ELECTRODE ASSEMBLY
20220357189 · 2022-11-10
Inventors
- Michael Cantor (Cambridge Cambridgeshire, GB)
- Andrew Dames (Cambridge Cambridgeshire, GB)
- Matthew Price (Cambridge Cambridgeshire, GB)
- Paul Dunaway (Cary, NC, US)
- Mike Zimmerman (Uniontown, PA, US)
- James Evett (Winslow Buckinghamshire, GB)
Cpc classification
International classification
Abstract
An electrode assembly for an electromagnetic flow meter (1; FIG. 1) is disclosed. The electrode assembly comprises a housing, which may be a flow tube (2; FIG. 1) of the electromagnetic flow meter, having a passage (123) between first and second ends (1241, 1242), an electrode (125) comprising a plug of porous material, for example formed of porous graphite, at least partially disposed within the passage proximate the first end, and an electrically-conductive polymer connector (125) at least partially disposed within the passage and in direct contact with the electrode.
Claims
1. An electrode assembly for an electromagnetic flow meter, the electrode assembly comprising: a housing having a passage between first and second ends; an electrode comprising a plug of porous material at least partially disposed within the passage proximate the first end; and an electrically-conductive polymer connector at least partially disposed within the passage and in direct contact with the electrode.
2. The electrode assembly of claim 1, wherein the electrode comprises or is formed from graphite.
3. The electrode assembly of claim 1, wherein the electrically-conductive polymer connector is an electrically-conductive polymer seal disposed within the passage, interposed between the electrode and a further connector, and is arranged to electrically connect the electrode and the further connector and to provide a fluid-tight seal in the passage between the electrode and the further connector.
4. The electrode assembly of claim 3, wherein the further connector comprises or is predominantly formed of electrically-conductive polymer or a non-noble metal, for example, copper, or an alloy comprising a non-noble metal, such as brass.
5. (canceled)
6. The electrode assembly of claim 1, wherein the electrically-conductive polymer connector is at least partially disposed within the passage in direct electrical contact with the electrode, wherein the assembly further comprises: a seal, a weld and/or a bond line to provide a fluid-tight seal between the first end of the passage and a non-wetted section of the flow meter.
7. The electrode assembly of claim 1, wherein the electrically-conductive polymer connector comprises or is predominantly formed from an elastomer.
8. The electrode assembly of claim 1, wherein the electrically-conductive polymer connector abuts the electrode and/or is compressed and/or is compressed against the electrode.
9. (canceled)
10. (canceled)
11. (canceled)
12. The electrode assembly of claim 1, wherein the electrically-conductive polymer connector, the seal, the weld and/or the bond line is/are arranged to withstand a pressure of at least 6.5 MPa.
13. The electrode assembly of claim 1, wherein the electrically-conductive polymer connector comprises or is predominantly formed from silicone.
14. (canceled)
15. The electrode assembly of claim 1, wherein the electrically-conductive polymer connector comprises particles of electrically-conductive material.
16. The electrode assembly of claim 15, wherein the electrically-conductive material is carbon.
17. The electrode assembly of claim 1, wherein the electrically-conductive polymer connector comprises carbon black.
18. (canceled)
19. (canceled)
20. The electrode assembly of claim 1, wherein the electrically-conductive polymer connector is seated in the electrode.
21. An electromagnetic flow meter comprising: a flow tube having a flow passage; first and second electrode assemblies disposed on opposite sides of the flow tube, each of the first and second electrode assemblies respectively comprising the electrode assembly of claim 1, and the first and second electrode assemblies arranged such that respective electrodes are in fluid communication with the flow passage; and a magnetic field source for providing a magnetic field across the flow passage between the electrodes.
22. The electromagnetic flow meter of claim 21, wherein the flow tube provides respective housings for the first and second electrode assemblies.
23. The electromagnetic flow meter of claim 21, wherein the magnetic field source comprises: a length of remanent magnetic material; and a coil wound around at least a portion of the length of remanent magnetic material.
24. The electromagnetic flow meter of claim 21, further comprising: circuitry connected directly or indirectly to the further connectors or the electrically-conductive polymer connectors arranged to perform a flow measurement.
