One-piece washing tablet made from combination of compositions and preparation method thereof

Abstract

A one-piece combination detergent tablet is provided and includes: a detergent composition body A, a color-care and anti-stain composition body B, and an antibacterial and softening composition body C. The detergent composition body A includes: an anionic surfactant A, a non-ionic surfactant A, a polymeric water-soluble film A, an additive A, and water. The color-care and anti-stain composition body B includes: an anionic surfactant B; a non-ionic surfactant B; a polymeric water-soluble film B; an additive B; and water. The antibacterial and softening composition body C includes: a non-ionic surfactant C, a quaternary ammonium cationic surfactant, a polymeric water-soluble film C an additive C, and water. The one-piece combination detergent tablet can be stably stored and has an extended shelf life and a reduced transportation costs.

Claims

1. A one-piece combination detergent tablet, comprising: a detergent composition body A, a color-care and anti-stain composition body B, and an antibacterial and softening composition body C; wherein the detergent composition body A, the color-care and anti-stain composition body B, and the antibacterial and softening composition body C are independently arranged from each other and are arranged on a same surface of a water-soluble sheet; wherein the detergent composition body A comprises: an anionic surfactant A in a mass proportion of 16%-24%; a non-ionic surfactant A in a mass proportion of 5%-9%; a polymeric water-soluble film A in a mass proportion of 8%-15%; an additive A in a mass proportion of 9%-12%; and water for the rest; the color-care and anti-stain composition body B comprises: an anionic surfactant B in a mass proportion of 6%-12%; a non-ionic surfactant B in a mass proportion of 18%-24%; a polymeric water-soluble film B in a mass proportion of 7%-10%; an additive B in a mass proportion of 9%-14%; and water for the rest; the antibacterial and softening composition body C comprises: a non-ionic surfactant C in a mass proportion of 16%-25%; a quaternary ammonium cationic surfactant in a mass proportion of 5%-10%; a polymeric water-soluble film C in a mass proportion of 12%-18%; an additive C in a mass proportion of 14%-22%; and water for the rest; the total amount of the non-ionic surfactant A, the non-ionic surfactant B, and the non-ionic surfactant C in the one-piece combination detergent tablet is greater than the total amount of the anionic surfactant A and the anionic surfactant B; and each of the polymeric water-soluble film A, the polymeric water-soluble film B, and the polymeric water-soluble film C is made from polyvinyl alcohol being compounded with polyvinyl pyrrolidone; the anionic surfactant A is made by sodium dodecyl sulfate, ?-olefin sulfonate, fatty acid methyl ester sulfonate, sodium dodecyl polyether sulfate, and fatty acid methyl ester ethoxylate sulfate sodium salt being compounded with each other in a mass ratio of 5:2:1:1:1; the anionic surfactant B is made by sodium dodecyl sulfate, ?-olefin sulfonate, fatty acid methyl ester sulfonate, sodium dodecyl polyether sulfate, fatty acid methyl ester ethoxylate sulfate sodium salt being compounded with each other in a mass ratio of 4:1:1:2:1; the non-ionic surfactant A is made by fatty alcohol polyoxyethylene ether, FMEE surfactant, and cocamide being compounded with each other; the non-ionic surfactant B is made by alkyl glycosides, FMEE surfactant, and cocamide being compounded with each other; and the non-ionic surfactant C is made by fatty alcohol polyoxyethylene ether, FMEE surfactant, cocamide, and alkyl glycoside being compounded with each other.

2. The one-piece combination detergent tablet according to claim 1, wherein, the non-ionic surfactant A is made by fatty alcohol polyoxyethylene ether, FMEE surfactant, and cocamide being compounded with each other in a mass ratio of 3:2:2; the non-ionic surfactant B is made by alkyl glycosides, FMEE surfactant, and cocamide being compounded with each other in a mass ratio of 2:2:1; and the non-ionic surfactant C is made by fatty alcohol polyoxyethylene ether, FMEE surfactant, cocamide, and alkyl glycoside being compounded with each other in a mass ratio of 1:1:3:4.

3. The one-piece combination detergent tablet according to claim 1, wherein, the quaternary ammonium cationic surfactant comprises one or more of: dialkyl dimethyl ammonium chloride, dialkyl imidazoline salt, dialkyl amido quaternary ammonium salt, and ethyl bis(2-palmitate)-based hydroxyethyl methyl ammonium sulfate.

