Methods of fabricating a polycrystalline diamond compact
10099346 ยท 2018-10-16
Assignee
Inventors
Cpc classification
B24D3/04
PERFORMING OPERATIONS; TRANSPORTING
F16C33/043
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F16C17/04
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B22F3/16
PERFORMING OPERATIONS; TRANSPORTING
B22F2005/001
PERFORMING OPERATIONS; TRANSPORTING
B22F2998/10
PERFORMING OPERATIONS; TRANSPORTING
F16C17/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B22F2998/10
PERFORMING OPERATIONS; TRANSPORTING
C22C26/00
CHEMISTRY; METALLURGY
F16C33/26
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B22F7/06
PERFORMING OPERATIONS; TRANSPORTING
B22F3/24
PERFORMING OPERATIONS; TRANSPORTING
C22C2026/006
CHEMISTRY; METALLURGY
B22F7/062
PERFORMING OPERATIONS; TRANSPORTING
International classification
E21B10/46
FIXED CONSTRUCTIONS
B24D3/10
PERFORMING OPERATIONS; TRANSPORTING
B22F3/24
PERFORMING OPERATIONS; TRANSPORTING
B22F3/16
PERFORMING OPERATIONS; TRANSPORTING
B24D3/34
PERFORMING OPERATIONS; TRANSPORTING
Abstract
Embodiments relate to PDCs, methods of fabricating PDCs, and applications for such PDCs. In an embodiment, a PDC includes a substrate and a pre-sintered PCD table including an interfacial surface that is bonded to the substrate. The pre-sintered PCD table may be substantially free of leaching by-products in a region at least proximate to the interfacial surface. In an embodiment, a method of fabricating a PDC includes providing an at least partially leached PCD including an interfacial surface. The method includes removing at least some leaching by-products from the at least partially leached PCD table. After removing the at least some leaching by-products, the method includes bonding the interfacial surface of the at least partially leached PCD table to a substrate to form a PDC.
Claims
1. A method, comprising: providing an at least partially leached polycrystalline diamond body including leaching by-products; cleaning the at least partially leached polycrystalline diamond body to remove at least some of the leaching by-products from the at least partially leached polycrystalline diamond body; after cleaning the at least partially leached polycrystalline diamond body, assembling the least at least partially leached polycrystalline diamond body with an infiltrant to form an assembly; subjecting the assembly to a high-temperature/high-pressure process, at a temperature of at least about 1000 C. and a pressure of at least about 4 GPa, to infiltrate the at least partially leached polycrystalline diamond body with the infiltrant; and leaching a portion of the infiltrant from the infiltrated polycrystalline diamond body.
2. The method of claim 1 wherein cleaning the at least partially leached polycrystalline diamond body to remove at least some of the leaching by-products from the at least partially leached polycrystalline diamond body includes subjecting the at least partially leached polycrystalline diamond body to a non-ambient pressure and an elevated temperature effective to remove the at least some of the leaching by-products from the at least partially leached polycrystalline diamond body.
3. The method of claim 2 wherein the non-ambient pressure is a pressure less than ambient pressure.
4. The method of claim 2 wherein the elevated temperature is at least about 600 C.
5. The method of claim 2 wherein subjecting the at least partially leached polycrystalline diamond body to a non-ambient pressure and an elevated temperature effective to remove the at least some of the leaching by-products from the at least partially leached polycrystalline diamond body includes heating the at least partially leached polycrystalline diamond body under partial vacuum conditions.
6. The method of claim 1 wherein the temperature is about 1300 C. to about 1600 C. and the pressure is about 5 GPa to about 8 GPa.
7. The method of claim 1, further comprising removing at least some leaching by-products generated during the leaching the portion of the infiltrant.
