SYSTEMS AND METHODS FOR PRODUCING SYRUPS AND POWDERS FROM SUGAR CANE USING COLD TECHNOLOGY AND PRODUCTS CONTAINING SAME
20180298457 ยท 2018-10-18
Inventors
Cpc classification
A23L33/125
HUMAN NECESSITIES
A23L3/0155
HUMAN NECESSITIES
C13B10/003
CHEMISTRY; METALLURGY
C13B20/16
CHEMISTRY; METALLURGY
A23L3/32
HUMAN NECESSITIES
International classification
C13B10/02
CHEMISTRY; METALLURGY
Abstract
Systems, apparatuses, and methods for producing and using a sugar cane syrup, juice, or powder. In one embodiment, the invention is directed to a system and associated processes for processing sugar cane using a cold processing pipeline in a manner that retains its natural nutritional value while producing a syrup, juice, or powder without significant separation of the natural nutrients or use of harmful chemicals.
Claims
1. A method for processing sugar cane, comprising: soaking the raw cane in a first bio-acidifier solution prior to juicing; juicing the soaked raw cane to produce raw cane juice; conditioning the juice, brix 13-15 to a pH of between 3.8 to 4.5 by adding an amount of a second bio-acidifier solution; passing the conditioned raw cane juice through a cooling component to reduce the temperature of the raw cane juice to between 2 and 4 degrees C.; subjecting the cooled raw cane juice to an evaporation step, wherein the evaporation step temperature is maintained within a range of 37 to 50 degrees C. until the Brix value reaches 60-72 Brix; subjecting the output of the evaporation step to a process to prevent degradation from microbiological activity; and packaging the output of the cold product protection process.
2. The method of claim 1, wherein the first and second bio-acidifier solutions consist of lime juice, lemon juice, citric acid, ascorbic acid, or other natural solution.
3. The method of claim 2, wherein the raw cane is soaked in the bio-acidifier solution for a period of between 2 to 4 hours, and the solution contains a concentration of between 0.01-0.5% of the lime juice, lemon juice, citric acid, ascorbic acid, or other natural solution.
4. The method of claim 1, wherein the juicing of the soaked raw cane is performed using a mill.
5. The method of claim 1, wherein the raw cane juice is conditioned by adding the bio-acidifier solution until the pH reaches a value between 3.8-4.2, and the solution contains a concentration of between 0.3-2% of the lime juice, lemon juice, citric acid, ascorbic acid, or other natural solution.
6. The method of claim 1, wherein the cooling component is a heat exchanger.
7. The method of claim 1, wherein the process to prevent degradation from microbiological activity is performed using one of UV photo purification, HPP high pressure processing, PEF pulsed electrical field, or microfiltration.
8. The method of claim 7, wherein the UV photo-purification process includes exposing the output of the evaporation process to UV-C radiation.
9. The method of claim 1, wherein the output of the process to prevent degradation from microbiological activity is a syrup having nutritional components in substantially the natural relationships and ratios as would occur in the unprocessed sugar cane.
10. The method of claim 9, wherein the nutritional components include one or more of iron, calcium, magnesium, potassium, B-vitamins, trace minerals, enzymes, and antioxidants.
11. The method of claim 1, further comprising evaporating the output of the process to prevent degradation from microbiological activity to a value of 70 brix as a preliminary step to produce a dry powder.
12. The method of claim 11, wherein the evaporation which produces the powder is performed by a low temperature vacuum belt dryer or spray drier.
13. The method of claim 1, wherein the evaporation step temperature is approximately 40 degrees C.
14. A system for processing sugar cane, comprising: a container for soaking the raw cane, the container including a first bio-acidifier solution; a juicing element for juicing the soaked raw cane to produce raw cane juice; a container for conditioning a pH of the raw cane juice, brix 13-15, to a pH of between 3.8 to 4.5 by adding an amount of a second bio-acidifier solution; a cooling element operative to reduce the temperature of the raw cane juice to between 2 and 4 degrees C.; an evaporator for subjecting the cooled raw cane juice to an evaporation process, wherein the evaporation process temperature is maintained within a range of 37 to 50 degrees C. until the Brix value reaches 60-72 Brix; a processing element for protecting the output of the evaporator from degradation from microbiological activity; and a packager for packing the output of the cold product protection process.