4. A method of preparing the one-piece combination detergent tablet according to claim 1, the method comprising: an operation 1 of preparing the detergent composition body A, wherein, (1) the polymeric water-soluble film A is added to deionized water to form a component A, while adding, the component A is heated for dissolving the polymeric water-soluble film A; and a premixed material A is obtained; and (2) the anionic surfactant A and the non-ionic surfactant A are added into the premixed material A; after the anionic surfactant A, the non-ionic surfactant A, and the premixed material A are mixed uniformly, the additive A is further added to obtain a mixture, the mixture is stirred, and a slurry A is obtained; an operation 2 of preparing the color-care and anti-stain composition body B, wherein (1) the polymeric water-soluble film B is added into deionized water to form a component B, the component B is heated for dissolving the polymeric water-soluble film B, and a premixed material B is obtained; and (2) the anionic surfactant B and the non-ionic surfactant B are added into the premixed material B; after the anionic surfactant B, the non-ionic surfactant B, and the premixed material B are mixed uniformly, the additive B is further added to obtain a mixture; the mixture is stirred evenly; and a slurry B is obtained; an operation 3 of preparing the antibacterial and softening composition body C, wherein (1) the polymeric water-soluble film C is added into deionized water to form a component C, the component C is heated for dissolving the polymeric water-soluble film C, and a premixed material C is obtained; and (2) the non-ionic surfactant C and the quaternary ammonium cationic surfactant are added into the premixed material C; after the non-ionic surfactant C, the quaternary ammonium cationic surfactant, and the premixed material C are mixed uniformly, the additive C is further added; and a slurry C is obtained; an operation 4 of preparing the one-piece combination detergent tablet; wherein each of the slurry A, the slurry B, and the slurry C is conveyed into a fixed manifold conveying pipe respectively to reach a heated rotatable cylinder having slurry grooves isolated from each other; water is removed from each of the slurry A, the slurry B, and the slurry C, and each of the water-removed slurry A, the water-removed slurry B, and the water-removed slurry C is shaped into a sheet form having respective compositions for detergency, and the one-piece combination detergent tablet is obtained.

5. A one-piece combination detergent tablet, comprising a detergent composition body A, a color-care and anti-stain composition body B, and an antibacterial and softening composition body C; wherein the detergent composition body A, the color-care and anti-stain composition body B, and the antibacterial and softening composition body C are independently arranged from each other and are arranged on a same surface of a water-soluble sheet; wherein the detergent composition body A comprises: an anionic surfactant A in a mass proportion of 16%-24%; a non-ionic surfactant A in a mass proportion of 5%-9%; a polymeric water-soluble film A in a mass proportion of 8%-15%; an additive A in a mass proportion of 9%-12%; and water for the rest; the color-care and anti-stain composition body B comprises: an anionic surfactant B in a mass proportion of 6%-12%; a non-ionic surfactant B in a mass proportion of 18%-24%; a polymeric water-soluble film B in a mass proportion of 7%-10%; an additive B in a mass proportion of 9%-14%; and water for the rest; the antibacterial and softening composition body C comprises: a non-ionic surfactant C in a mass proportion of 16%-25%; a quaternary ammonium cationic surfactant in a mass proportion of 5%-10%; a polymeric water-soluble film C in a mass proportion of 12%-18%; an additive C in a mass proportion of 14%-22%; an alkyl guanidine-type microbicide; and water for the rest; wherein the alkyl guanidine-type microbicide is one or more of: dodecyl guanidine acetate, poly(hexamethylene bisguanidine), poly(aminopropyl bisguanidine), chlorhexidine acetate, hydroxy phenyl ether; the total amount of the non-ionic surfactant A, the non-ionic surfactant B, and the non-ionic surfactant C in the one-piece combination detergent tablet is greater than the total amount of the anionic surfactant A and the anionic surfactant B; each of the polymeric water-soluble film A, the polymeric water-soluble film B, and the polymeric water-soluble film C is made from polyvinyl alcohol being compounded with polyvinyl pyrrolidone; the anionic surfactant A is made by sodium dodecyl sulfate, ?-olefin sulfonate, fatty acid methyl ester sulfonate, sodium dodecyl polyether sulfate, and fatty acid methyl ester ethoxylate sulfate sodium salt being compounded with each other in a mass ratio of 5:2:1:1:1; the anionic surfactant B is made by sodium dodecyl sulfate, ?-olefin sulfonate, fatty acid methyl ester sulfonate, sodium dodecyl polyether sulfate, fatty acid methyl ester ethoxylate sulfate sodium salt being compounded with each other in a mass ratio of 4:1:1:2:1; the non-ionic surfactant A is made by fatty alcohol polyoxyethylene ether, FMEE surfactant, and cocamide being compounded with each other; the non-ionic surfactant B is made by alkyl glycosides, FMEE surfactant, and cocamide being compounded with each other; and the non-ionic surfactant C is made by fatty alcohol polyoxyethylene ether, FMEE surfactant, cocamide, and alkyl glycoside being compounded with each other.

