Soil treatment method

Abstract

A method for treating expansive soils includes excavating a hole in a superficial expansive soil layer from an excavation site to form the hole and form an expansive soil material. Further, the expansive soil material is mixed with an inert material, at least two chemical additives, and a binder to form an additive soil material. The additive soil material is further poured into the hole in the excavation site to form an additive soil layer. The inert material is a sand, the chemical additives are a sulfur and a silica fume, and the binder is a dicyclopentadiene. The sand and the sulfur are present in the additive soil material in an amount from 30 wt. % to 40 wt. % and 12 wt. % to 25 wt. %, respectively, based on a total weight of the additive soil material.

Claims

1. Soil treatment method, comprising: excavating a superficial expansive soil layer at an excavation site to form a hole having a depth of 1 m to 6 m in the superficial expansive soil layer and provide an expansive soil material; mixing the expansive soil material with an inert material, sulfur, silica fume, and dicyclopentadiene to form an additive soil material; and adding the additive soil material into the hole at the excavation site to form an additive soil layer; wherein the additive soil material is added to the hole in layered increments of from 25 cm thick to 100 cm thick; and wherein the inert material is a sand, and the sand is present in the additive soil material in an amount from 30 weight % (wt. %) to 40 wt. % based on a total weight of the additive soil material; and wherein the sulfur is present in the additive soil material in an amount from 12 wt. % to 25 wt. % based on the total weight of the additive soil material, and wherein the silica fume and the dicyclopentadiene are present in a combined amount of from 35 wt. % to 60 wt. % based on the total weight of the additive soil material.

2. The method of claim 1, wherein the additive soil material is added to the hole in the absence of water.

3. The method of claim 1, further comprising heating the additive soil material to a temperature in a range of from 115? C. to 140? C. before the adding the additive soil material to the hole.

4. The method of claim 1, further comprising: adding the dicyclopentadiene to the sulfur and the silica fume during the mixing of the additive soil material.

5. The method of claim 4, wherein the dicyclopentadiene is added to the sulfur in a molten state at a temperature in the range of from 115? C. to 140? C.

6. The method of claim 1, wherein the sulfur is present in the additive soil material in an amount of 25 wt. % based on the total weight of the additive soil material.

7. The method of claim 1, wherein the inert material has a particle size ranging from 0.07 mm to 2 mm.

8. The method of claim 1, wherein the inert material does not include any of a hygroscopic salt, a clay, a silt, and an organic matter.

9. The method of claim 1, wherein the silica fume is undensified.

10. The method of claim 1, wherein: silicon dioxide (SiO.sub.2) is present in the silica fume in an amount from 80 wt. % to 90 wt. % based on a total weight of the silica fume; aluminum oxide (Al.sub.2O.sub.3) is present in the silica fume in an amount from 1 wt. % to 1.5 wt. % based on the total weight of the silica fume; iron oxide (Fe.sub.2O.sub.3) is present in the silica fume in an amount from 1.4 wt. % to 2 wt. % based on the total weight of the silica fume; magnesium oxide (MgO) is present in the silica fume in an amount from 0.2 wt. % to 0.8 wt. % based on the total weight of the silica fume; sodium oxide (Na.sub.2O) is present in the silica fume in an amount from 0.5 wt. % to 1.2 wt. % based on the total weight of the silica fume; and potassium oxide (K.sub.2O) is present in the silica fume in an amount from 0.5 wt. % to 1.2 wt. % based on the total weight of the silica fume.

