NEUTRALIZATION PLANT

Abstract

The invention relates to a neutralization plant (100) comprising at least one reaction chamber (102) having a first feed (114) for an acid-containing product and at least one further feed (116) for a base-containing product, wherein at least one of the feeds (114, 116) comprises at least one valve means (118, 120) for controlling the inflow amount into the reaction chamber (102), wherein the ion controller apparatus (104, 204, 205) comprises at least one evaluation device (106, 206) set up for determining at least one actual ion concentration based on an actual pH of the mixture (122) present in the reaction chamber (102) and wherein the ion controller apparatus (104, 204) comprises at least one ion controller device (108, 208) comprising at least one ion controller (110, 210.1, 210.2, 211) set up for controlling the valve means (118, 120) according to the actual ion concentration and a target ion concentration.

Claims

1. Neutralization plant, comprising: at least one reaction chamber having a first feed for an acid-containing product and at least one further feed for a base-containing product, wherein at least one of the feeds comprises at least one valve means for controlling the inflow amount into the reaction chamber, wherein the ion controller apparatus comprises at least one evaluation device set up for determining at least one actual ion concentration based on an actual pH of the mixture present in the reaction chamber and the ion controller apparatus comprises at least one ion controller device comprising at least one ion controller set up for controlling the valve means according to the actual ion concentration and a target ion concentration.

2. Neutralization plant according to claim 1, wherein the evaluation device comprises a first evaluation module set up for determining a first actual ion concentration based on the actual pH and the evaluation device comprises at least one further evaluation module set up for determining at least one further actual ion concentration based on the actual pH.

3. Neutralization plant according to claim 2, wherein the first actual ion concentration is an actual OH.sup.? ion concentration and/or the further actual ion concentration is an actual H3O.sup.+ ion concentration.

4. Neutralization plant according to claim 2, wherein the ion controller device comprises a first ion controller and at least one further ion controller, the first ion controller is set up to control the valve means according to the first actual ion concentration and the first target ion concentration and the further ion controller is set up to control the valve means according to the further actual ion concentration and the further target ion concentration.

5. Neutralization plant according to claim 4, wherein the first ion controller is an OH.sup.? ion controller and/or the further ion controller is an H3O.sup.+ ion controller.

6. Neutralization plant according to claim 4, wherein the ion controller apparatus comprises at least one ion controller selection device set up for determining an active ion controller from the first ion controller and the further ion controller, wherein only the active ion controller controls the valve means.

7. Neutralization plant according to claim 6, wherein the ion controller selection device is set up to determine the active ion controller based on the control deviation between the first actual ion concentration and the first target ion concentration and/or the control deviation between the further actual ion concentration and the further target ion concentration.

8. Neutralization plant according to claim 6, wherein the ion controller selection device comprises a first controlled variable deviation module set up for determining the magnitude of the control deviation between the first actual ion concentration and the first target ion concentration, the ion controller selection device comprises at least one further controlled variable deviation module set up for determining the magnitude of the control deviation between the further actual ion concentration and the further target ion concentration, the ion controller selection device comprises at least one comparison module set up for comparing the determined magnitudes and the ion controller selection device is set up for determining the active ion controller based on the comparison result.

9. Neutralization plant according to claim 6, wherein the ion controller selection device is set up for switching the inactive ion controller to tracking such that a substantially smooth switchover between the first ion controller and the further ion controller is achieved.

10. Neutralization plant according to claim 1, wherein the ion controller is a PID controller.

11. Neutralization plant according to claim 1, wherein the ion controller apparatus comprises at least one correction device set up for correcting the actual pH and/or the target pH of the mixture present in the reaction chamber.

12. Neutralization plant according to claim 1, wherein a combined ion controller is provided, the combined ion controller is set up to control the valve means according to an actual combined ion concentration and a target combined ion concentration, wherein a first determination module set up for determining the actual combined ion concentration according to the actual OH.sup.? ion concentration and the actual H3O.sup.+ ion concentration is provided and/or wherein a further determination module set up for determining the target combined ion concentration according to the target OH.sup.? ion concentration and the target H3O.sup.+ ion concentration is provided.