Description

DETAILED DESCRIPTION

(1) The present disclosure will be described in further detail below by referring to the embodiments.

(2) Embodiments 1-2

(3) In the present embodiment, a one-piece combination detergent tablet is provided and includes a detergent composition body A, a color-care and anti-stain composition body B, and an antibacterial and softening composition body C.

(4) The detergent composition body A includes the following components:

(5) an anionic surfactant A; a non-ionic surfactant A; a polymeric water-soluble film A; an additive A; and water.

(6) The color-care and anti-stain composition body B includes the following components:

(7) an anionic surfactant B; a nonionic surfactant B; a polymeric water-soluble film B; an additive B; and water.

(8) The antibacterial and softening composition body C includes the following components:

(9) a non-ionic surfactant C; a quaternary ammonium cationic surfactant; a polymeric water-soluble film C; an additive C; and water.

(10) The total amount of the non-ionic surfactants in the one-piece combination detergent tablet is greater than the total amount of the anionic surfactants.

(11) Each of the polymeric water-soluble film A, the polymeric water-soluble film B, and the polymeric water-soluble film C is made from polyvinyl alcohol being compounded with polyvinyl pyrrolidone.

(12) The polyvinyl alcohol has a degree of polymerization of 1800, a molecular weight of 80,000 MW, and an alkalization degree of 85%-90%. A hydrophobically modified acrylic polymer is used as a dispersant. Dimethyl 1,4-benzenedicarboxylate polymer with 1,2-propanediol, diester with ?-methyl-?-hydroxypol or water soluble polyester is used as a stain-removing polymer. Sokalan HP 20 is polyethylene imine ethoxylate. A modified vinyl pyrrolidone/vinylimidazole co-polymer is used as a high-performance anti-colour stringing detergent.

Embodiment 3

(13) The amount of each component for the Embodiment 3 is different from that for the Embodiment 1. That is, in the present embodiment, the anionic surfactant A is made by sodium dodecyl sulfate, ?-olefin sulfonate, fatty acid methyl ester sulfonate, sodium dodecyl polyether sulfate, and fatty acid methyl ester ethoxylate sulfate sodium salt being compounded with each other in a mass ratio of 5:2:1:1:1:1.

(14) The anionic surfactant B is made by sodium dodecyl sulfate, ?-olefin sulfonate, fatty acid methyl ester sulfonate, sodium dodecyl polyether sulfate, sodium salt of fatty acid methyl ester ethoxylate sulfate being compounded with each other in a mass ratio of 4:1:1:2:1.

(15) The non-ionic surfactant A is made by fatty alcohol polyoxyethylene ether, FMEE surfactant, and cocamide being compounded with each other in a mass ratio of 3:2:2.

(16) The non-ionic surfactant B is made by alkyl glycosides, FMEE surfactant, and cocamide being compounded with each other in a mass ratio of 2:2:1.

(17) The non-ionic surfactant C is made by fatty alcohol polyoxyethylene ether, FMEE surfactant, cocamide, and alkyl glycoside being compounded with each other in a mass ratio of 1:1:3:4.

(18) A method of preparing the one-piece combination detergent tablet includes the following operations.

(19) In an operation 1, the detergent composition body A is prepared.

