Cosmetic or dermatological preparation comprising a combination of a dye and an anti-inflammatory active ingredient

Abstract

The present invention is a cosmetic or dermatological preparation comprising 0.01% by weight to 5% by weight of at least one red light-filtering dye and 0.0001% by weight to 10% by weight of at least one anti-inflammatory active ingredient. The preparation can be used for the prophylaxis and treatment of sun-irritated skin and to aid the body's own repair mechanisms.

Claims

1. A cosmetic or dermatological preparation, wherein the preparation comprises from 0.01% to 5% by weight of at least one red light-filtering dye, at least one white pigment, and from 0.0001% to 10% by weight of at least one anti-inflammatory active ingredient which comprises at least one aqueous extract of Glycyrrhiza inflate, and wherein the preparation does not contain strontium cations.

2. The preparation of claim 1, wherein the at least one anti-inflammatory active ingredient further comprises Hamamelis.

3. The preparation of claim 1, wherein the at least one anti-inflammatory active ingredient further comprises panthenol.

4. The preparation of claim 2, wherein the at least one anti-inflammatory active ingredient further comprises panthenol.

5. The preparation of claim 1, wherein the at least one anti-inflammatory active ingredient further comprises chamomile extract.

6. The preparation of claim 1, wherein the at least one aqueous extract is present in a concentration of from 0.01% to 2% by weight.

7. The preparation of claim 4, wherein the preparation comprises from 0.01% to 2% by weight of the at least one aqueous extract of Glycyrrhiza inflata, at least 1% by weight of Hamamelis and at least 1% by weight of panthenol.

8. The preparation of claim 1, wherein the red light-filtering dye comprises at least one green pigment.

9. The preparation of claim 8, wherein the at least one green pigment comprises at least one of Colorona Brilliant Green, Colorona Egyptian Emerald, Timiron Splendid Green, Vert Oxyde Crome Anhydre N, Vert Oxyde Crome Hydrate W886 and Outremer Supercosmetique W 6803.

10. The preparation of claim 8, wherein the at least one green pigment comprises at least one of CI 77288 and CI 77289.

11. The preparation of claim 8, wherein the at least one green pigment is present in a concentration of from 0.08% to 0.25% by weight.

12. The preparation of claim 1, wherein the preparation comprises at least 2.25% by weight of the at least one white pigment.

13. The preparation of claim 12, wherein the at least one white pigment comprises at least one of titanium dioxide, bismuth oxide, and barium sulfate.

14. The preparation of claim 12, wherein the at least one white pigment comprises CI 77891.

15. The preparation of claim 1, wherein the preparation further comprises at least one blue pigment.

16. The preparation of claim 15, wherein a weight ratio of the at least one blue pigment to the at least one red light-filtering dye is from 1:1 to 1:100.

17. The preparation of claim 15, wherein the at least one blue pigment comprises CI 77007.

18. The preparation of claim 1, wherein the preparation further comprises PPG-6 decyltetradeceth-30.

19. The preparation of claim 18, wherein the preparation further comprises butylene glycol.

20. The preparation of claim 1, wherein the preparation is present in the form of an emulsion.

21. The preparation of claim 20, wherein the emulsion is a W/O emulsion or an O/W emulsion.

22. The preparation of claim 20, wherein the emulsion is a W/S emulsion or a S/W emulsion.

23. A cosmetic or dermatological preparation, wherein the preparation comprises from 0.01% to 0.25% by weight of at least one green pigment, at least 2.25% by weight of at least one white pigment, at least one blue pigment, a weight ratio of the at least one blue pigment to the at least one green pigment being from 1:1 to 1:100, and from 0.0001% to 10% by weight of at least one anti-inflammatory active ingredient which comprises at least on aqueous extract of Glycyrrhiza inflata, and wherein the preparation does not contain strontium cations.

24. The preparation of claim 23, wherein the preparation comprises at least 0.1% by weight of the at least one green pigment.

25. The preparation of claim 23, wherein the at least one anti-inflammatory active ingredient further comprises at least one of Hamamelis and panthenol.

26. The preparation of claim 25, wherein the preparation comprises from 0.01% to 5% by weight of at least one aqueous extract of Glycyrrhiza inflata, at least 1% by weight of Hamamelis and at least 1% by weight of panthenol.

27. The preparation of claim 23, wherein the at least one green pigment comprises at least one of Colorona Brilliant Green, Colorona Egyptian Emerald, Timiron Splendid Green, Vert Oxyde Crome Anhydre N, Vert Oxyde Crome Hydrate W886 and Outremer Supercosmetique W 6803.

28. The preparation of claim 23, wherein the at least one green pigment comprises at least one of CI 77288 and CI 77289.

29. The preparation of claim 28, wherein the at least one blue pigment comprises CI 77007.

30. The preparation of claim 29, wherein the at least one white pigment comprises CI 77891.

31. The preparation of claim 23, wherein the at least one green pigment comprises at least one of CI 77491, CI 77499 and CI 77492.

32. The preparation of claim 23, wherein the preparation further comprises PPG-6 decyltetradeceth-30.

33. A cosmetic or dermatological preparation, wherein the preparation comprises from 0.1% to 0.2% by weight of at least one green pigment selected from CI 77288 and CI 77289, at least one blue pigment in a weight ratio of the at least one blue pigment to the at least one green pigment of from 1:1 to 1:100, and from 0.0001% to 10% by weight of at least one anti-inflammatory active ingredient which comprises at least one aqueous extract of Glycyrrhiza inflata, and wherein the preparation does not contain strontium cations.

34. The preparation of claim 33, wherein the preparation is present in the form of an emulsion.

35. The preparation of claim 33, wherein the preparation further comprises PPG-6 decyltetradeceth-30.

36. The preparation of claim 33, wherein the at least one blue pigment comprises CI 77007.

37. The preparation of claim 33, wherein the preparation further comprises at least one white pigment.

38. The preparation of claim 37, wherein the at least one white pigment comprises at least one of bismuth oxide and barium sulfate.

Description

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

(1) The invention is of course not limited to preparations which are applied after sunbathing, but naturally includes all cosmetic and dermatological applications in which an inflammation-alleviating effect could be desirable or advantageous. Mention may be made here in particular also of shaving burn, as often arises after shaving.

(2) The invention therefore further provides the use of cosmetic or dermatological formulations for the care of photodamaged and shaving-stressed skin and/or for the alleviation or the after-reactions of the skin to the effect of UV radiation and/or shaving, and for the treatment and care of reddened skin caused by disease, such as, for example, rosacea.

(3) Preferred anti-inflammatory active ingredients are Hamamelis, Glycyrrhiza inflata, panthenol and camomile extract, and combinations thereof.

(4) The plant species Glycyrrhiza inflata belongs, like the liquorice which is official in Europe Glycyrrhiza glabra, to the genus Glycyrrhiza, which belongs to the Fabaceae plant family (pea plants). The drug Radix Glycyrrhizae inflatae, i.e. the root of the plant, is used, for example, in Far Eastern medicine. The use of the drug as anti-inflammatory is likewise known.

(5) A constituent of the aqueous extract of Radix Glycyrrhizae inflatae is licochalcone A, which is characterized by the following structural formula:

(6) ##STR00001##

(7) It is assumed that this substance, possibly in synergy with the other constituents of the extract, has part of the effect according to the invention.

(8) The anti-inflammatory effect of licochalcone A is known per se. To achieve this effect in topical formulations, however, the solubility of licochalcone A in the vehicle and an adequate dermal bioavailability are important prerequisites. However, licochalcone A is a sparingly soluble substance which can crystallize out during storage and processing. This crystallization tendency represents a considerable problem since active ingredient crystals can lead to cosmetic inelegance, formula instabilities and/or loss of activity. According to the invention, it has therefore been achieved by the preparations according to the invention to increase the solubility of licochalcone A and thus its bioavailability. Accordingly, cosmetic or dermatological preparations with a content of licochalcone A in combination with red light-filtering dyes are also in particular in accordance with the invention.

(9) Surprisingly the synergism is evident particularly advantageously if the cosmetic or dermatological preparations comprise 0.01% by weight to 10% by weight, in particular 0.05 to 5% by weight, very particularly 0.1 to 2% by weight, of anti-inflammatory active ingredient, in particular an aqueous extract from Radix Glycyrrhizae inflatae.

