup.15 989 R.sup.H14 G.sup.16 210 R.sup.H15 G.sup.13 470 R.sup.H15 G.sup.14 730 R.sup.H15 G.sup.15 990 R.sup.H15 G.sup.16 211 R.sup.H16 G.sup.13 471 R.sup.H16 G.sup.14 731 R.sup.H16 G.sup.15 991 R.sup.H16 G.sup.16 212 R.sup.H17 G.sup.13 472 R.sup.H17 G.sup.14 732 R.sup.H17 G.sup.15 992 R.sup.H17 G.sup.16 213 R.sup.H18 G.sup.13 473 R.sup.H18 G.sup.14 733 R.sup.H18 G.sup.15 993 R.sup.H18 G.sup.16 214 R.sup.H19 G.sup.13 474 R.sup.H19 G.sup.14 734 R.sup.H19 G.sup.15 994 R.sup.H19 G.sup.16 215 R.sup.H20 G.sup.13 475 R.sup.H20 G.sup.14 735 R.sup.H20 G.sup.15 995 R.sup.H20 G.sup.16 216 R.sup.H21 G.sup.13 476 R.sup.H21 G.sup.14 736 R.sup.H21 G.sup.15 996 R.sup.H21 G.sup.16 217 R.sup.H22 G.sup.13 477 R.sup.H22 G.sup.14 737 R.sup.H22 G.sup.15 997 R.sup.H22 G.sup.16 218 R.sup.H23 G.sup.13 478 R.sup.H23 G.sup.14 738 R.sup.H23 G.sup.15 998 R.sup.H23 G.sup.16 219 R.sup.H24 G.sup.13 479 R.sup.H24 G.sup.14 739 R.sup.H24 G.sup.15 999 R.sup.H24 G.sup.16 220 R.sup.H25 G.sup.13 480 R.sup.H25 G.sup.14 740 R.sup.H25 G.sup.15 1000 R.sup.H25 G.sup.16 221 R.sup.H26 G.sup.13 481 R.sup.H26 G.sup.14 741 R.sup.H26 G.sup.15 1001 R.sup.H26 G.sup.16 222 R.sup.H27 G.sup.13 482 R.sup.H27 G.sup.14 742 R.sup.H27 G.sup.15 1002 R.sup.H27 G.sup.16 223 R.sup.H28 G.sup.13 483 R.sup.H28 G.sup.14 743 R.sup.H28 G.sup.15 1003 R.sup.H28 G.sup.16 224 R.sup.H29 G.sup.13 484 R.sup.H29 G.sup.14 744 R.sup.H29 G.sup.15 1004 R.sup.H29 G.sup.16 225 R.sup.H30 G.sup.13 485 R.sup.H30 G.sup.14 745 R.sup.H30 G.sup.15 1005 R.sup.H30 G.sup.16 226 R.sup.H31 G.sup.13 486 R.sup.H31 G.sup.14 746 R.sup.H31 G.sup.15 1006 R.sup.H31 G.sup.16 227 R.sup.H32 G.sup.13 487 R.sup.H32 G.sup.14 747 R.sup.H32 G.sup.15 1007 R.sup.H32 G.sup.16 228 R.sup.H33 G.sup.13 488 R.sup.H33 G.sup.14 748 R.sup.H33 G.sup.15 1008 R.sup.H33 G.sup.16 229 R.sup.H34 G.sup.13 489 R.sup.H34 G.sup.14 749 R.sup.H34 G.sup.15 1009 R.sup.H34 G.sup.16 230 R.sup.H35 G.sup.13 490 R.sup.H35 G.sup.14 750 R.sup.H35 G.sup.15 1010 R.sup.H35 G.sup.16 231 R.sup.H36 G.sup.13 491 R.sup.H36 G.sup.14 751 R.sup.H36 G.sup.15 1011 R.sup.H36 G.sup.16 232 R.sup.H37 G.sup.13 492 R.sup.H37 G.sup.14 752 R.sup.H37 G.sup.15 1012 R.sup.H37 G.sup.16 233 R.sup.H38 G.sup.13 493 R.sup.H38 G.sup.14 753 R.sup.H38 G.sup.15 1013 R.sup.H38 G.sup.16 234 R.sup.H39 G.sup.13 494 R.sup.H39 G.sup.14 754 R.sup.H39 G.sup.15 1014 R.sup.H39 G.sup.16 235 R.sup.H40 G.sup.13 495 R.sup.H40 G.sup.14 755 R.sup.H40 G.sup.15 1015 R.sup.H40 G.sup.16 236 R.sup.H41 G.sup.13 496 R.sup.H41 G.sup.14 756 R.sup.H41 G.sup.15 1016 R.sup.H41 G.sup.16 237 R.sup.H42 G.sup.13 497 R.sup.H42 G.sup.14 757 R.sup.H42 G.sup.15 1017 R.sup.H42 G.sup.16 238 R.sup.H43 G.sup.13 498 R.sup.H43 G.sup.14 758 R.sup.H43 G.sup.15 1018 R.sup.H43 G.sup.16 239 R.sup.H44 G.sup.13 499 R.sup.H44 G.sup.14 759 R.sup.H44 G.sup.15 1019 R.sup.H44 G.sup.16 240 R.sup.H45 G.sup.13 500 R.sup.H45 G.sup.14 760 R.sup.H45 G.sup.15 1020 R.sup.H45 G.sup.16 241 R.sup.H46 G.sup.13 501 R.sup.H46 G.sup.14 761 R.sup.H46 G.sup.15 1021 R.sup.H46 G.sup.16 242 R.sup.H47 G.sup.13 502 R.sup.H47 G.sup.14 762 R.sup.H47 G.sup.15 1022 R.sup.H47 G.sup.16 243 R.sup.H48 G.sup.13 503 R.sup.H48 G.sup.14 763 R.sup.H48 G.sup.15 1023 R.sup.H48 G.sup.16 244 R.sup.H49 G.sup.13 504 R.sup.H49 G.sup.14 764 R.sup.H49 G.sup.15 1024 R.sup.H49 G.sup.16 245 R.sup.H50 G.sup.13 505 R.sup.H50 G.sup.14 765 R.sup.H50 G.sup.15 1025 R.sup.H50 G.sup.16 246 R.sup.H51 G.sup.13 506 R.sup.H51 G.sup.14 766 R.sup.H51 G.sup.15 1026 R.sup.H51 G.sup.16 247 R.sup.H52 G.sup.13 507 R.sup.H52 G.sup.14 767 R.sup.H52 G.sup.15 1027 R.sup.H52 G.sup.16 248 R.sup.H53 G.sup.13 508 R.sup.H53 G.sup.14 768 R.sup.H53 G.sup.15 1028 R.sup.H53 G.sup.16 249 R.sup.H54 G.sup.13 509 R.sup.H54 G.sup.14 769 R.sup.H54 G.sup.15 1029 R.sup.H54 G.sup.16 250 R.sup.H55 G.sup.13 510 R.sup.H55 G.sup.14 770 R.sup.H55 G.sup.15 1030 R.sup.H55 G.sup.16 251 R.sup.H56 G.sup.13 511 R.sup.H56 G.sup.14 771 R.sup.H56 G.sup.15 1031 R.sup.H56 G.sup.16 252 R.sup.H57 G.sup.13 512 R.sup.H57 G.sup.14 772 R.sup.H57 G.sup.15 1032 R.sup.H57 G.sup.16 253 R.sup.H58 G.sup.13 513 R.sup.H58 G.sup.14 773 R.sup.H58 G.sup.15 1033 R.sup.H58 G.sup.16 254 R.sup.H59 G.sup.13 514 R.sup.H59 G.sup.14 774 R.sup.H59 G.sup.15 1034 R.sup.H59 G.sup.16 255 R.sup.H60 G.sup.13 515 R.sup.H60 G.sup.14 775 R.sup.H60 G.sup.15 1035 R.sup.H60 G.sup.16 256 R.sup.H61 G.sup.13 516 R.sup.H61 G.sup.14 776 R.sup.H61 G.sup.15 1036 R.sup.H61 G.sup.16 257 R.sup.H62 G.sup.13 517 R.sup.H62 G.sup.14 777 R.sup.H62 G.sup.15 1037 R.sup.H62 G.sup.16 258 R.sup.H63 G.sup.13 518 R.sup.H63 G.sup.14 778 R.sup.H63 G.sup.15 1038 R.sup.H63 G.sup.16 259 R.sup.H64 G.sup.13 519 R.sup.H64 G.sup.14 779 R.sup.H64 G.sup.15 1039 R.sup.H64 G.sup.16 260 R.sup.H65 G.sup.13 520 R.sup.H65 G.sup.14 780 R.sup.H65 G.sup.15 1040 R.sup.H65 G.sup.16 1041 R.sup.H1 G.sup.17 1042 R.sup.H33 G.sup.17 1043 R.sup.H1 G.sup.18 1044 R.sup.H33 G.sup.18 1045 R.sup.H2 G.sup.17 1046 R.sup.H34 G.sup.17 1047 R.sup.H2 G.sup.18 1048 R.sup.H34 G.sup.18 1049 R.sup.H3 G.sup.17 1050 R.sup.H35 G.sup.17 1051 R.sup.H3 G.sup.18 1052 R.sup.H35 G.sup.18 1053 R.sup.H4 G.sup.17 1054 R.sup.H36 G.sup.17 1055 R.sup.H4 G.sup.18 1056 R.sup.H36 G.sup.18 1057 R.sup.H5 G.sup.17 1058 R.sup.H37 G.sup.17 1059 R.sup.H5 G.sup.18 1060 R.sup.H37 G.sup.18 1061 R.sup.H6 G.sup.17 1062 R.sup.H38 G.sup.17 1063 R.sup.H6 G.sup.18 1064 R.sup.H38 G.sup.18 1065 R.sup.H7 G.sup.17 1066 R.sup.H39 G.sup.17 1067 R.sup.H7 G.sup.18 1068 R.sup.H39 G.sup.18 1069 R.sup.H8 G.sup.17 1070 R.sup.H40 G.sup.17 1071 R.sup.H8 G.sup.18 1072 R.sup.H40 G.sup.18 1073 R.sup.H9 G.sup.17 1074 R.sup.H41 G.sup.17 1075 R.sup.H9 G.sup.18 1076 R.sup.H41 G.sup.18 1077 R.sup.H10 G.sup.17 1078 R.sup.H42 G.sup.17 1079 R.sup.H10 G.sup.18 1080 R.sup.H42 G.sup.18 1081 R.sup.H11 G.sup.17 1082 R.sup.H43 G.sup.17 1083 R.sup.H11 G.sup.18 1084 R.sup.H43 G.sup.18 1085 R.sup.H12 G.sup.17 1086 R.sup.H44 G.sup.17 1087 R.sup.H12 G.sup.18 1088 R.sup.H44 G.sup.18 1089 R.sup.H13 G.sup.17 1090 R.sup.H45 G.sup.17 1091 R.sup.H13 G.sup.18 1092 R.sup.H45 G.sup.18 1093 R.sup.H14 G.sup.17 1094 R.sup.H46 G.sup.17 1095 R.sup.H14 G.sup.18 1096 R.sup.H46 G.sup.18 1097 R.sup.H15 G.sup.17 1098 R.sup.H47 G.sup.17 1099 R.sup.H15 G.sup.18 1100 R.sup.H47 G.sup.18 1101 R.sup.H16 G.sup.17 1102 R.sup.H48 G.sup.17 1103 R.sup.H16 G.sup.18 1104 R.sup.H48 G.sup.18 1105 R.sup.H17 G.sup.17 1106 R.sup.H49 G.sup.17 1107 R.sup.H17 G.sup.18 1108 R.sup.H49 G.sup.18 1109 R.sup.H18 G.sup.17 1110 R.sup.H50 G.sup.17 1111 R.sup.H18 G.sup.18 1112 R.sup.H50 G.sup.18 1113 R.sup.H19 G.sup.17 1114 R.sup.H51 G.sup.17 1115 R.sup.H19 G.sup.18 1116 R.sup.H51 G.sup.18 1117 R.sup.H20 G.sup.17 1118 R.sup.H52 G.sup.17 1119 R.sup.H20 G.sup.18 1120 R.sup.H52 G.sup.18 1121 R.sup.H21 G.sup.17 1122 R.sup.H53 G.sup.17 1123 R.sup.H21 G.sup.18 1124 R.sup.H53 G.sup.18 1125 R.sup.H22 G.sup.17 1126 R.sup.H54 G.sup.17 1127 R.sup.H22 G.sup.18 1128 R.sup.H54 G.sup.18 1129 R.sup.H23 G.sup.17 1130 R.sup.H55 G.sup.17 1131 R.sup.H23 G.sup.18 1132 R.sup.H55 G.sup.18 1133 R.sup.H24 G.sup.17 1134 R.sup.H56 G.sup.17 1135 R.sup.H24 G.sup.18 1136 R.sup.H56 G.sup.18 1137 R.sup.H25 G.sup.17 1138 R.sup.H57 G.sup.17 1139 R.sup.H25 G.sup.18 1140 R.sup.H57 G.sup.18 1141 R.sup.H26 G.sup.17 1142 R.sup.H58 G.sup.17 1143 R.sup.H26 G.sup.18 1144 R.sup.H58 G.sup.18 1145 R.sup.H27 G.sup.17 1146 R.sup.H59 G.sup.17 1147 R.sup.H27 G.sup.18 1148 R.sup.H59 G.sup.18 1149 R.sup.H28 G.sup.17 1150 R.sup.H60 G.sup.17 1151 R.sup.H28 G.sup.18 1152 R.sup.H60 G.sup.18 1153 R.sup.H29 G.sup.17 1154 R.sup.H61 G.sup.17 1155 R.sup.H29 G.sup.18 1156 R.sup.H61 G.sup.18 1157 R.sup.H30 G.sup.17 1158 R.sup.H62 G.sup.17 1159 R.sup.H30 G.sup.18 1160 R.sup.H62 G.sup.18 1161 R.sup.H31 G.sup.17 1162 R.sup.H63 G.sup.17 1163 R.sup.H31 G.sup.18 1164 R.sup.H63 G.sup.18 1165 R.sup.H32 G.sup.17 1166 R.sup.H64 G.sup.17 1167 R.sup.H32 G.sup.18 1168 R.sup.H64 G.sup.18 1169 R.sup.H65 G.sup.17 1170 R.sup.H65 G.sup.18 wherein R.sup.H1 to R.sup.H65 have the following structures ##STR00315## ##STR00316## ##STR00317## ##STR00318## ##STR00319## ##STR00320## wherein G.sup.1 to G.sup.18 have the following structures: ##STR00321## ##STR00322## ##STR00323##
12. The OLED of claim 4, wherein L.sup.3-L.sup.4 is selected from the group consisting of: L.sub.Cj-I having a structure based on formula ##STR00324## and L.sub.Cj-II having a structure based on formula ##STR00325## wherein j is an integer from 1 to 1416, wherein for each L.sub.Cj in L.sub.Cj-I and L.sub.Cj-II, R.sup.201 and R.sup.202 are each independently defined as follows: TABLE-US-00010 L.sub.Cj R.sup.201 R.sup.202 L.sub.Cj R.sup.201 R.sup.202 L.sub.Cj R.sup.201 R.sup.202 L.sub.Cj R.sup.201 R.sup.202 L.sub.C1 R.sup.D1 R.sup.D1 L.sub.C193 R.sup.D1 R.sup.D3 L.sub.C385 R.sup.D17 R.sup.D40 L.sub.C577 R.sup.D143 R.sup.D120 L.sub.C2 R.sup.D2 R.sup.D2 L.sub.C194 R.sup.D1 R.sup.D4 L.sub.C386 R.sup.D17 R.sup.D41 L.sub.C578 R.sup.D143 R.sup.D133 L.sub.C3 R.sup.D3 R.sup.D3 L.sub.C195 R.sup.D1 R.sup.D5 L.sub.C387 R.sup.D17 R.sup.D42 L.sub.C579 R.sup.D143 R.sup.D134 L.sub.C4 R.sup.D4 R.sup.D4 L.sub.C196 R.sup.D1 R.sup.D9 L.sub.C388 R.sup.D17 R.sup.D43 L.sub.C580 R.sup.D143 R.sup.D135 L.sub.C5 R.sup.D5 R.sup.D5 L.sub.C197 R.sup.D1 R.sup.D10 L.sub.C389 R.sup.D17 R.sup.D48 L.sub.C581 R.sup.D143 R.sup.D136 L.sub.C6 R.sup.D6 R.sup.D6 L.sub.C198 R.sup.D1 R.sup.D17 L.sub.C390 R.sup.D17 R.sup.D49 L.sub.C582 R.sup.D143 R.sup.D144 L.sub.C7 R.sup.D7 R.sup.D7 L.sub.C199 R.sup.D1 R.sup.D18 L.sub.C391 R.sup.D17 R.sup.D50 L.sub.C583 R.sup.D143 R.sup.D145 L.sub.C8 R.sup.D8 R.sup.D8 L.sub.C200 R.sup.D1 R.sup.D20 L.sub.C392 R.sup.D17 R.sup.D54 L.sub.C584 R.sup.D143 R.sup.D146 L.sub.C9 R.sup.D9 R.sup.D9 L.sub.C201 R.sup.D1 R.sup.D22 L.sub.C393 R.sup.D17 R.sup.D55 L.sub.C585 R.sup.D143 R.sup.D147 L.sub.C10 R.sup.D10 R.sup.D10 L.sub.C202 R.sup.D1 R.sup.D37 L.sub.C394 R.sup.D17 R.sup.D58 L.sub.C586 R.sup.D143 R.sup.D149 L.sub.C11 R.sup.D11 R.sup.D11 L.sub.C203 R.sup.D1 R.sup.D40 L.sub.C395 R.sup.D17 R.sup.D59 L.sub.C587 R.sup.D143 R.sup.D151 L.sub.C12 R.sup.D12 R.sup.D12 L.sub.C204 R.sup.D1 R.sup.D41 L.sub.C396 R.sup.D17 R.sup.D78 L.sub.C588 R.sup.D143 R.sup.D154 L.sub.C13 R.sup.D13 R.sup.D13 L.sub.C205 R.sup.D1 R.sup.D42 L.sub.C397 R.sup.D17 R.sup.D79 L.sub.C589 R.sup.D143 R.sup.D155 L.sub.C14 R.sup.D14 R.sup.D14 L.sub.C206 R.sup.D1 R.sup.D43 L.sub.C398 R.sup.D17 R.sup.D81 L.sub.C590 R.sup.D143 R.sup.D161 L.sub.C15 R.sup.D15 R.sup.D15 L.sub.C207 R.sup.D1 R.sup.D48 L.sub.C399 R.sup.D17 R.sup.D87 L.sub.C591 R.sup.D143 R.sup.D175 L.sub.C16 R.sup.D16 R.sup.D16 L.sub.C208 R.sup.D1 R.sup.D49 L.sub.C400 R.sup.D17 R.sup.D88 L.sub.C592 R.sup.D144 R.sup.D3 L.sub.C17 R.sup.D17 R.sup.D17 L.sub.C209 R.sup.D1 R.sup.D50 L.sub.C401 R.sup.D17 R.sup.D89 L.sub.C593 R.sup.D144 R.sup.D5 L.sub.C18 R.sup.D18 R.sup.D18 L.sub.C210 R.sup.D1 R.sup.D54 L.sub.C402 R.sup.D17 R.sup.D93 L.sub.C594 R.sup.D144 R.sup.D17 L.sub.C19 R.sup.D19 R.sup.D19 L.sub.C211 R.sup.D1 R.sup.D55 L.sub.C403 R.sup.D17 R.sup.D116 L.sub.C595 R.sup.D144 R.sup.D18 L.sub.C20 R.sup.D20 R.sup.D20 L.sub.C212 R.sup.D1 R.sup.D58 L.sub.C404 R.sup.D17 R.sup.D117 L.sub.C596 R.sup.D144 R.sup.D20 L.sub.C21 R.sup.D21 R.sup.D21 L.sub.C213 R.sup.D1 R.sup.D59 L.sub.C405 R.sup.D17 R.sup.D118 L.sub.C597 R.sup.D144 R.sup.D22 L.sub.C22 R.sup.D22 R.sup.D22 L.sub.C214 R.sup.D1 R.sup.D78 L.sub.C406 R.sup.D17 R.sup.D119 L.sub.C598 R.sup.D144 R.sup.D37 L.sub.C23 R.sup.D23 R.sup.D23 L.sub.C215 R.sup.D1 R.sup.D79 L.sub.C407 R.sup.D17 R.sup.D120 L.sub.C599 R.sup.D144 R.sup.D40 L.sub.C24 R.sup.D24 R.sup.D24 L.sub.C216 R.sup.D1 R.sup.D81 L.sub.C408 R.sup.D17 R.sup.D133 L.sub.C600 R.sup.D144 R.sup.D41 L.sub.C25 R.sup.D25 R.sup.D25 L.sub.C217 R.sup.D1 R.sup.D87 L.sub.C409 R.sup.D17 R.sup.D134 L.sub.C601 R.sup.D144 R.sup.D42 L.sub.C26 R.sup.D26 R.sup.D26 L.sub.C218 R.sup.D1 R.sup.D88 L.sub.C410 R.sup.D17 R.sup.D135 L.sub.C602 R.sup.D144 R.sup.D43 L.sub.C27 R.sup.D27 R.sup.D27 L.sub.C219 R.sup.D1 R.sup.D89 L.sub.C411 R.sup.D17 R.sup.D136 L.sub.C603 R.sup.D144 R.sup.D48 L.sub.C28 R.sup.D28 R.sup.D28 L.sub.C220 R.sup.D1 R.sup.D93 L.sub.C412 R.sup.D17 R.sup.D143 L.sub.C604 R.sup.D144 R.sup.D49 L.sub.C29 R.sup.D29 R.sup.D29 L.sub.C221 R.sup.D1 R.sup.D116 L.sub.C413 R.sup.D17 R.sup.D144 L.sub.C605 R.sup.D144 R.sup.D54 L.sub.C30 R.sup.D30 R.sup.D30 L.sub.C222 R.sup.D1 R.sup.D117 L.sub.C414 R.sup.D17 R.sup.D145 L.sub.C606 R.sup.D144 R.sup.D58 L.sub.C31 R.sup.D31 R.sup.D31 L.sub.C223 R.sup.D1 R.sup.D118 L.sub.C415 R.sup.D17 R.sup.D146 L.sub.C607 R.sup.D144 R.sup.D59 L.sub.C32 R.sup.D32 R.sup.D32 L.sub.C224 R.sup.D1 R.sup.D119 L.sub.C416 R.sup.D17 R.sup.D147 L.sub.C608 R.sup.D144 R.sup.D78 L.sub.C33 R.sup.D33 R.sup.D33 L.sub.C225 R.sup.D1 R.sup.D120 L.sub.C417 R.sup.D17 R.sup.D149 L.sub.C609 R.sup.D144 R.sup.D79 L.sub.C34 R.sup.D34 R.sup.D34 L.sub.C226 R.sup.D1 R.sup.D133 L.sub.C418 R.sup.D17 R.sup.D151 L.sub.C610 R.sup.D144 R.sup.D81 L.sub.C35 R.sup.D35 R.sup.D35 L.sub.C227 R.sup.D1 R.sup.D134 L.sub.C419 R.sup.D17 R.sup.D154 L.sub.C611 R.sup.D144 R.sup.D87 L.sub.C36 R.sup.D36 R.sup.D36 L.sub.C228 R.sup.D1 R.sup.D135 L.sub.C420 R.sup.D17 R.sup.D155 L.sub.C612 R.sup.D144 R.sup.D88 L.sub.C37 R.sup.D37 R.sup.D37 L.sub.C229 R.sup.D1 R.sup.D136 L.sub.C421 R.sup.D17 R.sup.D161 L.sub.C613 R.sup.D144 R.sup.D89 L.sub.C38 R.sup.D38 R.sup.D38 L.sub.C230 R.sup.D1 R.sup.D143 L.sub.C422 R.sup.D17 R.sup.D175 L.sub.C614 R.sup.D144 R.sup.D93 L.sub.C39 R.sup.D39 R.sup.D39 L.sub.C231 R.sup.D1 R.sup.D144 L.sub.C423 R.sup.D50 R.sup.D3 L.sub.C615 R.sup.D144 R.sup.D116 L.sub.C40 R.sup.D40 R.sup.D40 L.sub.C232 R.sup.D1 R.sup.D145 L.sub.C424 R.sup.D50 R.sup.D5 L.sub.C616 R.sup.D144 R.sup.D117 L.sub.C41 R.sup.D41 R.sup.D41 L.sub.C233 R.sup.D1 R.sup.D146 L.sub.C425 R.sup.D50 R.sup.D18 L.sub.C617 R.sup.D144 R.sup.D118 L.sub.C42 R.sup.D42 R.sup.D42 L.sub.C234 R.sup.D1 R.sup.D147 L.sub.C426 R.sup.D50 R.sup.D20 L.sub.C618 R.sup.D144 R.sup.D119 L.sub.C43 R.sup.D43 R.sup.D43 L.sub.C235 R.sup.D1 R.sup.D149 L.sub.C427 R.sup.D50 R.sup.D22 L.sub.C619 R.sup.D144 R.sup.D120 L.sub.C44 R.sup.D44 R.sup.D44 L.sub.C236 R.sup.D1 R.sup.D151 L.sub.C428 R.sup.D50 R.sup.D37 L.sub.C620 R.sup.D144 R.sup.D133 L.sub.C45 R.sup.D45 R.sup.D45 L.sub.C237 R.sup.D1 R.sup.D154 L.sub.C429 R.sup.D50 R.sup.D40 L.sub.C621 R.sup.D144 R.sup.D134 L.sub.C46 R.sup.D46 R.sup.D46 L.sub.C238 R.sup.D1 R.sup.D155 L.sub.C430 R.sup.D50 R.sup.D41 L.sub.C622 R.sup.D144 R.sup.D135 L.sub.C47 R.sup.D47 R.sup.D47 L.sub.C239 R.sup.D1 R.sup.D161 L.sub.C431 R.sup.D50 R.sup.D42 L.sub.C623 R.sup.D144 R.sup.D136 L.sub.C48 R.sup.D48 R.sup.D48 L.sub.C240 R.sup.D1 R.sup.D175 L.sub.C432 R.sup.D50 R.sup.D43 L.sub.C624 R.sup.D144 R.sup.D145 L.sub.C49 R.sup.D49 R.sup.D49 L.sub.C241 R.sup.D4 R.sup.D3 L.sub.C433 R.sup.D50 R.sup.D48 L.sub.C625 R.sup.D144 R.sup.D146 L.sub.C50 R.sup.D50 R.sup.D50 L.sub.C242 R.sup.D4 R.sup.D5 L.sub.C434 R.sup.D50 R.sup.D49 L.sub.C626 R.sup.D144 R.sup.D147 L.sub.C51 R.sup.D51 R.sup.D51 L.sub.C243 R.sup.D4 R.sup.D9 L.sub.C435 R.sup.D50 R.sup.D54 L.sub.C627 R.sup.D144 R.sup.D149 L.sub.C52 R.sup.D52 R.sup.D52 L.sub.C244 R.sup.D4 R.sup.D10 L.sub.C436 R.sup.D50 R.sup.D55 L.sub.C628 R.sup.D144 R.sup.D151 L.sub.C53 R.sup.D53 R.sup.D55 L.sub.C245 R.sup.D4 R.sup.D17 L.sub.C437 R.sup.D50 R.sup.D58 L.sub.C629 R.sup.D144 R.sup.D154 L.sub.C54 R.sup.D54 R.sup.D54 L.sub.C246 R.sup.D4 R.sup.D18 L.sub.C438 R.sup.D50 R.sup.D59 L.sub.C630 R.sup.D144 R.sup.D155 L.sub.C55 R.sup.D55 R.sup.D55 L.sub.C247 R.sup.D4 R.sup.D20 L.sub.C439 R.sup.D50 R.sup.D78 L.sub.C631 R.sup.D144 R.sup.D161 L.sub.C56 R.sup.D56 R.sup.D56 L.sub.C248 R.sup.D4 R.sup.D22 L.sub.C440 R.sup.D50 R.sup.D79 L.sub.C632 R.sup.D144 R.sup.D175 L.sub.C57 R.sup.D57 R.sup.D57 L.sub.C249 R.sup.D4 R.sup.D37 L.sub.C441 R.sup.D50 R.sup.D81 L.sub.C633 R.sup.D145 R.sup.D3 L.sub.C58 R.sup.D58 R.sup.D58 L.sub.C250 R.sup.D4 R.sup.D40 L.sub.C442 R.sup.D50 R.sup.D87 L.sub.C634 R.sup.D145 R.sup.D5 L.sub.C59 R.sup.D59 R.sup.D59 L.sub.C251 R.sup.D4 R.sup.D41 L.sub.C443 R.sup.D50 R.sup.D88 L.sub.C635 R.sup.D145 R.sup.D17 L.sub.C60 R.sup.D60 R.sup.D60 L.sub.C252 R.sup.D4 R.sup.D42 L.sub.C444 R.sup.D50 R.sup.D89 L.sub.C636 R.sup.D145 R.sup.D18 L.sub.C61 R.sup.D61 R.sup.D61 L.sub.C253 R.sup.D4 R.sup.D43 L.sub.C445 R.sup.D50 R.sup.D93 L.sub.C637 R.sup.D145 R.sup.D20 L.sub.C62 R.sup.D62 R.sup.D62 L.sub.C254 R.sup.D4 R.sup.D48 L.sub.C446 R.sup.D50 R.sup.D116 L.sub.C638 R.sup.D145 R.sup.D22 L.sub.C63 R.sup.D63 R.sup.D63 L.sub.C255 R.sup.D4 R.sup.D49 L.sub.C447 R.sup.D50 R.sup.D117 L.sub.C639 R.sup.D145 R.sup.D37 L.sub.C64 R.sup.D64 R.sup.D64 L.sub.C256 R.sup.D4 R.sup.D50 L.sub.C448 R.sup.D50 R.sup.D118 L.sub.C640 R.sup.D145 R.sup.D40 L.sub.C65 R.sup.D65 R.sup.D65 L.sub.C257 R.sup.D4 R.sup.D54 L.sub.C449 R.sup.D50 R.sup.D119 L.sub.C641 R.sup.D145 R.sup.D41 L.sub.C66 R.sup.D66 R.sup.D66 L.sub.C258 R.sup.D4 R.sup.D55 L.sub.C450 R.sup.D50 R.sup.D120 L.sub.C642 R.sup.D145 R.sup.D42 L.sub.C67 R.sup.D67 R.sup.D67 L.sub.C259 R.sup.D4 R.sup.D58 L.sub.C451 R.sup.D50 R.sup.D133 L.sub.C643 R.sup.D145 R.sup.D43 L.sub.C68 R.sup.D68 R.sup.D68 L.sub.C260 R.sup.D4 R.sup.D59 L.sub.C452 R.sup.D50 R.sup.D134 L.sub.C644 R.sup.D145 R.sup.D48 L.sub.C69 R.sup.D69 R.sup.D69 L.sub.C261 R.sup.D4 R.sup.D78 L.sub.C453 R.sup.D50 R.sup.D135 L.sub.C645 R.sup.D145 R.sup.D49 L.sub.C70 R.sup.D70 R.sup.D70 L.sub.C262 R.sup.D4 R.sup.D79 L.sub.C454 R.sup.D50 R.sup.D136 L.sub.C646 R.sup.D145 R.sup.D54 L.sub.C71 R.sup.D71 R.sup.D71 L.sub.C263 R.sup.D4 R.sup.D81 L.sub.C455 R.sup.D50 R.sup.D143 L.sub.C647 R.sup.D145 R.sup.D58 L.sub.C72 R.sup.D72 R.sup.D72 L.sub.C264 R.sup.D4 R.sup.D87 L.sub.C456 R.sup.D50 R.sup.D144 L.sub.C648 R.sup.D145 R.sup.D59 L.sub.C73 R.sup.D73 R.sup.D73 L.sub.C265 R.sup.D4 R.sup.D88 L.sub.C457 R.sup.D50 R.sup.D145 L.sub.C649 R.sup.D145 R.sup.D78 L.sub.C74 R.sup.D74 R.sup.D74 L.sub.C266 R.sup.D4 R.sup.D89 L.sub.C458 R.sup.D50 R.sup.D146 L.sub.C650 R.sup.D145 R.sup.D79 L.sub.C75 R.sup.D75 R.sup.D75 L.sub.C267 R.sup.D4 R.sup.D93 L.sub.C459 R.sup.D50 R.sup.D147 L.sub.C651 R.sup.D145 R.sup.D81 L.sub.C76 R.sup.D76 R.sup.D76 L.sub.C268 R.sup.D4 R.sup.D116 L.sub.C460 R.sup.D50 R.sup.D149 L.sub.C652 R.sup.D145 R.sup.D87 L.sub.C77 R.sup.D77 R.sup.D77 L.sub.C269 R.sup.D4 R.sup.D117 L.sub.C461 R.sup.D50 R.sup.D151 L.sub.C653 R.sup.D145 R.sup.D88 L.sub.C78 R.sup.D78 R.sup.D78 L.sub.C270 R.sup.D4 R.sup.D118 L.sub.C462 R.sup.D50 R.sup.D154 L.sub.C654 R.sup.D145 R.sup.D89 L.sub.C79 R.sup.D79 R.sup.D79 L.sub.C271 R.sup.D4 R.sup.D119 L.sub.C463 R.sup.D50 R.sup.D155 L.sub.C655 R.sup.D145 R.sup.D93 L.sub.C80 R.sup.D80 R.sup.D80 L.sub.C272 R.sup.D4 R.sup.D120 L.sub.C464 R.sup.D50 R.sup.D161 L.sub.C656 R.sup.D145 R.sup.D116 L.sub.C81 R.sup.D81 R.sup.D81 L.sub.C273 R.sup.D4 R.sup.D133 L.sub.C465 R.sup.D50 R.sup.D175 L.sub.C657 R.sup.D145 R.sup.D117 L.sub.C82 R.sup.D82 R.sup.D82 L.sub.C274 R.sup.D4 R.sup.D134 L.sub.C466 R.sup.D55 R.sup.D3 L.sub.C658 R.sup.D145 R.sup.D118 L.sub.C83 R.sup.D83 R.sup.D83 L.sub.C275 R.sup.D4 R.sup.D135 L.sub.C467 R.sup.D55 R.sup.D5 L.sub.C659 R.sup.D145 R.sup.D119 L.sub.C84 R.sup.D84 R.sup.D84 L.sub.C276 R.sup.D4 R.sup.D136 L.sub.C468 R.sup.D55 R.sup.D18 L.sub.C660 R.sup.D145 R.sup.D120 L.sub.C85 R.sup.D85 R.sup.D85 L.sub.C277 R.sup.D4 R.sup.D143 L.sub.C469 R.sup.D55 R.sup.D20 L.sub.C661 R.sup.D145 R.sup.D133 L.sub.C86 R.sup.D86 R.sup.D86 L.sub.C278 R.sup.D4 R.sup.D144 L.sub.C470 R.sup.D55 R.sup.D22 L.sub.C662 R.sup.D145 R.sup.D134 L.sub.C87 R.sup.D87 R.sup.D87 L.sub.C279 R.sup.D4 R.sup.D145 L.sub.C471 R.sup.D55 R.sup.D37 L.sub.C663 R.sup.D145 R.sup.D135 L.sub.C88 R.sup.D88 R.sup.D88 L.sub.C280 R.sup.D4 R.sup.D146 L.sub.C472 R.sup.D55 R.sup.D40 L.sub.C664 R.sup.D145 R.sup.D136 L.sub.C89 R.sup.D89 R.sup.D89 L.sub.C281 R.sup.D4 R.sup.D147 L.sub.C473 R.sup.D55 R.sup.D41 L.sub.C665 R.sup.D145 R.sup.D146 L.sub.C90 R.sup.D90 R.sup.D90 L.sub.C282 R.sup.D4 R.sup.D149 L.sub.C474 R.sup.D55 R.sup.D42 L.sub.C666 R.sup.D145 R.sup.D147 L.sub.C91 R.sup.D91 R.sup.D91 L.sub.C283 R.sup.D4 R.sup.D151 L.sub.C475 R.sup.D55 R.sup.D43 L.sub.C667 R.sup.D145 R.sup.D149 L.sub.C92 R.sup.D92 R.sup.D92 L.sub.C284 R.sup.D4 R.sup.D154 L.sub.C476 R.sup.D55 R.sup.D48 L.sub.C668 R.sup.D145 R.sup.D151 L.sub.C93 R.sup.D93 R.sup.D93 L.sub.C285 R.sup.D4 R.sup.D155 L.sub.C477 R.sup.D55 R.sup.D49 L.sub.C669 R.sup.D145 R.sup.D154 L.sub.C94 R.sup.D94 R.sup.D94 L.sub.C286 R.sup.D4 R.sup.D161 L.sub.C478 R.sup.D55 R.sup.D54 L.sub.C670 R.sup.D145 R.sup.D155 L.sub.C95 R.sup.D95 R.sup.D95 L.sub.C287 R.sup.D4 R.sup.D175 L.sub.C479 R.sup.D55 R.sup.D58 L.sub.C671 R.sup.D145 R.sup.D161 L.sub.C96 R.sup.D96 R.sup.D96 L.sub.C288 R.sup.D9 R.sup.D3 L.sub.C480 R.sup.D55 R.sup.D59 L.sub.C672 R.sup.D145 R.sup.D175 L.sub.C97 R.sup.D97 R.sup.D97 L.sub.C289 R.sup.D9 R.sup.D5 L.sub.C481 R.sup.D55 R.sup.D78 L.sub.C673 R.sup.D146 R.sup.D3 L.sub.C98 R.sup.D98 R.sup.D98 L.sub.C290 R.sup.D9 R.sup.D10 L.sub.C482 R.sup.D55 R.sup.D79 L.sub.C674 R.sup.D146 R.sup.D5 L.sub.C99 R.sup.D99 R.sup.D99 L.sub.C291 R.sup.D9 R.sup.D17 L.sub.C483 R.sup.D55 R.sup.D81 L.sub.C675 R.sup.D146 R.sup.D17 L.sub.C100 R.sup.D100 R.sup.D100 L.sub.C292 R.sup.D9 R.sup.D38 L.sub.C484 R.sup.D55 R.sup.D87 L.sub.C676 R.sup.D146 R.sup.D38 L.sub.C101 R.sup.D101 R.sup.D101 L.sub.C293 R.sup.D9 R.sup.D20 L.sub.C485 R.sup.D55 R.sup.D88 L.sub.C677 R.sup.D146 R.sup.D20 L.sub.C102 R.sup.D102 R.sup.D102 L.sub.C294 R.sup.D9 R.sup.D22 L.sub.C486 R.sup.D55 R.sup.D89 L.sub.C678 R.sup.D146 R.sup.D22 L.sub.C103 R.sup.D103 R.sup.D103 L.sub.C295 R.sup.D9 R.sup.D37 L.sub.C487 R.sup.D55 R.sup.D93 L.sub.C679 R.sup.D146 R.sup.D37 L.sub.C104 R.sup.D104 R.sup.D104 L.sub.C296 R.sup.D9 R.sup.D40 L.sub.C488 R.sup.D55 R.sup.D116 L.sub.C680 R.sup.D146 R.sup.D40 L.sub.C105 R.sup.D105 R.sup.D105 L.sub.C297 R.sup.D9 R.sup.D41 L.sub.C489 R.sup.D55 R.sup.D117 L.sub.C681 R.sup.D146 R.sup.D41 L.sub.C106 R.sup.D106 R.sup.D106 L.sub.C298 R.sup.D9 R.sup.D42 L.sub.C490 R.sup.D55 R.sup.D118 L.sub.C682 R.sup.D146 R.sup.D42 L.sub.C107 R.sup.D107 R.sup.D107 L.sub.C299 R.sup.D9 R.sup.D43 L.sub.C491 R.sup.D55 R.sup.D119 L.sub.C683 R.sup.D146 R.sup.D43 L.sub.C108 R.sup.D108 R.sup.D108 L.sub.C300 R.sup.D9 R.sup.D48 L.sub.C492 R.sup.D55 R.sup.D120 L.sub.C684 R.sup.D146 R.sup.D48 L.sub.C109 R.sup.D109 R.sup.D109 L.sub.C301 R.sup.D9 R.sup.D49 L.sub.C493 R.sup.D55 R.sup.D133 L.sub.C685 R.sup.D146 R.sup.D49 L.sub.C110 R.sup.D110 R.sup.D110 L.sub.C302 R.sup.D9 R.sup.D50 L.sub.C494 R.sup.D55 R.sup.D134 L.sub.C686 R.sup.D146 R.sup.D54 L.sub.C111 R.sup.D111 R.sup.D111 L.sub.C303 R.sup.D9 R.sup.D54 L.sub.C495 R.sup.D55 R.sup.D135 L.sub.C687 R.sup.D146 R.sup.D58 L.sub.C112 R.sup.D112 R.sup.D112 L.sub.C304 R.sup.D9 R.sup.D55 L.sub.C496 R.sup.D55 R.sup.D136 L.sub.C688 R.sup.D146 R.sup.D59 L.sub.C113 R.sup.D113 R.sup.D113 L.sub.C305 R.sup.D9 R.sup.D58 L.sub.C497 R.sup.D55 R.sup.D143 L.sub.C689 R.sup.D146 R.sup.D78 L.sub.C114 R.sup.D114 R.sup.D114 L.sub.C306 R.sup.D9 R.sup.D59 L.sub.C498 R.sup.D55 R.sup.D144 L.sub.C690 R.sup.D146 R.sup.D79 L.sub.C115 R.sup.D115 R.sup.D115 L.sub.C307 R.sup.D9 R.sup.D78 L.sub.C499 R.sup.D55 R.sup.D145 L.sub.C691 R.sup.D146 R.sup.D81 L.sub.C116 R.sup.D116 R.sup.D116 L.sub.C308 R.sup.D9 R.sup.D79 L.sub.C500 R.sup.D55 R.sup.D146 L.sub.C692 R.sup.D146 R.sup.D87 L.sub.C117 R.sup.D117 R.sup.D117 L.sub.C309 R.sup.D9 R.sup.D81 L.sub.C501 R.sup.D55 R.sup.D147 L.sub.C693 R.sup.D146 R.sup.D88 L.sub.C118 R.sup.D118 R.sup.D118 L.sub.C310 R.sup.D9 R.sup.D87 L.sub.C502 R.sup.D55 R.sup.D149 L.sub.C694 R.sup.D146 R.sup.D89 L.sub.C119 R.sup.D119 R.sup.D119 L.sub.C311 R.sup.D9 R.sup.D88 L.sub.C503 R.sup.D55 R.sup.D151 L.sub.C695 R.sup.D146 R.sup.D93 L.sub.C120 R.sup.D120 R.sup.D120 L.sub.C312 R.sup.D9 R.sup.D89 L.sub.C504 R.sup.D55 R.sup.D154 L.sub.C696 R.sup.D146 R.sup.D117 L.sub.C121 R.sup.D121 R.sup.D121 L.sub.C313 R.sup.D9 R.sup.D93 L.sub.C505 R.sup.D55 R.sup.D155 L.sub.C697 R.sup.D146 R.sup.D118 L.sub.C122 R.sup.D122 R.sup.D122 L.sub.C314 R.sup.D9 R.sup.D116 L.sub.C506 R.sup.D55 R.sup.D161 L.sub.C698 R.sup.D146 R.sup.D119 L.sub.C123 R.sup.D123 R.sup.D123 L.sub.C315 R.sup.D9 R.sup.D117 L.sub.C507 R.sup.D55 R.sup.175 L.sub.C699 R.sup.D146 R.sup.D120 L.sub.C124 R.sup.D124 R.sup.D124 L.sub.C316 R.sup.D9 R.sup.D118 L.sub.C508 R.sup.D116 R.sup.D3 L.sub.C700 R.sup.D146 R.sup.D133 L.sub.C125 R.sup.D125 R.sup.D125 L.sub.C317 R.sup.D9 R.sup.D119 L.sub.C509 R.sup.D116 R.sup.D5 L.sub.C701 R.sup.D146 R.sup.D134 L.sub.C126 R.sup.D126 R.sup.D126 L.sub.C318 R.sup.D9 R.sup.D120 L.sub.C510 R.sup.D116 R.sup.D17 L.sub.C702 R.sup.D146 R.sup.D135 L.sub.C127 R.sup.D127 R.sup.D127 L.sub.C319 R.sup.D9 R.sup.D133 L.sub.C511 R.sup.D116 R.sup.D38 L.sub.C703 R.sup.D146 R.sup.D136 L.sub.C128 R.sup.D128 R.sup.D128 L.sub.C320 R.sup.D9 R.sup.D134 L.sub.C512 R.sup.D116 R.sup.D20 L.sub.C704 R.sup.D146 R.sup.D146 L.sub.C129 R.sup.D129 R.sup.D129 L.sub.C321 R.sup.D9 R.sup.D135 L.sub.C513 R.sup.D116 R.sup.D22 L.sub.C705 R.sup.D146 R.sup.D147 L.sub.C130 R.sup.D130 R.sup.D130 L.sub.C322 R.sup.D9 R.sup.D136 L.sub.C514 R.sup.D116 R.sup.D37 L.sub.C706 R.sup.D146 R.sup.D149 L.sub.C131 R.sup.D131 R.sup.D131 L.sub.C323 R.sup.D9 R.sup.D143 L.sub.C515 R.sup.D116 R.sup.D40 L.sub.C707 R.sup.D146 R.sup.D151 L.sub.C132 R.sup.D132 R.sup.D132 L.sub.C324 R.sup.D9 R.sup.D144 L.sub.C516 R.sup.D116 R.sup.D41 L.sub.C708 R.sup.D146 R.sup.D154 L.sub.C133 R.sup.D133 R.sup.D133 L.sub.C325 R.sup.D9 R.sup.D145 L.sub.C517 R.sup.D116 R.sup.D42 L.sub.C709 R.sup.D146 R.sup.D155 L.sub.C134 R.sup.D134 R.sup.D134 L.sub.C326 R.sup.D9 R.sup.D146 L.sub.C518 R.sup.D116 R.sup.D43 L.sub.C710 R.sup.D146 R.sup.D161 L.sub.C135 R.sup.D135 R.sup.D135 L.sub.C327 R.sup.D9 R.sup.D147 L.sub.C519 R.sup.D116 R.sup.D48 L.sub.C711 R.sup.D146 R.sup.D175 L.sub.C136 R.sup.D136 R.sup.D136 L.sub.C328 R.sup.D9 R.sup.D149 L.sub.C520 R.sup.D116 R.sup.D49 L.sub.C712 R.sup.D133 R.sup.D3 L.sub.C137 R.sup.D137 R.sup.D137 L.sub.C329 R.sup.D9 R.sup.D151 L.sub.C521 R.sup.D116 R.sup.D54 L.sub.C713 R.sup.D133 R.sup.D5 L.sub.C138 R.sup.D138 R.sup.D138 L.sub.C330 R.sup.D9 R.sup.D154 L.sub.C522 R.sup.D116 R.sup.D58 L.sub.C714 R.sup.D133 R.sup.D3 L.sub.C139 R.sup.D139 R.sup.D139 L.sub.C331 R.sup.D9 R.sup.D155 L.sub.C523 R.sup.D116 R.sup.D59 L.sub.C715 R.sup.D133 R.sup.D18 L.sub.C140 R.sup.D140 R.sup.D140 L.sub.C332 R.sup.D9 R.sup.D161 L.sub.C524 R.sup.D116 R.sup.D78 L.sub.C716 R.sup.D133 R.sup.D20 L.sub.C141 R.sup.D141 R.sup.D141 L.sub.C333 R.sup.D9 R.sup.D175 L.sub.C525 R.sup.D116 R.sup.D79 L.sub.C717 R.sup.D133 R.sup.D22 L.sub.C142 R.sup.D142 R.sup.D142 L.sub.C334 R.sup.D10 R.sup.D3 L.sub.C526 R.sup.D116 R.sup.D81 L.sub.C718 R.sup.D133 R.sup.D37 L.sub.C143 R.sup.D143 R.sup.D143 L.sub.C335 R.sup.D10 R.sup.D5 L.sub.C527 R.sup.D116 R.sup.D87 L.sub.C719 R.sup.D133 R.sup.D40 L.sub.C144 R.sup.D144 R.sup.D144 L.sub.C336 R.sup.D10 R.sup.D17 L.sub.C528 R.sup.D116 R.sup.D88 L.sub.C720 R.sup.D133 R.sup.D41 L.sub.C145 R.sup.D145 R.sup.D145 L.sub.C337 R.sup.D10 R.sup.D18 L.sub.C529 R.sup.D116 R.sup.D89 L.sub.C721 R.sup.D133 R.sup.D42 L.sub.C146 R.sup.D146 R.sup.D146 L.sub.C338 R.sup.D10 R.sup.D20 L.sub.C530 R.sup.D116 R.sup.D93 L.sub.C722 R.sup.D133 R.sup.D43 L.sub.C147 R.sup.D147 R.sup.D147 L.sub.C339 R.sup.D10 R.sup.D22 L.sub.C531 R.sup.D116 R.sup.D117 L.sub.C723 R.sup.D133 R.sup.D48 L.sub.C148 R.sup.D148 R.sup.D148 L.sub.C340 R.sup.D10 R.sup.D37 L.sub.C532 R.sup.D116 R.sup.D118 L.sub.C724 R.sup.D133 R.sup.D49 L.sub.C149 R.sup.D149 R.sup.D149 L.sub.C341 R.sup.D10 R.sup.D40 L.sub.C533 R.sup.D116 R.sup.D119 L.sub.C725 R.sup.D133 R.sup.D54 L.sub.C150 R.sup.D150 R.sup.D150 L.sub.C342 R.sup.D10 R.sup.D41 L.sub.C534 R.sup.D116 R.sup.D120 L.sub.C726 R.sup.D133 R.sup.D58 L.sub.C151 R.sup.D151 R.sup.D151 L.sub.C343 R.sup.D10 