Carburized La2O3 and Lu2O3 co-doped Mo filament cathode and its fabrication method

Abstract

A carburized La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped Mo filament cathode and its fabrication method, which belongs to the technical field of rare earth-refractory metal cathodes. The rare earth oxides are La.sub.2O.sub.3 and Lu.sub.2O.sub.3, and the total concentration of rare earth oxides ranges from 2.0-5.0 wt. %. The La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped molybdenum oxide powers are prepared by Sol-Gel method. La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped Mo powers are prepared by two calcining steps. Then pressing and sintering the mixed powders to obtain the molybdenum rods; operating mechanical and heat processes of the molybdenum rods to obtain molybdenum filament. Operating electrolytic cleaning, straightening, winding modeling and cutting treatments with Mo filament to obtain the un-carburized La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped Mo cathode. And then carburize the filament cathode at a high temperature for a short time to obtain a cathode with high carburization degree. And then operate the out-gassing treatment and activation treatment with the cathode at a high temperature to obtain an environmental and non-radioactive cathode with good emission current and emission stability.

Claims

1. A new kind of rare earth oxide doped molybdenum filament cathode material, the rare earth oxides are lanthanum oxide (La.sub.2O.sub.3) and lutetium oxide (Lu.sub.2O.sub.3); the total concentration of rare earth oxides is 2.0-5.0 wt. %, the rest is Mo, and lanthanum oxide and lutetium oxide is mixed in any proportions.

2. The method of claim 1, wherein the total concentration of rare earth oxides ranges from 3 to 4.5 wt. %.

3. The method of claim 1, wherein the lanthanum oxide and lutetium oxide is mixed in the weight ratios of (2-5):1.

4. The method of claim 1, wherein the lanthanum oxide and lutetium oxide is mixed in the weight ratio of 4:1.

5. A method of manufacturing a La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped molybdenum filament cathode material, comprising: (1) mixing the solutions of Lu(NO.sub.3).sub.3.6H.sub.2O, La(NO.sub.3).sub.3.6H.sub.2O, (NH.sub.4).sub.6Mo.sub.7O.sub.24.4H.sub.2O and citric acid with persistently agitation and setting the mixed solution in water bath to obtain a wet gel; the weight ration of Lu(NO.sub.3).sub.3.6H.sub.2O, La(NO.sub.3).sub.3.6H.sub.2O and (NH.sub.4).sub.6Mo.sub.7O.sub.24.4H.sub.2O is determined by the weight ratio of Mo, La.sub.2O.sub.3 and Lu.sub.2O.sub.3; the weight ratios of (NH.sub.4).sub.6Mo.sub.7O.sub.24.4H.sub.2O and citric acid is 1:(0.8-1.5); drying the wet gel to obtain the xerogel and then calcining the xerogel at 500-680 C. to obtain La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped MoO.sub.3 mixed powers; (2) the La.sub.2O.sub.3, Lu.sub.2O.sub.3 and MoO.sub.3 mixed powders obtained by claim (1) are calcined by two steps in hydrogen atmosphere; first step is calcining the La.sub.2O.sub.3, Lu.sub.2O.sub.3 and MoO.sub.3 mixed powders in hydrogen atmosphere at the temperature ranges from 500 to 680 C. to obtain La.sub.2O.sub.3, Lu.sub.2O.sub.3 doped MoO.sub.2 powders thoroughly; then the second step is calcining the La.sub.2O.sub.3, Lu.sub.2O.sub.3 doped MoO.sub.2 powders further in hydrogen atmosphere at 800-980 C. to obtain La.sub.2O.sub.3 and Lu.sub.2O.sub.3 doped Mo powders completely; (3) pressing and sintering the La.sub.2O.sub.3 and Lu.sub.2O.sub.3 doped Mo powders to obtain the molybdenum rods at the sintering temperature between 1800 to 2030 C.; (4) operating further treatments of the La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped molybdenum rods prepared by claim (3) to obtain the un-carburized La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped molybdenum filament cathode, comprising: rotary swaging treatment, drawing treatment, electrolytic cleaning treatment, straightening treatment, winding treatment, modeling treatment and cutting treatment; (5) assembling of the un-carburized La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped molybdenum filament cathode prepared by claim (4) and then carburizing the La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped Mo filament cathode; the temperature of carburization treatment of the present invention ranges from 1550 to 1900 C. for 60-150 s, and the carburization degree of the present invention is about 10-50%.