15. The system of claim 14, wherein the first and second bio-acidifier solution are each one or more of lime juice, lemon juice, citric acid, ascorbic acid, or other natural solution.
16. The system of claim 14, wherein the processing element for protecting the output of the evaporator from degradation from microbiological activity uses one of UV photo purification, HPP high pressure processing, PEF pulsed electrical field, or microfiltration.
17. The system of claim 16, wherein the photo-purification process includes exposing the output of the evaporation process to UV-C radiation.
18. The system of claim 14, wherein the juicing element for juicing the soaked raw cane to produce raw cane juice is a mill.
19. The system of claim 14, wherein the evaporation process temperature is approximately 40 degrees C.
20. The system of claim 14, further comprising a second evaporator for evaporating the output of the processing element for protecting the output of the evaporator from degradation from microbiological activity to produce a powder.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0030] Embodiments of the invention in accordance with the present disclosure will be described with reference to the drawings, in which:
[0031]
[0032]
[0033]
[0034]
[0035] Note that the same numbers are used throughout the disclosure and figures to reference like components and features.
DETAILED DESCRIPTION
[0036] The subject matter of embodiments of the present invention is described here with specificity to meet statutory requirements, but this description is not necessarily intended to limit the scope of the claims. The claimed subject matter may be embodied in other ways, may include different elements or steps, and may be used in conjunction with other existing or future technologies. This description should not be interpreted as implying any particular order or arrangement among or between various steps or elements except when the order of individual steps or arrangement of elements is explicitly described.
[0037] Embodiments of the invention will be described more fully hereinafter with reference to the accompanying drawings, which form a part hereof, and which show, by way of illustration, exemplary embodiments by which the invention may be practiced. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein; rather, these embodiments are provided so that this disclosure will satisfy the statutory requirements and convey the scope of the invention to those skilled in the art.
[0038] As mentioned, embodiments of the sugar cane processing pipeline described herein may be used to produce a syrup, juice, or powder that retain much (if not all) of the nutritional value that is removed from refined sugar products that are produced using a conventional processing pipeline. Furthermore, besides the beneficial nutrients noted in the previous Table, the products of the process described herein (i.e., juice, syrup, and powder) also contain Polyphenols, such as Flavonoid and Phenolic Acid that function as antioxidants.
[0039] Based on a study titled Antioxidant Activity in Sugarcane Juice and its Protective Role Against Radiation Induced DNA Damage, an ORAC test was conducted on three varieties of fresh sugarcane juice. The ORAC value of these 3 different varieties of Sugar cane are shown in a table from the study, which is reproduced below. The study reveals that sugarcane juice has the ability to scavenge free radicals, reduce iron complex and inhibit lipid peroxidation, and explains possible mechanisms by which sugarcane juice exhibits its beneficial effects in relation to its reported health benefits.
[0040] Note that the study was conducted using cane juice that has yet to go through the processing pipeline described herein. After that processing, the inventor expects to find much higher ORAC levels due to the cold evaporation process, which essentially concentrates the juice and raises the ORAC numbers reported above. In addition, because of the relatively low processing temperatures used, the inventor expects that most if not all of the original vitamins, minerals, antioxidants and other beneficial constituents will remain intact and beneficial. It is noted that ORAC value is a quantitative method of measuring the antioxidant activity of plasma, foods, natural extracts, etc., and has become a standard, although not a unique method over the last five years. ORAC values, in micromole TE, Trolox (a soluble analogue of Vitamin E, used as a standard) equivalents per 100 g for cane syrup are shown in the Table below:
TABLE-US-00002 TABLE 1 Total phenolic and flavonoid content of sugarcane juice and their antioxidant activities measured by ORAC assay Sugarcane Total phenolic Total flavonoid ORAC value juice content (mg GA content (mg quercetin (mol TE/ (varieties) eq/ml juice).sup.a eq/ml juice).sup.a ml juice).sup.b Co.C-419 631.5 4.4 3.57 0.03 16.35 DSEM.Co.C-671 664.5 3.9 4.88 0.02 18.53 Co.C-86032 402.3 7.9 2.43 0.04 23.64 GA eq- is gallic acid equivalent. TE- is trolox equivalent. .sup.aData expressed is mean standard error of four independent experiments. .sup.bData expressed is of single experiment.
