COMPOUNDS FOR USE IN CATALYST COMPOSITIONS FOR THE PRODUCTION OF POLYOLEFINS

Abstract

The present invention relates to compounds according to formula I:

##STR00001##

wherein: each R1-R10 may individually be H, a halogen, an alkoxy moiety, a siloxy moiety, a nitrogen-containing moiety, an alkyl moiety, an aryl moiety, or an aralkyl moiety, wherein each R1-R10 comprises ≤10 carbon atoms, wherein each of R1-R10 may form a cyclic moiety with an adjacent R1-R10 moiety; Y is O or N—R11, wherein R11 is an alkyl, cycloalkyl, aryl or aralkyl moiety comprising 1-12 carbon atoms; M is a group 3 or 4 transition metal; X is a sigma-bonded ligand, or a diene; z is the number of ligands X that are bonded to M. Such compounds may be used in a catalyst system for olefin polymerisation.

Claims

1. Compound according to formula I: ##STR00012## wherein: each R1-R10 is individually H, a halogen, an alkoxy moiety, a siloxy moiety, a nitrogen-containing moiety, an alkyl moiety, an aryl moiety, or an aralkyl moiety, wherein each R1-R10 comprises ≤10 carbon atoms, wherein each of R1-R10 may form a cyclic moiety with an adjacent R1-R10 moiety; Y is O or N—R11, wherein R11 is an alkyl, cycloalkyl, aryl or aralkyl moiety comprising 1-12 carbon atoms; M is a group 3 or 4 transition metal; X is a sigma-bonded ligand, or a diene; z is the number of ligands X that are bonded to M.

2. Compound according to claim 1, wherein R5 and R6 are the same or are different, and: are hydrogen or a moiety selected from methyl, ethyl, n-butyl, t-butyl, isobutyl or phenyl, or together form a cyclic moiety.

3. Compound according to claim 1, wherein each R1 and R3 individually are a moiety selected from methyl, ethyl, isopropyl, n-butyl, t-butyl, isobutyl, adamantyl, or phenyl.

4. Compound according to claim 1, wherein R7 forms a cyclic moiety with R8, and/or R8 forms a cyclic moiety with R9, and/or R9 forms a cyclic moiety with R10.

5. Compound according to claim 1, wherein the moieties R1-R4 are such that the moiety: ##STR00013## of formula I is a moiety selected from: ##STR00014##

6. Compound according to claim 1, wherein the moieties R7-R10 are such that the moiety: ##STR00015## of formula I is a moiety selected from: ##STR00016##

7. Compound according to claim 1, wherein MXz is selected from ZrCl.sub.2, TiCl.sub.2, HfCl.sub.2, Zr(CH.sub.3).sub.2, Ti(CH.sub.3).sub.2, Hf(CH.sub.3).sub.2, Zr(benzyl).sub.2, Ti(benzyl).sub.2, Hf(benzyl).sub.2, Ti(1,3-butadiene) or Ti(1,3-pentadiene).

8. Compound according to claim 1, wherein Y is O or N—R11, wherein R11 is selected from methyl, ethyl, n-propyl, i-propyl, t-butyl, cyclohexyl, cyclododecyl, or a substituted or unsubstituted phenyl.

9. Compound according to claim 1, wherein the compound is supported onto a polymeric support, a clay material, or an inorganic oxide.

10. Catalyst composition comprising the compound according to claim 1, wherein the composition further comprises an activator.

11. Catalyst composition comprising the compound according to claim 1, wherein the catalyst composition further comprises a main group organometallic compounds.

12. Catalyst composition comprising the compound according to claim 1, wherein the catalyst composition further comprises a compound containing at least one active hydrogen.

13. Process for the polymerisation of olefins, the process comprising polymerizing ethylene or propylene, or copolymerizing ethylene or propylene with one or more comonomer(s) in the presence of the catalyst composition according to claim 10.

14. Process according to claim 13, wherein the process is a copolymerisation process of ethylene with one or more comonomer(s), wherein the comonomer(s) are selected from propene, 1-butene, 1-hexene, 1-octene, norbornene, ethylidene-norbornene, vinyl-norbornene, vinyl-cyclohexane, styrene, or 4-methyl-1-pentene.

15. Polymer produced according to the process of claim 13, wherein the polymer comprises 1.0 to 80.0 wt. % of polymer moieties derived from a comonomer, as

Description

DETAILED DESCRIPTION

[0030] Each R5 and R6 may be the same or different. Preferably, both R5 and R6 are the same. Each R5 and R6 may be hydrogen or a moiety selected from methyl, ethyl, n-butyl, t-butyl, isobutyl or phenyl. Preferably, both R5 and R6 are the same and selected from hydrogen or a moiety selected from methyl, ethyl, n-butyl, or t-butyl. R5 and R6 may form a cyclic moiety. Examples of such cyclic moieties are cyclohexyl or fluorenyl. In a preferred embodiment, both R5 and R6 are CHs-moieties.

[0031] In some embodiments of the invention, both R2 and R4 are hydrogen.

[0032] For example, R7 may form a cyclic moiety with R8. In certain embodiments, R7 and R8 together form an aromatic ring moiety that may be substituted or that may be unsubstituted. For example, R8 may form a cyclic moiety with R9. For example, R9 may form a cyclic moiety with R10. In certain embodiments, R9 and R10 together form an aromatic ring moiety that may be substituted or that may be unsubstituted. For example, where R7 and R8 form a cyclic moiety, it is preferred that R9 and R10 together form a cyclic moiety that is identical to that formed by R7 and R8.

[0033] For example, the moieties R7-R10 may be such that the moiety:

##STR00003##

of formula I is a moiety selected from:

##STR00004## ##STR00005##

[0034] For reasons of clarity, it needs to be understood that the dotted line in the above-presented figures indicates the position where the moiety is connected to the vinyl-based bridging moiety.

[0035] For example, each R1 and R3 may individually be a moiety selected from methyl, ethyl, isopropyl, n-butyl, isobutyl, t-butyl, adamantyl, phenyl, fluorine or methoxy. In certain embodiments, both R1 and R3 are the same. For example, both R1 and R3 may be a moiety selected from methyl, t-butyl, or phenyl. For example, both R2 and R4 may be hydrogen, and both R1 and R3 may be the same and may be a moiety selected from methyl, t-butyl, or phenyl.

[0036] For example, the moieties R1-R4 may be such that the moiety:

##STR00006##

of formula I is a moiety selected from:

##STR00007##

[0037] For reasons of clarity, it needs to be understood that the dotted line in the above-presented figures indicates the position where the moiety is connected to the vinyl-based bridging moiety.

[0038] Preferably, M is titanium. The moiety MX.sub.z may for example be selected from ZrCl.sub.2, TiCl.sub.2, HfCl.sub.2, Zr(CH.sub.3).sub.2, Ti(CH.sub.3).sub.2, Hf(CH.sub.3).sub.2, Zr(benzyl).sub.2, Ti(benzyl).sub.2, Hf(benzyl).sub.2, Ti(1,3-butadiene) or Ti(1,3-pentadiene). Preferably, MX.sub.z is TiCl.sub.2 or Ti(CH.sub.3).sub.2.

