High-volume fast separation of multi-phase components in fluid suspensions
10071383 ยท 2018-09-11
Assignee
Inventors
Cpc classification
B01D21/283
PERFORMING OPERATIONS; TRANSPORTING
B01D21/28
PERFORMING OPERATIONS; TRANSPORTING
B03B5/00
PERFORMING OPERATIONS; TRANSPORTING
International classification
B03B5/00
PERFORMING OPERATIONS; TRANSPORTING
B01D21/28
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A flow chamber is provided through which is flowed a mixture of a fluid and a particulate. The flow chamber comprises at least one multi-phase water inlet through which multi-phase water enters the flow chamber, a water outlet through which water exits the flow chamber, a solids outlet through which particles having a density at or above a pre-defined threshold exit the flow chamber, and a low density outlet through which particles having a density below the pre-defined threshold exit the flow chamber. Also provided are one or more ultrasonic transducers and one or more reflectors corresponding to each transducer to acoustically filter the fluid and cause particles/fluid to be selectively diverted to one of the outlets. Related apparatus, systems, techniques and articles are also described.
Claims
1. An apparatus comprising: a flow chamber comprising: at least one multi-phase fluid inlet through which multi-phase fluid enters the flow chamber at a high volume flow rate; at least one solids outlet; one or more ultrasonic transducers; and one or more reflectors corresponding to each transducer; each transducer being configured to form a three-dimensional acoustic field at a different ultrasonic frequency and each ultrasonic frequency being configured for a specific range of particulate sizes to, along with a geometry of the flow chamber, selectively separate particulates or droplets having a density at or above a pre-defined threshold from the multi-phase fluid by trapping the particulates or droplets in the three-dimensional acoustic field so that they agglomerate, coalesce, cluster, clump, or grow and increase in size such that they continuously fall out of the acoustic field and exit the flow chamber via the at least one solids outlet.
2. The apparatus of claim 1, wherein the one or more ultrasonic transducers operate at a frequency in a range of 100 kHz to 20 MHz.
3. The apparatus of claim 1, further comprising: a fluid outlet through which fluid exits the flow chamber; a low density outlet through which particulates or droplets having a density below the pre-defined threshold exit the flow chamber.
4. The apparatus of claim 3, wherein the multi-phase fluid inlet is disposed between the low density outlet and the one or more ultrasonic transducers.
5. The apparatus of claim 3, wherein the fluid outlet is disposed between the one or more ultrasonic transducers and the at least one solids outlet.
6. The apparatus of claim 3, wherein the flow chamber is oriented such that the multi-phase fluid is gravity fed from the multi-phase fluid inlet towards the solids outlet.
7. The apparatus of claim 1, wherein the particles are selected from the group consisting of microalgae, yeast, fungi, bacteria, spores, gases or oils, metal oxides, metal particles, clays, dirt, plastics, and any particulate with a nonzero contrast factor.
8. An apparatus comprising: a flow chamber comprising: at least one multi-phase fluid inlet through which multi-phase fluid enters the flow chamber at a high volume flow rate; at least one low density outlet; one or more ultrasonic transducers; and one or more reflectors corresponding to each transducer; each transducer being configured to form a three-dimensional acoustic field at a different ultrasonic frequency and each ultrasonic frequency being configured for a specific range of particulate sizes to, along with a geometry of the flow chamber, selectively separate particulates or droplets having a density below the pre-defined threshold from the multi-phase fluid by trapping the particulates or droplets in the three-dimensional acoustic field so that they agglomerate, coalesce, cluster, clump, or grow and increase in size such that they separate from the acoustic field and exit the flow chamber via the at least one low density outlet.
9. The apparatus of claim 8, wherein the one or more ultrasonic transducers operate at a frequency in a range of 100 kHz to 20 MHz.
10. The apparatus of claim 8, further comprising: a fluid outlet through which fluid exits the flow chamber; and a solids outlet through which particulates or droplets having a density at or above a pre-defined threshold exit the flow chamber.
11. The apparatus of claim 10, wherein the multi-phase fluid inlet is disposed between the at least one low density outlet and the one or more ultrasonic transducers.
12. The apparatus of claim 10, wherein the fluid outlet is disposed between the one or more ultrasonic transducers and the solids outlet.
13. The apparatus of claim 10, wherein the flow chamber is oriented such that the multi-phase fluid is gravity fed from the multi-phase fluid inlet towards the solids outlet.
14. The apparatus of claim 8, wherein the particles are selected from the group consisting of microalgae, yeast, fungi, bacteria, spores, gases or oils, metal oxides, metal particles, clays, dirt, plastics, and any particulate with a nonzero contrast factor.