(20) (1) The polymeric water-soluble film A is added to deionized water to form a material component, while adding, the material component is being stirred and being heated to reach 85? C. Heating is then turned off, and the material component is maintained at 85? C. constantly for 30 minutes until the material component is completely dissolved and swelled evenly, such that a premixed material A is obtained.

(21) (2) The anionic surfactant A and the non-ionic surfactant A are added into the premixed material A. After the anionic surfactant A, the non-ionic surfactant A, and the premixed material A are mixed uniformly, the additive A is further added to obtain a mixture. PH of the mixture is adjusted to be ?9.5, viscosity of the mixture is 25000 mPa.Math.s, and at this time, a temperature of the mixture is 65? C., such that a slurry A is obtained.

(22) In an operation 2, the color-care and anti-stain composition body B is prepared.

(23) (1) The polymeric water-soluble film B is added into deionized water to form a material component, while adding, the material component is being stirred and being heated to reach 90? C. Heating is then turned off, and the material component is maintained at 90? C. constantly for 30 minutes until the material component is completely dissolved and swelled evenly, such that a premixed material B is obtained.

(24) (2) The anionic surfactant B and the non-ionic surfactant B are added into the premixed material B. After the anionic surfactant B, the non-ionic surfactant B, and the premixed material B are mixed uniformly, the additive B is further added to obtain a mixture. PH of the mixture is adjusted to be ?8.2, viscosity of the mixture is 45000 mPa.Math.s, and at this time, a temperature of the mixture is 55? C., such that a slurry B is obtained.

(25) In an operation 3, the antibacterial and softening composition body C is prepared.

(26) (1) The polymeric water-soluble film C is added into deionized water to form a material component, while adding, the material component is being stirred and being heated to reach 85? C. Heating is then turned off, and the material component is maintained at 85? C. constantly for 30 minutes until the material component is completely dissolved and swelled evenly, such that a premixed material C is obtained.

(27) (2) The non-ionic surfactant C and the quaternary ammonium cationic surfactant are added into the premixed material C. After the non-ionic surfactant C, the quaternary ammonium cationic surfactant, and the premixed material C are mixed uniformly, the additive C is further added to obtain a mixture. PH of the mixture is adjusted to be in a range from 5.0 to 7.0, viscosity of the mixture is 40000 mPa.Math.s, and at this time, a temperature of the mixture is 50? C., such that a slurry C is obtained.

(28) In an operation 4, the one-piece combination detergent tablet is prepared.

(29) Each of the slurry A, the slurry B, and the slurry C is conveyed into a fixed manifold conveying pipe respectively to reach a heated rotatable cylinder having slurry grooves isolated from each other. Water is removed from each of the slurries, and each of the slurries is shaped into a sheet form having the respective compositions for washing. That is, the one-piece combination detergent tablet is obtained.

(30) The color-care and anti-stain composition body B and the antibacterial and softening composition body Care disposed on two sides of the detergent composition body A, respectively.

(31) Compositions and dosages of the compositions in the Embodiments 1-3 are shown in Table 1, and the dosages in Table 1 take kg as the unit.

