Nanowire Laser Structure and Fabrication Method
20180254611 ยท 2018-09-06
Assignee
Inventors
- Benedikt MAYER (Muenchen, DE)
- Gregor Koblmueller (Regensburg, DE)
- Jonathan Finley (Aschheim, DE)
- Johannes KLICPERA (Muenchen, DE)
- Gerhard Abstreiter (Hallbergmoos, DE)
Cpc classification
H01S5/341
ELECTRICITY
H01S5/026
ELECTRICITY
H01S3/14
ELECTRICITY
H01S5/305
ELECTRICITY
H01S5/0085
ELECTRICITY
H01S3/107
ELECTRICITY
H01S5/0092
ELECTRICITY
H01S5/0218
ELECTRICITY
H01S3/108
ELECTRICITY
H01S5/0243
ELECTRICITY
International classification
H01S5/34
ELECTRICITY
H01S5/30
ELECTRICITY
H01S5/026
ELECTRICITY
H01S5/183
ELECTRICITY
Abstract
A core-shell nanowire laser structure comprises a substrate (12), an elongated support element (14) extending from the substrate, the support element having a first diameter, and an elongated body element (16) extending on and/or around the support element, the body element having a second diameter at least two times larger than the first diameter, wherein the body element is spaced apart from the substrate.
Claims
1. A nanowire laser structure, comprising: a substrate; an elongated support element extending from said substrate, said support element having a first diameter; and an elongated body element extending on and/or around said support element, said body element having a second diameter at least two times larger than said first diameter; wherein said body element is spaced apart from said substrate.
2. The nanowire laser structure according to claim 1, further comprising a first reflective layer between said body element and said substrate.
3. The nanowire laser structure according to claim 2, wherein said first reflective layer comprises a distributed Bragg reflector and/or a high contrast grating.
4. The nanowire laser structure according to claim 1, further comprising a pn junction or a pin junction.
5. The nanowire laser structure according to claim 1, wherein said nanowire laser structure is adapted to emit a laser signal at a wavelength ?, wherein said first diameter of said support element is smaller than ?/(2n), wherein n denotes an index of refraction of said support element.
6. The nanowire laser structure according to claim 2, further comprising a second reflective layer formed above said body element on a side of said body element facing away from said substrate.
7. The nanowire laser structure according to claim 1, wherein said substrate comprises a waveguide.
8. The nanowire laser structure according to claim 1, further comprising: an interferometer element optically coupled to said body element, wherein said interferometer element comprises a first laser signal path and a second laser signal path that together form a closed loop; an output path coupled to said first laser signal path and said second laser signal path; and a gate element located in said second laser signal path, wherein said gate element is adapted to selectively change a refractive index of said second laser signal path.
9. The nanowire laser structure according to claim 8, further comprising a feedback path coupling said output path to said gate element.
10. A laser array comprising: a plurality of nanowire laser structures, each nanowire laser structure of said plurality of nanowire laser structures comprising an elongated support element extending from a substrate, said support element having a first diameter; and an elongated body element extending on and/or around said support element, said body element having a second diameter at least two times larger than said first diameter; wherein said body element is spaced apart from said substrate; and wherein said substrate of each nanowire laser structure is a common substrate of said plurality of nanowire laser structures.
11. The laser array according to claim 10, further comprising at least one cooling channel for a cooling medium, said cooling channel extending between adjacent nanowire laser structures of said plurality of nanowire laser structures.
12. A method for forming a nanowire laser structure, comprising: forming a first reflective layer on a substrate layer; forming a hole in said first reflective layer, said hole extending to said substrate layer; and growing a nanowire laser structure in said hole; wherein growing said nanowire laser structure comprises growing a support element in said hole through said first reflective layer at a first diameter, and extending said support element above said first reflective layer, and growing a body element around at least a portion of said support element that extends above said first reflective layer said body element having a second diameter at least two times larger than said first diameter.
13. The method according to claim 12, wherein said forming said hole comprises a step of forming a first hole in said first reflective layer by means of an anisotropic reactive ion etching, wherein said first hole terminates within said first reflective layer, and afterwards extending said first hole to said substrate layer by chemical etching.
14. The method according to claim 12, further comprising doping said support element and/or said body element to form a pn junction or a pin junction.