(10) It is very particularly advantageous to start from an aqueous extract which is known under the name Aqua Licorice Extract P-U from Maruzen, which is an aqueous mixture (about 10% by weight water) of Radix Glycyrrhizae inflatae (about 5% by weight, content of licochalcones A in the extract about 22%), PPG-6 decyltetradeceth-30 (about 25% by weight) and butylene glycol (about 60% by weight). The extract can then advantageously be added in an amount of from 0.01 to 10% by weight.

(11) It is also advantageous to use licochalcones A in other vehicle systems in a concentration of from 0.0001 to 5% by weight, in particular 0.001 to 1% by weight, very particularly 0.005-0.25% by weight. The active ingredient fraction in licochalcones is based on the total mass of the preparation.

(12) Hamamelis is a further known anti-inflammatory substance. Hamamelis, known in its North American homeland as witch hazel, resembles our hazelnut bush and is therefore also sometimes called witch hazel. The Hamamelis leaves contain essential oils, tannins (gallotannins) and flavonoids which make the plant a medicinal plant. Hamamelis has an anti-inflammatory, antiseptic, contracting, decongestant, locally hemostatic, hypotensive, angioprotective effect. Hamamelis is used in many cosmetic care preparations for skin care, in face washes, shaving lotions and hair tonics, for wounds which do not heal well, skin inflammations, skin reddening, aching muscles, lumbago, varicose veins, haemorrhoids, vein disorders such as varices, rheumatic complaints and hair problems.

(13) Panthenol, free international abbreviation for (±)-2,4-dihydroxy-N-(3-hydroxypropyl)-3,3-dimethylbutyramide (dexpanthenol, CTFA name: Panthenol)

(14) ##STR00002##
C.sub.9H.sub.19NO.sub.4, M.sub.R 205.25. Only the D form is used as vitamin, which is converted to pantothenic acid in the organism. The pantothenic acid is thought to encourage hair growth, for which reason it is used for the preparation of hair tonics. In addition, panthenol has a soothing effect in cases of sunburn and stimulates pigmentation. Panthenol is often a constituent of moisturizing creams and exhibits a moisturizing effect. Panthenol is used primarily for the treatment of inflammation of the gastrointestinal canal, the eye and the skin, also for wound healing disorders and in hair tonics and also cosmetics.

(15) Red light-filtering dyes, in particular green pigments, can be chosen from the corresponding positive list of the Cosmetics Directive or the EC list of cosmetic colorants. In most cases, they are identical to the dyes approved for foods.

(16) Advantageous green pigments can be chosen from the following group alone or in combination: Colorona Brilliant Green, Colorona Egyptian Emerald, Timiron Splendid Green, Vert Oxyde Crome Anhydre N, Vert Oxydede Crome Hydrate W886 and/or Outremer Supercosmetique W 6803. These said pigments are inter alia also listed under the corresponding CI numbers. Preference is therefore given in particular to the green pigments with the CI numbers CI 77288, CI 77289, CI 77007, CI 77891, CI 77491, CI 77499, CI 77891, CI 77499, CI 77288 and CI 77492.

(17) It is decisive for the dye that, when it is applied to a reddish or red background, it conveys a skin-coloured overall appearance. According to the invention, 0.01% by weight to 5% by weight, preferably 0.08 to 0.25% by weight, in particular 0.1 to 0.2% by weight, based on the total mass of the preparation, of red light-filtering dyes are therefore used.

(18) Red light-filtering means here that the red light part of visible light is absorbed and the complementary colour green becomes visible.

(19) By applying the preparation according to the invention containing red light-filtering dyes, such as, for example, the stated green pigments, to the skin which appears reddish in colour, for example as a result of solar irradiation or due to rosacea, the appearance of the skin will appear natural to the observer. In order to produce this effect, the choice and amount of red light-filtering dyes is significant. Moreover, an addition of white pigment is also advantageous, in particular all concealing, white pigments, in particular all titanium dioxides, bismuth oxides, barium sulphate. The white pigments readily cover the reddened skin and give a certain coverage. Without white pigments, a larger fraction of the other colour pigments is thus required.

(20) The addition of blue pigments in the ratio 1:1 to 1:100, based on the green pigment used, is likewise recommended. The blue pigment increases the colour-changing effect, meaning that the reddish skin colour is better converted to a natural brown, i.e. a natural skin colour. According to the invention, this special colour effect is possible with or without white and/or blue pigments by using the red light-filtering dyes in an amount ranging from 0.01 to 5% by weight.

(21) It is preferred for the purposes of the present invention if the cosmetic or dermatological preparations according to the invention comprise one or more alcohols, in particular if the formulations are to be in the form of an aftersun preparation and characterized by a particular cooling effect.

(22) The cosmetic or dermatological formulations for the purposes of the present invention can preferably additionally comprise one or more water phases besides one or more oil phases and, for example, be in the form of W/O, O/W, W/O/W or O/W/O emulsions. Such emulsions may preferably also be a microemulsion, a Pickering emulsion or a sprayable emulsion.

(23) Preferably, the formulations according to the invention also comprise further anti-inflammatory substances, such as, for example, allantoin, α-bisabolol, pantothenic acid, Royal jelly, azulene or Aloe-vera extract, and unsaponifiable fractions of avocado oil or soya oil and further substances which calm irritated skin. Further advantageous active ingredients are tannins, which have an astringent, anti-inflammatory and/or antisecretory effect.

(24) Moreover, the formulations according to the invention can also advantageously comprise dihydroxyacetone or nut extracts and further substances which are thought to achieve tanning.

(25) The cosmetic and/or dermatological formulations according to the invention can have the customary composition and be used, in particular, for the treatment and the care of the skin and/or the hair after sunbathing and as make-up product in decorative cosmetics. Accordingly, the formulations according to the invention may be used, depending on their formulation, for example as skin protection cream, cleansing milk, sunscreen lotion, nutrient cream, day or night cream etc. It is in some cases possible and advantageous to use the formulations according to the invention as a base for pharmaceutical formulations. Preference is given in particular to those cosmetic and dermatological formulations which are in the form of an aftersun skin care product or an aftershave product.

(26) For use, the cosmetic and dermatological formulations according to the invention are applied to the skin and/or the hair in an adequate amount in the manner customary for cosmetics, i.e. for example directly—following removal from a bottle, tube, pot or other container—or using an (impregnated) wipe.

(27) Impregnated wipes are used widely as objects of daily need in a very wide variety of fields. They allow, inter alia, efficient and skin-friendly cleaning and care, particularly also in the absence of (flowing) water. Here, the actual object of use consists of two components: a) a dry wipe which is made of material such as paper and/or a very wide variety of mixtures of natural or synthetic fibres and b) a low-viscosity impregnation solution.

(28) The present invention thus also provides cosmetic and dermatological wipes which are moistened with cosmetic or dermatological impregnation solutions which have a content of active ingredient combination according to the invention.

(29) “Dry” wipes (according to a)) preferred according to the invention consists of nonwoven, in particular water-jet-consolidated and/or water-jet-embossed nonwoven.

(30) Such nonwovens can have macroimpressions in any desired pattern. The choice to be made is governed firstly by the impregnation to be applied and secondly by the field of use in which the later wipe is to be used.

(31) It has proven advantageous for the wipe if it has a weight of from 35 to 120 g/m.sup.2, preferably from 40 to 60 g/m.sup.2 (measured at 20° C.±2° C. and at an atmospheric humidity of 65%+5% for 24 hours).

(32) The thickness of the nonwoven is preferably 0.4 mm to 2 mm, in particular 0.6 mm to 0.9 mm.

(33) The starting materials used for the nonwoven fabric of the wipe may generally be all organic and inorganic natural and synthetic fibre materials. Examples which may be mentioned are viscose, cotton, cellulose, jute, hemp, sisal, silk, wool, polypropylene, polyester, polyethylene terephthalate (PET), aramid, nylon, polyvinyl derivatives, polyurethanes, polylactide, polyhydroxyalkanoate, cellulose ester and/or polyethylene and also mineral fibres, such as glass fibres or carbon fibres. However, the present invention is not limited to the materials stated, but it is possible to use a large number of other fibres to form the nonwoven. In particular, it is advantageous for the purposes of the present invention if the fibres used are not soluble in water.