13. Computer-implemented method for neutralizing an acid-containing or base-containing mixture in a neutralization plant, comprising at least one reaction chamber comprising the acid-containing or base-containing mixture and at least one feed comprising at least one valve means for controlled feeding of an inflow amount into the reaction chamber, wherein the method comprises: a) providing an actual pH of the mixture present in the reaction chamber and at least one target ion concentration, b) transferring the actual pH to an evaluation device, wherein the evaluation device derives at least one actual ion concentration from the actual pH, c) transferring the actual ion concentration to an ion controller which determines a control deviation from the actual ion concentration from b) to the target ion concentration, d) controlling the feeding of the inflow amount into the reaction chamber by operation of the valve means according to the control deviation from c).

14. Method according to claim 13, wherein in a step a) the actual pH and optionally the target pH from a) is transferred into a correction device which corrects the actual pH and optionally the target pH via one or more influences on the dissociation of water selected from a group comprising acid and base combination, temperature and salt formation and in subsequent step b) the corrected actual pH and target pH are transferred to the evaluation device.

15. Ion controller apparatus for a neutralization plant, comprising: at least one evaluation device set up for determining at least one actual ion concentration from an actual pH of a mixture present in a reaction chamber of the neutralization plant and at least one ion controller device having at least one ion controller set up for controlling at least one valve means of a feed into the reaction chamber of the neutralization plant according to the actual ion concentration and a target ion concentration.

Description

[0039] There are now a great many options for configuring and further developing the inventive neutralization plant, the inventive method and the inventive ion controller apparatus. In this respect, reference should be made on the one hand to the patent claims arranged subordinate to the independent patent claims, on the other hand to the description of exemplary embodiments in conjunction with the drawing. In the drawing:

[0040] FIG. 1 shows an exemplary embodiment of a neutralization plant according to the present invention,

[0041] FIG. 2a shows an exemplary embodiment of an ion controller apparatus according to the present invention,

[0042] FIG. 2b shows a further exemplary embodiment of an ion controller apparatus according to the present invention,

[0043] FIG. 3a shows an exemplary embodiment of a method according to the present invention,

[0044] FIG. 3b shows a further exemplary embodiment of a method according to the present invention and

[0045] FIG. 4 shows a simulation example for neutralization of a hydrochloric acid stream HCl of 550 kg/h with a sodium hydroxide solution stream NaOH as the manipulated variable.

[0046] Hereinbelow, identical reference numerals are used for identical elements.

[0047] FIG. 1 shows a first exemplary embodiment of a neutralization plant 100 according to the present invention. The neutralization plant 100 comprises a reactor chamber 102 and a first exemplary embodiment of an ion controller apparatus 104 according to the present invention in the present case.

[0048] The reaction chamber 102 is set up such that a neutralization process may be performed therein. Via a first feed 114 an acid-containing product may be introduced into the reaction chamber 102, for example. Via a second feed 116 a base-containing product may be introduced into the reaction chamber 102. The inflow of the two products mayas will be explained hereinbelowbe controlled such that the products neutralize one another, i.e. the mixture 122 has a desired (neutral) pH. The mixture 122 may then be passed into the surroundings via an outlet 112. For example the mixture 122 may be introduced into a river, lake or the like without this causing damage to the environment.

[0049] The neutralization process will now be described by way of example for hydrochloric acid which is to be neutralized by addition of sodium hydroxide solution. In particular the mixture 122 in the reactor chamber comprising hydrochloric acid and sodium hydroxide solution is neutralized such that the mixture has a specifiable and desired pH, i.e. a target pH. In an exemplary plant the objective may be to feed the resulting mixture into the environment, for example a river. Here, the target pH may be for example between 7 and 8.5, for example 7.8?0.3.

[0050] The following example reaction may take place in the reactor chamber 102:

H.sub.3O.sub.(aq).sup.++Cl.sub.(aq).sup.?+Na.sub.(aq).sup.++OH.sub.(aq).sup.?.fwdarw.NaCl.sub.(aq)+2H.sub.2O(a)

[0051] In other words hydrochloric acid and sodium hydroxide solution may react to afford sodium chloride dissolved in water, and water.

[0052] The reactor chamber 102 may further comprise at least one measuring device 125. The measuring device 125 is in particular set up for capturing the actual pH of the mixture 122. The measuring device 125 may comprise a pH meter for example.

