ENERGY STORAGE AND RETRIEVAL SYSTEMS AND METHODS
20240318638 ยท 2024-09-26
Inventors
Cpc classification
F28D7/0016
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F04F13/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F01D15/08
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F28F2270/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F28D20/0034
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F28D7/0066
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F28F2235/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F03G4/063
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
F03G4/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F01D15/08
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F04F13/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
Energy storage and retrieval systems are disclosed, along with methods of storing and retrieving the energy. The systems include an energy storage system and a trilateral cycle. The energy storage system includes low- and high-temperature energy storage tanks storing one or more energy storage media that exchange heat with a working fluid in both a gradient heat exchanger and a substantially isothermal heat exchanger in the trilateral cycle. Pressure changing devices transport the energy storage medium/media between the storage tanks and through the heat exchangers. The working fluid rejects heat to the energy storage medium and drives a turbine when the system is charging, and the energy storage medium rejects heat to the working fluid when the system is discharging. In some embodiments, the energy storage medium drives a second turbine when the system is discharging.
Claims
1. An energy storage and retrieval system, comprising: a first low-temperature energy storage tank storing a first energy storage medium at a first temperature; a high-temperature energy storage tank storing the first energy storage medium at a second temperature higher than the first temperature and having a pressurized gas therein; one or more first pressure changing devices configured to transport the first energy storage medium between the first low-temperature energy storage tank and the high-temperature energy storage tank; a gradient heat exchanger through which the first energy storage medium passes, configured to exchange heat between the first energy storage medium and a working fluid over a temperature range; a substantially isothermal heat exchanger through which a second energy storage medium passes, configured to exchange heat at a substantially constant temperature between the working fluid and the second energy storage medium; a compressor/expander in fluid communication with the gradient heat exchanger and the substantially isothermal heat exchanger, configured to change a pressure of the working fluid between the gradient heat exchanger and the substantially isothermal heat exchanger; and one or more second pressure changing devices between and in fluid communication with the gradient heat exchanger and the substantially isothermal heat exchanger, configured to transport the working fluid from the substantially isothermal heat exchanger to the gradient heat exchanger when the energy storage and retrieval system is discharging and from the gradient heat exchanger to the substantially isothermal heat exchanger when the energy storage and retrieval system is charging.
2. The energy storage and retrieval system of claim 1, wherein the first low-temperature energy storage tank also has the pressurized gas therein, and the energy storage and retrieval system further comprises a first conduit fluidly connecting the pressurized gas in the first low-temperature energy storage tank and the pressurized gas in the high-temperature energy storage tank.
3. The energy storage and retrieval system of claim 2, wherein the first conduit passes through the gradient heat exchanger, and the pressurized gas in the first conduit exchanges heat with the first energy storage medium and/or the working fluid.
4. The energy storage and retrieval system of claim 1, wherein the first energy storage medium comprises water.
5. The energy storage and retrieval system of claim 1, wherein the one or more second pressure changing devices comprises: a first pump configured to transport the working fluid from the substantially isothermal heat exchanger to the gradient heat exchanger when the energy storage and retrieval system is discharging; and a first turbine between the gradient heat exchanger and the substantially isothermal heat exchanger, driven by the working fluid when the energy storage and retrieval system is charging.
6. The energy storage and retrieval system of claim 1, wherein the one or more first pressure changing devices comprise: a first circulation pump configured to transport the energy storage medium from the low-temperature energy storage tank to the high-temperature energy storage tank when the energy storage and retrieval system is charging; and a second circulation pump configured to transport the energy storage medium from the high-temperature energy storage tank to the low-temperature energy storage tank when the energy storage and retrieval system is discharging.
7. The energy storage and retrieval system of claim 2, wherein the one or more first pressure changing devices comprises a bidirectional pump.
8. The energy storage and retrieval system of claim 2, wherein the pressurized gas and the first conduit are configured to balance a first pressure in the high-temperature energy storage tank with a second pressure in the first low-temperature energy storage tank.
9. The energy storage and retrieval system of claim 1, further comprising: a second low-temperature energy storage tank, configured to store the second energy storage medium; and a third pump configured to move the second energy storage medium through the substantially isothermal heat exchanger when the energy storage and retrieval system is charging and when the energy storage and retrieval system is discharging.
10. The energy storage and retrieval system of claim 9, wherein the second energy storage medium comprises water.
11. The energy storage and retrieval system of claim 1, wherein the second energy storage medium comprises a man-made or natural body of water.