[0039] In a certain embodiment of the invention: [0040] R2 and R4 are hydrogen; [0041] R1 and R3 are the same and selected from methyl, ethyl, isopropyl, n-butyl, t-butyl or phenyl, preferably from methyl or t-butyl; and [0042] R5 and R6 are the same and selected from methyl, ethyl, isopropyl, n-butyl, t-butyl or phenyl, preferably methyl.

[0043] In a further particular embodiment of the invention, R7 and R8 are fused to form a ring structure and R9 and R10 are fused to form a ring structure such that they form a substituted or unsubstituted fluorenyl moiety that is bound to the vinyl-based bridging moiety at the 9 position. For example, R7-R10 may be such to form an unsubstituted fluorenyl moiety, or a 2,7-di-t-butyl substituted fluorenyl moiety, wherein the fluorenyl moiety is bound to the vinyl-based bridging moiety at the 9 position.

[0044] The vinyl-based bridging moiety in the present context is to be understood to be the moiety

##STR00008##

of formula I.

[0045] In a further embodiment of the invention, Y is oxygen or a nitrogen-containing group N—R11. R11 is preferably methyl, isopropyl, t-butyl, cyclohexyl, cyclododecyl or phenyl. Preferably, R11 is t-butyl or phenyl. In a further particular embodiment of the invention, Y is oxygen.

[0046] In catalyst systems for the polymerisation of olefins, the compounds of the invention can be used in combination with any activator that renders the system catalytically active in olefin polymerisation. Examples of such activators are for instance aluminoxanes such as methyl aluminoxanes (MAO), methyl-isobutyl aluminoxanes, and isobutyl aluminoxanes. Other suitable activators may for example be boron-based compounds, such as boron compounds containing (per)fluorinated aryl substituents, for example tris(pentafluorophenyl)borane and tetrakis(pentafluorophenyl)borate compounds. Examples of the latter are ammonium salts or trityl compounds of tetrakis(pentafluorophenyl)borate.

[0047] The catalysts based on the compounds of the present invention may be used in unsupported form, or may be used on a support material such as for instance polymeric supports, clay materials or inorganic oxides, such as for example silica or alumina. Alternatively, fluorided silica-alumina supports or sulfated alumina supports may be used. Methods for preparation of such supported polymerisation catalyst are well known in the art, and may be applied to the compounds of the present invention.

[0048] Preferably, the support is a silica having a surface area between 200 and 900 m.sup.2/g and/or a pore volume of >0.5 and <4.0 ml/g.

[0049] Alternatively, the support materials may be polymeric support materials, such as polyvinyl chloride, polystyrene, polyethylene or polypropylene.

[0050] The invention further also relates to a process for the preparation of olefin polymers by polymerisation of one or more olefins in the presence of a catalyst system comprising a compound of the present invention. In particular, wherein the catalyst system comprises a compound of the present invention and an activator, for example wherein the compound of the present invention is immobilised on a support.

[0051] In such process for the preparation of olefin polymers in the presence of a compound according to the invention, preferably a main group organometallic compound is present that can act as a scavenger compound to scrub impurities from the polymerisation system that might otherwise adversely affect the catalyst activity.

[0052] When X in formula I is a halogen, an alkoxide moiety or an amine moiety, an additional function of this main group organometallic compound is to substitute X with an organic group, for example to substitute X with an alkyl or aralkyl moiety such as a methyl, ethyl, propyl, isopropyl, butyl, isobutyl or benzyl moiety. This function of the main group organometallic compound is particularly advantageous when an activator other than an aluminoxanes is used. Suitable main group organometallic compounds are those able to exchange at least one or its organic moieties with X in the compounds of the invention.

[0053] For example, organolithium compounds, organomagnesium compounds, organoaluminium compounds, organozinc compounds, or mixtures thereof, may be used as such main group organometallic compound. Preferably, the main group organometallic compound is an organoaluminium compound. Suitable organoaluminium compounds are for example trimethylaluminium, triethylaluminium, triisopropylaluminium, tri-n-propylaluminium, triisobutylaluminium, tri-n-butylaluminium, tri-tert-butylaluminium, triamylaluminium, tri-n-hendaluminium, trioctylaluminium, isoprenylaluminium, dimethylaluminium ethoxide, diethylaluminium ethoxide, diisopropylaluminium ethoxide, di-n-propylaluminium ethoxide, diisobutylaluminium ethoxide, di-n-butylaluminium ethoxide, dimethylaluminium hydride, diethylaluminium hydride, diisopropylaluminium hydride, di-n-propylaluminium hydride, diisobutylaluminium hydride, and di-n-butylaluminium hydride. Mixture of these organoaluminium compounds are also suitable. Alternatively, aluminoxanes may be used as such main group organometallic compound. Examples of suitable aluminoxanes are methylaluminoxanes, methyl-isobutylaluminoxanes, isobutylaluminoxanes, and mixtures thereof.

[0054] In certain embodiments, it may be suitable to combine the main group organometallic compound with a compound containing at least one active hydrogen. Such combination may be done in-situ or ex-situ. In the present context, an active hydrogen means that the hydrogen atom is able to react with the main group organometallic compound. Suitable compounds comprising at least one active hydrogen in the context of the present invention are for example alcohol compounds, silanol compounds, and amine compounds. Suitable amine compounds are sterically encumbered amine compounds. Examples of sterically encumbered amine compounds are cyclohexyl amine or an alkylamine comprising at least one aliphatic group having at least four carbon atoms. Suitable alcohol compounds are preferably sterically encumbered alcohol compounds, such as substituted phenolic compounds. In principle, any substituted mono- or polyphenolic compound may be used. Suitable substituted monophenolic compounds are for example butylated hydroxytoluene (BHT, 2,6-di-t-butyl-4-methylphenol), 2,6-di-t-butylphenol, and α-tocopherol (vitamin E). Preferably, the amount of the compound comprising at least one active hydrogen is such that after combining this compound with the main group organometallic compound, the latter still contains organometallic bonds, preferably at least one organometallic bond per main group metal atom.

[0055] The process to produce the olefin polymers may start with the reaction of a compound of the invention and an activator, optionally in the presence of the main group organometallic compound, optionally in the presence of a compound comprising at least one active hydrogen atom, optionally in the presence of a suitable support material. This reaction may be performed in the same vessel as the reaction vessel wherein the olefin polymers are produced, or may be a separate vessel. It may be advantageous to combine the inventive compound at first with a portion of the quantity of the main group organometallic compound that is to be used, optionally in the presence of the compound containing at least one active hydrogen, before mixing with the activator. The resulting mixture may be fed to a polymerisation reactor. During the reactions as described here above, an inert solvent may be used.

[0056] The polymerisation reaction may be carried out in a slurry process, a solution process, or a gas-phase process.