[0053] Each of the at least two feeds 114, 116 of the present exemplary embodiment may comprise at least one valve means 118, 120. A valve means 118, 120 is set up for controlling the flow amount through a feed 114, 116. In other words the (respective) inflow amount into the reactor chamber 102 can be controlled via the valve means 118, 120. It will be appreciated that only the inflow of one of the at least two products can be controlled. When for example the problem addressed by the neutralization plant is that of neutralizing a byproduct of another process in order that this process need not be interrupted it is generally only the inflow of the manipulated variable, for example of the sodium hydroxide solution, that is controlled by the ion controller apparatus 104. In this case it is sufficient when merely the sodium hydroxide solution feed has a valve means which is controllable by the ion controller apparatus 104.

[0054] It will be appreciated that the reaction chamber is shown only schematically. The reaction chamber may comprise for example a plurality of chambers and/or at least one stirring means to achieve uniform mixing of the introduced substances/products.

[0055] The exemplary ion controller apparatus 104 according to the present invention comprises an evaluation device 106 and an ion controller device 108. The evaluation device 106 may in particular be or comprise a suitable data processing device comprising processor and storage means. The evaluation device 106 is in particular configured for determining at least one actual ion concentration from the actual pH provided and measured via a signal input 124.

[0056] The ion controller device 108 comprises at least one ion controller 110, such as a PID controller 110. Based on the at least one determined actual ion concentration and a target ion concentration provided via a signal input 126 the at least one ion controller 110 can control at least one valve means 118, 120 via a communication link 128. The target ion concentration corresponds in particular to the specifiable target pH.

[0057] FIG. 2a shows an exemplary embodiment of an ion controller apparatus 204 according to the present invention. The ion controller apparatus 204 comprises a correction device 230, an evaluation device 206, an ion controller selection device 232 and an ion controller device 208. Via a first signal input 224 the (current) actual pH of the mixture present in a reaction chamber may be provided to the (optional) correction device 230. Via a further signal input 226 the target pH may be provided to the correction device 230.

[0058] The correction device 230 may comprise data processing means, such as processor and storage means, set up for correcting the actual pH and/or the target pH. In particular a first correction module 230.1 may be provided for correcting the measured and provided actual pH by accounting for known influences (for example acid and base combination, temperature, salt formation) on dissociation of water. By way of example the corrected actual pH without the influence of salt formation may be calculated at a temperature of 25? C. The calculation may be performed as follows:

pH_corrected=pH?dpH.sub.brine?dpH(T),(a2)

wherein for example dpH.sub.brine is a pH correction to correct the influence of brine on pH and dpH(T) is a temperature-dependent pH correction to correct the influence of temperature.

[0059] The target pH may be converted in the same way in a further correction module 230.2.

[0060] It will be appreciated that structurally only one signal input or a multiplicity of signal inputs may also be provided. It will further be appreciated that the target pH may also be deposited and be retrievable in a storage device of the ion controller apparatus 204. It will likewise be appreciated that a correction device 230 may be eschewed when (previously) corrected pH values can be provided. For example a measuring device which already performs an automatic correction may be provided.

[0061] In the present exemplary embodiment the corrected actual pH and the corrected target pH (referred to hereinbelow as actual pH and target pH) are provided to the evaluation device 206. In the present preferred embodiment the evaluation device 206 comprises four evaluation modules 206.1 to 206.4.

[0062] The first evaluation module 206.1 obtains the actual pH as input. The first evaluation module 206.1 is set up for determining an actual OH.sup.? ion concentration from the actual pH. The OH.sup.? ion concentration may in particular be calculated according to the following calculation scheme:

Actual OH.sup.? ion concentration=10.sup.(?14+actual pH)(b)

The target OH.sup.? ion concentration may be calculated correspondingly in evaluation module 206.2:

Target OH.sup.? ion concentration=10.sup.(?14+target pH)(c)

[0063] It will be appreciated that in other embodiments of the present invention the target OH.sup.? ion concentration may be specified instead of a target pH and for example may be stored and may be retrievable in a storage means. In this case a calculation according to formula (c) may be eschewed.

