Coated stainless steel member

Abstract

The present invention provides a method for producing a coated stainless steel member, comprising: performing Wood's strike nickel plating on a stainless steel substrate, and then performing cationic electrodeposition on a formed Wood's strike nickel plating layer.

Claims

1. A method for producing a coated stainless steel member, comprising: performing Wood's strike nickel plating on a stainless steel substrate; and then performing cationic electrodeposition to form a cationic electrodeposition coating layer directly on a formed Wood's strike nickel plating layer.

2. The production method according to claim 1, comprising: degreasing the stainless steel substrate; performing the Wood's strike nickel plating on the degreased stainless steel substrate; and performing the cationic electrodeposition on the formed Wood's strike nickel plating layer; followed by baking.

3. The production method according to claim 2, wherein the coated stainless steel member is a fuel inlet pipe for an automobile fuel tank.

4. The production method according to claim 1, wherein the coated stainless steel member is a fuel inlet pipe for an automobile fuel tank.

5. The production method according to claim 1, wherein the coated stainless steel member is a fuel inlet pipe for an automobile fuel tank.

Description

DESCRIPTION OF THE PREFERRED EMBODIMENTS

(1) A method for producing a coated stainless steel member of the present invention comprises: performing Wood's strike nickel plating on a stainless steel substrate; and then performing cationic electrodeposition on a formed Wood's strike nickel plating layer. The method of the present invention makes it possible to provide a coated stainless steel member comprising: a stainless steel substrate; and a Wood's strike nickel plating layer and a cationic electrodeposition coating layer which are stacked in this order on the stainless steel substrate.

(2) As for a basic bath composition for the Wood's strike nickel plating used in the present invention, a known Wood's strike nickel plating bath can be used, and the bath is composed of nickel chloride and hydrochloric acid. The concentration of nickel chloride in the bath is preferably 200 to 300 g/L, and more preferably 220 to 240 g/L. Meanwhile, the concentration of hydrochloric acid (35% aqueous hydrogen chloride solution) in the bath is preferably 100 ml/L to 300 ml/L, and more preferably 125 to 230 ml/L. In addition, boric acid serving as a buffering agent and an anti-mist agent can also be added to the Wood's strike nickel plating bath. The concentration of boric acid in the bath is, for example, 10 to g/L, and preferably 25 to 35 g/L. Meanwhile, the concentration of the anti-mist agent in the bath is, for example, 0.1 to 10 g/L, and preferably 0.5 to 3 g/L. Moreover, the kind of the anti-mist agent is not limited, and an example thereof is DS-55 (manufactured by DIPSOL CHEMICALS Co., Ltd.). The pH of the Wood's strike nickel plating bath is generally 1 or lower.

(3) The temperature at which the Wood's strike nickel plating is performed by using the Wood's strike nickel plating bath may be normal temperature, and preferably 20 C. to 60 C., and more preferably 40 to 50 C. The cathode current density for performing the plating is, for example, 0.5 A/dm.sup.2 or higher, preferably 1 to 10 A/dm.sup.2, and more preferably 3 to 8 A/dm.sup.2. The time for which the plating is performed is preferably set so that the product of the plating time and the cathode current density can be 100 (secondA/dm.sup.2) or larger. The product is more preferably 150 to 1000 (secondA/dm.sup.2). The thickness of a nickel plating film obtained under such plating conditions is generally in the range from 0.005 to 0.3 m, and preferably from 0.02 to 0.25.

(4) Cationic electrodeposition is performed on the Wood's strike nickel plating layer. As the cationic electrodeposition, a known cationic electrodeposition can be employed. For example, a stainless steel member subjected to the Wood's strike nickel plating is immersed in a cationic electrodeposition paint composed of a resin, a pigment, and the like, which meet the purpose of the coating. An article to be coated is used as a cathode (), and an electrode plate set in a diaphragm chamber in an electrodeposition tank is used as an anode (+). A direct current is applied across the cathode () and the anode (+), so that a coating film is deposited on the article to be coated. After that, a water-washing step is conducted. Then, the deposited coating film is dried and cured by baking in a baking furnace. Thus, a coating film excellent in adhesion to the stainless steel can be obtained. Examples of the cationic electrodeposition paint include acrylic paints, alkyd paints, urethane paints, epoxy paints, and the like. The paints are provided as cationic aqueous solutions or emulsions.