R.sup.D42 L.sub.C535 R.sup.D116 R.sup.D133 L.sub.C727 R.sup.D133 R.sup.D59 L.sub.C152 R.sup.D152 R.sup.D152 L.sub.C344 R.sup.D10 R.sup.D43 L.sub.C536 R.sup.D116 R.sup.D134 L.sub.C728 R.sup.D133 R.sup.D78 L.sub.C153 R.sup.D153 R.sup.D153 L.sub.C345 R.sup.D10 R.sup.D48 L.sub.C537 R.sup.D116 R.sup.D135 L.sub.C729 R.sup.D133 R.sup.D79 L.sub.C154 R.sup.D154 R.sup.D154 L.sub.C346 R.sup.D10 R.sup.D49 L.sub.C538 R.sup.D116 R.sup.D136 L.sub.C730 R.sup.D133 R.sup.D81 L.sub.C155 R.sup.D155 R.sup.D155 L.sub.C347 R.sup.D10 R.sup.D50 L.sub.C539 R.sup.D116 R.sup.D143 L.sub.C731 R.sup.D133 R.sup.D87 L.sub.C156 R.sup.D156 R.sup.D156 L.sub.C348 R.sup.D10 R.sup.D54 L.sub.C540 R.sup.D116 R.sup.D144 L.sub.C732 R.sup.D133 R.sup.D88 L.sub.C157 R.sup.D157 R.sup.D157 L.sub.C349 R.sup.D10 R.sup.D55 L.sub.C541 R.sup.D116 R.sup.D145 L.sub.C733 R.sup.D133 R.sup.D89 L.sub.C158 R.sup.D158 R.sup.D158 L.sub.C350 R.sup.D10 R.sup.D58 L.sub.C542 R.sup.D116 R.sup.D146 L.sub.C734 R.sup.D133 R.sup.D93 L.sub.C159 R.sup.D159 R.sup.D159 L.sub.C351 R.sup.D10 R.sup.D59 L.sub.C543 R.sup.D116 R.sup.D147 L.sub.C735 R.sup.D133 R.sup.D117 L.sub.C160 R.sup.D160 R.sup.D160 L.sub.C352 R.sup.D10 R.sup.D78 L.sub.C544 R.sup.D116 R.sup.D149 L.sub.C736 R.sup.D133 R.sup.D118 L.sub.C161 R.sup.D161 R.sup.D161 L.sub.C353 R.sup.D10 R.sup.D79 L.sub.C545 R.sup.D116 R.sup.D151 L.sub.C737 R.sup.D133 R.sup.D119 L.sub.C162 R.sup.D162 R.sup.D162 L.sub.C354 R.sup.D10 R.sup.D81 L.sub.C546 R.sup.D116 R.sup.D154 L.sub.C738 R.sup.D133 R.sup.D120 L.sub.C163 R.sup.D163 R.sup.D163 L.sub.C355 R.sup.D10 R.sup.D87 L.sub.C547 R.sup.D116 R.sup.D155 L.sub.C739 R.sup.D133 R.sup.D133 L.sub.C164 R.sup.D164 R.sup.D164 L.sub.C356 R.sup.D10 R.sup.D88 L.sub.C548 R.sup.D116 R.sup.D161 L.sub.C740 R.sup.D133 R.sup.D134 L.sub.C165 R.sup.D165 R.sup.D165 L.sub.C357 R.sup.D10 R.sup.D89 L.sub.C549 R.sup.D116 R.sup.D175 L.sub.C741 R.sup.D133 R.sup.D135 L.sub.C166 R.sup.D166 R.sup.D166 L.sub.C358 R.sup.D10 R.sup.D93 L.sub.C550 R.sup.D143 R.sup.D3 L.sub.C742 R.sup.D133 R.sup.D136 L.sub.C167 R.sup.D167 R.sup.D167 L.sub.C359 R.sup.D10 R.sup.D116 L.sub.C551 R.sup.D143 R.sup.D5 L.sub.C743 R.sup.D133 R.sup.D146 L.sub.C168 R.sup.D168 R.sup.D168 L.sub.C360 R.sup.D10 R.sup.D117 L.sub.C552 R.sup.D143 R.sup.D17 L.sub.C744 R.sup.D133 R.sup.D147 L.sub.C169 R.sup.D169 R.sup.D169 L.sub.C361 R.sup.D10 R.sup.D118 L.sub.C553 R.sup.D143 R.sup.D18 L.sub.C745 R.sup.D133 R.sup.D149 L.sub.C170 R.sup.D170 R.sup.D170 L.sub.C362 R.sup.D10 R.sup.D119 L.sub.C554 R.sup.D143 R.sup.D20 L.sub.C746 R.sup.D133 R.sup.D151 L.sub.C171 R.sup.D171 R.sup.D171 L.sub.C363 R.sup.D10 R.sup.D120 L.sub.C555 R.sup.D143 R.sup.D22 L.sub.C747 R.sup.D133 R.sup.D154 L.sub.C172 R.sup.D172 R.sup.D172 L.sub.C364 R.sup.D10 R.sup.D133 L.sub.C556 R.sup.D143 R.sup.D37 L.sub.C748 R.sup.D133 R.sup.D155 L.sub.C173 R.sup.D173 R.sup.D173 L.sub.C365 R.sup.D10 R.sup.D134 L.sub.C557 R.sup.D143 R.sup.D40 L.sub.C749 R.sup.D133 R.sup.D161 L.sub.C174 R.sup.D174 R.sup.D174 L.sub.C366 R.sup.D10 R.sup.D135 L.sub.C558 R.sup.D143 R.sup.D41 L.sub.C750 R.sup.D133 R.sup.D175 L.sub.C175 R.sup.D175 R.sup.D175 L.sub.C367 R.sup.D10 R.sup.D136 L.sub.C559 R.sup.D143 R.sup.D42 L.sub.C751 R.sup.D175 R.sup.D3 L.sub.C176 R.sup.D176 R.sup.D176 L.sub.C368 R.sup.D10 R.sup.D143 L.sub.C560 R.sup.D143 R.sup.D43 L.sub.C752 R.sup.D175 R.sup.D5 L.sub.C177 R.sup.D177 R.sup.D177 L.sub.C369 R.sup.D10 R.sup.D144 L.sub.C561 R.sup.D143 R.sup.D48 L.sub.C753 R.sup.D175 R.sup.D18 L.sub.C178 R.sup.D178 R.sup.D178 L.sub.C370 R.sup.D10 R.sup.D145 L.sub.C562 R.sup.D143 R.sup.D49 L.sub.C754 R.sup.D175 R.sup.D20 L.sub.C179 R.sup.D179 R.sup.D179 L.sub.C371 R.sup.D10 R.sup.D146 L.sub.C563 R.sup.D143 R.sup.D54 L.sub.C755 R.sup.D175 R.sup.D22 L.sub.C180 R.sup.D180 R.sup.D180 L.sub.C372 R.sup.D10 R.sup.D147 L.sub.C564 R.sup.D143 R.sup.D58 L.sub.C756 R.sup.D175 R.sup.D37 L.sub.C181 R.sup.D181 R.sup.D181 L.sub.C373 R.sup.D10 R.sup.D149 L.sub.C565 R.sup.D143 R.sup.D59 L.sub.C757 R.sup.D175 R.sup.D40 L.sub.C182 R.sup.D182 R.sup.D182 L.sub.C374 R.sup.D10 R.sup.D151 L.sub.C566 R.sup.D143 R.sup.D78 L.sub.C758 R.sup.D175 R.sup.D41 L.sub.C183 R.sup.D183 R.sup.D183 L.sub.C375 R.sup.D10 R.sup.D154 L.sub.C567 R.sup.D143 R.sup.D79 L.sub.C759 R.sup.D175 R.sup.D42 L.sub.C184 R.sup.D184 R.sup.D184 L.sub.C376 R.sup.D10 R.sup.D155 L.sub.C568 R.sup.D143 R.sup.D81 L.sub.C760 R.sup.D175 R.sup.D43 L.sub.C185 R.sup.D185 R.sup.D185 L.sub.C377 R.sup.D10 R.sup.D161 L.sub.C569 R.sup.D143 R.sup.D87 L.sub.C761 R.sup.D175 R.sup.D48 L.sub.C186 R.sup.D186 R.sup.D186 L.sub.C378 R.sup.D10 R.sup.D175 L.sub.C570 R.sup.D143 R.sup.D88 L.sub.C762 R.sup.D175 R.sup.D49 L.sub.C187 R.sup.D187 R.sup.D187 L.sub.C379 R.sup.D17 R.sup.D3 L.sub.C571 R.sup.D143 R.sup.D89 L.sub.C763 R.sup.D175 R.sup.D54 L.sub.C188 R.sup.D188 R.sup.D188 L.sub.C380 R.sup.D17 R.sup.D5 L.sub.C572 R.sup.D143 R.sup.D93 L.sub.C764 R.sup.D175 R.sup.D58 L.sub.C189 R.sup.D189 R.sup.D189 L.sub.C381 R.sup.D17 R.sup.D18 L.sub.C573 R.sup.D143 R.sup.D116 L.sub.C765 R.sup.D175 R.sup.D59 L.sub.C190 R.sup.D190 R.sup.D190 L.sub.C382 R.sup.D17 R.sup.D20 L.sub.C574 R.sup.D143 R.sup.D117 L.sub.C766 R.sup.D175 R.sup.D78 L.sub.C191 R.sup.D191 R.sup.D191 L.sub.C383 R.sup.D17 R.sup.D22 L.sub.C575 R.sup.D143 R.sup.D118 L.sub.C767 R.sup.D175 R.sup.D79 L.sub.C192 R.sup.D192 R.sup.D192 L.sub.C384 R.sup.D17 R.sup.D37 L.sub.C576 R.sup.D143 R.sup.D119 L.sub.C768 R.sup.D175 R.sup.D81 L.sub.C769 R.sup.D193 R.sup.D193 L.sub.C877 R.sup.D1 R.sup.D193 L.sub.C985 R.sup.D4 R.sup.D193 L.sub.C1093 R.sup.D9 R.sup.D193 L.sub.C770 R.sup.D194 R.sup.D194 L.sub.C878 R.sup.D1 R.sup.D194 L.sub.C986 R.sup.D4 R.sup.D194 L.sub.C1094 R.sup.D9 R.sup.D194 L.sub.C771 R.sup.D195 R.sup.D195 L.sub.C879 R.sup.D1 R.sup.D195 L.sub.C987 R.sup.D4 R.sup.D195 L.sub.C1095 R.sup.D9 R.sup.D195 L.sub.C772 R.sup.D196 R.sup.D196 L.sub.C880 R.sup.D1 R.sup.D196 L.sub.C988 R.sup.D4 R.sup.D196 L.sub.C1096 R.sup.D9 R.sup.D196 L.sub.C773 R.sup.D197 R.sup.D197 L.sub.C881 R.sup.D1 R.sup.D197 L.sub.C989 R.sup.D4 R.sup.D197 L.sub.C1097 R.sup.D9 R.sup.D197 L.sub.C774 R.sup.D198 R.sup.D198 L.sub.C882 R.sup.D1 R.sup.D198 L.sub.C990 R.sup.D4 R.sup.D198 L.sub.C1098 R.sup.D9 R.sup.D198 L.sub.C775 R.sup.D199 R.sup.D199 L.sub.C883 R.sup.D1 R.sup.D199 L.sub.C991 R.sup.D4 R.sup.D199 L.sub.C1099 R.sup.D9 R.sup.D199 L.sub.C776 R.sup.D200 R.sup.D200 L.sub.C884 R.sup.D1 R.sup.D200 L.sub.C992 R.sup.D4 R.sup.D200 L.sub.C1100 R.sup.D9 R.sup.D200 L.sub.C777 R.sup.D201 R.sup.D201 L.sub.C885 R.sup.D1 R.sup.D201 L.sub.C993 R.sup.D4 R.sup.D201 L.sub.C1101 R.sup.D9 R.sup.D201 L.sub.C778 R.sup.D202 R.sup.D202 L.sub.C886 R.sup.D1 R.sup.D202 L.sub.C994 R.sup.D4 R.sup.D202 L.sub.C1102 R.sup.D9 R.sup.D202 L.sub.C779 R.sup.D203 R.sup.D203 L.sub.C887 R.sup.D1 R.sup.D203 L.sub.C995 R.sup.D4 R.sup.D203 L.sub.C1103 R.sup.D9 R.sup.D203 L.sub.C780 R.sup.D204 R.sup.D204 L.sub.C888 R.sup.D1 R.sup.D204 L.sub.C996 R.sup.D4 R.sup.D204 L.sub.C1104 R.sup.D9 R.sup.D204 L.sub.C781 R.sup.D205 R.sup.D205 L.sub.C889 R.sup.D1 R.sup.D205 L.sub.C997 R.sup.D4 R.sup.D205 L.sub.C1105 R.sup.D9 R.sup.D205 L.sub.C782 R.sup.D206 R.sup.D206 L.sub.C890 R.sup.D1 R.sup.D206 L.sub.C998 R.sup.D4 R.sup.D206 L.sub.C1106 R.sup.D9 R.sup.D206 L.sub.C783 R.sup.D207 R.sup.D207 L.sub.C891 R.sup.D1 R.sup.D207 L.sub.C999 R.sup.D4 R.sup.D207 L.sub.C1107 R.sup.D9 R.sup.D207 L.sub.C784 R.sup.D208 R.sup.D208 L.sub.C892 R.sup.D1 R.sup.D208 L.sub.C1000 R.sup.D4 R.sup.D208 L.sub.C1108 R.sup.D9 R.sup.D208 L.sub.C785 R.sup.D209 R.sup.D209 L.sub.C893 R.sup.D1 R.sup.D209 L.sub.C1001 R.sup.D4 R.sup.D209 L.sub.C1109 R.sup.D9 R.sup.D209 L.sub.C786 R.sup.D210 R.sup.D210 L.sub.C894 R.sup.D1 R.sup.D210 L.sub.C1002 R.sup.D4 R.sup.D210 L.sub.C1110 R.sup.D9 R.sup.D210 L.sub.C787 R.sup.D211 R.sup.D211 L.sub.C895 R.sup.D1 R.sup.D211 L.sub.C1003 R.sup.D4 R.sup.D211 L.sub.C1111 R.sup.D9 R.sup.D211 L.sub.C788 R.sup.D212 R.sup.D212 L.sub.C896 R.sup.D1 R.sup.D212 L.sub.C1004 R.sup.D4 R.sup.D212 L.sub.C1112 R.sup.D9 R.sup.D212 L.sub.C789 R.sup.D213 R.sup.D213 L.sub.C897 R.sup.D1 R.sup.D213 L.sub.C1005 R.sup.D4 R.sup.D213 L.sub.C1113 R.sup.D9 R.sup.D213 L.sub.C790 R.sup.D214 R.sup.D214 L.sub.C898 R.sup.D1 R.sup.D214 L.sub.C1006 R.sup.D4 R.sup.D214 L.sub.C1114 R.sup.D9 R.sup.D214 L.sub.C791 R.sup.D215 R.sup.D215 L.sub.C899 R.sup.D1 R.sup.D215 L.sub.C1007 R.sup.D4 R.sup.D215 L.sub.C1115 R.sup.D9 R.sup.D215 L.sub.C792 R.sup.D216 R.sup.D216 L.sub.C900 R.sup.D1 R.sup.D216 L.sub.C1008 R.sup.D4 R.sup.D216 L.sub.C1116 R.sup.D9 R.sup.D216 L.sub.C793 R.sup.D217 R.sup.D217 L.sub.C901 R.sup.D1 R.sup.D217 L.sub.C1009 R.sup.D4 R.sup.D217 L.sub.C1117 R.sup.D9 R.sup.D217 L.sub.C794 R.sup.D218 R.sup.D218 L.sub.C902 R.sup.D1 R.sup.D218 L.sub.C1010 R.sup.D4 R.sup.D218 L.sub.C1118 R.sup.D9 R.sup.D218 L.sub.C795 R.sup.D219 R.sup.D219 L.sub.C903 R.sup.D1 R.sup.D219 L.sub.C11011 R.sup.D4 R.sup.D219 L.sub.C1119 R.sup.D9 R.sup.D219 L.sub.C796 R.sup.D220 R.sup.D220 L.sub.C904 R.sup.D1 R.sup.D220 L.sub.C1012 R.sup.D4 R.sup.D220 L.sub.C1120 R.sup.D9 R.sup.D220 L.sub.C797 R.sup.D221 R.sup.D221 L.sub.C905 R.sup.D1 R.sup.D221 L.sub.C1013 R.sup.D4 R.sup.D221 L.sub.C1121 R.sup.D9 R.sup.D221 L.sub.C798 R.sup.D222 R.sup.D222 L.sub.C906 R.sup.D1 R.sup.D222 L.sub.C1014 R.sup.D4 R.sup.D222 L.sub.C1122 R.sup.D9 R.sup.D222 L.sub.C799 R.sup.D223 R.sup.D223 L.sub.C907 R.sup.D1 R.sup.D223 L.sub.C1015 R.sup.D4 R.sup.D223 L.sub.C1123 R.sup.D9 R.sup.D223 L.sub.C800 R.sup.D224 R.sup.D224 L.sub.C908 R.sup.D1 R.sup.D224 L.sub.C1016 R.sup.D4 R.sup.D224 L.sub.C1124 R.sup.D9 R.sup.D224 L.sub.C801 R.sup.D225 R.sup.D225 L.sub.C909 R.sup.D1 R.sup.D225 L.sub.C1017 R.sup.D4 R.sup.D225 L.sub.C1125 R.sup.D9 R.sup.D225 L.sub.C802 R.sup.D226 R.sup.D226 L.sub.C910 R.sup.D1 R.sup.D226 L.sub.C1018 R.sup.D4 R.sup.D226 L.sub.C1126 R.sup.D9 R.sup.D226 L.sub.C803 R.sup.D227 R.sup.D227 L.sub.C911 R.sup.D1 R.sup.D227 L.sub.C1019 R.sup.D4 R.sup.D227 L.sub.C1127 R.sup.D9 R.sup.D227 L.sub.C804 R.sup.D228 R.sup.D228 L.sub.C912 R.sup.D1 R.sup.D228 L.sub.C1020 R.sup.D4 R.sup.D228 L.sub.C1128 R.sup.D9 R.sup.D228 L.sub.C805 R.sup.D229 R.sup.D229 L.sub.C913 R.sup.D1 R.sup.D229 L.sub.C1021 R.sup.D4 R.sup.D229 L.sub.C1129 R.sup.D9 R.sup.D229 L.sub.C806 R.sup.D230 R.sup.D230 L.sub.C914 R.sup.D1 R.sup.D230 L.sub.C1022 R.sup.D4 R.sup.D230 L.sub.C1130 R.sup.D9 R.sup.D230 L.sub.C807 R.sup.D231 R.sup.D231 L.sub.C915 R.sup.D1 R.sup.D231 L.sub.C1023 R.sup.D4 R.sup.D231 L.sub.C1131 R.sup.D9 R.sup.D231 L.sub.C808 R.sup.D232 R.sup.D232 L.sub.C916 R.sup.D1 R.sup.D232 L.sub.C1024 R.sup.D4 R.sup.D232 L.sub.C1132 R.sup.D9 R.sup.D232 L.sub.C809 R.sup.D233 R.sup.D233 L.sub.C917 R.sup.D1 R.sup.D233 L.sub.C1025 R.sup.D4 R.sup.D233 L.sub.C1133 R.sup.D9 R.sup.D233 L.sub.C810 R.sup.D234 R.sup.D234 L.sub.C918 R.sup.D1 R.sup.D234 L.sub.C1026 R.sup.D4 R.sup.D234 L.sub.C1134 R.sup.D9 R.sup.D234 L.sub.C811 R.sup.D235 R.sup.D235 L.sub.C919 R.sup.D1 R.sup.D235 L.sub.C1027 R.sup.D4 R.sup.D235 L.sub.C1135 R.sup.D9 R.sup.D235 L.sub.C812 R.sup.D236 R.sup.D236 L.sub.C920 R.sup.D1 R.sup.D236 L.sub.C1028 R.sup.D4 R.sup.D236 L.sub.C1136 R.sup.D9 R.sup.D236 L.sub.C813 R.sup.D237 R.sup.D237 L.sub.C921 R.sup.D1 R.sup.D237 L.sub.C1029 R.sup.D4 R.sup.D237 L.sub.C1137 R.sup.D9 R.sup.D237 L.sub.C814 R.sup.D238 R.sup.D238 L.sub.C922 R.sup.D1 R.sup.D238 L.sub.C1030 R.sup.D4 R.sup.D238 L.sub.C1138 R.sup.D9 R.sup.D238 L.sub.C815 R.sup.D239 R.sup.D239 L.sub.C923 R.sup.D1 R.sup.D239 L.sub.C1031 R.sup.D4 R.sup.D239 L.sub.C1139 R.sup.D9 R.sup.D239 L.sub.C816 R.sup.D240 R.sup.D240 L.sub.C924 R.sup.D1 R.sup.D240 L.sub.C1032 R.sup.D4 R.sup.D240 L.sub.C1140 R.sup.D9 R.sup.D240 L.sub.C817 R.sup.D241 R.sup.D241 L.sub.C925 R.sup.D1 R.sup.D241 L.sub.C1033 R.sup.D4 R.sup.D241 L.sub.C1141 R.sup.D9 R.sup.D241 L.sub.C818 R.sup.D242 R.sup.D242 L.sub.C926 R.sup.D1 R.sup.D242 L.sub.C1034 R.sup.D4 R.sup.D242 L.sub.C1142 R.sup.D9 R.sup.D242 L.sub.C819 R.sup.D243 R.sup.D243 L.sub.C927 R.sup.D1 R.sup.D243 L.sub.C1035 R.sup.D4 R.sup.D243 L.sub.C1143 R.sup.D9 R.sup.D243 L.sub.C820 R.sup.D244 R.sup.D244 L.sub.C928 R.sup.D1 R.sup.D244 L.sub.C1036 R.sup.D4 R.sup.D244 L.sub.C1144 R.sup.D9 R.sup.D244 L.sub.C821 R.sup.D245 R.sup.D245 L.sub.C929 R.sup.D1 R.sup.D245 L.sub.C1037 R.sup.D4 R.sup.D245 L.sub.C1145 R.sup.D9 R.sup.D245 L.sub.C822 R.sup.D246 R.sup.D246 L.sub.C930 R.sup.D1 R.sup.D246 L.sub.C1038 R.sup.D4 R.sup.D246 L.sub.C1146 R.sup.D9 R.sup.D246 L.sub.C823 R.sup.D17 R.sup.D193 L.sub.C931 R.sup.D50 R.sup.D193 L.sub.C1039 R.sup.D145 R.sup.D193 L.sub.C1147 R.sup.D168 R.sup.D193 L.sub.C824 R.sup.D17 R.sup.D194 L.sub.C932 R.sup.D50 R.sup.D194 L.sub.C1040 R.sup.D145 R.sup.D194 L.sub.C1148 R.sup.D168 R.sup.D194 L.sub.C825 R.sup.D17 R.sup.D195 L.sub.C933 R.sup.D50 R.sup.D195 L.sub.C1041 R.sup.D145 R.sup.D195 L.sub.C1149 R.sup.D168 R.sup.D195 L.sub.C826 R.sup.D17 R.sup.D196 L.sub.C934 R.sup.D50 R.sup.D196 L.sub.C1042 R.sup.D145 R.sup.D196 L.sub.C1150 R.sup.D168 R.sup.D196 L.sub.C827 R.sup.D17 R.sup.D197 L.sub.C935 R.sup.D50 R.sup.D197 L.sub.C1043 R.sup.D145 R.sup.D197 L.sub.C1151 R.sup.D168 R.sup.D197 L.sub.C828 R.sup.D17 R.sup.D198 L.sub.C936 R.sup.D50 R.sup.D198 L.sub.C1044 R.sup.D145 R.sup.D198 L.sub.C1152 R.sup.D168 R.sup.D198 L.sub.C829 R.sup.D17 R.sup.D199 L.sub.C937 R.sup.D50 R.sup.D199 L.sub.C1045 R.sup.D145 R.sup.D199 L.sub.C1153 R.sup.D168 R.sup.D199 L.sub.C830 R.sup.D17 R.sup.D200 L.sub.C938 R.sup.D50 R.sup.D200 L.sub.C1046 R.sup.D145 R.sup.D200 L.sub.C1154 R.sup.D168 R.sup.D200 L.sub.C831 R.sup.D17 R.sup.D201 L.sub.C939 R.sup.D50 R.sup.D201 L.sub.C1047 R.sup.D145 R.sup.D201 L.sub.C1155 R.sup.D168 R.sup.D201 L.sub.C832 R.sup.D17 R.sup.D202 L.sub.C940 R.sup.D50 R.sup.D202 L.sub.C1048 R.sup.D145 R.sup.D202 L.sub.C1156 R.sup.D168 R.sup.D202 L.sub.C833 R.sup.D17 R.sup.D203 L.sub.C941 R.sup.D50 R.sup.D203 L.sub.C1049 R.sup.D145 R.sup.D203 L.sub.C1157 R.sup.D168 R.sup.D203 L.sub.C834 R.sup.D17 R.sup.D204 L.sub.C942 R.sup.D50 R.sup.D204 L.sub.C1050 R.sup.D145 R.sup.D204 L.sub.C1158 R.sup.D168 R.sup.D204 L.sub.C835 R.sup.D17 R.sup.D205 L.sub.C943 R.sup.D50 R.sup.D205 L.sub.C1051 R.sup.D145 R.sup.D205 L.sub.C1159 R.sup.D168 R.sup.D205 L.sub.C836 R.sup.D17 R.sup.D206 L.sub.C944 R.sup.D50 R.sup.D206 L.sub.C1052 R.sup.D145 R.sup.D206 L.sub.C1160 R.sup.D168 R.sup.D206 L.sub.C837 R.sup.D17 R.sup.D207 L.sub.C945 R.sup.D50 R.sup.D207 L.sub.C1053 R.sup.D145 R.sup.D207 L.sub.C1161 R.sup.D168 R.sup.D207 L.sub.C838 R.sup.D17 R.sup.D208 L.sub.C946 R.sup.D50 R.sup.D208 L.sub.C1054 R.sup.D145 R.sup.D208 L.sub.C1162 R.sup.D168 R.sup.D208 L.sub.C839 R.sup.D17 R.sup.D209 L.sub.C947 R.sup.D50 R.sup.D209 L.sub.C1055 R.sup.D145 R.sup.D209 L.sub.C1163 R.sup.D168 R.sup.D209 L.sub.C840 R.sup.D17 R.sup.D210 L.sub.C948 R.sup.D50 R.sup.D210 L.sub.C1056 R.sup.D145 R.sup.D210 L.sub.C1164 R.sup.D168 R.sup.D210 L.sub.C841 R.sup.D17 R.sup.D211 L.sub.C949 R.sup.D50 R.sup.D211 L.sub.C1057 R.sup.D145 R.sup.D211 L.sub.C1165 R.sup.D168 R.sup.D211 L.sub.C842 R.sup.D17 R.sup.D212 L.sub.C950 R.sup.D50 R.sup.D212 L.sub.C1058 R.sup.D145 R.sup.D212 L.sub.C1166 R.sup.D168 R.sup.D212 L.sub.C843 R.sup.D17 R.sup.D213 L.sub.C951 R.sup.D50 R.sup.D213 L.sub.C1059 R.sup.D145 R.sup.D213 L.sub.C1167 R.sup.D168 R.sup.D213 L.sub.C844 R.sup.D17 R.sup.D214 L.sub.C952 R.sup.D50 R.sup.D214 L.sub.C1060 R.sup.D145 R.sup.D214 L.sub.C1168 R.sup.D168 R.sup.D214 L.sub.C845 R.sup.D17 R.sup.D215 L.sub.C953 R.sup.D50 R.sup.D215 L.sub.C1061 R.sup.D145 R.sup.D215 L.sub.C1169 R.sup.D168 R.sup.D215 L.sub.C846 R.sup.D17 R.sup.D216 L.sub.C954 R.sup.D50 R.sup.D216 L.sub.C1062 R.sup.D145 R.sup.D216 L.sub.C1170 R.sup.D168 R.sup.D216 L.sub.C847 R.sup.D17 R.sup.D217 L.sub.C955 R.sup.D50 R.sup.D217 L.sub.C1063 R.sup.D145 R.sup.D217 L.sub.C1171 R.sup.D168 R.sup.D217 L.sub.C848 R.sup.D17 R.sup.D218 L.sub.C956 R.sup.D50 R.sup.D218 L.sub.C1064 R.sup.D145 R.sup.D218 L.sub.C1172 R.sup.D168 R.sup.D218 L.sub.C849 R.sup.D17 R.sup.D219 L.sub.C957 R.sup.D50 R.sup.D219 L.sub.C1065 R.sup.D145 R.sup.D219 L.sub.C1173 R.sup.D168 R.sup.D219 L.sub.C850 R.sup.D17 R.sup.D220 L.sub.C958 R.sup.D50 R.sup.D220 L.sub.C1066 R.sup.D145 R.sup.D220 L.sub.C1174 R.sup.D168 R.sup.D220 L.sub.C851 R.sup.D17 R.sup.D221 L.sub.C959 R.sup.D50 R.sup.D221 L.sub.C1067 R.sup.D145 R.sup.D221 L.sub.C1175 R.sup.D168 R.sup.D221 L.sub.C852 R.sup.D17 R.sup.D222 L.sub.C960 R.sup.D50 R.sup.D222 L.sub.C1068 R.sup.D145 R.sup.D222 L.sub.C1176 R.sup.D168 R.sup.D222 L.sub.C853 R.sup.D17 R.sup.D223 L.sub.C961 R.sup.D50 R.sup.D223 L.sub.C1069 R.sup.D145 R.sup.D223 L.sub.C1177 R.sup.D168 R.sup.D223 L.sub.C854 R.sup.D17 R.sup.D224 L.sub.C962 R.sup.D50 R.sup.D224 L.sub.C1070 R.sup.D145 R.sup.D224 L.sub.C1178 R.sup.D168 R.sup.D224 L.sub.C855 R.sup.D17 R.sup.D225 L.sub.C963 R.sup.D50 R.sup.D225 L.sub.C1071 R.sup.D145 R.sup.D225 L.sub.C1179 R.sup.D168 R.sup.D225 L.sub.C856 R.sup.D17 R.sup.D226 L.sub.C964 R.sup.D50 R.sup.D226 L.sub.C1072 R.sup.D145 R.sup.D226 L.sub.C1180 R.sup.D168 R.sup.D226 L.sub.C857 R.sup.D17 R.sup.D227 L.sub.C965 R.sup.D50 R.sup.D227 L.sub.C1073 R.sup.D145 R.sup.D227 L.sub.C1181 R.sup.D168 R.sup.D227 L.sub.C858 R.sup.D17 R.sup.D228 L.sub.C966 R.sup.D50 R.sup.D228 L.sub.C1074 R.sup.D145 R.sup.D228 L.sub.C1182 R.sup.D168 R.sup.D228 L.sub.C859 R.sup.D17 R.sup.D229 L.sub.C967 R.sup.D50 R.sup.D229 L.sub.C1075 R.sup.D145 R.sup.D229 L.sub.C1183 R.sup.D168 R.sup.D229 L.sub.C860 R.sup.D17 R.sup.D230 L.sub.C968 R.sup.D50 R.sup.D230 L.sub.C1076 R.sup.D145 R.sup.D230 L.sub.C1184 R.sup.D168 R.sup.D230 L.sub.C861 R.sup.D17 R.sup.D231 L.sub.C969 R.sup.D50 R.sup.D231 L.sub.C1077 R.sup.D145 R.sup.D231 L.sub.C1185 R.sup.D168 R.sup.D231 L.sub.C862 R.sup.D17 R.sup.D232 L.sub.C970 R.sup.D50 R.sup.D232 L.sub.C1078 R.sup.D145 R.sup.D232 L.sub.C1186 R.sup.D168 R.sup.D232 L.sub.C863 R.sup.D17 R.sup.D233 L.sub.C971 R.sup.D50 R.sup.D233 L.sub.C1079 R.sup.D145 R.sup.D233 L.sub.C1187 R.sup.D168 R.sup.D233 L.sub.C864 R.sup.D17 R.sup.D234 L.sub.C972 R.sup.D50 R.sup.D234 L.sub.C1080 R.sup.D145 R.sup.D234 L.sub.C1188 R.sup.D168 R.sup.D234 L.sub.C865 R.sup.D17 R.sup.D235 L.sub.C973 R.sup.D50 R.sup.D235 L.sub.C1081 R.sup.D145 R.sup.D235 L.sub.C1189 R.sup.D168 R.sup.D235 L.sub.C866 R.sup.D17 R.sup.D236 L.sub.C974 R.sup.D50 R.sup.D236 L.sub.C1082 R.sup.D145 R.sup.D236 L.sub.C1190 R.sup.D168 R.sup.D236 L.sub.C867 R.sup.D17 R.sup.D237 L.sub.C975 R.sup.D50 R.sup.D237 L.sub.C1083 R.sup.D145 R.sup.D237 L.sub.C1191 R.sup.D168 R.sup.D237 L.sub.C868 R.sup.D17 R.sup.D238 L.sub.C976 R.sup.D50 R.sup.D238 L.sub.C1084 R.sup.D145 R.sup.D238 L.sub.C1192 R.sup.D168 R.sup.D238 L.sub.C869 R.sup.D17 R.sup.D239 L.sub.C977 R.sup.D50 R.sup.D239 L.sub.C1085 R.sup.D145 R.sup.D239 L.sub.C1193 R.sup.D168 R.sup.D239 L.sub.C870 R.sup.D17 R.sup.D240 L.sub.C978 R.sup.D50 R.sup.D240 L.sub.C1086 R.sup.D145 R.sup.D240 L.sub.C1194 R.sup.D168 R.sup.D240 L.sub.C871 R.sup.D17 R.sup.D241 L.sub.C979 R.sup.D50 R.sup.D241 L.sub.C1087 R.sup.D145 R.sup.D241 L.sub.C1195 R.sup.D168 R.sup.D241 L.sub.C872 R.sup.D17 R.sup.D242 L.sub.C980 R.sup.D50 R.sup.D242 L.sub.C1088 R.sup.D145 R.sup.D242 L.sub.C1196 R.sup.D168 R.sup.D242 L.sub.C873 R.sup.D17 R.sup.D243 L.sub.C981 R.sup.D50 R.sup.D243 L.sub.C1089 R.sup.D145 R.sup.D243 L.sub.C1197 R.sup.D168 R.sup.D243 L.sub.C874 R.sup.D17 R.sup.D244 L.sub.C982 R.sup.D50 R.sup.D244 L.sub.C1090 R.sup.D145 R.sup.D244 L.sub.C1198 R.sup.D168 R.sup.D244 L.sub.C875 R.sup.D17 R.sup.D245 L.sub.C983 R.sup.D50 R.sup.D245 L.sub.C1091 R.sup.D145 R.sup.D245 L.sub.C1199 R.sup.D168 R.sup.D245 L.sub.C876 R.sup.D17 R.sup.D246 L.sub.C984 R.sup.D50 R.sup.D246 L.sub.C1092 R.sup.D145 R.sup.D246 L.sub.C1200 R.sup.D168 R.sup.D246 L.sub.C1201 R.sup.D10 R.sup.D193 L.sub.C1255 R.sup.D55 R.sup.D193 L.sub.C1309 R.sup.D37 R.sup.D193 L.sub.C1363 R.sup.D143 R.sup.D193 L.sub.C1202 R.sup.D10 R.sup.D194 L.sub.C1256 R.sup.D55 R.sup.D194 L.sub.C1310 R.sup.D37 R.sup.D194 L.sub.C1364 R.sup.D143 R.sup.D194 L.sub.C1203 R.sup.D10 R.sup.D195 L.sub.C1257 R.sup.D55 R.sup.D195 L.sub.C1311 R.sup.D37 R.sup.D195 L.sub.C1365 R.sup.D143 R.sup.D195 L.sub.C1204 R.sup.D10 R.sup.D196 L.sub.C1258 R.sup.D55 R.sup.D196 L.sub.C1312 R.sup.D37 R.sup.D196 L.sub.C1366 R.sup.D143 R.sup.D196 L.sub.C1205 R.sup.D10 R.sup.D197 L.sub.C1259 R.sup.D55 R.sup.D197 L.sub.C1313 R.sup.D37 R.sup.D197 L.sub.C1367 R.sup.D143 R.sup.D197 L.sub.C1206 R.sup.D10 R.sup.D198 L.sub.C1260 R.sup.D55 R.sup.D198 L.sub.C1314 R.sup.D37 R.sup.D198 L.sub.C1368 R.sup.D143 R.sup.D198 L.sub.C1207 R.sup.D10 R.sup.D199 L.sub.C1261 R.sup.D55 R.sup.D199 L.sub.C1315 R.sup.D37 R.sup.D199 L.sub.C1369 R.sup.D143 R.sup.D199 L.sub.C1208 R.sup.D10 R.sup.D200 L.sub.C1262 R.sup.D55 R.sup.D200 L.sub.C1316 R.sup.D37 R.sup.D200 L.sub.C1370 R.sup.D143 R.sup.D200 L.sub.C1209 R.sup.D10 R.sup.D201 L.sub.C1263 R.sup.D55 R.sup.D201 L.sub.C1317 R.sup.D37 R.sup.D201 L.sub.C1371 R.sup.D143 R.sup.D201 L.sub.C1210 R.sup.D10 R.sup.D202 L.sub.C1264 R.sup.D55 R.sup.D202 L.sub.C1318 R.sup.D37 R.sup.D202 L.sub.C1372 R.sup.D143 R.sup.D202 L.sub.C1211 R.sup.D10 R.sup.D203 L.sub.C1265 R.sup.D55 R.sup.D203 L.sub.C1319 R.sup.D37 R.sup.D203 L.sub.C1373 R.sup.D143 R.sup.D203 L.sub.C1212 R.sup.D10 R.sup.D204 L.sub.C1266 R.sup.D55 R.sup.D204 L.sub.C1320 R.sup.D37 R.sup.D204 L.sub.C1374 R.sup.D143 R.sup.D204 L.sub.C1213 R.sup.D10 R.sup.D205 L.sub.C1267 R.sup.D55 R.sup.D205 L.sub.C1321 R.sup.D37 R.sup.D205 L.sub.C1375 R.sup.D143 R.sup.D205 L.sub.C1214 R.sup.D10 R.sup.D206 L.sub.C1268 R.sup.D55 R.sup.D206 L.sub.C1322 R.sup.D37 R.sup.D206 L.sub.C1376 R.sup.D143 R.sup.D206 L.sub.C1215 R.sup.D10 R.sup.D207 L.sub.C1269 R.sup.D55 R.sup.D207 L.sub.C1323 R.sup.D37 R.sup.D207 L.sub.C1377 R.sup.D143 R.sup.D207 L.sub.C1216 R.sup.D10 R.sup.D208 L.sub.C1270 R.sup.D55 R.sup.D208 L.sub.C1324 R.sup.D37 R.sup.D208 L.sub.C1378 R.sup.D143 R.sup.D208 L.sub.C1217 R.sup.D10 R.sup.D209 L.sub.C1271 R.sup.D55 R.sup.D209 L.sub.C1325 R.sup.D37 R.sup.D209 L.sub.C1379 R.sup.D143 R.sup.D209 L.sub.C1218 R.sup.D10 R.sup.D210 L.sub.C1272 R.sup.D55 R.sup.D210 L.sub.C1326 R.sup.D37 R.sup.D210 L.sub.C1380 R.sup.D143 R.sup.D210 L.sub.C1219 R.sup.D10 R.sup.D211 L.sub.C1273 R.sup.D55 R.sup.D211 L.sub.C1327 R.sup.D37 R.sup.D211 L.sub.C1381 R.sup.D143 R.sup.D211 L.sub.C1220 R.sup.D10 R.sup.D212 L.sub.C1274 R.sup.D55 R.sup.D212 L.sub.C1328 R.sup.D37 R.sup.D212 L.sub.C1382 R.sup.D143 R.sup.D212 L.sub.C1221 R.sup.D10 R.sup.D213 L.sub.C1275 R.sup.D55 R.sup.D213 L.sub.C1329 R.sup.D37 R.sup.D213 L.sub.C1383 R.sup.D143 R.sup.D213 L.sub.C1222 R.sup.D10 R.sup.D214 L.sub.C1276 R.sup.D55 R.sup.D214 L.sub.C1330 R.sup.D37 R.sup.D214 L.sub.C1384 R.sup.D143 R.sup.D214 L.sub.C1223 R.sup.D10 R.sup.D215 L.sub.C1277 R.sup.D55 R.sup.D215 L.sub.C1331 R.sup.D37 R.sup.D215 L.sub.C1385 R.sup.D143 R.sup.D215 L.sub.C1224 R.sup.D10 R.sup.D216 L.sub.C1278 R.sup.D55 R.sup.D216 L.sub.C1332 R.sup.D37 R.sup.D216 L.sub.C1386 R.sup.D143 R.sup.D216 L.sub.C1225 R.sup.D10 R.sup.D217 L.sub.C1279 R.sup.D55 R.sup.D217 L.sub.C1333 R.sup.D37 R.sup.D217 L.sub.C1387 R.sup.D143 R.sup.D217 L.sub.C1226 R.sup.D10 R.sup.D218 L.sub.C1280 R.sup.D55 R.sup.D218 L.sub.C1334 R.sup.D37 R.sup.D218 L.sub.C1388 R.sup.D143 R.sup.D218 L.sub.C1227 R.sup.D10 R.sup.D219 L.sub.C1281 R.sup.D55 R.sup.D219 L.sub.C1335 R.sup.D37 R.sup.D219 L.sub.C1389 R.sup.D143 R.sup.D219 L.sub.C1228 R.sup.D10 R.sup.D220 L.sub.C1282 R.sup.D55 R.sup.D220 L.sub.C1336 R.sup.D37 R.sup.D220 L.sub.C1390 R.sup.D143 R.sup.D220 L.sub.C1229 R.sup.D10 R.sup.D221 L.sub.C1283 R.sup.D55 R.sup.D221 L.sub.C1337 R.sup.D37 R.sup.D221 L.sub.C1391 R.sup.D143 R.sup.D221 L.sub.C1230 R.sup.D10 R.sup.D222 L.sub.C1284 R.sup.D55 R.sup.D222 L.sub.C1338 R.sup.D37 R.sup.D222 L.sub.C1392 R.sup.D143 R.sup.D222 L.sub.C1231 R.sup.D10 R.sup.D223 L.sub.C1285 R.sup.D55 R.sup.D223 L.sub.C1339 R.sup.D37 R.sup.D223 L.sub.C1393 R.sup.D143 R.sup.D223 L.sub.C1232 R.sup.D10 R.sup.D224 L.sub.C1286 R.sup.D55 R.sup.D224 L.sub.C1340 R.sup.D37 R.sup.D224 L.sub.C1394 R.sup.D143 R.sup.D224 L.sub.C1233 R.sup.D10 R.sup.D225 L.sub.C1287 R.sup.D55 R.sup.D225 L.sub.C1341 R.sup.D37 R.sup.D225 L.sub.C1395 R.sup.D143 R.sup.D225 L.sub.C1234 R.sup.D10 R.sup.D226 L.sub.C1288 R.sup.D55 R.sup.D226 L.sub.C1342 R.sup.D37 R.sup.D226 L.sub.C1396 R.sup.D143 R.sup.D226 L.sub.C1235 R.sup.D10 R.sup.D227 L.sub.C1289 R.sup.D55 R.sup.D227 L.sub.C1343 R.sup.D37 R.sup.D227 L.sub.C1397 R.sup.D143 R.sup.D227 L.sub.C1236 R.sup.D10 R.sup.D228 L.sub.C1290 R.sup.D55 R.sup.D228 L.sub.C1344 R.sup.D37 R.sup.D228 L.sub.C1398 R.sup.D143 R.sup.D228 L.sub.C1237 R.sup.D10 R.sup.D229 L.sub.C1291 R.sup.D55 R.sup.D229 L.sub.C1345 R.sup.D37 R.sup.D229 L.sub.C1399 R.sup.D143 R.sup.D229 L.sub.C1238 R.sup.D10 R.sup.D230 L.sub.C1292 R.sup.D55 R.sup.D230 L.sub.C1346 R.sup.D37 R.sup.D230 L.sub.C1400 R.sup.D143 R.sup.D230 L.sub.C1239 R.sup.D10 R.sup.D231 L.sub.C1293 R.sup.D55 R.sup.D231 L.sub.C1347 R.sup.D37 R.sup.D231 L.sub.C1401 R.sup.D143 R.sup.D231 L.sub.C1240 R.sup.D10 R.sup.D232 L.sub.C1294 R.sup.D55 R.sup.D232 L.sub.C1348 R.sup.D37 R.sup.D232 L.sub.C1402 R.sup.D143 R.sup.D232 L.sub.C1241 R.sup.D10 R.sup.D233 L.sub.C1295 R.sup.D55 R.sup.D233 L.sub.C1349 R.sup.D37 R.sup.D233 L.sub.C1403 R.sup.D143 R.sup.D233 L.sub.C1242 R.sup.D10 R.sup.D234 L.sub.C1296 R.sup.D55 R.sup.D234 L.sub.C1350 R.sup.D37 R.sup.D234 L.sub.C1404 R.sup.D143 R.sup.D234 L.sub.C1243 R.sup.D10 R.sup.D235 L.sub.C1297 R.sup.D55 R.sup.D235 L.sub.C1351 R.sup.D37 R.sup.D235 L.sub.C1405 R.sup.D143 R.sup.D235 L.sub.C1244 R.sup.D10 R.sup.D236 L.sub.C1298 R.sup.D55 R.sup.D236 L.sub.C1352 R.sup.D37 R.sup.D236 L.sub.C1406 R.sup.D143 R.sup.D236 L.sub.C1245 R.sup.D10 R.sup.D237 L.sub.C1299 R.sup.D55 R.sup.D237 L.sub.C1353 R.sup.D37 R.sup.D237 L.sub.C1407 R.sup.D143 R.sup.D237 L.sub.C1246 R.sup.D10 R.sup.D238 L.sub.C1300 R.sup.D55 R.sup.D238 L.sub.C1354 R.sup.D37 R.sup.D238 L.sub.C1408 R.sup.D143 R.sup.D238 L.sub.C1247 R.sup.D10 R.sup.D239 L.sub.C1301 R.sup.D55 R.sup.D239 L.sub.C1355 R.sup.D37 R.sup.D239 L.sub.C1409 R.sup.D143 R.sup.D239 L.sub.C1248 R.sup.D10 R.sup.D240 L.sub.C1302 R.sup.D55 R.sup.D240 L.sub.C1356 R.sup.D37 R.sup.D240 L.sub.C1410 R.sup.D143 R.sup.D240 L.sub.C1249 R.sup.D10 R.sup.D241 L.sub.C1303 R.sup.D55 R.sup.D241 L.sub.C1357 R.sup.D37 R.sup.D241 L.sub.C1411 R.sup.D143 R.sup.D241 L.sub.C1250 R.sup.D10 R.sup.D242 L.sub.C1304 R.sup.D55 R.sup.D242 L.sub.C1358 R.sup.D37 R.sup.D242 L.sub.C1412 R.sup.D143 R.sup.D242 L.sub.C1251 R.sup.D10 R.sup.D243 L.sub.C1305 R.sup.D55 R.sup.D243 L.sub.C1359 R.sup.D37 R.sup.D243 L.sub.C1413 R.sup.D143 R.sup.D243 L.sub.C1252 R.sup.D10 R.sup.D244 L.sub.C1306 R.sup.D55 R.sup.D244 L.sub.C1360 R.sup.D37 R.sup.D244 L.sub.C1414 R.sup.D143 R.sup.D244 L.sub.C1253 R.sup.D10 R.sup.D245 L.sub.C1307 R.sup.D55 R.sup.D245 L.sub.C1361 R.sup.D37 R.sup.D245 L.sub.C1415 R.sup.D143 R.sup.D245 L.sub.C1254 R.sup.D10 R.sup.D246 L.sub.C1308 R.sup.D55 R.sup.D246 L.sub.C1362 R.sup.D37 R.sup.D246 L.sub.C1416 R.sup.D143 R.sup.D246 wherein R.sup.D1 to R.sup.D246 have the following structures: ##STR00326## ##STR00327## ##STR00328## ##STR00329## ##STR00330## ##STR00331## ##STR00332## ##STR00333## ##STR00334## ##STR00335## ##STR00336## ##STR00337## ##STR00338## ##STR00339## ##STR00340## ##STR00341## ##STR00342## ##STR00343## ##STR00344## ##STR00345## ##STR00346## ##STR00347## ##STR00348## ##STR00349## ##STR00350## ##STR00351## ##STR00352##
13. The OLED of claim 12, wherein the first emitter is selected from the group consisting of: (L.sub.B1-1).sub.2Ir(L.sub.C1-I) to (L.sub.B4-1170).sub.2Ir(L.sub.C1416-I) based on the general formula (L.sub.Bp-h).sub.2Ir(L.sub.Cj-I), and (L.sub.B1-1).sub.2Ir(L.sub.C1-II) to (L.sub.B4-1170).sub.2Ir(L.sub.C1416-II) based on the general formula (L.sub.Bp-h).sub.2Ir(L.sub.Cj-II); wherein p is an integer from 1 to 4, and h is an integer from 1 to 1170.