25. The electrode assembly of claim 1, further comprising: a further connector, wherein the electrically-conductive polymer connector is disposed within the passage interposed between the electrode and the further connector and is arranged to electrically connect the electrode and the further connector.
26. The electrode assembly of claim 25, wherein the further connector comprises or is predominantly formed of a non-noble metal or an alloy comprising a non-noble metal
27. The electrode assembly of claim 25, further comprising: a seal to provide a fluid-tight seal between the first and second ends of the passage.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0036] Certain embodiments of the present invention will now be described, by way of example, with reference to the accompanying drawings, in which:
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DETAILED DESCRIPTION OF CERTAIN EMBODIMENTS
Electromagnetic Flow Meter 1
[0054] Referring to
[0055] The flow meter 1 includes a flow tube 2 defining a flow passage 3 for a fluid 4 having a direction of flow 5 (in this case, along the x-axis), a magnetic field source in the form of a coil (not shown), first and second poles 7 for providing a transverse magnetic field 8 (in this case, along the z-axis) to the flow passage 3 from the coil (not shown) and a pair of electrodes 9 which face each other on opposite sides of the flow tube 2 and which are exposed to the flow passage 3 so as to be in contact with the fluid 4 when it flows through the flow passage. The electrodes 9 are arranged along a line 10 (in this case, along the y-axis) which is perpendicular to both the direction of flow 5 and the magnetic field 8. The flow tube 2 comprises or is lined with an electrically-insulating material, such as a suitable plastic.
[0056] When an electrically-conductive fluid 4, such as ion-containing water, a mixture of water and glycol, or other suitable fluid, flows through flow passage 3 and through the magnetic field 8, an electromotive force (emf) is induced which can be measured by a circuitry 11 using the electrodes 7. The emf is proportional to the velocity of the fluid 4. Thus, the flow rate of the fluid 4 can be determined.
First Electrode Assembly 121
[0057] Referring to
[0058] The electrode assembly 121 comprises a housing 122, which in this case takes the form of the flow tube 2 (
[0059] The electrode assembly 121 comprises an electrode 125 (for providing the electrode 9 in
[0060] The electrode assembly 121 further comprises a first connector 126 (or “terminal”) in the form of a metal pin, disposed within the passage proximate the second end of the passage 123 and an electrically-conductive polymer connector 127 (also referred to as an “electrically-conductive polymer seal”) disposed within the passage 123, interposed between the electrode 125 and the first connector 126 (which may also be referred to as a “further connector”). The further connector 126 may be made from brass or other relatively inexpensive conductive metal, such as copper, or metal alloy, but may have a surface coating of gold. The further connector 126 may be made from a conductive polymer. The electrically-conductive polymer seal 127 may be formed from an elastomer, such as silicone or ethylene propylene diene monomer (EPDM) rubber loaded, with particles of electrically-conductive material, such as carbon (for example, in the form of carbon black or carbon nanotubes) or silver (for example, in the form of silver flakes).
[0061] The electrically-conductive polymer seal 127 is arranged to electrically connect the electrode 125 and pin 126 and to provide a fluid-tight seal in the passage between the electrode 125 and pin 126. The seal 127 is generally disc-shaped, having a diameter D.sub.2 of about 4 mm and a length L.sub.2 of about 3 mm.
[0062] The further connector 126 includes a disc portion 126.sub.1 and a rod portion 126.sub.2 upstanding from the center of the disc portion 126.sub.1 extending towards the second end 124.sub.2 of the passage 123. The electrically-conductive polymer seal 127 is compressed between an outwardly-facing face 128.sub.2 of the electrode 125 and an inwardly-facing face 129 of the further connector 126. A retainer 130 may be used to maintain physical contact between the electrode 125 and pin 126. The electrode assembly 121 is formed by insert moulding of the electrode 125.
[0063] The electrically-conductive polymer seal 127 is in direct electrical contact with the graphite electrode 125 and is in direct electrical contact with the further connector 126.
[0064] In use, an inwardly-facing face 128.sub.1 (or “front face”) of the porous graphite electrode 125 is presented to the fluid 4. The fluid 4 permeates throughout the porous graphite electrode 125 to make a good electrical contact with the large surface area provided by the porous graphite electrode 125 and the fluid 4 may reach the electrically-conductive polymer seal 127. The fluid 4 is in good electrical contact with the large area provided by the porous graphite electrode 125 and the conductive polymer seal 127 make good electrical contact with the porous graphite electrode 125.
