Fractioned separation of valuable substances from aqueous many-component mixtures

Abstract

The invention relates to a method for the fractioned separation of valuable substances from aqueous many-component mixtures such as aqueous wastes, sludges and sewage sludge under supercritical conditions. The invention also comprises valuable substance fractions that are enriched after the method according to the invention, more particularly phosphorous-containing and phosphorous- and ammonium-containing compounds such as fertilisers and synthesis gas as an energy source and as a valuable substance for the chemicals industry. The invention comprises devices for carrying out the methods. With the method and devices according to the invention, valuable substances can be completely recovered from wastes, sludges and sewage sludge and given a new use. The methods and devices are particularly suitable for recovering phosphorous and ammonium in the form of plant-available fertiliser, for recovering metals and heavy metals, for producing synthesis gas and for obtaining hydrogen from synthesis gas, i.e. for mobility.

Claims

1. A method for the fractional separation of a plurality of substances from an aqueous multicomponent mixture, comprising compression of the aqueous multicomponent mixture to 25 to 35 MPa, heating of the compressed aqueous multicomponent mixture to 200 to 300 degrees Celsius and removal of a first substance fraction wherein the first substance fraction comprises solids, further heating of the compressed aqueous multicomponent mixture to 300 to 400 degrees Celsius and removal of a second substance fraction wherein the second substance fraction comprises metal salts, further heating of the compressed aqueous multicomponent mixture to 400 to 550 degrees Celsius and removal of a third substance fraction wherein the third substance fraction comprises phosphate and/or ammonium.

2. The method according to claim 1, wherein the compressed aqueous multicomponent mixture, after the separation of the first, second and third substance fractions is heated in a reactor with exclusion of oxygen for one to five minutes to a maximum of 700 degrees Celsius, forming a reaction product that comprises synthesis gas and water.

3. The method according to claim 2, wherein the reaction product is guided into a product line and the product line containing the reaction product is guided through a heat exchanger in which thermal energy is transferred from the reaction product to compressed aqueous multicomponent mixture, which heats the compressed aqueous multicomponent mixture to 400 to 550 degrees Celsius.

4. The method according to claim 2, wherein the reaction product is guided in a product line through a second heat exchanger in which thermal energy is transferred from the reaction product to compressed aqueous multicomponent mixture, which heats the compressed aqueous multicomponent mixture to 300 to 400 degrees Celsius.

5. The method according to claim 2, wherein the reaction product is guided in a product line through a further heat exchanger in which thermal energy is transferred from the reaction product to compressed aqueous multicomponent mixture, which heats the compressed aqueous multicomponent mixture to 200 to 300 degrees Celsius.

6. The method according to claim 1, wherein a precipitating agent is added to the compressed aqueous multicomponent mixture after heating of the compressed aqueous multicomponent mixture to 400 to 550 degrees Celsius.

7. The method according to claim 2, wherein a precipitating agent is added to the reaction product, and a fourth substance fraction is separated and isolated.

8. The method according to claim 6, wherein the precipitating agent is selected from Mg.sup.2+ or Ca.sup.2+ or K.sup.+ or Mg.sup.2+ and Ca.sup.2+ or Mg.sup.2+ and K.sup.+ or Ca.sup.2+ and K.sup.+ or Mg.sup.2+ and Ca.sup.2+ and K.sup.+, and wherein the ions are used in the form of their salts.

9. The method according to claim 1, wherein the aqueous multicomponent mixture is selected from sewage sludge, organic waste, aqueous organic waste, industrial waste, municipal waste, animal waste, agricultural waste, garden waste, animal meal, vegetable waste, marc, fly ash, sewage sludge fly ash, food industry waste, drilling mud, sludge, waste from biogas plants, digestate, liquid manure and waste water.

10. The method according to claim 1, wherein the method further comprises purifying water, producing phosphorus compounds, producing ammonium compounds, producing sand, producing metals, producing metal salts from aqueous multicomponent mixtures, or producing hydrogen and/or generating electricity.

Description

(1) The invention is described in more detail in the following figures. However, the figures do not restrict the invention to these embodiments.