12. A method of storing energy, comprising: storing a first energy storage medium at a first temperature in a first low-temperature energy storage tank; passing the first energy storage medium through a gradient heat exchanger; compressing a working fluid; passing the compressed working fluid through the gradient heat exchanger; rejecting heat from the compressed working fluid to the first energy storage medium over a temperature range between the first temperature and a second temperature higher than the first temperature in the gradient heat exchanger, thereby heating the first energy storage medium and cooling the compressed working fluid; storing the heated energy storage medium in a high-temperature energy storage tank at the second temperature; and exchanging heat between the working fluid and a second energy storage medium at a substantially constant temperature, thereby changing a phase of the working fluid.
13. The method of claim 12, further comprising balancing a pressure in the high-temperature energy storage tank with a pressure in the first low-temperature energy storage tank using a pressurized gas in each of the low-temperature and high-temperature energy storage tanks and a conduit in fluid communication with each of the low-temperature and high-temperature energy storage tanks.
14. The method of claim 13, further comprising exchanging heat between the pressurized gas and at least one of the first energy storage medium and/or the working fluid, wherein the conduit passes through the gradient heat exchanger.
15. The method of claim 12, further comprising: driving a turbine with the cooled, compressed working fluid; and/or pumping the second energy storage medium through the isothermal heat exchanger from either a second low-temperature energy storage tank or a man-made or natural body of water.
16. A method of retrieving stored energy, comprising: storing a first energy storage medium at a first temperature in a high-temperature energy storage tank; passing the first energy storage medium through a gradient heat exchanger; passing a working fluid in a trilateral cycle through the gradient heat exchanger; rejecting heat from the first energy storage medium to the working fluid over a temperature range between the first temperature and a second temperature lower than the first temperature in the gradient heat exchanger, thereby heating the working fluid and cooling the first energy storage medium; storing the cooled first energy storage medium at the second temperature in a first low-temperature energy storage tank; expanding the heated working fluid; and exchanging heat between the expanded working fluid and a second energy storage medium at a substantially constant temperature, thereby changing a phase of the expanded working fluid.
17. The method of claim 16, further comprising balancing a pressure in the high-temperature energy storage tank with a pressure in the first low-temperature energy storage tank using a pressurized gas in each of the low-temperature and high-temperature energy storage tanks and a conduit in fluid communication with each of the high-temperature energy storage tank and the first low-temperature energy storage tank.
18. The method of claim 17, further comprising exchanging heat between the pressurized gas and at least one of the expanded working fluid and the first energy storage medium, wherein the conduit passes through the gradient heat exchanger.
19. The method of claim 16, further comprising pumping the second energy storage medium through the isothermal heat exchanger from either a second low-temperature energy storage tank or a man-made or natural body of water.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION
[0036] Reference will now be made in detail to one or more embodiments of the invention, examples of which are illustrated in the accompanying drawings. While the invention will be described in conjunction with the following embodiments, it will be understood that the descriptions are not intended to limit the invention to these embodiments. On the contrary, the invention is intended to cover alternatives, modifications and equivalents that may be included within the spirit and scope of the invention. Furthermore, in the following detailed description, numerous specific details are set forth in order to provide a thorough understanding of the present invention. However, it will be readily apparent to one skilled in the art that the present invention may be practiced without these specific details. In other instances, well-known methods, procedures and components have not been described in detail so as not to unnecessarily obscure aspects of the present invention. Furthermore, it should be understood that the possible permutations and combinations described herein are not meant to limit the invention. Specifically, variations that are not inconsistent may be mixed and matched as desired.
[0037] The technical proposal(s) of embodiments of the present invention will be fully and clearly described in conjunction with the drawings in the following embodiments. It will be understood that the descriptions are not intended to limit the invention to these embodiments. Based on the described embodiments of the present invention, other embodiments can be obtained by one skilled in the art without creative contribution and are in the scope of legal protection given to the present invention.
[0038] Furthermore, all characteristics, measures or processes disclosed in this document, except characteristics and/or processes that are mutually exclusive, can be combined in any manner and in any combination possible. Any characteristic disclosed in the present specification, claims, Abstract and Figures can be replaced by other equivalent characteristics or characteristics with similar objectives, purposes and/or functions, unless specified otherwise.