(32) TABLE-US-00001 TABLE 1 Embodiment Embodiment Embodiment 1 2 3 detergent Anionic sodium dodecyl sulfate 3 8 10 composition surfactant ?-olefin sulfonate 5 6 4 body A A Fatty acid methyl ester 4 2 2 sulfonate Sodium dodecyl polyether 2 4 2 sulfate Fatty acid methyl ester 2 4 2 ethoxy sulfonate sodium Total 16 24 20 Non-ionic Fatty alcohol 2 4 3 surfactant polyoxyethylene ether A FMEE surfactant 2 3 2 cocamide 1 2 2 Total 5 9 7 Polymeric polyvinyl alcohol 4 10 7 water-soluble polyvinylpyrrolidone 4 5 3 film A Total 8 15 10 Additive hydrophobically modified 3 3 3 A acrylic polymer glycerol 3 3 3 sodium citrate 1 1 1 Glutamic acid 1 1 1 Tetrasodium diacetate salt Hydroxyethyl cellulose 0.5 0.5 0.5 Daily-use flavorings 1 1 1 Microencapsulated 0.5 0.5 0.5 flavorings Hydroxyphenyl methyl 0.1 0.1 0.1 ester reactive dye 0.1 0.1 0.1 Total 10.2 10.2 10.2 water 60.8 41.8 52.8 Total 100 100 100 color-care Anionic sodium dodecyl sulfate 1 3 4 and anti- surfactant ?-olefin sulfonate 2 2 1 stain B Fatty acid methyl ester 1 4 1 composition sulfonate body B Sodium dodecyl polyether 1 2 2 sulfate Fatty acid methyl ester 1 1 1 ethoxy sulfonate sodium salt Total 6 12 9 Non-ionic alkyl glycoside 6 8 8 surfactant FMEE surfactant 8 6 8 B cocamide 4 10 4 Total 18 24 20 Polymeric polyvinyl alcohol 5 6 7 water-soluble polyvinylpyrrolidone 2 4 2 film B Total 7 10 9 Additive stain-removing polymer 1 1 1 B Sokalan HP 20 3 3 3 modified vinyl 0.5 0.5 0.5 pyrrolidone/vinylimidazole co-polymer Glycerol 3 3 3 sodium citrate 1 1 1 sodium iminodisuccinate 0.5 0.5 0.5 Carboxymethyl cellulose 0.5 0.5 0.5 Daily-use flavorings 1 1 1 hydroxyphenyl ether 0.3 0.3 0.3 Reactive dye 0.1 0.1 0.1 Total 10.9 10.9 10.9 Water 58.1 43.1 51.1 Total 100 100 100 antibacterial Non-ionic Fatty alcohol 3 5 2 and surfactant polyoxyethylene ether softening C FMEE surfactant 3 5 2 composition cocamide 4 7 6 body C alkyl glycoside 6 8 8 Total 16 25 18 Cationic Ethyl dipalmitate 3 5 5 surfactant hydroxyethyl methylammonium sulfate Sokalan HP 20 2 5 3 Total 5 10 8 Polymeric polyvinyl alcohol 6 10 9 water-soluble polyvinylpyrrolidone 6 8 6 film C Total 12 18 15 Additive stain-removing polymer 0.5 0.5 0.5 C Glycerol 3 3 3 sodium citrate 1.5 1.5 1.5 citric acid 0.5 0.5 0.5 Hydroxyethyl cellulose 0.5 0.5 0.5 pea starch 10 10 10 Bentonite clay 5 5 5 Daily-use flavorings 1 1 1 Total 22 22 22 Water 45 25 37 Total 100 100 100

Embodiment 4

(33) Compared to the Embodiment 3, in the present embodiment, the antibacterial and softening composition body C further includes a zwitter-ionic surfactant. The zwitter-ionic surfactant is made by lauramidopropylamine oxide and cocamidopropyl betaine being compounded with each other in a mass ratio of 1:1.

Embodiment 5

(34) Compared to the Embodiment 3, in the present embodiment, the antibacterial and softening composition body C further includes an alkyl guanidine-type microbicide. The alkyl guanidine-type microbicide is made by poly(aminopropylidenebiguanide) and chlorhexidine acetate being compounded with each other in a mass ratio of 1:2.

(35) Control Experiment 1

(36) Compared to the Embodiment 3, in the present control experiment, the amount of the anionic surfactant A is less than the amount of the non-ionic surfactant A. That is, the amount of the anionic surfactant A is 7 kg, and the amount of the non-ionic surfactant A is 20 kg.

(37) Control Experiment 2

(38) Compared to the Embodiment 3, in the present control experiment, the amount of the non-ionic surfactant B is less than the amount of the anionic surfactant B. That is, the amount of the non-ionic surfactant B is 9 kg, and the amount of the anionic surfactant B is 20 kg.

(39) Control Experiment 3

(40) Compared to the Embodiment 3, in the present control experiment, the amount of the non-ionic surfactant C is less than the amount of the quaternary ammonium cationic surfactant. That is, the amount of the non-ionic surfactant C is 8 kg, and the amount of the quaternary ammonium cationic surfactant is 18 kg.

(41) Control Experiment 4

(42) Compared to the Embodiment 3, in the present control experiment, the anionic surfactant A is made by sodium dodecyl sulfate and ?-olefin sulfonate being compounded with each other in a mass ratio of 5:5. The anionic surfactant B is made by fatty acid methyl ester sulfonate and sodium dodecyl polyether sulfate being compounded with each other in a mass ratio of 5:4.