[0057] The activator may be an aluminoxane-based activator. When a mixture of the inventive compound and such aluminoxanes-based activator is used, the activator may preferably be used in a quantity of between 10 and 100,000 moles of aluminium, preferably of between 10 and 10,000 moles of aluminium, per mole of the transition metal in the inventive compound.

[0058] Alternatively, the activator may be an organoboron-based activator. When a mixture of the inventive compound and such organoboron-based activator is used, the activator may preferably be used in a quantity of between 0.1 and 100 moles of boron, preferably of between 0.5 and 50 moles of boron, per mole of the transition metal in the inventive compound.

[0059] When the polymerisation is performed in a slurry or a solution process, the solvent that is used may be any organic solvent as is typically used in olefin polymerisation processes. For example, the solvent may be benzene, toluene, xylene, propane, butane, pentane, hexane, heptane, cyclohexane, methylcyclohexane, and methylchloride. Alternatively, the olefin that is to be polymerised may be used as solvent.

[0060] In the process to produce olefin polymers, the polymerisation conditions such as temperature, time, pressure, and monomer concentration may be chosen within wide limits. The polymerisation temperature may for example be in the range of between −100° C. and 300° C., preferably between 0° C. and 240° C., more preferably between 50° C. and 200° C. The polymerisation time may for example be in the range from 10 seconds to 20 hours, preferably from 1 minute to 10 hours, more preferably from 3 minutes to 5 hours. In the polymerisation of ethylene, the ethylene pressure may for example be in the range of from 1 to 3500 bar, preferably from 1 to 2500 bar, more preferably from 1 to 1000 bar, even more preferably from 1 to 500 bar, yet even more preferably from 1 to 100 bar.

[0061] The molecular weight of the polymer may be controlled by well-known means such as the use of hydrogen or zinc-alkyls in the polymerisation. The polymerisation may be conducted in a batch process, a semi-continuous process, or a continuous process. The polymerisation may be conducted in two or more steps of different polymerisation conditions. The polymer that is produced may be separated from the solvent that is employed in the polymerisation reaction and from residual monomers and optionally comonomers, and dried by methods known to the person skilled in the art.

[0062] In a process for the production of olefin polymers using the compounds of the present invention, the polymerisation may involve a homopolymerisation of an olefin monomer, or a copolymerisation of an olefin monomer and one or more comonomer(s). The olefin monomer may for example be ethylene or propylene. The comonomer may for example be ethylene, propylene, 1-butene, 1-pentene, 3-methyl-1-butene, 3,3,-dimethyl-1-butene, 4-methyl-1-pentene, 3-methyl-1-pentene, 1-hexene, 1-octene, 1-nonene, 1-decene; a conjugated or a non-conjugated diene such as butadiene, 1,4-hexadiene, a substituted or unsubstituted norbornene, 5-ethylidene-2-norbornene, vinyl-norbornene, dicyclopentadiene, 4-methyl-1,4-hexadiene, 1,9-decadiene, or 7-methyl-1,6-octadiene; cyclic olefins such as cyclobutene, cyclopentene; or other olefinic compounds such as isobutene, vinyl-cyclohexane, or styrene.

[0063] Preferably, the olefin monomer is ethylene. The polymer produced using ethylene as olefin monomer may be referred to as an ethylene homopolymer, or, in case that the polymerisation is a copolymerisation reaction, an ethylene copolymer. Such ethylene homopolymers and copolymers may together be referred to as polyethylenes. In the case that for example three monomers are used, one can also produce terpolymers, for example if a combination of ethylene, propylene and a third comonomer containing at least two olefinic bonds, such as norbornadiene, dicylopentadiene, ethylidene-norbornene or vinyl-norbornene, are used, one can make terpolymers that can be referred to as EPDM. Preferably, the comonomer is an olefin having 3 or more carbon atoms, for example an olefin comprising 3 to 10 carbon atoms, such as an α-olefin comprising 3 to 10 carbon atoms.

[0064] Preferably, the comonomer is selected from propene, 1-butene, 1-hexene, 1-octene, norbornene, vinyl-cyclohexane, styrene, and 4-methyl-1-pentene. Preferably, the olefin monomer is ethylene, and the comonomer is selected from 1-butene, 1-hexene, 1-octene, norbornene, vinyl-cyclohexane, styrene, and 4-methyl-1-pentene.

[0065] Preferably, the process for the production of olefin polymers using the compounds of the present invention is copolymerisation of an olefin monomer and one or more comonomer(s), wherein the olefin monomer is ethylene, and the comonomer is selected from 1-butene, 1-hexene, 1-octene, norbornene, vinyl-cyclohexane, styrene, and 4-methyl-1-pentene. Particularly preferable, the process for the production of olefin polymers using the compounds of the present invention is copolymerisation of an olefin monomer and one or more comonomer(s), wherein the olefin monomer is ethylene, and the comonomer is selected from 1-butene, 1-hexene, 4-methyl-pentene-1, vinylcyclohexane, and 1-octene.

[0066] In case that the polymerisation is a copolymerisation of an olefin and one or more comonomer(s), the olefin and the comonomer(s) are different compounds.

[0067] The olefin polymer may for example comprise from 1.0 to 80.0 wt. % of moieties derived from the comonomer, preferably from 5.0 to 60.0 wt %, more preferably from 10.0 to 50.0 wt %, or from 10.0 to 30.0 wt %, with regard to the total weight of the olefin polymer. The ethylene copolymer may for example comprise from 1.0 to 80.0 wt. % of moieties derived from the comonomer, preferably from 5.0 to 60.0 wt %, more preferably from 10.0 to 50.0 wt %, or from 10.0 to 30.0 wt %, with regard to the total weight of the ethylene copolymer.

[0068] The polyethylene may for example have a melt mass-flow rate as determined in accordance with ASTM D1238-10 at 190° C. at a load of 2.16 kg (MFI.sub.2.16) of ≥0.1 and ≤125 g/10 min. For example, the polyethylene may have an MFI.sub.2.16 of ≥0.1 and ≤50 g/10 min, or ≥0.3 and ≤10.0 g/10 min, or ≥0.5 and ≤5.0 g/10 min.

[0069] The polyethylene may for example have a density of ≥855 kg/m.sup.3 and ≤965 kg/m.sup.3, as determined in accordance with ASTM D1505-10. The polyethylene may for example have a density of ≥855 and ≤910 kg/m.sup.3, or of ≥875 and ≤900 kg/m.sup.3. The polyethylene may for example have a density of ≥910 and ≤925 kg/m.sup.3, or of ≥910 and ≤920 kg/m.sup.3, or of ≥915 and ≤920 kg/m.sup.3. The polyethylene may for example have a density of ≥925 and ≤940 kg/m.sup.3, or of ≥930 and ≤940 kg/m.sup.3. The polyethylene may for example have a density of ≥940 and ≤965 kg/m.sup.3, or of ≥945 and ≤960 kg/m.sup.3.