8. The method of claim 1 wherein the infiltrant includes at least one of iron, cobalt, or nickel.
9. A method, comprising: providing an at least partially leached polycrystalline diamond body including leaching by-products; cleaning the at least partially leached polycrystalline diamond body to remove at least some of the leaching by-products from the at least partially leached polycrystalline diamond body; after cleaning the at least partially leached polycrystalline diamond body, assembling the least at least partially leached polycrystalline diamond body with a substrate including an infiltrant to form an assembly; subjecting the assembly to a high-temperature/high-pressure process, at a pressure of about 5 GPa or less, to infiltrate the at least partially leached polycrystalline diamond body with the infiltrant and bond the infiltrated polycrystalline diamond body to the substrate; and leaching a portion of the infiltrant from the infiltrated polycrystalline diamond body to which the substrate is bonded.
10. The method of claim 9 wherein cleaning the at least partially leached polycrystalline diamond body to remove at least some of the leaching by-products from the at least partially leached polycrystalline diamond body includes subjecting the at least partially leached polycrystalline diamond body to a non-ambient pressure and an elevated temperature effective to remove the at least some of the leaching by-products from the at least partially leached polycrystalline diamond body.
11. The method of claim 9 wherein the non-ambient pressure is a partial vacuum.
12. The method of claim 9 wherein the elevated temperature is at least about 600 C.
13. The method of claim 9 wherein the pressure is about 4 GPa to about 5 GPa.
14. The method of claim 9 wherein the infiltrant includes at least one of iron, cobalt, or nickel.
15. The method of claim 9, further comprising: forming a polycrystalline diamond body in a high-pressure/high-temperature sintering process; and at least partially leaching the polycrystalline diamond body of catalyst to form the at least partially leached polycrystalline diamond body.
16. A method, comprising: providing an at least partially leached polycrystalline diamond body that is substantially free of leaching by-products generated during leaching of a polycrystalline diamond body from which the at least partially leached polycrystalline diamond body is formed; assembling the least at least partially leached polycrystalline diamond body with a substrate including an infiltrant to form an assembly; and subjecting the assembly to a high-temperature/high-pressure process, at a pressure of at least about 4 GPa, to infiltrate the at least partially leached polycrystalline diamond body with the infiltrant and bond the infiltrated polycrystalline diamond body to the substrate.
17. The method of claim 16, further comprising leaching a portion of the infiltrant from the infiltrated polycrystalline diamond body to which the substrate is bonded.
18. The method of claim 17 wherein leaching a portion of the infiltrant from the infiltrated polycrystalline diamond body to which the substrate is bonded includes leaching the infiltrant to a selected leach depth of about 50 m to about 500 m.
19. The method of claim 16 wherein the leaching by-products include at least one of an oxide or a salt.
20. The method of claim 16 wherein the high-temperature/high-pressure process is performed at the pressure of about 5 GPa to about 8 GPa and a temperature of about 1300 C. to about 1600 C.
21. The method of claim 16 wherein the infiltrant includes at least one of iron, cobalt, or nickel.
22. The method of claim 16, further comprising: forming a polycrystalline diamond body in a high-pressure/high-temperature sintering process; at least partially leaching the polycrystalline diamond body of catalyst to form the at least partially leached polycrystalline diamond body including leaching by-products; and cleaning the at least partially leached polycrystalline diamond body to remove at least some of the leaching by-products from the at least partially leached polycrystalline diamond body.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The drawings illustrate several embodiments of the invention, wherein identical reference numerals refer to identical elements or features in different views or embodiments shown in the drawings.
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DETAILED DESCRIPTION
(13) Embodiments of the invention relate to methods of fabricating a PDC and PDCs so-formed. The PDC embodiments disclosed herein may be used in a variety of applications, such as drilling tools (e.g., compacts, cutting elements, gage trimmers, etc.), machining equipment, bearing apparatuses, wire-drawing dies, and other apparatuses.
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(15) The at least partially leached PCD table 100 may be fabricated by subjecting a plurality of diamond particles (e.g., diamond particles having an average particle size between 0.5 m to about 150 m) to a HPHT sintering process in the presence of a catalyst, such as cobalt, nickel, iron, or an alloy of any of the preceding metals to facilitate intergrowth between the diamond particles and form a PCD table comprising bonded diamond grains defining interstitial regions with the catalyst disposed within the interstitial regions. The as-sintered PCD table may be leached by immersion in an acid, such as aqua-regia, a solution of 90% nitric acid/10% de-ionized water, or subjected to another suitable process to remove at least a portion of the catalyst from the interstitial regions of the polycrystalline diamond table and form the at least partially leached PCD table 100. In one embodiment, the sintered diamond grains of the at least partially leached PCD table 100 may exhibit an average grain size of about 20 m or less.