11. The method of claim 1, wherein the additive soil material has a cation exchange capacity of from 80-150 meq/100 g.

12. The method of claim 1, wherein the additive soil material has a specific surface area of from 400-900 m.sup.2/g.

13. The method of claim 1, wherein the sulfur is exclusively elemental sulfur.

14. The method of claim 1, wherein the additive material further comprises fly ash.

15. The method of claim 1, wherein the inert material has a particle size ranging from 2 mm to 5 mm.

16. The method of claim 1, wherein the silica fume has a specific gravity of from 2 to 3.

17. The method of claim 1, wherein the silica fume has a mean grain size of from 0.1 to 0.5 ?m.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) A more complete appreciation of this disclosure and many of the attendant advantages thereof will be readily obtained as the same becomes better understood by reference to the following detailed description when considered in connection with the accompanying drawings, wherein:

(2) FIG. 1 is a schematic flow diagram of a method for treating expansive soils, according to certain embodiments;

(3) FIG. 2 shows an image of an exemplary expansive soil to be treated by the method of FIG. 1, according to certain embodiments;

(4) FIG. 3 shows an image of an exemplary sand used as an inert material in the method of treating expansive soils, according to certain embodiments;

(5) FIG. 4 shows an image of a sulfur used as a chemical additive in the method of treating expansive soils, according to certain embodiments;

(6) FIG. 5 shows an image of a silica fume used as a chemical additive in the method of treating expansive soils, according to certain embodiments; and

(7) FIG. 6 shows a structure of dicyclopentadiene used as a binder in the method of treating expansive soils, according to certain embodiments.

DETAILED DESCRIPTION

(8) In the drawings, reference numerals designate identical or corresponding parts throughout the several views. Further, as used herein, the words a, an and the like generally carry a meaning of one or more, unless stated otherwise.

(9) Furthermore, the terms approximately, approximate, about, and similar terms generally refer to ranges that include the identified value within a margin of 20%, 10%, or preferably 5%, and any values therebetween.

(10) As used herein, the term excavating refers to a process of digging the ground for construction purposes.

(11) As used herein, the term superficial refers to a soil layer that is only on the surface, not deep.

(12) As used herein, the term additives refers to the substance that is added to the soil in small amounts for stabilization of the soil.

(13) As used herein, the term inert material refers to a waste that does not undergo any significant physical, chemical, or biological transformations and is unlikely to adversely affect other matter with which it comes into contact.

(14) As used herein, the term binder refers to a material applied to the soil and/or soil surface to permanently or temporarily prevent water-induced erosion of exposed soils on construction sites.

(15) As used herein, the term undensified refers to dustless, uniform, smooth, free of lumps, and flows readily for bulk handling applications.

(16) As used herein, the term ignition value refers to a minimum temperature required to start or cause combustion, regardless of an igniting element.

(17) As used herein, the term hygroscopic refers to a property of a material having a habit of absorbing moisture from the air.

(18) As used herein, the term organic matter refers to the carbon-based compounds and compositions found within natural and engineered, terrestrial, and aquatic environments.

(19) As used herein, the term smectite group refers to a mineral mixture of various swelling sheet silicates, which have a three-layer 2:1 structure and belong to the clay minerals. Smectites mainly relate to montmorillonite but can often contain secondary minerals such as quartz and calcite.

(20) As used herein, the term pozzolanic activity refers to a measure for the degree of reaction over time or the reaction rate between a pozzolan and Ca.sup.2+ or calcium hydroxide (Ca(OH).sub.2) in the presence of water.

(21) As used herein, the term fly ash refers to hydrocarbon (e.g., coal) combustion residuals (CCRs) which are a hydrocarbon, especially coal, combustion product that is composed of particulates (fine particles of burned fuel) that are driven out of coal-fired boilers together with the flue gases.

(22) Embodiments of the present disclosure are directed to a stabilization method for treating expansive soils using chemical additives. The present study helps in elimination of swelling potential of soils, to improve soil strength and soil breaking capacity, to reduce settlement, and to decrease considerable soil permeability. The method includes excavating a superficial expansive soil layer to a medium depth (preferably less than six meters) and mix chemical additives, a binder, and an inert material with the excavated material. The inert material includes a fine to medium well-graded sand, the chemical additives include a sulfur and silica fume, and the binder includes dicyclopentadiene.