14. The OLED of claim 1, wherein the first host has the formula of G.sup.D-L-G.sup.A; and L is a direct bond or an organic linker; wherein each of the at least one donor group G.sup.D independently comprises at least one moiety selected from the group consisting of amino, indole, carbazole, benzothiophene, benzofuran, benzoselenophene, dibenzothiophene, dibenzofuran, and dibenzoselenophene; and wherein each of the at least one acceptor group G.sup.A independently comprises at least one moiety selected from the group consisting of nitrile, isonitrile, fluoride, a six-membered aromatic ring having at least one nitrogen, and a 5-membered aromatic ring having at least two heteroatoms.
15. The OLED of claim 1, wherein each of the at least one donor group G.sup.D independently comprises at least one moiety selected from the group consisting of: ##STR00353## wherein X is selected from the group consisting of O, S, Se, and NR; and wherein each R is independently selected from (i) G.sup.A, (ii) an organic linker bonded to G.sup.A, and (iii) a terminal group selected from the group consisting of alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, aryl, heteroaryl, and combinations thereof; and wherein each of the at least one acceptor group G.sup.A independently comprises at least one moiety selected from the group consisting of nitrile, isonitrile, borane, fluoride, pyridine, pyrimidine, pyrazine, triazine, aza-carbazole, aza-dibenzothiophene, aza-dibenzofuran, aza-dibenzoselenophene, aza-triphenylene, imidazole, pyrazole, oxazole, thiazole, isoxazole, isothiazole, triazole, thiadiazole, and oxadiazole.
16. The OLED of claim 1, wherein the first host comprises at least two donor groups G.sup.D; and at least two acceptor groups G.sup.A; wherein each donor group G.sup.D and acceptor group G.sup.A can be the same or different; wherein any pair of donor groups G.sup.D is separated by at least one acceptor group G.sup.A; and wherein any pair of acceptor groups G.sup.A is separated by at least one donor group G.sup.D.
17. The OLED of claim 1, wherein each of the at least one donor group G.sup.D is independently selected from the group consisting of: ##STR00354## ##STR00355## ##STR00356## ##STR00357## ##STR00358## ##STR00359## ##STR00360## ##STR00361## ##STR00362## ##STR00363## ##STR00364## ##STR00365## ##STR00366## ##STR00367## ##STR00368## ##STR00369## ##STR00370## ##STR00371## ##STR00372## wherein each donor group G.sup.D is at least monovalent; and wherein, in structures containing a dashed line, the dashed line represents a bond to a linker or an acceptor group G.sup.A; and wherein each of the at least one acceptor group G.sup.A is independently selected from the group consisting of: ##STR00373## ##STR00374## ##STR00375## ##STR00376## ##STR00377## ##STR00378## wherein each acceptor group G.sup.A is at least monovalent; and wherein, in structures containing a dashed line, the dashed line represents a bond to a linker or a donor group G.sup.D.
18. The OLED of claim 1, wherein the first host is selected from the group consisting of: ##STR00379## ##STR00380## ##STR00381## ##STR00382## ##STR00383## ##STR00384## ##STR00385## ##STR00386## ##STR00387## ##STR00388## ##STR00389## ##STR00390## ##STR00391## ##STR00392## ##STR00393## ##STR00394##
19. An emissive layer comprising: a first host; and a first emitter; wherein the first emitter is selected from the group consisting of (L.sup.1-L.sup.2).sub.nIr(L.sub.A).sub.3−n and (L.sub.B).sub.nIr(L.sup.3-L.sup.4).sub.3−n; wherein (L.sup.1-L.sup.2).sub.nIr(L.sub.A).sub.3−n is ##STR00395## and (L.sub.B).sub.nIr(L.sup.3-L.sup.4).sub.3−n is ##STR00396## wherein each R.sup.S11, R.sup.S12, and R.sup.S13 independently represents zero, mono, or up to a maximum allowed substitution to its associated ring; wherein each L.sup.1-L.sup.2 and L.sup.3-L.sup.4 independently represents an anionic bidentate ligand; wherein n is 1 or 2; wherein each R.sup.S1, R.sup.S2, R.sup.S3, R.sup.S4, R.sup.S5, R.sup.S6, is independently selected from the group consisting of alkyl, cycloalkyl, partially or fully fluorinated variants thereof, partially or fully deuterated variants thereof, and combinations thereof; wherein each R.sup.S11, R.sup.S12, and R.sup.S13 is independently a hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, boryl, and combinations thereof; wherein at least one of R.sup.S11, R.sup.S12, and R.sup.S13 is selected from the group consisting of deuterium, silyl, C1 to C3 alkyl, substituted or unsubstituted cycloalkyl, and a branch substituted or unsubstituted alkyl with the branching occurs at the benzylic position; and wherein the first host comprises at least one donor group G.sup.D, and at least one acceptor group G.sup.A.
20. A consumer product comprising an organic light emitting device (OLED), comprising: an anode; a cathode; and an organic emissive layer disposed between the anode and the cathode comprising: a first host; and a first emitter; wherein the first emitter is selected from the group consisting of (L.sup.1-L.sup.2).sub.nIr(L.sub.A).sub.3−n and (L.sub.B).sub.nIr(L.sup.3-L.sup.4).sub.3−n; wherein (L.sup.1-L.sup.2).sub.nIr(L.sub.A).sub.3−n is ##STR00397## and (L.sub.B).sub.nIr(L.sup.3-L.sup.4).sub.3−n is ##STR00398## wherein each R.sup.S11, R.sup.S12, and R.sup.S13 independently represents zero, mono, or up to a maximum allowed substitution to its associated ring; wherein each L.sup.1-L.sup.2 and L.sup.3-L.sup.4 independently represents an anionic bidentate ligand; wherein n is 1 or 2; wherein each R.sup.S1, R.sup.S2, R.sup.S3, R.sup.S4, R.sup.S5, R.sup.S6, is independently selected from the group consisting of alkyl, cycloalkyl, partially or fully fluorinated variants thereof, partially or fully deuterated variants thereof, and combinations thereof; wherein each R.sup.S11, R.sup.S12, R.sup.S13 is independently a hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, boryl, and combinations thereof; wherein at least one of R.sup.S11, R.sup.S12, and R.sup.S13 is selected from the group consisting of deuterium, silyl, C1 to C3 alkyl, substituted or unsubstituted cycloalkyl, and a branch substituted or unsubstituted alkyl with the branching occurs at the benzylic position; and wherein the first host comprises at least one donor group G.sup.D, and at least one acceptor group G.sup.A.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0009]
[0010]
DETAILED DESCRIPTION
A. Terminology
[0011] Unless otherwise specified, the below terms used herein are defined as follows:
[0012] As used herein, the term “organic” includes polymeric materials as well as small molecule organic materials that may be used to fabricate organic opto-electronic devices. “Small molecule” refers to any organic material that is not a polymer, and “small molecules” may actually be quite large. Small molecules may include repeat units in some circumstances. For example, using a long chain alkyl group as a substituent does not remove a molecule from the “small molecule” class. Small molecules may also be incorporated into polymers, for example as a pendent group on a polymer backbone or as a part of the backbone. Small molecules may also serve as the core moiety of a dendrimer, which consists of a series of chemical shells built on the core moiety. The core moiety of a dendrimer may be a fluorescent or phosphorescent small molecule emitter. A dendrimer may be a “small molecule,” and it is believed that all dendrimers currently used in the field of OLEDs are small molecules.
[0013] As used herein, “top” means furthest away from the substrate, while “bottom” means closest to the substrate. Where a first layer is described as “disposed over” a second layer, the first layer is disposed further away from substrate. There may be other layers between the first and second layer, unless it is specified that the first layer is “in contact with” the second layer. For example, a cathode may be described as “disposed over” an anode, even though there are various organic layers in between.
[0014] As used herein, “solution processable” means capable of being dissolved, dispersed, or transported in and/or deposited from a liquid medium, either in solution or suspension form.
[0015] A ligand may be referred to as “photoactive” when it is believed that the ligand directly contributes to the photoactive properties of an emissive material. A ligand may be referred to as “ancillary” when it is believed that the ligand does not contribute to the photoactive properties of an emissive material, although an ancillary ligand may alter the properties of a photoactive ligand.
[0016] As used herein, and as would be generally understood by one skilled in the art, a first “Highest Occupied Molecular Orbital” (HOMO) or “Lowest Unoccupied Molecular Orbital” (LUMO) energy level is “greater than” or “higher than” a second HOMO or LUMO energy level if the first energy level is closer to the vacuum energy level. Since ionization potentials (IP) are measured as a negative energy relative to a vacuum level, a higher HOMO energy level corresponds to an IP having a smaller absolute value (an IP that is less negative). Similarly, a higher LUMO energy level corresponds to an electron affinity (EA) having a smaller absolute value (an EA that is less negative). On a conventional energy level diagram, with the vacuum level at the top, the LUMO energy level of a material is higher than the HOMO energy level of the same material. A “higher” HOMO or LUMO energy level appears closer to the top of such a diagram than a “lower” HOMO or LUMO energy level.
[0017] As used herein, and as would be generally understood by one skilled in the art, a first work function is “greater than” or “higher than” a second work function if the first work function has a higher absolute value. Because work functions are generally measured as negative numbers relative to vacuum level, this means that a “higher” work function is more negative. On a conventional energy level diagram, with the vacuum level at the top, a “higher” work function is illustrated as further away from the vacuum level in the downward direction. Thus, the definitions of HOMO and LUMO energy levels follow a different convention than work functions.
[0018] The terms “halo,” “halogen,” and “halide” are used interchangeably and refer to fluorine, chlorine, bromine, and iodine.
[0019] The term “acyl” refers to a substituted carbonyl radical (C(O)—R.sub.s).
[0020] The term “ester” refers to a substituted oxycarbonyl (—O—C(O)—R.sub.s or —C(O)—O—R.sub.s) radical.
[0021] The term “ether” refers to an —OR.sub.s radical.
[0022] The terms “sulfanyl” or “thio-ether” are used interchangeably and refer to a —SR.sub.s radical.
[0023] The term “sulfinyl” refers to a —S(O)—R.sub.s radical.
[0024] The term “sulfonyl” refers to a —SO.sub.2—R.sub.s radical.
[0025] The term “phosphino” refers to a —P(R.sub.s).sub.3 radical, wherein each R.sub.s can be same or different.
[0026] The term “silyl” refers to a —Si(R.sub.s).sub.3 radical, wherein each R.sub.s can be same or different.
[0027] The term “boryl” refers to a —B(R.sub.s).sub.2 radical or its Lewis adduct —B(R.sub.s).sub.3 radical, wherein R.sub.s can be same or different.
[0028] In each of the above, R.sub.s can be hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, and combination thereof. Preferred R.sub.s is selected from the group consisting of alkyl, cycloalkyl, aryl, heteroaryl, and combination thereof.
[0029] The term “alkyl” refers to and includes both straight and branched chain alkyl radicals. Preferred alkyl groups are those containing from one to fifteen carbon atoms and includes methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl, and the like. Additionally, the alkyl group may be optionally substituted.
[0030] The term “cycloalkyl” refers to and includes monocyclic, polycyclic, and spiro alkyl radicals. Preferred cycloalkyl groups are those containing 3 to 12 ring carbon atoms and includes cyclopropyl, cyclopentyl, cyclohexyl, bicyclo[3.1.1]heptyl, spiro[4.5]decyl, spiro[5.5]undecyl, adamantyl, and the like. Additionally, the cycloalkyl group may be optionally substituted.
[0031] The terms “heteroalkyl” or “heterocycloalkyl” refer to an alkyl or a cycloalkyl radical, respectively, having at least one carbon atom replaced by a heteroatom. Optionally the at least one heteroatom is selected from O, S, N, P, B, Si and Se, preferably, O, S or N. Additionally, the heteroalkyl or heterocycloalkyl group may be optionally substituted.
[0032] The term “alkenyl” refers to and includes both straight and branched chain alkene radicals. Alkenyl groups are essentially alkyl groups that include at least one carbon-carbon double bond in the alkyl chain Cycloalkenyl groups are essentially cycloalkyl groups that include at least one carbon-carbon double bond in the cycloalkyl ring. The term “heteroalkenyl” as used herein refers to an alkenyl radical having at least one carbon atom replaced by a heteroatom. Optionally the at least one heteroatom is selected from O, S, N, P, B, Si, and Se, preferably, O, S, or N. Preferred alkenyl, cycloalkenyl, or heteroalkenyl groups are those containing two to fifteen carbon atoms. Additionally, the alkenyl, cycloalkenyl, or heteroalkenyl group may be optionally substituted.
[0033] The term “alkynyl” refers to and includes both straight and branched chain alkyne radicals. Alkynyl groups are essentially alkyl groups that include at least one carbon-carbon triple bond in the alkyl chain. Preferred alkynyl groups are those containing two to fifteen carbon atoms. Additionally, the alkynyl group may be optionally substituted.
[0034] The terms “aralkyl” or “arylalkyl” are used interchangeably and refer to an alkyl group that is substituted with an aryl group. Additionally, the aralkyl group may be optionally substituted.
[0035] The term “heterocyclic group” refers to and includes aromatic and non-aromatic cyclic radicals containing at least one heteroatom. Optionally the at least one heteroatom is selected from O, S, N, P, B, Si, and Se, preferably, O, S, or N. Hetero-aromatic cyclic radicals may be used interchangeably with heteroaryl. Preferred hetero-non-aromatic cyclic groups are those containing 3 to 7 ring atoms which includes at least one hetero atom, and includes cyclic amines such as morpholino, piperidino, pyrrolidino, and the like, and cyclic ethers/thio-ethers, such as tetrahydrofuran, tetrahydropyran, tetrahydrothiophene, and the like. Additionally, the heterocyclic group may be optionally substituted.
[0036] The term “aryl” refers to and includes both single-ring aromatic hydrocarbyl groups and polycyclic aromatic ring systems. The polycyclic rings may have two or more rings in which two carbons are common to two adjoining rings (the rings are “fused”) wherein at least one of the rings is an aromatic hydrocarbyl group, e.g., the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls. Preferred aryl groups are those containing six to thirty carbon atoms, preferably six to twenty carbon atoms, more preferably six to twelve carbon atoms. Especially preferred is an aryl group having six carbons, ten carbons or twelve carbons. Suitable aryl groups include phenyl, biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene, preferably phenyl, biphenyl, triphenyl, triphenylene, fluorene, and naphthalene. Additionally, the aryl group may be optionally substituted.
[0037] The term “heteroaryl” refers to and includes both single-ring aromatic groups and polycyclic aromatic ring systems that include at least one heteroatom. The heteroatoms include, but are not limited to O, S, N, P, B, Si, and Se. In many instances, O, S, or N are the preferred heteroatoms. Hetero-single ring aromatic systems are preferably single rings with 5 or 6 ring atoms, and the ring can have from one to six heteroatoms. The hetero-polycyclic ring systems can have two or more rings in which two atoms are common to two adjoining rings (the rings are “fused”) wherein at least one of the rings is a heteroaryl, e.g., the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls. The hetero-polycyclic aromatic ring systems can have from one to six heteroatoms per ring of the polycyclic aromatic ring system. Preferred heteroaryl groups are those containing three to thirty carbon atoms, preferably three to twenty carbon atoms, more preferably three to twelve carbon atoms. Suitable heteroaryl groups include dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine, preferably dibenzothiophene, dibenzofuran, dibenzoselenophene, carbazole, indolocarbazole, imidazole, pyridine, triazine, benzimidazole, 1,2-azaborine, 1,3-azaborine, 1,4-azaborine, borazine, and aza-analogs thereof. Additionally, the heteroaryl group may be optionally substituted.
[0038] Of the aryl and heteroaryl groups listed above, the groups of triphenylene, naphthalene, anthracene, dibenzothiophene, dibenzofuran, dibenzoselenophene, carbazole, indolocarbazole, imidazole, pyridine, pyrazine, pyrimidine, triazine, and benzimidazole, and the respective aza-analogs of each thereof are of particular interest.
[0039] The terms alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aralkyl, heterocyclic group, aryl, and heteroaryl, as used herein, are independently unsubstituted, or independently substituted, with one or more general substituents.
[0040] In many instances, the general substituents are selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, boryl, and combinations thereof.
[0041] In some instances, the preferred general substituents are selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, heteroalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, aryl, heteroaryl, nitrile, isonitrile, sulfanyl, boryl, and combinations thereof.
[0042] In some instances, the more preferred general substituents are selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, alkoxy, aryloxy, amino, silyl, boryl, aryl, heteroaryl, sulfanyl, and combinations thereof.
[0043] In yet other instances, the most preferred general substituents are selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, aryl, heteroaryl, and combinations thereof.
[0044] The terms “substituted” and “substitution” refer to a substituent other than H that is bonded to the relevant position, e.g., a carbon or nitrogen. For example, when R′ represents mono-substitution, then one R′ must be other than H (i.e., a substitution). Similarly, when R′ represents di-substitution, then two of R′ must be other than H. Similarly, when R′ represents zero or no substitution, for example, can be a hydrogen for available valencies of ring atoms, as in carbon atoms for benzene and the nitrogen atom in pyrrole, or simply represents nothing for ring atoms with fully filled valencies, e.g., the nitrogen atom in pyridine. The maximum number of substitutions possible in a ring structure will depend on the total number of available valencies in the ring atoms.
[0045] As used herein, “combinations thereof” indicates that one or more members of the applicable list are combined to form a known or chemically stable arrangement that one of ordinary skill in the art can envision from the applicable list. For example, an alkyl and deuterium can be combined to form a partial or fully deuterated alkyl group; a halogen and alkyl can be combined to form a halogenated alkyl substituent; and a halogen, alkyl, and aryl can be combined to form a halogenated arylalkyl. In one instance, the term substitution includes a combination of two to four of the listed groups. In another instance, the term substitution includes a combination of two to three groups. In yet another instance, the term substitution includes a combination of two groups. Preferred combinations of substituent groups are those that contain up to fifty atoms that are not hydrogen or deuterium, or those which include up to forty atoms that are not hydrogen or deuterium, or those that include up to thirty atoms that are not hydrogen or deuterium. In many instances, a preferred combination of substituent groups will include up to twenty atoms that are not hydrogen or deuterium.
[0046] The “aza” designation in the fragments described herein, i.e. aza-dibenzofuran, aza-dibenzothiophene, etc. means that one or more of the C—H groups in the respective aromatic ring can be replaced by a nitrogen atom, for example, and without any limitation, azatriphenylene encompasses both dibenzo[f,h]quinoxaline and dibenzo[f,h]quinoline. One of ordinary skill in the art can readily envision other nitrogen analogs of the aza-derivatives described above, and all such analogs are intended to be encompassed by the terms as set forth herein.
[0047] As used herein, “deuterium” refers to an isotope of hydrogen. Deuterated compounds can be readily prepared using methods known in the art. For example, U.S. Pat. No. 8,557,400, Patent Pub. No. WO 2006/095951, and U.S. Pat. Application Pub. No. US 2011/0037057, which are hereby incorporated by reference in their entireties, describe the making of deuterium-substituted organometallic complexes. Further reference is made to Ming Yan, et al., Tetrahedron 2015, 71, 1425-30 and Atzrodt et al., Angew. Chem. Int. Ed. (Reviews) 2007, 46, 7744-65, which are incorporated by reference in their entireties, describe the deuteration of the methylene hydrogens in benzyl amines and efficient pathways to replace aromatic ring hydrogens with deuterium, respectively.
[0048] It is to be understood that when a molecular fragment is described as being a substituent or otherwise attached to another moiety, its name may be written as if it were a fragment (e.g. phenyl, phenylene, naphthyl, dibenzofuryl) or as if it were the whole molecule (e.g. benzene, naphthalene, dibenzofuran). As used herein, these different ways of designating a substituent or attached fragment are considered to be equivalent.
[0049] In some instance, a pair of adjacent substituents can be optionally joined or fused into a ring. The preferred ring is a five, six, or seven-membered carbocyclic or heterocyclic ring, includes both instances where the portion of the ring formed by the pair of substituents is saturated and where the portion of the ring formed by the pair of substituents is unsaturated. As used herein, “adjacent” means that the two substituents involved can be on the same ring next to each other, or on two neighboring rings having the two closest available substitutable positions, such as 2, 2′ positions in a biphenyl, or 1, 8 position in a naphthalene, as long as they can form a stable fused ring system.
B. The Compounds of the Present Disclosure
[0050] Disclosed are emitter compounds selected from the group consisting of (L.sup.1-L.sup.2).sub.nIr(L.sub.A).sub.3−n and (L.sub.B).sub.nIr(L.sup.3-L.sup.4).sub.3−n;
wherein (L.sup.1-L.sup.2).sub.nIr(L.sub.A).sub.3−n is
##STR00004##
and (L.sub.B).sub.nIr(L.sup.3-L.sup.4).sub.3−n is
##STR00005##
wherein each R.sup.S11, R.sup.S12, and R.sup.S13 independently represents zero, mono, or up to a maximum allowed substitution to its associated ring;
wherein each L.sup.1-L.sup.2 and L.sup.3-L.sup.4 independently represents an anionic bidentate ligand;
wherein n is 1 or 2;
wherein each R.sup.S1, R.sup.S2, R.sup.S3, R.sup.S4, R.sup.S5, R.sup.S6, is independently selected from the group consisting of alkyl, cycloalkyl, partially or fully fluorinated variants thereof, partially or fully deuterated variants thereof, and combinations thereof;
wherein each R.sup.S11, R.sup.S12, and R.sup.S13 is independently a hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, boryl, and combinations thereof;
wherein at least one of R.sup.S11, R.sup.S12, and R.sup.S13 is selected from the group consisting of deuterium, silyl, C1 to C3 alkyl, substituted or unsubstituted cycloalkyl, and a branch substituted or unsubstituted alkyl with the branching occurs at the benzylic position; and
wherein the first host comprises at least one donor group G.sup.D, and at least one acceptor group G.sup.A.
C. The OLEDs and the Devices of the Present Disclosure
[0051] In another aspect, the present disclosure also provides an OLED device comprising a first organic layer that contains a compound as disclosed in the above compounds section of the present disclosure.
[0052] In some embodiments, the OLED comprises: an anode; a cathode; and an organic emissive layer disposed between the anode and the cathode. The emissive layer comprises: a first host; and a first emitter; where the first emitter is selected from the group consisting of (L.sup.1-L.sup.2).sub.nIr(L.sub.A).sub.3−n and (L.sub.B).sub.nIr(L.sup.3-L.sup.4).sub.3−n;
wherein (L.sup.1-L.sup.2).sub.nIr(L.sub.A).sub.3−n is
##STR00006##
and (L.sub.B).sub.nIr(L.sup.3-L.sup.4).sub.3−n is
##STR00007##
wherein: each R.sup.S11, R.sup.S12, and R.sup.S13 independently represents zero, mono, or up to a maximum allowed substitution to its associated ring; each L.sup.1-L.sup.2 and L.sup.3-L.sup.4 independently represents an anionic bidentate ligand; n is 1 or 2;
each R.sup.S1, R.sup.S2, R.sup.S3, R.sup.S4, R.sup.S5, R.sup.S6, is independently selected from the group consisting of alkyl, cycloalkyl, partially or fully fluorinated variants thereof, partially or fully deuterated variants thereof, and combinations thereof; each R.sup.S11, R.sup.S12, and R.sup.S13 is independently a hydrogen or a substituent selected from the group consisting of the general substituents described above; at least one of R.sup.S11, R.sup.S12, and R.sup.S13 is selected from the group consisting of deuterium, silyl, alkyl, cycloalkyl, partially or fully fluorinated variants thereof, and combinations thereof; wherein any two substituents of R.sup.S1, R.sup.S2, R.sup.S3, R.sup.S4, R.sup.S5, R.sup.S6, R.sup.S11, R.sup.S12, and R.sup.S13 can be joined or fused into a ring; and the first host comprises at least one donor group G.sup.D, and at least one acceptor group G.sup.A. Thus, the ligand L.sub.B can be
##STR00008##
[0053] In some embodiments of the OLED, at least one of R.sup.S11, R.sup.S12, and R.sup.S13 is selected from the group consisting of deuterium, silyl, C1 to C3 alkyl, substituted or unsubstituted cycloalkyl, and a branch substituted or unsubstituted alkyl with the branching occurs at the benzylic position.
[0054] In some embodiments of the OLED, each R.sup.S11, R.sup.S12, and R.sup.S13 is independently a hydrogen or a substituent selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, heteroalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, aryl, heteroaryl, nitrile, isonitrile, sulfanyl, boryl, and combinations thereof.
[0055] In some embodiments of the OLED, n is 2.
[0056] In some embodiments of the OLED, where the first emitter has the formula (L.sub.B).sub.nIr(L.sup.3-L.sup.4).sub.3−n, the first emitter is selected from the group consisting of:
##STR00009##
wherein X′ is selected from the group consisting of BR.sub.e, BR.sub.eR.sub.f, NR.sub.e, PR.sub.e, O, S, Se, C═O, S═O, SO.sub.2, CR.sub.eR.sub.f, SiR.sub.eR.sub.f, and GeR.sub.eR.sub.f; wherein each R′, R″, and R.sup.S14 is independently a hydrogen or a general substituent described above; and wherein any two substituents of R.sub.e, R.sub.f, and R.sup.S14 can be joined or fused into a ring.
[0057] In some embodiments of the OLED, the first emitter is Compound A having formula (L.sup.1-L.sup.2).sub.nIr(L.sub.A).sub.3−n whose structure
##STR00010##
[0058] In some embodiments of the OLED where the first emitter is Compound A, the ligand (L.sup.1-L.sup.2) is selected from the group consisting of:
##STR00011##
wherein: Y.sup.1 to Y.sup.10 are each independently selected from the group consisting of carbon and nitrogen; Y′ is selected from the group consisting of BR.sub.e, BR.sub.eR.sub.f, NR.sub.e, PR.sub.e, O, S, Se, C═O, S═O, SO.sub.2, CR.sub.eR.sub.f, SiR.sub.eR.sub.f, and GeR.sub.eR.sub.f; R.sub.e and R.sub.f are optionally fused or joined to form a ring; R.sub.a, and R.sub.b each independently represent zero, mono, or up to a maximum allowed substitution to its associated ring; each of R.sub.a, R.sub.b, R.sub.e and R.sub.f is independently hydrogen or a substituent selected from the group consisting of the general substituents defined herein; and two adjacent substituents of R.sub.a, and R.sub.b are optionally fused or joined to form a ring or form a multidentate ligand.
[0059] In some embodiments of the OLED where the first emitter is Compound A, the ligand (L.sup.1-L.sup.2) is selected from the group consisting of:
##STR00012## ##STR00013## ##STR00014## ##STR00015## ##STR00016## ##STR00017## ##STR00018##
wherein: R.sub.a′, and R.sub.b′ each independently represent zero, mono, or up to a maximum allowed substitution to its associated ring; R.sub.a′, and R.sub.b′ each independently hydrogen or a substituent selected from the group consisting of the general substituents defined herein; and two adjacent substituents of R.sub.a′, and R.sub.b′ can be fused or joined to form a ring or form a multidentate ligand.
[0060] In some embodiments of the OLED where the first emitter is Compound A, the ligand (L.sup.1-L.sup.2) is selected from the group consisting of:
L.sup.1-L.sup.2-1-i based on Structure 1:
##STR00019##
L.sup.1-L.sup.2-2-i based on Structure 2:
##STR00020##
L.sup.1-L.sup.2-3-i based on Structure 3:
##STR00021##
L.sup.1-L.sup.2-4-i based on Structure 4:
##STR00022##
L.sup.1-L.sup.2-5-i based on Structure 5:
##STR00023##
L.sup.1-L.sup.2-6-i based on Structure 6:
##STR00024##
L.sup.1-L.sup.2-7-i based on Structure 7:
##STR00025##
L.sup.1-L.sup.2-8-i based on Structure 8:
##STR00026##
L.sup.1-L.sup.2-9-i based on Structure 9:
##STR00027##
L.sup.1-L.sup.2-10-i based on Structure 10:
##STR00028##
L.sup.1-L.sup.2-11-i based on Structure 11:
##STR00029##
L.sup.1-L.sup.2-12-i based on Structure 12:
##STR00030##
L.sup.1-L.sup.2-13-i based on Structure 13:
##STR00031##
L.sup.1-L.sup.2-14-i based on Structure 14:
##STR00032##
and L.sup.1-L.sup.2-15-i based on Structure 15:
##STR00033##
L.sup.1-L.sup.2-16-i based on Structure 16:
##STR00034##
L.sup.1-L.sup.2-17-i based on Structure 17:
##STR00035##
wherein i is an integer from 1 to 810, and for each i, R.sub.E, and G are as defined below:
TABLE-US-00001 i R.sub.E G 1 R.sup.1 G.sup.1 2 R.sup.2 G.sup.1 3 R.sup.3 G.sup.1 4 R.sup.4 G.sup.1 5 R.sup.5 G.sup.1 6 R.sup.6 G.sup.1 7 R.sup.7 G.sup.1 8 R.sup.8 G.sup.1 9 R.sup.9 G.sup.1 10 R.sup.10 G.sup.1 11 R.sup.11 G.sup.1 12 R.sup.12 G.sup.1 13 R.sup.13 G.sup.1 14 R.sup.14 G.sup.1 15 R.sup.15 G.sup.1 16 R.sup.16 G.sup.1 17 R.sup.17 G.sup.1 18 R.sup.18 G.sup.1 19 R.sup.19 G.sup.1 20 R.sup.20 G.sup.1 21 R.sup.21 G.sup.1 22 R.sup.22 G.sup.1 23 R.sup.23 G.sup.1 24 R.sup.24 G.sup.1 25 R.sup.25 G.sup.1 26 R.sup.26 G.sup.1 27 R.sup.27 G.sup.1 28 R.sup.28 G.sup.1 29 R.sup.29 G.sup.1 30 R.sup.30 G.sup.1 31 R.sup.31 G.sup.1 32 R.sup.32 G.sup.1 33 R.sup.33 G.sup.1 34 R.sup.34 G.sup.1 35 R.sup.35 G.sup.1 36 R.sup.36 G.sup.1 37 R.sup.37 G.sup.1 38 R.sup.38 G.sup.1 39 R.sup.39 G.sup.1 40 R.sup.40 G.sup.1 41 R.sup.41 G.sup.1 42 R.sup.42 G.sup.1 43 R.sup.43 G.sup.1 44 R.sup.44 G.sup.1 45 R.sup.45 G.sup.1 46 R.sup.1 G.sup.5 47 R.sup.2 G.sup.5 48 R.sup.3 G.sup.5 49 R.sup.4 G.sup.5 50 R.sup.5 G.sup.5 51 R.sup.6 G.sup.5 52 R.sup.7 G.sup.5 53 R.sup.8 G.sup.5 54 R.sup.9 G.sup.5 55 R.sup.10 G.sup.5 56 R.sup.11 G.sup.5 57 R.sup.12 G.sup.5 58 R.sup.13 G.sup.5 59 R.sup.14 G.sup.5 60 R.sup.15 G.sup.5 61 R.sup.16 G.sup.5 62 R.sup.17 G.sup.5 63 R.sup.18 G.sup.5 64 R.sup.19 G.sup.5 65 R.sup.20 G.sup.5 66 R.sup.21 G.sup.5 67 R.sup.22 G.sup.5 68 R.sup.23 G.sup.5 69 R.sup.24 G.sup.5 70 R.sup.25 G.sup.5 71 R.sup.26 G.sup.5 72 R.sup.27 G.sup.5 73 R.sup.28 G.sup.5 74 R.sup.29 G.sup.5 75 R.sup.30 G.sup.5 76 R.sup.31 G.sup.5 77 R.sup.32 G.sup.5 78 R.sup.33 G.sup.5 79 R.sup.34 G.sup.5 80 R.sup.35 G.sup.5 81 R.sup.36 G.sup.5 82 R.sup.37 G.sup.5 83 R.sup.38 G.sup.5 84 R.sup.39 G.sup.5 85 R.sup.40 G.sup.5 86 R.sup.41 G.sup.5 87 R.sup.42 G.sup.5 88 R.sup.43 G.sup.5 89 R.sup.44 G.sup.5 90 R.sup.45 G.sup.5 91 R.sup.1 G.sup.9 92 R.sup.2 G.sup.9 93 R.sup.3 G.sup.9 94 R.sup.4 G.sup.9 95 R.sup.5 G.sup.9 96 R.sup.6 G.sup.9 97 R.sup.7 G.sup.9 98 R.sup.8 G.sup.9 99 R.sup.9 G.sup.9 100 R.sup.10 G.sup.9 101 R.sup.11 G.sup.9 102 R.sup.12 G.sup.9 103 R.sup.13 G.sup.9 104 R.sup.14 G.sup.9 105 R.sup.15 G.sup.9 106 R.sup.16 G.sup.9 107 R.sup.17 G.sup.9 108 R.sup.18 G.sup.9 109 R.sup.19 G.sup.9 110 R.sup.20 G.sup.9 111 R.sup.21 G.sup.9 112 R.sup.22 G.sup.9 113 R.sup.23 G.sup.9 114 R.sup.24 G.sup.9 115 R.sup.25 G.sup.9 116 R.sup.26 G.sup.9 117 R.sup.27 G.sup.9 118 R.sup.28 G.sup.9 119 R.sup.29 G.sup.9 120 R.sup.30 G.sup.9 121 R.sup.31 G.sup.9 122 R.sup.32 G.sup.9 123 R.sup.33 G.sup.9 124 R.sup.34 G.sup.9 125 R.sup.35 G.sup.9 126 R.sup.36 G.sup.9 127 R.sup.37 G.sup.9 128 R.sup.38 G.sup.9 129 R.sup.39 G.sup.9 130 R.sup.40 G.sup.9 131 R.sup.41 G.sup.9 132 R.sup.42 G.sup.9 133 R.sup.43 G.sup.9 134 R.sup.44 G.sup.9 135 R.sup.45 G.sup.9 136 R.sup.1 G.sup.13 137 R.sup.2 G.sup.13 138 R.sup.3 G.sup.13 139 R.sup.4 G.sup.13 140 R.sup.5 G.sup.13 141 R.sup.6 G.sup.13 142 R.sup.7 G.sup.13 143 R.sup.8 G.sup.13 144 R.sup.9 G.sup.13 145 R.sup.10 G.sup.13 146 R.sup.11 G.sup.13 147 R.sup.12 G.sup.13 148 R.sup.13 G.sup.13 149 R.sup.14 G.sup.13 150 R.sup.15 G.sup.13 151 R.sup.16 G.sup.13 152 R.sup.17 G.sup.13 153 R.sup.18 G.sup.13 154 R.sup.19 G.sup.13 155 R.sup.20 G.sup.13 156 R.sup.21 G.sup.13 157 R.sup.22 G.sup.13 158 R.sup.23 G.sup.13 159 R.sup.24 G.sup.13 160 R.sup.25 G.sup.13 161 R.sup.26 G.sup.13 162 R.sup.27 G.sup.13 163 R.sup.28 G.sup.13 164 R.sup.29 G.sup.13 165 R.sup.30 G.sup.13 166 R.sup.31 G.sup.13 167 R.sup.32 G.sup.13 168 R.sup.33 G.sup.13 169 R.sup.34 G.sup.13 170 R.sup.35 G.sup.13 171 R.sup.36 G.sup.13 172 R.sup.37 G.sup.13 173 R.sup.38 G.sup.13 174 R.sup.39 G.sup.13 175 R.sup.40 G.sup.13 176 R.sup.41 G.sup.13 177 R.sup.42 G.sup.13 178 R.sup.43 G.sup.13 179 R.sup.44 G.sup.13 180 R.sup.45 G.sup.13 181 R.sup.1 G.sup.17 182 R.sup.2 G.sup.17 183 R.sup.3 G.sup.17 184 R.sup.4 G.sup.17 185 R.sup.5 G.sup.17 186 R.sup.6 G.sup.17 187 R.sup.7 G.sup.17 188 R.sup.8 G.sup.17 189 R.sup.9 G.sup.17 190 R.sup.10 G.sup.17 191 R.sup.11 G.sup.17 192 R.sup.12 G.sup.17 193 R.sup.13 G.sup.17 194 R.sup.14 G.sup.17 195 R.sup.15 G.sup.17 196 R.sup.16 G.sup.17 197 R.sup.17 G.sup.17 198 R.sup.18 G.sup.17 199 R.sup.19 G.sup.17 200 R.sup.20 G.sup.17 201 R.sup.21 G.sup.17 202 R.sup.22 G.sup.17 203 R.sup.23 G.sup.17 204 R.sup.1 G.sup.2 205 R.sup.2 G.sup.2 206 R.sup.3 G.sup.2 207 R.sup.4 G.sup.2 208 R.sup.5 G.sup.2 209 R.sup.6 G.sup.2 210 R.sup.7 G.sup.2 211 R.sup.8 G.sup.2 212 R.sup.9 G.sup.2 213 R.sup.10 G.sup.2 214 R.sup.11 G.sup.2 215 R.sup.12 G.sup.2 216 R.sup.13 G.sup.2 217 R.sup.14 G.sup.2 218 R.sup.15 G.sup.2 219 R.sup.16 G.sup.2 220 R.sup.17 G.sup.2 221 R.sup.18 G.sup.2 222 R.sup.19 G.sup.2 223 R.sup.20 G.sup.2 224 R.sup.21 G.sup.2 225 R.sup.22 G.sup.2 226 R.sup.23 G.sup.2 227 R.sup.24 G.sup.2 228 R.sup.25 G.sup.2 229 R.sup.26 G.sup.2 230 R.sup.27 G.sup.2 231 R.sup.28 G.sup.2 232 R.sup.29 G.sup.2 233 R.sup.30 G.sup.2 234 R.sup.31 G.sup.2 235 R.sup.32 G.sup.2 236 R.sup.33 G.sup.2 237 R.sup.34 G.sup.2 238 R.sup.35 G.sup.2 239 R.sup.36 G.sup.2 240 R.sup.37 G.sup.2 241 R.sup.38 G.sup.2 242 R.sup.39 G.sup.2 243 R.sup.40 G.sup.2 244 R.sup.41 G.sup.2 245 R.sup.42 G.sup.2 246 R.sup.43 G.sup.2 247 R.sup.44 G.sup.2 248 R.sup.45 G.sup.2 249 R.sup.1 G.sup.6 250 R.sup.2 G.sup.6 251 R.sup.3 G.sup.6 252 R.sup.4 G.sup.6 253 R.sup.5 G.sup.6 254 R.sup.6 G.sup.6 255 R.sup.7 G.sup.6 256 R.sup.8 G.sup.6 257 R.sup.9 G.sup.6 258 R.sup.10 G.sup.6 259 R.sup.11 G.sup.6 260 R.sup.12 G.sup.6 261 R.sup.13 G.sup.6 262 R.sup.14 G.sup.6 263 R.sup.15 G.sup.6 264 R.sup.16 G.sup.6 265 R.sup.17 G.sup.6 266 R.sup.18 G.sup.6 267 R.sup.19 G.sup.6 268 R.sup.20 G.sup.6 269 R.sup.21 G.sup.6 270 R.sup.22 G.sup.6 271 R.sup.23 G.sup.6 272 R.sup.24 G.sup.6 273 R.sup.25 G.sup.6 274 R.sup.26 G.sup.6 275 R.sup.27 G.sup.6 276 R.sup.28 G.sup.6 277 R.sup.29 G.sup.6 278 R.sup.30 G.sup.6 279 R.sup.31 G.sup.6 280 R.sup.32 G.sup.6 281 R.sup.33 G.sup.6 282 R.sup.34 G.sup.6 283 R.sup.35 G.sup.6 284 R.sup.36 G.sup.6 285 R.sup.37 G.sup.6 286 R.sup.38 G.sup.6 287 R.sup.39 G.sup.6 288 R.sup.40 G.sup.6 289 R.sup.41 G.sup.6 290 R.sup.42 G.sup.6 291 R.sup.43 G.sup.6 292 R.sup.44 G.sup.6 293 R.sup.45 G.sup.6 294 R.sup.1 G.sup.10 295 R.sup.2 G.sup.10 296 R.sup.3 G.sup.10 297 R.sup.4 G.sup.10 298 R.sup.5 G.sup.10 299 R.sup.6 G.sup.10 300 R.sup.7 G.sup.10 301 R.sup.8 G.sup.10 302 R.sup.9 G.sup.10 303 R.sup.10 G.sup.10 304 R.sup.11 G.sup.10 305 R.sup.12 G.sup.10 306 R.sup.13 G.sup.10 307 R.sup.14 G.sup.10 308 R.sup.15 G.sup.10 309 R.sup.16 G.sup.10 310 R.sup.17 G.sup.10 311 R.sup.18 G.sup.10 312 R.sup.19 G.sup.10 313 R.sup.20 G.sup.10 314 R.sup.21 G.sup.10 315 R.sup.22 G.sup.10 316 R.sup.23 G.sup.10 317 R.sup.24 G.sup.10 318 R.sup.25 G.sup.10 319 R.sup.26 G.sup.10 320 R.sup.27 G.sup.10 321 R.sup.28 G.sup.10 322 R.sup.29 G.sup.10 323 R.sup.30 G.sup.10 324 R.sup.31 G.sup.10 325 R.sup.32 G.sup.10 326 R.sup.33 G.sup.10 327 R.sup.34 G.sup.10 328 R.sup.35 G.sup.10 329 R.sup.36 G.sup.10 330 R.sup.37 G.sup.10 331 R.sup.38 G.sup.10 332 R.sup.39 G.sup.10 333 R.sup.40 G.sup.10 334 R.sup.41 G.sup.10 335 R.sup.42 G.sup.10 336 R.sup.43 G.sup.10 337 R.sup.44 G.sup.10 338 R.sup.45 G.sup.10 339 R.sup.1 G.sup.14 340 R.sup.2 G.sup.14 341 R.sup.3 G.sup.14 342 R.sup.4 G.sup.14 343 R.sup.5 G.sup.14 344 R.sup.6 G.sup.14 345 R.sup.7 G.sup.14 346 R.sup.8 G.sup.14 347 R.sup.9 G.sup.14 348 R.sup.10 G.sup.14 349 R.sup.11 G.sup.14 350 R.sup.12 G.sup.14 351 R.sup.13 G.sup.14 352 R.sup.14 G.sup.14 353 R.sup.15 G.sup.14 354 R.sup.16 G.sup.14 355 R.sup.17 G.sup.14 356 R.sup.18 G.sup.14 357 R.sup.19 G.sup.14 358 R.sup.20 G.sup.14 359 R.sup.21 G.sup.14 360 R.sup.22 G.sup.14 361 R.sup.23 G.sup.14 362 R.sup.24 G.sup.14 363 R.sup.25 G.sup.14 364 R.sup.26 G.sup.14 365 R.sup.27 G.sup.14 366 R.sup.28 G.sup.14 367 R.sup.29 G.sup.14 368 R.sup.30 G.sup.14 369 R.sup.31 G.sup.14 370 R.sup.32 G.sup.14 371 R.sup.33 G.sup.14 372 R.sup.34 G.sup.14 373 R.sup.35 G.sup.14 374 R.sup.36 G.sup.14 375 R.sup.37 G.sup.14 376 R.sup.38 G.sup.14 377 R.sup.39 G.sup.14 378 R.sup.40 G.sup.14 379 R.sup.41 G.sup.14 380 R.sup.42 G.sup.14 381 R.sup.43 G.sup.14 382 R.sup.44 G.sup.14 383 R.sup.45 G.sup.14 384 R.sup.24 G.sup.17 385 R.sup.25 G.sup.17 386 R.sup.26 G.sup.17 387 R.sup.27 G.sup.17 388 R.sup.28 G.sup.17 389 R.sup.29 G.sup.17 390 R.sup.30 G.sup.17 391 R.sup.31 G.sup.17 392 R.sup.32 G.sup.17 393 R.sup.33 G.sup.17 394 R.sup.34 G.sup.17 395 R.sup.35 G.sup.17 396 R.sup.36 G.sup.17 397 R.sup.37 G.sup.17 398 R.sup.38 G.sup.17 399 R.sup.39 G.sup.17 400 R.sup.40 G.sup.17 401 R.sup.41 G.sup.17 402 R.sup.42 G.sup.17 403 R.sup.43 G.sup.17 404 R.sup.44 G.sup.17 405 R.sup.45 G.sup.17 406 R.sup.23 G.sup.18 407 R.sup.1 G.sup.3 408 R.sup.2 G.sup.3 409 R.sup.3 G.sup.3 410 R.sup.4 G.sup.3 411 R.sup.5 G.sup.3 412 R.sup.6 G.sup.3 413 R.sup.7 G.sup.3 414 R.sup.8 G.sup.3 415 R.sup.9 G.sup.3 416 R.sup.10 G.sup.3 417 R.sup.11 G.sup.3 418 R.sup.12 G.sup.3 419 R.sup.13 G.sup.3 420 R.sup.14 G.sup.3 421 R.sup.15 G.sup.3 422 R.sup.16 G.sup.3 423 R.sup.17 G.sup.3 424 R.sup.18 G.sup.3 425 R.sup.19 G.sup.3 426 R.sup.20 G.sup.3 427 R.sup.21 G.sup.3 428 R.sup.22 G.sup.3 429 R.sup.23 G.sup.3 430 R.sup.24 G.sup.3 431 R.sup.25 G.sup.3 432 R.sup.26 G.sup.3 433 R.sup.27 G.sup.3 434 R.sup.28 G.sup.3 435 R.sup.29 G.sup.3 436 R.sup.30 G.sup.3 437 R.sup.31 G.sup.3 438 R.sup.32 G.sup.3 439 R.sup.33 G.sup.3 440 R.sup.34 G.sup.3 441 R.sup.35 G.sup.3 442 R.sup.36 G.sup.3 443 R.sup.37 G.sup.3 444 R.sup.38 G.sup.3 445 R.sup.39 G.sup.3 446 R.sup.40 G.sup.3 447 R.sup.41 G.sup.3 448 R.sup.42 G.sup.3 449 R.sup.43 G.sup.3 450 R.sup.44 G.sup.3 451 R.sup.45 G.sup.3 452 R.sup.1 G.sup.7 453 R.sup.2 G.sup.7 454 R.sup.3 G.sup.7 455 R.sup.4 G.sup.7 456 R.sup.5 G.sup.7 457 R.sup.6 G.sup.7 458 R.sup.7 G.sup.7 459 R.sup.8 G.sup.7 460 R.sup.9 G.sup.7 461 R.sup.10 G.sup.7 462 R.sup.11 G.sup.7 463 R.sup.12 G.sup.7 464 R.sup.13 G.sup.7 465 R.sup.14 G.sup.7 466 R.sup.15 G.sup.7 467 R.sup.16 G.sup.7 468 R.sup.17 G.sup.7 469 R.sup.18 G.sup.7 470 R.sup.19 G.sup.7 471 R.sup.20 G.sup.7 472 R.sup.21 G.sup.7 473 R.sup.22 G.sup.7 474 R.sup.23 G.sup.7 475 R.sup.24 G.sup.7 476 R.sup.25 G.sup.7 477 R.sup.26 G.sup.7 478 R.sup.27 G.sup.7 479 R.sup.28 G.sup.7 480 R.sup.29 G.sup.7 481 R.sup.30 G.sup.7 482 R.sup.31 G.sup.7 483 R.sup.32 G.sup.7 484 R.sup.33 G.sup.7 485 R.sup.34 G.sup.7 486 R.sup.35 G.sup.7 487 R.sup.36 G.sup.7 488 R.sup.37 G.sup.7 489 R.sup.38 G.sup.7 490 R.sup.39 G.sup.7 491 R.sup.40 G.sup.7 492 R.sup.41 G.sup.7 493 R.sup.42 G.sup.7 494 R.sup.43 G.sup.7 495 R.sup.44 G.sup.7 496 R.sup.45 G.sup.7 497 R.sup.1 G.sup.11 498 R.sup.2 G.sup.11 499 R.sup.3 G.sup.11 500 R.sup.4 G.sup.11 501 R.sup.5 G.sup.11 502 R.sup.6 G.sup.11 503 R.sup.7 G.sup.11 504 R.sup.8 G.sup.11 505 R.sup.9 G.sup.11 506 R.sup.10 G.sup.11 507 R.sup.11 G.sup.11 508 R.sup.12 G.sup.11 509 R.sup.13 G.sup.11 510 R.sup.14 G.sup.11 511 R.sup.15 G.sup.11 512 R.sup.16 G.sup.11 513 R.sup.17 G.sup.11 514 R.sup.18 G.sup.11 515 R.sup.19 G.sup.11 516 R.sup.20 G.sup.11 517 R.sup.21 G.sup.11 518 R.sup.22 G.sup.11 519 R.sup.23 G.sup.11 520 R.sup.24 G.sup.11 521 R.sup.25 G.sup.11 522 R.sup.26 G.sup.11 523 R.sup.27 G.sup.11 524 R.sup.28 G.sup.11 525 R.sup.29 G.sup.11 526 R.sup.30 G.sup.11 527 R.sup.31 G.sup.11 528 R.sup.32 G.sup.11 529 R.sup.33 G.sup.11 530 R.sup.34 G.sup.11 531 R.sup.35 G.sup.11 532 R.sup.36 G.sup.11 533 R.sup.37 G.sup.11 534 R.sup.38 G.sup.11 535 R.sup.39 G.sup.11 536 R.sup.40 G.sup.11 537 R.sup.41 G.sup.11 538 R.sup.42 G.sup.11 539 R.sup.43 G.sup.11 540 R.sup.44 G.sup.11 541 R.sup.45 G.sup.11 542 R.sup.1 G.sup.15 543 R.sup.2 G.sup.15 544 R.sup.3 G.sup.15 545 R.sup.4 G.sup.15 546 R.sup.5 G.sup.15 547 R.sup.6 G.sup.15 548 R.sup.7 G.sup.15 549 R.sup.8 G.sup.15 550 R.sup.9 G.sup.15 551 R.sup.10 G.sup.15 552 R.sup.11 G.sup.15 553 R.sup.12 G.sup.15 554 R.sup.13 G.sup.15 555 R.sup.14 G.sup.15 556 R.sup.15 G.sup.15 557 R.sup.16 G.sup.15 558 R.sup.17 G.sup.15 559 R.sup.18 G.sup.15 560 R.sup.19 G.sup.15 561 R.sup.20 G.sup.15 562 R.sup.21 G.sup.15 563 R.sup.22 G.sup.15 564 R.sup.23 G.sup.15 565 R.sup.24 G.sup.15 566 R.sup.25 G.sup.15 567 R.sup.26 G.sup.15 568 R.sup.27 G.sup.15 569 R.sup.28 G.sup.15 570 R.sup.29 G.sup.15 571 R.sup.30 G.sup.15 572 R.sup.31 G.sup.15 573 R.sup.32 G.sup.15 574 R.sup.33 G.sup.15 575 R.sup.34 G.sup.15 576 R.sup.35 G.sup.15 577 R.sup.36 G.sup.15 578 R.sup.37 G.sup.15 579 R.sup.38 G.sup.15 580 R.sup.39 G.sup.15 581 R.sup.40 G.sup.15 582 R.sup.41 G.sup.15 583 R.sup.42 G.sup.15 584 R.sup.43 G.sup.15 585 R.sup.44 G.sup.15 586 R.sup.45 G.sup.15 587 R.sup.1 G.sup.18 588 R.sup.2 G.sup.18 589 R.sup.3 G.sup.18 590 R.sup.4 G.sup.18 591 R.sup.5 G.sup.18 592 R.sup.6 G.sup.18 593 R.sup.7 G.sup.18 594 R.sup.8 G.sup.18 595 R.sup.9 G.sup.18 596 R.sup.10 G.sup.18 597 R.sup.11 G.sup.18 598 R.sup.12 G.sup.18 599 R.sup.13 G.sup.18 600 R.sup.14 G.sup.18 601 R.sup.15 G.sup.18 602 R.sup.16 G.sup.18 603 R.sup.17 G.sup.18 604 R.sup.18 G.sup.18 605 R.sup.19 G.sup.18 606 R.sup.20 G.sup.18 607 R.sup.21 G.sup.18 608 R.sup.22 G.sup.18 609 R.sup.1 G.sup.4 610 R.sup.2 G.sup.4 611 R.sup.3 G.sup.4 612 R.sup.4 G.sup.4 613 R.sup.5 G.sup.4 614 R.sup.6 G.sup.4 615 R.sup.7 G.sup.4 616 R.sup.8 G.sup.4 617 R.sup.9 G.sup.4 618 R.sup.10 G.sup.4 619 R.sup.11 G.sup.4 620 R.sup.12 G.sup.4 621 R.sup.13 G.sup.4 622 R.sup.14 G.sup.4 623 R.sup.15 G.sup.4 624 R.sup.16 G.sup.4 625 R.sup.17 G.sup.4 626 R.sup.18 G.sup.4 627 R.sup.19 G.sup.4 628 R.sup.20 G.sup.4 629 R.sup.21 G.sup.4 630 R.sup.22 G.sup.4 631 R.sup.23 G.sup.4 632 R.sup.24 G.sup.4 633 R.sup.25 G.sup.4 634 R.sup.26 G.sup.4 635 R.sup.27 G.sup.4 636 R.sup.28 G.sup.4 637 R.sup.29 G.sup.4 638 R.sup.30 G.sup.4 639 R.sup.31 G.sup.4 640 R.sup.32 G.sup.4 641 R.sup.33 G.sup.4 642 R.sup.34 G.sup.4 643 R.sup.35 G.sup.4 644 R.sup.36 G.sup.4 645 R.sup.37 G.sup.4 646 R.sup.38 G.sup.4 647 R.sup.39 G.sup.4 648 R.sup.40 G.sup.4 649 R.sup.41 G.sup.4 650 R.sup.42 G.sup.4 651 R.sup.43 G.sup.4 652 R.sup.44 G.sup.4 653 R.sup.45 G.sup.4 654 R.sup.1 G.sup.8 655 R.sup.2 G.sup.8 656 R.sup.3 G.sup.8 657 R.sup.4 G.sup.8 658 R.sup.5 G.sup.8 659 R.sup.6 G.sup.8 660 R.sup.7 G.sup.8 661 R.sup.8 G.sup.8 662 R.sup.9 G.sup.8 663 R.sup.10 G.sup.8 664 R.sup.11 G.sup.8 665 R.sup.12 G.sup.8 666 R.sup.13 G.sup.8 667 R.sup.14 G.sup.8 668 R.sup.15 G.sup.8 669 R.sup.16 G.sup.8 670 R.sup.17 G.sup.8 671 R.sup.18 G.sup.8 672 R.sup.19 G.sup.8 673 R.sup.20 G.sup.8 674 R.sup.21 G.sup.8 675 R.sup.22 G.sup.8 676 R.sup.23 G.sup.8 677 R.sup.24 G.sup.8 678 R.sup.25 G.sup.8 679 R.sup.26 G.sup.8 680 R.sup.27 G.sup.8 681 R.sup.28 G.sup.8 682 R.sup.29 G.sup.8 683 R.sup.30 G.sup.8 684 R.sup.31 G.sup.8 685 R.sup.32 G.sup.8 686 R.sup.33 G.sup.8 687 R.sup.34 G.sup.8 688 R.sup.35 G.sup.8 689 R.sup.36 G.sup.8 690 R.sup.37 G.sup.8 691 R.sup.38 G.sup.8 692 R.sup.39 G.sup.8 693 R.sup.40 G.sup.8 694 R.sup.41 G.sup.8 695 R.sup.42 G.sup.8 696 R.sup.43 G.sup.8 697 R.sup.44 G.sup.8 698 R.sup.45 G.sup.8 699 R.sup.1 G.sup.12 700 R.sup.2 G.sup.12 701 R.sup.3 G.sup.12 702 R.sup.4 G.sup.12 703 R.sup.5 G.sup.12 704 R.sup.6 G.sup.12 705 R.sup.7 G.sup.12 706 R.sup.8 G.sup.12 707 R.sup.9 G.sup.12 708 R.sup.10 G.sup.12 709 R.sup.11 G.sup.12 710 R.sup.12 G.sup.12 711 R.sup.13 G.sup.12 712 R.sup.14 G.sup.12 713 R.sup.15 G.sup.12 714 R.sup.16 G.sup.12 715 R.sup.17 G.sup.12 716 R.sup.18 G.sup.12 717 R.sup.19 G.sup.12 718 R.sup.20 G.sup.12 719 R.sup.21 G.sup.12 720 R.sup.22 G.sup.12 721 R.sup.23 G.sup.12 722 R.sup.24 G.sup.12 723 R.sup.25 G.sup.12 724 R.sup.26 G.sup.12 725 R.sup.27 G.sup.12 726 R.sup.28 G.sup.12 727 R.sup.29 G.sup.12 728 R.sup.30 G.sup.12 729 R.sup.31 G.sup.12 730 R.sup.32 G.sup.12 731 R.sup.33 G.sup.12 732 R.sup.34 G.sup.12 733 R.sup.35 G.sup.12 734 R.sup.36 G.sup.12 735 R.sup.37 G.sup.12 736 R.sup.38 G.sup.12 737 R.sup.39 G.sup.12 738 R.sup.40 G.sup.12 739 R.sup.41 G.sup.12 740 R.sup.42 G.sup.12 741 R.sup.43 G.sup.12 742 R.sup.44 G.sup.12 743 R.sup.45 G.sup.12 744 R.sup.1 G.sup.16 745 R.sup.2 G.sup.16 746 R.sup.3 G.sup.16 747 R.sup.4 G.sup.16 748 R.sup.5 G.sup.16 749 R.sup.6 G.sup.16 750 R.sup.7 G.sup.16 751 R.sup.8 G.sup.16 752 R.sup.9 G.sup.16 753 R.sup.10 G.sup.16 754 R.sup.11 G.sup.16 755 R.sup.12 G.sup.16 756 R.sup.13 G.sup.16 757 R.sup.14 G.sup.16 758 R.sup.15 G.sup.16 759 R.sup.16 G.sup.16 760 R.sup.17 G.sup.16 761 R.sup.18 G.sup.16 762 R.sup.19 G.sup.16 763 R.sup.20 G.sup.16 764 R.sup.21 G.sup.16 765 R.sup.22 G.sup.16 766 R.sup.23 G.sup.16 767 R.sup.24 G.sup.16 768 R.sup.25 G.sup.16 769 R.sup.26 G.sup.16 770 R.sup.27 G.sup.16 771 R.sup.28 G.sup.16 772 R.sup.29 G.sup.16 773 R.sup.30 G.sup.16 774 R.sup.31 G.sup.16 775 R.sup.32 G.sup.16 776 R.sup.33 G.sup.16 777 R.sup.34 G.sup.16 778 R.sup.35 G.sup.16 779 R.sup.36 G.sup.16 780 R.sup.37 G.sup.16 781 R.sup.38 G.sup.16 782 R.sup.39 G.sup.16 783 R.sup.40 G.sup.16 784 R.sup.41 G.sup.16 785 R.sup.42 G.sup.16 786 R.sup.43 G.sup.16 787 R.sup.44 G.sup.16 788 R.sup.45 G.sup.16 789 R.sup.24 G.sup.18 790 R.sup.25 G.sup.18 791 R.sup.26 G.sup.18 792 R.sup.27 G.sup.18 793 R.sup.28 G.sup.18 794 R.sup.29 G.sup.18 795 R.sup.30 G.sup.18 796 R.sup.31 G.sup.18 797 R.sup.32 G.sup.18 798 R.sup.33 G.sup.18 799 R.sup.34 G.sup.18 800 R.sup.35 G.sup.18 801 R.sup.36 G.sup.18 802 R.sup.37 G.sup.18 803 R.sup.38 G.sup.18 804 R.sup.39 G.sup.18 805 R.sup.40 G.sup.18 806 R.sup.41 G.sup.18 807 R.sup.42 G.sup.18 808 R.sup.43 G.sup.18 809 R.sup.44 G.sup.18 810 R.sup.45 G.sup.18
wherein R.sup.1 to R.sup.45 have the following structures:
##STR00036## ##STR00037## ##STR00038## ##STR00039##
and
wherein G.sup.1 to G.sup.18 have the following structures:
##STR00040## ##STR00041## ##STR00042##
[0061] In some embodiments of the OLED, where the first emitter is Compound A, each R.sup.S1, R.sup.S2, R.sup.S3, R.sup.S4, R.sup.S5, R.sup.S6 is independently selected from the group consisting of methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl, cyclopentyl, cyclohexyl, phenyl, 2,6-dimethylphenyl, 2,4,6-trimethylphenyl, 2,6-diisopropylphenyl, and combinations thereof.
[0062] In some embodiments of the OLED, where the first emitter is Compound A, the L.sub.A ligand is selected from the group consisting of:
L.sub.A1-k based on Structure A1:
##STR00043##
L.sub.A2-k based on Structure A2:
##STR00044##
L.sub.A3-k based on Structure A3:
##STR00045##
L.sub.A4-k based on Structure A4
##STR00046##
L.sub.A5-k based on Structure A5:
##STR00047##
and L.sub.A6-k based on Structure A6:
##STR00048##
wherein k is an integer from 1 to 600, and for each k, R.sub.D, R.sub.F, and R.sub.G are as defined below:
TABLE-US-00002 k R.sup.D R.sup.F R.sup.G 1 R.sup.D1 R.sup.D1 R.sup.D1 2 R.sup.D2 R.sup.D2 R.sup.D2 3 R.sup.D3 R.sup.D3 R.sup.D3 4 R.sup.D4 R.sup.D4 R.sup.D4 5 R.sup.D5 R.sup.D5 R.sup.D5 6 R.sup.D6 R.sup.D6 R.sup.D6 7 R.sup.D7 R.sup.D7 R.sup.D7 8 R.sup.D8 R.sup.D8 R.sup.D8 9 R.sup.D9 R.sup.D9 R.sup.D9 10 R.sup.D10 R.sup.D10 R.sup.D10 11 R.sup.D11 R.sup.D11 R.sup.D11 12 R.sup.D12 R.sup.D12 R.sup.D12 13 R.sup.D13 R.sup.D13 R.sup.D13 14 R.sup.D14 R.sup.D14 R.sup.D14 15 R.sup.D15 R.sup.D15 R.sup.D15 16 R.sup.D16 R.sup.D16 R.sup.D16 17 R.sup.D17 R.sup.D17 R.sup.D17 18 R.sup.D18 R.sup.D18 R.sup.D18 19 R.sup.D19 R.sup.D19 R.sup.D19 20 R.sup.D20 R.sup.D20 R.sup.D20 21 R.sup.D21 R.sup.D21 R.sup.D21 22 R.sup.D22 R.sup.D22 R.sup.D22 23 R.sup.D23 R.sup.D23 R.sup.D23 24 R.sup.D1 R.sup.D2 R.sup.D2 25 R.sup.D1 R.sup.D3 R.sup.D3 26 R.sup.D1 R.sup.D4 R.sup.D4 27 R.sup.D1 R.sup.D5 R.sup.D5 28 R.sup.D1 R.sup.D6 R.sup.D6 29 R.sup.D1 R.sup.D7 R.sup.D7 30 R.sup.D1 R.sup.D8 R.sup.D8 31 R.sup.D1 R.sup.D9 R.sup.D9 32 R.sup.D1 R.sup.D10 R.sup.D10 33 R.sup.D1 R.sup.D11 R.sup.D11 34 R.sup.D1 R.sup.D12 R.sup.D12 35 R.sup.D1 R.sup.D13 R.sup.D13 36 R.sup.D1 R.sup.D14 R.sup.D14 37 R.sup.D1 R.sup.D15 R.sup.D15 38 R.sup.D1 R.sup.D16 R.sup.D16 39 R.sup.D1 R.sup.D17 R.sup.D17 40 R.sup.D1 R.sup.D18 R.sup.D18 41 R.sup.D1 R.sup.D19 R.sup.D19 42 R.sup.D1 R.sup.D20 R.sup.D20 43 R.sup.D1 R.sup.D21 R.sup.D21 44 R.sup.D1 R.sup.D22 R.sup.D22 45 R.sup.D1 R.sup.D23 R.sup.D23 46 R.sup.D1 R.sup.D2 R.sup.D3 47 R.sup.D1 R.sup.D2 R.sup.D4 48 R.sup.D1 R.sup.D2 R.sup.D5 49 R.sup.D1 R.sup.D2 R.sup.D6 50 R.sup.D1 R.sup.D2 R.sup.D7 51 R.sup.D1 R.sup.D2 R.sup.D8 52 R.sup.D1 R.sup.D2 R.sup.D9 53 R.sup.D1 R.sup.D2 R.sup.D10 54 R.sup.D1 R.sup.D2 R.sup.D11 55 R.sup.D1 R.sup.D2 R.sup.D12 56 R.sup.D1 R.sup.D2 R.sup.D13 57 R.sup.D1 R.sup.D2 R.sup.D14 58 R.sup.D1 R.sup.D2 R.sup.D15 59 R.sup.D1 R.sup.D2 R.sup.D16 60 R.sup.D1 R.sup.D2 R.sup.D17 61 R.sup.D1 R.sup.D2 R.sup.D18 62 R.sup.D1 R.sup.D2 R.sup.D19 63 R.sup.D1 R.sup.D2 R.sup.D20 64 R.sup.D1 R.sup.D2 R.sup.D21 65 R.sup.D1 R.sup.D2 R.sup.D22 66 R.sup.D1 R.sup.D2 R.sup.D23 67 R.sup.D1 R.sup.D3 R.sup.D4 68 R.sup.D1 R.sup.D3 R.sup.D5 69 R.sup.D1 R.sup.D3 R.sup.D6 70 R.sup.D1 R.sup.D3 R.sup.D7 71 R.sup.D1 R.sup.D3 R.sup.D8 72 R.sup.D1 R.sup.D3 R.sup.D9 73 R.sup.D1 R.sup.D3 R.sup.D10 74 R.sup.D1 R.sup.D3 R.sup.D11 75 R.sup.D1 R.sup.D3 R.sup.D12 76 R.sup.D1 R.sup.D3 R.sup.D13 77 R.sup.D1 R.sup.D3 R.sup.D14 78 R.sup.D1 R.sup.D3 R.sup.D15 79 R.sup.D1 R.sup.D3 R.sup.D16 80 R.sup.D1 R.sup.D3 R.sup.D17 81 R.sup.D1 R.sup.D3 R.sup.D18 82 R.sup.D1 R.sup.D3 R.sup.D19 83 R.sup.D1 R.sup.D3 R.sup.D20 84 R.sup.D1 R.sup.D3 R.sup.D21 85 R.sup.D1 R.sup.D3 R.sup.D22 86 R.sup.D1 R.sup.D3 R.sup.D23 87 R.sup.D1 R.sup.D4 R.sup.D5 88 R.sup.D1 R.sup.D4 R.sup.D6 89 R.sup.D1 R.sup.D4 R.sup.D7 90 R.sup.D1 R.sup.D4 R.sup.D8 91 R.sup.D1 R.sup.D4 R.sup.D9 92 R.sup.D1 R.sup.D4 R.sup.D10 93 R.sup.D1 R.sup.D4 R.sup.D11 94 R.sup.D1 R.sup.D4 R.sup.D12 95 R.sup.D1 R.sup.D4 R.sup.D13 96 R.sup.D1 R.sup.D4 R.sup.D14 97 R.sup.D1 R.sup.D4 R.sup.D15 98 R.sup.D1 R.sup.D4 R.sup.D16 99 R.sup.D1 R.sup.D4 R.sup.D17 100 R.sup.D1 R.sup.D4 R.sup.D18 101 R.sup.D1 R.sup.D4 R.sup.D19 102 R.sup.D1 R.sup.D4 R.sup.D20 103 R.sup.D1 R.sup.D4 R.sup.D21 104 R.sup.D1 R.sup.D4 R.sup.D22 105 R.sup.D1 R.sup.D4 R.sup.D23 106 R.sup.D1 R.sup.D5 R.sup.D6 107 R.sup.D1 R.sup.D5 R.sup.D7 108 R.sup.D1 R.sup.D5 R.sup.D8 109 R.sup.D1 R.sup.D5 R.sup.D9 110 R.sup.D1 R.sup.D5 R.sup.D10 111 R.sup.D1 R.sup.D5 R.sup.D11 112 R.sup.D1 R.sup.D5 R.sup.D12 113 R.sup.D1 R.sup.D5 R.sup.D13 114 R.sup.D1 R.sup.D5 R.sup.D14 115 R.sup.D1 R.sup.D5 R.sup.D15 116 R.sup.D1 R.sup.D5 R.sup.D16 117 R.sup.D1 R.sup.D5 R.sup.D17 118 R.sup.D1 R.sup.D5 R.sup.D18 119 R.sup.D1 R.sup.D5 R.sup.D19 120 R.sup.D1 R.sup.D5 R.sup.D20 121 R.sup.D1 R.sup.D5 R.sup.D21 122 R.sup.D1 R.sup.D5 R.sup.D22 123 R.sup.D1 R.sup.D5 R.sup.D23 124 R.sup.D1 R.sup.D6 R.sup.D7 125 R.sup.D1 R.sup.D6 R.sup.D8 126 R.sup.D1 R.sup.D6 R.sup.D9 127 R.sup.D1 R.sup.D6 R.sup.D10 128 R.sup.D1 R.sup.D6 R.sup.D11 129 R.sup.D1 R.sup.D6 R.sup.D12 130 R.sup.D1 R.sup.D6 R.sup.D13 131 R.sup.D1 R.sup.D6 R.sup.D14 132 R.sup.D1 R.sup.D6 R.sup.D15 133 R.sup.D1 R.sup.D6 R.sup.D16 134 R.sup.D1 R.sup.D6 R.sup.D17 135 R.sup.D1 R.sup.D6 R.sup.D18 136 R.sup.D1 R.sup.D6 R.sup.D19 137 R.sup.D1 R.sup.D6 R.sup.D20 138 R.sup.D1 R.sup.D6 R.sup.D21 139 R.sup.D1 R.sup.D6 R.sup.D22 140 R.sup.D1 R.sup.D6 R.sup.D23 141 R.sup.D1 R.sup.D7 R.sup.D8 142 R.sup.D1 R.sup.D7 R.sup.D9 143 R.sup.D1 R.sup.D7 R.sup.D10 144 R.sup.D1 R.sup.D7 R.sup.D11 145 R.sup.D1 R.sup.D7 R.sup.D12 146 R.sup.D1 R.sup.D7 R.sup.D13 147 R.sup.D1 R.sup.D7 R.sup.D14 148 R.sup.D1 R.sup.D7 R.sup.D15 149 R.sup.D1 R.sup.D7 R.sup.D16 150 R.sup.D1 R.sup.D7 R.sup.D17 151 R.sup.D1 R.sup.D7 R.sup.D18 152 R.sup.D1 R.sup.D7 R.sup.D19 153 R.sup.D1 R.sup.D7 R.sup.D20 154 R.sup.D1 R.sup.D7 R.sup.D21 155 R.sup.D1 R.sup.D7 R.sup.D22 156 R.sup.D1 R.sup.D7 R.sup.D23 157 R.sup.D1 R.sup.D8 R.sup.D9 158 R.sup.D1 R.sup.D8 R.sup.D10 159 R.sup.D1 R.sup.D8 R.sup.D11 160 R.sup.D1 R.sup.D8 R.sup.D12 161 R.sup.D1 R.sup.D8 R.sup.D13 162 R.sup.D1 R.sup.D8 R.sup.D14 163 R.sup.D1 R.sup.D8 R.sup.D15 164 R.sup.D1 R.sup.D8 R.sup.D16 165 R.sup.D1 R.sup.D8 R.sup.D17 166 R.sup.D1 R.sup.D8 R.sup.D18 167 R.sup.D1 R.sup.D8 R.sup.D19 168 R.sup.D1 R.sup.D8 R.sup.D20 169 R.sup.D1 R.sup.D8 R.sup.D21 170 R.sup.D1 R.sup.D8 R.sup.D22 171 R.sup.D1 R.sup.D8 R.sup.D23 172 R.sup.D1 R.sup.D9 R.sup.D10 173 R.sup.D1 R.sup.D9 R.sup.D11 174 R.sup.D1 R.sup.D9 R.sup.D12 175 R.sup.D1 R.sup.D9 R.sup.D13 176 R.sup.D1 R.sup.D9 R.sup.D14 177 R.sup.D1 R.sup.D9 R.sup.D15 178 R.sup.D1 R.sup.D9 R.sup.D16 179 R.sup.D1 R.sup.D9 R.sup.D17 180 R.sup.D1 R.sup.D9 R.sup.D18 181 R.sup.D1 R.sup.D9 R.sup.D19 182 R.sup.D1 R.sup.D9 R.sup.D20 183 R.sup.D1 R.sup.D9 R.sup.D21 184 R.sup.D1 R.sup.D9 R.sup.D22 185 R.sup.D1 R.sup.D9 R.sup.D23 186 R.sup.D1 R.sup.D10 R.sup.D11 187 R.sup.D1 R.sup.D10 R.sup.D12 188 R.sup.D1 R.sup.D10 R.sup.D13 189 R.sup.D1 R.sup.D10 R.sup.D14 190 R.sup.D1 R.sup.D10 R.sup.D15 191 R.sup.D1 R.sup.D10 R.sup.D16 192 R.sup.D1 R.sup.D10 R.sup.D17 193 R.sup.D1 R.sup.D10 R.sup.D18 194 R.sup.D1 R.sup.D10 R.sup.D19 195 R.sup.D1 R.sup.D10 R.sup.D20 196 R.sup.D1 R.sup.D10 R.sup.D21 197 R.sup.D1 R.sup.D10 R.sup.D22 198 R.sup.D1 R.sup.D10 R.sup.D23 199 R.sup.D1 R.sup.D11 R.sup.D12 200 R.sup.D1 R.sup.D11 R.sup.D13 201 R.sup.D1 R.sup.D11 R.sup.D14 202 R.sup.D1 R.sup.D11 R.sup.D15 203 R.sup.D1 R.sup.D11 R.sup.D16 204 R.sup.D1 R.sup.D11 R.sup.D17 205 R.sup.D1 R.sup.D11 R.sup.D18 206 R.sup.D1 R.sup.D11 R.sup.D19 207 R.sup.D1 R.sup.D11 R.sup.D20 208 R.sup.D1 R.sup.D11 R.sup.D21 209 R.sup.D1 R.sup.D11 R.sup.D22 210 R.sup.D1 R.sup.D11 R.sup.D23 211 R.sup.D1 R.sup.D12 R.sup.D13 212 R.sup.D1 R.sup.D12 R.sup.D14 213 R.sup.D1 R.sup.D12 R.sup.D15 214 R.sup.D1 R.sup.D12 R.sup.D16 215 R.sup.D1 R.sup.D12 R.sup.D17 216 R.sup.D1 R.sup.D12 R.sup.D18 217 R.sup.D1 R.sup.D12 R.sup.D19 218 R.sup.D1 R.sup.D12 R.sup.D20 219 R.sup.D1 R.sup.D12 R.sup.D21 220 R.sup.D1 R.sup.D12 R.sup.D22 221 R.sup.D1 R.sup.D12 R.sup.D23 222 R.sup.D1 R.sup.D13 R.sup.D14 223 R.sup.D1 R.sup.D13 R.sup.D15 224 R.sup.D1 R.sup.D13 R.sup.D16 225 R.sup.D1 R.sup.D13 R.sup.D17 226 R.sup.D1 R.sup.D13 R.sup.D18 227 R.sup.D1 R.sup.D13 R.sup.D19 228 R.sup.D1 R.sup.D13 R.sup.D20 229 R.sup.D1 R.sup.D13 R.sup.D21 230 R.sup.D1 R.sup.D13 R.sup.D22 231 R.sup.D1 R.sup.D13 R.sup.D23 232 R.sup.D1 R.sup.D14 R.sup.D15 233 R.sup.D1 R.sup.D14 R.sup.D16 234 R.sup.D1 R.sup.D14 R.sup.D17 235 R.sup.D1 R.sup.D14 R.sup.D18 236 R.sup.D1 R.sup.D14 R.sup.D19 237 R.sup.D1 R.sup.D14 R.sup.D20 238 R.sup.D1 R.sup.D14 R.sup.D21 239 R.sup.D1 R.sup.D14 R.sup.D22 240 R.sup.D1 R.sup.D14 R.sup.D23 241 R.sup.D1 R.sup.D15 R.sup.D16 242 R.sup.D1 R.sup.D15 R.sup.D17 243 R.sup.D1 R.sup.D15 R.sup.D18 244 R.sup.D1 R.sup.D15 R.sup.D19 245 R.sup.D1 R.sup.D15 R.sup.D20 246 R.sup.D1 R.sup.D15 R.sup.D21 247 R.sup.D1 R.sup.D15 R.sup.D22 248 R.sup.D1 R.sup.D15 R.sup.D23 249 R.sup.D1 R.sup.D16 R.sup.D17 250 R.sup.D1 R.sup.D16 R.sup.D18 251 R.sup.D1 R.sup.D16 R.sup.D19 252 R.sup.D1 R.sup.D16 R.sup.D20 253 R.sup.D1 R.sup.D16 R.sup.D21 254 R.sup.D1 R.sup.D16 R.sup.D22 255 R.sup.D1 R.sup.D16 R.sup.D23 256 R.sup.D1 R.sup.D17 R.sup.D18 257 R.sup.D1 R.sup.D17 R.sup.D19 258 R.sup.D1 R.sup.D17 R.sup.D20 259 R.sup.D1 R.sup.D17 R.sup.D21 260 R.sup.D1 R.sup.D17 R.sup.D22 261 R.sup.D1 R.sup.D17 R.sup.D23 262 R.sup.D1 R.sup.D18 R.sup.D19 263 R.sup.D1 R.sup.D18 R.sup.D20 264 R.sup.D1 R.sup.D18 R.sup.D21 265 R.sup.D1 R.sup.D18 R.sup.D22 266 R.sup.D1 R.sup.D18 R.sup.D23 267 R.sup.D1 R.sup.D19 R.sup.D20 268 R.sup.D1 R.sup.D19 R.sup.D21 269 R.sup.D1 R.sup.D19 R.sup.D22 270 R.sup.D1 R.sup.D19 R.sup.D23 271 R.sup.D1 R.sup.D20 R.sup.D21 272 R.sup.D1 R.sup.D20 R.sup.D22 273 R.sup.D1 R.sup.D20 R.sup.D23 274 R.sup.D1 R.sup.D21 R.sup.D22 275 R.sup.D1 R.sup.D21 R.sup.D23 276 R.sup.D1 R.sup.D22 R.sup.D23 277 R.sup.D2 R.sup.D2 R.sup.D2 278 R.sup.D2 R.sup.D3 R.sup.D3 279 R.sup.D2 R.sup.D4 R.sup.D4 280 R.sup.D2 R.sup.D5 R.sup.D5 281 R.sup.D2 R.sup.D6 R.sup.D6 282 R.sup.D2 R.sup.D7 R.sup.D7 283 R.sup.D2 R.sup.D8 R.sup.D8 284 R.sup.D2 R.sup.D9 R.sup.D9 285 R.sup.D2 R.sup.D10 R.sup.D10 286 R.sup.D2 R.sup.D11 R.sup.D11 287 R.sup.D2 R.sup.D12 R.sup.D12 288 R.sup.D2 R.sup.D13 R.sup.D13 289 R.sup.D2 R.sup.D14 R.sup.D14 290 R.sup.D2 R.sup.D15 R.sup.D15 291 R.sup.D2 R.sup.D16 R.sup.D16 292 R.sup.D2 R.sup.D17 R.sup.D17 293 R.sup.D2 R.sup.D18 R.sup.D18 294 R.sup.D2 R.sup.D19 R.sup.D19 295 R.sup.D2 R.sup.D20 R.sup.D20 296 R.sup.D2 R.sup.D21 R.sup.D21 297 R.sup.D2 R.sup.D22 R.sup.D22 298 R.sup.D2 R.sup.D23 R.sup.D23 299 R.sup.D2 R.sup.D2 R.sup.D3 300 R.sup.D2 R.sup.D2 R.sup.D4 301 R.sup.D2 R.sup.D2 R.sup.D5 302 R.sup.D2 R.sup.D2 R.sup.D6 303 R.sup.D2 R.sup.D2 R.sup.D7 304 R.sup.D2 R.sup.D2 R.sup.D8 305 R.sup.D2 R.sup.D2 R.sup.D9 306 R.sup.D2 R.sup.D2 R.sup.D10 307 R.sup.D2 R.sup.D2 R.sup.D11 308 R.sup.D2 R.sup.D2 R.sup.D12 309 R.sup.D2 R.sup.D2 R.sup.D13 310 R.sup.D2 R.sup.D2 R.sup.D14 311 R.sup.D2 R.sup.D2 R.sup.D15 312 R.sup.D2 R.sup.D2 R.sup.D16 313 R.sup.D2 R.sup.D2 R.sup.D17 314 R.sup.D2 R.sup.D2 R.sup.D18 315 R.sup.D2 R.sup.D2 R.sup.D19 316 R.sup.D2 R.sup.D2 R.sup.D20 317 R.sup.D2 R.sup.D2 R.sup.D21 318 R.sup.D2 R.sup.D2 R.sup.D22 319 R.sup.D2 R.sup.D2 R.sup.D23 320 R.sup.D2 R.sup.D3 R.sup.D4 321 R.sup.D2 R.sup.D3 R.sup.D5 322 R.sup.D2 R.sup.D3 R.sup.D6 323 R.sup.D2 R.sup.D3 R.sup.D7 324 R.sup.D2 R.sup.D3 R.sup.D8 325 R.sup.D2 R.sup.D3 R.sup.D9 326 R.sup.D2 R.sup.D3 R.sup.D10 327 R.sup.D2 R.sup.D3 R.sup.D11 328 R.sup.D2 R.sup.D3 R.sup.D12 329 R.sup.D2 R.sup.D3 R.sup.D13 330 R.sup.D2 R.sup.D3 R.sup.D14 331 R.sup.D2 R.sup.D3 R.sup.D15 332 R.sup.D2 R.sup.D3 R.sup.D16 333 R.sup.D2 R.sup.D3 R.sup.D17 334 R.sup.D2 R.sup.D3 R.sup.D18 335 R.sup.D2 R.sup.D3 R.sup.D19 336 R.sup.D2 R.sup.D3 R.sup.D20 337 R.sup.D2 R.sup.D3 R.sup.D21 338 R.sup.D2 R.sup.D3 R.sup.D22 339 R.sup.D2 R.sup.D3 R.sup.D23 340 R.sup.D2 R.sup.D4 R.sup.D5 341 R.sup.D2 R.sup.D4 R.sup.D6 342 R.sup.D2 R.sup.D4 R.sup.D7 343 R.sup.D2 R.sup.D4 R.sup.D8 344 R.sup.D2 R.sup.D4 R.sup.D9 345 R.sup.D2 R.sup.D4 R.sup.D10 346 R.sup.D2 R.sup.D4 R.sup.D11 347 R.sup.D2 R.sup.D4 R.sup.D12 348 R.sup.D2 R.sup.D4 R.sup.D13 349 R.sup.D2 R.sup.D4 R.sup.D14 350 R.sup.D2 R.sup.D4 R.sup.D15 351 R.sup.D2 R.sup.D4 R.sup.D16 352 R.sup.D2 R.sup.D4 R.sup.D17 353 R.sup.D2 R.sup.D4 R.sup.D18 354 R.sup.D2 R.sup.D4 R.sup.D19 355 R.sup.D2 R.sup.D4 R.sup.D20 356 R.sup.D2 R.sup.D4 R.sup.D21 357 R.sup.D2 R.sup.D4 R.sup.D22 358 R.sup.D2 R.sup.D4 R.sup.D23 359 R.sup.D2 R.sup.D5 R.sup.D6 360 R.sup.D2 R.sup.D5 R.sup.D7 361 R.sup.D2 R.sup.D5 R.sup.D8 362 R.sup.D2 R.sup.D5 R.sup.D9 363 R.sup.D2 R.sup.D5 R.sup.D10 364 R.sup.D2 R.sup.D5 R.sup.D11 365 R.sup.D2 R.sup.D5 R.sup.D12 366 R.sup.D2 R.sup.D5 R.sup.D13 367 R.sup.D2 R.sup.D5 R.sup.D14 368 R.sup.D2 R.sup.D5 R.sup.D15 369 R.sup.D2 R.sup.D5 R.sup.D16 370 R.sup.D2 R.sup.D5 R.sup.D17 371 R.sup.D2 R.sup.D5 R.sup.D18 372 R.sup.D2 R.sup.D5 R.sup.D19 373 R.sup.D2 R.sup.D5 R.sup.D20 374 R.sup.D2 R.sup.D5 R.sup.D21 375 R.sup.D2 R.sup.D5 R.sup.D22 376 R.sup.D2 R.sup.D5 R.sup.D23 377 R.sup.D2 R.sup.D6 R.sup.D7 378 R.sup.D2 R.sup.D6 R.sup.D8 379 R.sup.D2 R.sup.D6 R.sup.D9 380 R.sup.D2 R.sup.D6 R.sup.D10 381 R.sup.D2 R.sup.D6 R.sup.D11 382 R.sup.D2 R.sup.D6 R.sup.D12 383 R.sup.D2 R.sup.D6 R.sup.D13 384 R.sup.D2 R.sup.D6 R.sup.D14 385 R.sup.D2 R.sup.D6 R.sup.D15 386 R.sup.D2 R.sup.D6 R.sup.D16 387 R.sup.D2 R.sup.D6 R.sup.D17 388 R.sup.D2 R.sup.D6 R.sup.D18 389 R.sup.D2 R.sup.D6 R.sup.D19 390 R.sup.D2 R.sup.D6 R.sup.D20 391 R.sup.D2 R.sup.D6 R.sup.D21 392 R.sup.D2 R.sup.D6 R.sup.D22 393 R.sup.D2 R.sup.D6 R.sup.D23 394 R.sup.D2 R.sup.D7 R.sup.D8 395 R.sup.D2 R.sup.D7 R.sup.D9 396 R.sup.D2 R.sup.D7 R.sup.D10 397 R.sup.D2 R.sup.D7 R.sup.D11 398 R.sup.D2 R.sup.D7 R.sup.D12 399 R.sup.D2 R.sup.D7 R.sup.D13 400 R.sup.D2 R.sup.D7 R.sup.D14 401 R.sup.D2 R.sup.D7 R.sup.D15 402 R.sup.D2 R.sup.D7 R.sup.D16 403 R.sup.D2 R.sup.D7 R.sup.D17 404 R.sup.D2 R.sup.D7 R.sup.D18 405 R.sup.D2 R.sup.D7 R.sup.D19 406 R.sup.D2 R.sup.D7 R.sup.D20 407 R.sup.D2 R.sup.D7 R.sup.D21 408 R.sup.D2 R.sup.D7 R.sup.D22 409 R.sup.D2 R.sup.D7 R.sup.D23 410 R.sup.D2 R.sup.D8 R.sup.D9 411 R.sup.D2 R.sup.D8 R.sup.D10 412 R.sup.D2 R.sup.D8 R.sup.D11 413 R.sup.D2 R.sup.D8 R.sup.D12 414 R.sup.D2 R.sup.D8 R.sup.D13 415 R.sup.D2 R.sup.D8 R.sup.D14 416 R.sup.D2 R.sup.D8 R.sup.D15 417 R.sup.D2 R.sup.D8 R.sup.D16 418 R.sup.D2 R.sup.D8 R.sup.D17 419 R.sup.D2 R.sup.D8 R.sup.D18 420 R.sup.D2 R.sup.D8 R.sup.D19 421 R.sup.D2 R.sup.D8 R.sup.D20 422 R.sup.D2 R.sup.D8 R.sup.D21 423 R.sup.D2 R.sup.D8 R.sup.D22 424 R.sup.D2 R.sup.D8 R.sup.D23 425 R.sup.D2 R.sup.D9 R.sup.D10 426 R.sup.D2 R.sup.D9 R.sup.D11 427 R.sup.D2 R.sup.D9 R.sup.D12 428 R.sup.D2 R.sup.D9 R.sup.D13 429 R.sup.D2 R.sup.D9 R.sup.D14 430 R.sup.D2 R.sup.D9 R.sup.D15 431 R.sup.D2 R.sup.D9 R.sup.D16 432 R.sup.D2 R.sup.D9 R.sup.D17 433 R.sup.D2 R.sup.D9 R.sup.D18 434 R.sup.D2 R.sup.D9 R.sup.D19 435 R.sup.D2 R.sup.D9 R.sup.D20 436 R.sup.D2 R.sup.D9 R.sup.D21 437 R.sup.D2 R.sup.D9 R.sup.D22 438 R.sup.D2 R.sup.D9 R.sup.D23 439 R.sup.D2 R.sup.D10 R.sup.D11 440 R.sup.D2 R.sup.D10 R.sup.D12 441 R.sup.D2 R.sup.D10 R.sup.D13 442 R.sup.D2 R.sup.D10 R.sup.D14 443 R.sup.D2 R.sup.D10 R.sup.D15 444 R.sup.D2 R.sup.D10 R.sup.D16 445 R.sup.D2 R.sup.D10 R.sup.D17 446 R.sup.D2 R.sup.D10 R.sup.D18 447 R.sup.D2 R.sup.D10 R.sup.D19 448 R.sup.D2 R.sup.D10 R.sup.D20 449 R.sup.D2 R.sup.D10 R.sup.D21 450 R.sup.D2 R.sup.D10 R.sup.D22 451 R.sup.D2 R.sup.D10 R.sup.D23 452 R.sup.D2 R.sup.D11 R.sup.D12 453 R.sup.D2 R.sup.D11 R.sup.D13 454 R.sup.D2 R.sup.D11 R.sup.D14 455 R.sup.D2 R.sup.D11 R.sup.D15 456 R.sup.D2 R.sup.D11 R.sup.D16 457 R.sup.D2 R.sup.D11 R.sup.D17 458 R.sup.D2 R.sup.D11 R.sup.D18 459 R.sup.D2 R.sup.D11 R.sup.D19 460 R.sup.D2 R.sup.D11 R.sup.D20 461 R.sup.D2 R.sup.D11 R.sup.D21 462 R.sup.D2 R.sup.D11 R.sup.D22 463 R.sup.D2 R.sup.D11 R.sup.D23 464 R.sup.D2 R.sup.D12 R.sup.D13 465 R.sup.D2 R.sup.D12 R.sup.D14 466 R.sup.D2 R.sup.D12 R.sup.D15 467 R.sup.D2 R.sup.D12 R.sup.D16 468 R.sup.D2 R.sup.D12 R.sup.D17 469 R.sup.D2 R.sup.D12 R.sup.D18 470 R.sup.D2 R.sup.D12 R.sup.D19 471 R.sup.D2 R.sup.D12 R.sup.D20 472 R.sup.D2 R.sup.D12 R.sup.D21 473 R.sup.D2 R.sup.D12 R.sup.D22 474 R.sup.D2 R.sup.D12 R.sup.D23 475 R.sup.D2 R.sup.D13 R.sup.D14 476 R.sup.D2 R.sup.D13 R.sup.D15 477 R.sup.D2 R.sup.D13 R.sup.D16 478 R.sup.D2 R.sup.D13 R.sup.D17 479 R.sup.D2 R.sup.D13 R.sup.D18 480 R.sup.D2 R.sup.D13 R.sup.D19 481 R.sup.D2 R.sup.D13 R.sup.D20 482 R.sup.D2 R.sup.D13 R.sup.D21 483 R.sup.D2 R.sup.D13 R.sup.D22 484 R.sup.D2 R.sup.D13 R.sup.D23 485 R.sup.D2 R.sup.D14 R.sup.D15 486 R.sup.D2 R.sup.D14 R.sup.D16 487 R.sup.D2 R.sup.D14 R.sup.D17 488 R.sup.D2 R.sup.D14 R.sup.D18 489 R.sup.D2 R.sup.D14 R.sup.D19 490 R.sup.D2 R.sup.D14 R.sup.D20 491 R.sup.D2 R.sup.D14 R.sup.D21 492 R.sup.D2 R.sup.D14 R.sup.D22 493 R.sup.D2 R.sup.D14 R.sup.D23 494 R.sup.D2 R.sup.D15 R.sup.D16 495 R.sup.D2 R.sup.D15 R.sup.D17 496 R.sup.D2 R.sup.D15 R.sup.D18 497 R.sup.D2 R.sup.D15 R.sup.D19 498 R.sup.D2 R.sup.D15 R.sup.D20 499 R.sup.D2 R.sup.D15 R.sup.D21 500 R.sup.D2 R.sup.D15 R.sup.D22 501 R.sup.D2 R.sup.D15 R.sup.D23 502 R.sup.D2 R.sup.D16 R.sup.D17 503 R.sup.D2 R.sup.D16 R.sup.D18 504 R.sup.D2 R.sup.D16 R.sup.D19 505 R.sup.D2 R.sup.D16 R.sup.D20 506 R.sup.D2 R.sup.D16 R.sup.D21 507 R.sup.D2 R.sup.D16 R.sup.D22 508 R.sup.D2 R.sup.D16 R.sup.D23 509 R.sup.D2 R.sup.D17 R.sup.D18 510 R.sup.D2 R.sup.D17 R.sup.D19 511 R.sup.D2 R.sup.D17 R.sup.D20 512 R.sup.D2 R.sup.D17 R.sup.D21 513 R.sup.D2 R.sup.D17 R.sup.D22 514 R.sup.D2 R.sup.D17 R.sup.D23 515 R.sup.D2 R.sup.D18 R.sup.D19 516 R.sup.D2 R.sup.D18 R.sup.D20 517 R.sup.D2 R.sup.D18 R.sup.D21 518 R.sup.D2 R.sup.D18 R.sup.D22 519 R.sup.D2 R.sup.D18 R.sup.D23 520 R.sup.D2 R.sup.D19 R.sup.D20 521 R.sup.D2 R.sup.D19 R.sup.D21 522 R.sup.D2 R.sup.D19 R.sup.D22 523 R.sup.D2 R.sup.D19 R.sup.D23 524 R.sup.D2 R.sup.D20 R.sup.D21 525 R.sup.D2 R.sup.D20 R.sup.D22 526 R.sup.D2 R.sup.D20 R.sup.D23 527 R.sup.D2 R.sup.D21 R.sup.D22 528 R.sup.D2 R.sup.D21 R.sup.D23 529 R.sup.D2 R.sup.D22 R.sup.D23 530 R.sup.D19 R.sup.D2 R.sup.D2 531 R.sup.D19 R.sup.D3 R.sup.D3 532 R.sup.D19 R.sup.D4 R.sup.D4 533 R.sup.D19 R.sup.D5 R.sup.D5 534 R.sup.D19 R.sup.D6 R.sup.D6 535 R.sup.D19 R.sup.D7 R.sup.D7 536 R.sup.D19 R.sup.D8 R.sup.D8 537 R.sup.D19 R.sup.D9 R.sup.D9 538 R.sup.D19 R.sup.D10 R.sup.D10 539 R.sup.D19 R.sup.D11 R.sup.D11 540 R.sup.D19 R.sup.D12 R.sup.D12 541 R.sup.D19 R.sup.D13 R.sup.D13 542 R.sup.D19 R.sup.D14 R.sup.D14 543 R.sup.D19 R.sup.D15 R.sup.D15 544 R.sup.D19 R.sup.D16 R.sup.D16 545 R.sup.D19 R.sup.D17 R.sup.D17 546 R.sup.D19 R.sup.D18 R.sup.D18 547 R.sup.D19 R.sup.D19 R.sup.D19 548 R.sup.D19 R.sup.D20 R.sup.D20 549 R.sup.D19 R.sup.D21 R.sup.D21 550 R.sup.D19 R.sup.D22 R.sup.D22 551 R.sup.D19 R.sup.D23 R.sup.D23 552 R.sup.D19 R.sup.D2 R.sup.D3 553 R.sup.D19 R.sup.D2 R.sup.D4 554 R.sup.D19 R.sup.D2 R.sup.D5 555 R.sup.D19 R.sup.D2 R.sup.D6 556 R.sup.D19 R.sup.D2 R.sup.D7 557 R.sup.D19 R.sup.D2 R.sup.D8 558 R.sup.D19 R.sup.D2 R.sup.D9 559 R.sup.D19 R.sup.D2 R.sup.D10 560 R.sup.D19 R.sup.D2 R.sup.D11 561 R.sup.D19 R.sup.D2 R.sup.D12 562 R.sup.D19 R.sup.D2 R.sup.D13 563 R.sup.D19 R.sup.D2 R.sup.D14 564 R.sup.D19 R.sup.D2 R.sup.D15 565 R.sup.D19 R.sup.D2 R.sup.D16 566 R.sup.D19 R.sup.D2 R.sup.D17 567 R.sup.D19 R.sup.D2 R.sup.D18 568 R.sup.D19 R.sup.D2 R.sup.D19 569 R.sup.D19 R.sup.D2 R.sup.D20 570 R.sup.D19 R.sup.D2 R.sup.D21 571 R.sup.D19 R.sup.D2 R.sup.D22 572 R.sup.D19 R.sup.D2 R.sup.D23 573 R.sup.D19 R.sup.D3 R.sup.D4 574 R.sup.D19 R.sup.D3 R.sup.D5 575 R.sup.D19 R.sup.D3 R.sup.D6 576 R.sup.D19 R.sup.D3 R.sup.D7 577 R.sup.D19 R.sup.D3 R.sup.D8 578 R.sup.D19 R.sup.D3 R.sup.D9 579 R.sup.D19 R.sup.D3 R.sup.D10 580 R.sup.D19 R.sup.D3 R.sup.D11 581 R.sup.D19 R.sup.D3 R.sup.D12 582 R.sup.D19 R.sup.D3 R.sup.D13 583 R.sup.D19 R.sup.D3 R.sup.D14 584 R.sup.D19 R.sup.D3 R.sup.D15 585 R.sup.D19 R.sup.D3 R.sup.D16 586 R.sup.D19 R.sup.D3 R.sup.D17 587 R.sup.D19 R.sup.D3 R.sup.D18 588 R.sup.D19 R.sup.D3 R.sup.D19 589 R.sup.D19 R.sup.D3 R.sup.D20 590 R.sup.D19 R.sup.D3 R.sup.D21 591 R.sup.D19 R.sup.D3 R.sup.D22 592 R.sup.D19 R.sup.D3 R.sup.D23 593 R.sup.D19 R.sup.D4 R.sup.D5 594 R.sup.D19 R.sup.D4 R.sup.D6 595 R.sup.D19 R.sup.D4 R.sup.D7 596 R.sup.D19 R.sup.D4 R.sup.D8 597 R.sup.D19 R.sup.D4 R.sup.D9 598 R.sup.D19 R.sup.D4 R.sup.D10 599 R.sup.D19 R.sup.D4 R.sup.D11 600 R.sup.D19 R.sup.D4 R.sup.D12
wherein R.sup.D1 to R.sup.D23 have the following structures:
##STR00049## ##STR00050## ##STR00051##
[0063] In some embodiments of the OLED, the first emitter is selected from the group consisting of: (L.sup.1-L.sup.2-1-1).sub.2Ir(L.sub.A1-1) to (L.sup.1-L.sup.2-17-810).sub.2Ir(L.sub.A6-600) based on the general formula of (L.sup.1-L.sup.2-m-i).sub.2Ir(L.sub.An-k), wherein m is an integer from 1 to 17, i is an integer from 1 to 810, n is an integer from 1 to 6, and k is an integer from 1 to 600.