[0039] For the sake of convenience and simplicity, part, portion, and region may be used interchangeably herein, but are generally given their art-recognized meanings. Wherever one such term is used, it also encompasses the other terms. Also, unless indicated otherwise from the context of its use herein, the terms known, fixed, given, certain and predetermined generally refer to a value, quantity, parameter, constraint, condition, state, process, procedure, method, practice, or combination thereof that is, in theory, variable, but is typically set in advance and not varied thereafter when in use.
[0040] The term ambient temperature, which may also be known as room temperature, refers to a temperature typically in the range of 15-30? C. (e.g., 18-25? C., or any temperature or range of temperatures therein).
[0041] In part, the present invention concerns a method and system for thermal energy storage and retrieval.
[0042] The expansion-heat exchange-compression-heat exchange cycle Aug. 18, 2017-22-8 (charging) and Aug. 9, 2021-17-18 (discharging) may use pentane(s) (i.e., n-pentane or a mixture of pentane isomers) as the working fluid, although other fluids, such as hexane(s), butane, propane, cyclopentane, acetone, cyclopentane, isopentane, undecane, HFO-1336mzz-Z, R123 (which is suitable, its potential phase-out in commercial use notwithstanding), R1233zd, or similar materials, may also be suitable. This cycle is implemented as a trilateral cycle, as shown in
[0043] In the trilateral cycle, a gradient heat exchanger 7 (
[0044] When the system is charging, the energy storage medium is pumped by the pump 19 from the low-temperature energy storage tank 5, through the heat exchanger 7 from a first port 15 to a second port 16, to the high-temperature energy storage tank 6, and the working fluid (which may be at a relatively high pressure due to compression by the compressor 8) passes through the heat exchanger 7 from a third port 18 to a fourth port 17. When the system is discharging, the energy storage medium flows from the high-temperature energy storage tank 6, through the heat exchanger 7 from the second port 16 to the first port 15, through a turbine 20, to the low-temperature energy storage tank 5, and the working fluid is pumped by a pump 21 through the heat exchanger 7 from the fourth port 17 to the third port 18. The turbine 20 drives the generation of electricity or other form of usable energy (e.g., mechanical energy). Three-way valves 11 and 12 control the flow of the energy storage medium through the pump 19 and the turbine 20, and three-way valves 13 and 14 control the flow of the working fluid through the pump 21 and a second turbine 22 in the trilateral cycle.
[0045] A traditional heat exchanger 9 exchanges heat between the working fluid and the energy storage medium in the low-temperature energy storage tank 5. There may be a relatively small difference (e.g., about 0? C.) between the temperature of the working fluid entering the heat exchanger 9 and exiting the heat exchanger 9, corresponding to the horizontal (isothermal) part 4-1 of the trilateral cycle in the entropy diagram of
[0046] When the system is charging, part of the energy storage medium is pulled through the heat exchanger 9 by a two-way pump 10. The working fluid passes through the heat exchanger 9 from the second turbine 22 to the compressor 8. The second turbine 22 may also drive the generation of electricity or other form of usable energy (e.g., mechanical energy). Alternatively, the second turbine 22 may drive one or more of the pumps 10, 19 and 21. When the system is discharging, the two-way pump 10 moves some of the energy storage medium from the low-temperature energy storage tank 5 through the heat exchanger 9, while the working fluid passes through the heat exchanger 9 from the expander 8 (i.e., the reverse function/operation of the compressor 8) to the pump 21. Thus, the horizontal (isothermal) part 4-1 of the entropy diagram in
[0047] The gradient heat exchanger 7 may comprise a heat exchanger exemplified in
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[0049] Alternative embodiments of the heat conducting and heat isolating element of
[0050] The heat transfer element of
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[0055] In
[0056] When the hot storage tank 6 in
[0057] Referring now to
[0058] In various modifications, there may also be a pressure sensor (not shown) in the pipe 202 to monitor and/or measure the pressure of the gas 210, a valve through which additional pressurized gas can be added to (or excess pressurized gas can be removed from) the pipe 202 or the low-temperature energy storage tank 51 (e.g., for safety reasons), and/or one or more pressure-activated valves (e.g., between a tank 51 or 50 and the pipe 202) to control when the pressurized gas 201 is transferred from one of the tanks 51 and 50 to the other (e.g., when pressure differential on opposite sides of the valve exceeds a predetermined value, such as in the range of 1-10 atm). On the other hand, when the water flows from the low-temperature energy storage tank 51 to the high-temperature energy storage tank 50, the pressure decreases in the low-temperature energy storage tank 51, and the pressurized gas 201 flows from the high-temperature energy storage tank 50 to the low-temperature energy storage tank 51.