(34) In a particularly advantageous embodiment of the nonwoven, the fibres consist of a mixture of 70% viscose and 30% PET.

(35) Fibres of high-strength polymers such as polyamide, polyester and/or highly drawn polyethylene are also particularly advantageous.

(36) Moreover, the fibres can also be coloured in order to be able to emphasize and/or enhance the visual attractiveness of the nonwoven. The fibres can additionally comprise UV stabilizers and/or preservatives.

(37) The fibres used to form the wipe preferably have a water-absorption rate of more than 60 mm/[10 min] (measured using the EDANA test 10.1-72), in particular more than 80 mm/[10 min].

(38) Furthermore, the fibres used to form the wipe preferably have a water-absorption capacity of more than 5 g/g (measured using the EDANA test 10.1-72), in particular more than 8 g/g.

(39) It is advantageous for the purposes of the present invention if the weight ratio of the unimpregnated wipe to the impregnation solution is chosen from the range from 2:1 to 1:6.

(40) The cosmetic and dermatological formulations or preparations according to the invention specified within the scope of the description of the present invention represent advantageous impregnation solutions for cosmetic and dermatological wipes for the purposes of the present invention.

(41) It is advantageous if the impregnation solutions according to the invention are of low viscosity, in particular sprayable, and have, for example, a viscosity of less than 2000 mPa.Math.s, in particular less than 1500 mPa.Math.s (measuring instrument: Haake Viskotester VT-02 at 25° C.).

(42) Preferred embodiment of the preparation according to the invention is therefore an emulsion, an aerosol, a concealer (cover stick) or a gel.

(43) A preparation according to the invention as concealer (cover stick) is particularly suitable and thus preferred since even very small areas of skin can be treated in a targeted manner. In known guide formulations for suitable cover sticks with which the person skilled in the art is familiar, according to the invention the synergistic combination of dye and active ingredient is included, thus giving preparations according to the invention.

(44) The cosmetic and dermatological formulations according to the invention can comprise cosmetic auxiliaries as are customarily used in such preparations, e.g. preservatives, bactericides, perfumes, substances for preventing foaming, dyes, pigments which have a colouring effect, thickeners, moisturizing and/or humectant substances, fats, oils, waxes or other customary constituents of a cosmetic or dermatological formulation, such as alcohols, polyols, polymers, foam stabilizers, electrolytes, organic solvents and/or silicone derivatives, and moisturizers.

(45) Moisturizers is the term used for substances or mixtures of substances which, following application or distribution on the surface of the skin, impart to cosmetic or dermatological preparations the property of reducing the moisture loss by the horny layer (also called transepidermal water loss (TEWL)) and/or positively influencing hydration of the horny layer.

(46) Advantageous moisturizers for the purposes of the present invention are, for example, glycerol, lactic acid, pyrrolidonecarboxylic acid and urea. It is also particularly advantageous to use polymeric moisturizers from the group of water-soluble and/or water-swellable and/or water-gellable polysaccharides. Particularly advantageous are, for example, hyaluronic acid and/or a fucose-rich polysaccharide which is listed in the Chemical Abstracts under the registry number 178463-23-5 and is available, for example, under the name Fucogel®1000 from SOLABIA S. A. Glycerol can be used as moisturizer for the purposes of the present application in the range from 0.05-30% by weight, particularly preferably 1-10%.

(47) The amounts of cosmetic or dermatological auxiliaries and carrier substances and perfume to be used in each case can be determined easily by the person skilled in the art by simple experimentation, depending on the nature of the particular product.

(48) An additional content of antioxidants is generally preferred. According to the invention, favourable antioxidants which can be used are all antioxidants customary or suitable for cosmetic and/or dermatological applications.

(49) The antioxidants are advantageously chosen from the group consisting of amino acids (e.g. glycine, histidine, tyrosine, tryptophan) and derivatives thereof, imidazoles (e.g. urocanic acid) and derivatives thereof, peptides, such as D,L-carnosine, D-carnosine, L-carnosine and derivatives thereof (e.g. anserine), carotenoids, carotenes (e.g. α-carotene, β-carotene, lycopene) and derivatives thereof, lipoic acid and derivatives thereof (e.g. dihydrolipoic acid), aurothioglucose, propylthiouracil and other thiols (e.g. thioredoxin, glutathione, cysteine, cystine, cystamine and the glycosyl, N-acetyl, methyl, ethyl, propyl, amyl, butyl and lauryl, palmitoyl, oleyl, γ-linoleyl, cholesteryl and glyceryl esters thereof) and salts thereof, dilauryl thiodipropionate, distearyl thiodipropionate, thiodipropionic acid and derivatives thereof (esters, ethers, peptides, lipids, nucleotides, nucleosides and salts), and sulphoximine compounds (e.g. buthionine sulphoximines, homocysteine sulphoximine, buthionine sulphones, penta-, hexa-, heptathionine sulphoximine) in very low tolerated doses (e.g. pmol to μmol/kg), and also (metal) chelating agents (e.g. α-hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin), α-hydroxy acids (e.g. citric acid, lactic acid, malic acid), humic acid, melanins, bile acid, bile extracts, bilirubin, biliverdin, EDTA, EGTA and derivatives thereof, unsaturated fatty acids and derivatives thereof (e.g. γ-linolenic acid, linoleic acid, oleic acid), folic acid and derivatives thereof, alanine diacetic acid, flavonoids, polyphenols, catechins, vitamin C and derivatives (e.g. ascorbyl palmitate, Mg ascorbyl phosphate, ascorbyl acetate), tocopherols and derivatives (e.g. vitamin E acetate), and coniferyl benzoate of benzoin resin, rutinic acid and derivatives thereof, ferulic acid and derivatives thereof, butylhydroxytoluene, butylhydroxyanisole, nordihydroguaiacic acid, nordihydroguaiaretic acid, trihydroxybutyrophenone, uric acid and derivatives thereof, mannose and derivatives thereof, zinc and derivatives thereof (e.g. ZnO, ZnSO.sub.4), selenium and derivatives thereof (e.g. selenemethionine), stilbenes and derivatives thereof (e.g. stilbene oxide, trans-stilbene oxide) and the derivatives (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides and lipids) of these specified active ingredients which are suitable according to the invention.

(50) The amount of the abovementioned antioxidants (one or more compounds) in the emulsions is preferably 0.001 to 30% by weight, particularly preferably 0.05 to 20% by weight, in particular 0.1 to 10% by weight, based on the total weight of the preparation.

(51) If vitamin E and/or derivatives thereof are the antioxidant or the antioxidants, it is advantageous to choose their particular concentrations from the range from 0.001 to 10% by weight, based on the total weight of the formulation.

(52) If vitamin A or vitamin A derivatives, or carotenes or derivatives thereof are the antioxidant or the antioxidants, it is advantageous to choose their particular concentrations from the range from 0.001 to 10% by weight, based on the total weight of the formulation.

(53) Within the scope of the present disclosure, the expression “lipids” is sometimes used as the generic term for fats, oils, waxes and the like, as is entirely familiar to the person skilled in the art. The terms “oil phase” and “lipid phase” are also used synonymously.

(54) Oils and fats differ from one another inter alia in their polarity, which is difficult to define. It has already been proposed to adopt interfacial tension towards water as a measure of the polarity index of an oil or of an oil phase. This means that the greater the polarity of the oil phase in question, the lower the interfacial tension between this oil phase and water. According to the invention, the interfacial tension is regarded as being one possible measure of the polarity of a given oil component.

(55) Polar oils are, for example, those from the group of lecithins and of fatty acid triglycerides, namely the triglycerol esters of saturated and/or unsaturated, branched and/or unbranched alkanecarboxylic acids with a chain length of from 8 to 24, in particular 12 to 18 carbon atoms. The fatty acid triglycerides can, for example, be chosen advantageously from the group of synthetic, semisynthetic and natural oils, such as, for example, olive oil, sunflower oil, soya oil, peanut oil, rapeseed oil, almond oil, palm oil, coconut oil, castor oil, wheatgerm oil, grapeseed oil, thistle oil, evening primrose oil, macadamia nut oil and the like.

(56) Particularly advantageous polar lipids for the purposes of the present invention are all natural lipids such as, for example, olive oil, sunflower oil, soya oil, peanut oil, rapeseed oil, almond oil, palm oil, coconut oil, castor oil, wheatgerm oil, grapeseed oil, thistle oil, evening primrose oil, macadamia nut oil, maize germ oil, avocado oil and the like, and those listed below.