[0064] In some embodiments of the OLED, where the first emitter is Compound A, the first emitter can be selected from the group consisting of:
##STR00052## ##STR00053## ##STR00054## ##STR00055## ##STR00056## ##STR00057## ##STR00058## ##STR00059## ##STR00060## ##STR00061## ##STR00062## ##STR00063## ##STR00064## ##STR00065## ##STR00066## ##STR00067## ##STR00068## ##STR00069##
[0065] In some embodiments of the OLED where the first emitter is Compound B, Compound C, Compound D, or Compound E, at least one of R.sup.S11, R.sup.S12, and R.sup.S13 is selected from the group consisting of:
##STR00070## ##STR00071## ##STR00072## ##STR00073## ##STR00074## ##STR00075## ##STR00076##
[0066] In some embodiments of the OLED where the first emitter is Compound B, Compound C, Compound D, or Compound E, all having the formula (L.sub.B).sub.nIr(L.sup.3-L.sup.4).sub.3−n, the first emitter is selected from the group consisting of:
##STR00077## ##STR00078##
wherein when there is more than one R.sup.S11 or R.sup.S13, each R.sup.S11 and R.sup.S13 can be the same or different.
[0067] In some embodiments of the OLED where the first emitter is Compound B, Compound C, Compound D, or Compound E, all having the formula (L.sub.B).sub.nIr(L.sup.3-L.sup.4).sub.3−n, the ligand L.sub.B is selected from the group consisting of:
L.sub.B1-h based on Structure B1:
##STR00079##
L.sub.B2-h based on Structure B2:
##STR00080##
L.sub.B3-h based on Structure B3:
##STR00081##
L.sub.B4-h based on Structure B4:
##STR00082##
and
L.sub.B5-h based on Structure B5:
##STR00083##
wherein h is an integer from 1 to 1170, and for each h, R.sup.H, and G are defined as below:
TABLE-US-00003 h R.sup.H G h R.sup.H G h R.sup.H G h R.sup.H G 1 R.sup.H1 G.sup.1 261 R.sup.H1 G.sup.2 521 R.sup.H1 G.sup.3 781 R.sup.H1 G.sup.4 2 R.sup.H2 G.sup.1 262 R.sup.H2 G.sup.2 522 R.sup.H2 G.sup.3 782 R.sup.H2 G.sup.4 3 R.sup.H3 G.sup.1 263 R.sup.H3 G.sup.2 523 R.sup.H3 G.sup.3 783 R.sup.H3 G.sup.4 4 R.sup.H4 G.sup.1 264 R.sup.H4 G.sup.2 524 R.sup.H4 G.sup.3 784 R.sup.H4 G.sup.4 5 R.sup.H5 G.sup.1 265 R.sup.H5 G.sup.2 525 R.sup.H5 G.sup.3 785 R.sup.H5 G.sup.4 6 R.sup.H6 G.sup.1 266 R.sup.H6 G.sup.2 526 R.sup.H6 G.sup.3 786 R.sup.H6 G.sup.4 7 R.sup.H7 G.sup.1 267 R.sup.H7 G.sup.2 527 R.sup.H7 G.sup.3 787 R.sup.H7 G.sup.4 8 R.sup.H8 G.sup.1 268 R.sup.H8 G.sup.2 528 R.sup.H8 G.sup.3 788 R.sup.H8 G.sup.4 9 R.sup.H9 G.sup.1 269 R.sup.H9 G.sup.2 529 R.sup.H9 G.sup.3 789 R.sup.H9 G.sup.4 10 R.sup.H10 G.sup.1 270 R.sup.H10 G.sup.2 530 R.sup.H10 G.sup.3 790 R.sup.H10 G.sup.4 11 R.sup.H11 G.sup.1 271 R.sup.H11 G.sup.2 531 R.sup.H11 G.sup.3 791 R.sup.H11 G.sup.4 12 R.sup.H12 G.sup.1 272 R.sup.H12 G.sup.2 532 R.sup.H12 G.sup.3 792 R.sup.H12 G.sup.4 13 R.sup.H13 G.sup.1 273 R.sup.H13 G.sup.2 533 R.sup.H13 G.sup.3 793 R.sup.H13 G.sup.4 14 R.sup.H14 G.sup.1 274 R.sup.H14 G.sup.2 534 R.sup.H14 G.sup.3 794 R.sup.H14 G.sup.4 15 R.sup.H15 G.sup.1 275 R.sup.H15 G.sup.2 535 R.sup.H15 G.sup.3 795 R.sup.H15 G.sup.4 16 R.sup.H16 G.sup.1 276 R.sup.H16 G.sup.2 536 R.sup.H16 G.sup.3 796 R.sup.H16 G.sup.4 17 R.sup.H17 G.sup.1 277 R.sup.H17 G.sup.2 537 R.sup.H17 G.sup.3 797 R.sup.H17 G.sup.4 18 R.sup.H18 G.sup.1 278 R.sup.H18 G.sup.2 538 R.sup.H18 G.sup.3 798 R.sup.H18 G.sup.4 19 R.sup.H19 G.sup.1 279 R.sup.H19 G.sup.2 539 R.sup.H19 G.sup.3 799 R.sup.H19 G.sup.4 20 R.sup.H20 G.sup.1 280 R.sup.H20 G.sup.2 540 R.sup.H20 G.sup.3 800 R.sup.H20 G.sup.4 21 R.sup.H21 G.sup.1 281 R.sup.H21 G.sup.2 541 R.sup.H21 G.sup.3 801 R.sup.H21 G.sup.4 22 R.sup.H22 G.sup.1 282 R.sup.H22 G.sup.2 542 R.sup.H22 G.sup.3 802 R.sup.H22 G.sup.4 23 R.sup.H23 G.sup.1 283 R.sup.H23 G.sup.2 543 R.sup.H23 G.sup.3 803 R.sup.H23 G.sup.4 24 R.sup.H24 G.sup.1 284 R.sup.H24 G.sup.2 544 R.sup.H24 G.sup.3 804 R.sup.H24 G.sup.4 25 R.sup.H25 G.sup.1 285 R.sup.H25 G.sup.2 545 R.sup.H25 G.sup.3 805 R.sup.H25 G.sup.4 26 R.sup.H26 G.sup.1 286 R.sup.H26 G.sup.2 546 R.sup.H26 G.sup.3 806 R.sup.H26 G.sup.4 27 R.sup.H27 G.sup.1 287 R.sup.H27 G.sup.2 547 R.sup.H27 G.sup.3 807 R.sup.H27 G.sup.4 28 R.sup.H28 G.sup.1 288 R.sup.H28 G.sup.2 548 R.sup.H28 G.sup.3 808 R.sup.H28 G.sup.4 29 R.sup.H29 G.sup.1 289 R.sup.H29 G.sup.2 549 R.sup.H29 G.sup.3 809 R.sup.H29 G.sup.4 30 R.sup.H30 G.sup.1 290 R.sup.H30 G.sup.2 550 R.sup.H30 G.sup.3 810 R.sup.H30 G.sup.4 31 R.sup.H31 G.sup.1 291 R.sup.H31 G.sup.2 551 R.sup.H31 G.sup.3 811 R.sup.H31 G.sup.4 32 R.sup.H32 G.sup.1 292 R.sup.H32 G.sup.2 552 R.sup.H32 G.sup.3 812 R.sup.H32 G.sup.4 33 R.sup.H33 G.sup.1 293 R.sup.H33 G.sup.2 553 R.sup.H33 G.sup.3 813 R.sup.H33 G.sup.4 34 R.sup.H34 G.sup.1 294 R.sup.H34 G.sup.2 554 R.sup.H34 G.sup.3 814 R.sup.H34 G.sup.4 35 R.sup.H35 G.sup.1 295 R.sup.H35 G.sup.2 555 R.sup.H35 G.sup.3 815 R.sup.H35 G.sup.4 36 R.sup.H36 G.sup.1 296 R.sup.H36 G.sup.2 556 R.sup.H36 G.sup.3 816 R.sup.H36 G.sup.4 37 R.sup.H37 G.sup.1 297 R.sup.H37 G.sup.2 557 R.sup.H37 G.sup.3 817 R.sup.H37 G.sup.4 38 R.sup.H38 G.sup.1 298 R.sup.H38 G.sup.2 558 R.sup.H38 G.sup.3 818 R.sup.H38 G.sup.4 39 R.sup.H39 G.sup.1 299 R.sup.H39 G.sup.2 559 R.sup.H39 G.sup.3 819 R.sup.H39 G.sup.4 40 R.sup.H40 G.sup.1 300 R.sup.H40 G.sup.2 560 R.sup.H40 G.sup.3 820 R.sup.H40 G.sup.4 41 R.sup.H41 G.sup.1 301 R.sup.H41 G.sup.2 561 R.sup.H41 G.sup.3 821 R.sup.H41 G.sup.4 42 R.sup.H42 G.sup.1 302 R.sup.H42 G.sup.2 562 R.sup.H42 G.sup.3 822 R.sup.H42 G.sup.4 43 R.sup.H43 G.sup.1 303 R.sup.H43 G.sup.2 563 R.sup.H43 G.sup.3 823 R.sup.H43 G.sup.4 44 R.sup.H44 G.sup.1 304 R.sup.H44 G.sup.2 564 R.sup.H44 G.sup.3 824 R.sup.H44 G.sup.4 45 R.sup.H45 G.sup.1 305 R.sup.H45 G.sup.2 565 R.sup.H45 G.sup.3 825 R.sup.H45 G.sup.4 46 R.sup.H46 G.sup.1 306 R.sup.H46 G.sup.2 566 R.sup.H46 G.sup.3 826 R.sup.H46 G.sup.4 47 R.sup.H47 G.sup.1 307 R.sup.H47 G.sup.2 567 R.sup.H47 G.sup.3 827 R.sup.H47 G.sup.4 48 R.sup.H48 G.sup.1 308 R.sup.H48 G.sup.2 568 R.sup.H48 G.sup.3 828 R.sup.H48 G.sup.4 49 R.sup.H49 G.sup.1 309 R.sup.H49 G.sup.2 569 R.sup.H49 G.sup.3 829 R.sup.H49 G.sup.4 50 R.sup.H50 G.sup.1 310 R.sup.H50 G.sup.2 570 R.sup.H50 G.sup.3 830 R.sup.H50 G.sup.4 51 R.sup.H51 G.sup.1 311 R.sup.H51 G.sup.2 571 R.sup.H51 G.sup.3 831 R.sup.H51 G.sup.4 52 R.sup.H52 G.sup.1 312 R.sup.H52 G.sup.2 572 R.sup.H52 G.sup.3 832 R.sup.H52 G.sup.4 53 R.sup.H53 G.sup.1 313 R.sup.H53 G.sup.2 573 R.sup.H53 G.sup.3 833 R.sup.H53 G.sup.4 54 R.sup.H54 G.sup.1 314 R.sup.H54 G.sup.2 574 R.sup.H54 G.sup.3 834 R.sup.H54 G.sup.4 55 R.sup.H55 G.sup.1 315 R.sup.H55 G.sup.2 575 R.sup.H55 G.sup.3 835 R.sup.H55 G.sup.4 56 R.sup.H56 G.sup.1 316 R.sup.H56 G.sup.2 576 R.sup.H56 G.sup.3 836 R.sup.H56 G.sup.4 57 R.sup.H57 G.sup.1 317 R.sup.H57 G.sup.2 577 R.sup.H57 G.sup.3 837 R.sup.H57 G.sup.4 58 R.sup.H58 G.sup.1 318 R.sup.H58 G.sup.2 578 R.sup.H58 G.sup.3 838 R.sup.H58 G.sup.4 59 R.sup.H59 G.sup.1 319 R.sup.H59 G.sup.2 579 R.sup.H59 G.sup.3 839 R.sup.H59 G.sup.4 60 R.sup.H60 G.sup.1 320 R.sup.H60 G.sup.2 580 R.sup.H60 G.sup.3 840 R.sup.H60 G.sup.4 61 R.sup.H61 G.sup.1 321 R.sup.H61 G.sup.2 581 R.sup.H61 G.sup.3 841 R.sup.H61 G.sup.4 62 R.sup.H62 G.sup.1 322 R.sup.H62 G.sup.2 582 R.sup.H62 G.sup.3 842 R.sup.H62 G.sup.4 63 R.sup.H63 G.sup.1 323 R.sup.H63 G.sup.2 583 R.sup.H63 G.sup.3 843 R.sup.H63 G.sup.4 64 R.sup.H64 G.sup.1 324 R.sup.H64 G.sup.2 584 R.sup.H64 G.sup.3 844 R.sup.H64 G.sup.4 65 R.sup.H65 G.sup.1 325 R.sup.H65 G.sup.2 585 R.sup.H65 G.sup.3 845 R.sup.H65 G.sup.4 66 R.sup.H1 G.sup.5 326 R.sup.H1 G.sup.6 586 R.sup.H1 G.sup.7 846 R.sup.H1 G.sup.8 67 R.sup.H2 G.sup.5 327 R.sup.H2 G.sup.6 587 R.sup.H2 G.sup.7 847 R.sup.H2 G.sup.8 68 R.sup.H3 G.sup.5 328 R.sup.H3 G.sup.6 588 R.sup.H3 G.sup.7 848 R.sup.H3 G.sup.8 69 R.sup.H4 G.sup.5 329 R.sup.H4 G.sup.6 589 R.sup.H4 G.sup.7 849 R.sup.H4 G.sup.8 70 R.sup.H5 G.sup.5 330 R.sup.H5 G.sup.6 590 R.sup.H5 G.sup.7 850 R.sup.H5 G.sup.8 71 R.sup.H6 G.sup.5 331 R.sup.H6 G.sup.6 591 R.sup.H6 G.sup.7 851 R.sup.H6 G.sup.8 72 R.sup.H7 G.sup.5 332 R.sup.H7 G.sup.6 592 R.sup.H7 G.sup.7 852 R.sup.H7 G.sup.8 73 R.sup.H8 G.sup.5 333 R.sup.H8 G.sup.6 593 R.sup.H8 G.sup.7 853 R.sup.H8 G.sup.8 74 R.sup.H9 G.sup.5 334 R.sup.H9 G.sup.6 594 R.sup.H9 G.sup.7 854 R.sup.H9 G.sup.8 75 R.sup.H10 G.sup.5 335 R.sup.H10 G.sup.6 595 R.sup.H10 G.sup.7 855 R.sup.H10 G.sup.8 76 R.sup.H11 G.sup.5 336 R.sup.H11 G.sup.6 596 R.sup.H11 G.sup.7 856 R.sup.H11 G.sup.8 77 R.sup.H12 G.sup.5 337 R.sup.H12 G.sup.6 597 R.sup.H12 G.sup.7 857 R.sup.H12 G.sup.8 78 R.sup.H13 G.sup.5 338 R.sup.H13 G.sup.6 598 R.sup.H13 G.sup.7 858 R.sup.H13 G.sup.8 79 R.sup.H14 G.sup.5 339 R.sup.H14 G.sup.6 599 R.sup.H14 G.sup.7 859 R.sup.H14 G.sup.8 80 R.sup.H15 G.sup.5 340 R.sup.H15 G.sup.6 600 R.sup.H15 G.sup.7 860 R.sup.H15 G.sup.8 81 R.sup.H16 G.sup.5 341 R.sup.H16 G.sup.6 601 R.sup.H16 G.sup.7 861 R.sup.H16 G.sup.8 82 R.sup.H17 G.sup.5 342 R.sup.H17 G.sup.6 602 R.sup.H17 G.sup.7 862 R.sup.H17 G.sup.8 83 R.sup.H18 G.sup.5 343 R.sup.H18 G.sup.6 603 R.sup.H18 G.sup.7 863 R.sup.H18 G.sup.8 84 R.sup.H19 G.sup.5 344 R.sup.H19 G.sup.6 604 R.sup.H19 G.sup.7 864 R.sup.H19 G.sup.8 85 R.sup.H20 G.sup.5 345 R.sup.H20 G.sup.6 605 R.sup.H20 G.sup.7 865 R.sup.H20 G.sup.8 86 R.sup.H21 G.sup.5 346 R.sup.H21 G.sup.6 606 R.sup.H21 G.sup.7 866 R.sup.H21 G.sup.8 87 R.sup.H22 G.sup.5 347 R.sup.H22 G.sup.6 607 R.sup.H22 G.sup.7 867 R.sup.H22 G.sup.8 88 R.sup.H23 G.sup.5 348 R.sup.H23 G.sup.6 608 R.sup.H23 G.sup.7 868 R.sup.H23 G.sup.8 89 R.sup.H24 G.sup.5 349 R.sup.H24 G.sup.6 609 R.sup.H24 G.sup.7 869 R.sup.H24 G.sup.8 90 R.sup.H25 G.sup.5 350 R.sup.H25 G.sup.6 610 R.sup.H25 G.sup.7 870 R.sup.H25 G.sup.8 91 R.sup.H26 G.sup.5 351 R.sup.H26 G.sup.6 611 R.sup.H26 G.sup.7 871 R.sup.H26 G.sup.8 92 R.sup.H27 G.sup.5 352 R.sup.H27 G.sup.6 612 R.sup.H27 G.sup.7 872 R.sup.H27 G.sup.8 93 R.sup.H28 G.sup.5 353 R.sup.H28 G.sup.6 613 R.sup.H28 G.sup.7 873 R.sup.H28 G.sup.8 94 R.sup.H29 G.sup.5 354 R.sup.H29 G.sup.6 614 R.sup.H29 G.sup.7 874 R.sup.H29 G.sup.8 95 R.sup.H30 G.sup.5 355 R.sup.H30 G.sup.6 615 R.sup.H30 G.sup.7 875 R.sup.H30 G.sup.8 96 R.sup.H31 G.sup.5 356 R.sup.H31 G.sup.6 616 R.sup.H31 G.sup.7 876 R.sup.H31 G.sup.8 97 R.sup.H32 G.sup.5 357 R.sup.H32 G.sup.6 617 R.sup.H32 G.sup.7 877 R.sup.H32 G.sup.8 98 R.sup.H33 G.sup.5 358 R.sup.H33 G.sup.6 618 R.sup.H33 G.sup.7 878 R.sup.H33 G.sup.8 99 R.sup.H34 G.sup.5 359 R.sup.H34 G.sup.6 619 R.sup.H34 G.sup.7 879 R.sup.H34 G.sup.8 100 R.sup.H35 G.sup.5 360 R.sup.H35 G.sup.6 620 R.sup.H35 G.sup.7 880 R.sup.H35 G.sup.8 101 R.sup.H36 G.sup.5 361 R.sup.H36 G.sup.6 621 R.sup.H36 G.sup.7 881 R.sup.H36 G.sup.8 102 R.sup.H37 G.sup.5 362 R.sup.H37 G.sup.6 622 R.sup.H37 G.sup.7 882 R.sup.H37 G.sup.8 103 R.sup.H38 G.sup.5 363 R.sup.H38 G.sup.6 623 R.sup.H38 G.sup.7 883 R.sup.H38 G.sup.8 104 R.sup.H39 G.sup.5 364 R.sup.H39 G.sup.6 624 R.sup.H39 G.sup.7 884 R.sup.H39 G.sup.8 105 R.sup.H40 G.sup.5 365 R.sup.H40 G.sup.6 625 R.sup.H40 G.sup.7 885 R.sup.H40 G.sup.8 106 R.sup.H41 G.sup.5 366 R.sup.H41 G.sup.6 626 R.sup.H41 G.sup.7 886 R.sup.H41 G.sup.8 107 R.sup.H42 G.sup.5 367 R.sup.H42 G.sup.6 627 R.sup.H42 G.sup.7 887 R.sup.H42 G.sup.8 108 R.sup.H43 G.sup.5 368 R.sup.H43 G.sup.6 628 R.sup.H43 G.sup.7 888 R.sup.H43 G.sup.8 109 R.sup.H44 G.sup.5 369 R.sup.H44 G.sup.6 629 R.sup.H44 G.sup.7 889 R.sup.H44 G.sup.8 110 R.sup.H45 G.sup.5 370 R.sup.H45 G.sup.6 630 R.sup.H45 G.sup.7 890 R.sup.H45 G.sup.8 111 R.sup.H46 G.sup.5 371 R.sup.H46 G.sup.6 631 R.sup.H46 G.sup.7 891 R.sup.H46 G.sup.8 112 R.sup.H47 G.sup.5 372 R.sup.H47 G.sup.6 632 R.sup.H47 G.sup.7 892 R.sup.H47 G.sup.8 113 R.sup.H48 G.sup.5 373 R.sup.H48 G.sup.6 633 R.sup.H48 G.sup.7 893 R.sup.H48 G.sup.8 114 R.sup.H49 G.sup.5 374 R.sup.H49 G.sup.6 634 R.sup.H49 G.sup.7 894 R.sup.H49 G.sup.8 115 R.sup.H50 G.sup.5 375 R.sup.H50 G.sup.6 635 R.sup.H50 G.sup.7 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R.sup.H62 G.sup.5 387 R.sup.H62 G.sup.6 647 R.sup.H62 G.sup.7 907 R.sup.H62 G.sup.8 128 R.sup.H63 G.sup.5 388 R.sup.H63 G.sup.6 648 R.sup.H63 G.sup.7 908 R.sup.H63 G.sup.8 129 R.sup.H64 G.sup.5 389 R.sup.H64 G.sup.6 649 R.sup.H64 G.sup.7 909 R.sup.H64 G.sup.8 130 R.sup.H65 G.sup.5 390 R.sup.H65 G.sup.6 650 R.sup.H65 G.sup.7 910 R.sup.H65 G.sup.8 131 R.sup.H1 G.sup.9 391 R.sup.H1 G.sup.10 651 R.sup.H1 G.sup.11 911 R.sup.H1 G.sup.12 132 R.sup.H2 G.sup.9 392 R.sup.H2 G.sup.10 652 R.sup.H2 G.sup.11 912 R.sup.H2 G.sup.12 133 R.sup.H3 G.sup.9 393 R.sup.H3 G.sup.10 653 R.sup.H3 G.sup.11 913 R.sup.H3 G.sup.12 134 R.sup.H4 G.sup.9 394 R.sup.H4 G.sup.10 654 R.sup.H4 G.sup.11 914 R.sup.H4 G.sup.12 135 R.sup.H5 G.sup.9 395 R.sup.H5 G.sup.10 655 R.sup.H5 G.sup.11 915 R.sup.H5 G.sup.12 136 R.sup.H6 G.sup.9 396 R.sup.H6 G.sup.10 656 R.sup.H6 G.sup.11 916 R.sup.H6 G.sup.12 137 R.sup.H7 G.sup.9 397 R.sup.H7 G.sup.10 657 R.sup.H7 G.sup.11 917 R.sup.H7 G.sup.12 138 R.sup.H8 G.sup.9 398 R.sup.H8 G.sup.10 658 R.sup.H8 G.sup.11 918 R.sup.H8 G.sup.12 139 R.sup.H9 G.sup.9 399 R.sup.H9 G.sup.10 659 R.sup.H9 G.sup.11 919 R.sup.H9 G.sup.12 140 R.sup.H10 G.sup.9 400 R.sup.H10 G.sup.10 660 R.sup.H10 G.sup.11 920 R.sup.H10 G.sup.12 141 R.sup.H11 G.sup.9 401 R.sup.H11 G.sup.10 661 R.sup.H11 G.sup.11 921 R.sup.H11 G.sup.12 142 R.sup.H12 G.sup.9 402 R.sup.H12 G.sup.10 662 R.sup.H12 G.sup.11 922 R.sup.H12 G.sup.12 143 R.sup.H13 G.sup.9 403 R.sup.H13 G.sup.10 663 R.sup.H13 G.sup.11 923 R.sup.H13 G.sup.12 144 R.sup.H14 G.sup.9 404 R.sup.H14 G.sup.10 664 R.sup.H14 G.sup.11 924 R.sup.H14 G.sup.12 145 R.sup.H15 G.sup.9 405 R.sup.H15 G.sup.10 665 R.sup.H15 G.sup.11 925 R.sup.H15 G.sup.12 146 R.sup.H16 G.sup.9 406 R.sup.H16 G.sup.10 666 R.sup.H16 G.sup.11 926 R.sup.H16 G.sup.12 147 R.sup.H17 G.sup.9 407 R.sup.H17 G.sup.10 667 R.sup.H17 G.sup.11 927 R.sup.H17 G.sup.12 148 R.sup.H18 G.sup.9 408 R.sup.H18 G.sup.10 668 R.sup.H18 G.sup.11 928 R.sup.H18 G.sup.12 149 R.sup.H19 G.sup.9 409 R.sup.H19 G.sup.10 669 R.sup.H19 G.sup.11 929 R.sup.H19 G.sup.12 150 R.sup.H20 G.sup.9 410 R.sup.H20 G.sup.10 670 R.sup.H20 G.sup.11 930 R.sup.H20 G.sup.12 151 R.sup.H21 G.sup.9 411 R.sup.H21 G.sup.10 671 R.sup.H21 G.sup.11 931 R.sup.H21 G.sup.12 152 R.sup.H22 G.sup.9 412 R.sup.H22 G.sup.10 672 R.sup.H22 G.sup.11 932 R.sup.H22 G.sup.12 153 R.sup.H23 G.sup.9 413 R.sup.H23 G.sup.10 673 R.sup.H23 G.sup.11 933 R.sup.H23 G.sup.12 154 R.sup.H24 G.sup.9 414 R.sup.H24 G.sup.10 674 R.sup.H24 G.sup.11 934 R.sup.H24 G.sup.12 155 R.sup.H25 G.sup.9 415 R.sup.H25 G.sup.10 675 R.sup.H25 G.sup.11 935 R.sup.H25 G.sup.12 156 R.sup.H26 G.sup.9 416 R.sup.H26 G.sup.10 676 R.sup.H26 G.sup.11 936 R.sup.H26 G.sup.12 157 R.sup.H27 G.sup.9 417 R.sup.H27 G.sup.10 677 R.sup.H27 G.sup.11 937 R.sup.H27 G.sup.12 158 R.sup.H28 G.sup.9 418 R.sup.H28 G.sup.10 678 R.sup.H28 G.sup.11 938 R.sup.H28 G.sup.12 159 R.sup.H29 G.sup.9 419 R.sup.H29 G.sup.10 679 R.sup.H29 G.sup.11 939 R.sup.H29 G.sup.12 160 R.sup.H30 G.sup.9 420 R.sup.H30 G.sup.10 680 R.sup.H30 G.sup.11 940 R.sup.H30 G.sup.12 161 R.sup.H31 G.sup.9 421 R.sup.H31 G.sup.10 681 R.sup.H31 G.sup.11 941 R.sup.H31 G.sup.12 162 R.sup.H32 G.sup.9 422 R.sup.H32 G.sup.10 682 R.sup.H32 G.sup.11 942 R.sup.H32 G.sup.12 163 R.sup.H33 G.sup.9 423 R.sup.H33 G.sup.10 683 R.sup.H33 G.sup.11 943 R.sup.H33 G.sup.12 164 R.sup.H34 G.sup.9 424 R.sup.H34 G.sup.10 684 R.sup.H34 G.sup.11 944 R.sup.H34 G.sup.12 165 R.sup.H35 G.sup.9 425 R.sup.H35 G.sup.10 685 R.sup.H35 G.sup.11 945 R.sup.H35 G.sup.12 166 R.sup.H36 G.sup.9 426 R.sup.H36 G.sup.10 686 R.sup.H36 G.sup.11 946 R.sup.H36 G.sup.12 167 R.sup.H37 G.sup.9 427 R.sup.H37 G.sup.10 687 R.sup.H37 G.sup.11 947 R.sup.H37 G.sup.12 168 R.sup.H38 G.sup.9 428 R.sup.H38 G.sup.10 688 R.sup.H38 G.sup.11 948 R.sup.H38 G.sup.12 169 R.sup.H39 G.sup.9 429 R.sup.H39 G.sup.10 689 R.sup.H39 G.sup.11 949 R.sup.H39 G.sup.12 170 R.sup.H40 G.sup.9 430 R.sup.H40 G.sup.10 690 R.sup.H40 G.sup.11 950 R.sup.H40 G.sup.12 171 R.sup.H41 G.sup.9 431 R.sup.H41 G.sup.10 691 R.sup.H41 G.sup.11 951 R.sup.H41 G.sup.12 172 R.sup.H42 G.sup.9 432 R.sup.H42 G.sup.10 692 R.sup.H42 G.sup.11 952 R.sup.H42 G.sup.12 173 R.sup.H43 G.sup.9 433 R.sup.H43 G.sup.10 693 R.sup.H43 G.sup.11 953 R.sup.H43 G.sup.12 174 R.sup.H44 G.sup.9 434 R.sup.H44 G.sup.10 694 R.sup.H44 G.sup.11 954 R.sup.H44 G.sup.12 175 R.sup.H45 G.sup.9 435 R.sup.H45 G.sup.10 695 R.sup.H45 G.sup.11 955 R.sup.H45 G.sup.12 176 R.sup.H46 G.sup.9 436 R.sup.H46 G.sup.10 696 R.sup.H46 G.sup.11 956 R.sup.H46 G.sup.12 177 R.sup.H47 G.sup.9 437 R.sup.H47 G.sup.10 697 R.sup.H47 G.sup.11 957 R.sup.H47 G.sup.12 178 R.sup.H48 G.sup.9 438 R.sup.H48 G.sup.10 698 R.sup.H48 G.sup.11 958 R.sup.H48 G.sup.12 179 R.sup.H49 G.sup.9 439 R.sup.H49 G.sup.10 699 R.sup.H49 G.sup.11 959 R.sup.H49 G.sup.12 180 R.sup.H50 G.sup.9 440 R.sup.H50 G.sup.10 700 R.sup.H50 G.sup.11 960 R.sup.H50 G.sup.12 181 R.sup.H51 G.sup.9 441 R.sup.H51 G.sup.10 701 R.sup.H51 G.sup.11 961 R.sup.H51 G.sup.12 182 R.sup.H52 G.sup.9 442 R.sup.H52 G.sup.10 702 R.sup.H52 G.sup.11 962 R.sup.H52 G.sup.12 183 R.sup.H53 G.sup.9 443 R.sup.H53 G.sup.10 703 R.sup.H53 G.sup.11 963 R.sup.H53 G.sup.12 184 R.sup.H54 G.sup.9 444 R.sup.H54 G.sup.10 704 R.sup.H54 G.sup.11 964 R.sup.H54 G.sup.12 185 R.sup.H55 G.sup.9 445 R.sup.H55 G.sup.10 705 R.sup.H55 G.sup.11 965 R.sup.H55 G.sup.12 186 R.sup.H56 G.sup.9 446 R.sup.H56 G.sup.10 706 R.sup.H56 G.sup.11 966 R.sup.H56 G.sup.12 187 R.sup.H57 G.sup.9 447 R.sup.H57 G.sup.10 707 R.sup.H57 G.sup.11 967 R.sup.H57 G.sup.12 188 R.sup.H58 G.sup.9 448 R.sup.H58 G.sup.10 708 R.sup.H58 G.sup.11 968 R.sup.H58 G.sup.12 189 R.sup.H59 G.sup.9 449 R.sup.H59 G.sup.10 709 R.sup.H59 G.sup.11 969 R.sup.H59 G.sup.12 190 R.sup.H60 G.sup.9 450 R.sup.H60 G.sup.10 710 R.sup.H60 G.sup.11 970 R.sup.H60 G.sup.12 191 R.sup.H61 G.sup.9 451 R.sup.H61 G.sup.10 711 R.sup.H61 G.sup.11 971 R.sup.H61 G.sup.12 192 R.sup.H62 G.sup.9 452 R.sup.H62 G.sup.10 712 R.sup.H62 G.sup.11 972 R.sup.H62 G.sup.12 193 R.sup.H63 G.sup.9 453 R.sup.H63 G.sup.10 713 R.sup.H63 G.sup.11 973 R.sup.H63 G.sup.12 194 R.sup.H64 G.sup.9 454 R.sup.H64 G.sup.10 714 R.sup.H64 G.sup.11 974 R.sup.H64 G.sup.12 195 R.sup.H65 G.sup.9 455 R.sup.H65 G.sup.10 715 R.sup.H65 G.sup.11 975 R.sup.H65 G.sup.12 196 R.sup.H1 G.sup.13 456 R.sup.H1 G.sup.14 716 R.sup.H1 G.sup.15 976 R.sup.H1 G.sup.16 197 R.sup.H2 G.sup.13 457 R.sup.H2 G.sup.14 717 R.sup.H2 G.sup.15 977 R.sup.H2 G.sup.16 198 R.sup.H3 G.sup.13 458 R.sup.H3 G.sup.14 718 R.sup.H3 G.sup.15 978 R.sup.H3 G.sup.16 199 R.sup.H4 G.sup.13 459 R.sup.H4 G.sup.14 719 R.sup.H4 G.sup.15 979 R.sup.H4 G.sup.16 200 R.sup.H5 G.sup.13 460 R.sup.H5 G.sup.14 720 R.sup.H5 G.sup.15 980 R.sup.H5 G.sup.16 201 R.sup.H6 G.sup.13 461 R.sup.H6 G.sup.14 721 R.sup.H6 G.sup.15 981 R.sup.H6 G.sup.16 202 R.sup.H7 G.sup.13 462 R.sup.H7 G.sup.14 722 R.sup.H7 G.sup.15 982 R.sup.H7 G.sup.16 203 R.sup.H8 G.sup.13 463 R.sup.H8 G.sup.14 723 R.sup.H8 G.sup.15 983 R.sup.H8 G.sup.16 204 R.sup.H9 G.sup.13 464 R.sup.H9 G.sup.14 724 R.sup.H9 G.sup.15 984 R.sup.H9 G.sup.16 205 R.sup.H10 G.sup.13 465 R.sup.H10 G.sup.14 725 R.sup.H10 G.sup.15 985 R.sup.H10 G.sup.16 206 R.sup.H11 G.sup.13 466 R.sup.H11 G.sup.14 726 R.sup.H11 G.sup.15 986 R.sup.H11 G.sup.16 207 R.sup.H12 G.sup.13 467 R.sup.H12 G.sup.14 727 R.sup.H12 G.sup.15 987 R.sup.H12 G.sup.16 208 R.sup.H13 G.sup.13 468 R.sup.H13 G.sup.14 728 R.sup.H13 G.sup.15 988 R.sup.H13 G.sup.16 209 R.sup.H14 G.sup.13 469 R.sup.H14 G.sup.14 729 R.sup.H14 G.sup.15 989 R.sup.H14 G.sup.16 210 R.sup.H15 G.sup.13 470 R.sup.H15 G.sup.14 730 R.sup.H15 G.sup.15 990 R.sup.H15 G.sup.16 211 R.sup.H16 G.sup.13 471 R.sup.H16 G.sup.14 731 R.sup.H16 G.sup.15 991 R.sup.H16 G.sup.16 212 R.sup.H17 G.sup.13 472 R.sup.H17 G.sup.14 732 R.sup.H17 G.sup.15 992 R.sup.H17 G.sup.16 213 R.sup.H18 G.sup.13 473 R.sup.H18 G.sup.14 733 R.sup.H18 G.sup.15 993 R.sup.H18 G.sup.16 214 R.sup.H19 G.sup.13 474 R.sup.H19 G.sup.14 734 R.sup.H19 G.sup.15 994 R.sup.H19 G.sup.16 215 R.sup.H20 G.sup.13 475 R.sup.H20 G.sup.14 735 R.sup.H20 G.sup.15 995 R.sup.H20 G.sup.16 216 R.sup.H21 G.sup.13 476 R.sup.H21 G.sup.14 736 R.sup.H21 G.sup.15 996 R.sup.H21 G.sup.16 217 R.sup.H22 G.sup.13 477 R.sup.H22 G.sup.14 737 R.sup.H22 G.sup.15 997 R.sup.H22 G.sup.16 218 R.sup.H23 G.sup.13 478 R.sup.H23 G.sup.14 738 R.sup.H23 G.sup.15 998 R.sup.H23 G.sup.16 219 R.sup.H24 G.sup.13 479 R.sup.H24 G.sup.14 739 R.sup.H24 G.sup.15 999 R.sup.H24 G.sup.16 220 R.sup.H25 G.sup.13 480 R.sup.H25 G.sup.14 740 R.sup.H25 G.sup.15 1000 R.sup.H25 G.sup.16 221 R.sup.H26 G.sup.13 481 R.sup.H26 G.sup.14 741 R.sup.H26 G.sup.15 1001 R.sup.H26 G.sup.16 222 R.sup.H27 G.sup.13 482 R.sup.H27 G.sup.14 742 R.sup.H27 G.sup.15 1002 R.sup.H27 G.sup.16 223 R.sup.H28 G.sup.13 483 R.sup.H28 G.sup.14 743 R.sup.H28 G.sup.15 1003 R.sup.H28 G.sup.16 224 R.sup.H29 G.sup.13 484 R.sup.H29 G.sup.14 744 R.sup.H29 G.sup.15 1004 R.sup.H29 G.sup.16 225 R.sup.H30 G.sup.13 485 R.sup.H30 G.sup.14 745 R.sup.H30 G.sup.15 1005 R.sup.H30 G.sup.16 226 R.sup.H31 G.sup.13 486 R.sup.H31 G.sup.14 746 R.sup.H31 G.sup.15 1006 R.sup.H31 G.sup.16 227 R.sup.H32 G.sup.13 487 R.sup.H32 G.sup.14 747 R.sup.H32 G.sup.15 1007 R.sup.H32 G.sup.16 228 R.sup.H33 G.sup.13 488 R.sup.H33 G.sup.14 748 R.sup.H33 G.sup.15 1008 R.sup.H33 G.sup.16 229 R.sup.H34 G.sup.13 489 R.sup.H34 G.sup.14 749 R.sup.H34 G.sup.15 1009 R.sup.H34 G.sup.16 230 R.sup.H35 G.sup.13 490 R.sup.H35 G.sup.14 750 R.sup.H35 G.sup.15 1010 R.sup.H35 G.sup.16 231 R.sup.H36 G.sup.13 491 R.sup.H36 G.sup.14 751 R.sup.H36 G.sup.15 1011 R.sup.H36 G.sup.16 232 R.sup.H37 G.sup.13 492 R.sup.H37 G.sup.14 752 R.sup.H37 G.sup.15 1012 R.sup.H37 G.sup.16 233 R.sup.H38 G.sup.13 493 R.sup.H38 G.sup.14 753 R.sup.H38 G.sup.15 1013 R.sup.H38 G.sup.16 234 R.sup.H39 G.sup.13 494 R.sup.H39 G.sup.14 754 R.sup.H39 G.sup.15 1014 R.sup.H39 G.sup.16 235 R.sup.H40 G.sup.13 495 R.sup.H40 G.sup.14 755 R.sup.H40 G.sup.15 1015 R.sup.H40 G.sup.16 236 R.sup.H41 G.sup.13 496 R.sup.H41 G.sup.14 756 R.sup.H41 G.sup.15 1016 R.sup.H41 G.sup.16 237 R.sup.H42 G.sup.13 497 R.sup.H42 G.sup.14 757 R.sup.H42 G.sup.15 1017 R.sup.H42 G.sup.16 238 R.sup.H43 G.sup.13 498 R.sup.H43 G.sup.14 758 R.sup.H43 G.sup.15 1018 R.sup.H43 G.sup.16 239 R.sup.H44 G.sup.13 499 R.sup.H44 G.sup.14 759 R.sup.H44 G.sup.15 1019 R.sup.H44 G.sup.16 240 R.sup.H45 G.sup.13 500 R.sup.H45 G.sup.14 760 R.sup.H45 G.sup.15 1020 R.sup.H45 G.sup.16 241 R.sup.H46 G.sup.13 501 R.sup.H46 G.sup.14 761 R.sup.H46 G.sup.15 1021 R.sup.H46 G.sup.16 242 R.sup.H47 G.sup.13 502 R.sup.H47 G.sup.14 762 R.sup.H47 G.sup.15 1022 R.sup.H47 G.sup.16 243 R.sup.H48 G.sup.13 503 R.sup.H48 G.sup.14 763 R.sup.H48 G.sup.15 1023 R.sup.H48 G.sup.16 244 R.sup.H49 G.sup.13 504 R.sup.H49 G.sup.14 764 R.sup.H49 G.sup.15 1024 R.sup.H49 G.sup.16 245 R.sup.H50 G.sup.13 505 R.sup.H50 G.sup.14 765 R.sup.H50 G.sup.15 1025 R.sup.H50 G.sup.16 246 R.sup.H51 G.sup.13 506 R.sup.H51 G.sup.14 766 R.sup.H51 G.sup.15 1026 R.sup.H51 G.sup.16 247 R.sup.H52 G.sup.13 507 R.sup.H52 G.sup.14 767 R.sup.H52 G.sup.15 1027 R.sup.H52 G.sup.16 248 R.sup.H53 G.sup.13 508 R.sup.H53 G.sup.14 768 R.sup.H53 G.sup.15 1028 R.sup.H53 G.sup.16 249 R.sup.H54 G.sup.13 509 R.sup.H54 G.sup.14 769 R.sup.H54 G.sup.15 1029 R.sup.H54 G.sup.16 250 R.sup.H55 G.sup.13 510 R.sup.H55 G.sup.14 770 R.sup.H55 G.sup.15 1030 R.sup.H55 G.sup.16 251 R.sup.H56 G.sup.13 511 R.sup.H56 G.sup.14 771 R.sup.H56 G.sup.15 1031 R.sup.H56 G.sup.16 252 R.sup.H57 G.sup.13 512 R.sup.H57 G.sup.14 772 R.sup.H57 G.sup.15 1032 R.sup.H57 G.sup.16 253 R.sup.H58 G.sup.13 513 R.sup.H58 G.sup.14 773 R.sup.H58 G.sup.15 1033 R.sup.H58 G.sup.16 254 R.sup.H59 G.sup.13 514 R.sup.H59 G.sup.14 774 R.sup.H59 G.sup.15 1034 R.sup.H59 G.sup.16 255 R.sup.H60 G.sup.13 515 R.sup.H60 G.sup.14 775 R.sup.H60 G.sup.15 1035 R.sup.H60 G.sup.16 256 R.sup.H61 G.sup.13 516 R.sup.H61 G.sup.14 776 R.sup.H61 G.sup.15 1036 R.sup.H61 G.sup.16 257 R.sup.H62 G.sup.13 517 R.sup.H62 G.sup.14 777 R.sup.H62 G.sup.15 1037 R.sup.H62 G.sup.16 258 R.sup.H63 G.sup.13 518 R.sup.H63 G.sup.14 778 R.sup.H63 G.sup.15 1038 R.sup.H63 G.sup.16 259 R.sup.H64 G.sup.13 519 R.sup.H64 G.sup.14 779 R.sup.H64 G.sup.15 1039 R.sup.H64 G.sup.16 260 R.sup.H65 G.sup.13 520 R.sup.H65 G.sup.14 780 R.sup.H65 G.sup.15 1040 R.sup.H65 G.sup.16 1041 R.sup.H1 G.sup.17 1042 R.sup.H33 G.sup.17 1043 R.sup.H1 G.sup.18 1044 R.sup.H33 G.sup.18 1045 R.sup.H2 G.sup.17 1046 R.sup.H34 G.sup.17 1047 R.sup.H2 G.sup.18 1048 R.sup.H34 G.sup.18 1049 R.sup.H3 G.sup.17 1050 R.sup.H35 G.sup.17 1051 R.sup.H3 G.sup.18 1052 R.sup.H35 G.sup.18 1053 R.sup.H4 G.sup.17 1054 R.sup.H36 G.sup.17 1055 R.sup.H4 G.sup.18 1056 R.sup.H36 G.sup.18 1057 R.sup.H5 G.sup.17 1058 R.sup.H37 G.sup.17 1059 R.sup.H5 G.sup.18 1060 R.sup.H37 G.sup.18 1061 R.sup.H6 G.sup.17 1062 R.sup.H38 G.sup.17 1063 R.sup.H6 G.sup.18 1064 R.sup.H38 G.sup.18 1065 R.sup.H7 G.sup.17 1066 R.sup.H39 G.sup.17 1067 R.sup.H7 G.sup.18 1068 R.sup.H39 G.sup.18 1069 R.sup.H8 G.sup.17 1070 R.sup.H40 G.sup.17 1071 R.sup.H8 G.sup.18 1072 R.sup.H40 G.sup.18 1073 R.sup.H9 G.sup.17 1074 R.sup.H41 G.sup.17 1075 R.sup.H9 G.sup.18 1076 R.sup.H41 G.sup.18 1077 R.sup.H10 G.sup.17 1078 R.sup.H42 G.sup.17 1079 R.sup.H10 G.sup.18 1080 R.sup.H42 G.sup.18 1081 R.sup.H11 G.sup.17 1082 R.sup.H43 G.sup.17 1083 R.sup.H11 G.sup.18 1084 R.sup.H43 G.sup.18 1085 R.sup.H12 G.sup.17 1086 R.sup.H44 G.sup.17 1087 R.sup.H12 G.sup.18 1088 R.sup.H44 G.sup.18 1089 R.sup.H13 G.sup.17 1090 R.sup.H45 G.sup.17 1091 R.sup.H13 G.sup.18 1092 R.sup.H45 G.sup.18 1093 R.sup.H14 G.sup.17 1094 R.sup.H46 G.sup.17 1095 R.sup.H14 G.sup.18 1096 R.sup.H46 G.sup.18 1097 R.sup.H15 G.sup.17 1098 R.sup.H47 G.sup.17 1099 R.sup.H15 G.sup.18 1100 R.sup.H47 G.sup.18 1101 R.sup.H16 G.sup.17 1102 R.sup.H48 G.sup.17 1103 R.sup.H16 G.sup.18 1104 R.sup.H48 G.sup.18 1105 R.sup.H17 G.sup.17 1106 R.sup.H49 G.sup.17 1107 R.sup.H17 G.sup.18 1108 R.sup.H49 G.sup.18 1109 R.sup.H18 G.sup.17 1110 R.sup.H50 G.sup.17 1111 R.sup.H18 G.sup.18 1112 R.sup.H50 G.sup.18 1113 R.sup.H19 G.sup.17 1114 R.sup.H51 G.sup.17 1115 R.sup.H19 G.sup.18 1116 R.sup.H51 G.sup.18 1117 R.sup.H20 G.sup.17 1118 R.sup.H52 G.sup.17 1119 R.sup.H20 G.sup.18 1120 R.sup.H52 G.sup.18 1121 R.sup.H21 G.sup.17 1122 R.sup.H53 G.sup.17 1123 R.sup.H21 G.sup.18 1124 R.sup.H53 G.sup.18 1125 R.sup.H22 G.sup.17 1126 R.sup.H54 G.sup.17 1127 R.sup.H22 G.sup.18 1128 R.sup.H54 G.sup.18 1129 R.sup.H23 G.sup.17 1130 R.sup.H55 G.sup.17 1131 R.sup.H23 G.sup.18 1132 R.sup.H55 G.sup.18 1133 R.sup.H24 G.sup.17 1134 R.sup.H56 G.sup.17 1135 R.sup.H24 G.sup.18 1136 R.sup.H56 G.sup.18 1137 R.sup.H25 G.sup.17 1138 R.sup.H57 G.sup.17 1139 R.sup.H25 G.sup.18 1140 R.sup.H57 G.sup.18 1141 R.sup.H26 G.sup.17 1142 R.sup.H58 G.sup.17 1143 R.sup.H26 G.sup.18 1144 R.sup.H58 G.sup.18 1145 R.sup.H27 G.sup.17 1146 R.sup.H59 G.sup.17 1147 R.sup.H27 G.sup.18 1148 R.sup.H59 G.sup.18 1149 R.sup.H28 G.sup.17 1150 R.sup.H60 G.sup.17 1151 R.sup.H28 G.sup.18 1152 R.sup.H60 G.sup.18 1153 R.sup.H29 G.sup.17 1154 R.sup.H61 G.sup.17 1155 R.sup.H29 G.sup.18 1156 R.sup.H61 G.sup.18 1157 R.sup.H30 G.sup.17 1158 R.sup.H62 G.sup.17 1159 R.sup.H30 G.sup.18 1160 R.sup.H62 G.sup.18 1161 R.sup.H31 G.sup.17 1162 R.sup.H63 G.sup.17 1163 R.sup.H31 G.sup.18 1164 R.sup.H63 G.sup.18 1165 R.sup.H32 G.sup.17 1166 R.sup.H64 G.sup.17 1167 R.sup.H32 G.sup.18 1168 R.sup.H64 G.sup.18 1169 R.sup.H65 G.sup.17 1170 R.sup.H65 G.sup.18