(2) FIG. 1 shows an apparatus for carrying out the method according to the invention with a storage tank 1, cutting device 2, pump 3, feedstock line 12, heat exchanger 4, separator 5, valve 6, reactor 8 with superheater 7, product line 13, cooler/dryer 14, gas storage tank 15, circulation water line 16, power generator 17, e.g. gas turbine, combined heat and power plant, line with precipitating agent 18. The storage tank 1 is filled with feedstock 31. The first valuable fraction 41, the second valuable fraction 42, the third valuable fraction 43 and the fourth valuable fraction 44 are withdrawn via valves. Water 46 can also be discharged or fed into the circulating water line 16. Synthesis gas 45 is collected in a gas storage tank 15 and converted into electric current 47 via a power generator 17. The addition of precipitating agent 32 is carried out via a pump 3 and line with precipitating agent 18 after separation of the synthesis gas 45 from the reaction product in the fourth valuable substance fraction 44.

(3) FIG. 2 shows an apparatus for carrying out the method according to the invention with a storage tank 1, cutting device 2, pump 3, feedstock line 12, heat exchanger 4, separator 5, valve 6, reactor 8 with superheater 7, product line 13, cooler/dryer 14, gas storage tank 15, circulation water line 16, power generator 17, e.g. gas turbine, combined heat and power plant, line with precipitating agent 18. The storage tank 1 is filled with feedstock 31. The first valuable fraction 41, the second valuable fraction 42, the third valuable fraction 43 and the fourth valuable fraction 44 are withdrawn via valves. Water 46 can also be discharged or fed into the circulating water line 16. Synthesis gas 45 is collected in a gas storage tank 15 and converted into electric current 47 via a power generator 17. The addition of precipitating agent 32 is carried out via a pump 3 and line with precipitating agent 18 in the third valuable substance fraction 43 by adding the precipitating agent to the compressed feedstock 31 in the third separator 5.

(4) FIG. 3 shows an apparatus for carrying out the method according to the invention with a storage tank 1, cutting device 2, pump 3, feed line 12, heat exchanger 4, separator 5, valve 6, reactor 8 with superheater 7, product line 13, cooler/dryer 14, gas storage tank 15, circulation water line 16, power generator 17 e.g. gas turbine, combined heat and power plant, line with precipitating agent 18. The storage tank 1 is filled with feedstock 31. The first valuable fraction 41, the second valuable fraction 42, the third valuable fraction 43 and the fourth valuable fraction 44 are withdrawn via valves. Water 46 can also be discharged or fed into the circulating water line 16. Synthesis gas 45 is collected in a gas storage tank 15 and converted into electric current 47 via a power generator 17. The addition of precipitating agent 32 is carried out via a pump 3 and line with precipitating agent 18 in the reactor 8 and separation of the fourth valuable substance fraction 44 via a valve 6.

(5) In the description, the same reference numerals are used for the same and equivalent parts.

(6) It should be noted at this point that all the above-described parts taken per se individually and in any combination, in particular the details illustrated in the drawings, are claimed as essential to the invention. Variations thereof are familiar to the person skilled in the art.

REFERENCE NUMERALS

(7) Apparatus for carrying out the method:

(8) 1 storage tank

(9) 2 cutting device

(10) 3 pump

(11) 4 heat exchanger

(12) 5 separator

(13) 6 valve

(14) 7 superheater

(15) 8 reactor

(16) 9 demister (droplet separator)

(17) 10 separating vessel

(18) 11 synthesis gas line

(19) 12 feedstock line

(20) 13 product line

(21) 14 cooler/dryer

(22) 15 gas storage tank

(23) 15 circulation water line

(24) 16 electric current generator (gas turbine/combined heat and power unit)

(25) 18 line with precipitating agent

(26) Feedstocks:

(27) 31 feedstock, in particular aqueous multicomponent mixture

(28) 32 precipitating agent

(29) Valuable substances:

(30) 41 first valuable substance fraction

(31) 42 second valuable substance fraction

(32) 43 third valuable substance fraction

(33) 44 fourth valuable substance fraction

(34) 45 synthesis gas

(35) 46 water

(36) 47 electric current