BALLISTIC PLATE MATERIALS AND METHOD
20180243967 ยท 2018-08-30
Inventors
- Jim Curtin (Pittsford, NY, US)
- Tanner Paul Miller (Bozeman, MT, US)
- Katelyn Kalberer (Bellevue, WA, US)
- Kent D. Saucedo (Mesa, AZ, US)
Cpc classification
F41H5/0435
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F41H5/0414
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B29C51/10
PERFORMING OPERATIONS; TRANSPORTING
B29C70/44
PERFORMING OPERATIONS; TRANSPORTING
B29C51/14
PERFORMING OPERATIONS; TRANSPORTING
International classification
B29C51/14
PERFORMING OPERATIONS; TRANSPORTING
Abstract
An armor production tool including a housing having at least two housing portions that form a substantially air-tight chamber when closed. The tool can include a lower thermal diaphragm forming at least a portion of a mold, and an upper thermal diaphragm forming at least a portion of the mold and capable of engaging the lower flexible membrane. The thermal diaphragms may comprise a thermal transfer membrane, a pressure bearing membrane and a fluid dispersion layer between the thermal transfer membrane and the pressure bearing member. A heating or cooling fluid can be circulated through the fluid dispersion layer to apply heat or to cool the armor part during the molding process. The tool can include a pressure port for pressurizing the chamber and to move the thermal diaphragm towards each other to apply compression on the molded armor part, and a locking mechanism for locking the two housing portions.
Claims
1. An armor production tool, comprising: a tool upper part comprising an upper thermal diaphragm assembly that at least partially defines an upper pressure chamber and an upper molding chamber; a tool lower part operably connected to the tool upper part, the tool lower part comprising a lower thermal diaphragm assembly that at least partially defines a lower pressure chamber and a lower molding chamber; wherein one of the upper thermal diaphragm assembly or the lower thermal diaphragm assembly comprise a thermal transfer membrane proximate the respective upper or lower molding chamber, a pressure bearing membrane proximate the respective upper or pressure chamber and a fluid dispersion layer disposed between the thermal transfer membrane and the pressure bearing membrane; and wherein the fluid dispersion layer is in fluid communication with a supply of fluid for introducing one of heated or cooled fluid into the fluid dispersion layer.
2. The armor production tool of claim 1, wherein at least one of said pressure chamber of said tool upper part and said pressure chamber of said lower upper part is in fluid communication with a first pressurized fluid supply.
3. The armor production tool of claim 1, wherein pressure chamber of said tool upper part is in fluid communication with said first pressurized fluid supply and said pressure chamber of said lower upper part is in fluid communication with a second pressurized fluid supply.
4. The armor production tool of claim 1, wherein the tool upper part and the tool lower part are moveable between an open position and a closed position.
5. The armor production tool of claim 1, wherein said thermal transfer membrane, said pressure bearing membrane, and said fluid dispersion layer are flexible.
6. The armor production tool of claim 1, wherein said thermal transfer membrane, said pressure bearing membrane, and said fluid dispersion layer are elastic.
7. The armor production tool of claim 1, wherein one of the upper thermal diaphragm assembly or the lower thermal diaphragm assembly further comprises a fluid dispersion manifold disposed to sandwich said pressure bearing membrane between said fluid dispersion manifold and a sidewall of said armor production tool.
8. The armor production tool of claim 6, wherein one of the upper thermal diaphragm assembly or the lower thermal diaphragm assembly further comprises a compression/sealing ring disposed to sandwich said thermal transfer membrane between said fluid dispersion manifold and said compression/sealing ring.
9. The armor production tool of claim 7, wherein the fluid dispersion manifold is disposed around the perimeter of the thermal transfer membrane and the pressure bearing membrane, and the compression/sealing ring and is disposed around the perimeter of the thermal transfer membrane.
10. The armor production tool of claim 6, wherein the fluid dispersion manifold is in fluid communication with both the fluid dispersion layer and the supply of fluid for introducing one of heated or cooled fluid into the fluid dispersion layer.
11. A method for molding armor using the armor production tool of claim 1, the method comprising: enclosing a part of armor within a molding chamber defined by the upper molding chamber and the lower molding chamber; introducing air into at least one of said upper pressure chamber or said lower pressure chamber to apply pressure on said part within the molding chamber; circulating a heated fluid through the fluid dispersion layer of at least one of the upper thermal diaphragm assembly or the lower thermal diaphragm assembly to apply heat to said part within the molding chamber.