(57) TABLE-US-00001 Polarity Trade name INCI name [mN/m] Isofol 14 T Butyl Decanol (+) Hexyl Octanol (+) 19.8 Hexyl Decanol (+) Butyl Octanol Lipovol MOS-130 Tridecyl Stearate (+) Tridecyl Trimellitate 19.4 (+) Dipentaerythrityl Hexacaprylate/Hexacaprate Castor oil 19.2 Isofol Ester 0604 19.1 Miglyol 840 Propylene Glycol Dicaprylate/Dicaprate 18.7 Isofol 12 Butyl Octanol 17.4 Tegosoft SH Stearyl Heptanoate 17.8 Avocado oil 14.5 Cetiol B Dibutyl Adipate 14.3 Dermol 488 PEG 2 Diethylene Hexanoate 10.1 Cosmacol ELI C12–13 Alkyl Lactate 8.8 Dermol 489 Diethylene Glycol Dioctanoate/ 8.6 Diisononanoate Cosmacol ETI Di-C12/13 Alkyl Tartrate 7.1 Emerest 2384 Propylene Glycol Monoisostearate 6.2 Myritol 331 Cocoglycerides 5.1 Prisorine 2041 GTIS Triisostearin 2.4

(58) The oil phase can also advantageously be chosen from the group of dialkyl ethers, the group of saturated or unsaturated, branched or unbranched alcohols. It is particularly advantageous if the oil phase has a content of C.sub.12-15-alkyl benzoate or consists entirely of this.

(59) In addition, the oil phase can advantageously be chosen from the group of Guerbet alcohols. Guerbet alcohols are named after Marcel Guerbet, who described their preparation for the first time. They are formed according to the reaction equation

(60) ##STR00003##
by oxidation of an alcohol to give an aldehyde, by aldol condensation of the aldehyde, elimination of water from the aldol and hydrogenation of the allyl aldehyde. Guerbet alcohols are liquid even at low temperatures and cause virtually no skin irritations. They can be used advantageously as fatting, superfatting and also refatting constituents in skincare and haircare compositions.

(61) The use of Guerbet alcohols in cosmetics is known per se. Such species are then in most cases characterized by the structure

(62) ##STR00004##
Here, R.sub.1 and R.sub.2 are usually unbranched alkyl radicals.

(63) According to the invention, the Guerbet alcohol or alcohols are chosen from the group in which R.sub.1=propyl, butyl, pentyl, hexyl, heptyl or octyl and R.sub.2=hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl or tetradecyl.

(64) Guerbet alcohols preferred according to the invention are 2-butyloctanol—it has the chemical structure

(65) ##STR00005##
and is available, for example, under the trade name Isofolo® 12 from Condea Chemie GmbH—and 2-hexyldecanol—it has the chemical structure

(66) ##STR00006##
and is available, for example, under the trade name Isofol® 16 from Condea Chemie GmbH. Mixtures of Guerbet alcohols according to the invention are also used advantageously according to the invention. Mixtures of 2-butyloctanol and 2-hexyl-decanol are available, for example, under the trade name Isofol®14 from Condea Chemie GmbH.

(67) The total amount of Guerbet alcohols in the finished cosmetic or dermatological preparations is advantageously chosen from the range up to 25.0% by weight, preferably 0.5-15.0% by weight, based on the total weight of the preparations.

(68) Any desired mixtures of such oil and wax components are also used advantageously for the purposes of the present invention. It may in some cases also be advantageous to use waxes, for example cetyl palmitate, as the sole lipid component of the oil phase.

(69) Particularly advantageous mid-polar lipids for the purposes of the present invention are the substances listed below:

(70) TABLE-US-00002 Polarity Trade name INCI name [mN/m] DUB VCl 10 Isodecyl Neopentanoate 29.9 Dermol IHD Isohexyl Decanoate 29.7 Dermol 108 Isodecyl Octanoate 29.6 Dihexyl Ether Dihexyl Ether 29.2 Dermol 109 Isodecyl 3,5,5-Trimethyl Hexanoate 29.1 Cetiol SN Cetearyl Isononanoate 28.6 Isopropyl palmitate Isopropyl Palmitate 28.8 DC Fluid 345 Cyclomethicone 28.5 Dow Corning Cyclopolydimethylsiloxan 28.5 Fluid 244 Jojoba oil Gold 26.2 Wacker AK 100 Dimethicone 26.9 Dermol 98 3,5,5-Trimethyl 2-Ethylhexanoate 26.2 Dow Corning Open 25.3 Fluid 246 Eutanol G Octyldodecanol 24.8 Isofol 16 Hexyldecanol 24.3 Dermol 139 Isotridecyl 3,5,5-Trimethylhexanonanoate 24.5 Cetiol PGL Hexyldecanol (+) Hexyl Decyl Laurate 24.3 Cegesoft C24 Octyl Palmitate 23.1 M.O.D. Octyldodecyl Myristate 22.1 Macadamia Nut Oil 22.1 Silicone oil Phenyltrimethicone 22.7 VP 1120 Isocarb 12 Butyloctanoic Acid 22.1 Isopropyl stearate Isopropyl Stearate 21.9 Finsolv TN C12–15 Alkyl Benzoate 21.8 Dermofeel BGC Butylene Glycol Caprylate/Caprate 21.5 Miglyol 812 Caprylic/Capric Triglyceride 21.3 Trivent OCG Tricaprylin 20.2 Dermol 866 PEG Diethyl hexanoate/Diisononanoate/ 20.1 Ethylhexyl Isononanoate

(71) Nonpolar oils are, for example, those which are chosen from the group of branched and unbranched hydrocarbons and hydrocarbon waxes, in particular Vaseline (petrolatum), paraffin oil, squalane and squalene, polyolefins and hydrogenated polyisobutenes. Among the polyolefins, polydecenes are the preferred substances.

(72) Particularly advantageous nonpolar lipids for the purposes of the present invention are the substances listed below:

(73) TABLE-US-00003 Polarity Trade name INCI name [mN/m] Ecolane 130 Cycloparaffin 49.1 Nexbase 2006 FG Polydecene 46.7 Polysynlane Hydrogenated Polyisobutene 44.7 Wacker Silicone oil AK Polydimethylsiloxane 46.5 50 Solvent ICH Isohexadecane 43.8 Pionier 2076 Mineral Oil 43.7 Pionier 6301 Mineral Oil 43.7 Wacker Silicone oil AK Polydimethylsiloxane 42.4 35 Isoeicosane Isoeicosane 41.9 Wacker Silicone oil AK Polydimethylsiloxane 40.9 20 Isofol 1212 Carbonate 40.3 Softcutol O Ethoxydiglycol Oleate 40.5 Lipodermanol OL Decyl Olivate 40.3 Cetiol S Dioctylcyclohexane 39.0 Pionier 2071 Mineral Oil 38.3 Hydrobrite 1000 PO Paraffinum Liquidum 37.6 Tegosoft HP Isocetyl Palmitate 36.2 Isofol Ester 1693 33.5 Isofol Ester 1260 33.0 Dow Corning Fluid 245 Cyclopentasiloxane 32.3 Prisorine 2036 Octyl Isostearate 31.6 Cetiol CC Dicaprylyl Carbonate 31.7 Dermol 99 Trimethylhexyl Isononanoate 31.1 Dermol 89 2-Ethylhexyl Isononanoate 31.0 Cetiol OE Dicaprylyl Ether 30.9 Dihexyl carbonate Dihexyl Carbonate 30.9 Silkflo 366 NF Polydecene 30.1 Estol 1540 EHC Octyl Cocoate 30.0

(74) However, it is also advantageous to use mixtures of lipids with higher and lower polarity and the like. For example the oil phase can advantageously be chosen from the group of branched and unbranched hydrocarbons and hydrocarbon waxes, dialkyl ethers, the group of saturated or unsaturated, branched or unbranched alcohols, and fatty acid triglycerides, namely the triglycerol esters of saturated and/or unsaturated, branched and/or unbranched alkanecarboxylic acids with a chain length of from 8 to 24, in particular 12-18, carbon atoms. The fatty acid triglycerides can, for example, advantageously be chosen from the group of synthetic, semisynthetic and natural oils, e.g. olive oil, sunflower oil, soya oil, peanut oil, rapeseed oil, almond oil, palm oil, coconut oil, palm kernel oil and the like, provided the conditions required in the main claim are observed.