[0059] The expansion-heat exchange-compression-heat exchange cycle 61-16-17-57-60-58-62-61 (charging) and 61-62-58-59-57-17-16-61 (discharging) is essentially the same as the expansion-heat exchange-compression-heat exchange cycle in
[0060] In the trilateral cycle of
[0061] When the system is charging, the energy storage medium is pumped by the pump 52 from the low-temperature energy storage tank 51, through the heat exchanger 56, to the high-temperature energy storage tank 50, and the working fluid in the trilateral cycle passes through the heat exchanger 56 from port 16 to port 17, a turbine 60, and an isothermal heat exchanger 62 to a two-way compressor/expander 61. The turbine 60 drives the generation of electricity or other form of usable energy (e.g., mechanical energy). When the system is discharging, the energy storage medium is pumped by a second pump 53 from the high-temperature energy storage tank 50 to the low-temperature energy storage tank 51, and the working fluid in the trilateral cycle is pumped by a third pump 59 through the heat exchanger 56 from the port 17 to the port 16. In this case, because the pressure in the low-temperature energy storage tank 51, and the high-temperature energy storage tank 50 is essentially the same, the pump 53 moves the energy storage medium from the high-temperature energy storage tank 50 to the low-temperature energy storage tank 51, as there is no excess pressure in the high-temperature energy storage tank 50 to drive fluid flow through the heat exchanger 56 and a turbine. Check valves 54 and 55 control the flow of the energy storage medium through the pumps 52 and 53, and three-way valves 57 and 58 control the flow of the working fluid through the pump 59 and the turbine 60 in the trilateral cycle.
[0062] The isothermal heat exchanger 62 exchanges heat between the working fluid and the energy storage medium in the low-temperature energy storage tank 51. There may be a relatively small difference (e.g., about 0? C.) between the temperature of the working fluid entering the heat exchanger 62 and exiting the heat exchanger 62, corresponding to the horizontal (isothermal) part 4-1 of the trilateral cycle in the entropy diagram of
[0063] When the system is charging, the energy storage medium is pulled through the heat exchanger 62 by a two-way pump 63. The working fluid passes through the heat exchanger 62 from the turbine 60 to the compressor 61. Alternatively or additionally, the turbine 60 may drive one or both of the pumps 52 and 63. When the system is discharging, the two-way pump 63 moves some of the energy storage medium from the low-temperature energy storage tank 51 through the heat exchanger 62, while the working fluid passes through the heat exchanger 62 from the expander 61 (i.e., the reverse function/operation of the compressor 61) to the pump 59. Thus, the horizontal (isothermal) part 4-1 of the entropy diagram in
[0064] The pressurized gas 201 can be air when the high-temperature energy storage tank 50 is galvanized or coated with a protective layer. When the high-temperature energy storage tank 50 is made of steel, the pressurized gas 201 may be an inert gas, such as nitrogen or argon, to prevent corrosion of the steel.
[0065] In one advantageous embodiment shown in
[0066] When the high-temperature energy storage tank 50 is not full for a sufficiently long time, the pressurized gas 201 in the tank 50 is saturated with water vapor. However, that heat (e.g., of vaporization) is not lost because it is returned to the hot water in the tank 50 via the heat exchanger 31 during charging. Alternatively, to prevent water vapor from evaporating and mixing with the pressurized gas 201 in the high-temperature energy storage tank 50, the water surface can be covered with a floating body or a layer of a liquid that does not mix with the water and that has a lower density than water (e.g., silicone oil or, at the operating temperatures in the high-temperature energy storage tank 50, paraffin wax).
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[0068] The energy storage system and trilateral cycle of
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[0070] The energy storage system in
[0071] The foregoing descriptions of specific embodiments of the present invention have been presented for purposes of illustration and description. They are not intended to be exhaustive or to limit the invention to the precise forms disclosed, and obviously many modifications and variations are possible in light of the above teaching. The embodiments were chosen and described in order to best explain the principles of the invention and its practical application, to thereby enable others skilled in the art to best utilize the invention and various embodiments with various modifications as are suited to the particular use contemplated.