wherein R.sup.H1 to R.sup.H65 have the following structures:
##STR00084## ##STR00085## ##STR00086## ##STR00087## ##STR00088## ##STR00089## ##STR00090##
wherein G.sup.1 to G.sup.16 have the following structures:
##STR00091## ##STR00092## ##STR00093##
[0068] In some embodiments of the OLED where the first emitter is Compound B, Compound C, Compound D, or Compound E, all having the formula (L.sub.B).sub.nIr(L.sup.3-L.sup.4).sub.3−n the ligand (L.sup.3-L.sup.4) is selected from the group consisting of:
L.sub.Cj-1 having a structure based on formula
##STR00094##
and
L.sub.Cj-11 having a structure based on formula
##STR00095##
wherein j is an integer from 1 to 1416, wherein for each L.sub.Cj in L.sub.Cj-1 and L.sub.Cj-11, R.sup.201 and R.sup.202 are each independently defined as follows:
TABLE-US-00004 L.sub.Cj R.sup.201 R.sup.202 L.sub.Cj R.sup.201 R.sup.202 L.sub.Cj R.sup.201 R.sup.202 L.sub.Cj R.sup.201 R.sup.202 L.sub.C1 R.sup.D1 R.sup.D1 L.sub.C193 R.sup.D1 R.sup.D3 L.sub.C385 R.sup.D17 R.sup.D40 L.sub.C577 R.sup.D143 R.sup.D120 L.sub.C2 R.sup.D2 R.sup.D2 L.sub.C194 R.sup.D1 R.sup.D4 L.sub.C386 R.sup.D17 R.sup.D41 L.sub.C578 R.sup.D143 R.sup.D133 L.sub.C3 R.sup.D3 R.sup.D3 L.sub.C195 R.sup.D1 R.sup.D5 L.sub.C387 R.sup.D17 R.sup.D42 L.sub.C579 R.sup.D143 R.sup.D134 L.sub.C4 R.sup.D4 R.sup.D4 L.sub.C196 R.sup.D1 R.sup.D9 L.sub.C388 R.sup.D17 R.sup.D43 L.sub.C580 R.sup.D143 R.sup.D135 L.sub.C5 R.sup.D5 R.sup.D5 L.sub.C197 R.sup.D1 R.sup.D10 L.sub.C389 R.sup.D17 R.sup.D48 L.sub.C581 R.sup.D143 R.sup.D136 L.sub.C6 R.sup.D6 R.sup.D6 L.sub.C198 R.sup.D1 R.sup.D17 L.sub.C390 R.sup.D17 R.sup.D49 L.sub.C582 R.sup.D143 R.sup.D144 L.sub.C7 R.sup.D7 R.sup.D7 L.sub.C199 R.sup.D1 R.sup.D18 L.sub.C391 R.sup.D17 R.sup.D50 L.sub.C583 R.sup.D143 R.sup.D145 L.sub.C8 R.sup.D8 R.sup.D8 L.sub.C200 R.sup.D1 R.sup.D20 L.sub.C392 R.sup.D17 R.sup.D54 L.sub.C584 R.sup.D143 R.sup.D146 L.sub.C9 R.sup.D9 R.sup.D9 L.sub.C201 R.sup.D1 R.sup.D22 L.sub.C393 R.sup.D17 R.sup.D55 L.sub.C585 R.sup.D143 R.sup.D147 L.sub.C10 R.sup.D10 R.sup.D10 L.sub.C202 R.sup.D1 R.sup.D37 L.sub.C394 R.sup.D17 R.sup.D58 L.sub.C586 R.sup.D143 R.sup.D149 L.sub.C11 R.sup.D11 R.sup.D11 L.sub.C203 R.sup.D1 R.sup.D40 L.sub.C395 R.sup.D17 R.sup.D59 L.sub.C587 R.sup.D143 R.sup.D151 L.sub.C12 R.sup.D12 R.sup.D12 L.sub.C204 R.sup.D1 R.sup.D41 L.sub.C396 R.sup.D17 R.sup.D78 L.sub.C588 R.sup.D143 R.sup.D154 L.sub.C13 R.sup.D13 R.sup.D13 L.sub.C205 R.sup.D1 R.sup.D42 L.sub.C397 R.sup.D17 R.sup.D79 L.sub.C589 R.sup.D143 R.sup.D155 L.sub.C14 R.sup.D14 R.sup.D14 L.sub.C206 R.sup.D1 R.sup.D43 L.sub.C398 R.sup.D17 R.sup.D81 L.sub.C590 R.sup.D143 R.sup.D161 L.sub.C15 R.sup.D15 R.sup.D15 L.sub.C207 R.sup.D1 R.sup.D48 L.sub.C399 R.sup.D17 R.sup.D87 L.sub.C591 R.sup.D143 R.sup.D175 L.sub.C16 R.sup.D16 R.sup.D16 L.sub.C208 R.sup.D1 R.sup.D49 L.sub.C400 R.sup.D17 R.sup.D88 L.sub.C592 R.sup.D144 R.sup.D3 L.sub.C17 R.sup.D17 R.sup.D17 L.sub.C209 R.sup.D1 R.sup.D50 L.sub.C401 R.sup.D17 R.sup.D89 L.sub.C593 R.sup.D144 R.sup.D5 L.sub.C18 R.sup.D18 R.sup.D18 L.sub.C210 R.sup.D1 R.sup.D54 L.sub.C402 R.sup.D17 R.sup.D93 L.sub.C594 R.sup.D144 R.sup.D17 L.sub.C19 R.sup.D19 R.sup.D19 L.sub.C211 R.sup.D1 R.sup.D55 L.sub.C403 R.sup.D17 R.sup.D116 L.sub.C595 R.sup.D144 R.sup.D18 L.sub.C20 R.sup.D20 R.sup.D20 L.sub.C212 R.sup.D1 R.sup.D58 L.sub.C404 R.sup.D17 R.sup.D117 L.sub.C596 R.sup.D144 R.sup.D20 L.sub.C21 R.sup.D21 R.sup.D21 L.sub.C213 R.sup.D1 R.sup.D59 L.sub.C405 R.sup.D17 R.sup.D118 L.sub.C597 R.sup.D144 R.sup.D22 L.sub.C22 R.sup.D22 R.sup.D22 L.sub.C214 R.sup.D1 R.sup.D78 L.sub.C406 R.sup.D17 R.sup.D119 L.sub.C598 R.sup.D144 R.sup.D37 L.sub.C23 R.sup.D23 R.sup.D23 L.sub.C215 R.sup.D1 R.sup.D79 L.sub.C407 R.sup.D17 R.sup.D120 L.sub.C599 R.sup.D144 R.sup.D40 L.sub.C24 R.sup.D24 R.sup.D24 L.sub.C216 R.sup.D1 R.sup.D81 L.sub.C408 R.sup.D17 R.sup.D133 L.sub.C600 R.sup.D144 R.sup.D41 L.sub.C25 R.sup.D25 R.sup.D25 L.sub.C217 R.sup.D1 R.sup.D87 L.sub.C409 R.sup.D17 R.sup.D134 L.sub.C601 R.sup.D144 R.sup.D42 L.sub.C26 R.sup.D26 R.sup.D26 L.sub.C218 R.sup.D1 R.sup.D88 L.sub.C410 R.sup.D17 R.sup.D135 L.sub.C602 R.sup.D144 R.sup.D43 L.sub.C27 R.sup.D27 R.sup.D27 L.sub.C219 R.sup.D1 R.sup.D89 L.sub.C411 R.sup.D17 R.sup.D136 L.sub.C603 R.sup.D144 R.sup.D48 L.sub.C28 R.sup.D28 R.sup.D28 L.sub.C220 R.sup.D1 R.sup.D93 L.sub.C412 R.sup.D17 R.sup.D143 L.sub.C604 R.sup.D144 R.sup.D49 L.sub.C29 R.sup.D29 R.sup.D29 L.sub.C221 R.sup.D1 R.sup.D116 L.sub.C413 R.sup.D17 R.sup.D144 L.sub.C605 R.sup.D144 R.sup.D54 L.sub.C30 R.sup.D30 R.sup.D30 L.sub.C222 R.sup.D1 R.sup.D117 L.sub.C414 R.sup.D17 R.sup.D145 L.sub.C606 R.sup.D144 R.sup.D58 L.sub.C31 R.sup.D31 R.sup.D31 L.sub.C223 R.sup.D1 R.sup.D118 L.sub.C415 R.sup.D17 R.sup.D146 L.sub.C607 R.sup.D144 R.sup.D59 L.sub.C32 R.sup.D32 R.sup.D32 L.sub.C224 R.sup.D1 R.sup.D119 L.sub.C416 R.sup.D17 R.sup.D147 L.sub.C608 R.sup.D144 R.sup.D78 L.sub.C33 R.sup.D33 R.sup.D33 L.sub.C225 R.sup.D1 R.sup.D120 L.sub.C417 R.sup.D17 R.sup.D149 L.sub.C609 R.sup.D144 R.sup.D79 L.sub.C34 R.sup.D34 R.sup.D34 L.sub.C226 R.sup.D1 R.sup.D133 L.sub.C418 R.sup.D17 R.sup.D151 L.sub.C610 R.sup.D144 R.sup.D81 L.sub.C35 R.sup.D35 R.sup.D35 L.sub.C227 R.sup.D1 R.sup.D134 L.sub.C419 R.sup.D17 R.sup.D154 L.sub.C611 R.sup.D144 R.sup.D87 L.sub.C36 R.sup.D36 R.sup.D36 L.sub.C228 R.sup.D1 R.sup.D135 L.sub.C420 R.sup.D17 R.sup.D155 L.sub.C612 R.sup.D144 R.sup.D88 L.sub.C37 R.sup.D37 R.sup.D37 L.sub.C229 R.sup.D1 R.sup.D136 L.sub.C421 R.sup.D17 R.sup.D161 L.sub.C613 R.sup.D144 R.sup.D89 L.sub.C38 R.sup.D38 R.sup.D38 L.sub.C230 R.sup.D1 R.sup.D143 L.sub.C422 R.sup.D17 R.sup.D175 L.sub.C614 R.sup.D144 R.sup.D93 L.sub.C39 R.sup.D39 R.sup.D39 L.sub.C231 R.sup.D1 R.sup.D144 L.sub.C423 R.sup.D50 R.sup.D3 L.sub.C615 R.sup.D144 R.sup.D116 L.sub.C40 R.sup.D40 R.sup.D40 L.sub.C232 R.sup.D1 R.sup.D145 L.sub.C424 R.sup.D50 R.sup.D5 L.sub.C616 R.sup.D144 R.sup.D117 L.sub.C41 R.sup.D41 R.sup.D41 L.sub.C233 R.sup.D1 R.sup.D146 L.sub.C425 R.sup.D50 R.sup.D18 L.sub.C617 R.sup.D144 R.sup.D118 L.sub.C42 R.sup.D42 R.sup.D42 L.sub.C234 R.sup.D1 R.sup.D147 L.sub.C426 R.sup.D50 R.sup.D20 L.sub.C618 R.sup.D144 R.sup.D119 L.sub.C43 R.sup.D43 R.sup.D43 L.sub.C235 R.sup.D1 R.sup.D149 L.sub.C427 R.sup.D50 R.sup.D22 L.sub.C619 R.sup.D144 R.sup.D120 L.sub.C44 R.sup.D44 R.sup.D44 L.sub.C236 R.sup.D1 R.sup.D151 L.sub.C428 R.sup.D50 R.sup.D37 L.sub.C620 R.sup.D144 R.sup.D133 L.sub.C45 R.sup.D45 R.sup.D45 L.sub.C237 R.sup.D1 R.sup.D154 L.sub.C429 R.sup.D50 R.sup.D40 L.sub.C621 R.sup.D144 R.sup.D134 L.sub.C46 R.sup.D46 R.sup.D46 L.sub.C238 R.sup.D1 R.sup.D155 L.sub.C430 R.sup.D50 R.sup.D41 L.sub.C622 R.sup.D144 R.sup.D135 L.sub.C47 R.sup.D47 R.sup.D47 L.sub.C239 R.sup.D1 R.sup.D161 L.sub.C431 R.sup.D50 R.sup.D42 L.sub.C623 R.sup.D144 R.sup.D136 L.sub.C48 R.sup.D48 R.sup.D48 L.sub.C240 R.sup.D1 R.sup.D175 L.sub.C432 R.sup.D50 R.sup.D43 L.sub.C624 R.sup.D144 R.sup.D145 L.sub.C49 R.sup.D49 R.sup.D49 L.sub.C241 R.sup.D4 R.sup.D3 L.sub.C433 R.sup.D50 R.sup.D48 L.sub.C625 R.sup.D144 R.sup.D146 L.sub.C50 R.sup.D50 R.sup.D50 L.sub.C242 R.sup.D4 R.sup.D5 L.sub.C434 R.sup.D50 R.sup.D49 L.sub.C626 R.sup.D144 R.sup.D147 L.sub.C51 R.sup.D51 R.sup.D51 L.sub.C243 R.sup.D4 R.sup.D9 L.sub.C435 R.sup.D50 R.sup.D54 L.sub.C627 R.sup.D144 R.sup.D149 L.sub.C52 R.sup.D52 R.sup.D52 L.sub.C244 R.sup.D4 R.sup.D10 L.sub.C436 R.sup.D50 R.sup.D55 L.sub.C628 R.sup.D144 R.sup.D151 L.sub.C53 R.sup.D53 R.sup.D53 L.sub.C245 R.sup.D4 R.sup.D17 L.sub.C437 R.sup.D50 R.sup.D58 L.sub.C629 R.sup.D144 R.sup.D154 L.sub.C54 R.sup.D54 R.sup.D54 L.sub.C246 R.sup.D4 R.sup.D18 L.sub.C438 R.sup.D50 R.sup.D59 L.sub.C630 R.sup.D144 R.sup.D155 L.sub.C55 R.sup.D55 R.sup.D55 L.sub.C247 R.sup.D4 R.sup.D20 L.sub.C439 R.sup.D50 R.sup.D78 L.sub.C631 R.sup.D144 R.sup.D161 L.sub.C56 R.sup.D56 R.sup.D56 L.sub.C248 R.sup.D4 R.sup.D22 L.sub.C440 R.sup.D50 R.sup.D79 L.sub.C632 R.sup.D144 R.sup.D175 L.sub.C57 R.sup.D57 R.sup.D57 L.sub.C249 R.sup.D4 R.sup.D37 L.sub.C441 R.sup.D50 R.sup.D81 L.sub.C633 R.sup.D145 R.sup.D3 L.sub.C58 R.sup.D58 R.sup.D58 L.sub.C250 R.sup.D4 R.sup.D40 L.sub.C442 R.sup.D50 R.sup.D87 L.sub.C634 R.sup.D145 R.sup.D5 L.sub.C59 R.sup.D59 R.sup.D59 L.sub.C251 R.sup.D4 R.sup.D41 L.sub.C443 R.sup.D50 R.sup.D88 L.sub.C635 R.sup.D145 R.sup.D17 L.sub.C60 R.sup.D60 R.sup.D60 L.sub.C252 R.sup.D4 R.sup.D42 L.sub.C444 R.sup.D50 R.sup.D89 L.sub.C636 R.sup.D145 R.sup.D18 L.sub.C61 R.sup.D61 R.sup.D61 L.sub.C253 R.sup.D4 R.sup.D43 L.sub.C445 R.sup.D50 R.sup.D93 L.sub.C637 R.sup.D145 R.sup.D20 L.sub.C62 R.sup.D62 R.sup.D62 L.sub.C254 R.sup.D4 R.sup.D48 L.sub.C446 R.sup.D50 R.sup.D116 L.sub.C638 R.sup.D145 R.sup.D22 L.sub.C63 R.sup.D63 R.sup.D63 L.sub.C255 R.sup.D4 R.sup.D49 L.sub.C447 R.sup.D50 R.sup.D117 L.sub.C639 R.sup.D145 R.sup.D37 L.sub.C64 R.sup.D64 R.sup.D64 L.sub.C256 R.sup.D4 R.sup.D50 L.sub.C448 R.sup.D50 R.sup.D118 L.sub.C640 R.sup.D145 R.sup.D40 L.sub.C65 R.sup.D65 R.sup.D65 L.sub.C257 R.sup.D4 R.sup.D54 L.sub.C449 R.sup.D50 R.sup.D119 L.sub.C641 R.sup.D145 R.sup.D41 L.sub.C66 R.sup.D66 R.sup.D66 L.sub.C258 R.sup.D4 R.sup.D55 L.sub.C450 R.sup.D50 R.sup.D120 L.sub.C642 R.sup.D145 R.sup.D42 L.sub.C67 R.sup.D67 R.sup.D67 L.sub.C259 R.sup.D4 R.sup.D58 L.sub.C451 R.sup.D50 R.sup.D133 L.sub.C643 R.sup.D145 R.sup.D43 L.sub.C68 R.sup.D68 R.sup.D68 L.sub.C260 R.sup.D4 R.sup.D59 L.sub.C452 R.sup.D50 R.sup.D134 L.sub.C644 R.sup.D145 R.sup.D48 L.sub.C69 R.sup.D69 R.sup.D69 L.sub.C261 R.sup.D4 R.sup.D78 L.sub.C453 R.sup.D50 R.sup.D135 L.sub.C645 R.sup.D145 R.sup.D49 L.sub.C70 R.sup.D70 R.sup.D70 L.sub.C262 R.sup.D4 R.sup.D79 L.sub.C454 R.sup.D50 R.sup.D136 L.sub.C646 R.sup.D145 R.sup.D54 L.sub.C71 R.sup.D71 R.sup.D71 L.sub.C263 R.sup.D4 R.sup.D81 L.sub.C455 R.sup.D50 R.sup.D143 L.sub.C647 R.sup.D145 R.sup.D58 L.sub.C72 R.sup.D72 R.sup.D72 L.sub.C264 R.sup.D4 R.sup.D87 L.sub.C456 R.sup.D50 R.sup.D144 L.sub.C648 R.sup.D145 R.sup.D59 L.sub.C73 R.sup.D73 R.sup.D73 L.sub.C265 R.sup.D4 R.sup.D88 L.sub.C457 R.sup.D50 R.sup.D145 L.sub.C649 R.sup.D145 R.sup.D78 L.sub.C74 R.sup.D74 R.sup.D74 L.sub.C266 R.sup.D4 R.sup.D89 L.sub.C458 R.sup.D50 R.sup.D146 L.sub.C650 R.sup.D145 R.sup.D79 L.sub.C75 R.sup.D75 R.sup.D75 L.sub.C267 R.sup.D4 R.sup.D93 L.sub.C459 R.sup.D50 R.sup.D147 L.sub.C651 R.sup.D145 R.sup.D81 L.sub.C76 R.sup.D76 R.sup.D76 L.sub.C268 R.sup.D4 R.sup.D116 L.sub.C460 R.sup.D50 R.sup.D149 L.sub.C652 R.sup.D145 R.sup.D87 L.sub.C77 R.sup.D77 R.sup.D77 L.sub.C269 R.sup.D4 R.sup.D117 L.sub.C461 R.sup.D50 R.sup.D151 L.sub.C653 R.sup.D145 R.sup.D88 L.sub.C78 R.sup.D78 R.sup.D78 L.sub.C270 R.sup.D4 R.sup.D118 L.sub.C462 R.sup.D50 R.sup.D154 L.sub.C654 R.sup.D145 R.sup.D89 L.sub.C79 R.sup.D79 R.sup.D79 L.sub.C271 R.sup.D4 R.sup.D119 L.sub.C463 R.sup.D50 R.sup.D155 L.sub.C655 R.sup.D145 R.sup.D93 L.sub.C80 R.sup.D80 R.sup.D80 L.sub.C272 R.sup.D4 R.sup.D120 L.sub.C464 R.sup.D50 R.sup.D161 L.sub.C656 R.sup.D145 R.sup.D116 L.sub.C81 R.sup.D81 R.sup.D81 L.sub.C273 R.sup.D4 R.sup.D133 L.sub.C465 R.sup.D50 R.sup.D175 L.sub.C657 R.sup.D145 R.sup.D117 L.sub.C82 R.sup.D82 R.sup.D82 L.sub.C274 R.sup.D4 R.sup.D134 L.sub.C466 R.sup.D55 R.sup.D3 L.sub.C658 R.sup.D145 R.sup.D118 L.sub.C83 R.sup.D83 R.sup.D83 L.sub.C275 R.sup.D4 R.sup.D135 L.sub.C467 R.sup.D55 R.sup.D5 L.sub.C659 R.sup.D145 R.sup.D119 L.sub.C84 R.sup.D84 R.sup.D84 L.sub.C276 R.sup.D4 R.sup.D136 L.sub.C468 R.sup.D55 R.sup.D18 L.sub.C660 R.sup.D145 R.sup.D120 L.sub.C85 R.sup.D85 R.sup.D85 L.sub.C277 R.sup.D4 R.sup.D143 L.sub.C469 R.sup.D55 R.sup.D20 L.sub.C661 R.sup.D145 R.sup.D133 L.sub.C86 R.sup.D86 R.sup.D86 L.sub.C278 R.sup.D4 R.sup.D144 L.sub.C470 R.sup.D55 R.sup.D22 L.sub.C662 R.sup.D145 R.sup.D134 L.sub.C87 R.sup.D87 R.sup.D87 L.sub.C279 R.sup.D4 R.sup.D145 L.sub.C471 R.sup.D55 R.sup.D37 L.sub.C663 R.sup.D145 R.sup.D135 L.sub.C88 R.sup.D88 R.sup.D88 L.sub.C280 R.sup.D4 R.sup.D146 L.sub.C472 R.sup.D55 R.sup.D40 L.sub.C664 R.sup.D145 R.sup.D136 L.sub.C89 R.sup.D89 R.sup.D89 L.sub.C281 R.sup.D4 R.sup.D147 L.sub.C473 R.sup.D55 R.sup.D41 L.sub.C665 R.sup.D145 R.sup.D146 L.sub.C90 R.sup.D90 R.sup.D90 L.sub.C282 R.sup.D4 R.sup.D149 L.sub.C474 R.sup.D55 R.sup.D42 L.sub.C666 R.sup.D145 R.sup.D147 L.sub.C91 R.sup.D91 R.sup.D91 L.sub.C283 R.sup.D4 R.sup.D151 L.sub.C475 R.sup.D55 R.sup.D43 L.sub.C667 R.sup.D145 R.sup.D149 L.sub.C92 R.sup.D92 R.sup.D92 L.sub.C284 R.sup.D4 R.sup.D154 L.sub.C476 R.sup.D55 R.sup.D48 L.sub.C668 R.sup.D145 R.sup.D151 L.sub.C93 R.sup.D93 R.sup.D93 L.sub.C285 R.sup.D4 R.sup.D155 L.sub.C477 R.sup.D55 R.sup.D49 L.sub.C669 R.sup.D145 R.sup.D154 L.sub.C94 R.sup.D94 R.sup.D94 L.sub.C286 R.sup.D4 R.sup.D161 L.sub.C478 R.sup.D55 R.sup.D54 L.sub.C670 R.sup.D145 R.sup.D155 L.sub.C95 R.sup.D95 R.sup.D95 L.sub.C287 R.sup.D4 R.sup.D175 L.sub.C479 R.sup.D55 R.sup.D58 L.sub.C671 R.sup.D145 R.sup.D161 L.sub.C96 R.sup.D96 R.sup.D96 L.sub.C288 R.sup.D9 R.sup.D3 L.sub.C480 R.sup.D55 R.sup.D59 L.sub.C672 R.sup.D145 R.sup.D175 L.sub.C97 R.sup.D97 R.sup.D97 L.sub.C289 R.sup.D9 R.sup.D5 L.sub.C481 R.sup.D55 R.sup.D78 L.sub.C673 R.sup.D146 R.sup.D3 L.sub.C98 R.sup.D98 R.sup.D98 L.sub.C290 R.sup.D9 R.sup.D10 L.sub.C482 R.sup.D55 R.sup.D79 L.sub.C674 R.sup.D146 R.sup.D5 L.sub.C99 R.sup.D99 R.sup.D99 L.sub.C291 R.sup.D9 R.sup.D17 L.sub.C483 R.sup.D55 R.sup.D81 L.sub.C675 R.sup.D146 R.sup.D17 L.sub.C100 R.sup.D100 R.sup.D100 L.sub.C292 R.sup.D9 R.sup.D18 L.sub.C484 R.sup.D55 R.sup.D87 L.sub.C676 R.sup.D146 R.sup.D18 L.sub.C101 R.sup.D101 R.sup.D101 L.sub.C293 R.sup.D9 R.sup.D20 L.sub.C485 R.sup.D55 R.sup.D88 L.sub.C677 R.sup.D146 R.sup.D20 L.sub.C102 R.sup.D102 R.sup.D102 L.sub.C294 R.sup.D9 R.sup.D22 L.sub.C486 R.sup.D55 R.sup.D89 L.sub.C678 R.sup.D146 R.sup.D22 L.sub.C103 R.sup.D103 R.sup.D103 L.sub.C295 R.sup.D9 R.sup.D37 L.sub.C487 R.sup.D55 R.sup.D93 L.sub.C679 R.sup.D146 R.sup.D37 L.sub.C104 R.sup.D104 R.sup.D104 L.sub.C296 R.sup.D9 R.sup.D40 L.sub.C488 R.sup.D55 R.sup.D116 L.sub.C680 R.sup.D146 R.sup.D40 L.sub.C105 R.sup.D105 R.sup.D105 L.sub.C297 R.sup.D9 R.sup.D41 L.sub.C489 R.sup.D55 R.sup.D117 L.sub.C681 R.sup.D146 R.sup.D41 L.sub.C106 R.sup.D106 R.sup.D106 L.sub.C298 R.sup.D9 R.sup.D42 L.sub.C490 R.sup.D55 R.sup.D118 L.sub.C682 R.sup.D146 R.sup.D42 L.sub.C107 R.sup.D107 R.sup.D107 L.sub.C299 R.sup.D9 R.sup.D43 L.sub.C491 R.sup.D55 R.sup.D119 L.sub.C683 R.sup.D146 R.sup.D43 L.sub.C108 R.sup.D108 R.sup.D108 L.sub.C300 R.sup.D9 R.sup.D48 L.sub.C492 R.sup.D55 R.sup.D120 L.sub.C684 R.sup.D146 R.sup.D48 L.sub.C109 R.sup.D109 R.sup.D109 L.sub.C301 R.sup.D9 R.sup.D49 L.sub.C493 R.sup.D55 R.sup.D133 L.sub.C685 R.sup.D146 R.sup.D49 L.sub.C110 R.sup.D110 R.sup.D110 L.sub.C302 R.sup.D9 R.sup.D50 L.sub.C494 R.sup.D55 R.sup.D134 L.sub.C686 R.sup.D146 R.sup.D54 L.sub.C111 R.sup.D111 R.sup.D111 L.sub.C303 R.sup.D9 R.sup.D54 L.sub.C495 R.sup.D55 R.sup.D135 L.sub.C687 R.sup.D146 R.sup.D58 L.sub.C112 R.sup.D112 R.sup.D112 L.sub.C304 R.sup.D9 R.sup.D55 L.sub.C496 R.sup.D55 R.sup.D136 L.sub.C688 R.sup.D146 R.sup.D59 L.sub.C113 R.sup.D113 R.sup.D113 L.sub.C305 R.sup.D9 R.sup.D58 L.sub.C497 R.sup.D55 R.sup.D143 L.sub.C689 R.sup.D146 R.sup.D78 L.sub.C114 R.sup.D114 R.sup.D114 L.sub.C306 R.sup.D9 R.sup.D59 L.sub.C498 R.sup.D55 R.sup.D144 L.sub.C690 R.sup.D146 R.sup.D79 L.sub.C115 R.sup.D115 R.sup.D115 L.sub.C307 R.sup.D9 R.sup.D78 L.sub.C499 R.sup.D55 R.sup.D145 L.sub.C691 R.sup.D146 R.sup.D81 L.sub.C116 R.sup.D116 R.sup.D116 L.sub.C308 R.sup.D9 R.sup.D79 L.sub.C500 R.sup.D55 R.sup.D146 L.sub.C692 R.sup.D146 R.sup.D87 L.sub.C117 R.sup.D117 R.sup.D117 L.sub.C309 R.sup.D9 R.sup.D981 L.sub.C501 R.sup.D55 R.sup.D147 L.sub.C693 R.sup.D146 R.sup.D88 L.sub.C118 R.sup.D118 R.sup.D118 L.sub.C310 R.sup.D9 R.sup.D87 L.sub.C502 R.sup.D55 R.sup.D149 L.sub.C694 R.sup.D146 R.sup.D89 L.sub.C119 R.sup.D119 R.sup.D119 L.sub.C311 R.sup.D9 R.sup.D88 L.sub.C503 R.sup.D55 R.sup.D151 L.sub.C695 R.sup.D146 R.sup.D93 L.sub.C120 R.sup.D120 R.sup.D120 L.sub.C312 R.sup.D9 R.sup.D89 L.sub.C504 R.sup.D55 R.sup.D154 L.sub.C696 R.sup.D146 R.sup.D117 L.sub.C121 R.sup.D121 R.sup.D121 L.sub.C313 R.sup.D9 R.sup.D93 L.sub.C505 R.sup.D55 R.sup.D155 L.sub.C697 R.sup.D146 R.sup.D118 L.sub.C122 R.sup.D122 R.sup.D122 L.sub.C314 R.sup.D9 R.sup.D116 L.sub.C506 R.sup.D55 R.sup.D161 L.sub.C698 R.sup.D146 R.sup.D119 L.sub.C123 R.sup.D123 R.sup.D123 L.sub.C315 R.sup.D9 R.sup.D117 L.sub.C507 R.sup.D55 R.sup.D175 L.sub.C699 R.sup.D146 R.sup.D120 L.sub.C124 R.sup.D124 R.sup.D124 L.sub.C316 R.sup.D9 R.sup.D118 L.sub.C508 R.sup.D116 R.sup.D3 L.sub.C700 R.sup.D146 R.sup.D133 L.sub.C125 R.sup.D125 R.sup.D125 L.sub.C317 R.sup.D9 R.sup.D119 L.sub.C509 R.sup.D116 R.sup.D5 L.sub.C701 R.sup.D146 R.sup.D134 L.sub.C126 R.sup.D126 R.sup.D126 L.sub.C318 R.sup.D9 R.sup.D120 L.sub.C510 R.sup.D116 R.sup.D17 L.sub.C702 R.sup.D146 R.sup.D135 L.sub.C127 R.sup.D127 R.sup.D127 L.sub.C319 R.sup.D9 R.sup.D133 L.sub.C511 R.sup.D116 R.sup.D18 L.sub.C703 R.sup.D146 R.sup.D136 L.sub.C128 R.sup.D128 R.sup.D128 L.sub.C320 R.sup.D9 R.sup.D134 L.sub.C512 R.sup.D116 R.sup.D20 L.sub.C704 R.sup.D146 R.sup.D146 L.sub.C129 R.sup.D129 R.sup.D129 L.sub.C321 R.sup.D9 R.sup.D135 L.sub.C513 R.sup.D116 R.sup.D22 L.sub.C705 R.sup.D146 R.sup.D147 L.sub.C130 R.sup.D130 R.sup.D130 L.sub.C322 R.sup.D9 R.sup.D136 L.sub.C514 R.sup.D116 R.sup.D37 L.sub.C706 R.sup.D146 R.sup.D149 L.sub.C131 R.sup.D131 R.sup.D131 L.sub.C323 R.sup.D9 R.sup.D143 L.sub.C515 R.sup.D116 R.sup.D40 L.sub.C707 R.sup.D146 R.sup.D151 L.sub.C132 R.sup.D132 R.sup.D132 L.sub.C324 R.sup.D9 R.sup.D144 L.sub.C516 R.sup.D116 R.sup.D41 L.sub.C708 R.sup.D146 R.sup.D154 L.sub.C133 R.sup.D133 R.sup.D133 L.sub.C325 R.sup.D9 R.sup.D145 L.sub.C517 R.sup.D116 R.sup.D42 L.sub.C709 R.sup.D146 R.sup.D155 L.sub.C134 R.sup.D134 R.sup.D134 L.sub.C326 R.sup.D9 R.sup.D146 L.sub.C518 R.sup.D116 R.sup.D43 L.sub.C710 R.sup.D146 R.sup.D161 L.sub.C135 R.sup.D135 R.sup.D135 L.sub.C327 R.sup.D9 R.sup.D147 L.sub.C519 R.sup.D116 R.sup.D48 L.sub.C711 R.sup.D146 R.sup.D175 L.sub.C136 R.sup.D136 R.sup.D136 L.sub.C328 R.sup.D9 R.sup.D149 L.sub.C520 R.sup.D116 R.sup.D49 L.sub.C712 R.sup.D133 R.sup.D3 L.sub.C137 R.sup.D137 R.sup.D137 L.sub.C329 R.sup.D9 R.sup.D151 L.sub.C521 R.sup.D116 R.sup.D54 L.sub.C713 R.sup.D133 R.sup.D5 L.sub.C138 R.sup.D138 R.sup.D138 L.sub.C330 R.sup.D9 R.sup.D154 L.sub.C522 R.sup.D116 R.sup.D58 L.sub.C714 R.sup.D133 R.sup.D3 L.sub.C139 R.sup.D139 R.sup.D139 L.sub.C331 R.sup.D9 R.sup.D155 L.sub.C523 R.sup.D116 R.sup.D59 L.sub.C715 R.sup.D133 R.sup.D18 L.sub.C140 R.sup.D140 R.sup.D140 L.sub.C332 R.sup.D9 R.sup.D161 L.sub.C524 R.sup.D116 R.sup.D78 L.sub.C716 R.sup.D133 R.sup.D20 L.sub.C141 R.sup.D141 R.sup.D141 L.sub.C333 R.sup.D9 R.sup.D175 L.sub.C525 R.sup.D116 R.sup.D79 L.sub.C717 R.sup.D133 R.sup.D22 L.sub.C142 R.sup.D142 R.sup.D142 L.sub.C334 R.sup.D10 R.sup.D3 L.sub.C526 R.sup.D116 R.sup.D81 L.sub.C718 R.sup.D133 R.sup.D37 L.sub.C143 R.sup.D143 R.sup.D143 L.sub.C335 R.sup.D10 R.sup.D5 L.sub.C527 R.sup.D116 R.sup.D87 L.sub.C719 R.sup.D133 R.sup.D40 L.sub.C144 R.sup.D144 R.sup.D144 L.sub.C336 R.sup.D10 R.sup.D17 L.sub.C528 R.sup.D116 R.sup.D88 L.sub.C720 R.sup.D133 R.sup.D41 L.sub.C145 R.sup.D145 R.sup.D145 L.sub.C337 R.sup.D10 R.sup.D18 L.sub.C529 R.sup.D116 R.sup.D89 L.sub.C721 R.sup.D133 R.sup.D42 L.sub.C146 R.sup.D146 R.sup.D146 L.sub.C338 R.sup.D10 R.sup.D20 L.sub.C530 R.sup.D116 R.sup.D93 L.sub.C722 R.sup.D133 R.sup.D43 L.sub.C147 R.sup.D147 R.sup.D147 L.sub.C339 R.sup.D10 R.sup.D22 L.sub.C531 R.sup.D116 R.sup.D117 L.sub.C723 R.sup.D133 R.sup.D48 L.sub.C148 R.sup.D148 R.sup.D148 L.sub.C340 R.sup.D10 R.sup.D37 L.sub.C532 R.sup.D116 R.sup.D118 L.sub.C724 R.sup.D133 R.sup.D49 L.sub.C149 R.sup.D149 R.sup.D149 L.sub.C341 R.sup.D10 R.sup.D40 L.sub.C533 R.sup.D116 R.sup.D119 L.sub.C725 R.sup.D133 R.sup.D54 L.sub.C150 R.sup.D150 R.sup.D150 L.sub.C342 R.sup.D10 R.sup.D41 L.sub.C534 R.sup.D116 R.sup.D120 L.sub.C726 R.sup.D133 R.sup.D58 L.sub.C151 R.sup.D151 R.sup.D151 L.sub.C343 R.sup.D10 R.sup.D42 L.sub.C535 R.sup.D116 R.sup.D133 L.sub.C727 R.sup.D133 R.sup.D59 L.sub.C152 R.sup.D152 R.sup.D152 L.sub.C344 R.sup.D10 R.sup.D43 L.sub.C536 R.sup.D116 R.sup.D134 L.sub.C728 R.sup.D133 R.sup.D78 L.sub.C153 R.sup.D153 R.sup.D153 L.sub.C345 R.sup.D10 R.sup.D48 L.sub.C537 R.sup.D116 R.sup.D135 L.sub.C729 R.sup.D133 R.sup.D79 L.sub.C154 R.sup.D154 R.sup.D154 L.sub.C346 R.sup.D10 R.sup.D49 L.sub.C538 R.sup.D116 R.sup.D136 L.sub.C730 R.sup.D133 R.sup.D81 L.sub.C155 R.sup.D155 R.sup.D155 L.sub.C347 R.sup.D10 R.sup.D50 L.sub.C539 R.sup.D116 R.sup.D143 L.sub.C731 R.sup.D133 R.sup.D87 L.sub.C156 R.sup.D156 R.sup.D156 L.sub.C348 R.sup.D10 R.sup.D54 L.sub.C540 R.sup.D116 R.sup.D144 L.sub.C732 R.sup.D133 R.sup.D88 L.sub.C157 R.sup.D157 R.sup.D157 L.sub.C349 R.sup.D10 R.sup.D55 L.sub.C541 R.sup.D116 R.sup.D145 L.sub.C733 R.sup.D133 R.sup.D89 L.sub.C158 R.sup.D158 R.sup.D158 L.sub.C350 R.sup.D10 R.sup.D58 L.sub.C542 R.sup.D116 R.sup.D146 L.sub.C734 R.sup.D133 R.sup.D93 L.sub.C159 R.sup.D159 R.sup.D159 L.sub.C351 R.sup.D10 R.sup.D59 L.sub.C543 R.sup.D116 R.sup.D147 L.sub.C735 R.sup.D133 R.sup.D117 L.sub.C160 R.sup.D160 R.sup.D160 L.sub.C352 R.sup.D10 R.sup.D78 L.sub.C544 R.sup.D116 R.sup.D149 L.sub.C736 R.sup.D133 R.sup.D118 L.sub.C161 R.sup.D161 R.sup.D161 L.sub.C353 R.sup.D10 R.sup.D79 L.sub.C545 R.sup.D116 R.sup.D151 L.sub.C737 R.sup.D133 R.sup.D119 L.sub.C162 R.sup.D162 R.sup.D162 L.sub.C354 R.sup.D10 R.sup.D81 L.sub.C546 R.sup.D116 R.sup.D154 L.sub.C738 R.sup.D133 R.sup.D120 L.sub.C163 R.sup.D163 R.sup.D163 L.sub.C355 R.sup.D10 R.sup.D87 L.sub.C547 R.sup.D116 R.sup.D155 L.sub.C739 R.sup.D133 R.sup.D133 L.sub.C164 R.sup.D164 R.sup.D164 L.sub.C356 R.sup.D10 R.sup.D88 L.sub.C548 R.sup.D116 R.sup.D161 L.sub.C740 R.sup.D133 R.sup.D134 L.sub.C165 R.sup.D165 R.sup.D165 L.sub.C357 R.sup.D10 R.sup.D89 L.sub.C549 R.sup.D116 R.sup.D175 L.sub.C741 R.sup.D133 R.sup.D135 L.sub.C166 R.sup.D166 R.sup.D166 L.sub.C358 R.sup.D10 R.sup.D93 L.sub.C550 R.sup.D143 R.sup.D3 L.sub.C742 R.sup.D133 R.sup.D136 L.sub.C167 R.sup.D167 R.sup.D167 L.sub.C359 R.sup.D10 R.sup.D116 L.sub.C551 R.sup.D143 R.sup.D5 L.sub.C743 R.sup.D133 R.sup.D146 L.sub.C168 R.sup.D168 R.sup.D168 L.sub.C360 R.sup.D10 R.sup.D117 L.sub.C552 R.sup.D143 R.sup.D17 L.sub.C744 R.sup.D133 R.sup.D147 L.sub.C169 R.sup.D169 R.sup.D169 L.sub.C361 R.sup.D10 R.sup.D118 L.sub.C553 R.sup.D143 R.sup.D18 L.sub.C745 R.sup.D133 R.sup.D149 L.sub.C170 R.sup.D170 R.sup.D170 L.sub.C362 R.sup.D10 R.sup.D119 L.sub.C554 R.sup.D143 R.sup.D20 L.sub.C746 R.sup.D133 R.sup.D151 L.sub.C171 R.sup.D171 R.sup.D171 L.sub.C363 R.sup.D10 R.sup.D120 L.sub.C555 R.sup.D143 R.sup.D22 L.sub.C747 R.sup.D133 R.sup.D154 L.sub.C172 R.sup.D172 R.sup.D172 L.sub.C364 R.sup.D10 R.sup.D133 L.sub.C556 R.sup.D143 R.sup.D37 L.sub.C748 R.sup.D133 R.sup.D155 L.sub.C173 R.sup.D173 R.sup.D173 L.sub.C365 R.sup.D10 R.sup.D134 L.sub.C557 R.sup.D143 R.sup.D40 L.sub.C749 R.sup.D133 R.sup.D161 L.sub.C174 R.sup.D174 R.sup.D174 L.sub.C366 R.sup.D10 R.sup.D135 L.sub.C558 R.sup.D143 R.sup.D41 L.sub.C750 R.sup.D133 R.sup.D175 L.sub.C175 R.sup.D175 R.sup.D175 L.sub.C367 R.sup.D10 R.sup.D136 L.sub.C559 R.sup.D143 R.sup.D42 L.sub.C751 R.sup.D175 R.sup.D3 L.sub.C176 R.sup.D176 R.sup.D176 L.sub.C368 R.sup.D10 R.sup.D143 L.sub.C560 R.sup.D143 R.sup.D43 L.sub.C752 R.sup.D175 R.sup.D5 L.sub.C177 R.sup.D177 R.sup.D177 L.sub.C369 R.sup.D10 R.sup.D144 L.sub.C561 R.sup.D143 R.sup.D48 L.sub.C753 R.sup.D175 R.sup.D18 L.sub.C178 R.sup.D178 R.sup.D178 L.sub.C370 R.sup.D10 R.sup.D145 L.sub.C562 R.sup.D143 R.sup.D49 L.sub.C754 R.sup.D175 R.sup.D20 L.sub.C179 R.sup.D179 R.sup.D179 L.sub.C371 R.sup.D10 R.sup.D146 L.sub.C563 R.sup.D143 R.sup.D54 L.sub.C755 R.sup.D175 R.sup.D22 L.sub.C180 R.sup.D180 R.sup.D180 L.sub.C372 R.sup.D10 R.sup.D147 L.sub.C564 R.sup.D143 R.sup.D58 L.sub.C756 R.sup.D175 R.sup.D37 L.sub.C181 R.sup.D181 R.sup.D181 L.sub.C373 R.sup.D10 R.sup.D149 L.sub.C565 R.sup.D143 R.sup.D59 L.sub.C757 R.sup.D175 R.sup.D40 L.sub.C182 R.sup.D182 R.sup.D182 L.sub.C374 R.sup.D10 R.sup.D151 L.sub.C566 R.sup.D143 R.sup.D78 L.sub.C758 R.sup.D175 R.sup.D41 L.sub.C183 R.sup.D183 R.sup.D183 L.sub.C375 R.sup.D10 R.sup.D154 L.sub.C567 R.sup.D143 R.sup.D79 L.sub.C759 R.sup.D175 R.sup.D42 L.sub.C184 R.sup.D184 R.sup.D184 L.sub.C376 R.sup.D10 R.sup.D155 L.sub.C568 R.sup.D143 R.sup.D81 L.sub.C760 R.sup.D175 R.sup.D43 L.sub.C185 R.sup.D185 R.sup.D185 L.sub.C377 R.sup.D10 R.sup.D161 L.sub.C569 R.sup.D143 R.sup.D87 L.sub.C761 R.sup.D175 R.sup.D48 L.sub.C186 R.sup.D186 R.sup.D186 L.sub.C378 R.sup.D10 R.sup.D175 L.sub.C570 R.sup.D143 R.sup.D88 L.sub.C762 R.sup.D175 R.sup.D49 L.sub.C187 R.sup.D187 R.sup.D187 L.sub.C379 R.sup.D17 R.sup.D3 L.sub.C571 R.sup.D143 R.sup.D89 L.sub.C763 R.sup.D175 R.sup.D54 L.sub.C188 R.sup.D188 R.sup.D188 L.sub.C380 R.sup.D17 R.sup.D5 L.sub.C572 R.sup.D143 R.sup.D93 L.sub.C764 R.sup.D175 R.sup.D58 L.sub.C189 R.sup.D189 R.sup.D189 L.sub.C381 R.sup.D17 R.sup.D18 L.sub.C573 R.sup.D143 R.sup.D113 L.sub.C765 R.sup.D175 R.sup.D59 L.sub.C190 R.sup.D190 R.sup.D190 L.sub.C382 R.sup.D17 R.sup.D20 L.sub.C574 R.sup.D143 R.sup.D117 L.sub.C766 R.sup.D175 R.sup.D78 L.sub.C191 R.sup.D191 R.sup.D191 L.sub.C383 R.sup.D17 R.sup.D22 L.sub.C575 R.sup.D143 R.sup.D118 L.sub.C767 R.sup.D175 R.sup.D79 L.sub.C192 R.sup.D192 R.sup.D192 L.sub.C384 R.sup.D17 R.sup.D37 L.sub.C576 R.sup.D143 R.sup.D119 L.sub.C768 R.sup.D175 R.sup.D81 L.sub.C769 R.sup.D193 R.sup.D193 L.sub.C877 R.sup.D1 R.sup.D193 L.sub.C985 R.sup.D4 R.sup.D193 L.sub.C1093 R.sup.D9 R.sup.D193 L.sub.C770 R.sup.D194 R.sup.D194 L.sub.C878 R.sup.D1 R.sup.D194 L.sub.C986 R.sup.D4 R.sup.D194 L.sub.C1094 R.sup.D9 R.sup.D194 L.sub.C771 R.sup.D195 R.sup.D195 L.sub.C879 R.sup.D1 R.sup.D195 L.sub.C987 R.sup.D4 R.sup.D195 L.sub.C1095 R.sup.D9 R.sup.D195 L.sub.C772 R.sup.D196 R.sup.D196 L.sub.C880 R.sup.D1 R.sup.D196 L.sub.C988 R.sup.D4 R.sup.D196 L.sub.C1096 R.sup.D9 R.sup.D196 L.sub.C773 R.sup.D197 R.sup.D197 L.sub.C881 R.sup.D1 R.sup.D197 L.sub.C989 R.sup.D4 R.sup.D197 L.sub.C1097 R.sup.D9 R.sup.D197 L.sub.C774 R.sup.D198 R.sup.D198 L.sub.C882 R.sup.D1 R.sup.D198 L.sub.C990 R.sup.D4 R.sup.D198 L.sub.C1098 R.sup.D9 R.sup.D198 L.sub.C775 