[0070] It has been found that using the compounds of the present invention, it is possible to produce ethylene copolymers wherein the comonomer is selected from 1-butene, 1-hexene, and 1-octene with particularly high incorporation of the comonomer. The amount of incorporation of the comonomer may be expressed as the amount of short chain branches per 1000 carbon atoms in the polymer. The amount of short chain branches may for example be determined using .sup.13C NMR via the method as described by Randall, Rev. Macromol. Chem. Phys., C. 29, V. 2&3, p. 285-297. The ethylene copolymer may for example comprise at least 10, 25, or 80 short chain branches per 1000 carbon atoms in the polymer. The ethylene copolymer may comprise at most 200, 100, 50 or 25 short chain branches per 1000 carbon atoms in the polymer. The ethylene copolymer may for example comprise at least 10 and at most 200 short chain branches per 1000 carbon atoms in the polymer, or at least 15 and at most 100, or at least 20 and at most 50.

[0071] The polyethylene may have a number-average molecular weight (M.sub.n) of between 1,000 and 1,000,000 g/mol, preferably between 10,000 and 500,000 g/mol, more preferably between 20,000 and 250,000 g/mol. The polyethylene may have a weight-average molecular weight (M.sub.w) of between 2,000 and 5,000,000 g/mol, preferably between 5,000 and 1,000,000 g/mol, more preferably between 10,000 and 500,000 g/mol. The M.sub.w and M.sub.n are determined in accordance with ASTM D6474-12, using 1,2,4-trichlorobenzene or o-dichlorobenzene as solvent, and calibrated using polyethylene or polystyrene standards. The polyethylene may for example have a molecular weight distribution M.sub.w/M.sub.n of ≥2.0 and ≤5.0, or ≥2.1 and ≤4.0, or ≥2.5 and ≤3.5.

[0072] The invention will now be illustrated by the following non-limiting examples.

Compounds

[0073] A number of compounds as listed in the table below were produced. The compounds C-1 through C-5 were provided as comparative materials, the compounds I-1 through I-8 demonstrate the present invention.

##STR00009## ##STR00010## ##STR00011##

Wherein Ph stands for phenyl and Me stands for methyl.

Syntheses

General Considerations

[0074] All manipulations with air- and moisture-sensitive compounds were carried out under argon or nitrogen atmosphere using standard glove box, Schlenk, or high-vacuum line techniques. THF and diethyl ether were dried over sodium benzophenone ketyl and distilled before use. All organic chemicals were purchased and used as received from Aldrich. NMR spectra of substances and precatalysts were recorded on Bruker AV400 or Bruker Avance-II 600 spectrometer for 1-3% solutions in deuterated solvents. NMR solvents were purchased from Deutero GmbH. Chemical shifts were reported using the residual solvent signal. Ti(NMe.sub.2).sub.2Cl.sub.2 [C. Wang et. al., Organometallics 2005, 24(20), 4760], Zr(NMe.sub.2).sub.2Cl.sub.2thf.sub.2 and Hf(NMe.sub.2).sub.2Cl.sub.2thf.sub.2 [S. Brenner et. al., Z. anorg. allg. Chem. 1995, 621, 2021], 2,4-di-ted-butyl-1-(methoxymethoxy)benzene [T. Kurahashi et. al., J. Am. Chem. Soc. 2011, 133(21), 8307], 1-[2-(methoxymethoxy)-5-methylphenyl]adamantine [JP 2018162231 (A)], 2-bromo-3-methylbut-2-enal [T. R. Ramadhar et. al., Synlett 2017, 28(20), 2865], methyl 2-bromo-3-methylbut-2-enoate [H. Mori et. al., J. Org. Chem. 1998, 63(24), 8704], 2,2′-dibromo-4,4′-di-tert-butylbiphenyl [J. Y. Corey et. al., Organometallics 2010, 29(21), 5708], 2,2′-dibromo-5,5′-di-tert-butylbiphenyl [H. A. Brune et. al., J. Organomet. Chem. 1991, 402(2), 171], 6,7-dibromo-1,2,3,4-tetrahydro-1,1,4,4-tetramethylnaphthalene [I. Rose et. al., Nat. Mater. 2017, 16(9), 932], 2-ted-butyl-4-fluorophenol [US Patent WO2008/147952A1], N-tert-butyl-4-methylaniline [J. R. Gage et. al., J. Org. Chem. 1995, 60(8), 2613], 2-bromo-N-phenylaniline [C. A. Wheaton et. al., Organometallics 2013, 32(21), 6148] were prepared according to the literature procedures.

[0075] 2-tert-Butyl-4-fluoro-1-(methoxymethoxy)benzene. 2-tert-Butyl-4-fluorophenol (4.3 g, 26.0 mmol) was added in small portions to NaH (60% dispersion in mineral oil, 1.1 g, 26.8 mmol) in THF (100 ml) at 0° C. Further on, this mixture was warmed up to room temperature, then cooled to 0° C., and MOMCl (2.8 g, 36.4 mmol) was added dropwise. The reaction mixture was stirred overnight at room temperature then poured into cold water, and the organic layer was separated. The aqueous layer was extracted with ether (2×100 ml). The combined organic extract was dried over Na.sub.2SO.sub.4 and then evaporated to dryness. The product was isolated by flash-chromatography on silica gel 60 (40-63 um; eluent: hexane-dichloromethane=5:1, vol.) giving 4.8 g (87%) of a colorless oil.

[0076] 3,3′-Dibromo-5,5,5′,5′,8,8,8′,8′-octamethyl-5,5′,6,6′,7,7′,8,8′-octahydro-2,2′-binaphthalene. 34.6 ml nBuLi (86.7 mmol, 2.5 M in n-hexanes) was added dropwise to a solution of 60.0 g (173 mmol) of 6,7-dibromo-1,2,3,4-tetrahydro-1,1,4,4-tetramethylnaphthalene in THF (500 mL) by vigorous stirring for 30 min at −78° C. Further on, this mixture was warmed to 0° C., and 10 ml of 3 M HCl was added. The organic solvents were removed by rotary evaporation, and the residue was extracted with diethyl ether. The combined extract was concentrated under reduced pressure, and the crude product was purified by recrystallization from a mixture of isopropanol and dichloromethane to give 37.05 g (80%) of pure product.

[0077] 2-Bromo-N-(tert-butyl)-4-methylaniline. To a solution of 17.4 g (0.107 mmol) of N-(tert-butyl)-4-methylaniline in 100 ml of DMF a solution of 18.7 g (0.105 mol) of N-bromosuccinimide in 100 ml of DMF was added dropwise at 0° C. The reaction mixture was stirred overnight at room temperature and then poured into 500 ml of water. The obtained mixture was extracted with ether (3×100 ml). The combined organic extract was washed with water (3×200 ml), dried over Na.sub.2SO.sub.4, and then evaporated to dryness. The residue was distilled in vacuum to give 20.2 g (78%) of the tale product as a colorless oil, b.p. 100-105° C./1 mbar.