15. (canceled)
16. The nanowire laser structure according to claim 7, wherein said support element extends from said waveguide.
17. The method according to claim 13, wherein the chemical etching is hydrofluoric acid etching.
Description
DETAILED DESCRIPTION OF EXAMPLE EMBODIMENTS
[0118] The features and numerous advantages of the nanowire laser structure and fabrication method will best become apparent from a detailed description of example embodiments with reference to the accompanying drawings, in which:
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[0132]
[0133]
[0134]
[0135] In the configuration of
[0136] In an example, the support element 14 and the body element 16 are both formed from a III-V semiconductor, such as GaAs, InGaAs, InP, and/or GaP. However, the choice of the material depends on the desired application, and in other configurations a II-VI semiconductor and/or a group-III nitride, in particular GaN and/or AlGaN may likewise be employed.
[0137] Both the support element 14 and the body element 16 may be cylindrical or hexagonal or triangular. However, depending on the materials used in the fabrication process, other shapes may likewise be employed.
[0138] As can be taken from
[0139] The dimensions of the nanowire laser structure 10 are chosen in accordance with the laser wavelength of the laser signal that the nanowire laser structure 10 is supposed to emit. For instance, a diameter d.sub.1 of the support element 14 may be chosen smaller than ?/(2.Math.n), when n denotes an index of refraction of the support element 14. A diameter d.sub.1<?/(2.Math.n) prevents laser wavelengths from forming and resonating within the support element 14, and hence prevents direct contact or coupling of these laser wavelengths with the underlying substrate 12 on which the support element 14 is formed.
[0140] An outer diameter d.sub.2 of the body element 16 may be at least two times larger than the diameter d.sub.1 of the support element 14, and in particular may amount to at least ?/n, wherein n denotes an index of refraction of the body element 16. Laser wavelengths may foist and resonate along the lengthwise direction l of the body element 16. The body element 16 thus serves as a laser cavity.
[0141] Depending on the laser wavelength, the diameter d.sub.1 of the support element 14 may be in the range between 80 nm and 300 nm. Correspondingly, the diameter d.sub.2 of the body element 16 may amount to at least 160 nm, in particular at least 400 nm or at least 600 nm.
[0142] The first reflective layer 18 serves to reflect the laser modes at the lower end of the body element 16, and therefore provides resonant recirculation of the optical modes for lasing of the nanowire structure 10. The inventors found that the first reflective layer 18 enhances the modal reflectivity at the nanowire interface and enables reflectivities of 0.9 and beyond, two to three orders of magnitude higher than what could be obtained by reflecting the laser modes directly off the silicon substrate 12. The small nanowire waveguide (body element 16) provides low order waveguiding with beta factors of 0.2 and beyond. Even though the nanowire structure 10 is anchored directly to the silicon substrate 12 via the support element 14, it hence maintains excellent wave-guiding properties with reflectivities larger than 90% due to the separation of the body element 16 from the substrate 12 by means of the first reflective layer 18.
[0143] Preferably, a thickness t of the first reflective layer 18 may be chosen as an integer multiple of ?/(2.Math.n), wherein n denotes an index of refraction of the first reflective layer 18. This thickness allows reflection both on an upper surface side of the first reflective layer 18 at the interface with the body element 16 and on a lower surface side of the first reflective layer 18 at the interface with the underlying substrate 12, and thereby further enhances the reflective properties.
[0144] Depending on the desired laser wavelength, the thickness t of the first reflective layer 18 may be chosen in the range between 100 nm and 800 nm.
[0145] A length l of the body element 16 may amount to at least 1 ?m. With a cavity length of at least 1 ?m, the inventors found that losses may be efficiently suppressed. If the reflectivity of the first reflective layer 18 is particularly good, even shorter body elements may be used.
[0146]
[0147] A metallic contact layer 20 may double as a second reflective layer at the top of the body element 16, and may thereby further enhance the confinement, and thus further lower the lasing threshold.
[0148] However, a separate second reflective layer 22 may likewise be formed on an upper side of the body element 16, as schematically shown in the cross-section of
[0149] In the configurations of
[0150] The first reflective layer 18 not only serves to provide optical feedback, but also doubles as an isolation layer between the substrate 12 and the body element 16.
[0151] In the configurations of
[0152] However, a lateral pn-junction may also be employed, as shown in
[0153] The n-doped upper portion may be connected to the cathode via the electrical contact layer 20, whereas the p-doped lower portion may be connected to the anode via the substrate 12 and support element 14, allowing current to be injected into the nanowire laser structure 10 at the lateral pn-junction.