6. The method of claim 5, wherein further the assembly of the vacuum tube and doing the out-gassing treatment of the vacuum tube equipped with the carburized La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped Mo filament cathode at 1600 to 1900 C. for 20 to 60 mins, and the current of the out-gassing treatment is 10-12.5 A; then activate the La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped Mo filament cathode at 1450 to 1650 C. for 10 to 30 mins; finally assemble the activated vacuum tube into a magnetron.

7. The method to claim 1, wherein the working temperature of the carburized La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped Mo filament cathode working in the magnetrons ranges from 1200 to 1400 C.

8. The method to claim 1, wherein the magnetrons equipped with the carburized La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped Mo filament cathode are applied to the microwave oven.

9. The method to claim 2, wherein the working temperature of the carburized La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped Mo filament cathode working in the magnetrons ranges from 1200 to 1400 C.

10. The method to claim 3, wherein the working temperature of the carburized La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped Mo filament cathode working in the magnetrons ranges from 1200 to 1400 C.

11. The method to claim 4, wherein the working temperature of the carburized La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped Mo filament cathode working in the magnetrons ranges from 1200 to 1400 C.

12. The method to claim 5, wherein the working temperature of the carburized La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped Mo filament cathode working in the magnetrons ranges from 1200 to 1400 C.

13. The method to claim 6, wherein the working temperature of the carburized La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped Mo filament cathode working in the magnetrons ranges from 1200 to 1400 C.

14. The method to claim 2, wherein the magnetrons equipped with the carburized La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped Mo filament cathode are applied to the microwave oven.

15. The method to claim 3, wherein the magnetrons equipped with the carburized La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped Mo filament cathode are applied to the microwave oven.

16. The method to claim 4, wherein the magnetrons equipped with the carburized La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped Mo filament cathode are applied to the microwave oven.

17. The method to claim 5, wherein the magnetrons equipped with the carburized La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped Mo filament cathode are applied to the microwave oven.

18. The method to claim 6, wherein the magnetrons equipped with the carburized La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped Mo filament cathode are applied to the microwave oven.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0017] The techniques of the present disclosure will now be described in detail with reference to the accompanying drawings.

[0018] FIG. 1 is a lifetime graph of output power of microwave oven versus time of a cathode as illustrated in example 5.

EXAMPLES

[0019] From the foregoing it will be appreciated that, although specific embodiments of the present disclosure have been described herein for purposes of illustration, various modifications may be made without deviating from the spirit and scope of the present disclosure. Accordingly, the present disclosure is not limited except as by the appended claims.

Example 1

[0020] Rare earth oxide was quantified in a weight fraction of 2 wt. % based on the rare earth oxide co-doped Mo powders, and the rest was Mo. Dissolving 42.53 g of La(NO.sub.3).sub.3.6H.sub.2O, 9.43 g of Lu(NO.sub.3).sub.3.6H.sub.2O, 1803.5 g of (NH.sub.4).sub.6Mo.sub.7O.sub.24.4H.sub.2O and 1855 g of C.sub.6H.sub.8O.sub.7.H.sub.2O in de-ionized water respectively and completely, adding the citric acid, La(NO.sub.3).sub.3 and Lu(NO.sub.3).sub.3 solution into the (NH.sub.4).sub.6Mo.sub.7O.sub.24 solution slowly with persistently agitation; setting the mixed solution in a water-bath heating environment to obtain a wet gel; drying the wet gel to obtain the xerogel; calcining the xerogel at 500 C. to obtain La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped MoO.sub.3 powers; and calcining the mixed trioxide powders in hydrogen atmosphere at 550 C. to obtain La.sub.2O.sub.3, Lu.sub.2O.sub.3 doped MoO.sub.2 powders thoroughly; calcining the mixed oxide powders further in hydrogen at 980 C. to obtain La.sub.2O.sub.3 and Lu.sub.2O.sub.3 doped Mo powders completely; pressing the mixed powers into REO co-doped Mo billet at 150 MPa and remained for 15 mins; and sintering the REO co-doped Mo billets to obtain REO co-doped Mo rods at 1800 C. Rotary swaging the Mo rods for a few times to become the Mo sticks. Drawing the Mo sticks to decrease the diameter of the sticks to obtain the Mo filaments by multi drawing process. Cleaning the colloidal graphite on the surface of the Mo filament by electrolytic cleaning processes, and straightens the cleaned Mo filament. Winding Mo filament to a coil spring filament and annealing and modeling the Mo coil spring filament; cutting the molybdenum coil spring filament to small segments and each segment as a Mo filament cathode. First assembly of the filament cathodes and doing the carburization treatment of the REO co-doped Mo filament cathode at 1800 C. for 70 s and the carburization degree was 32.3%. Second assembly of the vacuum tubes and doing the out-gassing treatment of the magnetrons equipped with the carburized REO co-doped Mo filament cathode at 1800 C. for 30 minutes; and then third assembly of magnetrons and doing the activation treatment of the REO co-doped Mo filament cathode at 1600 C. for 30 minutes. Testing the direct current emission property of the electronic tube and the result was shown in Table 1. Then we tested the output power of the magnetron tube when the working temperature was 1250 C.