[0078] 2-Bromo-trans-stilbene (L1). A mixture of benzyl chloride (7.0 g, 55.3 mmol) and triethyl phosphite (10.1 g, 60.8 mmol) was stirred under nitrogen for 17 h at 160° C. Further on, this mixture was cooled to room temperature and then diluted with 150 ml of THF. The resulting solution was cooled to 0° C., and 2.0 g of NaH (83.0 mmol) was added at 0° C. The obtained mixture was stirred for 30 min at 0° C., and then o-bromobenzaldehyde (11.3 g, 60.9 mmol) was added via a syringe at 0° C. The formed mixture was stirred for 18 h at room temperature, then diluted with diethyl ether (400 ml), washed with water (4×100 ml). The organic phase was separated, dried over Na.sub.2SO.sub.4, and evaporated to dryness. The residue was distilled in vacuum giving 10.0 g (70%) of L1, b.p.=125-135° C./1 mbar.

[0079] 1-(1-Bromo-2-methylprop-1-en-1-yl)-2-phenyl-1H-indene (L2). To a solution of 2-bromo-trans-stilbene (5.0 g, 19.3 mmol) in 100 ml of THF nBuLi in hexanes (8.1 ml, 2.5 M, 20.3 mmol) was added dropwise at −78° C. This mixture was stirred for 40 min at −78° C., and then 2-bromo-3-methylbut-2-enal (4.1 g, 25.1 mmol) was added dropwise at −78° C. The resulting mixture was warmed to −30° C., and then saturated aqueous NH.sub.4Cl (100 ml) was added. This mixture was extracted with diethyl ether (3×100 ml), the combined organic phase was collected, dried over Na.sub.2SO.sub.4, and then evaporated to dryness. To the residue toluene (1.2 L) and TsOH (4.0 g, 23.2 mmol) were added, and the resulting mixture was refluxed with Dean-Stark head for 3 h. Next, the formed hot solution was passed through the short pad of Celite, and the filtrate was evaporated to dryness. The residue was recrystallized from hexane giving a white solid (3.5 g, 56%).

[0080] 3-[1-(3,5-Di-tert-butyl-2-(methoxymethoxy)phenyl)-2-methylprop-1-en-1-yl]-2-phenyl-1H-indene (L3). To a solution of 2,4-di-tert-butyl-1-(methoxymethoxy)benzene (6.9 g, 27.2 mmol) in 100 ml of diethyl ether nBuLi in hexanes (11.1 ml, 2.5 M, 27.7 mmol) was added at room temperature. This mixture was stirred overnight at room temperature, cooled to −78° C., and then a solution of 12 (3.0 g, 9.2 mmol) in 40 ml of THF was added. The resulting mixture was stirred overnight at room temperature and then poured into 200 ml of water. The organic layer was separated, and the aqueous layer was extracted with diethyl ether (3×50 ml). The combined organic extract was dried over Na.sub.2SO.sub.4 and then evaporated to dryness. The product was isolated via flash chromatography on silica gel 60 (40-63 um, eluent: hexane-dichloromethane=from 10:1 to 3:1, vol.) giving 3.5 g (77%) of a yellow solid.

[0081] 2,4-Di-tert-butyl-6-[2-methyl-1-(2-phenyl-1H-inden-3-yl)prop-1-en-1-yl]phenol (L4). To a solution of L3 (3.5 g, 7.1 mmol) in a mixture of THF (100 ml) and methanol (200 ml) 0.3 ml of 12 M HCl was added, and this mixture was stirred overnight at 50° C. Further on, the obtained mixture was evaporated to dryness, and the product was isolated from the residue by flash chromatography on silica gel 60 (40-63 um, eluent: hexane-dichloromethane=10:1, vol.). Yield: 2.8 g (88%) of an orange oil.

[0082] General procedure A for synthesis of half-metallocene dichloride complexes. .sup.nBuLi (2.5 M, 12.8 mmol) was added to a solution of proligand (6.4 mmol) in 60 mL of THF at −78° C. The obtained mixture was allowed to warm to room temperature and then stirred for 2 h. Further on, this solution was cooled to −78° C., and Ti(NMe.sub.2).sub.2Cl.sub.2 or M(NMe.sub.2).sub.2Cl.sub.2(THF).sub.2 (M=Zr or Hf) (6.4 mmol) was added in one portion at −78° C. The resulting mixture was warmed to room temperature, and then the solvent was evaporated. The residue was extracted with hot toluene, and insoluble materials were removed by filtration through Celite. Further on, dimethyldichlorosilane (0.86 ml, 7.05 mmol) was added to the filtrate at room temperature, the resulting mixture was stirred for 16 h at 50° C., then cooled to room temperature, and finally passed through a short pad of Celite. The filtrate was evaporated to dryness, the residue was triturated in hot hexane (50 ml), and the formed suspension was filtered through glass frit (G4). If needed the precipitate (the desired product) can be recrystallyzed from toluene-hexane.

[0083] General procedure B for synthesis of half-metallocene dimethyl complexes. A solution of MeMgBr in ether (2.9 M, 22 mmol) was added to a suspension of the respective half-metallocene dichloride complex (10 mmol) in ether (100 ml) at −30° C. The resulting mixture was stirred for 22 h at room temperature. Then, the solvent was evaporated in vacuum, the residue was extracted with hot toluene, and insoluble materials were removed by filtration through a short pad of Celite. The obtained filtrate was evaporated to dryness in vacuum, and the residue was recrystallized from toluene-hexane at −30° C. The precipitated solid was collected, washed with small amount of hexane, and then dried in vacuum.

[0084] Complex L5 (=I-1). General procedure A was applied to L4 to yield L5, which corresponds to inventive compound 1-1.

[0085] Complex L6 (=I-5). General procedure B was applied to L5 to yield L6, which corresponds to inventive compound 1-5.

[0086] General procedure C for syntheses of substituted 9-(1-bromo-2-methylprop-1-en-1-yl)-9H-fluoren-9-ols. To a solution of substituted 2,2′-dibromobiphenyl (110.6 mmol) in diethyl ether (800 ml) nBuLi in hexanes (90.3 ml, 2.5 M, 221.2 mmol) was added dropwise at 0° C. The formed slurry was stirred for 1 h at 0° C., and then anhydrous MgBr.sub.2 (40.7 g, 221.2 mmol) was added in one portion. The resulting mixture was stirred for another 1 h at 0° C., and then methyl 2-bromo-3-methylbut-2-enoate (21.4 g, 110.6 mmol) was added. The obtained mixture was stirred overnight at room temperature, then saturated aqueous NH.sub.4Cl (200 ml) was added. The organic layer was separated, and the aqueous layer was extracted with diethyl ether (2×200 ml). The combined organic extract was dried over Na.sub.2SO.sub.4 and then evaporated to dryness. The product was isolated by flash chromatography on silica gel 60 (40-63 um, eluent: hexane-dichloromethane=from 10:1 to 1:1, vol.).