(43) Control Experiment 5

(44) Compared to the Embodiment 3, in the present control experiment, the non-ionic surfactant A is made by fatty alcohol polyoxyethylene ether and cocamide being compounded with each other in a mass ratio of 3:4. The non-ionic surfactant B is made by fatty alcohol polyoxyethylene ether and cocamide being compounded with each other in a mass ratio of 4:1. The non-ionic surfactant C is made by fatty alcohol polyoxyethylene ether, FMEE surfactant, and alkyl glycoside being compounded with each other in a mass ratio of 3:3:3.

(45) Experiment 1

(46) 10 g of the one-piece combination detergent tablet prepared in each of the above Embodiments and in each of the control experiments is respectively added to 100 g of water to form 10 detergent solutions. A plurality of uniformly shaped and sized carbon-black oil-stained cloth JB-01, a plurality of protein-stained cloth JB-02, and a plurality of sebum-stained cloth JB-03 are prepared by performing cloth preparation methods specified in the GB/T13174-2008 Determination of detergent performance and cyclic washing performance of cloth-washing materials. Further, a stain removal value of each one-piece combination detergent tablet prepared in each of the above Embodiments and in each of the control experiments is determined in accordance with the GB/T13174-2008 Determination of detergent performance and cyclic washing performance of cloth-washing materials.

(47) Experiment 2

(48) In the present experiment, a bacterial inhibition rate (%) of the one-piece combination detergent tablet prepared in each of the above Embodiments and in each of the control experiments is determined by following the method of testing the microbial inhibition effect of anti-microbial daily chemical products (quantification of suspensions) specified in the Appendix 7.3 of the QB/T2738-2012 Evaluation method of antimicrobial and microbial inhibition for daily chemical products. The bacterial inhibition rate of ?50% indicates that the one-piece combination detergent tablet has a bacterial inhibition effect. The bacterial inhibition rate of ?90% indicates that the bacterial inhibition effect of the one-piece combination detergent tablet is strong.

(49) Results of the above experiments are shown in Table 2

(50) TABLE-US-00002 TABLE 2 Whether the bacterial inhibition one-piece performance combi- Staphylococcus nation Decontamination E. coli aureus detergent performance inhibition inhibition rate tablet is JB-01 JB-02 JB-03 rate (%) (%) shaped Embod- 25.42 6.35 10.23 98.13 98.25 YES iment 1 Embod- 26.08 6.49 10.45 98.56 98.47 YES iment 2 Embod- 26.59 6.50 10.52 98.64 98.82 YES iment 3 Embod- 28.30 7.94 11.90 98.70 98.92 YES iment 4 Embod- 25.85 6.68 10.68 99.98 99.93 YES iment 5 Embod- 25.16 5.88 9.84 95.12 96.36 NO iment 1 Embod- 24.22 4.56 8.63 89.24 87.49 YES iment 2 Embod- 24.57 4.72 8.79 88.65 88.51 YES iment 3 Embod- 22.08 4.03 8.14 90.22 93.04 YES iment 4 Control 23.41 4.25 8.36 91.08 94.85 YES experi- ment 5 Detergent 25.13 6.11 9.82 97.54 97.26 in the market

(51) According to comparison between the control experiment 1 and the embodiment 3 in Table 2, the amount of the anionic surfactant A in the control experiment 1 is less than the amount of the non-ionic surfactant A in the control experiment 1, and the one-piece combination detergent tablet cannot be stably shaped. Due to the fact that the amount of the anionic surfactant A is less than the amount of the non-ionic surfactant A, the total amount of the non-ionic surfactant in the one-piece combination detergent tablet is larger, such that the one-piece combination detergent tablet to cannot be shaped properly.

(52) According to comparison between the control experiment 2 and the embodiment 3 in Table 2, the amount of the non-ionic surfactant B in the control experiment 2 is less than the amount of the anionic surfactant B in the control experiment 2. The decontamination performance of the control experiment 2 is not as good as that of the embodiment 3, and the bacterial inhibition performance of the control experiment 2 is not as good as that of the embodiment 3. Due to the fact that the total amount of the non-ionic surfactant in the one-piece combination detergent tablet is less, the anionic surfactant B and the quaternary ammonium salt cationic surfactant interferes with each other, such that the decontamination performance and the bacterial inhibition performance of the one-piece combination detergent tablet are reduced.