12. A method for producing an armor part, the method comprising: enclosing a part within a molding chamber of a molding tool, said molding chamber defined by a tool upper part and a tool lower part; introducing a pressurized gas or fluid into a pressure chamber of at least one of the tool upper part and a tool lower part, wherein said pressure chamber of said at least one of the tool upper part and the tool lower part is separated from said molding chamber by a thermal diaphragm assembly, wherein said thermal diaphragm assembly comprises a thermal transfer membrane proximate the molding chamber, a pressure bearing membrane proximate the pressure chamber of said at least one of the tool upper part and the tool lower part and a fluid dispersion layer disposed between the thermal transfer membrane and the pressure bearing membrane; circulating one of a heated fluid or a cooled fluid through said fluid dispersion layer of said thermal diaphragm assembly of said at least one of the tool upper part and the tool lower part.
13. The method of claim 12 wherein the introducing a pressurized gas or fluid step further comprises the steps of: introducing a first pressurized gas or fluid into a first pressure chamber of the tool upper part, wherein said tool upper part comprises a first thermal diaphragm assembly separating said first pressure chamber from said molding chamber; and introducing a second pressurized gas or fluid into a second pressure chamber of the tool lower part, and said tool lower part comprises a second thermal diaphragm assembly separating said second pressure chamber from said molding chamber.
14. The method of claim 13 wherein said circulating one of a heated fluid or a cooled fluid through said fluid dispersion layer of said thermal diaphragm assembly step comprises: circulating one of said heated fluid or said cooled fluid through a first fluid dispersion layer of said first thermal diaphragm assembly; and circulating one of said heated fluid or said cooled fluid through a second fluid dispersion layer of said second thermal diaphragm assembly.
15. The method of claim 14, wherein said introducing a pressurized gas step and said circulating one of a heated fluid or a cooled fluid through said fluid dispersion layer of said thermal diaphragm assembly step occur simultaneously during at least a portion of the duration of molding said part.
16. The method of claim 12 wherein said circulating one of a heated fluid or a cooled fluid through said fluid dispersion layer of said thermal diaphragm assembly step comprises: circulating one of said heated fluid or said cooled fluid through a first fluid dispersion layer of a first thermal diaphragm assembly of said tool upper part, wherein said first thermal diaphragm assembly separates a first pressure chamber of said tool upper part from said molding chamber; and circulating one of said heated fluid or said cooled fluid through a second fluid dispersion layer of a second thermal diaphragm assembly of said tool lower part, wherein said second thermal diaphragm assembly separates a second pressure chamber of said tool lower part from said molding chamber.
17. The method of claim 12, wherein said introducing a pressurized gas step and said circulating one of a heated fluid or a cooled fluid through said fluid dispersion layer of said thermal diaphragm assembly step occur simultaneously during at least a portion of the duration of molding said part.
Description
DESCRIPTION OF THE DRAWINGS
[0018] The accompanying drawings form a part of the specification and are to be read in conjunction therewith, in which like reference numerals are employed to indicate like or similar parts in the various views, and wherein:
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DETAILED DESCRIPTION
[0049] Before any embodiments of the invention are explained in detail, it is to be understood that the invention is not limited in its application to the details of construction and the arrangement of components set forth in the following description or illustrated in the following drawings. The invention is capable of other embodiments and of being practiced or of being carried out in various ways. Also, it is to be understood that the phraseology and terminology used herein is for the purpose of description and should not be regarded as limiting. The use of including, comprising, or having and variations thereof herein is meant to encompass the items listed thereafter and equivalents thereof as well as additional items. Unless specified or limited otherwise, the terms mounted, connected, supported, and coupled and variations thereof are used broadly and encompass both direct and indirect mountings, connections, supports, and couplings. Further, connected and coupled are not restricted to physical or mechanical connections or couplings.