[0041]
[0042] The diffuser 102 is used to clean raw cane coming from the field and is heated to 70-80 degrees C. to remove field dirt and rocks, and to minimize bacteria. A dewatering mill or juicer 104 sends the juice back through the diffuser for re-heating before entering the juice weighing scale 106 in batches before going into the second heating phase, commonly termed juice heating 108. The cane juice is heated as flocculation chemicals, such as lime, bleaching agents or hydrolyzed polyacrylamides are added and organic sediments and insoluble minerals drop out of solution (i.e., they precipitate). These sediments and minerals, such as calcium or magnesium salts (which are unwanted in the refining process), drop out or flocculate and accumulate in what is termed mill mud 110 at the bottom of the juice-heating tank, where the flocculation process is performed at a temperature in the range of 80-100 degrees C.
[0043] Sugar cane mill mud has a composition that may include organic carbon, Nitrogen, Phosphorus, Potassium, Calcium, Magnesium, Sulphur, Copper, Zinc, Iron, Manganese, and Boron. The mill mud composition, which is due to the flocculation step in the conventional processing pipeline. Further, mill mud has an acidic pH in the range of 4-4.9, and contributes to the BOD (biological oxygen demand) and COD (chemical oxygen demand) load in the wastewater. This is damaging to available water supplies and causes contamination (which may require chemicals to remediate the problem at the municipal level).
[0044] Note that mill mud has traditionally been applied to the surrounding sugar cane fields to provide some soil nutrition, although the procedure of spreading mill mud back on cane fields is really dumping a slurry-like material that the local processor has no use for. The volume of mill mud may be significant, and the mud typically contains trace minerals and unwanted chemicals. Note that due to the volume of material and newer analysis of this practice, mill mud is now viewed as a potential soil contaminate and source of ground water and stream pollution. Note also that embodiments of the processing pipeline described herein effectively eliminate the production of mill mud.
[0045] The process or component referred to as the clarifier 112 in the Figure separates the mill mud and chemicals in a rotary filter and the clarified juice (which includes molasses) moves into the first evaporation stage 114. In making refined sugar, this evaporation is completed in double or triple effect evaporators with each one leading to the next evaporation step, which is set at a higher level of vacuum than the previous step. These evaporation temperatures range from 80-100 degrees C. for prolonged periods. In a conventional processing workflow, the end goal at this stage is a brix level of 75-85 brix prior to entering the pan boiling station 116. This is where the product called golden syrup is pulled off (i.e., filtered out or otherwise removed). The golden syrup has a glycemic index of around 65, with the sugar content being approximately sucrose at 27%, and reducing sugars (comprised of glucose and fructose) of around 47%, with ash at 3% and water at 18%.
[0046] At this point in a conventional process, the syrup moves into a boiling pan evaporation phase 116 to increase brix and viscosity, before moving on to a crystallization phase 118, where crystallization begins to occur at 95+ brix. After a centrifugation phase 120 to remove the molasses, the crystals contain no or very few remaining nutrients and only sucrose, unless molasses is added back in to make light brown sugar. The crystalized sucrose is then subjected to another heating step 122 for purposes of drying the crystals to under 2% moisture, followed by cooling and conditioning to avoid clumping in the final package.