[0065] Using a graphite electrode 125 can help to reduce the cost of the flow meter while maintaining performance. Furthermore, the electrode assembly can be used in a very low-conductivity fluid (e.g., <20 μSm.sup.−1). Moreover, an ‘O’-ring need not be used to prevent fluid from reaching metrology electronics in the register (not shown).
Second Electrode Assembly 221
[0066] Referring to
[0067] The electrode assembly 221 comprises a housing 222, which in this case takes the form of the flow tube 2 (
[0068] The electrode assembly 221 comprises an electrode 225 in the form of a porous graphite plug, disposed within the passage 223 proximate the first end 224.sub.1 of the passage 223. The electrode 225 is generally cylindrical and has a front face diameter of about 4 mm and a length of about 5 to 10 mm. An inner section of the electrode 225 (i.e., the section proximate the first end of the passage) has a slightly smaller diameter than an outer section, and thus allows the electrode assembly to assembled after the housing 222 (i.e., flow tube) has been moulded.
[0069] The electrode assembly 221 further comprises a first connector 226 in the form of a metal pin, disposed within the passage 223 proximate the second end of the passage 223 and an electrically-conductive polymer connector 227 (also referred to as an “electrically-conductive polymer seal”) disposed within the passage 223, interposed between the electrode 225 and pin 226. The first connector 226 (or “further connector”) may be made from brass or other relatively inexpensive conductive metal or metal alloy. The further connector 226 may be made from a conductive polymer. The electrically-conductive polymer seal 227 may be formed from an elastomer, such as silicone or ethylene propylene diene monomer (EPDM) rubber loaded, with particles of electrically-conductive material, such as carbon (for example, in the form of carbon black or carbon nanotubes) or silver (for example, in the form of silver flakes).
[0070] The electrically-conductive polymer seal 227 is arranged to electrically connect the electrode 225 and pin 226 and to provide a fluid-tight seal in the passage between the electrode 225 and pin 226. The seal 227 is generally disc-shaped, having a diameter of about 4 mm and a length of about 3 mm.
[0071] The further connector 226 includes a disc portion 226.sub.1 and a rod portion 226.sub.2 upstanding from the centre of the disc portion 226.sub.1 extending towards the second end 224.sub.2 of the passage 223. The electrically-conductive polymer seal 227 is compressed between an outwardly-facing face 228.sub.2 of the electrode 225 and an inwardly-facing face 229 of the further connector 226.
[0072] A retainer 230, in this case in the form of a starlock washer, may be used to maintain physical contact between the electrode 225, seal 227 and further connector 226. The electrode assembly 221 is assembled after the housing 222 (i.e., flow tube) has been moulded.
[0073] The wall of the flow tube 2 may extend outwardly to provide a neck 231 to accommodate the electrode assembly 221.
[0074] The electrically-conductive polymer seal 227 is in direct electrical contact with the graphite electrode 225 and is in direct electrical contact with the further connector 226.
[0075] In use, an inwardly-facing face 228.sub.1 (or “front face”) of the porous graphite electrode 225 is presented to the fluid 4. The fluid 4 permeates throughout the porous graphite electrode 225 and may reach the electrically-conductive polymer seal 227.
[0076] The fluid 4 is in good electrical contact with the large area provided by the porous graphite electrode and the conductive polymer seal 127 make good electrical contact with the porous graphite electrode 225.
[0077] Using a graphite electrode can help to reduce the cost of the flow meter while maintaining performance. Furthermore, the assembly can be used in a very low-conductivity fluid (e.g., <20 μSm.sup.−1). Moreover, an ‘O’-ring need not be used to prevent fluid from reaching metrology electronics in the register (not shown).
Third Electrode Assembly 321
[0078] Referring to
[0079] The third electrode assembly 321 is the same as the electrode assembly 221 (
[0080] This can help to increase sealing band pressure between the inside of the passage 223 (or “bore”) and the seal 227, thus enabling operation at potentially higher water pressures.