[0154] As described above, in a nanowire laser structure according to the invention, the diameter d.sub.2 of the body element may define the optical mode that is supported by the nanowire waveguide. The length l of the body element 16 in the nanowire material may define the laser wavelength which resonates with the desired optical mode. In an example, the diameter d.sub.2 of the body element 16 is chosen no larger than two times the laser wavelength ?/n in the body element 16 with index of refraction n. Typically, the diameter d.sub.2 of the body element 16 can be chosen in the range of 100 to 800 nm, depending on the laser wavelength. The first reflective layer 18 may be chosen at a thickness t in the range of 50 to 400 nm, and likewise depends on the optical mode and on the laser wavelength ?.
[0155] The electrical properties of the nanowire laser structures 10, 10, the electrical contacts and doping profiles can be adjusted and tailored to the desired optical laser modes. In order to achieve an efficient population inversion in the nanowire cavity, the carrier recombination can be spatially matched with the optical mode along the entire nanowire so to minimize residual parts without radiative recombination that could act as absorber regions and therefore contribute to losses. Given that electrons typically have a much higher mobility than holes, electrons carry most of the electric current along the nanowire. As a result, most radiative recombination takes place at the anode.
[0156] The inventors found that this effect may be counterbalanced with a graded doping structure along the support element 14. For instance, an n-type support element 14 may be strongly doped in the vicinity of the cathode, with a doping concentration in the range of 10.sup.20/cm.sup.3, and gradually more lightly doped towards the anode, reaching a doping concentration in the range of 10.sup.17/cm.sup.3 in the vicinity of the anode. The graded doping may reduce the electron current to the anode end of the nanowire, and may therefore lead to a more homogeneous recombination, and hence a more efficient nanowire laser structure with superior optical properties.
[0157] A high electron mobility may also lead to radiative recombination spreading away from the center of the nanowire laser structure, which may result in a suboptimal overlap with the electromagnetic field of the fundamental optical mode. This effect can be countered with the use of two different dopings in the body element 16. A thin, highly p-doped layer in an inner part of the body element 16, adjacent to the support element 14, may trap electrons and radiative recombination at the center of the nanowire laser structure. For improved electrical conductivity, the outer area of the body element 16 may also be p-doped, but to a lesser degree.
[0158]
[0159] As illustrated in
[0160] As can be taken from
[0161] All other components of the nanowire laser structure 10 largely correspond to those described in detail above with reference to
[0162] Configurations with a n-doped support element 14 and a p-doped body element 16 have been described above with reference to
[0163] In an exemplary inverse configuration, the p-doped support element 14 may be uniformly doped, and a doping concentration of the n-doped body element 16 may decrease gradually from the cathode end to the anode end of the nanowire structure. A doping of the substrate 12 may also be inversed.
[0164]
[0165]
[0166] Given that the nanowire laser shown in
[0167] The coupling to the underlying waveguide layer 34 can be further enhanced by placing a scattering object 36 in the waveguide layer 34 at a position underneath the body element 16, as schematically illustrated in
[0168] An example in which a grating 38 serves to enhance the coupling between the body element 16 and the waveguide layer 34 is shown in
[0169] In the examples described above, the support element 14 and body element 16 extend along a normal direction of an upper surface of the substrate 12. This configuration may result from the growth of the support element 14 on a silicon (111) surface. However, other growth substrates such as a silicon (100) surface can be used to grow tilted nanowires, as schematically shown in
[0170] Tilted nanowires as depicted in
[0171] In some embodiments, the waveguide layer 34 may be formed of a semiconductor material, such as Si and the electrical connections for driving the nanowire laser structure may be applied directly to the waveguide layer 34, thereby establishing an electrical contact with the support element 14 extending from the waveguide layer 34.
[0172] In alternative configurations, the support element 14 may extend through the waveguide layer 34 to the underlying substrate 12, and the electrical connections may be provided at the substrate 12.
[0173] In the configurations described above with
[0174] Embodiments have so far been described with reference to a single nanowire grown on a substrate. However, it is a particular advantage of the present invention that the structure and fabrication techniques are highly scalable and can be employed to provide large arrays of nanowire laser structures.