[0047]
[0048] A product of the conventional processing pipeline called evaporated sugar or whole cane sugar, non-crystallized sugars are not put in a centrifuge and the molasses is not separated out of the mixture. Instead, the juice from crushed sugar cane stalks is heated and clarified using flocculation chemicals and the liquid is typically open-pan evaporated by boiling until the sugar spontaneously crystallizes at a high moisture content of 80-83+ brix, Usually this forms a solid block after cooling to room temperature in some sort of mold. The resulting sweetener, which retains all molasses and minerals, can be chipped off in chunks or ground into brown granules. Because of its high moisture and molasses content and affinity to absorb water, such whole cane sugars are typically not free flowing and are very difficult to handle in large, industrial-scale applications. For this reason, they are primarily sold in retail stores for direct consumption: examples include products sold or traded locally between villages or sold in traditional retail stores. These wet sugars are usually not produced under HACCP or inspected conditions. Depending on the country or place or manufacture, these products have names such as Raparua, Panella, Jaggery, and Moscavado and are not to be confused with the product produced by the system and methods described herein.
[0049]
[0067] An important difference between a traditional refined white sugar/molasses production plant (such as that described with reference to
[0068] In some implementations, the innovative system may utilize international manufacturing locations near to sugar cane growing fields to ensure freshness. In some implementations, the innovative system and processes include juicing and evaporating within 6-24 hours (or as soon as is practical) after cutting the cane to ensure a fresh juice that has not begun to significantly ferment, or oxidize, has minimized reducing sugar development (that is, glucose and fructose), and preventing off-flavors or compromised nutritional traits.
[0069] Benefits, advantages, and aspects of embodiments of the system and methods described herein include one or more of the following: [0070] a) a relatively low-to-medium glycemic index syrup, produced using non-traditional processing protocols that include maintaining processing temperatures in a range between 37 and 50 degrees C. (with a preferred value of approximately 40 degrees C.), in order to maximize the functionality of the natural nutrition in the sugar cane. In this regard, note that the GI separates carbohydrate-containing foods into three general categories: [0071] i. High Glycemic Index Foods (GI 70+) causing a rapid rise in blood-glucose levels; [0072] ii. Intermediate/Medium Glycemic Index Foods (GI 56-69) causing a medium rise in blood-glucose; and [0073] iii. Low Glycemic Index Foods (GI 55 or less) causing a slower rise in blood sugar. [0074] b) a syrup that contains naturally occurring plant pigments (a source of beneficial nutrients); [0075] c) a syrup containing naturally occurring nutrients in their native (or close to) ratios, including enzymes, vitamins, trace minerals, antioxidants and plant pigments. Note that sugarcane contains various phytochemicals including phenolic compounds, plant sterols, and policosanols; [0076] d) a syrup using no processing chemicals aside from those used for natural pH adjustment (such as lemon or lime juice, ascorbic acid, citric acid, or other natural source); [0077] e) a syrup that may be used as part of high-value applications and formulas, including (but not limited to) medical syrups, pharmaceutical low-to-medium GI applications, cosmeceutical, mediums to transport vitamins, minerals, cough syrups, elixirs, and use as a fermentation substrate for companies who prefer chemical-free or certified organic growing mediums; [0078] f) a market focus on sourcing organic and/or sustainable grown cane; [0079] g) to replace traditional refined cane syrup product uses in the medical field, or in medical or foods for diabetic consumers; and [0080] h) utilizing one or more of UV photo purification, HPP high pressure processing, PEF pulsed electrical field, microfiltration, or other device or process referred to herein to perform a cold (below 40 degrees C.) pasteurization step, thereby eliminating spoilage organisms.
[0081] Note that by offering a nutrient-dense bacteriologically clean syrup or powder, the innovative system and methods are capable of supplying a unique product into the medical and pharmaceutical fields; this product is provided in a familiar syrup or powder delivery system that contains significant nutrients and provides a potentially lower GI product depending on the formula, while delivering an acceptable sweet flavor (with roughly a 1-to-1 replacement ratio with respect to other sweetening syrups, which is an aspect that is highly desirable).