Example 2

[0021] Rare earth oxide was quantified in a weight fraction of 2.5 wt. % based on the rare earth oxide co-doped Mo powders, and the rest was Mo.

[0022] Dissolving 53.16 g of La(NO.sub.3).sub.3.6H.sub.2O, 11.79 g of Lu(NO.sub.3).sub.3.6H.sub.2O, 1794.2 g of (NH.sub.4).sub.6Mo.sub.7O.sub.24.4H.sub.2O and 1859 g of C.sub.6H.sub.8O.sub.7.H.sub.2O in de-ionized water respectively and completely, adding the citric acid, La(NO.sub.3).sub.3 and Lu(NO.sub.3).sub.3 solution into the (NH.sub.4).sub.6Mo.sub.7O.sub.24 solution slowly with persistently agitation; setting the mixed solution in a water-bath heating environment to obtain a wet gel; drying the wet gel to obtain the xerogel; calcining the xerogel at 550 C. to obtain La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped MoO.sub.3 powers; and calcining the mixed trioxide powders in hydrogen atmosphere at 550 C. to obtain La.sub.2O.sub.3, Lu.sub.2O.sub.3 doped MoO.sub.2 powders thoroughly; calcining the mixed oxide powders further in hydrogen at 950 C. to obtain La.sub.2O.sub.3 and Lu.sub.2O.sub.3 doped Mo powders completely; pressing the mixed powers into REO co-doped Mo billet at 150 MPa and remained for 15 minutes; and sintering the REO co-doped Mo billets to obtain REO co-doped Mo rods at 1800 C. Rotary swaging the Mo rods for a few times to become the Mo sticks. Drawing the Mo sticks to decrease the diameter of the sticks to obtain the Mo filaments by multi drawing process. Cleaning the colloidal graphite on the surface of the Mo filament by electrolytic cleaning processes, and straightens the cleaned Mo filament. Winding Mo filament to a coil spring filament and annealing and modeling the Mo coil spring filament; cutting the molybdenum coil spring filament to small segments and each segment as a Mo filament cathode. First assembly of the filament cathodes and doing the carburization treatment of the REO co-doped Mo filament cathode at 1800 C. for 70 s and its carburization degree was 34.1%. Second assembly of the vacuum tubes and doing the out-gassing treatment of the magnetrons equipped with the carburized REO co-doped Mo filament cathode at 1800 C. for 30 mins; and then third assembly of magnetrons and doing the activation treatment of the REO co-doped Mo filament cathode at 1600 C. for 30 mins. Testing the direct current emission property of the electronic tube and the result was shown in Table 1. Then we tested the output power of the magnetron tube when the working temperature was 1250 C.

Example 3

[0023] Rare earth oxide was quantified in a weight fraction of 3 wt. % based on the rare earth oxide co-doped Mo powders, and the rest was Mo.