[0175]
[0176] As can be taken from
[0177] The support elements 44.sub.1 to 44.sub.4 are electrically connected to the cathode via the common substrate 12. Moreover,
[0178] As can be further taken from
[0179] Each of the nanowire laser structures 42.sub.1 to 42.sub.4 may be driven to emit laser light at respective wavelengths ?.sub.1 to ?.sub.4. In some configurations, the wavelengths ?.sub.1 to ?.sub.4 may coincide, whereas in other configurations, different nanowire laser structures 42.sub.1 to 42.sub.4 of the nanowire laser array 40 may be adapted and driven to emit different wavelengths ?.sub.1 to ?.sub.4. The nanowire laser array 40 may hence be employed as a semi-coherent light source on the nanoscale, enabling large-scale nanowire laser devices that could replace today's semiconductor lasers and have the potential of being several orders of magnitude more energy and cost efficient.
[0180] The constructive and destructive interference between the individual nanowire laser structures 42.sub.1 to 42.sub.4 of the nanowire laser array 40 determines the far field emission profile of the nanowire laser array 40, and may be adapted and tailored by carefully choosing the separations d between adjacent nanowire laser structures and their relative positions on the common growth substrate 12. Such a nanowire laser array 40 could serve as a very efficient light projector.
[0181] Assuming a pitch d=50 nm between adjacent nanowire laser structures 42.sub.1 to 42.sub.4, the monolithic integration of 400 million nanowire lasers on a single 1 cm?1 cm piece of silicon wafer could be fabricating requiring only a single growth. From their measurements, the inventors estimate that a single nanowire laser may emit at least 20 nW, and hence the 1 cm?1 cm piece of nanowire lasers could therefore easily emit in the range 8 W of coherent optical power.
[0182] In order to additionally tailor the emission profile of the array 40, a lens configuration may be employed, such as a microlens array or a solid immersion lens 52 placed on top of a plurality of top reflection layers 50.sub.1 to 50.sub.4, as schematically illustrated in
[0183] Compared to an array of LED diodes, nanowire laser structures emit point-like, and hence can reach a significantly higher luminosity. In order to form the far field with the help of a micro lens array, techniques known from LEDs can be employed such as those described in M. Sieler et al., Design and realization of an ultra-slim array projector, Microopics Conference (MOC), 2011 17th, 1-4. IEEE, 2011, and Ultraslim fixed pattern projectors with inherent homogenization of illumination, Applied optics 51, Nr. 1 (2012): 64-74.
[0184] Nanowire laser arrays on silicon as described with reference to
[0185] In the examples described above with reference to
[0186] In some applications, the nanowire laser structures 10, 10, 10 or the nanowire laser array 40 may be optically coupled to an interferometer element, such as for ultrafast pulse emission, as will now be described with reference to
[0187] In the schematic illustration of
[0188] As can be further taken from
[0189] Assuming that the nanowire laser structure 10 emits light with a wavelength ? whereas the optical gate 64 is only sensitive to light with a wavelength at or around ?/2 and is initially deactivated, a nonlinear effect may cause a phase shift in the optical gate 64 as soon as an ignition pulse of wavelength ?/2 hits the gate 64. This will allow constructive interference at the output path 60 of the interferometer element 56, and all the energy accumulated in the interferometer element 56 can be emitted in the form of a laser pulse within a time duration that is given by L/c, wherein L is the optical path length of the interferometer element 56 and c denotes the speed of light. Assuming L=3 ?m, this results in a 10 fs pulse.
[0190] Ultrafast light pulses of this type can be employed to generate frequency combs for applications in high precision spectroscopy, optical metrology, atomic clocks, or novel GPS technology. Furthermore, if generated with high repetition rates, ultrafast laser pulses could boost the speed of optical data communication.
[0191]
[0192] The components of the interferometer element 56 generally correspond to those described above with reference to
[0193] Example techniques for fabricating the nanowire laser structure and laser array described above will now be explained in greater detail with reference to
[0194] Site-selective growth of nanowire laser structures on semiconductor materials, in particular silicon, is of great interest for future photonic devices. To achieve sufficient reflectivities for lasing operations, thin holes to house the support elements need to be fabricated in the first reflective layer 18. As an example, holes of a diameter of approximately 80 nm may need to be fabricated into an approximately 200 nm thick SiO.sub.2 layer. The challenges in this process result from the finite resistivity of the resist that is easily etched faster than the underlying first reflective layer 18.