(75) Fat and/or wax components to be used advantageously according to the invention can be chosen from the group of vegetable waxes, animal waxes, mineral waxes and petrochemical waxes. According to the invention, candelilla wax, carnauba wax, Japan wax, esparto grass wax, cork wax, guaruma wax, rice germ oil wax, sugar cane wax, berry wax, ouricury wax, montan wax, jojoba wax, shea butter, beeswax, shellac wax, spermaceti, lanolin (wool wax), uropygial grease, ceresine, ozokerite (earth wax), paraffin waxes and micro waxes, for example, are favourable, provided the conditions required in the main claim are observed.

(76) Further advantageous fat and/or wax components are chemically modified waxes and synthetic waxes, such as, for example those available under the trade names Syncrowax HRC (glyceryl tribehenate), and Syncrowax AW 1C (C.sub.18-36-fatty acid) from CRODA GmbH, and montan ester waxes, sasol waxes, hydrogenated jojoba waxes, synthetic or modified beeswaxes (e.g. dimethicone copolyol beeswax and/or C.sub.30-50-alkyl beeswax), polyalkylene waxes, polyethylene glycol waxes, but also chemically modified fats, such as, for example, hydrogenated vegetable oils (for example hydrogenated castor oil and/or hydrogenated coconut fatty glycerides), triglycerides, such as, for example, trihydroxystearin, fatty acids, fatty acid esters and glycol esters, such as, for example, C.sub.20-40-alkyl stearate, C.sub.20-40-alkylhydroxystearoyl stearate and/or glycol montanate. In addition, also advantageous are certain organosilicon compounds which have similar physical properties to said fat and/or wax components, such as, for example, stearoxytrimethylsilane, provided the conditions required in the main claim are observed.

(77) According to the invention, the fat and/or wax components can either be present individually or else in a mixture. Any desired mixtures of such oil and wax components are also used advantageously for the purposes of the present invention.

(78) The oil phase is advantageously chosen from the group consisting of 2-ethylhexyl isostearate, octyldodecanol, isotridecyl isononanoate, butylene glycol dicaprylate/dicaprate, 2-ethylhexyl cocoate, C.sub.12-15-alkyl benzoate, caprylic/capric triglyceride, dicaprylyl ether provided the conditions required in the main claim are observed.

(79) Mixtures of octyldodecanol, caprylic/capric triglyceride, dicaprylyl ether, dicaprylyl carbonate, cocoglycerides, or mixtures of C.sub.12-15-alkyl benzoate and 2-ethylhexyl isostearate, mixtures of C.sub.12-15-alkyl benzoate and butylene glycol dicaprylate/dicaprate, and mixtures of C.sub.12-15-alkyl benzoate, 2-ethylhexyl isostearate and isotridecyl isononanoate are particularly advantageous provided the conditions required in the main claim are observed.

(80) Of the hydrocarbons, paraffin oil, cycloparaffin, squalane, squalene, hydrogenated polyisobutene and/or polydecene are to be used advantageously for the purposes of the present invention, provided the conditions required in the main claim are observed.

(81) It may likewise be advantageous to choose the oil phase of the preparations according to the invention partially or completely from the group of cyclic and/or linear silicones, which are also referred to as “silicone oils” for the purposes of the present disclosure. Such silicones or silicone oils may be in the form of monomers which are generally characterized by structural elements, as follows:

(82) ##STR00007##

(83) Silicone oils are high molecular weight synthetic polymeric compounds in which silicon atoms are joined via oxygen atoms in a chain-like and/or reticular manner and the remaining valencies of the silicon are saturated by hydrocarbon radicals (in most cases methyl groups, less often ethyl, propyl, phenyl groups, inter alia).

(84) Linear silicones with a plurality of siloxyl units to be used advantageously according to the invention are generally characterized by structural elements as follows:

(85) ##STR00008##
where the silicon atoms may be substituted by identical or different alkyl radicals and/or aryl radicals, which are shown here in general terms by the radicals R.sub.1-R.sub.4 (that is to say the number of different radicals is not necessarily limited to up to 4). m can here assume values from 2-200,000.

(86) Systematically, the linear silicone oils are referred to as polyorganosiloxanes; the methyl-substituted polyorganosiloxanes, which represent the most important compounds of this group in terms of amount and are characterized by the following structural formula

(87) ##STR00009##
are also referred to as polydimethylsiloxane and Dimethicone (INCI). Dimethicones have various chain lengths and various molecular weights. Dimethicones of various chain lengths and phenyltrimethicones are particularly advantageous linear silicone oils for the purposes of the present invention.

(88) Particularly advantageous polyorganosiloxanes for the purposes of the present invention are also, for example, dimethylpolysiloxanes [poly(dimethylsiloxane)], which are available, for example, under the trade names ABIL 10 to 10 000 from Th. Goldschmidt. Also advantageous are phenylmethylpolysiloxanes (INCl: Phenyl Dimethicone, Phenyl Trimethicone), cyclic silicones (octamethylcyclotetrasiloxane and decamethylcyclopentasiloxane), which are also referred to according to INCI as Cyclomethicone, amino-modified silicones (INCl: Amodimethicone) and silicone waxes, e.g. polysiloxane-polyalkylene copolymers (INCl: Stearyl Dimethicone and Cetyl Dimethicone) and dialkoxydimethylpolysiloxanes (stearoxy dimethicones and behenoxy stearyl dimethicones) which are available as various Abil wax grades from Th. Goldschmidt.

(89) Also particularly advantageous for the purposes of the present invention are the silicone oils listed below:

(90) TABLE-US-00004 Polarity Trade name INCI name [mN/m] Wacker Silicone oil AK Polydimethylsiloxane 26.9 100 Wacker Silicone oil AK Polydimethylsiloxane 46.5 50 Wacker Silicone oil AK Polydimethylsiloxane 42.4 35 Wacker Silicone oil AK Polydimethylsiloxane 40.9 20 Dow Corning Fluid 245 Cyclopentasiloxane 32.3 Dow Corning Fluid 345 Cyclomethicone 28.5

(91) Cyclic silicones to be used advantageously according to the invention are generally characterized by structural elements as follows

(92) ##STR00010##
where the silicon atoms may be substituted by identical or different alkyl radicals and/or aryl radicals, which are shown here in general terms by the radicals R.sub.1-R.sub.4 (that is to say the number of different radicals is not necessarily limited to up to 4). n can here assume values from 3/2 to 20. Fractional values for n take into consideration the fact that uneven numbers of siloxyl groups may be present in the cycle.

(93) Particularly advantageous cyclic silicone oils for the purposes of the present invention are cyclomethicones, in particular cyclomethicone D5 and/or cyclomethicone D6.

(94) Advantageous silicone oils and/or silicone waxes for the purposes of the present invention are cyclic and/or linear silicone oils and silicone waxes.

(95) It is particularly advantageous for the purposes of the present invention to choose the ratio of lipids to silicone oils as approximately 1:1 (generally x:y).

(96) Phenyltrimethicone is advantageously chosen as silicone oil. Other silicone oils, for example dimethicone, phenyldimethicone, cyclomethicone (octamethylcyclotetrasiloxane), for example hexamethylcyclotrisiloxane, polydimethylsiloxane, poly(methylphenylsiloxane), cetyldimethicone, behenoxydimethicone are also to be used advantageously for the purposes of the present invention.

(97) Also advantageous are mixtures of cyclomethicone and isotridecyl isononanoate, and those of cyclomethicone and 2-ethylhexyl isostearate.

(98) It is, however, also advantageous to choose silicone oils of similar constitution to the above-named compounds, whose organic side chains are derivatized, for example polyethoxylated and/or polypropoxylated. These include, for example, polysiloxane-polyalkyl-polyether copolymers, such as cetyldimethicone copolyol and cetyldimethicone copolyol (and) polyglyceryl-4-isostearate (and) hexyl laurate.