[0064] The third evaluation module 206.3 obtains the actual pH as input. The third evaluation module 206.3 is set up for determining the actual H3O.sup.+ ion concentration from the actual pH. The H3O.sup.+ ion concentration may in particular be calculated according to the following calculation scheme:

Actual H3O.sup.+ ion concentration=10.sup.(?actual pH)(d)

[0065] The target H3O.sup.+ ion concentration may be calculated correspondingly in evaluation module 206.4:

Target H3O.sup.+ ion concentration=10.sup.(?target pH)(e)

[0066] In other words the pH values are antilogarithmized by the calculation schemes. It will be appreciated that in other embodiments of the present invention the target H3O.sup.+ ion concentration may be specified instead of a target pH and for example may be stored and may be retrievable in a storage means. In this case a calculation according to formula (e) may be eschewed.

[0067] As may further be derived from the exemplary embodiment of FIG. 2a the ion controller device 208 preferably comprises two ion controllers 210.1 and 210.2. The first ion controller 210.1, in particular an OH.sup.? ion controller 210.1, obtains the target OH.sup.? ion concentration and the actual OH.sup.? ion concentration as inputs. The second ion controller 210.2, in particular an H3O+ ion controller 210.2, obtains the target H3O.sup.+ ion concentration and the actual H3O.sup.+ ion concentration as inputs. Both ion controllers 210.1 and 210.2 are set up for deriving a manipulated variable from the control deviation.

[0068] As described hereinbelow an ion controller selection device 232 can select which of the two ion controllers 210.1, 210.2 is actually used for controlling the at least one valve means. It has been found in particular that to achieve the exactest possible control and thus adaptation of the pH level of the mixture in the reactor chamber the controller having the larger controlled variable deviation in terms of magnitude is selected from the ion controllers. In other words only one of the ion controllers 210.1, 210.2 is ever active while the other is rendered inactive.

[0069] In particular, three modules 232.1 to 232.3 may be provided in the ion controller selection device 232 to this end. A first controlled variable deviation module 232.1 is set up for determining the control deviation for the OH.sup.? ion concentration. A second controlled variable deviation module 232.2 is set up for determining the control deviation for the H3O.sup.+ ion concentration. This may be effected in particular based on the following calculation scheme:

Control deviation=abs(target ion concentration?actual ion concentration)(f)

[0070] The calculated magnitudes (abs) of the respective control deviations may be provided by the controlled variable deviation modules 232.1, 232.2 to the third module 232.3, in particular a comparison module 232.3. The comparison module 232.3 is set up for comparing the provided magnitudes of the control deviation with one another. One of the ion controllers 210.1, 210.2 may then be activated according to the comparison result. In particular, the ion controller 210.1, 210.2 having the larger control deviation in terms of magnitude is activated.

[0071] The inactive ion controller 210.1, 210.2 may be set to tracking by the ion controller selection device 232. Here, tracking is to be understood as meaning in particular that the inactive ion controller 210.1, 210.2 tracks the manipulated variable of active ion controller 210.1, 210.2. During an activation a smooth switchover (manipulated variable is constant at moment of switchover) between the ion controllers 210.1, 210.2 can be achieved.

[0072] FIG. 2b shows a further exemplary embodiment of an ion controller apparatus 205 according to the present invention. The ion controller apparatus 205 differs from the above-described ion controller apparatus 204 in particular in terms of the blocks described by reference numerals 211 and 233.1, 233.2.

[0073] The actual OH.sup.? ion concentration may from evaluation module 206.1 and the actual H3O.sup.+ ion concentration from evaluation module 206.3 be supplied to the first determination module 233.1 as inputs. The first determination module 233.1 is in particular set up for calculating the actual combined ion concentration according to the following calculation scheme:

When actual H3O.sup.+ ion concentration >actual OH.sup.? ion concentration, actual combined ion concentration=actual H3O.sup.+ ion concentration otherwise actual combined ion concentration=(?1)*actual OH.sup.? ion concentration.

[0074] The target OH.sup.? ion concentration from evaluation module 206.2 and the target H3O.sup.+ ion concentration from evaluation module 206.4 may be supplied to the further determination module 233.2 as inputs. The further determination module 233.2 is in particular set up for calculating the target combined ion concentration according to the following calculation scheme:

When target H3O.sup.+ ion concentration <target OH.sup.? ion concentration, target combined ion concentration=target H3O.sup.+ ion concentration otherwise target combined ion concentration=(?1)*target OH.sup.? ion concentration.