[0024] Dissolving 63.79 g of La(NO.sub.3).sub.3.6H.sub.2O, 14.15 g of Lu(NO.sub.3).sub.3.6H.sub.2O, 1785.0 g of (NH.sub.4).sub.6Mo.sub.7O.sub.24.4H.sub.2O and 1862.9 g of C.sub.6H.sub.8O.sub.7.H.sub.2O in de-ionized water respectively and completely, adding the citric acid, La(NO.sub.3).sub.3 and Lu(NO.sub.3).sub.3 solution into the (NH.sub.4).sub.6Mo.sub.7O.sub.24 solution slowly with persistently agitation; setting the mixed solution in a water-bath heating environment to obtain a wet gel; drying the wet gel to obtain the xerogel; calcining the xerogel at 550 C. to obtain La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped MoO.sub.3 powers; and calcining the mixed trioxide powders in hydrogen atmosphere at 550 C. to obtain La.sub.2O.sub.3, Lu.sub.2O.sub.3 doped MoO.sub.2 powders thoroughly; calcining the mixed oxide powders further in hydrogen at 950 C. to obtain La.sub.2O.sub.3 and Lu.sub.2O.sub.3 doped Mo powders completely; pressing the mixed powers into REO co-doped Mo billet at 150 MPa and remained for 15 mins; and sintering the REO co-doped Mo billets to obtain REO co-doped Mo rods at 1850 C. Rotary swaging the Mo rods for a few times to become the Mo sticks. Drawing the Mo sticks to decrease the diameter of the sticks to obtain the Mo filaments by multi drawing process. Cleaning the colloidal graphite on the surface of the Mo filament by electrolytic cleaning processes, and straightens the cleaned Mo filament. Winding Mo filament to a coil spring filament and annealing and modeling the Mo coil spring filament; cutting the molybdenum coil spring filament to small segments and each segment as a Mo filament cathode. First assembly of the filament cathodes and doing the carburization treatment of the REO co-doped Mo filament cathode at 1700 C. for 75 s and its carburization degree was 28.2%. Second assembly of the vacuum tubes and doing the out-gassing treatment of the magnetrons equipped with the carburized REO co-doped Mo filament cathode at 1800 C. for 30 mins; and then the third assembly of magnetrons and doing the activation treatment of the REO co-doped Mo filament cathode at 1600 C. for 30 mins. Testing the direct current emission property of the electronic tube and the result was shown in Table 1. Then we tested the output power of the magnetron tube when the working temperature was 1250 C.

Example 4

[0025] Rare earth oxide was quantified in a weight fraction of 3.5 wt. % based on the rare earth oxide co-doped Mo powders, and the rest was Mo.

[0026] Dissolving 74.43 g of La(NO.sub.3).sub.3.6H.sub.2O, 16.50 g of Lu(NO.sub.3).sub.3.6H.sub.2O, 1775.8 g of (NH.sub.4).sub.6Mo.sub.7O.sub.24.4H.sub.2O and 1866.7 g of C.sub.6H.sub.8O.sub.7.H.sub.2O in de-ionized water respectively and completely, adding the citric acid, La(NO.sub.3).sub.3 and Lu(NO.sub.3).sub.3 solution into the (NH.sub.4).sub.6Mo.sub.7O.sub.24 solution slowly with persistently agitation; setting the mixed solution in a water-bath heating environment to obtain a wet gel; drying the wet gel to obtain the xerogel; calcining the xerogel at 600 C. to obtain La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped MoO.sub.3 powers; and calcining the mixed trioxide powders in hydrogen atmosphere at 600 C. to obtain La.sub.2O.sub.3, Lu.sub.2O.sub.3 doped MoO.sub.2 powders thoroughly; calcining the mixed oxide powders further in hydrogen at 920 C. to obtain La.sub.2O.sub.3 and Lu.sub.2O.sub.3 doped Mo powders completely; pressing the mixed powers into REO co-doped Mo billet at 150 MPa and remained for 15 minutes; and sintering the REO co-doped Mo billets to obtain REO co-doped Mo rods at 1850 C. Rotary swaging the Mo rods for a few times to become the Mo sticks. Drawing the Mo sticks to decrease the diameter of the sticks to obtain the Mo filaments by multi drawing process. Cleaning the colloidal graphite on the surface of the Mo filament by electrolytic cleaning processes and straightens the cleaned Mo filament. Winding Mo filament to a coil spring filament and annealing and modeling the Mo coil spring filament; cutting the molybdenum coil spring filament to small segments and each segment as a Mo filament cathode. First assembly of the filament cathodes and doing the carburization treatment of the REO co-doped Mo filament cathode at 1700 C. for 75 s and its carburization degree was 29.3%. Second assembly of the vacuum tubes and doing the out-gassing treatment of the magnetrons equipped with the carburized REO co-doped Mo filament cathode at 1800 C. for 30 mins; and then the third assembly of magnetrons and doing the activation treatment of the REO co-doped Mo filament cathode at 1600 C. for 30 mins. Testing the direct current emission property of the electronic tube and the result was shown in Table 1. Then we tested the output power of the magnetron tube when the working temperature was 1250 C.