[0082] Possible product applications for the innovative syrup and powder may include: [0083] Low GI medical foods; [0084] glucose delivery systems; [0085] as a carrier for liquid vitamins, minerals, pre and probiotics taken orally; [0086] cough syrup; [0087] fermentation mediums for the production of enzymes, and biological substances; [0088] beverages, candy/confectionary, cereal, coffee & vending; [0089] condiments, sauces & dressing; [0090] convenience foods; [0091] dairy, yogurt, drinks; [0092] fillings; [0093] foods targeting diabetic consumers; [0094] frozen ice cream and novelties; [0095] gelatin, icing/glaze, jam/jelly, mixers; [0096] snacks [0097] cosmetics
[0098] In addition to other benefits, embodiments of the low temperature process described herein produce a unique 13-15 brix cane juice, a 60-72 brix cane syrup, and a dried powder that each have superior nutritional qualities over any refined or natural sweeteners. As realized by the inventor, the cold process described herein not only provides an improved sweetener or sweetening agent, but also a nutrient dense nutraceutical syrup or powder for use in a number of applications or contexts, from food, to candy, to cosmetics, pharmaceuticals, to medicine.
[0099] Embodiments of the system and processing pipeline described herein eliminate the need for process chemicals and severe heat treatments, and may be used to produce (in some embodiments) a signature greenish colored syrup with the majority of nutrients naturally found in the cane plant (Saccharin officinarum L) still intact, highly bioavailable, and in their natural ratios to each other. This provides an alternative sweetener and a unique functional ingredient for use in applications where the manufacturer may want to increase the overall nutrient content for a manufactured food, thereby allowing them to make specific label health claims. As understood by the inventor, the described system and processing pipeline represent the first process that addresses the production of cold processed whole cane syrup without harsh chemicals, and provides an ability to maintain nutrient quality, quantity, good taste and odor.
[0100] As noted, embodiments of the low temperature process described herein are intended to minimize nutrient damage by reducing processing temperatures in all phases below the range of 37 to 50 degrees C., and eliminating the use of the processing chemicals used in producing refined sugar. This approach preserves the nutritional value of a wide range of nutrients that are normally destroyed by the relatively high temperatures used in conventional processing pipelines. The result is to produce a nutraceutical product containing vitamins B1, B2, B3, B5, B6 minerals, iron, calcium, chromium, cobalt, copper, magnesium, manganese, phosphorous, potassium, and zinc, along with antioxidants including polyphenols such as Apigenis, Tricin, Luteolin, and Cinnamic acid in their respective amounts and proportions as would be found in raw sugar cane. The combination of low temperature processing, pretreatment of the cane (soaking in a bio-acidifier solution), the pH adjustment of the cane juice using a bio-acidifier (e.g., lime juice, lemon juice, ascorbic acid, citric acid, other natural solution, etc.), and the cold processing temperatures can also slow down the enzymatic browning reaction that is catalyzed by Polyphenoloxidase (PPO) and Peroxidase (POD).
[0101] Syrups are a concentrated solution of a sugar mixed in water or other aqueous liquid. In medical terminology, medicinal syrups or syrups are nearly saturated solutions of sugar in water in which medicinal substances or drugs are dissolved; basically, it is an oral suspension in liquid form where the medical syrup or pharmaceutical syrup is used as a vehicle for the delivery of medicine. It is usually used as a flavored vehicle for drugs. Syrups should be kept closely tight in a cool, dry place after use in order to preserve them.