(16) As a result of the leaching process used to remove the catalyst, the at least partially leached PCD table 100 may include leaching by-products. For example, the solution used to remove, for example, cobalt from the interstitial regions may leave one or more types of residual salts, one or more types of oxides, combinations of the foregoing, or another leaching by-product within at least some of the interstitial regions of the at least partially leached PCD table 100. For example, depending upon the chemistry of the leaching solution, the leaching by-products may comprise a salt of nitric acid, hydrochloric acid, phosphoric acid, acetic acid, or mixtures of the foregoing. For example, the salt may be cobalt nitrate or cobalt chloride. The leaching by-products may also comprise a metal oxide, such as an oxide of tungsten, cobalt or other metal-solvent catalyst, and/or another type of metal present in the catalyst of the at least partially leached PCD table 100 prior to leaching. It is currently believed that such leaching by-products may block, obstruct, or otherwise inhibit infiltration of the at least partially leached PCD table 100 with a catalyst, such as cobalt, when the at least partially leached PCD table 100 is bonded to a substrate. Additionally, such leaching by-products may inhibit back filling with a non-catalyst material such as silicon.
(17) Referring to
(18) In another embodiment, at least some of the leaching by-products may be removed from the at least partially leached PCD table 100 using a chemical cleaning process. For example, the at least partially leached PCD table 100 may be immersed in hydrofluoric acid. The concentration of the hydrofluoric acid and the immersion time of the at least partially leached PCD table 100 in the hydrofluoric acid may be selected so that at least some of the leaching by-products and, in some embodiments, substantially all of the leaching by-products may be removed from the at least partially leached PCD table 100.
(19) In one embodiment of a chemical cleaning process, at least some of the leaching by-products may be removed using an ultrasonic cleaning process. For example, the at least partially leached PCD table 100 may be immersed in a selected solvent and ultrasonic energy applied to the selected solvent for a selected period of time to effect removal of at least some of the leaching by-products and, in some embodiments, substantially all of the leaching by-products may be removed from the at least partially leached PCD table 100. The selected solvent may be an aqueous solution (e.g., hydrofluoric acid) or an organic solvent.
(20) Referring to
(21) Referring to
(22) The assembly of the at least partially leached PCD table 100 and substrate 108 may be placed in a pressure transmitting medium, such as a refractory metal can, graphite structure, pyrophyllite or other pressure transmitting structure, or another suitable container or supporting element. The pressure transmitting medium, including the assembly, may be subjected to a HPHT process using a HPHT press at a temperature of at least about 1000 Celsius (e.g., about 1300 Celsius to about 1600 Celsius) and a pressure of at least 40 kilobar (e.g., about 50 kilobar to about 80 kilobar) for a time sufficient to bond the at least partially leached PCD table 100 to the substrate 108 and form a PDC 110 as shown in
(23) Because the at least partially leached PCD table 100 was cleaned to remove at least some of the leaching by-products prior to bonding to the substrate 108, the PCD table 112 so-formed may be substantially free of the leaching by-products. In embodiments when the second interfacial surface 104 is substantially planarized as shown in
(24) Referring to
(25) In an embodiment, after leaching the PCD table 112, the PCD table 112 may be cleaned using any of the previously described cleaning processes, such as thermal or chemical cleaning, to remove some or substantially all leaching by-products therefrom. It is currently believed that removing at least some of the leaching by-products from the PCD table 112 may increase the thermal stability of the PCD table 112.
(26) In an embodiment, the at least partially leached PCD table 100 is not formed by sintering the diamond particles on a cemented-tungsten-carbide substrate or otherwise in the presence of tungsten carbide. In such an embodiment, the interstitial regions of the at least partially leached PCD table 100 may contain no tungsten and/or no tungsten carbide or insignificant amounts of tungsten and/or tungsten carbide, which can inhibit removal of the catalyst.