[0050] The following discussion is presented to enable a person skilled in the art to make and use embodiments of the invention. Various modifications to the illustrated embodiments will be readily apparent to those skilled in the art, and the generic principles herein can be applied to other embodiments and applications without departing from embodiments of the invention. Thus, embodiments of the invention are not intended to be limited to embodiments shown, but are to be accorded the widest scope consistent with the principles and features disclosed herein. The following detailed description is to be read with reference to the figures, in which like elements in different figures have like reference numerals. The figures, which are not necessarily to scale, depict selected embodiments and are not intended to limit the scope of embodiments of the invention. Skilled artisans will recognize the examples provided herein have many useful alternatives and fall within the scope of embodiments of the invention.
[0051] Some embodiments of the invention include a body armor composite structure material, and apparatus and methods of fabrication. Some embodiments include a body armor composite structure material that can include stacking a plurality of layers of one or more different materials and bonding the materials to form a substantially monolithic composite article that can function as body armor. For example, as shown
[0052] For example, in some embodiments, a back-face reduction layer 150 can be coupled to the catchment layer 140. In some embodiments, an outer layer covering at least a strike-face or front impact receiving side of the body armor composite 10 (the at least one strike-face layer 120) can include a bump guard 100. In some embodiments, the bump guard 100 can include a spacer fabric, or can include polymeric foam. In some embodiments, the desired shape of the armor is defined at least by the strike-face layer 120, and any other layers can be shaped to substantially the same shape as the strike-face layer 120.
[0053] In the example embodiments shown in
[0054] In some further embodiments, the body armor composite 10 can include at least one wicking layer (not shown). In some embodiments, at least one wicking layer can be configured and arranged to substantially transport perspiration away from a user's body. For example, in some embodiments, at least one wicking layer can be coupled to an external surface of the body armor composite 10 (i.e., either to a bump guard layer 100 and/or the one or more back-face reduction layers 150). In this instance, the at least one wicking layer can be configured and arranged to contact at least one surface of a user.
[0055] In some further embodiments, the body armor composite 10 can include more or less layers and/or arrangements of layers than those shown in
[0056] In some embodiments, the body armor composite 10, 15 can include at least one strike-face 120. In some embodiments, the strike-face 120 can comprise a ceramic material. In some embodiments, the strike-face 120 can be a substantially flat or substantially planar.
[0057] In some other embodiments, particularly those designed to be used as human body armor, the strike-face 120 can include substantially non-planar portions. For example,
[0058] In some embodiments, in order to enable forming and manufacture of the body armor composite 10, 15 with one or more layers and/or portions of the body armor composite 10, 15 that can be substantially non-planar, some embodiments include a process that can include at least one manufacturing step where pre-formed layers (e.g., layers 700a positioned on preform 450 shown in
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[0060] Some embodiments of the invention include methods of forming body armor composite structures utilizing the preforms 400, 450 formed by the methods described earlier. For example, in some embodiments, body armor composite 10 as shown in
[0061] In some embodiments, the process 500 can include trimming and shaping the plurality of layers 700a that are initially formed in step 505 to a desired armor shape (e.g. to fit the strike-face 120). In some alternative embodiments, one or more of the layers 700a can be trimmed to a desired shape once the composite lay-up (e.g., 850 in
[0062] In some embodiments, resin can be applied to both top and bottom surfaces of the strike-face 120 (step 550), and the strike-face 120 can be positioned onto the preform 450 (shown as step 560). In some further embodiments, resin can be applied to the top and bottom surfaces of a strike-face reinforcement material 130 (shown as step 570), and steps 560, 570 can be repeated based on the desired number of layers of strike-face reinforcement material 130. Further, in some embodiments, resin can be applied to both top and bottom surfaces of the catchment layer 140 (shown as step 580), which can subsequently be positioned onto the preform 450 (shown as step 590). Steps 580, 590 can be repeated based on the desired number of layers of catchment layer 140. In some embodiments, resin can be applied to the bottom surfaces of the back-face reduction material 150 (shown as step 600), which can subsequently be positioned onto the preform 450 (shown as step 610, and illustrated in
[0063] In some embodiments, a release film 50 can be laid into (or otherwise applied to) the surface of the stack in step 620, and the preform 400 can be positioned on the stack (illustrated in