15. An apparatus comprising: a flow chamber comprising: at least one multi-phase fluid inlet through which multi-phase fluid enters the flow chamber at a high volume flow rate; at least one fluid outlet; one or more ultrasonic transducers; and one or more reflectors corresponding to each transducer; each transducer being configured to form a three-dimensional acoustic field at a different ultrasonic frequency and each ultrasonic frequency being configured for a specific range of particulate sizes to, along with a geometry of the flow chamber, selectively separate particulates or droplets from the multi-phase fluid by trapping the particulates or droplets in the three-dimensional acoustic field, the remaining multi-phase fluid exiting the flow chamber via the at least one fluid outlet.
16. The apparatus of claim 15, further comprising: a solids outlet through which particulates or droplets having a density at or above a pre-defined threshold exit the flow chamber; and a low density outlet through which particulates or droplets having a density below the pre-defined threshold exit the flow chamber.
17. The apparatus of claim 16, wherein the flow chamber is oriented such that the multi-phase fluid is gravity fed from the multi-phase fluid inlet towards the solids outlet.
18. The apparatus of claim 15, wherein the particles are selected from the group consisting of microalgae, yeast, fungi, bacteria, spores, gases or oils, metal oxides, metal particles, clays, dirt, plastics, and any particulate with a nonzero contrast factor.
19. An apparatus comprising: a flow chamber comprising: at least one multi-phase fluid inlet through which multi-phase fluid enters the flow chamber at a high volume flow rate; at least one outlet; one or more ultrasonic transducers; and one or more reflectors corresponding to each transducer; each transducer being configured to form a three-dimensional acoustic field at a different ultrasonic frequency and each ultrasonic frequency being configured for a specific range of particulate sizes to, along with a geometry of the flow chamber, selectively separate particulates or droplets from the multi-phase fluid by trapping the particulates or droplets in the three-dimensional acoustic field so that they agglomerate, coalesce, cluster, clump, or grow and increase in size such that they continuously separate from the acoustic field and exit the flow chamber via the at least one solids outlet.
20. A method of separating particulate and/or droplets from a multi-phase fluid, comprising: flowing the multi-phase fluid through a flow chamber at a flow rate of up to 120 mL/min; and trapping particulates or droplets in a three-dimensional acoustic field against the flow of the multi-phase fluid within the flow chamber, each three-dimensional acoustic field being maintained at a different ultrasonic frequency, and each ultrasonic frequency being configured for a specific range of particulate or droplet sizes, such that the particulates or droplets agglomerate, coalesce, cluster, clump, or grow and increase in size such that they continuously fall out of the acoustic field due to gravity or rise out due to buoyancy forces and exit the flow chamber; wherein the flow chamber comprises: at least one multi-phase fluid inlet through which multi-phase fluid enters the flow chamber; at least one outlet through which the particulate or droplet clusters exit the flow chamber; one or more ultrasonic transducers configured to form the three-dimensional acoustic field; and one or more reflectors corresponding to each transducer.
Description
DESCRIPTION OF DRAWINGS
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DETAILED DESCRIPTION
(15) The current subject matter utilizes acoustophoresis, a low-power, no-pressure-drop, no-clog, solid-state approach to particle removal from fluid dispersions: i.e., it is used to achieve separations that are more typically performed with porous filters and centrifuges, but it has none of the disadvantages of these systems. For example, the diagram 100 of
(16) The acoustic radiation force (F.sub.ac) acts on the secondary-phase particles (or fluid droplets), pushing them to the nodes (or antinodes) of the acoustic standing wave. The magnitude of the force depends on the particle density and compressibility relative to the fluid medium, and increases with the particle volume. The diagram 100 of
(17) The current subject matter is advantageous in that it uses acoustophoresis for separations in extremely high volumes and in flowing systems with very high flow rates. Separations have been done for micron-size particles, for which the acoustophoretic force is quite small. For example, B. Lipkens, J. Dionne, A. Trask, B. Szczur, A. Stevens, E. Rietman, Separation of micron-sized particles in macro-scale cavities by ultrasonic standing waves, Presented at the International Congress on Ultrasonics, Santiago, Jan. 11-17, 2009; and B. Lipkens, J. Dionne, M. Costolo, A. Stevens, and E. Rietman, Separation of bacterial spores from flowing water in macro-scale cavities by ultrasonic standing waves, (Arxiv) June 2010, the contents of both papers are hereby fully incorporated by reference) show that Bacillus cereus bacterial spores (a model for anthrax) have been trapped at 15% efficiency in an acoustophoretic cavity embedded in a flow system that can process drinking water at rates up to 120 mL/minute (1 cm/second linear flow). The concentration ratio has been as high as 1000 in a single-pass, small-scale prototype acoustocollector. The techniques described in this paper will scale up to higher flow rates or larger flow channel, which has been proven in a 66 system and processing to 12 in dimension.