(23) Referring to FIG. 1, a schematic flow diagram of the method 100 for treating expansive soils is illustrated. The order in which the method 100 is described is not intended to be construed as a limitation, and any number of the described method steps may be combined in any order to implement the method 100. Additionally, individual steps may be removed or skipped from the method 100 without departing from the spirit and scope of the present disclosure.

(24) At step 102, the method 100 includes excavating a hole in a superficial expansive soil layer from an excavation site to form the hole and provide an expansive soil material. The expansive soil material has the ability to shrink or swell when a change in environment occurs and moisture migration into or out of the soil material results. In some embodiments, the excavating forms a hole having a depth from 1 meter (m) to 6 m. The expansive soils, shown in FIG. 2, are characterized by the presence of clay minerals having an expanding lattice type of inorganic compounds. The clay minerals may be characterized as having very weak van der Waals forces in between the adjacent unit cells of the inorganic compounds. The clay minerals belong to the smectite group materials of which montmorillonite is a member.

(25) At step 104, the method 100 includes mixing the expansive soil material with the inert material, at least two chemical additives, and the binder to form an additive soil material. In some embodiments, the additive soil material has a cation exchange capacity of from 80-150 milliequivalents (meq)/100 g. In some embodiments, the additive soil material has a specific surface area of 400-900 square meters per gram (m.sup.2/g). The inert material is preferably a sand, shown in FIG. 3, which is a granular material. According to the present disclosure, the sand is present in the additive soil material in an amount from 30 weight percentage (wt. %) to 40 wt. % based on a total weight of the additive soil material. The sand is made up of fine rock particles and is preferably a washed sand, e.g., a sand washed with water to remove water soluble components such as salts. Further, the sand is a naturally occurring and finely divided rock comprising particles or granules ranging in size from 0.075 to 2 mm. The grains of the sand may be sharp, strong, and angular. The sand may include three categories based on its size: a fine sand, a medium sand, and a coarse sand. In one embodiment, the inert material may be the fine sand and may have a particle size ranging from 0.075 mm to 0.425 mm. In another embodiment, the inert material may be the medium sand which may have a particle size ranging from 0.425 mm to 2 mm. In yet another embodiment, the inert material may be the coarse sand which may have a particle size ranging from 2 mm to 4.75 mm. Silica (silicon dioxide, SiO.sub.2) is a common constituent of sand. The silica is preferably in the form of quartz, which, because of its chemical inertness and considerable hardness, is resistant to weathering. In some embodiments, the inert sand material does not include hygroscopic salts, clay, silt, and organic matter.

(26) According to the present disclosure, the at least two chemical additives are sulfur and a silica fume. The sulfur is present in the additive soil material in an amount from 12 wt. % to 25 wt. % based on the total weight of the additive soil material. In some embodiments, the sulfur is present in the additive soil material in an amount of 25 wt. % based on the total weight of the additive soil material. In some embodiments, the sulfur is exclusively elemental sulfur (FIG. 4). The sulfur in its native form is a yellow crystalline solid and occurs as a pure element or as sulfide (S.sup.2?) and sulfate (SO.sub.4.sup.2?) minerals. The crystallography of the sulfur is complex. Depending on the specific conditions, the sulfur may be in the form of allotropes form several distinct crystal structures.

(27) The sulfur-treated soil helps to solidify and strengthen the soil by chemical binding and cooling from molten to solid forms. The sulfur modifies the soil foundation to an upgraded composite ground and reduces the cost of geotechnical work. The sulfur shows varied characteristics as shown in Table 1.

(28) TABLE-US-00001 TABLE 1 represents the characteristics of the sulfur. Atomic number 16 Atomic mass 32.06 g .Math. mol.sup.?1 Electro negativity 2.5 according to Pauling Density 2.07 g .Math. cm.sup.?3 at 20? C. Melting point 113? C. Boiling point 445? C. Vanderwaals radius 0.127 nm Ionic radius 0.184 (?2) nm; 0.029 (+6) Isotopes 5 Electronic shell [Ne] 3s.sup.23p.sup.4 Energy of first ionization 999.3 kJ .Math. mol.sup.?1 Energy of second ionization 2252 kJ .Math. mol.sup.?1 Energy of third ionisation 3357 kJ .Math. mol.sup.?1 Standard potential ?0.51 V