(5) In the method for producing a coated stainless steel member of the present invention, the Wood's strike nickel plating layer may be subjected to a zinc phosphate treatment, before the cationic electrodeposition is performed. This makes it possible to prevent decrease in adhesion of the coating due to an electric corrosion reaction caused by contact with other metal. As the zinc phosphate treatment, known zinc phosphate treatments used for ordinary coating can be used as they are.

(6) In the method for producing a coated stainless steel member of the present invention, it is preferable to degrease the stainless steel substrate, before the Wood's strike nickel plating is performed on the stainless steel substrate. By removing oil on the stainless steel, the effect of the Wood's strike nickel plating layer can be exerted more efficiently. As a degreasing agent and a degreasing method employed in the present invention, any known degreasing agent and any known degreasing method can be employed as appropriate. Examples of the degreasing agent include alkaline immersion degreasing agents, alkaline electrolysis degreasing agents, acidic emulsion degreasing agents, solvent cleaning agents, and the like. However, the degreasing agent is not limited thereto. Preferably, an alkaline cathode electrolysis degreasing agent is used. As the degreasing method, for example, an electrolysis immersion treatment is conducted generally at 30 to 55 C. for about several minutes. If needed, a preliminary degreasing treatment can also be conducted before the degreasing treatment.

(7) The present invention is applicable to stainless steel members required to have high corrosion resistance. In particular, the present invention is preferable for a stainless steel fuel inlet pipe for an automobile fuel tank.

(8) Next, the present invention is described while showing Examples and Comparative Examples.

EXAMPLES

(9) The present invention will be described in detail below with reference to the following non-limiting Examples and Comparative examples. It will be apparent to those skilled in the art that many changes can be made in the embodiments described without departing from the scope of the present invention.

Examples 1 to 5

(10) By using 50 g/L of a degreasing agent HD-37 (manufactured by DIPSOL CHEMICALS Co., Ltd.), an SUS436 panel (50 mm100 mm0.3 mm in thickness) is subjected to cathode electrolysis degreasing under conditions of 50 C., 10 minutes, and a cathode current density of 1 A/dm.sup.2. Subsequently, the panel was washed with water. After that, Wood's strike nickel plating was performed (40 C.) under plating conditions shown in Table 1 by using a bath having the following composition.

(11) TABLE-US-00001 Nickel chloride (NiCl.sub.2) 220 g/L 35% hydrochloric acid (HCl) 230 ml/L Boric acid (H.sub.3BO.sub.3) 30 g/L DS-55 (manufactured by 1 ml/L DIPSOL CHEMICALS Co., Ltd.)

(12) After that, the panel was washed with water, and subjected to cationic electrodeposition (25 to 30 m) in a usual manner, by using an electrodeposition paint CFA 590-034 manufactured by PPG. After washed with water, the panel was baked and dried at 200 C. for 25 minutes. The obtained coated panel was immersed in 5% aqueous sodium chloride at 55 C. for 240 hours, and the coating adhesion was evaluated. Table 1 shows the results.

(13) TABLE-US-00002 TABLE 1 Plating Conditions and Results of Evaluation of Coating Adhesion Current Plating Coating adhesion Plating density time Maximum peeling width, conditions (A/dm.sup.2) (second) both sides (mm) Example 1 1 180 2.0 to 5.0 Example 2 3 60 2.0 to 4.0 Example 3 5 30 2.0 to 4.0 Example 4 5 90 1.0 to 3.0 Example 5 5 180 1.0 to 2.0 *The evaluation was made based on the maximum peeling width between both sides (5 mm or less is desirable).