[0195] With reference to
[0196]
[0197] The ZEP resist layer on top of the SiO.sub.2 reflective layer 18 may be formed at a thickness of approximately 300 to 400 nm. Due to its high etching resistance and good resolution, this type of resist is highly suitable for the intense etching process required for deep hole etching in SiO.sub.2, and has been found to perform better than conventional PMMA typically used in e-beam lithography.
[0198] After spin coating and baking, sub-100 nanometer wide holes 70 are exposed in the ZEP resist layer 72 using standard electron beam lithography with a dose calibrated for good lithographic quality. The corresponding configuration is shown in
[0199] For ease of presentation, the technique is described for holes with circular openings. However, holes with a rectangular or hexagonal cross-section may likewise be formed.
[0200] If an array of nanowire lasers shall be formed on the same substrate 12, such as a nanowire laser array 40 described above with reference to
[0201] The structure can be developed in a ZED-N50 solution to remove the resist at the e-beam exposed positions only and thereby introduce a hole-profile into the ZEP layer. By using an anisotropic reactive ion etching (RIE) process with fluoric gas C.sub.4F.sub.8, this profile can then be transferred to the SiO.sub.2 reflective layer 18 underneath. The inventors found it advantageous not to complete the RIE etching process all the way down to the surface of the substrate 12, since this might cause damage and might hinder the nucleation and growth of nanowire structures in the desired quality. The RIB etching process may be completed in such a way that the bottom of the holes 70 terminate approximately 5 to 10 nm above the upper surface of the substrate 12, as schematically illustrated in
[0202] The process parameters for the RIE etching process can be optimized based on the respective RIE process chamber design. For instance, good results could be obtained with a temperature of 15? C., a pressure of approximately 2?10.sup.?5 mbar, an inductive coupled plasma (ICP) forward power of approximately 400 W, a RF generator forward power of approximately 100 W, a helium backing of approximately 10 sccm and a DC bias voltage of approximately 344 V.
[0203] The inventors found that the resistivity of the ZEP resist layer 72 has a remarkable dependence on the duration of the etching step, and generally increases with decreasing etching time per etching step. Good results could be obtained by dividing the total hole etching into six subsequent steps with the following sequence: 4?15 seconds, 1?10 seconds, and 1?7 seconds.
[0204] The resist may then be removed by a lift-off process in a ZDMAC solution for approximately five minutes during a supersonic treatment.
[0205] The remaining 5 to 10 nm of SiO.sub.2 at the bottom of the holes 70 may subsequently be removed by means of a hydrofluoric acid (HF) etching process with an etching rate that can be carefully adjusted based on calibration runs. Good results could be obtained with very low etching rates in the range of 0.5 to 3.5 nm/s so as to be able to terminate the wet chemical etching step right at the interface of the silicon substrate 12, as illustrated in
[0206] In a short oxygen plasma etching step and subsequent solving cleaning that may involve acetone and/or isopropanol, all residual organic substances are removed, and the sample is ready for growth of bottom-up nanowire laser structures from the holes 70. A plurality of epitaxial techniques can be employed in the growth of the nanowire laser structure 10, comprising molecular beam epitaxy (MBE) or metal-organic chemical vapor deposition (MOCVD).
[0207] The inventors found that good results can be achieved by refraining from using a gold metal catalyst, contrary to many conventional nanowire growth techniques. The reason is threefold: (i) Gold is not readily CMOS compatible if integration on existing CMOS platforms is desired; (ii) gold is reactive and may etch the underlying Si substrate 12, causing undesired defects; and (iii) the presence of a gold catalyst may inhibit the formation of radial growth of the nanowire laser cavity. The inventors obtained better results with a self-catalyzed growth process or a completely catalyst-free growth mode.