[0081] Other parts of the third electrode assembly 321 are the same as those of the electrode assembly 221 (
Fourth Electrode Assembly 421
[0082] Referring to
[0083] The fourth electrode assembly 421 is the same as the electrode assembly 221 (
[0084] The inwardly-facing face 428.sub.1 of the electrode 425 is the same as the inwardly -facing face 228.sub.1 (
[0085] Other parts of the fourth electrode assembly 421 are the same as those of the electrode assembly 221 (
Fifth Electrode Assembly 521
[0086] Referring to
[0087] The fifth electrode assembly 521 is the same as the electrode assembly 221 (
[0088] Other parts of the fifth electrode assembly 521 are the same as those of the electrode assembly 221 (
Sixth Electrode Assembly 621
[0089] Referring to
[0090] The sixth electrode assembly 621 is the same as the electrode assembly 221 (
[0091] Other parts of the sixth electrode assembly 621 are the same as those of the electrode assembly 221 (
Seventh Electrode Assembly 721
[0092] Referring to
[0093] The seventh electrode assembly 721 is the same as the electrode assembly 221 (
[0094] The starlock washer 230 may be omitted. When the sleeve 739 is used without the starlock washer 230, it provides force for compressing the seal. The sleeve 739 may be retained by weld(s) (using ultrasonic or thermal welding) or an adhesive.
[0095] The sleeve 739 includes a through hole 740 (or “bore”) having slightly larger diameter as the outer diameter of the rod portion 226.sub.1 of the further connector 226. The sleeve 739 includes a stepped outer surface 742 which corresponds to the stepped inner surface 242 of the passage 223.
[0096] The other parts of the electrode assembly 721 are the same as those of the electrode assembly 221 (
Eighth Electrode Assembly 821
[0097] Referring to
[0098] The eighth electrode assembly 821 is the same as the electrode assembly 221 (
[0099] The flexible printed circuit sheet 845 comprises a flexible electrically-insulating substrate formed from a suitable plastic, such as polyester, polyimide or PEEK, and one or more tracks (not shown) of metal or electrically-conductive polymer on the seal-facing face of the substrate.
[0100] The holding disc 846 comprises a main, flat portion 846.sub.1 and a central boss 846.sub.2 (or “stub”) which can help positioning of the starlock washer 230.
[0101] Other parts of the eighth electrode assembly 821 are the same as those of the electrode assembly 221 (
Ninth Electrode Assembly 921
[0102] Referring to
[0103] The ninth electrode assembly 921 is the same as the electrode assembly 221 (
[0104] The flexible printed circuit sheet 855 comprises a flexible electrically-insulating substrate formed from a suitable plastic, such as polyester, polyimide or PEEK, and one or more tracks (not shown) of metal or electrically-conductive polymer on the seal-facing face of the substrate.
[0105] The further connector 226 may be formed of brass and may be gold-coated. However, the further connector 226 may formed of electrically-conductive polymer. If the further connector 226 is formed of an electrically-conductive polymer, then the seal 227 may be omitted and, thus, the connector 226 may directly contact the electrode 225 provided another seal is used elsewhere. In this arrangement, the further connector 226 is referred to as an “electrically-conductive polymer connector”.
[0106] Other parts of the ninth electrode assembly 921 are the same as those of the electrode assembly 221 (
Tenth Electrode Assembly 1021
[0107] Referring to
[0108] The tenth electrode assembly 1021 is the same as the electrode assembly 221 (
[0109] The further connector 1026 may be formed of brass and may be gold-coated. However, the further connector 1026 may formed of an electrically-conductive polymer. If the further connector 1026 is formed of electrically-conductive polymer, then the seal 227 may be omitted and, thus, the connector 1026 may directly contact the electrode 225. In this arrangement, the connector 1026 is referred to as an “electrically-conductive polymer connector”.
[0110] Other parts of the tenth electrode assembly 1021 are the same as those of the electrode assembly 221 (
Eleventh Electrode Assembly 1121
[0111] Referring to
[0112] The eleventh electrode assembly 1121 is the same as the electrode assembly 221 (
[0113] Other parts of the eleventh electrode assembly 1121 are the same as those of the electrode assembly 221 (
Twelfth Electrode Assembly 1221
[0114] Referring to
[0115] The electrode assembly 1221 comprises a housing 1222, which in this case takes the form of the flow tube 2 (
[0116] The electrode assembly 1221 comprises an electrode 1225 in the form of a porous graphite plug, disposed within the passage 1223 proximate the first end 1224.sub.1 of the passage 1223. The electrode 1225 is generally cup-shaped and has a front face diameter of about 4 mm and a length of about 5 to 10 mm. An inner section of the electrode 1225 (i.e., the section proximate the first end of the passage) has a slightly smaller diameter than an outer section, although it can be larger. The electrode 1225 may be insert moulded or inserted after the housing is moulded.