(99) The lipid phase can be chosen advantageously from the following group of substances: mineral oils, mineral waxes; oils, such as triglycerides of capric acid or of caprylic acid, and also natural oils, such as, for example, castor oil; fats, waxes and other natural and synthetic fatty substances, preferably esters of fatty acids with alcohols of low carbon number, e.g. with isopropanol, propylene glycol or glycerol, or esters of fatty alcohols with alkanoic acids of low carbon number or with fatty acids; alkyl benzoates; silicone oils, such as dimethylpolysiloxanes, diethylpolysiloxanes, diphenylpolysiloxanes, and mixed forms thereof.

(100) The oil phase of the emulsions, oleogels and hydrodispersions or lipodispersions for the purposes of the present invention is advantageously chosen from the group of esters of saturated and/or unsaturated, branched and/or unbranched alkanecarboxylic acids with a chain length of from 3 to 30 carbon atoms and saturated and/or unsaturated, branched and/or unbranched alcohols with a chain length of from 3 to 30 carbon atoms, from the group of esters of aromatic carboxylic acids and saturated and/or unsaturated, branched and/or unbranched alcohols with a chain length of from 3 to 30 carbon atoms. Such ester oils can then advantageously be chosen from the group consisting of isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl oleate, n-butyl stearate, n-hexyl laurate, n-decyl oleate, isooctyl stearate, isononyl stearate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl laurate, 2-hexyldecyl stearate, 2-octyldodecyl palmitate, oleyl oleate, oleyl erucate, erucyl oleate, erucyl erucate, and synthetic, semisynthetic and natural mixtures of such esters, e.g. jojoba oil.

(101) Any desired mixtures of such oil and wax components are also used advantageously for the purposes of the present invention. It may in some instances also be advantageous to use waxes, for example cetyl palmitate, as the sole lipid component of the oil phase.

(102) The oil phase is advantageously chosen from the group consisting of 2-ethylhexyl isostearate, octyidodecanol, isotridecyl isononanoate, isoeicosane, 2-ethylhexyl cocoate, C.sub.12-15-alkyl benzoate, caprylic/capric triglyceride, dicaprylyl ether.

(103) Mixtures of C.sub.12-15-alkyl benzoate and 2-ethylhexyl isostearate, mixtures of C.sub.12-15-alkyl benzoate and isotridecyl isononanoate, and mixtures of C.sub.12-15-alkyl benzoate, 2-ethylhexyl isostearate and isotridecyl isononanoate are particularly advantageous.

(104) Of the hydrocarbons, paraffin oil, squalane and squalene are to be used advantageously for the purposes of the present invention.

(105) The aqueous phase of the formulations according to the invention optionally advantageously comprises alcohols, diols or polyols of low carbon number, and ethers thereof, preferably ethanol, isopropanol, propylene glycol, glycerol, ethylene glycol, ethylene glycol monoethyl or monobutyl ether, propylene glycol monomethyl, monoethyl or monobutyl ether, diethylene glycol monomethyl or monoethyl ether and analogous products, and also alcohols of low carbon number, e.g. ethanol, isopropanol, 1,2-propanediol, glycerol, and in particular one or more thickeners which can advantageously be chosen from the group consisting of silicon dioxide, aluminium silicates, polysaccharides and derivatives thereof, e.g. xanthan gum and/or hydroxypropylmethylcellulose, in each case individually or in combination.

(106) It is also advantageous for the purposes of the present invention to create cosmetic and dermatological preparations whose main purpose is not protection against sunlight but which nevertheless contain a content of UV protection substances. Thus, UV-A and/or UV-B filter substances are, for example, usually incorporated into day creams or make-up products. UV protection substances, like antioxidants and—if desired—preservatives, also represent effective protection of the preparations themselves against decay. Also favourable are cosmetic and dermatological preparations which are in the form of a sunscreen composition.

(107) The examples below illustrate the invention. The amounts given are percentages by weight based in each case on the total mass of the preparation. The example preparations according to the invention have a slight green shade and give the skin a natural appearance when applied to irritated or reddened skin. The colour shading of the preparations can be adapted individually within the claimed range depending on the ambient parameters, skin colour, degree of redness.

(108) TABLE-US-00005 W/O emulsions Example 1 2 3 4 5 Triglycerol diisostearate 1.0 0.5 0.25 2.0 3.0 Diglycerol 1.0 1.5 1.75 3.0 2.0 dipolyhydroxystearate Paraffin oil 12.5 10.0 8.0 5.0 17.5 Vaseline 8.0 6.0 5.0 12.0 2.5 Hydrogenated coco 2.0 1.0 2.5 5.0 0.25 glycerides Decyl oleate 0.5 0.75 1.0 2.0 0.25 Octyldodecanol 0.5 1.0 0.75 3.0 0.25 Aluminium stearate 0.4 0.3 0.6 1.0 0.05 Dicaprylyl carbonate 0.1 0.05 0.15 0.5 1.0 Hydrogenated castor oil 0.5 0.75 1.0 2.5 5.0 Magnesium sulphate 0.5 0.6 0.5 0.7 1.0 Glycerol 3.0 5.0 10.0 15.0 1.5 Citric acid 0.2 0.1 0.2 0.3 1.0 Sodium citrate 0.2 0.05 0.4 0.3 2.0 Perfume q.s. q.s. q.s. q.s. q.s. Ethanol 2.0 — 5.0 — — Caprylic/capric 2.0 2.5 3.0 5.0 0.5 triglyceride Potassium sorbate 0.04 0.15 0.05 0.03 0.4 Benzyl alcohol 0.3 0.4 0.25 0.15 — White pigment 2.5 3.0 2.25 3.5 5.0 (CI 77891) Green pigment 0.27 0.42 0.54 0.35 0.75 (CI 77288) Green pigment 0.088 0.1 0.16 0.095 0.25 (CI 77288) Blue pigment (CI 77007) 0.03 0.04 0.05 0.03 0.08 Panthenol 1.0 2.0 3.0 — — Glycyrrhiza inflata 0.025 0.035 — — 0.25 Hamamelis 1.0 2.0 — 5.0 — Water ad 100 ad 100 ad 100 ad 100 ad 100 Example 6 7 8 9 10 PEG-30 — 0.5 0.25 — 3.0 dipolyhydroxystearate Lanolin alcohol 1.0 1.5 1.75 3.0 — Paraffin oil 12.5 10.0 8.0 5.0 17.5 Vaseline 8.0 6.0 5.0 12.0 2.5 Hydrogenated 2.0 1.0 2.5 5.0 0.25 cocoglycerides Hydrogenated 0.5 0.75 1.0 2.0 0.25 polyisobutene Octyldodecanol 0.5 1.0 0.75 3.0 0.25 Aluminium stearate 0.4 0.3 0.6 1.0 0.05 Dicaprylyl carbonate 0.1 0.05 0.15 0.5 1.0 Hydrogenated castor oil 0.5 0.75 1.0 2.5 5.0 Microcrystalline 0.5 1.0 0.75 0.25 0.1 cellulose Magnesium sulphate 0.5 0.6 0.5 0.7 1.0 Glycerol 3.0 5.0 10.0 15.0 1.5 Citric acid 0.2 0.1 0.2 0.3 1.0 Perfume q.s. q.s. q.s. q.s. q.s. 1,3-Butylene glycol 2.0 — 5.0 — — Caprylic/capric 2.0 2.5 3.0 5.0 0.5 triglyceride Sodium dehydracetate — — 0.05 — — White pigment 2.5 3.0 2.25 3.5 5.0 (CI 77891) Green pigment 0.27 0.42 0.54 0.35 0.75 (CI 77288) Green pigment 0.088 0.1 0.16 0.095 0.25 (CI 77288) Blue pigment 0.03 0.04 0.05 0.03 0.08 (CI 77007) Panthenol 1.0 2.0 3.0 — — Glycyrrhiza inflata 0.025 0.035 — — 0.25 Hamamelis 1.0 2.0 — 5.0 — Potassium sorbate 0.3 0.4 0.25 0.15 — Water ad 100 ad 100 ad 100 ad 100 ad 100