(18) The current subject matter allows for the simultaneous agglomeration of suspended solids such as microorganisms and dirt (metal oxides) and oil droplets. The ability to translate and concentrate these secondary phases is known as acoustophoresis. Described herein is an improved flow chamber with two different ultrasonic transducer arrangements. Diagrams 200, 300 respectively of
(19) With reference to
(20) Several examples are shown in the photographs in
(21) Physics of Acoustophoresis.
(22) Acoustophoresis is the separation of a second phase (or phases) from a host fluid using sound pressure to create the driving force. An ultrasonic transducer operating at a fixed frequency f (Hz) is used to set up an acoustic standing wave in a fluid-filled cavity. A one dimensional standing wave is characterized by a local pressure p that is a function of position (x) and time (t),
p(x,t)=P cos(kx)cos(t),(1)
(23) where P is the amplitude of the acoustic pressure; k is the wavenumber (=2/, where is the wavelength), and =2f, where is the angular frequency. The pressure of the acoustic wave produces an acoustic radiation force F.sub.ac on secondary-phase elements according to
(24)
(25) where R.sub.p is the particle radius, .sub.f is the density of the fluid medium, c.sub.f is the speed of sound in the fluid, and X is the acoustic contrast factor, defined by
(26)
(27) where is the ratio of the particle density to fluid density and is the ratio of the speed of sound in the particle to the sound speed in the fluid. The acoustic radiation force acts in the direction of the acoustic field. The acoustic radiation force is proportional to the product of acoustic pressure and acoustic pressure gradient. An inspection of the acoustic radiation force shows that it is proportional to the particle volume, frequency (or wavenumber), the acoustic energy density (or the square of the acoustic pressure amplitude), and the acoustic contrast factor. Note also that the spatial dependency has twice the periodicity of the acoustic field. The acoustic radiation force is thus a function of two mechanical properties, namely density and compressibility.
(28) TABLE-US-00001 TABLE 1 Properties of water and 4 selected secondary phases. c (speed of sound X (density) in the medium) (dimen- (dimen- Material (kg/m.sup.3) (m/s) sionless) sionless) Water 1000 1509 Hexanes 720 1303 0.72 0.402 Blood Cells 1125 1900 1.125 0.185 Bacterial Spores 1100 1900 1.1 0.173 Magnetic beads 2000 1971 2.0 0.436
(29) For three dimensional acoustic fields, a more general approach for calculating the acoustic radiation force is needed. Gor'kov's (1962) formulation can be used for this (see L. P. Gor'kov, On the forces acting on a small particle in an acoustical field in an ideal fluid, Sov. Phys. Dokl., vol. 6, pp. 773-775, 1962). Gor'kov developed an expression for the acoustic radiation force F.sub.ac applicable to any sound field. The primary acoustic radiation force is defined as the gradient of a field potential U, given by
F.sub.ac=(U),(4)
(30) where the field potential U is defined as
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(32) and f.sub.1 and f.sub.2 are the monopole and dipole contributions defined by
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(34) where p(x,y,z,t) is the acoustic pressure, v(x,y,z,t) is the fluid particle velocity, and < > denote time averages. V.sub.o is the volume of the particle.
(35) The diagram 100 of
(36) Simulations regarding the current subject matter were run by plotting the following equation:
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(38) Where n is the number density of the suspended particulate, f is the frequency, c is the speed of sound, E.sub.ac is the energy density of the acoustic wave, R is the particle radius, X is the contrast factor, t is time, m is the dynamic viscosity of the fluid, and x is position in the standing wave. The equation describes the kinetics of the particles in the standing wave as a result of the action of the drag force and acoustic radiation force. This equation is derived in the paper by Feke et al.
(39) The diagrams of
(40) Diagram 500 of
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(42) As described above, two approaches to concentrating the particles through acoustic standing wave agglomeration (or coalescence). (1) The first approach as illustrated in
(43) The first implementation is shown in
(44) With the second approach, as shown in
(45) While this specification contains many specifics, these should not be construed as limitations on the scope of what is claimed or of what may be claimed, but rather as descriptions of features specific to particular variations. Certain features that are described in this specification in the context of separate variations can also be implemented in combination in a single variation. Conversely, various features that are described in the context of a single variation can also be implemented in multiple variations separately or in any suitable sub-combination. Moreover, although features may be described above as acting in certain combinations and even initially claimed as such, one or more features from a claimed combination can in some cases be excised from the combination, and the claimed combination may be directed to a sub-combination or a variation of a sub-combination. Similarly, while operations are depicted in the drawings in a particular order, this should not be understood as requiring that such operations be performed in the particular order shown or in sequential order, or that all illustrated operations be performed, to achieve desirable results. Only a few examples and implementations are disclosed. Variations, modifications and enhancements to the described examples and implementations and other implementations may be made based on what is disclosed.