(53) According to comparison between the control experiment 3 and the embodiment 3 in Table 2, the amount of the nonionic surfactant C in the control experiment 3 is less than the amount of the quaternary ammonium cationic surfactant in the control experiment 3, the detergent performance of the control experiment 3 is not as good as that of the embodiment 3, and the bacterial inhibition performance of the control experiment 3 is less than that of the embodiment 3. Due to the fact that the amount of the total non-ionic surfactant in the one-piece combination detergent tablet is less, the quaternary ammonium cationic surfactant, the anionic surfactant A, and the anionic surfactant B may interfere with each other, such that the detergent performance and the bacterial inhibition performance of the one-piece combination detergent tablet is reduced.

(54) In summary, only by compounding the various compositions reasonably, the total amount of the non-ionic surfactant in the one-piece combination detergent tablet is greater than the total amount of the anionic surfactant in the one-piece combination detergent tablet. In this way, when the one-piece combination detergent tablet is being in use, the influence, caused by the anionic surfactant, on the antimicrobial and softening effect of the quaternary ammonium cationic surfactant is reduced, and at the same time, the one-piece combination detergent tablet can be shaped properly.

(55) According to comparison between the control experiment 4 and the embodiment 3 in Table 2, the anionic surfactant A in the control experiment 4 is made by sodium dodecyl sulfate and ?-olefin sulfonate being compounded with each other. The anionic surfactant B in the control experiment 4 is made by fatty acid methyl ester sulfonate and sodium dodecyl polyether sulfate being compounded with each other. The decontamination performance and the bacterial inhibition performance of the control experiment 4 is less than that of the embodiment 3, indicating that the technical effect of the present application cannot be achieved if the anionic surfactant A and the anionic surfactant B are made by compounding compositions randomly.

(56) According to comparison between the control experiment 5 and the embodiment 3 in Table 2, the non-ionic surfactant A in the control experiment 5 is made by fatty alcohol polyoxyethylene ether and cocoamide being compounded with each other. The non-ionic surfactant B in the control experiment 5 is made by fatty alcohol polyoxyethylene ether and cocoamide being compounded with each other. The non-ionic surfactant C in the control experiment 5 is made by fatty alcohol polyoxyethylene ether, FMEE surfactant, and alkyl glucoside being compounded with each other. In this case, the decontamination performance and the bacterial inhibition performance of the control experiment 5 is less than that of the embodiment 3, indicating that the technical effect of the present application cannot be achieved if the non-ionic surfactant A, the non-ionic surfactant B, and the non-ionic surfactant C are made by compounding compositions randomly.

(57) According to comparison between the embodiment 4 and the embodiment 3 in Table 2, the one-piece combination detergent tablet further includes the zwitter-ionic surfactant, and the zwitter-ionic surfactant is made by lauramidopropylamine oxide and cocoamidopropyl betaine being compounded with each other in the mass ratio of 1:1, and in this case, the decontamination performance of the embodiment 4 is greater than that of the embodiment 3. It indicates that when the zwitter-ionic surfactant is added into the one-piece combination detergent tablet, the decontamination performance of the one-piece combination detergent tablet can be improved.

(58) According to comparison between the embodiment 5 and the embodiment 3 in Table 2, the one-piece combination detergent tablet further includes the alkyl guanidine-type microbicide, and the alkyl guanidine-type microbicide is made by poly(aminopropylbiguanide) and chlorhexidine acetate being compounded with each other in a mass ratio of 1:2, and in this case, the bacterial inhibition performance of the embodiment 5 is greater than that of the embodiment 3. It indicates that when the alkyl guanidine-type microbicide is added to the one-piece combination detergent tablet, the bacterial inhibition performance of the one-piece combination detergent tablet is improved.

(59) The above are the preferred embodiments of the present disclosure but does not limit the scope of the present disclosure. Therefore, any equivalent changes made in accordance with the structure, the shape and principles of the present disclosure shall be covered by the scope of the present disclosure.