R.sup.D199 R.sup.D199 L.sub.C883 R.sup.D1 R.sup.D199 L.sub.C991 R.sup.D4 R.sup.D199 L.sub.C1099 R.sup.D9 R.sup.D199 L.sub.C776 R.sup.D200 R.sup.D200 L.sub.C884 R.sup.D1 R.sup.D200 L.sub.C992 R.sup.D4 R.sup.D200 L.sub.C1100 R.sup.D9 R.sup.D200 L.sub.C777 R.sup.D201 R.sup.D201 L.sub.C885 R.sup.D1 R.sup.D201 L.sub.C993 R.sup.D4 R.sup.D201 L.sub.C1101 R.sup.D9 R.sup.D201 L.sub.C778 R.sup.D202 R.sup.D202 L.sub.C886 R.sup.D1 R.sup.D202 L.sub.C994 R.sup.D4 R.sup.D202 L.sub.C1102 R.sup.D9 R.sup.D202 L.sub.C779 R.sup.D203 R.sup.D203 L.sub.C887 R.sup.D1 R.sup.D203 L.sub.C995 R.sup.D4 R.sup.D203 L.sub.C1103 R.sup.D9 R.sup.D203 L.sub.C780 R.sup.D204 R.sup.D204 L.sub.C888 R.sup.D1 R.sup.D204 L.sub.C996 R.sup.D4 R.sup.D204 L.sub.C1104 R.sup.D9 R.sup.D204 L.sub.C781 R.sup.D205 R.sup.D205 L.sub.C889 R.sup.D1 R.sup.D205 L.sub.C997 R.sup.D4 R.sup.D205 L.sub.C1105 R.sup.D9 R.sup.D205 L.sub.C782 R.sup.D206 R.sup.D206 L.sub.C890 R.sup.D1 R.sup.D206 L.sub.C998 R.sup.D4 R.sup.D206 L.sub.C1106 R.sup.D9 R.sup.D206 L.sub.C783 R.sup.D207 R.sup.D207 L.sub.C891 R.sup.D1 R.sup.D207 L.sub.C999 R.sup.D4 R.sup.D207 L.sub.C1107 R.sup.D9 R.sup.D207 L.sub.C784 R.sup.D208 R.sup.D208 L.sub.C892 R.sup.D1 R.sup.D208 L.sub.C1000 R.sup.D4 R.sup.D208 L.sub.C1108 R.sup.D9 R.sup.D208 L.sub.C785 R.sup.D209 R.sup.D209 L.sub.C893 R.sup.D1 R.sup.D209 L.sub.C1001 R.sup.D4 R.sup.D209 L.sub.C1109 R.sup.D9 R.sup.D209 L.sub.C786 R.sup.D210 R.sup.D210 L.sub.C894 R.sup.D1 R.sup.D210 L.sub.C1002 R.sup.D4 R.sup.D210 L.sub.C1110 R.sup.D9 R.sup.D210 L.sub.C787 R.sup.D211 R.sup.D211 L.sub.C895 R.sup.D1 R.sup.D211 L.sub.C1003 R.sup.D4 R.sup.D211 L.sub.C1111 R.sup.D9 R.sup.D211 L.sub.C788 R.sup.D212 R.sup.D212 L.sub.C896 R.sup.D1 R.sup.D212 L.sub.C1004 R.sup.D4 R.sup.D212 L.sub.C1112 R.sup.D9 R.sup.D212 L.sub.C789 R.sup.D213 R.sup.D213 L.sub.C897 R.sup.D1 R.sup.D213 L.sub.C1005 R.sup.D4 R.sup.D213 L.sub.C1113 R.sup.D9 R.sup.D213 L.sub.C790 R.sup.D214 R.sup.D214 L.sub.C898 R.sup.D1 R.sup.D214 L.sub.C1006 R.sup.D4 R.sup.D214 L.sub.C1114 R.sup.D9 R.sup.D214 L.sub.C791 R.sup.D215 R.sup.D215 L.sub.C899 R.sup.D1 R.sup.D215 L.sub.C1007 R.sup.D4 R.sup.D215 L.sub.C1115 R.sup.D9 R.sup.D215 L.sub.C792 R.sup.D216 R.sup.D216 L.sub.C900 R.sup.D1 R.sup.D216 L.sub.C1008 R.sup.D4 R.sup.D216 L.sub.C1116 R.sup.D9 R.sup.D216 L.sub.C793 R.sup.D217 R.sup.D217 L.sub.C901 R.sup.D1 R.sup.D217 L.sub.C1009 R.sup.D4 R.sup.D217 L.sub.C1117 R.sup.D9 R.sup.D217 L.sub.C794 R.sup.D218 R.sup.D218 L.sub.C902 R.sup.D1 R.sup.D218 L.sub.C1010 R.sup.D4 R.sup.D218 L.sub.C1118 R.sup.D9 R.sup.D218 L.sub.C795 R.sup.D219 R.sup.D219 L.sub.C903 R.sup.D1 R.sup.D219 L.sub.C1011 R.sup.D4 R.sup.D219 L.sub.C1119 R.sup.D9 R.sup.D219 L.sub.C796 R.sup.D220 R.sup.D220 L.sub.C904 R.sup.D1 R.sup.D220 L.sub.C1012 R.sup.D4 R.sup.D220 L.sub.C1120 R.sup.D9 R.sup.D220 L.sub.C797 R.sup.D221 R.sup.D221 L.sub.C905 R.sup.D1 R.sup.D221 L.sub.C1013 R.sup.D4 R.sup.D221 L.sub.C1121 R.sup.D9 R.sup.D221 L.sub.C798 R.sup.D222 R.sup.D222 L.sub.C906 R.sup.D1 R.sup.D222 L.sub.C1014 R.sup.D4 R.sup.D222 L.sub.C1122 R.sup.D9 R.sup.D222 L.sub.C799 R.sup.D223 R.sup.D223 L.sub.C907 R.sup.D1 R.sup.D223 L.sub.C1015 R.sup.D4 R.sup.D223 L.sub.C1123 R.sup.D9 R.sup.D223 L.sub.C800 R.sup.D224 R.sup.D224 L.sub.C908 R.sup.D1 R.sup.D224 L.sub.C1016 R.sup.D4 R.sup.D224 L.sub.C1124 R.sup.D9 R.sup.D224 L.sub.C801 R.sup.D225 R.sup.D225 L.sub.C909 R.sup.D1 R.sup.D225 L.sub.C1017 R.sup.D4 R.sup.D225 L.sub.C1125 R.sup.D9 R.sup.D225 L.sub.C802 R.sup.D226 R.sup.D226 L.sub.C910 R.sup.D1 R.sup.D226 L.sub.C1018 R.sup.D4 R.sup.D226 L.sub.C1126 R.sup.D9 R.sup.D226 L.sub.C803 R.sup.D227 R.sup.D227 L.sub.C911 R.sup.D1 R.sup.D227 L.sub.C1019 R.sup.D4 R.sup.D227 L.sub.C1127 R.sup.D9 R.sup.D227 L.sub.C804 R.sup.D228 R.sup.D228 L.sub.C912 R.sup.D1 R.sup.D228 L.sub.C1020 R.sup.D4 R.sup.D228 L.sub.C1128 R.sup.D9 R.sup.D228 L.sub.C805 R.sup.D229 R.sup.D229 L.sub.C913 R.sup.D1 R.sup.D229 L.sub.C1021 R.sup.D4 R.sup.D229 L.sub.C1129 R.sup.D9 R.sup.D229 L.sub.C806 R.sup.D230 R.sup.D230 L.sub.C914 R.sup.D1 R.sup.D230 L.sub.C1022 R.sup.D4 R.sup.D230 L.sub.C1130 R.sup.D9 R.sup.D230 L.sub.C807 R.sup.D231 R.sup.D231 L.sub.C915 R.sup.D1 R.sup.D231 L.sub.C1023 R.sup.D4 R.sup.D231 L.sub.C1131 R.sup.D9 R.sup.D231 L.sub.C808 R.sup.D232 R.sup.D232 L.sub.C916 R.sup.D1 R.sup.D232 L.sub.C1024 R.sup.D4 R.sup.D232 L.sub.C1132 R.sup.D9 R.sup.D232 L.sub.C809 R.sup.D233 R.sup.D233 L.sub.C917 R.sup.D1 R.sup.D233 L.sub.C1025 R.sup.D4 R.sup.D233 L.sub.C1133 R.sup.D9 R.sup.D233 L.sub.C810 R.sup.D234 R.sup.D234 L.sub.C918 R.sup.D1 R.sup.D234 L.sub.C1026 R.sup.D4 R.sup.D234 L.sub.C1134 R.sup.D9 R.sup.D234 L.sub.C811 R.sup.D235 R.sup.D235 L.sub.C919 R.sup.D1 R.sup.D235 L.sub.C1027 R.sup.D4 R.sup.D235 L.sub.C1135 R.sup.D9 R.sup.D235 L.sub.C812 R.sup.D236 R.sup.D236 L.sub.C920 R.sup.D1 R.sup.D236 L.sub.C1028 R.sup.D4 R.sup.D236 L.sub.C1136 R.sup.D9 R.sup.D236 L.sub.C813 R.sup.D237 R.sup.D237 L.sub.C921 R.sup.D1 R.sup.D237 L.sub.C1029 R.sup.D4 R.sup.D237 L.sub.C1137 R.sup.D9 R.sup.D237 L.sub.C814 R.sup.D238 R.sup.D238 L.sub.C922 R.sup.D1 R.sup.D238 L.sub.C1030 R.sup.D4 R.sup.D238 L.sub.C1138 R.sup.D9 R.sup.D238 L.sub.C815 R.sup.D239 R.sup.D239 L.sub.C923 R.sup.D1 R.sup.D239 L.sub.C1031 R.sup.D4 R.sup.D239 L.sub.C1139 R.sup.D9 R.sup.D239 L.sub.C816 R.sup.D240 R.sup.D240 L.sub.C924 R.sup.D1 R.sup.D240 L.sub.C1032 R.sup.D4 R.sup.D240 L.sub.C1140 R.sup.D9 R.sup.D240 L.sub.C817 R.sup.D241 R.sup.D241 L.sub.C925 R.sup.D1 R.sup.D241 L.sub.C1033 R.sup.D4 R.sup.D241 L.sub.C1141 R.sup.D9 R.sup.D241 L.sub.C818 R.sup.D242 R.sup.D242 L.sub.C926 R.sup.D1 R.sup.D242 L.sub.C1034 R.sup.D4 R.sup.D242 L.sub.C1142 R.sup.D9 R.sup.D242 L.sub.C819 R.sup.D243 R.sup.D243 L.sub.C927 R.sup.D1 R.sup.D243 L.sub.C1035 R.sup.D4 R.sup.D243 L.sub.C1143 R.sup.D9 R.sup.D243 L.sub.C820 R.sup.D244 R.sup.D244 L.sub.C928 R.sup.D1 R.sup.D244 L.sub.C1036 R.sup.D4 R.sup.D244 L.sub.C1144 R.sup.D9 R.sup.D244 L.sub.C821 R.sup.D245 R.sup.D245 L.sub.C929 R.sup.D1 R.sup.D245 L.sub.C1037 R.sup.D4 R.sup.D245 L.sub.C1145 R.sup.D9 R.sup.D245 L.sub.C822 R.sup.D246 R.sup.D246 L.sub.C930 R.sup.D1 R.sup.D246 L.sub.C1038 R.sup.D4 R.sup.D246 L.sub.C1146 R.sup.D9 R.sup.D246 L.sub.C823 R.sup.D17 R.sup.D193 L.sub.C931 R.sup.D50 R.sup.D193 L.sub.C1039 R.sup.D145 R.sup.D193 L.sub.C1147 R.sup.D168 R.sup.D193 L.sub.C824 R.sup.D17 R.sup.D194 L.sub.C932 R.sup.D50 R.sup.D194 L.sub.C1040 R.sup.D145 R.sup.D194 L.sub.C1148 R.sup.D168 R.sup.D194 L.sub.C825 R.sup.D17 R.sup.D195 L.sub.C933 R.sup.D50 R.sup.D195 L.sub.C1041 R.sup.D145 R.sup.D195 L.sub.C1149 R.sup.D168 R.sup.D195 L.sub.C826 R.sup.D17 R.sup.D196 L.sub.C934 R.sup.D50 R.sup.D196 L.sub.C1042 R.sup.D145 R.sup.D196 L.sub.C1150 R.sup.D168 R.sup.D196 L.sub.C827 R.sup.D17 R.sup.D197 L.sub.C935 R.sup.D50 R.sup.D197 L.sub.C1043 R.sup.D145 R.sup.D197 L.sub.C1151 R.sup.D168 R.sup.D197 L.sub.C828 R.sup.D17 R.sup.D198 L.sub.C936 R.sup.D50 R.sup.D198 L.sub.C1044 R.sup.D145 R.sup.D198 L.sub.C1152 R.sup.D168 R.sup.D198 L.sub.C829 R.sup.D17 R.sup.D199 L.sub.C937 R.sup.D50 R.sup.D199 L.sub.C1045 R.sup.D145 R.sup.D199 L.sub.C1153 R.sup.D168 R.sup.D199 L.sub.C830 R.sup.D17 R.sup.D200 L.sub.C938 R.sup.D50 R.sup.D200 L.sub.C1046 R.sup.D145 R.sup.D200 L.sub.C1154 R.sup.D168 R.sup.D200 L.sub.C831 R.sup.D17 R.sup.D201 L.sub.C939 R.sup.D50 R.sup.D201 L.sub.C1047 R.sup.D145 R.sup.D201 L.sub.C1155 R.sup.D168 R.sup.D201 L.sub.C832 R.sup.D17 R.sup.D202 L.sub.C940 R.sup.D50 R.sup.D202 L.sub.C1048 R.sup.D145 R.sup.D202 L.sub.C1156 R.sup.D168 R.sup.D202 L.sub.C833 R.sup.D17 R.sup.D203 L.sub.C941 R.sup.D50 R.sup.D203 L.sub.C1049 R.sup.D145 R.sup.D203 L.sub.C1157 R.sup.D168 R.sup.D203 L.sub.C834 R.sup.D17 R.sup.D204 L.sub.C942 R.sup.D50 R.sup.D204 L.sub.C1050 R.sup.D145 R.sup.D204 L.sub.C1158 R.sup.D168 R.sup.D204 L.sub.C835 R.sup.D17 R.sup.D205 L.sub.C943 R.sup.D50 R.sup.D205 L.sub.C1051 R.sup.D145 R.sup.D205 L.sub.C1159 R.sup.D168 R.sup.D205 L.sub.C836 R.sup.D17 R.sup.D206 L.sub.C944 R.sup.D50 R.sup.D206 L.sub.C1052 R.sup.D145 R.sup.D206 L.sub.C1160 R.sup.D168 R.sup.D206 L.sub.C837 R.sup.D17 R.sup.D207 L.sub.C945 R.sup.D50 R.sup.D207 L.sub.C1053 R.sup.D145 R.sup.D207 L.sub.C1161 R.sup.D168 R.sup.D207 L.sub.C838 R.sup.D17 R.sup.D208 L.sub.C946 R.sup.D50 R.sup.D208 L.sub.C1054 R.sup.D145 R.sup.D208 L.sub.C1162 R.sup.D168 R.sup.D208 L.sub.C839 R.sup.D17 R.sup.D209 L.sub.C947 R.sup.D50 R.sup.D209 L.sub.C1055 R.sup.D145 R.sup.D209 L.sub.C1163 R.sup.D168 R.sup.D209 L.sub.C840 R.sup.D17 R.sup.D210 L.sub.C948 R.sup.D50 R.sup.D210 L.sub.C1056 R.sup.D145 R.sup.D210 L.sub.C1164 R.sup.D168 R.sup.D210 L.sub.C841 R.sup.D17 R.sup.D211 L.sub.C949 R.sup.D50 R.sup.D211 L.sub.C1057 R.sup.D145 R.sup.D211 L.sub.C1165 R.sup.D168 R.sup.D211 L.sub.C842 R.sup.D17 R.sup.D212 L.sub.C950 R.sup.D50 R.sup.D212 L.sub.C1058 R.sup.D145 R.sup.D212 L.sub.C1166 R.sup.D168 R.sup.D212 L.sub.C843 R.sup.D17 R.sup.D213 L.sub.C951 R.sup.D50 R.sup.D213 L.sub.C1059 R.sup.D145 R.sup.D213 L.sub.C1167 R.sup.D168 R.sup.D213 L.sub.C844 R.sup.D17 R.sup.D214 L.sub.C952 R.sup.D50 R.sup.D214 L.sub.C1060 R.sup.D145 R.sup.D214 L.sub.C1168 R.sup.D168 R.sup.D214 L.sub.C845 R.sup.D17 R.sup.D215 L.sub.C953 R.sup.D50 R.sup.D215 L.sub.C1061 R.sup.D145 R.sup.D215 L.sub.C1169 R.sup.D168 R.sup.D215 L.sub.C846 R.sup.D17 R.sup.D216 L.sub.C954 R.sup.D50 R.sup.D216 L.sub.C1062 R.sup.D145 R.sup.D216 L.sub.C1170 R.sup.D168 R.sup.D216 L.sub.C847 R.sup.D17 R.sup.D217 L.sub.C955 R.sup.D50 R.sup.D217 L.sub.C1063 R.sup.D145 R.sup.D217 L.sub.C1171 R.sup.D168 R.sup.D217 L.sub.C848 R.sup.D17 R.sup.D218 L.sub.C956 R.sup.D50 R.sup.D218 L.sub.C1064 R.sup.D145 R.sup.D218 L.sub.C1172 R.sup.D168 R.sup.D218 L.sub.C849 R.sup.D17 R.sup.D219 L.sub.C957 R.sup.D50 R.sup.D219 L.sub.C1065 R.sup.D145 R.sup.D219 L.sub.C1173 R.sup.D168 R.sup.D219 L.sub.C850 R.sup.D17 R.sup.D220 L.sub.C958 R.sup.D50 R.sup.D220 L.sub.C1066 R.sup.D145 R.sup.D220 L.sub.C1174 R.sup.D168 R.sup.D220 L.sub.C851 R.sup.D17 R.sup.D221 L.sub.C959 R.sup.D50 R.sup.D221 L.sub.C1067 R.sup.D145 R.sup.D221 L.sub.C1175 R.sup.D168 R.sup.D221 L.sub.C852 R.sup.D17 R.sup.D222 L.sub.C960 R.sup.D50 R.sup.D222 L.sub.C1068 R.sup.D145 R.sup.D222 L.sub.C1176 R.sup.D168 R.sup.D222 L.sub.C853 R.sup.D17 R.sup.D223 L.sub.C961 R.sup.D50 R.sup.D223 L.sub.C1069 R.sup.D145 R.sup.D223 L.sub.C1177 R.sup.D168 R.sup.D223 L.sub.C854 R.sup.D17 R.sup.D224 L.sub.C962 R.sup.D50 R.sup.D224 L.sub.C1070 R.sup.D145 R.sup.D224 L.sub.C1178 R.sup.D168 R.sup.D224 L.sub.C855 R.sup.D17 R.sup.D225 L.sub.C963 R.sup.D50 R.sup.D225 L.sub.C1071 R.sup.D145 R.sup.D225 L.sub.C1179 R.sup.D168 R.sup.D225 L.sub.C856 R.sup.D17 R.sup.D226 L.sub.C964 R.sup.D50 R.sup.D226 L.sub.C1072 R.sup.D145 R.sup.D226 L.sub.C1180 R.sup.D168 R.sup.D226 L.sub.C857 R.sup.D17 R.sup.D227 L.sub.C965 R.sup.D50 R.sup.D227 L.sub.C1073 R.sup.D145 R.sup.D227 L.sub.C1181 R.sup.D168 R.sup.D227 L.sub.C858 R.sup.D17 R.sup.D228 L.sub.C966 R.sup.D50 R.sup.D228 L.sub.C1074 R.sup.D145 R.sup.D228 L.sub.C1182 R.sup.D168 R.sup.D228 L.sub.C859 R.sup.D17 R.sup.D229 L.sub.C967 R.sup.D50 R.sup.D229 L.sub.C1075 R.sup.D145 R.sup.D229 L.sub.C1183 R.sup.D168 R.sup.D229 L.sub.C860 R.sup.D17 R.sup.D230 L.sub.C968 R.sup.D50 R.sup.D230 L.sub.C1076 R.sup.D145 R.sup.D230 L.sub.C1184 R.sup.D168 R.sup.D230 L.sub.C861 R.sup.D17 R.sup.D231 L.sub.C969 R.sup.D50 R.sup.D231 L.sub.C1077 R.sup.D145 R.sup.D231 L.sub.C1185 R.sup.D168 R.sup.D231 L.sub.C862 R.sup.D17 R.sup.D232 L.sub.C970 R.sup.D50 R.sup.D232 L.sub.C1078 R.sup.D145 R.sup.D232 L.sub.C1186 R.sup.D168 R.sup.D232 L.sub.C863 R.sup.D17 R.sup.D233 L.sub.C971 R.sup.D50 R.sup.D233 L.sub.C1079 R.sup.D145 R.sup.D233 L.sub.C1187 R.sup.D168 R.sup.D233 L.sub.C864 R.sup.D17 R.sup.D234 L.sub.C972 R.sup.D50 R.sup.D234 L.sub.C1080 R.sup.D145 R.sup.D234 L.sub.C1188 R.sup.D168 R.sup.D234 L.sub.C865 R.sup.D17 R.sup.D235 L.sub.C973 R.sup.D50 R.sup.D235 L.sub.C1081 R.sup.D145 R.sup.D235 L.sub.C1189 R.sup.D168 R.sup.D235 L.sub.C866 R.sup.D17 R.sup.D236 L.sub.C974 R.sup.D50 R.sup.D236 L.sub.C1082 R.sup.D145 R.sup.D236 L.sub.C1190 R.sup.D168 R.sup.D236 L.sub.C867 R.sup.D17 R.sup.D237 L.sub.C975 R.sup.D50 R.sup.D237 L.sub.C1083 R.sup.D145 R.sup.D237 L.sub.C1191 R.sup.D168 R.sup.D237 L.sub.C868 R.sup.D17 R.sup.D238 L.sub.C976 R.sup.D50 R.sup.D238 L.sub.C1084 R.sup.D145 R.sup.D238 L.sub.C1192 R.sup.D168 R.sup.D238 L.sub.C869 R.sup.D17 R.sup.D239 L.sub.C977 R.sup.D50 R.sup.D239 L.sub.C1085 R.sup.D145 R.sup.D239 L.sub.C1193 R.sup.D168 R.sup.D239 L.sub.C870 R.sup.D17 R.sup.D240 L.sub.C978 R.sup.D50 R.sup.D240 L.sub.C1086 R.sup.D145 R.sup.D240 L.sub.C1194 R.sup.D168 R.sup.D240 L.sub.C871 R.sup.D17 R.sup.D241 L.sub.C979 R.sup.D50 R.sup.D241 L.sub.C1087 R.sup.D145 R.sup.D241 L.sub.C1195 R.sup.D168 R.sup.D241 L.sub.C872 R.sup.D17 R.sup.D242 L.sub.C980 R.sup.D50 R.sup.D242 L.sub.C1088 R.sup.D145 R.sup.D242 L.sub.C1196 R.sup.D168 R.sup.D242 L.sub.C873 R.sup.D17 R.sup.D243 L.sub.C981 R.sup.D50 R.sup.D243 L.sub.C1089 R.sup.D145 R.sup.D243 L.sub.C1197 R.sup.D168 R.sup.D243 L.sub.C874 R.sup.D17 R.sup.D244 L.sub.C982 R.sup.D50 R.sup.D244 L.sub.C1090 R.sup.D145 R.sup.D244 L.sub.C1198 R.sup.D168 R.sup.D244 L.sub.C875 R.sup.D17 R.sup.D245 L.sub.C983 R.sup.D50 R.sup.D245 L.sub.C1091 R.sup.D145 R.sup.D245 L.sub.C1199 R.sup.D168 R.sup.D245 L.sub.C876 R.sup.D17 R.sup.D246 L.sub.C984 R.sup.D50 R.sup.D246 L.sub.C1092 R.sup.D145 R.sup.D246 L.sub.C1200 R.sup.D168 R.sup.D246 L.sub.C1201 R.sup.D10 R.sup.D193 L.sub.C1255 R.sup.D55 R.sup.D193 L.sub.C1309 R.sup.D37 R.sup.D193 L.sub.C1363 R.sup.D143 R.sup.D193 L.sub.C1202 R.sup.D10 R.sup.D194 L.sub.C1256 R.sup.D55 R.sup.D194 L.sub.C1310 R.sup.D37 R.sup.D194 L.sub.C1364 R.sup.D143 R.sup.D194 L.sub.C1203 R.sup.D10 R.sup.D195 L.sub.C1257 R.sup.D55 R.sup.D195 L.sub.C1311 R.sup.D37 R.sup.D195 L.sub.C1365 R.sup.D143 R.sup.D195 L.sub.C1204 R.sup.D10 R.sup.D196 L.sub.C1258 R.sup.D55 R.sup.D196 L.sub.C1312 R.sup.D37 R.sup.D196 L.sub.C1366 R.sup.D143 R.sup.D196 L.sub.C1205 R.sup.D10 R.sup.D197 L.sub.C1259 R.sup.D55 R.sup.D197 L.sub.C1313 R.sup.D37 R.sup.D197 L.sub.C1367 R.sup.D143 R.sup.D197 L.sub.C1206 R.sup.D10 R.sup.D198 L.sub.C1260 R.sup.D55 R.sup.D198 L.sub.C1314 R.sup.D37 R.sup.D198 L.sub.C1368 R.sup.D143 R.sup.D198 L.sub.C1207 R.sup.D10 R.sup.D199 L.sub.C1261 R.sup.D55 R.sup.D199 L.sub.C1315 R.sup.D37 R.sup.D199 L.sub.C1369 R.sup.D143 R.sup.D199 L.sub.C1208 R.sup.D10 R.sup.D200 L.sub.C1262 R.sup.D55 R.sup.D200 L.sub.C1316 R.sup.D37 R.sup.D200 L.sub.C1370 R.sup.D143 R.sup.D200 L.sub.C1209 R.sup.D10 R.sup.D201 L.sub.C1263 R.sup.D55 R.sup.D201 L.sub.C1317 R.sup.D37 R.sup.D201 L.sub.C1371 R.sup.D143 R.sup.D201 L.sub.C1210 R.sup.D10 R.sup.D202 L.sub.C1264 R.sup.D55 R.sup.D202 L.sub.C1318 R.sup.D37 R.sup.D202 L.sub.C1372 R.sup.D143 R.sup.D202 L.sub.C1211 R.sup.D10 R.sup.D203 L.sub.C1265 R.sup.D55 R.sup.D203 L.sub.C1319 R.sup.D37 R.sup.D203 L.sub.C1373 R.sup.D143 R.sup.D203 L.sub.C1212 R.sup.D10 R.sup.D204 L.sub.C1266 R.sup.D55 R.sup.D204 L.sub.C1320 R.sup.D37 R.sup.D204 L.sub.C1374 R.sup.D143 R.sup.D204 L.sub.C1213 R.sup.D10 R.sup.D205 L.sub.C1267 R.sup.D55 R.sup.D205 L.sub.C1321 R.sup.D37 R.sup.D205 L.sub.C1375 R.sup.D143 R.sup.D205 L.sub.C1214 R.sup.D10 R.sup.D206 L.sub.C1268 R.sup.D55 R.sup.D206 L.sub.C1322 R.sup.D37 R.sup.D206 L.sub.C1376 R.sup.D143 R.sup.D206 L.sub.C1215 R.sup.D10 R.sup.D207 L.sub.C1269 R.sup.D55 R.sup.D207 L.sub.C1323 R.sup.D37 R.sup.D207 L.sub.C1377 R.sup.D143 R.sup.D207 L.sub.C1216 R.sup.D10 R.sup.D208 L.sub.C1270 R.sup.D55 R.sup.D208 L.sub.C1324 R.sup.D37 R.sup.D208 L.sub.C1378 R.sup.D143 R.sup.D208 L.sub.C1217 R.sup.D10 R.sup.D209 L.sub.C1271 R.sup.D55 R.sup.D209 L.sub.C1325 R.sup.D37 R.sup.D209 L.sub.C1379 R.sup.D143 R.sup.D209 L.sub.C1218 R.sup.D10 R.sup.D210 L.sub.C1272 R.sup.D55 R.sup.D210 L.sub.C1326 R.sup.D37 R.sup.D210 L.sub.C1380 R.sup.D143 R.sup.D210 L.sub.C1219 R.sup.D10 R.sup.D211 L.sub.C1273 R.sup.D55 R.sup.D211 L.sub.C1327 R.sup.D37 R.sup.D211 L.sub.C1381 R.sup.D143 R.sup.D211 L.sub.C1220 R.sup.D10 R.sup.D212 L.sub.C1274 R.sup.D55 R.sup.D212 L.sub.C1328 R.sup.D37 R.sup.D212 L.sub.C1382 R.sup.D143 R.sup.D212 L.sub.C1221 R.sup.D10 R.sup.D213 L.sub.C1275 R.sup.D55 R.sup.D213 L.sub.C1329 R.sup.D37 R.sup.D213 L.sub.C1383 R.sup.D143 R.sup.D213 L.sub.C1222 R.sup.D10 R.sup.D214 L.sub.C1276 R.sup.D55 R.sup.D214 L.sub.C1330 R.sup.D37 R.sup.D214 L.sub.C1384 R.sup.D143 R.sup.D214 L.sub.C1223 R.sup.D10 R.sup.D215 L.sub.C1277 R.sup.D55 R.sup.D215 L.sub.C1331 R.sup.D37 R.sup.D215 L.sub.C1385 R.sup.D143 R.sup.D215 L.sub.C1224 R.sup.D10 R.sup.D216 L.sub.C1278 R.sup.D55 R.sup.D216 L.sub.C1332 R.sup.D37 R.sup.D216 L.sub.C1386 R.sup.D143 R.sup.D216 L.sub.C1225 R.sup.D10 R.sup.D217 L.sub.C1279 R.sup.D55 R.sup.D217 L.sub.C1333 R.sup.D37 R.sup.D217 L.sub.C1387 R.sup.D143 R.sup.D217 L.sub.C1226 R.sup.D10 R.sup.D218 L.sub.C1280 R.sup.D55 R.sup.D218 L.sub.C1334 R.sup.D37 R.sup.D218 L.sub.C1388 R.sup.D143 R.sup.D218 L.sub.C1227 R.sup.D10 R.sup.D219 L.sub.C1281 R.sup.D55 R.sup.D219 L.sub.C1335 R.sup.D37 R.sup.D219 L.sub.C1389 R.sup.D143 R.sup.D219 L.sub.C1228 R.sup.D10 R.sup.D220 L.sub.C1282 R.sup.D55 R.sup.D220 L.sub.C1336 R.sup.D37 R.sup.D220 L.sub.C1390 R.sup.D143 R.sup.D220 L.sub.C1229 R.sup.D10 R.sup.D221 L.sub.C1283 R.sup.D55 R.sup.D221 L.sub.C1337 R.sup.D37 R.sup.D221 L.sub.C1391 R.sup.D143 R.sup.D221 L.sub.C1230 R.sup.D10 R.sup.D222 L.sub.C1284 R.sup.D55 R.sup.D222 L.sub.C1338 R.sup.D37 R.sup.D222 L.sub.C1392 R.sup.D143 R.sup.D222 L.sub.C1231 R.sup.D10 R.sup.D223 L.sub.C1285 R.sup.D55 R.sup.D223 L.sub.C1339 R.sup.D37 R.sup.D223 L.sub.C1393 R.sup.D143 R.sup.D223 L.sub.C1232 R.sup.D10 R.sup.D224 L.sub.C1286 R.sup.D55 R.sup.D224 L.sub.C1340 R.sup.D37 R.sup.D224 L.sub.C1394 R.sup.D143 R.sup.D224 L.sub.C1233 R.sup.D10 R.sup.D225 L.sub.C1287 R.sup.D55 R.sup.D225 L.sub.C1341 R.sup.D37 R.sup.D225 L.sub.C1395 R.sup.D143 R.sup.D225 L.sub.C1234 R.sup.D10 R.sup.D226 L.sub.C1288 R.sup.D55 R.sup.D226 L.sub.C1342 R.sup.D37 R.sup.D226 L.sub.C1396 R.sup.D143 R.sup.D226 L.sub.C1235 R.sup.D10 R.sup.D227 L.sub.C1289 R.sup.D55 R.sup.D227 L.sub.C1343 R.sup.D37 R.sup.D227 L.sub.C1397 R.sup.D143 R.sup.D227 L.sub.C1236 R.sup.D10 R.sup.D228 L.sub.C1290 R.sup.D55 R.sup.D228 L.sub.C1344 R.sup.D37 R.sup.D228 L.sub.C1398 R.sup.D143 R.sup.D228 L.sub.C1237 R.sup.D10 R.sup.D229 L.sub.C1291 R.sup.D55 R.sup.D229 L.sub.C1345 R.sup.D37 R.sup.D229 L.sub.C1399 R.sup.D143 R.sup.D229 L.sub.C1238 R.sup.D10 R.sup.D230 L.sub.C1292 R.sup.D55 R.sup.D230 L.sub.C1346 R.sup.D37 R.sup.D230 L.sub.C1400 R.sup.D143 R.sup.D230 L.sub.C1239 R.sup.D10 R.sup.D231 L.sub.C1293 R.sup.D55 R.sup.D231 L.sub.C1347 R.sup.D37 R.sup.D231 L.sub.C1401 R.sup.D143 R.sup.D231 L.sub.C1240 R.sup.D10 R.sup.D232 L.sub.C1294 R.sup.D55 R.sup.D232 L.sub.C1348 R.sup.D37 R.sup.D232 L.sub.C1402 R.sup.D143 R.sup.D232 L.sub.C1241 R.sup.D10 R.sup.D233 L.sub.C1295 R.sup.D55 R.sup.D233 L.sub.C1349 R.sup.D37 R.sup.D233 L.sub.C1403 R.sup.D143 R.sup.D233 L.sub.C1242 R.sup.D10 R.sup.D234 L.sub.C1296 R.sup.D55 R.sup.D234 L.sub.C1350 R.sup.D37 R.sup.D234 L.sub.C1404 R.sup.D143 R.sup.D234 L.sub.C1243 R.sup.D10 R.sup.D235 L.sub.C1297 R.sup.D55 R.sup.D235 L.sub.C1351 R.sup.D37 R.sup.D235 L.sub.C1405 R.sup.D143 R.sup.D235 L.sub.C1244 R.sup.D10 R.sup.D236 L.sub.C1298 R.sup.D55 R.sup.D236 L.sub.C1352 R.sup.D37 R.sup.D236 L.sub.C1406 R.sup.D143 R.sup.D236 L.sub.C1245 R.sup.D10 R.sup.D237 L.sub.C1299 R.sup.D55 R.sup.D237 L.sub.C1353 R.sup.D37 R.sup.D237 L.sub.C1407 R.sup.D143 R.sup.D237 L.sub.C1246 R.sup.D10 R.sup.D238 L.sub.C1300 R.sup.D55 R.sup.D238 L.sub.C1354 R.sup.D37 R.sup.D238 L.sub.C1408 R.sup.D143 R.sup.D238 L.sub.C1247 R.sup.D10 R.sup.D239 L.sub.C1301 R.sup.D55 R.sup.D239 L.sub.C1355 R.sup.D37 R.sup.D239 L.sub.C1409 R.sup.D143 R.sup.D239 L.sub.C1248 R.sup.D10 R.sup.D240 L.sub.C1302 R.sup.D55 R.sup.D240 L.sub.C1356 R.sup.D37 R.sup.D240 L.sub.C1410 R.sup.D143 R.sup.D240 L.sub.C1249 R.sup.D10 R.sup.D241 L.sub.C1303 R.sup.D55 R.sup.D241 L.sub.C1357 R.sup.D37 R.sup.D241 L.sub.C1411 R.sup.D143 R.sup.D241 L.sub.C1250 R.sup.D10 R.sup.D242 L.sub.C1304 R.sup.D55 R.sup.D242 L.sub.C1358 R.sup.D37 R.sup.D242 L.sub.C1412 R.sup.D143 R.sup.D242 L.sub.C1251 R.sup.D10 R.sup.D243 L.sub.C1305 R.sup.D55 R.sup.D243 L.sub.C1359 R.sup.D37 R.sup.D243 L.sub.C1413 R.sup.D143 R.sup.D243 L.sub.C1252 R.sup.D10 R.sup.D244 L.sub.C1306 R.sup.D55 R.sup.D244 L.sub.C1360 R.sup.D37 R.sup.D244 L.sub.C1414 R.sup.D143 R.sup.D244 L.sub.C1253 R.sup.D10 R.sup.D245 L.sub.C1307 R.sup.D55 R.sup.D245 L.sub.C1361 R.sup.D37 R.sup.D245 L.sub.C1415 R.sup.D143 R.sup.D245 L.sub.C1254 R.sup.D10 R.sup.D246 L.sub.C1308 R.sup.D55 R.sup.D246 L.sub.C1362 R.sup.D37 R.sup.D246 L.sub.C1416 R.sup.D143 R.sup.D246
wherein R.sup.D1 to R.sup.D246 have the following structures:
##STR00096## ##STR00097## ##STR00098## ##STR00099## ##STR00100## ##STR00101## ##STR00102## ##STR00103## ##STR00104## ##STR00105## ##STR00106## ##STR00107## ##STR00108## ##STR00109##
##STR00110## ##STR00111## ##STR00112## ##STR00113## ##STR00114## ##STR00115## ##STR00116## ##STR00117## ##STR00118##
[0069] In some embodiments of the OLED, where the first emitter is Compound B, Compound C, Compound D, or Compound E, all having the formula (L.sub.B).sub.nIr(L.sup.3-L.sup.4).sub.3−n the ligand (L.sup.3-L.sup.4) is selected from the group consisting of only those L.sub.Cj-1 and L.sub.Cj-11 whose corresponding R.sup.201 and R.sup.202 are defined to be one the following structures: R.sup.D1, R.sup.D3, R.sup.D4, R.sup.D5, R.sup.D9, R.sup.D10, R.sup.D17, R.sup.D18, R.sup.D20, R.sup.D22, R.sup.D37, R.sup.D40, R.sup.D41, R.sup.D42, R.sup.D43, R.sup.D48, R.sup.D49, R.sup.D50, R.sup.D54, R.sup.D55, R.sup.D58, R.sup.D59, R.sup.D78, R.sup.D79, R.sup.D81, R.sup.D87, R.sup.D88, R.sup.D89, R.sup.D93, R.sup.D116, R.sup.D117, R.sup.D118, R.sup.D119, R.sup.D120, R.sup.D133, R.sup.D134, R.sup.D135, R.sup.D136, R.sup.D143, R.sup.D144, R.sup.D145, R.sup.D146, R.sup.D147, R.sup.D149, R.sup.D151, R.sup.D154, R.sup.D155, R.sup.D156, R.sup.D161, R.sup.D175, R.sup.D190, R.sup.D193, R.sup.D200, R.sup.D201, R.sup.D206, R.sup.D210, R.sup.D214, R.sup.D215, R.sup.D216, R.sup.D218, R.sup.D219, R.sup.D220, R.sup.D227, R.sup.D237, R.sup.D241, R.sup.D242, R.sup.D245, and R.sup.D246.
[0070] In some embodiments of the OLED, where the first emitter is Compound B, Compound C, Compound D, or Compound E, all having the formula (L.sub.B).sub.nIr(L.sup.3-L.sup.4).sub.3−n, the ligand (L.sup.3-L.sup.4) is selected from the group consisting of:
##STR00119## ##STR00120## ##STR00121## ##STR00122## ##STR00123##
[0071] In some embodiments of the OLED, the first emitter is selected from the group consisting of: (L.sub.B1-1).sub.2Ir(L.sub.C1-1) to (L.sub.B4-1170).sub.2Ir(L.sub.C1416-1) based on the general formula (L.sub.Bp-h).sub.2Ir(L.sub.Cj-1), and (L.sub.B1-1).sub.2Ir(L.sub.C1-II) to (L.sub.B4-1170).sub.2Ir(L.sub.C1416-II) based on the general formula (L.sub.Bp-h).sub.2Ir(L.sub.Cj-11); wherein p is an integer from 1 to 4, and h is an integer from 1 to 1170.
[0072] In some embodiments of the OLED where the first emitter is Compound B, Compound C, Compound D, or Compound E, the first emitter is selected from the group consisting of:
##STR00124## ##STR00125## ##STR00126## ##STR00127## ##STR00128## ##STR00129## ##STR00130## ##STR00131## ##STR00132## ##STR00133## ##STR00134## ##STR00135## ##STR00136## ##STR00137## ##STR00138## ##STR00139## ##STR00140## ##STR00141##
[0073] In some embodiments of the OLED where the first emitter is selected from the group consisting of (L.sup.1-L.sup.2).sub.nIr(L.sub.A).sub.3−n and (L.sub.B).sub.nIr(L.sup.3-L.sup.4).sub.3−n defined herein, the first host has the formula of C.sup.D-L-G.sup.A, wherein L is a direct bond or an organic linker. In some embodiments, each of the at least one donor group G.sup.D independently comprises at least one moiety selected from the group consisting of amino, indole, carbazole, benzothiophene, benzofuran, benzoselenophene, dibenzothiophene, dibenzofuran, and dibenzoselenophene.
[0074] In some embodiments of the OLED of the present disclosure, each of the at least one donor group G.sup.D independently comprises at least one moiety selected from the group consisting of amino, indole, carbazole, benzothiophene, benzofuran, benzoselenophene, dibenzothiophene, dibenzofuran, and dibenzoselenophene.
[0075] In some embodiments of the OLED where the first host has the formula of G.sup.D-L-G.sup.A, and L is a direct bond or an organic linker, each of the at least one acceptor group G.sup.A independently comprises at least one moiety selected from the group consisting of nitrile, isonitrile, fluoride, a six-membered aromatic ring having at least one nitrogen, and a 5-membered aromatic ring having at least two heteroatoms.
[0076] In some embodiments of the OLED of the present disclosure, each of the at least one acceptor group G.sup.A independently comprises at least one moiety selected from the group consisting of nitrile, isonitrile, fluoride, a six-membered aromatic ring having at least one nitrogen, and a 5-membered aromatic ring having at least two heteroatoms.
[0077] In some embodiments of the OLED of the present disclosure, each of the at least one donor group G.sup.D independently comprises at least one moiety selected from the group consisting of:
##STR00142##
wherein X is selected from the group consisting of O, S, Se, and NR; and wherein each R is independently selected from (i) G.sup.A, (ii) an organic linker bonded to G.sup.A, and (iii) a terminal group selected from the group consisting of alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, aryl, heteroaryl, and combinations thereof.
[0078] In some embodiments of the OLED of the present disclosure, each of the at least one acceptor group G.sup.A independently comprises at least one moiety selected from the group consisting of nitrile, isonitrile, borane, fluoride, pyridine, pyrimidine, pyrazine, triazine, aza-carbazole, aza-dibenzothiophene, aza-dibenzofuran, aza-dibenzoselenophene, aza-triphenylene, imidazole, pyrazole, oxazole, thiazole, isoxazole, isothiazole, triazole, thiadiazole, and oxadiazole.
[0079] In some embodiments of the OLED of the present disclosure, the first host comprises at least two donor groups G.sup.D; and at least two acceptor groups G.sup.A; wherein each donor group G.sup.D and acceptor group G.sup.A can be the same or different; wherein any pair of donor groups G.sup.D is separated by at least one acceptor group G.sup.A; and wherein any pair of acceptor groups G.sup.A is separated by at least one donor group G.sup.D. In some embodiments, the total number of the donor groups G.sup.D is equal to the total number of the acceptor groups G.sup.A.