(29) FIG. 5 shows an exemplary image of the silica fume which is a by-product of producing silicon metal or ferrosilicon alloys. The silica fume includes primarily amorphous (non-crystalline) SiO.sub.2. The silica fume has a large surface area, and the high SiO.sub.2 content. According to the present disclosure, the silica fume is undensified. The undensified silica fume is composed of SiO.sub.2 wollastonite. The particle characteristics of the undensified silica fume are ultrafine powder. The average particle size of the undensified silica fume is less than 1 micrometer (?m) and has a bulk density of up to about 400 kg/m.sup.3, pfreferably from 200 kg/m.sup.3 to 350 or about 300 kg/m.sup.3. The undensified silica fume has pozzolanic activity and may be reactive (pozzolanic) because of its chemical and physical properties.

(30) According to the present disclosure, the silica fume has a first phase in which silicon dioxide (SiO.sub.2) is present in the silica fume in an amount from 80 wt. % to 90 wt. % based on a total weight of the silica fume. In the present disclosure, the amount of SiO.sub.2 is 85 wt. % of the total weight of the silica fume. Aluminum oxide (Al.sub.2O.sub.3) may also be present in the silica fume in an amount from 1 wt. % to 1.5 wt. % based on the total weight of the silica fume. In the present disclosure, the amount of Al.sub.2O.sub.3 is most preferably 1.12 wt. % of the total weight of the silica fume. Iron oxide (Fe.sub.2O.sub.3) is preferably present in the silica fume in an amount from 1.4 wt. % to 2 wt. % based on the total weight of the silica fume. In the present disclosure, the amount of Fe.sub.2O.sub.3 is 1.46 wt. % of the total weight of the silica fume. In a preferred embodiment the expansive soil material further comprises Fe.sub.2O.sub.3 particles as a separate component. The Fe.sub.2O.sub.3 particles preferably have an an average particle size of less than 10 ?m, more preferably from 200 nm to 1 ?m.

(31) Magnesium oxide (MgO) may also be present in the silica fume in an amount from 0.2 wt. % to 0.8 wt. % based on the total weight of the silica fume. Sodium oxide (Na.sub.2O) may also be present in the silica fume in an amount from 0.5 wt. % to 1.2 wt. % based on the total weight of the silica fume. Potassium oxide (K.sub.2O) may also be present in the silica fume in an amount from 0.5 wt. % to 1.2 wt. % based on the total weight of the silica fume. In some embodiments, calcium oxide (CaO) may also be present in the silica fume. In some embodiments, the silica fume has a loss of ignition value of from 1 to 6. In some embodiments, the silica fume has a specific gravity of from 2 to 3. In the present disclosure, the silica fume preferably has a specific gravity of 2.22. In some embodiments, the silica fume has a mean grain size of from 0.1 to 0.5 ?m. In the present disclosure, the silica fume has the mean grain size of 0.15 ?m.

(32) In some embodiments, the at least two chemical additives further include fly ash. In one embodiment, the fly ash includes substantial amounts of silicon dioxide (SiO.sub.2) (both amorphous and crystalline). In another embodiment, fly ash includes aluminum oxide (Al.sub.2O.sub.3). In yet another embodiment, fly ash includes calcium oxide (CaO). The fly ash includes the mineral compounds in coal-bearing rock strata. The fly ash is used as a lightweight aggregate (LWA). The fly ash may offer many benefits, both economically and environmentally.

(33) According to the present disclosure, the binder is a dicyclopentadiene. In some embodiments, the dicyclopentadiene binder is added to the sulfur and/or the silica fume before and/or during the mixing that forms the additive soil material. FIG. 6 shows a chemical structure of the dicyclopentadiene which is a colorless material with a camphor-like odor.