[0075] As is further apparent from the exemplary embodiment of FIG. 2b a (single) combined ion controller 211 is provided and set up accordingly. As inputs the ion controller 211 receives the target combined ion concentration from the determination module 233.1 and the actual combined ion concentration from determination module 233.2. The combined ion controller 211 is set up for deriving a manipulated variable from the control deviation. A valve means may then be controlled with the manipulated variable.

[0076] The mode of operation of the ion controller apparatuses 204 and 211 are more particularly described below by means of FIGS. 3a and 3b and the above-described FIGS. 2a and 2b. FIGS. 3a and 3b show exemplary diagrams of exemplary embodiments of methods according to the present invention.

[0077] In a first step 301 the actual pH of the mixture in a reactor chamber may be measured. In particular the measured actual pH may be provided to the ion controller apparatus 204. In a subsequent (optional) step 302 the measured actual pH may be corrected. In particular, for example the temperature of the mixture may result in the measured actual pH comprising an error. The correction device 230 can calculate a corrected actual pH. Furthermore, a specifiable target pH may also be corrected correspondingly. It will be appreciated that a correction may be eschewed when the ion controller apparatus 204 is already provided with correct pH values. A target pH may optionally also be corrected in the same step.

[0078] Subsequently in step 303 at least one actual ion concentration may be determined at least from the provided correct actual pH (referred to hereinbelow as actual pH). It is preferable when in step 303 an actual H3O.sup.+ ion concentration and an actual OH.sup.? ion concentration are determined from the actual pH from an evaluation device 206. In particular a linearization of the control problem is undertaken by converting the actual pH and optionally the target pH according to an ion concentration. The conversion may be performed to afford either an H3O.sup.+ concentration or an OH.sup.? or COH.sup.? concentration. It is a particular objective of the conversion that the reaction of the auxiliary controlled variables (pH as H3O.sup.+ concentration or pH as OH.sup.? concentration) react to changes in the manipulated variable in the same order of magnitude. This is advantageous in particular for an improved, equivalent switchover between the ion controllers. The correction of the temperature influence and the salt influence may therefore preferably be effected such that the switchover of the ion controllers 210.1, 210.2 is effected (approximately) at the breakthrough point of the titration curve.

[0079] In the next step 304 it may then initially be decided which of the two ion controllers 210.1, 210.2 is activated for controlling. The selection of which of the two ion controllers 210.1, 210.2 is active may be determined by the ion controller selection device 232 in particular by reference to the control deviations. The ion controller 210.1, 210.2 having the larger control deviation in terms of magnitude may be activated. Said controller accordingly controls the process. The inactive ion controller 210.1, 210.2 may be set to tracking.

[0080] In step 305 the activated ion controller 210.1, 210.2 then controls the at least one valve means according to the actual ion concentration provided by the evaluation device 206 and the target ion concentration provided by the evaluation device 206.

[0081] Having regard to FIG. 3b steps 306 and 307 are provided instead of steps 304 and 305. In step 306 in particular the calculation of the actual combined ion concentration and the target combined ion concentration is effected by means of modules 233. 1 and 233.2.

[0082] In step 307 the activated combined ion controller 211 then controls the at least one valve means according to the determined actual combined ion concentration.

[0083] It will be appreciated that the above-described steps may be at least partly performed in parallel. In particular a (virtually) continuous monitoring and controlling of the neutralization process may be effected.

[0084] FIG. 4 shows an exemplary simulation example for neutralization of a hydrochloric acid stream HCl of 550 kg/h with a sodium hydroxide solution stream NaOH as the manipulated variable. The upper graph of FIG. 4 shows the pH breakthrough curve. The middle graph shows the ion concentrations (H3O.sup.+, OH.sup.?). The lower graph shows a combined ion concentration.

[0085] If switchover is effected at the breakthrough point of the titration curve the (linear) system response of the auxiliary controlled variables actual OH.sup.? ion concentration and actual H3O.sup.+ ion concentration to changes in the manipulated variable is identical with the exception of the prefix as is apparent from the middle graph of FIG. 4. With the exception of the effective direction (inverse, direct) both ion controllers may therefore be parameterized in the same way. As is shown by the lower graph the same system response (behaviour of the ion concentration upon alteration of the manipulated variable) can be achieved over both ion concentration ranges.