[0087] Syntheses via general procedure C: 9-(1-Bromo-2-methylprop-1-en-1-yl)-9H-fluoren-9-ol (F5), 9-(1-Bromo-2-methylprop-1-en-1-yl)-2,7-di-tert-butyl-9H-fluoren-9-ol (F6), 9-(1-Bromo-2-methylprop-1-en-1-yl)-3,6-di-tert-butyl-9H-fluoren-9-ol (F7), and 12-(1-Bromo-2-methylprop-1-en-1-yl)-1,1,4,4,7,7,10,10-octamethyl-2,3,4,7,8,9,10,12-octahydro-1H-dibenzo[b,h]fluoren-12-ol (F8) were each synthesized via general procedure C.

[0088] General procedure D for syntheses of substituted 9-(1-bromo-2-methylprop-1-en-1-yl)-9H-fluorenes. To a solution of substituted 9-(1-bromo-2-methylprop-1-en-1-yl)-9H-fluoren-9-ol (86.5 mmol) in dichloromethane (1.5 L) triethylsilane (68.9 ml, 432.5 mmol) was added in one portion. Further on, trifluoroacetic acid (33.1 ml, 432.5 mmol) was added dropwise by vigorous stirring at −20° C. The resulting mixture was stirred overnight at room temperature, then water (1.5 L) was added, the organic layer was separated, and the aqueous layer was extracted with dichloromethane (2×200 ml). The combined organic extract was washed with aqueous NaHCO.sub.3, then dried over Na.sub.2SO.sub.4, and evaporated to dryness. The residue was dissolved in hexane, the formed solution was passed through a short pad of silica gel 60 (40-63 um), and the elute was evaporated to dryness. The residue was dried in Kugelrohr apparatus (105° C., 0.5 mbar) for 4 h to get rid of siloxanes giving a white solid.

[0089] Syntheses via general procedure C: 9-(1-Bromo-2-methylprop-1-en-1-yl)-9H-fluorene (F9), 9-(1-Bromo-2-methylprop-1-en-1-yl)-2,7-di-tert-butyl-9H-fluorene (F10), 9-(1-Bromo-2-methylprop-1-en-1-yl)-3,6-di-tert-butyl-9H-fluorene (F11), and 12-(1-Bromo-2-methylprop-1-en-1-yl)-1,1,4,4,7,7,10,10-octamethyl-2,3,4,7,8,9,10,12-octahydro-1H-dibenzo[b,h]fluorine (F12) were each synthesized via general procedure D.

[0090] General procedure E for syntheses of substituted 9-(2-methylprop-1-en-1-ylidene)-9H-fluorenes. To solution of substituted 9-(1-bromo-2-methylprop-1-en-1-yl)-9H-fluorene (10.0 mmol) in 120 ml of THF lithium diisopropylamide mono(tetrahydrofuran) in cyclohexane (6.7 ml, 1.5 M, 10.1 mmol) was added at −78° C. This mixture was stirred for 2 h at room temperature, then poured into water (300 ml). The organic layer was separated, the aqueous layer was extracted with diethyl ether (3×50 ml). The combined organic extract was dried over Na.sub.2SO.sub.4 and then evaporated to dryness. The product was isolated by flash chromatography on silica gel 60 (40-63 um; eluent: hexane) giving a white solid.

[0091] Syntheses via general procedure E: 9-(2-Methylprop-1-en-1-ylidene)-9H-fluorene (F13), 2,7-Di-tert-butyl-9-(2-methylprop-1-en-1-ylidene)-9H-fluorene (F14), 3,6-Di-tert-butyl-9-(2-methylprop-1-en-1-ylidene)-9H-fluorene (F15), and 1,1,4,4,7,7,10,10-Octamethyl-12-(2-methylprop-1-en-1-ylidene)-2,3,4,7,8,9,10,12-octahydro-1H-dibenzo[b,h]fluorine (F16) were each synthesized via general procedure E.

[0092] General procedure F for syntheses of substituted (1-[2-(methoxymethoxy)phenyl]-2-methylprop-1-en-1-yl)-9,9a-dihydro-4aH-fluorenes. To a solution of ortho-substituted methoxymethoxybenzene (27.2 mmol) in diethyl ether (100 ml) nBuLi in hexanes (11.1 ml, 2.5 M, 27.7 mmol) was added at room temperature. This mixture was stirred overnight at room temperature, then cooled to −78° C., and a solution of substituted 9-(2-methylprop-1-en-1-ylidene)-9H-fluorene (9.2 mmol) in 40 ml of THF was added. The resulting mixture was stirred overnight at room temperature, then poured into water (200 ml). The organic layer was separated, and the aqueous layer was extracted with diethyl ether (3×50 ml). The combined organic extract was dried over Na.sub.2SO.sub.4 and then evaporated to dryness. The product was isolated by flash chromatography on silica gel 60 (40-63 um; eluent: hexane-dichloromethane=from 10:1 to 3:1, vol.) as a yellow oil.

[0093] Syntheses via general procedure F: 9-{1-[3,5-Di-tert-butyl-2-(methoxymethoxy)phenyl]-2-methylprop-1-en-1-yl}-9,9a-dihydro-4aH-fluorene (F17), 2,7-Di-tert-butyl-9-(1-[3,5-di-tert-butyl-2-(methoxmethoxy)phenyl]-2-methylprop-1-en-1-yl)-9,9a-dihydro-4aH-fluorene (F18), 2,7-Di-tert-butyl-9-{1-[3-tert-butyl-5-fluoro-2-(methoxymethoxy)phenyl]-2-methylprop-1-en-1-yl}-9,9a-dihydro-4aH-fluorene (F19), 2,7-Di-tert-butyl-9-{1-[3-(1-adamantyl)-2-(methoxmethoxy)-5-methylphenyl]-2-methylprop-1-en-1-yl}-9,9a-dihydro-4aH-fluorene (F20), 3,6-Di-tert-butyl-9-{1-[3,5-di-tert-butyl-2-(methoxmethoxy)phenyl]-2-methylprop-1-en-1-yl}-9,9a-dihydro-4aH-fluorene (F21), and 12-(1-[3,5-Di-tert-butyl-2-(methoxymethoxy)phenyl]-2-methylprop-1-en-1-yl)-1,1,4,4,7,7,10,10-octamethyl-2,3,4,7,8,9,10,12-octahydro-1H-dibenzo[b,h]fluorine (F22) were each synthesized via general procedure F.

[0094] General procedure G for syntheses of substituted 2-[1-(9,9a-dihydro-4aH-fluoren-9-yl)-2-methylprop-1-en-1-yl]phenols. To the obtained (1-[2-(methoxymethoxy)phenyl]-2-methylprop-1-en-1-yl)-9,9a-dihydro-4aH-fluorene (7.0 mmol) 50 ml of THF, 50 ml of methanol and 1 ml of 12 M HCl were subsequently added. The reaction mixture was stirred for three days (monitored by LC/MS) at 60° C. and then poured into 200 ml of water. The obtained mixture was extracted with dichloromethane (3×50 ml), the combined organic extract was dried over Na.sub.2SO.sub.4 and then evaporated to dryness. The product was isolated by flash chromatography on silica gel 60 (40-63 um; eluent: hexane-dichloromethane=10:1, vol.) giving a yellow oil.