[0117] The electrically-conductive polymer connector 1226 is formed from a rigid, electrically-conductive polymer which is loaded with particles of electrically-conductive material, such as carbon (for example, in the form of carbon black or carbon nanotubes) or silver (for example, in the form of silver flakes).
[0118] The plug-like electrically-conductive polymer connector 1226 is arranged to be seated in the cup-shaped electrode 1225 which includes a blind-hole 1270 for accommodating a distal end portion 1226.sub.1 of the electrically-conductive polymer connector 1226. The plug-like connector electrically-conductive polymer 1226 may be press-fitted into the cup-shaped electrode 1225. The electrode 1225 may have through-hole instead of a blind-hole.
[0119] The electrode assembly 1221 further comprises an ‘O’-ring 1271 arranged around the shaft of the electrically-conductive polymer connector 1226. The ‘O’-ring 1371 may comprise an electrically-insulating elastomer material or may comprise an electrically-conductive elastomer material, such as silicone or EPDM rubber, loaded with particles of electrically-conductive material, such as carbon (for example, in the form of carbon black or carbon nanotubes) or silver (for example, in the form of silver flakes).
[0120] A retainer 1230 may be used to maintain physical contact between the electrode 1225, and the electrically-conductive polymer connector 1226. The electrode assembly 1221 is formed by insert moulding.
[0121] In use, an inwardly-facing face 1228.sub.1 (or “front face”) of the porous graphite electrode 1225 is presented to the fluid 4. The fluid 4 permeates throughout electrode 1225 to make a good electrical contact with the large surface area provided by the porous graphite electrode 1225 and the fluid 4 may reach the electrically-conductive polymer connector 1226.
[0122] Using a graphite electrode 1225 can help to reduce the cost of the flow meter. Furthermore, the electrode assembly can be used in a very low-conductivity fluid (e.g., <20 μSm.sup.−1).
Thirteenth Electrode Assembly 1321
[0123] Referring to
[0124] The electrode assembly 1321 comprises a housing 1322, which in this case takes the form of the flow tube 2 (
[0125] The electrode assembly 1321 comprises an electrode 1325 in the form of a porous graphite plug, disposed within the passage 1323 proximate the first end 1324.sub.1 of the passage 1323. The electrode 1325 is generally cup-shaped and has a front face diameter of about 4 mm and a length of about 5 to 10 mm. An inner section 1325.sub.1 of the electrode 1325 (i.e., the section proximate the first end of the passage) has a slightly smaller diameter than an outer section 1325.sub.2, although it can be larger. The electrode 1325 may be insert moulded or inserted after the housing is moulded. The electrode 1325 includes a central blind hole 1381. The electrode 1325 may have a through-hole instead of a blind hole.
[0126] The electrode assembly 1321 further comprises a plug-like electrically-conductive polymer connector 1326 in the form of a headed, electrically-conductive polymer pin having first, second and third sections 1326.sub.1, 1326.sub.2, 1326.sub.3. The first and second sections 1326.sub.1, 1326.sub.2 are disposed within the passage 1323. The third section 1326.sub.3 provides a head which is generally wider than the passage 1323.
[0127] An inward-facing surface 1382 (or “underside”) of the third section 1326.sub.3 and an outward-facing surface 1383 (or “upper surface”) of the neck 1331 of the housing 1322 are correspondingly shaped and are arranged to form an annular face seal, e.g., using ultrasonic welding, adhesive etc. An ‘O’-ring need not be used. A radial seal may be formed by ultrasonic welding, for example, between the second section 1326.sub.2 of the electrically-conductive polymer connector 1326 and the housing neck 1331.
[0128] The electrically-conductive polymer connector 1326 is formed from a rigid, electrically-conductive polymer which is loaded with particles of electrically-conductive material, such as carbon (for example, in the form of carbon black or carbon nanotubes) or silver (for example, in the form of silver flakes).