[0208] In the sequel, a growth process for a nanowire laser structure 10 made from group III/group V semiconductors is described, but one skilled in the art will understand that similar techniques may be employed to fabricate nanowire laser structures from other semiconductor materials. In the self-catalyzed growth process, the group-III element may form a metallic droplet seed inside the hole 70 during the nucleation step. This seed droplet can comprise Ga or In, depending on whether GaAs or InGaAs-based nanowire lasers are desired. The growth temperature can be chosen so as to promote formation of the metal droplet only inside the hole 70, and not on the dielectric SiO.sub.2 layer 18. Good growth selectivity can be achieved by using high substrate temperatures in the range of 500? C. and beyond. Once a droplet has formed inside the hole 70, the nanowire growth will then be promoted in the vertical direction due to the preferential nanowire growth orientation along the (111) crystallographic plane on (111) silicon. The nanowire may first be grown to a length of 1 ?m or larger, such as 5 to 20 ?m, to define the length of the nanowire laser cavity. In this case, a typical diameter of the support element 14 may be in the range of approximately 20 to 150 nm, depending on the growth conditions, such as III-V flux/pressure and temperature. This diameter range is typically insufficient to allow for an effective mode confinement. However, after growth of the inner nanowire support element 14, the growth process may be changed from axial to lateral growth, so as to widen the nanowire structure and thereby form the body element 16. This may be achieved by lowering the growth temperature to exploit the facet-dependent growth rate differences and induce radial growth along the {110} or {112} stable planes of III-V compound semiconductor nanowires. Even in the phase with preferred lateral growth, some limited axial growth on the upper end of the nanowire structure may still take place, which can be helpful to ensure that the body element 16 surrounds and covers the support element 14 also at the upper end. Depending on the desired optical confinement of the fundamental optical modes, the radial growth may result in a diameter of the body element 16 in the range of 200 nm or larger, for instance 300 to 600 nm for GaAs and InGaAs-based nanowires. During this radial growth step, the group-V pressure/flux may be increased so that growth takes place under group-V rich conditions. This has the additional benefit that the V-rich growth environment consumes the self-catalyzed metal droplet at the nanowire growth front, and therefore leads to a specular mirror-like end facet.
[0209] The result is a nanowire laser array 40 with a plurality of nanowire laser structures 42.sub.1 to 42.sub.4 in which the respective body elements 16 extend laterally only above the SiO.sub.2 reflective layer 18, with a funnel-like support element 14 at the base that connects the respective body element 16 to the underlying substrate 12. As explained above, the nanowire laser structures 42.sub.1 to 42.sub.4 are anchored to the silicon substrate 12 while simultaneously maintaining their excellent waveguide properties with confinement factors larger than 90% above the dielectric reflective layer 18.
[0210] In a variant, the growth may proceed also without the use of self-catalyzed droplets. In this case, the nanowire laser cavity dimension may be given by the competition between the facet-dependent differences in growth rates. Under good conditions, growth of the nanowire may take place simultaneously in the vertical and radial direction. This holds the benefit that the cavity can be grown in a single growth step, as opposed to the self-catalyzed growth procedure described above with reference to
[0211] The basic steps of a method for forming a nanowire laser structure are summarized schematically in the flow diagram of
[0212] In a first step S10, the first reflective layer 18 is formed on the substrate layer 12. In a second step S12, a hole 70 is formed in the first reflective layer 18, wherein the hole 70 extends to the substrate layer 12. In a third step S14, a nanowire laser structure 10/42 is grown in the hole 70, wherein growing the nanowire laser structure 10/42 comprises growing a support element 14/44 in the hole 70 through the first reflective layer 18 at a first diameter d.sub.1, and extending the support element 14/44 above the first reflective layer 18, and growing a body element 16/46 around at least a portion of the support element 14/44 that extends above the first reflective layer 18, wherein the body element 16/44 has a second diameter d.sub.2 at least twice the first diameter d.sub.1.
[0213] In case the substrate 12 comprises a waveguide layer 34, such as described above with reference to
[0214] Another example technique for realizing deep nano-apertures in a dielectric layer such as SiO.sub.2 is a sacrificial nanowire growth technique that will now be described schematically with reference to
[0215] As illustrated in
[0216] Subsequent reactive ion etching (RIE) and/or hydrofluoric acid (HF) etching may then be employed to extend the holes 78 down through the dielectric mask layer 74 and to the upper surface of the silicon substrate 12. The resulting structure (after removal of the resist layer 76) is shown in
[0217] As illustrated in
[0218] Once the sacrificial nanowire structures 80 have been grown, in a subsequent step a thick dielectric layer 82 may be grown on the dielectric mask layer 74 and the sacrificial nanowire structures 80, as schematically illustrated in
[0219] As schematically shown in
[0220] In a subsequent step, the parasitic deposits of the dielectric layer 82 on the sacrificial nanowire structures 80 may be etched, such as by employing buffered hydrofluoric acid (HF). The inventors found that dipping the sample very shortly into the buffered HF solution is sufficient to remove the thin parasitic layer of the dielectric 82 from the sacrificial nanowire structures 80. The resulting sample is shown in
[0221] The sample may now be transferred to an annealing device capable of providing temperatures in the range of approximately 800? C. At these temperatures, the sacrificial nanowire structures 80 dissolve thermally. For instance, thermal decomposition of GaAs sacrificial nanowires 80 in high vacuum of 10.sup.?6 to 10.sup.?9 Torr requires annealing temperatures in the range of 650 to 750? C. The inventors found it helpful to monitor the evaporating species during the annealing procedure, such as by mass spectrometry in situ. The annealing process can be considered completed once no more measurable traces of the evaporating species are detected in the mass spectrometer. This allows the determination of the time duration of the annealing procedure.