[0095] Syntheses via general procedure G: 2,4-Di-tert-butyl-6-[1-(9,9a-dihydro-4aH-fluoren-9-yl)-2-methylprop-1-en-1-yl]phenol (F23), 2,4-Di-tert-butyl-6-[1-(2,7-di-tert-butyl-9,9a-dihydro-4aH-fluoren-9-yl)-2-methylprop-1-en-1-yl]phenol (F24), 2-Tert-butyl-4-fluoro-6-[1-(2,7-di-tert-butyl-9,9a-dihydro-4aH-fluoren-9-yl)-2-methylprop-1-en-1-yl]phenol (F25), 2-(1-Adamantyl)-4-methyl-6-[1-(2,7-di-tert-butyl-9,9a-dihydro-4aH-fluoren-9-yl)-2-methylprop-1-en-1-yl]phenol (F26), 2,4-Di-tert-butyl-6-[1-(3,6-d i-tert-butyl-9,9a-dihydro-4aH-fluoren-9-yl)-2-methylprop-1-en-1-yl]phenol (F27), and 2,4-Di-tert-butyl-6-[2-methyl-1-(1,1,4,4,7,7,10,10-octamethyl-2,3,4,7,8,9,10,12-octahydro-1H-dibenzo[b,h]fluoren-12-yl)prop-1-en-1-yl]phenol (F28) were each synthesized via general procedure G.

[0096] Syntheses via general procedure A: Complex F29, corresponding to inventive compound I-3, starting from F23; Complex F30, corresponding to inventive compound 1-2, starting from F24; Complex F31, starting from F24; Complex F32, starting from F24; Complex F33, starting from F25; Complex F34, corresponding to inventive compound 1-8, starting from F26; Complex F35, starting from F27; and Complex F36, corresponding to inventive compound 1-4, starting from F28, were each synthesized via general procedure A.

[0097] Syntheses via general procedure B: Complex F37, starting from F29; Complex F38, starting from FF30; Complex F39, starting from F31; Complex F40, starting from F32; and Complex F41, starting from F36, were each synthesized via general procedure A.

[0098] N-(tert-Butyl)-2-[1-(2,7-di-tert-butyl-9H-fluoren-9-yl)-2-methylprop-1-en-1-yl]-4-methylaniline (A1). To a solution of (tBu)(2-Br-4-MeC.sub.6H.sub.3)NH (5.0 g, 20.6 mmol) and TMEDA (6.5 mL, 43.4 mmol) in ether (50 mL) 2.1 equiv of nBuLi (17.3 mL, 2.5 M in hexanes, 43.4 mmol) was added dropwise by vigorous stirring at −35° C. A light yellow precipitate formed immediately. The resulting mixture was allowed to warm up to room temperature, and the precipitate was filtered off (G3), then dried in vacuum giving 2.2 g of a white solid (supposedly (tBu)[(TMEDA)Li(2-[4-MeC.sub.6H.sub.3]-1)]NLi(TMEDA), 5.4 mmol). To a solution of 2,7-di-tert-butyl-9-(2-methylprop-1-en-1-ylidene)-9H-fluorene (F14) (1.8 g, 5.4 mmol) in THF (30 ml) the above-described precipitate (2.2 g, 5.4 mmol) was added in one portion at −30° C. The obtained mixture was stirred overnight at room temperature forming red-orange solution. This solution was poured into water (100 ml), the crude product was extracted with diethyl ether (3×50 ml). The combined organic extract was dried over Na.sub.2SO.sub.4 and then evaporated to dryness. The product was isolated from the residue by flash chromatography on silica gel 60 (40-63 um; eluent: hexane-dichloromethane=10:1, vol.) giving 2.5 g (79% relative to allene) of a yellow glassy material.

[0099] N-Phenyl-2-[1-(2,7-di-tert-butyl-9H-fluoren-9-yl)-2-methylprop-1-en-1-yl]-aniline (A2). To a solution of (Ph)(2-BrC.sub.6H.sub.4)NH (5.8 g, 23.2 mmol) and TMEDA (7.3 mL, 48.7 mmol) in ether (60 mL) 2.1 equiv of nBuLi (19.5 mL, 2.5 M in hexanes, 48.7 mmol) was added dropwise by vigorous stirring at −35° C. A light yellow precipitate formed immediately. This mixture was allowed to warm up to room temperature, and the precipitate was filtered off (G3) and then dried in vacuum giving 1.3 g of a white solid (supposedly (Ph)[(TMEDA)Li(1-C.sub.6H.sub.4-2)]NLi(TMEDA), 3.14 mmol). To a solution of 2,7-di-tert-butyl-9-(2-methylprop-1-en-1-ylidene)-9H-fluorene (F14) (0.7 g, 2.1 mmol) in THF (20 ml) the above-described precipitate was added in one portion at −30° C. The formed mixture was stirred overnight at room temperature giving a red-orange solution which was then poured into water (100 ml). The crude product was extracted with diethyl ether (3×50 ml). The combined organic extract was dried over Na.sub.2SO.sub.4 and then evaporated to dryness. The product was isolated by flash chromatography on silica gel 60 (40-63 um, eluent: hexane-dichloromethane=10:1, vol.) giving 0.93 g (89% relative to allene) of a yellow glassy material.

[0100] Syntheses via general procedure A: Complex A3, corresponding to inventive compound 1-6, starting from A1; Complex A4, starting from A2; and Complex A5, corresponding to inventive compound 1-7 were each synthesized via general procedure A.

[0101] Compound C-4 was manufactured according to the procedure of Yano et al.

Polymerisation

[0102] Using the above listed inventive and comparative compounds as catalysts, a number of polymerisation experiments were conducted, of which the results are listed below.

[0103] The polymerizations were carried out in a Parallel Pressure Reactor (PPR48) for olefin polymerization. This equipment, containing 48 reactors mounted in a triple glove-box, was sold commercially by the company Symyx, thereafter by the company Freeslate. The applied polymerization protocols were as follows:

[0104] Prior to the execution of a library, the 48 PPR cells (reactors) undergo ‘bake-and-purge’ cycles overnight (8 h at 90-140° C. with intermittent dry N2 flow), to remove any contaminants and left-overs from previous experiments. After cooling to glove-box temperature, the stir tops are taken off, and the cells are fitted with disposable 10 mL glass inserts and PEEK stirring paddles (previously hot-dried under vacuum); the stir tops are then set back in place, the cells are loaded with the proper amounts of toluene (in the range 2.0-4.0 mL), comonomer (in the range 0.05-2.0 mL) and a tri-iso-butyl-aluminium (TiBAl)/butylated-hydroxy-toluene (BHT) (1:1 reaction product) solution, thermostated at 80° C., and brought to the operating pressure of 65 psig with ethylene. The TiBAl/BHT amount was chosen such that [Al]=3 mM.