(109) TABLE-US-00006 W/S Emulsion Example 11 12 13 14 15 Cetyl PEG/PPG-10/1 1.0 — — 3.0 5.0 dimethicones Cyclomethicone + 10.0 12.5 25 — — PEG/PPG-18/18 dimethicone (90:10) Cyclomethicone 12.5 15 28.0 25.0 17.5 Dimethicone 5.0 13.0 5.0 12.0 15.0 Hydrogenated 0.5 0.75 1.0 2.0 0.25 polyisobutene Octyldodecanol 0.5 1.0 0.75 3.0 0.25 Sodium chloride 2.0 0.6 2.5 0.7 1.0 Glycerol 3.0 5.0 10.0 15.0 1.5 Citric acid 0.2 0.1 0.2 0.3 1.0 Sodium citrate 1.0 0.1 0.4 0.9 2.5 Perfume q.s. q.s. q.s. q.s. q.s. Potassium sorbate 0.4 0.1 0.05 0.3 0.4 White pigment 2.5 3.0 2.25 3.5 5.0 (CI 77891) Green pigment 0.27 0.42 0.54 0.35 0.75 (CI 77288) Green pigment 0.088 0.1 0.16 0.095 0.25 (CI 77288) Blue pigment 0.03 0.04 0.05 0.03 0.08 (CI 77007) Panthenol 1.0 2.0 3.0 — — Glycyrrhiza inflata 0.025 0.035 — — 0.25 Hamamelis 1.0 2.0 — 5.0 — Cetyldimethicone 0.5 — 0.7 — — Benzyl alcohol — — 0.05 — 0.1 Water ad 100 ad 100 ad 100 ad 100 ad 100 Example 16 17 18 19 20 Cetyl PEG/PPG-10/1 1.0 — — 3.0 5.0 dimethicones Cyclomethicone + 10.0 12.5 25 — — PEG/PPG-18/18 dimethicone (90:10) Cyclomethicone 12.5 15 28.0 25.0 17.5 Dimethicone 5.0 13.0 5.0 12.0 15.0 Hydrogenated 0.5 0.75 1.0 2.0 0.25 polyisobutene Octyldodecanol 0.5 1.0 0.75 3.0 0.25 Sodium chloride 2.0 0.6 2.5 0.7 1.0 Glycerol 3.0 5.0 10.0 15.0 1.5 Lactic acid 0.2 0.1 0.2 — — Sodium lactate 0.2 1.0 0.05 — — Perfume q.s. q.s. q.s. q.s. q.s. Stearyldimethicone 0.5 — 0.7 — — White pigment 2.5 3.0 2.25 3.5 5.0 (CI 77891) Green pigment 0.27 0.42 0.54 0.35 0.75 (CI 77288) Green pigment 0.088 0.1 0.16 0.095 0.25 (CI 77288) Blue pigment 0.03 0.04 0.05 0.03 0.08 (CI 77007) Panthenol 1.0 2.0 3.0 — — Glycyrrhiza inflata 0.025 0.035 — — 0.25 Hamamelis 1.0 2.0 — 5.0 — Dehydracetic acid — — 0.05 — 0.1 Modified starch — 2.5 — 0.15 — Water ad 100 ad 100 ad 100 ad 100 ad 100

(110) TABLE-US-00007 W/O emulsions Example 21 22 23 24 25 TPEG-22 dodecyl 5.0 1.5 0.25 — 3.0 glycol copolymer PEG-45 dodecyl 1.0 1.5 1.75 3.0 — glycol polymer Paraffin oil 12.5 10.0 8.0 5.0 17.5 Isopropyl stearate 8.0 6.0 5.0 12.0 2.5 Hydrogenated 2.0 1.0 2.5 5.0 0.25 cocoglycerides Evening primrose oil 0.5 0.75 1.0 2.0 0.25 Octyldodecanol 0.5 1.0 0.75 3.0 0.25 Aluminium stearate 0.4 0.3 0.6 1.0 0.05 Dicaprylyl carbonate 0.1 0.05 0.15 0.5 1.0 Hydrogenated castor oil 0.5 0.75 1.0 2.5 5.0 Magnesium sulphate 0.5 0.6 0.5 0.7 1.0 Glycerol 3.0 5.0 10.0 15.0 1.5 Sodium citrate 0.2 0.1 — — — Citric acid 0.2 0.1 — — — Perfume q.s. q.s. q.s. q.s. q.s. White pigment 2.5 3.0 2.25 3.5 5.0 (CI 77891) Green pigment 0.27 0.42 0.54 0.35 0.75 (CI 77288) Green pigment 0.088 0.1 0.16 0.095 0.25 (CI 77288) Blue pigment (CI 77007) 0.03 0.04 0.05 0.03 0.08 Panthenol 1.0 2.0 3.0 — — Glycyrrhiza inflata 0.025 0.035 — — 0.25 Hamamelis 1.0 2.0 — 5.0 — 1,3-Butylene glycol 2.0 — 5.0 — — Caprylic/capric 2.0 2.5 3.0 5.0 0.5 triglyceride Potassium sorbate 0.4 0.15 0.05 0.3 0.4 Benzyl alcohol — — 0.05 — 0.1 Water ad 100 ad 100 ad 100 ad 100 ad 100 Example 26 27 28 29 30 Polyglyceryl-2- 3.0 — 0.25 — 3.0 dipolyhydroxystearate Polyglyceryl-3- 1.0 3.5 1.75 2.5 — diisostearate PEG-40 sorbitan — 2.5 0.5 3.5 3.0 isostearate Paraffin oil 12.5 10.0 8.0 5.0 17.5 Isopropyl stearate 8.0 6.0 5.0 12.0 2.5 Hydrogenated 2.0 1.0 2.5 5.0 0.25 cocoglycerides Isopropyl palmitate 0.5 1.0 0.75 3.0 0.25 Dicaprylyl carbonate 0.1 0.05 0.15 0.5 1.0 Hydrogenated castor oil 0.5 0.75 1.0 2.5 5.0 Magnesium sulphate 0.5 0.6 0.5 0.7 1.0 Glycerol 3.0 5.0 10.0 15.0 1.5 White pigment 2.5 3.0 2.25 3.5 5.0 (CI 77891) Green pigment 0.27 0.42 0.54 0.35 0.75 (CI 77288) Green pigment 0.088 0.1 0.16 0.095 0.25 (CI 77288) Blue pigment (CI 77007) 0.03 0.04 0.05 0.03 0.08 Panthenol 1.0 2.0 3.0 — — Glycyrrhiza inflata 0.025 0.035 — — 0.25 Hamamelis 1.0 2.0 — 5.0 — Citric acid 0.2 0.1 0.1 0.3 1.0 Sodium citrate 0.2 0.3 0.2 1.5 0.8 Perfume q.s. q.s. q.s. q.s. q.s. Caprylic/capric 2.0 2.5 3.0 5.0 0.5 triglyceride Potassium sorbate 0.24 0.15 0.05 0.3 0.4 Water ad 100 ad 100 ad 100 ad 100 ad 100

(111) TABLE-US-00008 Silicone-in-water emulsion Example 31 32 33 34 35 Dimethicone copolyol, 1.0 2.0 8.0 3.0 5.0 caprylic/capric triglyceride Cyclomethicone 12.5 15 25.0 10.0 7.5 Dimethicone 5.0 15.0 5.0 12.0 15.0 Mineral oil 0.5 0.75 1.0 2.0 0.25 Phenyltrimethicone 0.5 1.0 0.75 3.0 0.25 Glycerol 5.0 7.5 10.0 3.0 1.0 Xanthan gum — 0.1 — 0.25 1.0 Perfume q.s. q.s. q.s. q.s. q.s. White pigment 2.5 3.0 2.25 3.5 5.0 (CI 77891) Green pigment 0.27 0.42 0.54 0.35 0.75 (CI 77288) Green pigment 0.088 0.1 0.16 0.095 0.25 (CI 77288) Blue pigment (CI 77007) 0.03 0.04 0.05 0.03 0.08 Panthenol 1.0 2.0 3.0 — — Glycyrrhiza inflata 0.025 0.035 — — 0.25 Hamamelis 1.0 2.0 — 5.0 — Methylparaben 0.4 0.1 0.05 0.3 0.4 Propylparaben 0.3 0.4 0.25 0.15 — Iodopropynyl — — 0.05 — 0.1 butylcarbamate Water ad 100 ad 100 ad 100 ad 100 ad 100