[0080] In some embodiments of the OLED of the present disclosure, wherein each of the at least one donor group G.sup.D is independently selected from the group consisting of:
##STR00143## ##STR00144## ##STR00145## ##STR00146## ##STR00147## ##STR00148## ##STR00149## ##STR00150## ##STR00151## ##STR00152## ##STR00153## ##STR00154## ##STR00155## ##STR00156## ##STR00157## ##STR00158## ##STR00159##
wherein each donor group G.sup.D is at least monovalent; and in structures containing a dashed line, the dashed line represents a bond to a linker or an acceptor group G.sup.A.
[0081] In some embodiments of the OLED of the present disclosure, each of the at least one acceptor group G.sup.A is independently selected from the group consisting of:
##STR00160## ##STR00161## ##STR00162## ##STR00163## ##STR00164##
wherein, each acceptor group G.sup.A is at least monovalent; and in structures containing a dashed line, the dashed line represents a bond to a linker or a donor group G.sup.D.
[0082] In some embodiments of the OLED of the present disclosure, the first host is selected from the group consisting of:
##STR00165## ##STR00166## ##STR00167## ##STR00168## ##STR00169## ##STR00170## ##STR00171## ##STR00172## ##STR00173## ##STR00174## ##STR00175## ##STR00176## ##STR00177## ##STR00178##
[0083] In some embodiments of the OLED of the present disclosure, the compound is a sensitizer and the OLED further comprises an acceptor; and wherein the acceptor is selected from the group consisting of fluorescent emitter, delayed fluorescence emitter, and combination thereof.
[0084] In some embodiments, the organic layer may be an emissive layer and the compound as described herein may be an emissive dopant or a non-emissive dopant.
[0085] In some embodiments, the organic layer may further comprise a host, wherein the host comprises a triphenylene containing benzo-fused thiophene or benzo-fused furan, wherein any substituent in the host is an unfused substituent independently selected from the group consisting of C.sub.nH.sub.2n+1, OC.sub.nH.sub.2n+1, OAr.sub.1, N(C.sub.nH.sub.2n+1).sub.2, N(Ar.sub.1)(Ar.sub.2), CH═CH—C.sub.nH.sub.2n+1, C≡CC.sub.nH.sub.2n+1, Ar.sub.1, Ar.sub.1—Ar.sub.2, C.sub.nH.sub.2n—Ar.sub.1, or no substitution, wherein n is from 1 to 10; and wherein Ar.sub.1 and Ar.sub.e are independently selected from the group consisting of benzene, biphenyl, naphthalene, triphenylene, carbazole, and heteroaromatic analogs thereof.
[0086] In some embodiments, the organic layer may further comprise a host, wherein host comprises at least one chemical group selected from the group consisting of triphenylene, carbazole, indolocarbazole, dibenzothiophene, dibenzofuran, dibenzoselenophene, 5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracene, aza-triphenylene, aza-carbazole, aza-indolocarbazole, aza-dibenzothiophene, aza-dibenzofuran, aza-dibenzoselenophene, and aza-(5,9-dioxa-13b-bomnaphtho[3,2,1-de]anthracene).
[0087] In some embodiments, the host may be selected from the HOST Group consisting of:
##STR00179## ##STR00180## ##STR00181## ##STR00182## ##STR00183## ##STR00184## ##STR00185## ##STR00186##
and combinations thereof.
[0088] In some embodiments, the organic layer may further comprise a host, wherein the host comprises a metal complex.
[0089] In some embodiments, the compound as described herein may be a sensitizer; wherein the device may further comprise an acceptor; and wherein the acceptor may be selected from the group consisting of fluorescent emitter, delayed fluorescence emitter, and combination thereof.
[0090] In yet another aspect, the OLED of the present disclosure may also comprise an emissive region containing a compound as disclosed in the above compounds section of the present disclosure.
[0091] Also disclosed is an emissive layer in an OLED that comprises: a first host; and a first emitter; where the first emitter is selected from the group consisting of (L.sup.1-L.sup.2).sub.nIr(L.sub.A).sub.3−n and (L.sub.B).sub.nIr(L.sup.3-L.sup.4).sub.3−n;
where (L.sup.1-L.sup.2).sub.nIr(L.sub.A).sub.3−n is
##STR00187##
and (L.sub.B).sub.nIr(L.sup.3-L.sup.4).sub.3−n is
##STR00188##
wherein: each R.sup.S11, R.sup.S12, and R.sup.S13 independently represents zero, mono, or up to a maximum allowed substitution to its associated ring; each L.sup.1-L.sup.2 and L.sup.3-L.sup.4 independently represents an anionic bidentate ligand; n is 1 or 2; each R.sup.S1, R.sup.S2, R.sup.S3, R.sup.S4, R.sup.S5, R.sup.S6, is independently selected from the group consisting of alkyl, cycloalkyl, partially or fully fluorinated variants thereof, partially or fully deuterated variants thereof, and combinations thereof; each R.sup.S11, R.sup.S12, and R.sup.S13 is independently a hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, boryl, and combinations thereof; at least one of R.sup.S11, R.sup.S12, and R.sup.S13 is selected from the group consisting of deuterium, silyl, C1 to C3 alkyl, substituted or unsubstituted cycloalkyl, and a branch substituted or unsubstituted alkyl with the branching occurs at the benzylic position; and the first host comprises at least one donor group G.sup.D, and at least one acceptor group G.sup.A.
[0092] In some embodiments, at least one of the anode, the cathode, or a new layer disposed over the organic emissive layer functions as an enhancement layer. The enhancement layer comprises a plasmonic material exhibiting surface plasmon resonance that non-radiatively couples to the emitter material and transfers excited state energy from the emitter material to non-radiative mode of surface plasmon polariton. The enhancement layer is provided no more than a threshold distance away from the organic emissive layer, wherein the emitter material has a total non-radiative decay rate constant and a total radiative decay rate constant due to the presence of the enhancement layer and the threshold distance is where the total non-radiative decay rate constant is equal to the total radiative decay rate constant. In some embodiments, the OLED further comprises an outcoupling layer. In some embodiments, the outcoupling layer is disposed over the enhancement layer on the opposite side of the organic emissive layer. In some embodiments, the outcoupling layer is disposed on opposite side of the emissive layer from the enhancement layer but still outcouples energy from the surface plasmon mode of the enhancement layer. The outcoupling layer scatters the energy from the surface plasmon polaritons. In some embodiments this energy is scattered as photons to free space. In other embodiments, the energy is scattered from the surface plasmon mode into other modes of the device such as but not limited to the organic waveguide mode, the substrate mode, or another waveguiding mode. If energy is scattered to the non-free space mode of the OLED other outcoupling schemes could be incorporated to extract that energy to free space. In some embodiments, one or more intervening layer can be disposed between the enhancement layer and the outcoupling layer. The examples for interventing layer(s) can be dielectric materials, including organic, inorganic, perovskites, oxides, and may include stacks and/or mixtures of these materials.
[0093] The enhancement layer modifies the effective properties of the medium in which the emitter material resides resulting in any or all of the following: a decreased rate of emission, a modification of emission line-shape, a change in emission intensity with angle, a change in the stability of the emitter material, a change in the efficiency of the OLED, and reduced efficiency roll-off of the OLED device. Placement of the enhancement layer on the cathode side, anode side, or on both sides results in OLED devices which take advantage of any of the above-mentioned effects. In addition to the specific functional layers mentioned herein and illustrated in the various OLED examples shown in the figures, the OLEDs according to the present disclosure may include any of the other functional layers often found in OLEDs.
[0094] The enhancement layer can be comprised of plasmonic materials, optically active metamaterials, or hyperbolic metamaterials. As used herein, a plasmonic material is a material in which the real part of the dielectric constant crosses zero in the visible or ultraviolet region of the electromagnetic spectrum. In some embodiments, the plasmonic material includes at least one metal. In such embodiments the metal may include at least one of Ag, Al, Au, Ir, Pt, Ni, Cu, W, Ta, Fe, Cr, Mg, Ga, Rh, Ti, Ru, Pd, In, Bi, Ca alloys or mixtures of these materials, and stacks of these materials. In general, a metamaterial is a medium composed of different materials where the medium as a whole acts differently than the sum of its material parts. In particular, we define optically active metamaterials as materials which have both negative permittivity and negative permeability. Hyperbolic metamaterials, on the other hand, are anisotropic media in which the permittivity or permeability are of different sign for different spatial directions. Optically active metamaterials and hyperbolic metamaterials are strictly distinguished from many other photonic structures such as Distributed Bragg Reflectors (“DBRs”) in that the medium should appear uniform in the direction of propagation on the length scale of the wavelength of light. Using terminology that one skilled in the art can understand: the dielectric constant of the metamaterials in the direction of propagation can be described with the effective medium approximation. Plasmonic materials and metamaterials provide methods for controlling the propagation of light that can enhance OLED performance in a number of ways.
[0095] In some embodiments, the enhancement layer is provided as a planar layer. In other embodiments, the enhancement layer has wavelength-sized features that are arranged periodically, quasi-periodically, or randomly, or sub-wavelength-sized features that are arranged periodically, quasi-periodically, or randomly. In some embodiments, the wavelength-sized features and the sub-wavelength-sized features have sharp edges.
[0096] In some embodiments, the outcoupling layer has wavelength-sized features that are arranged periodically, quasi-periodically, or randomly, or sub-wavelength-sized features that are arranged periodically, quasi-periodically, or randomly. In some embodiments, the outcoupling layer may be composed of a plurality of nanoparticles and in other embodiments the outcoupling layer is composed of a plurality of nanoparticles disposed over a material. In these embodiments the outcoupling may be tunable by at least one of varying a size of the plurality of nanoparticles, varying a shape of the plurality of nanoparticles, changing a material of the plurality of nanoparticles, adjusting a thickness of the material, changing the refractive index of the material or an additional layer disposed on the plurality of nanoparticles, varying a thickness of the enhancement layer, and/or varying the material of the enhancement layer. The plurality of nanoparticles of the device may be formed from at least one of metal, dielectric material, semiconductor materials, an alloy of metal, a mixture of dielectric materials, a stack or layering of one or more materials, and/or a core of one type of material and that is coated with a shell of a different type of material. In some embodiments, the outcoupling layer is composed of at least metal nanoparticles wherein the metal is selected from the group consisting of Ag, Al, Au, Ir, Pt, Ni, Cu, W, Ta, Fe, Cr, Mg, Ga, Rh, Ti, Ru, Pd, In, Bi, Ca, alloys or mixtures of these materials, and stacks of these materials. The plurality of nanoparticles may have additional layer disposed over them. In some embodiments, the polarization of the emission can be tuned using the outcoupling layer. Varying the dimensionality and periodicity of the outcoupling layer can select a type of polarization that is preferentially outcoupled to air. In some embodiments the outcoupling layer also acts as an electrode of the device.
[0097] In yet another aspect, the present disclosure also provides a consumer product comprising an organic light-emitting device (OLED) having an anode; a cathode; and an organic layer disposed between the anode and the cathode, wherein the organic layer may comprise a compound as disclosed in the above compounds section of the present disclosure.
[0098] In some embodiments, the consumer product comprises an OLED having an anode; a cathode; and an organic emissive layer disposed between the anode and the cathode, wherein the organic emissive layer can comprise a first host; and a first emitter; wherein the first emitter is selected from the group consisting of (L.sup.1-L.sup.2).sub.nIr(L.sub.A).sub.3−n and (L.sub.B).sub.nIr(L.sup.3-L.sup.4).sub.3−n;
wherein (L.sup.1-L.sup.2).sub.nIr(L.sub.A).sub.3−n
##STR00189##
and (L.sub.B).sub.nIr(L.sup.3-L.sup.4).sub.3−n is
##STR00190##
wherein each R.sup.S11, R.sup.S12, and R.sup.S13 independently represents zero, mono, or up to a maximum allowed substitution to its associated ring;
wherein each L.sup.1-L.sup.2 and L.sup.3-L.sup.4 independently represents an anionic bidentate ligand;
wherein n is 1 or 2;
wherein each R.sup.S1, R.sup.S2, R.sup.S3, R.sup.S4, R.sup.S5, R.sup.S6, is independently selected from the group consisting of alkyl, cycloalkyl, partially or fully fluorinated variants thereof, partially or fully deuterated variants thereof, and combinations thereof;
wherein each R.sup.S11, R.sup.S12, and R.sup.S13 is independently a hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, boryl, and combinations thereof;
wherein at least one of R.sup.S11, R.sup.S12, and R.sup.S13 is selected from the group consisting of deuterium, silyl, C1 to C3 alkyl, substituted or unsubstituted cycloalkyl, and a branch substituted or unsubstituted alkyl with the branching occurs at the benzylic position; and
wherein the first host comprises at least one donor group G.sup.D, and at least one acceptor group G.sup.A.
[0099] In some embodiments, the consumer product can be one of a flat panel display, a computer monitor, a medical monitor, a television, a billboard, a light for interior or exterior illumination and/or signaling, a heads-up display, a fully or partially transparent display, a flexible display, a laser printer, a telephone, a cell phone, tablet, a phablet, a personal digital assistant (PDA), a wearable device, a laptop computer, a digital camera, a camcorder, a viewfinder, a micro-display that is less than 2 inches diagonal, a 3-D display, a virtual reality or augmented reality display, a vehicle, a video wall comprising multiple displays tiled together, a theater or stadium screen, a light therapy device, and a sign.
[0100] Generally, an OLED comprises at least one organic layer disposed between and electrically connected to an anode and a cathode. When a current is applied, the anode injects holes and the cathode injects electrons into the organic layer(s). The injected holes and electrons each migrate toward the oppositely charged electrode. When an electron and hole localize on the same molecule, an “exciton,” which is a localized electron-hole pair having an excited energy state, is formed. Light is emitted when the exciton relaxes via a photoemissive mechanism. In some cases, the exciton may be localized on an excimer or an exciplex. Non-radiative mechanisms, such as thermal relaxation, may also occur, but are generally considered undesirable.
[0101] Several OLED materials and configurations are described in U.S. Pat. Nos. 5,844,363, 6,303,238, and 5,707,745, which are incorporated herein by reference in their entirety.
[0102] The initial OLEDs used emissive molecules that emitted light from their singlet states (“fluorescence”) as disclosed, for example, in U.S. Pat. No. 4,769,292, which is incorporated by reference in its entirety. Fluorescent emission generally occurs in a time frame of less than 10 nanoseconds.
[0103] More recently, OLEDs having emissive materials that emit light from triplet states (“phosphorescence”) have been demonstrated. Baldo et al., “Highly Efficient Phosphorescent Emission from Organic Electroluminescent Devices,” Nature, vol. 395, 151-154, 1998; (“Baldo-I”) and Baldo et al., “Very high-efficiency green organic light-emitting devices based on electrophosphorescence,” Appl. Phys. Lett., vol. 75, No. 3, 4-6 (1999) (“Baldo-II”), are incorporated by reference in their entireties. Phosphorescence is described in more detail in U.S. Pat. No. 7,279,704 at cols. 5-6, which are incorporated by reference.
[0104]
[0105] More examples for each of these layers are available. For example, a flexible and transparent substrate-anode combination is disclosed in U.S. Pat. No. 5,844,363, which is incorporated by reference in its entirety. An example of a p-doped hole transport layer is m-MTDATA doped with F.sub.4-TCNQ at a molar ratio of 50:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. Examples of emissive and host materials are disclosed in U.S. Pat. No. 6,303,238 to Thompson et al., which is incorporated by reference in its entirety. An example of an n-doped electron transport layer is BPhen doped with Li at a molar ratio of 1:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. U.S. Pat. Nos. 5,703,436 and 5,707,745, which are incorporated by reference in their entireties, disclose examples of cathodes including compound cathodes having a thin layer of metal such as Mg:Ag with an overlying transparent, electrically-conductive, sputter-deposited ITO layer. The theory and use of blocking layers is described in more detail in U.S. Pat. No. 6,097,147 and U.S. Patent Application Publication No. 2003/0230980, which are incorporated by reference in their entireties. Examples of injection layers are provided in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety. A description of protective layers may be found in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety.
[0106]
[0107] The simple layered structure illustrated in
[0108] Structures and materials not specifically described may also be used, such as OLEDs comprised of polymeric materials (PLEDs) such as disclosed in U.S. Pat. No. 5,247,190 to Friend et al., which is incorporated by reference in its entirety. By way of further example, OLEDs having a single organic layer may be used. OLEDs may be stacked, for example as described in U.S. Pat. No. 5,707,745 to Forrest et al, which is incorporated by reference in its entirety. The OLED structure may deviate from the simple layered structure illustrated in
[0109] Unless otherwise specified, any of the layers of the various embodiments may be deposited by any suitable method. For the organic layers, preferred methods include thermal evaporation, ink-jet, such as described in U.S. Pat. Nos. 6,013,982 and 6,087,196, which are incorporated by reference in their entireties, organic vapor phase deposition (OVPD), such as described in U.S. Pat. No. 6,337,102 to Forrest et al., which is incorporated by reference in its entirety, and deposition by organic vapor jet printing (OVJP), such as described in U.S. Pat. No. 7,431,968, which is incorporated by reference in its entirety. Other suitable deposition methods include spin coating and other solution based processes. Solution based processes are preferably carried out in nitrogen or an inert atmosphere. For the other layers, preferred methods include thermal evaporation. Preferred patterning methods include deposition through a mask, cold welding such as described in U.S. Pat. Nos. 6,294,398 and 6,468,819, which are incorporated by reference in their entireties, and patterning associated with some of the deposition methods such as ink jet and organic vapor jet printing (OVJP). Other methods may also be used. The materials to be deposited may be modified to make them compatible with a particular deposition method. For example, substituents such as alkyl and aryl groups, branched or unbranched, and preferably containing at least 3 carbons, may be used in small molecules to enhance their ability to undergo solution processing. Substituents having 20 carbons or more may be used, and 3-20 carbons are a preferred range. Materials with asymmetric structures may have better solution processability than those having symmetric structures, because asymmetric materials may have a lower tendency to recrystallize Dendrimer substituents may be used to enhance the ability of small molecules to undergo solution processing.
[0110] Devices fabricated in accordance with embodiments of the present disclosure may further optionally comprise a barrier layer. One purpose of the barrier layer is to protect the electrodes and organic layers from damaging exposure to harmful species in the environment including moisture, vapor and/or gases, etc. The barrier layer may be deposited over, under or next to a substrate, an electrode, or over any other parts of a device including an edge. The barrier layer may comprise a single layer, or multiple layers. The barrier layer may be formed by various known chemical vapor deposition techniques and may include compositions having a single phase as well as compositions having multiple phases. Any suitable material or combination of materials may be used for the barrier layer. The barrier layer may incorporate an inorganic or an organic compound or both. The preferred barrier layer comprises a mixture of a polymeric material and a non-polymeric material as described in U.S. Pat. No. 7,968,146, PCT Pat. Application Nos. PCT/US2007/023098 and PCT/US2009/042829, which are herein incorporated by reference in their entireties. To be considered a “mixture”, the aforesaid polymeric and non-polymeric materials comprising the barrier layer should be deposited under the same reaction conditions and/or at the same time. The weight ratio of polymeric to non-polymeric material may be in the range of 95:5 to 5:95. The polymeric material and the non-polymeric material may be created from the same precursor material. In one example, the mixture of a polymeric material and a non-polymeric material consists essentially of polymeric silicon and inorganic silicon.
[0111] Devices fabricated in accordance with embodiments of the present disclosure can be incorporated into a wide variety of electronic component modules (or units) that can be incorporated into a variety of electronic products or intermediate components. Examples of such electronic products or intermediate components include display screens, lighting devices such as discrete light source devices or lighting panels, etc. that can be utilized by the end-user product manufacturers. Such electronic component modules can optionally include the driving electronics and/or power source(s). Devices fabricated in accordance with embodiments of the present disclosure can be incorporated into a wide variety of consumer products that have one or more of the electronic component modules (or units) incorporated therein. A consumer product comprising an OLED that includes the compound of the present disclosure in the organic layer in the OLED is disclosed. Such consumer products would include any kind of products that include one or more light source(s) and/or one or more of some type of visual displays. Some examples of such consumer products include flat panel displays, curved displays, computer monitors, medical monitors, televisions, billboards, lights for interior or exterior illumination and/or signaling, heads-up displays, fully or partially transparent displays, flexible displays, rollable displays, foldable displays, stretchable displays, laser printers, telephones, mobile phones, tablets, phablets, personal digital assistants (PDAs), wearable devices, laptop computers, digital cameras, camcorders, viewfinders, micro-displays (displays that are less than 2 inches diagonal), 3-D displays, virtual reality or augmented reality displays, vehicles, video walls comprising multiple displays tiled together, theater or stadium screen, a light therapy device, and a sign. Various control mechanisms may be used to control devices fabricated in accordance with the present disclosure, including passive matrix and active matrix. Many of the devices are intended for use in a temperature range comfortable to humans, such as 18 degrees C. to 30 degrees C., and more preferably at room temperature (20-25° C.), but could be used outside this temperature range, for example, from −40 degree C. to +80° C.
[0112] More details on OLEDs, and the definitions described above, can be found in U.S. Pat. No. 7,279,704, which is incorporated herein by reference in its entirety.
[0113] The materials and structures described herein may have applications in devices other than OLEDs. For example, other optoelectronic devices such as organic solar cells and organic photodetectors may employ the materials and structures. More generally, organic devices, such as organic transistors, may employ the materials and structures.
[0114] In some embodiments, the OLED has one or more characteristics selected from the group consisting of being flexible, being rollable, being foldable, being stretchable, and being curved. In some embodiments, the OLED is transparent or semi-transparent. In some embodiments, the OLED further comprises a layer comprising carbon nanotubes.
[0115] In some embodiments, the OLED further comprises a layer comprising a delayed fluorescent emitter. In some embodiments, the OLED comprises a RGB pixel arrangement or white plus color filter pixel arrangement. In some embodiments, the OLED is a mobile device, a hand held device, or a wearable device. In some embodiments, the OLED is a display panel having less than 10 inch diagonal or 50 square inch area. In some embodiments, the OLED is a display panel having at least 10 inch diagonal or 50 square inch area. In some embodiments, the OLED is a lighting panel.
[0116] In some embodiments, the compound can be an emissive dopant. In some embodiments, the compound can produce emissions via phosphorescence, fluorescence, thermally activated delayed fluorescence, i.e., TADF (also referred to as E-type delayed fluorescence; see, e.g., U.S. application Ser. No. 15/700,352, which is hereby incorporated by reference in its entirety), triplet-triplet annihilation, or combinations of these processes. In some embodiments, the emissive dopant can be a racemic mixture, or can be enriched in one enantiomer. In some embodiments, the compound can be homoleptic (each ligand is the same). In some embodiments, the compound can be heteroleptic (at least one ligand is different from others). When there are more than one ligand coordinated to a metal, the ligands can all be the same in some embodiments. In some other embodiments, at least one ligand is different from the other ligands. In some embodiments, every ligand can be different from each other. This is also true in embodiments where a ligand being coordinated to a metal can be linked with other ligands being coordinated to that metal to form a tridentate, tetradentate, pentadentate, or hexadentate ligands Thus, where the coordinating ligands are being linked together, all of the ligands can be the same in some embodiments, and at least one of the ligands being linked can be different from the other ligand(s) in some other embodiments.
[0117] In some embodiments, the compound can be used as a phosphorescent sensitizer in an OLED where one or multiple layers in the OLED contains an acceptor in the form of one or more fluorescent and/or delayed fluorescence emitters. In some embodiments, the compound can be used as one component of an exciplex to be used as a sensitizer. As a phosphorescent sensitizer, the compound must be capable of energy transfer to the acceptor and the acceptor will emit the energy or further transfer energy to a final emitter. The acceptor concentrations can range from 0.001% to 100%. The acceptor could be in either the same layer as the phosphorescent sensitizer or in one or more different layers. In some embodiments, the acceptor is a TADF emitter. In some embodiments, the acceptor is a fluorescent emitter. In some embodiments, the emission can arise from any or all of the sensitizer, acceptor, and final emitter.
[0118] According to another aspect, a formulation comprising the compound described herein is also disclosed.
[0119] The OLED disclosed herein can be incorporated into one or more of a consumer product, an electronic component module, and a lighting panel. The organic layer can be an emissive layer and the compound can be an emissive dopant in some embodiments, while the compound can be a non-emissive dopant in other embodiments.
[0120] In yet another aspect of the present disclosure, a formulation that comprises the novel compound disclosed herein is described. The formulation can include one or more components selected from the group consisting of a solvent, a host, a hole injection material, hole transport material, electron blocking material, hole blocking material, and an electron transport material, disclosed herein.
[0121] The present disclosure encompasses any chemical structure comprising the novel compound of the present disclosure, or a monovalent or polyvalent variant thereof. In other words, the inventive compound, or a monovalent or polyvalent variant thereof, can be a part of a larger chemical structure. Such chemical structure can be selected from the group consisting of a monomer, a polymer, a macromolecule, and a supramolecule (also known as supermolecule). As used herein, a “monovalent variant of a compound” refers to a moiety that is identical to the compound except that one hydrogen has been removed and replaced with a bond to the rest of the chemical structure. As used herein, a “polyvalent variant of a compound” refers to a moiety that is identical to the compound except that more than one hydrogen has been removed and replaced with a bond or bonds to the rest of the chemical structure. In the instance of a supramolecule, the inventive compound can also be incorporated into the supramolecule complex without covalent bonds.
D. Combination of the Compounds of the Present Disclosure with Other Materials
[0122] The materials described herein as useful for a particular layer in an organic light emitting device may be used in combination with a wide variety of other materials present in the device. For example, emissive dopants disclosed herein may be used in conjunction with a wide variety of hosts, transport layers, blocking layers, injection layers, electrodes and other layers that may be present. The materials described or referred to below are non-limiting examples of materials that may be useful in combination with the compounds disclosed herein, and one of skill in the art can readily consult the literature to identify other materials that may be useful in combination.
a) Conductivity Dopants:
[0123] A charge transport layer can be doped with conductivity dopants to substantially alter its density of charge carriers, which will in turn alter its conductivity. The conductivity is increased by generating charge carriers in the matrix material, and depending on the type of dopant, a change in the Fermi level of the semiconductor may also be achieved. Hole-transporting layer can be doped by p-type conductivity dopants and n-type conductivity dopants are used in the electron-transporting layer.
[0124] Non-limiting examples of the conductivity dopants that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: EP01617493, EP01968131, EP2020694, EP2684932, US20050139810, US20070160905, US20090167167, US2010288362, WO06081780, WO2009003455, WO2009008277, WO2009011327, WO2014009310, US2007252140, US2015060804, US20150123047, and US2012146012.
##STR00191## ##STR00192## ##STR00193##
b) HIL/HTL:
[0125] A hole injecting/transporting material to be used in the present disclosure is not particularly limited, and any compound may be used as long as the compound is typically used as a hole injecting/transporting material. Examples of the material include, but are not limited to: a phthalocyanine or porphyrin derivative; an aromatic amine derivative; an indolocarbazole derivative; a polymer containing fluorohydrocarbon; a polymer with conductivity dopants; a conducting polymer, such as PEDOT/PSS; a self-assembly monomer derived from compounds such as phosphoric acid and silane derivatives; a metal oxide derivative, such as MoO.sub.x; a p-type semiconducting organic compound, such as 1,4,5,8,9,12-Hexaazatriphenylenehexacarbonitrile; a metal complex, and a cross-linkable compounds.
[0126] Examples of aromatic amine derivatives used in HIL or HTL include, but not limit to the following general structures:
##STR00194##
[0127] Each of Ar.sup.1 to Ar.sup.9 is selected from the group consisting of aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene; the group consisting of aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and the group consisting of 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Each Ar may be unsubstituted or may be substituted by a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.
[0128] In one aspect, Ar.sup.1 to Ar.sup.9 is independently selected from the group consisting of:
##STR00195##
wherein k is an integer from 1 to 20; X.sup.101 to X.sup.108 is C (including CH) or N; Z.sup.101 is NAr.sup.1, O, or S; Ar.sup.1 has the same group defined above.
[0129] Examples of metal complexes used in HIL or HTL include, but are not limited to the following general formula:
##STR00196##
wherein Met is a metal, which can have an atomic weight greater than 40; (Y.sup.101-Y.sup.102) is a bidentate ligand, Y.sup.101 and Y.sup.102 are independently selected from C, N, O, P, and S; L.sup.101 is an ancillary ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and k′+k″ is the maximum number of ligands that may be attached to the metal.
[0130] In one aspect, (Y.sup.101-Y.sup.102) is a 2-phenylpyridine derivative. In another aspect, (Y.sup.101-Y.sup.102) is a carbene ligand. In another aspect, Met is selected from Ir, Pt, Os, and Zn. In a further aspect, the metal complex has a smallest oxidation potential in solution vs. Fc.sup.+/Fc couple less than about 0.6 V.
[0131] Non-limiting examples of the HIL and HTL materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN102702075, DE102012005215, EP01624500, EP01698613, EP01806334, EP01930964, EP01972613, EP01997799, EP02011790, EP02055700, EP02055701, EP1725079, EP2085382, EP2660300, EP650955, JP07-073529, JP2005112765, JP2007091719, JP2008021687, JP2014-009196, KR20110088898, KR20130077473, TW201139402, U.S. Ser. No. 06/517,957, US20020158242, US20030162053, US20050123751, US20060182993, US20060240279, US20070145888, US20070181874, US20070278938, US20080014464, US20080091025, US20080106190, US20080124572, US20080145707, US20080220265, US20080233434, US20080303417, US2008107919, US20090115320, US20090167161, US2009066235, US2011007385, US20110163302, US2011240968, US2011278551, US2012205642, US2013241401, US20140117329, US2014183517, U.S. Pat. Nos. 5,061,569, 5,639,914, WO05075451, WO07125714, WO08023550, WO08023759, WO2009145016, WO2010061824, WO2011075644, WO2012177006, WO2013018530, WO2013039073, WO2013087142, WO2013118812, WO2013120577, WO2013157367, WO2013175747, WO2014002873, WO2014015935, WO2014015937, WO2014030872, WO2014030921, WO2014034791, WO2014104514, WO2014157018.
##STR00197## ##STR00198## ##STR00199## ##STR00200## ##STR00201## ##STR00202## ##STR00203## ##STR00204## ##STR00205## ##STR00206## ##STR00207## ##STR00208## ##STR00209## ##STR00210## ##STR00211##
c) EBL:
[0132] An electron blocking layer (EBL) may be used to reduce the number of electrons and/or excitons that leave the emissive layer. The presence of such a blocking layer in a device may result in substantially higher efficiencies, and/or longer lifetime, as compared to a similar device lacking a blocking layer. Also, a blocking layer may be used to confine emission to a desired region of an OLED. In some embodiments, the EBL material has a higher LUMO (closer to the vacuum level) and/or higher triplet energy than the emitter closest to the EBL interface. In some embodiments, the EBL material has a higher LUMO (closer to the vacuum level) and/or higher triplet energy than one or more of the hosts closest to the EBL interface. In one aspect, the compound used in EBL contains the same molecule or the same functional groups used as one of the hosts described below.
d) Hosts:
[0133] The light emitting layer of the organic EL device of the present disclosure preferably contains at least a metal complex as light emitting material, and may contain a host material using the metal complex as a dopant material. Examples of the host material are not particularly limited, and any metal complexes or organic compounds may be used as long as the triplet energy of the host is larger than that of the dopant. Any host material may be used with any dopant so long as the triplet criteria is satisfied.
[0134] Examples of metal complexes used as host are preferred to have the following general formula:
##STR00212##
wherein Met is a metal; (Y.sup.103-Y.sup.104) is a bidentate ligand, Y.sup.103 and Y.sup.104 are independently selected from C, N, O, P, and S; L.sup.101 is an another ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and k′+k″ is the maximum number of ligands that may be attached to the metal.
[0135] In one aspect, the metal complexes are:
##STR00213##
wherein (O—N) is a bidentate ligand, having metal coordinated to atoms O and N.
[0136] In another aspect, Met is selected from Ir and Pt. In a further aspect, (Y.sup.103-Y.sup.104) is a carbene ligand.
[0137] In one aspect, the host compound contains at least one of the following groups selected from the group consisting of aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene; the group consisting of aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and the group consisting of 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Each option within each group may be unsubstituted or may be substituted by a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.
[0138] In one aspect, the host compound contains at least one of the following groups in the molecule:
##STR00214## ##STR00215##
wherein R.sup.101 is selected from the group consisting of hydrogen, deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, and when it is aryl or heteroaryl, it has the similar definition as Ar's mentioned above. k is an integer from 0 to 20 or 1 to 20. X.sup.101 to X.sup.108 are independently selected from C (including CH) or N. Z.sup.101 and Z.sup.102 are independently selected from NR.sup.101, O, or S.
[0139] Non-limiting examples of the host materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: EP2034538, EP2034538A, EP2757608, JP2007254297, KR20100079458, KR20120088644, KR20120129733, KR20130115564, TW201329200, US20030175553, US20050238919, US20060280965, US20090017330, US20090030202, US20090167162, US20090302743, US20090309488, US20100012931, US20100084966, US20100187984, US2010187984, US2012075273, US2012126221, US2013009543, US2013105787, US2013175519, US2014001446, US20140183503, US20140225088, US2014034914, U.S. Pat. No. 7,154,114, WO2001039234, WO2004093207, WO2005014551, WO2005089025, WO2006072002, WO2006114966, WO2007063754, WO2008056746, WO2009003898, WO2009021126, WO2009063833, WO2009066778, WO2009066779, WO2009086028, WO2010056066, WO2010107244, WO2011081423, WO2011081431, WO2011086863, WO2012128298, WO2012133644, WO2012133649, WO2013024872, WO2013035275, WO2013081315, WO2013191404, WO2014142472, US20170263869, US20160163995, U.S. Pat. No. 9,466,803,
##STR00216## ##STR00217## ##STR00218## ##STR00219## ##STR00220## ##STR00221## ##STR00222## ##STR00223## ##STR00224## ##STR00225## ##STR00226## ##STR00227##
e) Additional Emitters:
[0140] One or more additional emitter dopants may be used in conjunction with the compound of the present disclosure. Examples of the additional emitter dopants are not particularly limited, and any compounds may be used as long as the compounds are typically used as emitter materials. Examples of suitable emitter materials include, but are not limited to, compounds which can produce emissions via phosphorescence, fluorescence, thermally activated delayed fluorescence, i.e., TADF (also referred to as E-type delayed fluorescence), triplet-triplet annihilation, or combinations of these processes.
[0141] Non-limiting examples of the emitter materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN103694277, CN1696137, EB01238981, EP01239526, EP01961743, EP1239526, EP1244155, EP1642951, EP1647554, EP1841834, EP1841834B, EP2062907, EP2730583, JP2012074444, JP2013110263, JP4478555, KR1020090133652, KR20120032054, KR20130043460, TW201332980, U.S. Ser. No. 06/699,599, U.S. Ser. No. 06/916,554, US20010019782, US20020034656, US20030068526, US20030072964, US20030138657, US20050123788, US20050244673, US2005123791, US2005260449, US20060008670, US20060065890, US20060127696, US20060134459, US20060134462, US20060202194, US20060251923, US20070034863, US20070087321, US20070103060, US20070111026, US20070190359, US20070231600, US2007034863, US2007104979, US2007104980, US2007138437, US2007224450, US2007278936, US20080020237, US20080233410, US20080261076, US20080297033, US200805851, US2008161567, US2008210930, US20090039776, US20090108737, US20090115322, US20090179555, US2009085476, US2009104472, US20100090591, US20100148663, US20100244004, US20100295032, US2010102716, US2010105902, US2010244004, US2010270916, US20110057559, US20110108822, US20110204333, US2011215710, US2011227049, US2011285275, US2012292601, US20130146848, US2013033172, US2013165653, US2013181190, US2013334521, US20140246656, US2014103305, U.S. Pat. Nos. 6,303,238, 6,413,656, 6,653,654, 6,670,645, 6,687,266, 6,835,469, 6,921,915, 7,279,704, 7,332,232, 7,378,162, 7,534,505, 7,675,228, 7,728,137, 7,740,957, 7,759,489, 7,951,947, 8,067,099, 8,592,586, 8,871,361, WO06081973, WO06121811, WO07018067, WO07108362, WO07115970, WO07115981, WO08035571, WO2002015645, WO2003040257, WO2005019373, WO2006056418, WO2008054584, WO2008078800, WO2008096609, WO2008101842, WO2009000673, WO2009050281, WO2009100991, WO2010028151, WO2010054731, WO2010086089, WO2010118029, WO2011044988, WO2011051404, WO2011107491, WO2012020327, WO2012163471, WO2013094620, WO2013107487, WO2013174471, WO2014007565, WO2014008982, WO2014023377, WO2014024131, WO2014031977, WO2014038456, WO2014112450.
##STR00228## ##STR00229## ##STR00230## ##STR00231## ##STR00232## ##STR00233## ##STR00234## ##STR00235## ##STR00236## ##STR00237## ##STR00238## ##STR00239## ##STR00240## ##STR00241## ##STR00242## ##STR00243## ##STR00244## ##STR00245## ##STR00246## ##STR00247## ##STR00248##
f) HBL:
[0142] A hole blocking layer (HBL) may be used to reduce the number of holes and/or excitons that leave the emissive layer. The presence of such a blocking layer in a device may result in substantially higher efficiencies and/or longer lifetime as compared to a similar device lacking a blocking layer. Also, a blocking layer may be used to confine emission to a desired region of an OLED. In some embodiments, the HBL material has a lower HOMO (further from the vacuum level) and/or higher triplet energy than the emitter closest to the HBL interface. In some embodiments, the HBL material has a lower HOMO (further from the vacuum level) and/or higher triplet energy than one or more of the hosts closest to the HBL interface.
[0143] In one aspect, compound used in HBL contains the same molecule or the same functional groups used as host described above.
[0144] In another aspect, compound used in HBL contains at least one of the following groups in the molecule:
##STR00249##
wherein k is an integer from 1 to 20; L.sup.101 is another ligand, k′ is an integer from 1 to 3.
g) ETL:
[0145] Electron transport layer (ETL) may include a material capable of transporting electrons. Electron transport layer may be intrinsic (undoped), or doped. Doping may be used to enhance conductivity. Examples of the ETL material are not particularly limited, and any metal complexes or organic compounds may be used as long as they are typically used to transport electrons.
[0146] In one aspect, compound used in ETL contains at least one of the following groups in the molecule:
##STR00250##
wherein R.sup.101 is selected from the group consisting of hydrogen, deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, when it is aryl or heteroaryl, it has the similar definition as Ar's mentioned above. Ar.sup.1 to Ar.sup.3 has the similar definition as Ar's mentioned above. k is an integer from 1 to 20. X.sup.101 to X.sup.108 is selected from C (including CH) or N.
[0147] In another aspect, the metal complexes used in ETL contains, but not limit to the following general formula:
##STR00251##
wherein (O—N) or (N—N) is a bidentate ligand, having metal coordinated to atoms O, N or N, N; is another ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal.
[0148] Non-limiting examples of the ETL materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN103508940, EP01602648, EP01734038, EP01956007, JP2004-022334, JP2005149918, JP2005-268199, KR0117693, KR20130108183, US20040036077, US20070104977, US2007018155, US20090101870, US20090115316, US20090140637, US20090179554, US2009218940, US2010108990, US2011156017, US2011210320, US2012193612, US2012214993, US2014014925, US2014014927, US20140284580, U.S. Pat. Nos. 6,656,612, 8,415,031, WO2003060956, WO2007111263, WO2009148269, WO2010067894, WO2010072300, WO2011074770, WO2011105373, WO2013079217, WO2013145667, WO2013180376, WO2014104499, WO2014104535,
##STR00252## ##STR00253## ##STR00254## ##STR00255## ##STR00256## ##STR00257## ##STR00258## ##STR00259## ##STR00260##
h) Charge Generation Layer (CGL)
[0149] In tandem or stacked OLEDs, the CGL plays an essential role in the performance, which is composed of an n-doped layer and a p-doped layer for injection of electrons and holes, respectively. Electrons and holes are supplied from the CGL and electrodes. The consumed electrons and holes in the CGL are refilled by the electrons and holes injected from the cathode and anode, respectively; then, the bipolar currents reach a steady state gradually. Typical CGL materials include n and p conductivity dopants used in the transport layers.
[0150] In any above-mentioned compounds used in each layer of the OLED device, the hydrogen atoms can be partially or fully deuterated. Thus, any specifically listed substituent, such as, without limitation, methyl, phenyl, pyridyl, etc. may be undeuterated, partially deuterated, and fully deuterated versions thereof. Similarly, classes of substituents such as, without limitation, alkyl, aryl, cycloalkyl, heteroaryl, etc. also may be undeuterated, partially deuterated, and fully deuterated versions thereof.
[0151] It is understood that the various embodiments described herein are by way of example only and are not intended to limit the scope of the invention. For example, many of the materials and structures described herein may be substituted with other materials and structures without deviating from the spirit of the invention. The present invention as claimed may therefore include variations from the particular examples and preferred embodiments described herein, as will be apparent to one of skill in the art. It is understood that various theories as to why the invention works are not intended to be limiting.
E. Experimental Data
[0152] ##STR00261##
A mixture of 1-(3,5-dimethylphenyl)-6-isopropyl isoquinoline (28.5 g, 103.5 mmol, 2.0 equiv) in 2-ethoxyethanol (250 mL) and DIUF water (83 mL) was sparged with nitrogen for 10 minutes. Iridium(III) chloride hydrate (16.35 g, 51.7 mmol, 1.0 equiv) was added and sparging continued for 5 minutes. The reaction mixture was heated at 100° C. for 18 hours. The reaction mixture was cooled to room temperature. The suspension was filtered and the solids washed with water (5 mL), then methanol (3×20 mL) and dried on the filter funnel to give di-p-chloro-tetrakis[(1-(3,5-dimethylphenyl)-2′-yl)-6-isopropylisoquinolin-2-yl]diiridium(III) (19.7 g, 49% yield) as a red solid.
[0153] Pentane-2,4-dione (0.290 g, 2.90 mmol, 3.0 equiv) and powdered potassium carbonate (0.80 g, 5.80 mmol, 6.0 equiv) were sequentially added to a suspension of di-p-chloro-tetrakis[(1-(3,5-dimethylphenyl)-2′-yl)-6-isopropylisoquinolin-2-yl]diiridium(III (1.5 g, 0.966 mmol, 1.0 equiv) in methanol (15 mL) and dichloromethane (5 mL). The reaction mixture was heated at 45° C. for 30 minutes. The mixture was cooled to room temperature, then concentrated under reduced pressure. The residue was purified on an silica gel column, eluting with a gradient of 0 to 60% dichloromethane in heptanes to give bis[(1-(3,5-dimethylphenyl)-2′-yl)-6-isopropylisoquinolin-2-yl]-(2,4-pentanedionato-k.sub.2O,O′)iridium(III) (0.9 g, 56% yield) as a red solid.
##STR00262##
A solution of di-μ-chloro-tetrakis-[1-(3,5-dimethylphenyl-2-)-6-isopropylisoquinolin-2-yl]diiridium(III) (0.875 g, 0.6 mmol, 1.0 equiv) in 2-ethoxyethanol (20 mL) was sparged with nitrogen for 10 minutes. 3,7-Diethyl-3,7-dimethylnonane-4,6-dione (0.52 g, 2.2 mmol, 3.8 equiv) was added via syringe. After stirring for 5 minutes, powdered potassium carbonate (0.61 g, 4.4 mmol, 7.8 equiv) was added and the reaction mixture was stirred at room temperature for 16 hours in a flask wrapped in foil to exclude light. The reaction mixture was heated at 45° C. for 16 hours. The reaction mixture was cooled to room temperature and DIUF water (50 mL) added. The suspension was filtered and the red solid washed with DIUF water (100 mL) and methanol (20 mL) then dried in the vacuum oven at 45° C. for 1 hour. The red solid (0.85 g) was dry-loaded onto basic alumina (30 g) and purified on an Interchim automated chromatography system (80 g silica gel cartridge), eluting with 10-25% dichloro-methane in hexanes to give bis[1-(3,5-dimethylphenyl-2-yl))-6-isopropylisoquinolin-2-yl]-[3,7-diethyl-3,7-dimethylnonane-4,6-dionato-k.sub.2O,O]iridium(III) (0.47 g, 42% yield) as a red solid.
Device Examples
[0154] All example devices were fabricated by high vacuum (<10-7 Torr) thermal evaporation. The anode electrode was 1,200 Å of indium tin oxide (ITO). The cathode consisted of 10 Å of Liq (8-hydroxyquinoline lithium) followed by 1,000 Å of Al. All devices were encapsulated with a glass lid sealed with an epoxy resin in a nitrogen glove box (<1 ppm of H2O and O2) immediately after fabrication, and a moisture getter was incorporated inside the package. The organic stack of the device examples consisted of sequentially, from the ITO surface, 100 Å of LG101 (purchased from LG Chem) as the hole injection layer (HIL); 400 Å of HTM as a hole transporting layer (HTL); 50 Å of EBM as a electron blocking layer (EBL); 400 Å of an emissive layer (EML) containing host and 3% of emitter, and 350 Å of Liq (8-hydroxyquinolinelithium) doped with 35% of ETM as the electron transporting layer (ETL). Table 1 shows the thickness of the device layers and materials.
TABLE-US-00005 TABLE 1 Device layer materials and thicknesses Layer Material Thickness [Å] Anode ITO 1,200 HIL LG101 100 HTL HTM 400 EBL EBM 50 EML Host: Red emitter 3% 400 ETL Liq: ETM 35% 350 EIL Liq 10 Cathode Al 1,000
[0155] The chemical structures of the materials used in the devices are shown below:
##STR00263##
[0156] Upon fabrication, devices were tested for electroluminance (EL) and current density-voltage-luminance (JVL) characteristics. For this purpose, each sample was energized by the 2 channel Keysight B2902A SMU at a current density of 10 mA/cm.sup.2 and measured by the Photo Research PR735 Spectroradiometer. Radiance (W/str/cm.sup.2) from 380 nm to 1080 nm, and total integrated photon count were collected. Each device was then placed under a large area silicon photodiode for the JVL sweep. The integrated photon count of the device at 10 mA/cm.sup.2 is used to convert the photodiode current to photon count. The voltage is swept from 0 to a voltage equating to 200 mA/cm.sup.2. The EQE (external quantum efficiency) of a device is calculated using the total integrated photon count. All results are summarized in Table 2.
TABLE-US-00006 TABLE 2 At 10 mA/cm.sup.2 λ max FWHM Voltage EQE LE Device Dopant Host [nm] [nm] [V] [%] [cd/A] Device 1 Compound 1 Host 1 626 49 3.9 24.2 19.3 Device 2 Compound 1 Host 2 628 49 5.3 18.2 13.7 Device 3 Compound 2 Host 1 626 57 3.8 23.3 18.3 Device 4 Compound 2 Host 2 629 60 4.9 16.4 11.3
[0157] Table 2 is a summary of the performance of electroluminescence devices. First, when each emitter is doped in the same host (Device 1 vs Device 3, and Device 2 vs Device 4), the inventive device (Device 1) having Compound 1 as emitter exhibited significantly narrower FWHM. In general, the FWHM for a phosphorescent emitter complex is broad, such as the typical 57 or 60 nm as exhibited by the comparative devices (Device 3 and Device 4) with emitter Compound 2. It has been a long-sought goal to achieve the narrow FWHM. Narrower FWHM provides better color purity for the display application. As a background information, the ideal line shape is a single wavelength (single line). As can be seen here, the Compound 1 has about 10 nm smaller FWHM. In previous OLED research efforts, narrowing lineshape has been achieved nanometer by nanometer slowly. Therefore, the 8 nm and 11 nm reductions seen here are remarkably unexpected results. Second, when same emitter is doped into the different host (Device 1 vs Device 2, and Device 3 vs Device 4), the inventive device (Device 1) with Host 1 has shown a great improvement regarding lowering voltage, increasing EQE, and LE values. Such as when Device 1 is compared to Device 2, voltage decreases 26%, EQE increases 33%, LE increases 41%. Device 3 vs Device 4 has also shown the similar improvement. These improvement values are above any value that could be attributed to experimental error and the observed improvement is significant and unexpected. In summary, the inventive device described herein with the combination of specific types of emitters and hosts has shown unexpected synergy advantages over other similar emitters and hosts combinations.