[0105] The activator was trityl-tetrakis-pentafluorophenylborate (TTB) using a [B]/[Ti] molar ratio of 10. The catalyst injection sequence is as follows: proper volumes of a toluene ‘chaser’, a solution of the precatalyst in toluene (typically in the range 0.005-0.05 mmol L−1), and a toluene ‘buffer’ are uptaken into the slurry needle, and then injected into the cell of destination. The reaction is left to proceed under stirring (800 rpm) at constant temperature and pressure with continuous feed of ethylene for 5-60 min, and quenched by over-pressurizing the cell with dry air (preferred to other possible catalyst poisons because in case of cell or quench line leaks oxygen is promptly detected by the dedicated glove-box sensor).

[0106] After quenching, the cells are cooled down and vented, the stir-tops are removed, and the glass inserts containing the reaction phase are taken out and transferred to a Genevac EZ2-Plus centrifugal evaporator, where all volatiles are distilled out and the polymers are thoroughly dried overnight. Reaction yields are double-checked against on-line monomer conversion measurements by robotically weighing the dry polymers in a Bohdan Balance Automator while still in the reaction vials (subtracting the pre-recorded tare). Polymer aliquots are then sampled out for the characterizations.

[0107] GPC curves are recorded with a Freeslate Rapid GPC setup, equipped with a set of 2 mixed-bed Agilent PLgel 10 μm columns and a Polymer Char IR4 detector. The upper deck of the setup features a sample dissolution station for up to 48 samples in 10 mL magnetically stirred glass vials, 4 thermostated bays each accommodating 48 polymer solutions in 10 mL glass vials, and a dual arm robot with two heated injection needles. With robotic operation, pre-weighed polymer amounts (typically 1-4 mg) are dissolved in proper volumes of orthodichlorobenzene (ODCB) containing 0.40 mg mL−1 of 4-methyl-2,6-di-tert-butylphenol (BHT) as a stabilizer, so as to obtain solutions at a concentration of 0.5 to 1.0 mg mL−1. After 2-4 h at 150° C. under gentle stirring to ensure complete dissolution, the samples are transferred to a thermostated bay at 145° C., and sequentially injected into the system at 145° C. and a flow rate of 1.0 mL min-1. In post-trigger delay operation mode, the analysis time is 12.5 min per sample. Calibration is carried out with the universal method, using 10 monodisperse polystyrene samples (Mn between 1.3 and 3700 KDa). Before and after each campaign, samples from a known i-PP batch produced with an ansa-zirconocene catalyst are analyzed for a consistency check. The weight average molecular weight (M.sub.w) is expressed in kg/mol.

[0108] .sup.13C NMR spectra are recorded with a Bruker Avance 400 III spectrometer equipped with a 5 mm High Temperature Cryoprobe, and a robotic sample changer with pre-heated carousel (24 positions). The samples (20-30 mg) are dissolved at 120° C. in tetrachloroethane-1,2-d2 (0.6 mL), added with 0.40 mg mL−1 of BHT as a stabilizer, and loaded in the carousel maintained at the same temperature. The spectra are taken sequentially with automated tuning, matching and shimming. Typical operating conditions for routine measurements are: 45° pulse; acquisition time, 2.7 s; relaxation delay, 5.0 s; 400-800 transients (corresponding to an analysis time of 30-60 min). Broad-band proton decoupling is achieved with a modified WALTZ16 sequence (BI_WALTZ16_32 by Bruker).

[0109] Unless specified otherwise, the catalyst activity is indicated by Rp, the calculated polymerisation rate, expressed as kilograms of copolymer, produced per mmol of catalyst per mol of ethylene in the reactor-diluent per hour.

[0110] The weight average molecular weight M.sub.w and the number average molecular weight M.sub.n were determined in accordance with ASTM D6474 (2012), and expressed in kg/mol. The molecular weight distribution MWD is calculated as M.sub.w/M.sub.n.

[0111] Experiments 1-23 were conducted as copolymerisation experiments using 1-hexene (C6) as comonomer, or homopolymerisation experiments, i.e. in those experiments where the vol % of C6 is 0.

TABLE-US-00001 C6 M.sub.n M.sub.w PDI C6 inc Exp. Cat. (vol %) Activity - Rp (kg/mol) (kg/mol) (M.sub.w/M.sub.n) (mol %) 1 I-1 1 7540 84 200 2.4 5.0 2 2 3360 65 126 1.9 8.4 3 I-2 1 1180 130 430 3.3 7.2 4 2 1490 96 330 3.4 14.0  5 I-3 1 880 143 432 3.0 5.0 6 2 2250 82 202 2.5 10.4  7 I-4 1 360 192 689 3.6 6.9 8 2 860 152 443 2.9 7.9 9 I-5 1 4560 93 201 2.2 4.4 10 2 3600 53 115 2.2 8.2 11 I-6 2 3 186 1288 6.9 4.5 12 I-7 2 1 165 462 2.8 7.5 13 I-8 2 530 112 368 3.3 8.0 14 C-1 0 120 — — — — 15 10 74 — 0.7 — — 16 C-2 5 130 227 683 3.0 3.8 17 10 140 218 631 2.9 6.4 18 C-3 2 1260 16 36 2.3 5.3 19 C-4 1 620 188 470 2.5 1.3 20 5 580 144 345 2.4 6.6 21 C-5 0 590 — — — — 22 1 950 9 17 1.9 6.1 23 2 4130 4.1 10 2.5 11.0 

[0112] Comparative compounds C-1, C-3 and C-5 result in low molecular weight copolymers. Comparative compound C-2 results in relatively low activities and modest comonomer incorporation. The latter is indicated by experiment 17, which shows that in order to obtain >5 mol % 1-hexene incorporation, 10 vol % 1-hexene loading is required, which is 5 to 10 times higher loading of 1-hexene compared to the inventive compounds. Comparative compound C-4 results in relatively low comonomer incorporation, as indicated by the fact that for instance at 1 vol % 1-hexene loading, only 1.3 mol % 1-hexene is incorporated, being significantly lower compared to the experiments with the inventive compounds at 1 vol % 1-hexene loading.

[0113] From these results, it is apparent that the inventive compounds result in catalysts that display an excellent comonomer incorporation, as is illustrated by the higher hexene incorporation in comparison to the comparative catalysts. In addition, the inventive catalysts display high catalyst activity combined with high molecular weight copolymers.

[0114] In experiments 24 and 25, the inventive compound 1-1 was tested in copolymerizations of ethylene with 4-methyl-pentene-1 (4MP1) and vinyl-cyclohexane (VCH).

TABLE-US-00002 Loading of Comonomer comonomer M.sub.n M.sub.w PDI incorporation Exp. Comonomer (vol %) Activity - Rp (kg/mol) (kg/mol) (M.sub.w/M.sub.n) (mol %) 24 4MP1 2.0 6560 45 95 2.1 4.5 25 VCH 5.0 3220 13 25 1.9 5.8

[0115] These results illustrate that the inventive compounds result in catalysts that display excellent incorporation of sterically hindered olefins.