(112) TABLE-US-00009 O/W emulsion Example 36 37 38 39 40 Glyceryl stearate 1.0 — — 0.5 0.25 Polyethylene glycol(40) 10.0 — 5 — — stearate Triglycerol — 5.5 — — 2.5 methylglucose distearate Sorbitan stearate — 1.5 3 — — Cyclomethicone 2.5 15 8.0 5.0 7.5 Dimethicone 5.0 3.0 5.0 2.0 5.0 Behenyl alcohol 1 — 2 1 — Stearyl alcohol — 1 — 1 — Cetylstearyl alcohol — — 1 1 — Hydrogenated 0.5 0.75 1.0 2.0 0.25 polyisobutene Octyldodecanol 0.5 1.0 0.75 3.0 0.25 Perfume q.s. q.s. q.s. q.s. q.s. Methylparaben 0.4 0.1 0.05 0.3 0.4 Propylparaben 0.3 0.4 0.25 0.15 — Iodopropynyl — — 0.05 — 0.1 butylcarbamate White pigment 2.5 3.0 2.25 3.5 5.0 (CI 77891) Green pigment 0.27 0.42 0.54 0.35 0.75 (CI 77288) Green pigment 0.088 0.1 0.16 0.095 0.25 (CI 77288) Blue pigment (CI 77007) 0.03 0.04 0.05 0.03 0.08 Panthenol 1.0 2.0 3.0 — — Glycyrrhiza inflata 0.025 0.035 — — 0.25 Hamamelis 1.0 2.0 — 5.0 — Glycerol 5 10 3 15 7.5 Modified starch — 2.5 — 0.15 — Water ad 100 ad 100 ad 100 ad 100 ad 100 Example 41 42 43 44 45 Polyethylene glycol(21) 1 — 2.5 2 1.5 stearyl ether Polyethylene glycol(2) 1 — 5.5 3 7.5 stearyl ether Cetearyl glucoside — 8 — — — Behenyl alcohol 3 2 — 1 — Stearyl alcohol 3 2 — 2 — Cetylstearyl alcohol 3 4 — — 2 Hydrogenated 0.5 0.75 1.0 2.0 0.25 polyisobutene Octyldodecanol 0.5 1.0 0.75 3.0 0.25 Glycerol 5 10 15 3 7.5 Perfume q.s. q.s. q.s. q.s. q.s. Methylparaben 0.4 0.1 0.05 0.3 0.4 Propylparaben 0.3 0.4 0.25 0.15 — Iodopropynyl — — 0.05 — 0.1 butylcarbamate White pigment 2.5 3.0 2.25 3.5 5.0 (CI 77891) Green pigment 0.27 0.42 0.54 0.35 0.75 (CI 77288) Green pigment 0.088 0.1 0.16 0.095 0.25 (CI 77288) Blue pigment (CI 77007) 0.03 0.04 0.05 0.03 0.08 Panthenol 1.0 2.0 3.0 — — Glycyrrhiza inflata 0.025 0.035 — — 0.25 Hamamelis 1.0 2.0 — 5.0 — Modified starch 0.5 — — 0.15 — Water ad 100 ad 100 ad 100 ad 100 ad 100 Example 46 47 48 49 50 Glyceryl stearate citrate 1.0 0.5 0.1 0.5 0.3 Polyethylene glycol(20) 10.0 1.0 5 — — cetearyl ether Triglycerol — — — — 2.5 methylglucose distearate Dimethicone 0.5 3.0 0.75 1.5 0.2 Dicaprylyl carbonate 3 5 10 15 5 Stearyl alcohol — — — 1 0.2 Cetylstearyl alcohol — — 1 1 0.2 Tocopherol 0.5 0.5 0.75 0.25 0.1 Octyldodecanol 0.5 — 0.75 3.0 0.25 Carbomer 0.05 0.35 0.15 0.1 — Perfume q.s. q.s. q.s. q.s. q.s. Caprylic/capric 1 5 3 5 10 triglyceride Methylparaben 0.4 0.3 0.05 0.3 0.4 Iodopropynyl — — 0.05 — 0.1 butylcarbamate Phenoxyethanol — 0.5 — 0.15 — Sorbitol 10 — — 5 — Butylene glycol — — — 5 10 White pigment 2.5 3.0 2.25 3.5 5.0 (CI 77891) Green pigment 0.27 0.42 0.54 0.35 0.75 (CI 77288) Green pigment 0.088 0.1 0.16 0.095 0.25 (CI 77288) Blue pigment (CI 77007) 0.03 0.04 0.05 0.03 0.08 Panthenol 1.0 2.0 3.0 — — Glycyrrhiza inflata 0.025 0.035 — — 0.25 Hamamelis 1.0 2.0 — 5.0 — Propylene glycol — — 10 5 — Glycerol — 7.5 — — — Water ad 100 ad 100 ad 100 ad 100 ad 100 Example 51 52 53 54 55 Sorbitan stearate 0.86 — — 2.7 2.6 Titanium dioxide 1.5 4.0 3.75 3.1 5.5 Shea butter 1.5 2.5 3.75 — 3.0 Triglycerol 2.14 3.0 3.0 0.6 1.2 methylglucose distearate Squalane 2.0 — — 4.0 3.5 Dimethicone 4.0 3.0 5.0 3.0 2.75 Lauroyllysine 2.0 3.0 1.5 1.25 — Ethylhexyl 7.5 — — 1.3 1.3 methoxycinnamate C12-15 alkyl benzoate 2.0 2.5 3.75 3.0 4.5 Phenoxyethanol 0.5 0.4 0.4 0.75 0.5 Methylparaben 0.3 0.2 0.2 0.2 0.2 Glycerol 10.0 10.0 10.0 10.0 12.5 Propylparaben 0.1 0.1 0.1 0.1 0.1 Xanthan gum 0.2 0.1 0.1 0.2 0.1 White pigment 2.5 3.0 2.25 3.5 5.0 (CI 77891) Green pigment 0.27 0.42 0.54 0.35 0.75 (CI 77288) Green pigment 0.088 0.1 0.16 0.095 0.25 (CI 77288) Blue pigment (CI 77007) 0.03 0.04 0.05 0.03 0.08 Panthenol — 2.0 3.0 — — Glycyrrhiza inflata 0.025 0.035 — — 0.25 Hamamelis — 2.0 — 5.0 — Perfume q.s. q.s. q.s. q.s. q.s. Magnesium aluminium 0.3 — — — 0.5 silicate Butylene glycol 0.5 0.018 0.018 — 0.018 Water ad 100 ad 100 ad 100 ad 100 ad 100

(113) TABLE-US-00010 Emulsions for concealer application Example 56 57 58 59 60 Triglycerol diisostearate 5.12 4.25 3.75 6.22 5.26 Cyclopentasiloxane 14.8 10.8 8.5 16.7 12.3 Propylene glycol 6.23 10.0 8.0 5.0 5.96 dicaprylate/dicaprate Methyl methacrylate 4.15 3.18 5.0 4.35 2.5 crosspolymer Glyceryl oleate 2.5 1.5 2.5 3.5 2.75 Vaseline 2.23 3.23 1.23 1.95 2.45 Candelilla wax 1.11 1.0 0.75 2.2 0.25 Carnauba wax 1.11 0.3 0.6 1.0 0.25 Acrylate/octylacrylamide 1.0 1.5 0.75 1.25 1.0 copolymer Dimethicone 0.67 0.75 1.0 0.5 0.88 crosspolymer Panthenol 0.5 0.6 0.5 0.7 1.0 Glycerol 8.5 5.0 10.0 15.0 1.5 Butylene glycol 0.3 0.1 0.2 0.3 1.0 EDTA, disodium salt 0.2 0.05 0.4 0.3 0.18 Perfume — q.s. — q.s. — PEG/PPG-18/18 0.11 0.05 0.25 0.12 0.13 dimethicone White pigment 8.0 10.0 6.0 8.3 5.0 (CI 77891) Green pigment 0.81 0.42 0.54 0.35 0.75 (CI 77288) Iron oxide 0.152 0.1 0.16 0.095 0.25 (CI 77492) Mica 1.67 1.87 1.47 1.65 — Glycyrrhiza inflata 0.025 0.035 0.025 0.01 0.25 Diazolidinylurea 0.2 0.2 0.2 0.18 0.2 Iodopropynyl 0.016 0.018 0.016 0.018 0.018 butylcarbamate Phenoxyethanol 0.15 0.25 0.15 0.2 0.3 Hamamelis — 2.0 — 5.0 — Water ad 100 ad 100 ad 100 ad 100 ad 100