[0129] The first section 1326.sub.1 of the electrically-conductive polymer connector 1326 is arranged to be seated in the blind-hole 1381 of the cup-shaped electrode 1325. The electrically-conductive polymer connector 1326 may be press-fitted into the cup-shaped electrode 1325.
[0130] In use, an inwardly-facing face 1328.sub.1 (or “front face”) of the porous graphite electrode 1325 is presented to the fluid 4. The fluid 4 permeates throughout electrode 1325 to make a good electrical contact with the large surface area provided by the porous graphite electrode 1325 and the fluid 4 may reach the electrically-conductive polymer connector 1326.
[0131] Using a graphite electrode 1325 can help to reduce the cost of the flow meter. Furthermore, the electrode assembly can be used in a very low-conductivity fluid (e.g., <20 μSm.sup.−1).
Fourteenth Electrode Assembly 1421
[0132] Referring to
[0133] The fourteenth electrode assembly 1421 is the same as the thirteenth electrode assembly 1321 (
[0134] Other parts of the fourteenth electrode assembly 1421 are the same as those of the thirteenth electrode assembly 1321 (
Porosity of the Electrode
[0135] In the embodiments herein described, the electrode may be formed from porous graphite.
[0136] Referring to
[0137] Spectral voltage noise density is measured using a PC-based data-acquisition system (not shown) in combination with an ultra-low-noise pre-amplifier (not shown). The electrode terminals are connected to the differential inputs of the preamplifier, which applies a gain of too to the voltage between the terminals, such that it can be readily digitized by the DAQ system with sufficient resolution. Using Welch's method, the spectral noise density is calculated from the acquired time-series. The results for 1 Hz are plotted in
[0138] The intrinsic noise density of the pre-amplifier and acquisition system is sufficiently low that its contribution to the measured noise density for the electrode pairs can be neglected.
[0139]
Volume of the Electrode
[0140] Referring to
[0141]
[0142] Reducing the magnitude of the noise density of the electrodes is important at it is superimposed on the measured emf that is proportional to the flow velocity. Thus, a lower noise density reduces the time required to average-out any noise when taking a flow measurement. Therefore, a flowmeter with a large turn down ratio (e.g., 800 or higher) becomes viable to calibrate and use. In addition, it makes flowmeters with lower turn down ratios (e.g., 250 or lower) faster to calibrate in production and so lowers the productions cost.
[0143] The noise density of a pair of electrodes at 1 Hz can be less than or equal to 90 nV/sqrt(Hz), or less than or equal 60 nV/sqrt(Hz), or less than or equal 30 nV/sqrt(Hz). The noise density of a pair of electrodes at 1 Hz can be greater than or equal to 5 nV/sqrt(Hz).
Modifications
[0144] It will be appreciated that various modifications may be made to the embodiments hereinbefore described. Such modifications may involve equivalent and other features which are already known in the design, manufacture and use of electromagnetic flow meters and component parts thereof and which may be used instead of or in addition to features already described herein. Features of one embodiment may be replaced or supplemented by features of another embodiment.
[0145] Features of one embodiment may be used in another, different embodiment and vice versa, and modifications made to one embodiment can be made to another, different embodiment.
[0146] The electrodes herein described may have multiple holes and/or through holes and/or blind holes, and may be molded into a housing and/or a flowtube or may be assembled into to a housing and/or a flowtube.
[0147] The connector may be formed of electrically-conductive polymer. If the connector is formed of an electrically-conductive polymer, then the electrically-conductive seal may be omitted and, thus, the connector may be in direct contact with the electrode.
[0148] A separate retainer need not be used. For example, the connector may include a retaining feature, such as threads or barbs.
[0149] Although claims have been formulated in this application to particular combinations of features, it should be understood that the scope of the disclosure of the present invention also includes any novel features or any novel combination of features disclosed herein either explicitly or implicitly or any generalization thereof, whether or not it relates to the same invention as presently claimed in any claim and whether or not it mitigates any or all of the same technical problems as does the present invention. The applicants hereby give notice that new claims may be formulated to such features and/or combinations of such features during the prosecution of the present application or of any further application derived therefrom.