Example 5

[0027] Rare earth oxide was quantified in a weight fraction of 4 wt. % based on the rare earth oxide co-doped Mo powders, and the rest was Mo.

[0028] Dissolving 85.06 g of La(NO.sub.3).sub.3.6H.sub.2O, 18.86 g of Lu(NO.sub.3).sub.3.6H.sub.2O, 1766.6 g of (NH.sub.4).sub.6Mo.sub.7O.sub.24.4H.sub.2O and 1870.5 g of C.sub.6H.sub.8O.sub.7.H.sub.2O in de-ionized water respectively and completely, adding the citric acid, La(NO.sub.3).sub.3 and Lu(NO.sub.3).sub.3 solution into the (NH.sub.4).sub.6Mo.sub.7O.sub.24 solution slowly with persistently agitation; setting the mixed solution in a water-bath heating environment to obtain a wet gel; drying the wet gel to obtain the xerogel; calcining the xerogel at 600 C. to obtain La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped MoO.sub.3 powers; and calcining the mixed trioxide powders in hydrogen atmosphere at 600 C. to obtain La.sub.2O.sub.3, Lu.sub.2O.sub.3 doped MoO.sub.2 powders thoroughly; calcining the mixed oxide powders further in hydrogen at 900 C. to obtain La.sub.2O.sub.3 and Lu.sub.2O.sub.3 doped Mo powders completely; pressing the mixed powers into REO co-doped Mo billet at 150 MPa and remained for 15 minutes; and sintering the REO co-doped Mo billets to obtain REO co-doped Mo rods at 1900 C. And rotary swaging the Mo rods for a few times to become the Mo sticks. Drawing the Mo sticks to decrease the diameter of the sticks to obtain the Mo filaments by multi drawing process. Cleaning the colloidal graphite on the surface of the Mo filament by electrolytic cleaning processes, and straightens the cleaned Mo filament. Winding Mo filament to a coil spring filament and annealing and modeling the Mo coil spring filament; cutting the molybdenum coil spring filament to small segments and each segment as a Mo filament cathode. First assembly of the filament cathodes and doing the carburization treatment of the REO co-doped Mo filament cathode at 1600 C. for 80 s and its carburization degree was 28.2%. Second assembly of the vacuum tubes and doing the out-gassing treatment of the magnetrons equipped with the carburized REO co-doped Mo filament cathode at 1800 C. for 30 mins; and then the third assembly of magnetrons and doing the activation treatment of the REO co-doped Mo filament cathode at 1600 C. for 30 mins. Testing the direct current emission property of the electronic tube and the result was shown in Table 1. Then we tested the output power of the magnetron tube when the working temperature was 1250 C.

Example 6

[0029] Rare earth oxide was quantified in a weight fraction of 4.5 wt. % based on the rare earth oxide co-doped Mo powders, and the rest was Mo.