Example 6

(14) By using 50 g/L of a degreasing agent HD-37 (manufactured by DIPSOL CHEMICALS Co., Ltd.), an SUS436 panel (50 mm100 mm0.3 mm in thickness) was subjected to cathode electrolysis degreasing under conditions of 50 C., 10 minutes, and a cathode current density of 1 A/dm.sup.2. Subsequently, the panel was washed with water. After that, Wood's strike nickel plating was performed (40 C.) under plating conditions shown in Table 2 by using a bath having the following composition.

(15) TABLE-US-00003 Nickel chloride (NiCl.sub.2) 220 g/L 35% hydrochloric acid (HCl) 230 ml/L Boric acid (H.sub.3BO.sub.3) 30 g/L DS-55 (manufactured by 1 ml/L DIPSOL CHEMICALS Co., Ltd.)

(16) After that, the panel was washed with water, and subjected to cationic electrodeposition (25 to 30 m) in a usual manner, by using an electrodeposition paint CFA 590-034 manufactured by PPG. After being washed with water, the panel was baked and dried at 200 C. for 25 minutes. The obtained coated panel was immersed in 5% aqueous sodium chloride at 55 C. for 240 hours, and the coating adhesion was evaluated. Table 2 shows the results.

Comparative Example 1

(17) By using 50 g/L of a degreasing agent HD-37 (manufactured by DIPSOL CHEMICALS Co., Ltd.), an SUS436 panel (50 mm100 mm0.3 mm in thickness) was subjected to cathode electrolysis degreasing under conditions of 50 C., 10 minutes, and a cathode current density of 1 A/dm.sup.2. Subsequently, the panel was washed with water. After that, the panel was subjected to cationic electrodeposition (25 to 30 m) in a usual manner, by using an electrodeposition paint CFA 590-034 manufactured by PPG.

(18) After being washed with water, the panel was baked and dried at 200 C. for 25 minutes. The obtained coated panel was immersed in 5% aqueous sodium chloride at 55 C. for 240 hours, and the coating adhesion was evaluated. Table 2 shows the results.

Comparative Example 2

(19) By using 50 g/L of a degreasing agent HD-37 (manufactured by DIPSOL CHEMICALS Co., Ltd.), a SUS436 panel (50 mm100 mm0.3 mm in thickness) was subjected to cathode electrolysis degreasing under conditions of 50 C., 10 minutes, and a cathode current density of 1 A/dm.sup.2. Subsequently, the panel was washed with water. After that, an acid electrolysis treatment was conducted (60 C.) by using sulfuric acid (120 ml/L) at a cathode current density of 1 A/dm.sup.2 for 4 minutes. After that, the panel was washed with water, and subjected to cationic electrodeposition (25 to 30 m) in a usual manner by using an electrodeposition paint CFA 590-034 manufactured by PPG. After being washed with water, the panel was baked and dried at 200 C. for 25 minutes. The obtained coated panel was immersed in 5% aqueous sodium chloride at 55 C. for 240 hours, and the coating adhesion was evaluated. Table 2 shows the results.

(20) TABLE-US-00004 TABLE 2 Evaluation results of coating adhesion in a case where a ZnNi-plated bolt was fixed to each coated panel by a steel nut. Current Plating Coating adhesion Plating density time Maximum peeling width, conditions (A/dm.sup.2) (second) both sides (mm) Example 6 5 180 5 Comp. Ex. 1 10 or more Comp. Ex. 2 10 or more *The evaluation was made based on the maximum peeling width between both sides (5 mm or less is desirable).

INDUSTRIAL APPLICABILITY

(21) The present invention makes it possible to enhance coating adhesion to a stainless steel FIP, and thereby obtain corrosion resistance which meets the LEV-II regulations. In addition, since the film is chromium-free and has a high corrosion resistance, the film can be used as an environmentally friendly film in wide applications.