(34) TABLE-US-00002 TABLE 2 represents the characteristics of the dicyclopentadiene. Appearance White crystalline solid or colorless liquid Molecular C.sub.10H.sub.12 Formula Density 0.98 g .Math. cm.sup.?3 Melting point 32.5? C. Boiling point 170? C. Chemical 1,3-cyclopentadiene; Composition Coal Tar; Light benzol Molar Mass 132.20 g/mol Refractive n20/D 1.511

(35) In some embodiments, the silica fume and the dicyclopentadiene are present in a combined amount of from 35 wt. % to 60 wt. % based on the total weight of the additive soil material. In some embodiments, the dicyclopentadiene binder is added to the sulfur chemical additive once the sulfur chemical additive is molten in a temperature range from 115? C. to 140? C.

(36) At step 106, the method 100 includes adding the additive soil material into the hole in the excavation site to form an additive soil layer. In some embodiments, the method 100 further includes heating the additive soil material in a temperature range from 115? C. to 140? C. before adding/pouring the additive soil material into the hole. In some embodiments, the additive soil material is added in layered increments of 25 centimeters (cm) thick to 100 cm thick. In the present disclosure, the additive soil material is preferably added replaced in layers of 30 cm thick. The additive soil material may have existing moisture content. The treatment of the expansive soil takes place by moderate compaction without water. In some embodiments, the pouring of the additive soil material is conducted in the absence of water.

(37) According to the present disclosure, waste sulfur may be used as a component of the expansive oil material for the stabilization of expansive soils which is efficient compared to the existing solution due to waste disposal and contributions to environmental protection, e.g., formed from hydro-desulfurization of gas and oil. The sulfur exhibits numerous advantages as the stabilization material such as low cost, high availability, excellent physical properties, good chemical compatibility, and good processability. The sulfur stabilization of expansive soils outperforms the conventional stabilization method in terms of rapid gain of early strength, low shrinkage, low thermal conductivity, high durability resistance, and excellent adhesion.

(38) During the treatment process, according to the present disclosure, the excavated expansive soil material is mixed with the sand in an amount of 30 wt. % to 40 wt. %, and the sulfur is added to the mix in a proportion of 12 wt. % to 25 wt. %. The sand is added to alter the expansive soil mineralogy, change its fabric structure, decrease its clay content, and decrease its activity. Particularly, adding 25 wt. % of sulfur to the expansive material will lead to a firm-treated soil similar to a calcareous bedrock.

(39) The expansive soil material may be further heated above the melting point of elemental sulfur (e.g., between 115? C. to 140? C.). Dicyclopentadiene is preferably added to the molten sulfur to inhibit its crystallization and stabilize its polymeric structure. Further, to achieve or acquire high performance of the treated expansive soil material, the silica fume is added or combined with the mix. Particularly, in the additive soil material, the sulfur acts as the chemical stabilization additive, the dicyclopentadiene acts as the binder, and the silica fume acts as strengthening element. After the treatment process, the treated expansive soil material is added into the hole to form the additive soil layer across an area of the hole in the excavation site. Specifically, the additive soil layers of 30 cm thick are placed in the hole incrementally by moderate compaction without water (i.e., at the existing moisture content). As such, the method 100 of the present disclosure eliminates swelling potential of soils, improves soil strength and soil bearing capacity, reduces settlement, and decreases soil permeability.

(40) The dicyclopentadiene preferably undergoes a polymerization reaction at the elevated temperature at which the additive soil material is added to the hole in the expansive soil. Polymerization may proceed by ring opening metathesis polymerization to form a pol(dicyclopentadiene) polymer (poly-DCPD) that is multiply branched and/or crosslinked. In this form the poly-DCPD is insoluble in aqueous and organic liquids. Sulfur present during the polymerization may add across different polymers to further cross-link. The poly-DCPD helps to further stabilize the additive soil material after it is heated and added to the hole.

(41) Numerous modifications and variations of the present disclosure are possible in light of the above teachings. It is therefore to be understood that within the scope of the appended claims, the invention may be practiced otherwise than as specifically described herein.