[0030] Dissolving 95.69 g of La(NO.sub.3).sub.3.6H.sub.2O, 21.21 g of Lu(NO.sub.3).sub.3.6H.sub.2O, 1757.4 g of (NH.sub.4).sub.6Mo.sub.7O.sub.24.4H.sub.2O and 1874.3 g of C.sub.6H.sub.8O.sub.7.H.sub.2O in de-ionized water respectively and completely, adding the citric acid, La(NO.sub.3).sub.3 and Lu(NO.sub.3).sub.3 solution into the (NH.sub.4).sub.6Mo.sub.7O.sub.24 solution slowly with persistently agitation; setting the mixed solution in a 80 C. environment to obtain a wet gel; drying the wet gel to obtain the xerogel; calcining the xerogel at 650 C. to obtain La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped MoO.sub.3 powers; and calcining the mixed trioxide powders in hydrogen atmosphere at 600 C. to obtain La.sub.2O.sub.3, Lu.sub.2O.sub.3 doped MoO.sub.2 powders thoroughly; calcining the mixed oxide powders further in hydrogen at 980 C. to obtain La.sub.2O.sub.3 and Lu.sub.2O.sub.3 doped Mo powders completely; pressing the mixed powers into REO co-doped Mo billet at 150 MPa and remained for 15 mins; and sintering the REO co-doped Mo billets to obtain REO co-doped Mo rods at 1950 C.; rotary swaging the Mo rods for a few times to become the Mo sticks. Drawing the Mo sticks to decrease the diameter of the sticks to obtain the Mo filaments by multi drawing process. Cleaning the colloidal graphite on the surface of the Mo filament by electrolytic cleaning processes, and straightens the cleaned Mo filament. Winding Mo filament to a coil spring filament and annealing and modeling the Mo coil spring filament; cutting the molybdenum coil spring filament to small segments and each segment as a Mo filament cathode. First assembly of the filament cathodes and doing the carburization treatment of the REO co-doped Mo filament cathode at 1600 C. for 80 s and its carburization degree was 27.3%. Second assembly of the vacuum tubes and doing the out-gassing treatment of the magnetrons equipped with the carburized REO co-doped Mo filament cathode at 1800 C. for 30 mins; and then the third assembly of magnetrons and doing the activation treatment of the REO co-doped Mo filament cathode at 1600 C. for 30 mins. Testing the direct current emission property of the electronic tube and the result was shown in Table 1. Then we tested the output power of the magnetron tube when the working temperature was 1250 C.

Example 7

[0031] Rare earth oxide was quantified in a weight fraction of 5 wt. % based on the rare earth oxide co-doped Mo powders, and the rest was Mo.

[0032] Dissolving 106.32 g of La(NO.sub.3).sub.3.6H.sub.2O, 23.58 g of Lu(NO.sub.3).sub.3.6H.sub.2O, 1748.2 g of (NH.sub.4).sub.6Mo.sub.7O.sub.24.4H.sub.2O and 1878.1 g of C.sub.6H.sub.8O.sub.7.H.sub.2O in de-ionized water respectively and completely, adding the citric acid, La(NO.sub.3).sub.3 and Lu(NO.sub.3).sub.3 solution into the (NH.sub.4).sub.6Mo.sub.7O.sub.24 solution slowly with persistently agitation; setting the mixed solution in a 80 C. environment to obtain a wet gel; drying the wet gel to obtain the xerogel; calcining the xerogel at 680 C. to obtain La.sub.2O.sub.3 and Lu.sub.2O.sub.3 co-doped MoO.sub.3 powers; and calcining the mixed trioxide powders in hydrogen atmosphere at 650 C. to obtain La.sub.2O.sub.3, Lu.sub.2O.sub.3 doped MoO.sub.2 powders thoroughly; calcining the mixed oxide powders further in hydrogen at 850 C. to obtain La.sub.2O.sub.3 and Lu.sub.2O.sub.3 doped Mo powders completely; pressing the mixed powers into REO co-doped Mo billet at 150 MPa and remained for 15 minutes; and sintering the REO co-doped Mo billets to obtain REO co-doped Mo rods at 2000 C.; rotary swaging the Mo rods for a few times to become the Mo sticks. Drawing the Mo sticks to decrease the diameter of the sticks to obtain the Mo filaments by multi drawing process. Cleaning the colloidal graphite on the surface of the Mo filament by electrolytic cleaning processes, and straightens the cleaned Mo filament. Winding Mo filament to a coil spring filament and annealing and modeling the Mo coil spring filament; cutting the molybdenum coil spring filament to small segments and each segment as a Mo filament cathode. First assembly of the filament cathodes and doing the carburization treatment of the REO co-doped Mo filament cathode at 1550 C. for 100 s and its carburization degree was 25.4%. Second assembly of the vacuum tubes and doing the out-gassing treatment of the magnetrons equipped with the carburized REO co-doped Mo filament cathode at 1800 C. for 30 mins; and then the third assembly of magnetrons and doing the activation treatment of the REO co-doped Mo filament cathode at 1600 C. for 30 mins. Test the direct current emission property of the electronic tube and the result was shown in Table 1. Then we tested the output power of the magnetron tube when the working temperature was 1250 C.

TABLE-US-00001 TABLE 1 Table of the date of the carburizing degree and emission current tested without magnetic field Sample Emission Current (mA) 1 637 2 640 3 632 4 633 5 651 6 637 7 636