[0222] The annealing step leaves behind the configuration shown in
[0223] By means of the technique described above with reference to
[0224] The growth of a plurality of nanowire laser structures 42.sub.1 to 42.sub.4 in the nano-holes 84 may then proceed as described above with reference to
[0225] With reference to
[0226] The vertical nanowire growth described above with reference to
[0227] In order to still realize a vertically well-oriented nanowire laser structure on Si (100), one needs to force the nanowire growth into a (100) crystallographic orientation. This can be achieved by using sacrificial hollow microtube pillars made from dielectrics such as SiO.sub.2 or SiN directly on a Si (100) substrate. For instance, an array of well-defined micropillars with sizes of approximately the size of the final nanowire laser cavity may be formed by standard deep-reactive ion etching (RIB) or inductive coupled plasma (ICP) etching of a Si (100) substrate with lengths of 10 ?m or beyond and diameters of several hundred nanometers. This has already been demonstrated for third-generation Si-based nanostructured photovoltaic applications. One may then use either anionic oxidation or plasma-enhanced chemical vapor deposition (PECVD) growth to coat the Si micropillars with an SiO.sub.2 layer. In a subsequent step, the core of the SiO.sub.2/Si (100) micropillars may be selectively etched by selective wet chemical etchant, thereby leaving behind a hollow cylindrical SiO.sub.2 microtube. Employing this microtube on the Si (100) platform, the growth of the III-V compound semiconductor nanowire laser can then be promoted inside the hollow openings. The entire surface area around the hollow tube may consist of a dielectric mask layer, such as SiO.sub.2. This may guarantee that the growth species cannot adhere to the mask layer and only grow in areas where the naked Si (100) surface is exposed, i.e. inside the tube openings, resulting in a selective area growth. Once the nanowire laser structure is grown into these microtube openings to a length determined by the tube length, the sample is subsequently coated with a thick dielectric mirror, similarly to the technique described above with reference to
[0228] As described above with reference to
[0229] The description of the preferred embodiments and the Figures merely serve to illustrate the invention and the beneficial effects associated therewith, but it should not be understood to imply any limitation. The scope of the invention is to be determined from the appended claims.
REFERENCE SIGNS
[0230] 10, 10, 10 nanowire laser structure [0231] 12 substrate [0232] 14 support element, core [0233] 16 body element, shell [0234] 18 first reflective layer [0235] 20 contact layer [0236] 22 second reflective layer [0237] 24 radial pn junction [0238] 26 lateral pn junction [0239] 28 intrinsic layer of the body element 16 [0240] 30 barrier layer of the body element 16 [0241] 32 outer layer of the body element 16 [0242] 34 waveguide layer [0243] 36 scattering object [0244] 38 grating [0245] 40 nanowire laser array [0246] 42.sub.1-42.sub.4 nanowire laser structures of nanowire laser array 40 [0247] 44.sub.1-44.sub.4 support elements of nanowire laser structures 42.sub.1-42.sub.4 [0248] 46.sub.1-46.sub.4 body elements of nanowire laser structures 42.sub.1-42.sub.4 [0249] 48 common contact layer [0250] 50.sub.1-50.sub.4 top reflection layers of nanowire laser structures 42.sub.1-42.sub.4 [0251] 52 lens [0252] 54 cooling channels [0253] 56, 56 interferometer element [0254] 58.sub.1, 58.sub.2 branches of interferometer element 56, 56 [0255] 60 output path of interferometer element 56, 56 [0256] 62 reflective element [0257] 64 optical gate [0258] 66 feedback path [0259] 68 non-linear element [0260] 70 holes [0261] 72 resist layer [0262] 74 dielectric mask layer [0263] 76 resist layer [0264] 78 holes [0265] 80 sacrificial nanowire structures [0266] 82 dielectric layer [0267] 84 nano-holes