(27) In other embodiments, a PCD table may be formed by HPHT sintering diamond particles in the presence of tungsten carbide. For example, diamond particles may be placed adjacent to a cemented tungsten carbide substrate and/or tungsten carbide particles may be mixed with the diamond particles prior to HPHT sintering. In such an embodiment, the PCD table so-formed may include tungsten and/or tungsten carbide that is swept in with the catalyst from the substrate or intentionally mixed with the diamond particles during HPHT sintering process. For example, some tungsten and/or tungsten carbide from the substrate may be dissolved or otherwise transferred by the liquefied catalyst (e.g., cobalt from a cobalt-cemented tungsten carbide substrate) of the substrate that sweeps into the diamond particles. The PCD table so-formed may be separated from the substrate using a lapping process, a grinding process, wire-electrical-discharge machining (wire EDM), or another suitable material-removal process. The separated PCD table may be immersed in a suitable solution (e.g., a hydrochloric acid/hydrogen peroxide solution) to remove substantially all of the catalyst from the interstitial regions and form the at least partially leached PCD table 100. However, an indeterminate amount of tungsten and/or tungsten carbide may still remain distributed throughout the at least partially leached PCD table 100 even after leaching.
(28) Referring to
(29) Referring to the cross-sectional views of
(30) Referring to
(31) After leaching the PCD table 304, the PCD table 304 may be treated using any of the previously described cleaning processes, such as thermal or chemical cleaning, to remove some or substantially all leaching by-products therefrom from the first volume 308. It is currently believed that removing at least some of the leaching by-products from the PCD table 304 may increase the thermal stability of the PCD table 304.
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(34) The PDCs disclosed herein may also be utilized in applications other than rotary drill bits. For example, the disclosed PDC embodiments may be used in thrust-bearing assemblies, radial bearing assemblies, wire-drawing dies, artificial joints, machining elements, and heat sinks.
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(36) In use, the bearing surfaces 612 of one of the thrust-bearing assemblies 602 bears against the opposing bearing surfaces 612 of the other one of the bearing assemblies 602. For example, one of the thrust-bearing assemblies 602 may be operably coupled to a shaft to rotate therewith and may be termed a rotor. The other one of the thrust-bearing assemblies 602 may be held stationary and may be termed a stator.
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(38) Referring to
(39) One of the thrust-bearing assemblies 602 of the thrust-bearing apparatus 600.sub.1 is configured as a stator that does not rotate and the other one of the thrust-bearing assemblies 602 is configured as a rotor that is attached to the output shaft 806 and rotates with the output shaft 806. One of the thrust-bearing assemblies 602 of the thrust-bearing apparatus 600.sub.2 is configured as a stator that does not rotate and the other one of the thrust-bearing assemblies 602 is configured as a rotor that is attached to the output shaft 806 and rotates with the output shaft 806. The on-bottom thrust generated when the drill bit 808 engages the bottom of the borehole may be carried, at least in part, by the first thrust-bearing apparatus 600.sub.1. Fluid flow through the power section of the downhole drilling motor 804 may cause what is commonly referred to as off-bottom thrust, which may be carried, at least in part, by the second thrust-bearing apparatus 600.sub.2.
(40) In operation, drilling fluid may be circulated through the downhole drilling motor 804 to generate torque and effect rotation of the output shaft 806 and the rotary drill bit 808 attached thereto so that a borehole may be drilled. A portion of the drilling fluid may also be used to lubricate opposing bearing surfaces of the bearing elements 606 of the thrust-bearing assemblies 602.
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(42) While various aspects and embodiments have been disclosed herein, other aspects and embodiments are contemplated. The various aspects and embodiments disclosed herein are for purposes of illustration and are not intended to be limiting. Additionally, the words including, having, and variants thereof (e.g., includes and has) as used herein, including the claims, shall have the same meaning as the word comprising and variants thereof (e.g., comprise and comprises) and mean including, but not limited to.