[0102] Medicinal syrups are widely consumed as children medicines, though medicated syrups for adults are also available. In general, there are various medicinal syrups such as cough syrups, iron syrups, calcium syrups, syrups for digestion, anti-allergy syrup, anti-fever syrup and so on that may benefit from use of the processing pipeline and its end products described herein. Some of the most popular medicated syrups are given in the list below; there are many medicines which are available in both tablet and syrup forms. [0103] Ambroxol [0104] Amoxicillin [0105] Bromhexine [0106] Cefpodoxime Proxetil [0107] Cefixime [0108] Cefadroxil [0109] Cephalexin [0110] Cefuroxime [0111] Paracetamol [0112] Chlorpheniramine Maleate [0113] Dextromethorphan [0114] Erythromycin [0115] Ephedrine/Guaifenesin Syrup [0116] Iron Tonic [0117] Multivitamins [0118] Cefaclor [0119] Salbutamol [0120] Cetirizine Hydrochloride [0121] Protein Powder [0122] Cloxacillin [0123] Pseudoephedrine [0124] Clarithromycin [0125] Phenylephrine
Elixirs: A clear, sweetened, hydro-alcoholic liquid intended for oral use; elixirs contain flavoring substances and are used either as vehicles or for the therapeutic effect of the active medicinal agents.
Cosmetics: Polyphenols are plant compounds with high anti-oxidative activity making them attractive as ingredients for cosmetics. The chemical structure of polyphenolic compounds causes their reducing properties, which allow them to act as antioxidants and free radical scavengers.
[0126] Note that aligning with the work of Dr. Kannar (Kannar and Kitchen, 2016), it is contemplated within the scope of the Whole Cane processing pipeline and its products that the process and/or resulting products may be incorporated into various conventional pharmaceutical and cosmeceutical preparations and dosage forms, such as tablets (plain and coated) for use orally, bucally and sublingually, capsules (hard and soft, gelatin, with or without additional coatings), powders, granules (including effervescent granules), pellets, micro particulates, solutions (such as micellar, syrups, elixir and drops), lozenges, pastilles, ampoules, emulsions, micro emulsions, ointments, creams, suppositories, gels and transdermal patches, other transdermal delivery methods.
[0127] The present invention may also be impregnated, mixed, emulsified, sprayed or coated onto carriers such as cellulose, methycellulose, dextrose, cyclodextrose, cyclodextrin, maltitol, fiber and fiber containing bioactives to improve delivery. Delivery may also be enhanced with a range of surfactants, lipids, complexes, solvents and co-solvents pharmaceutical delivery systems know in the pharmaceutical art to improve bioavailability, absorption and efficacy. For reference, see (1) Kannar, D and Kitchen, J. B. 2016. U.S. Pat. No. 9,364,016 B2, and (2) Zillich, O. V., Schweiggert-Weisz, U., Eisner, P. and Kerscher, M. 2015.
[0128] All references, including publications, patent applications, and patents, cited herein are hereby incorporated by reference to the same extent as if each reference were individually and specifically indicated to be incorporated by reference and/or were set forth in its entirety herein.
[0129] The use of the terms a and an and the and similar referents in the specification and in the following claims are to be construed to cover both the singular and the plural, unless otherwise indicated herein or clearly contradicted by context. The terms having, including, containing and similar referents in the specification and in the following claims are to be construed as open-ended terms (e.g., meaning including, but not limited to,) unless otherwise noted. Recitation of ranges of values herein are merely indented to serve as a shorthand method of referring individually to each separate value inclusively falling within the range, unless otherwise indicated herein, and each separate value is incorporated into the specification as if it were individually recited herein. All methods described herein can be performed in any suitable order unless otherwise indicated herein or clearly contradicted by context. The use of any and all examples, or exemplary language (e.g., such as) provided herein, is intended merely to better illuminate embodiments of the invention and does not pose a limitation to the scope of the invention unless otherwise claimed. No language in the specification should be construed as indicating any non-claimed element as essential to each embodiment of the present invention.
[0130] Different arrangements of the components depicted in the drawings or described above, as well as components and steps not shown or described are possible. Similarly, some features and sub-combinations are useful and may be employed without reference to other features and sub-combinations. Embodiments of the invention have been described for illustrative and not restrictive purposes, and alternative embodiments will become apparent to readers of this patent. Accordingly, the present invention is not limited to the embodiments described above or depicted in the drawings, and various embodiments and modifications can be made without departing from the scope of the claims below.