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[0065] In some embodiments, body armor composite 10, 15 and a wide range of other products can be formed using a method 500 shown in
[0066] Some embodiments of the invention include processes for forming body armor composite 15 or other products using flexible mold technologies. For example,
[0067] Some embodiments of the invention include preparing an assembly of a plurality of layers 700a within the mold tool 1200, and using the mold tool 1200 to laminate the layers 700a to form a monolithic structure comprising the body armor composite 15. For example, some embodiments of the invention include preparing one or more backing layers 115 in step 665. In some embodiments, one or more layers of the body armor composite 15 can be cut, shaped and/or trimmed to a shape that is substantially the same as a strike-face layer 120. In some embodiments, the strike-face layer 120 can comprise a ceramic material. A resin pre-polymer mixture can be prepared in step 670, and a front cover can be placed in the flexible mold tool 1200 (step 672). In some embodiments, the front cover can comprise a plate cover layer 160. In some embodiments, the plate cover layer 160 can comprise a bump guard 100. In some embodiments, resin can be applied to the strike-face layer 120 in step 674, and the strike-face layer 120 can be placed into the plate cover layer 160 in the mold tool 1200. In some further embodiments, resin can be applied to the one or more backing layers 115 in step 678, and the one or more backing layers 115 can be placed onto the strike-face layer 120 in the mold tool 1200 in step 680. In some embodiments, step 682 can include positioning a back cover layer 165 onto the one or more backing layers 115, and step 684 can include closing the mold tool 1200. In step 686, pressure and/or heat can be applied to the mold tool 1200 for a specific time period, after which the body armor composite 15 can be removed from the mold tool 1200 in step 688.
[0068] In some embodiments, the one or more backing layers 115 can comprise a strike-face layer 120, a strike-face reinforcement layer 130, a catchment layer 140, and/or a back-face reduction layer 150. Further, in some embodiments, a bump guard 100 can be placed between the plate cover layer 160 and the strike-face layer 120. In some other embodiments, an optional fabric layer 170 can be placed over either the plate cover layer 160 and/or the back cover layer 165 to form an outer fabric layer. In some embodiments, the composite can be formed by thermally bonding some layers of various materials to themselves under pressure. In some embodiments, various electro-mechancial components can be integrated into the composite structure to form a multi-functional ballistically resistant composite. In some embodiments, a plurality of layers, materials and resins may be vacuum bagged within the mold or tool to evacuate gases and assure no gaseous inclusions compromise the composite.
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[0070] In some embodiments, either the lower membrane 1230 and/or the upper membrane 1235 can comprise a preform cavity 1237. In some embodiments, the height of the preform cavity 1237 is substantially equal to the thickness of the laminated body armor composite 15. A plurality of layers 700a can then be formed and laminated using the process 660. In the case of the use of the mold tool 1200 in place of the press assembly 800 in the process 500, the height of the preform cavity 1237 can include the thickness of the laminated body armor composite 10, 15 including the preforms 400, 450.
[0071] When using either of the processes 500, 660, layers 700a can be laminated by pressurizing the mold tool 1200. In some embodiments, each of the portions 1205a, 1205b can include at least one pressure port 1240. In some embodiments, the pressurizable lower chamber 1210a and upper chamber 1210b can be pressurized using a compressed gas (e.g., air). In some embodiments, the pressurizable lower chamber 1210a and upper chamber 1210b can be at least partially simultaneously pressurized. In some embodiments, after a specific period of time, the pressurizable lower chamber 1210a and upper chamber 1210b of the mold tool 1200 can be substantially depressurized, and opened to enable access to a lamination structure (e.g., such as a body armor composite 15). In some embodiments, a pressure between 100 psi and 150 psi is desirable.
[0072] In some embodiments, the housing 1205 can be formed from machined billet aluminum. In some further embodiments, the housing 1205 can comprise other metals such as steel or iron, or other suitable materials including fiber-reinforced plastics, polymers or other composite materials. Some embodiments further include a high durometer silicone frame formed around the perimeter of the interface between the portions 1205a, 1205b.
[0073] In some embodiments, one or more layers of body armor composite 10, 15 can be bonded at ambient room temperature. For example, in some embodiments, one or more layers of body armor composite 10, 15 can be bonded at a temperature between about 65 F. and about 80 F. In other embodiments, one or more layers of body armor composite 10, 15 can be bonded at a temperature that is higher than ambient room temperature (i.e., greater than about 80 F.). In some embodiments, the layers and/or the resin can be preheated to 90 F. or other desired temperatures to reduce cycle time.
[0074] The bonding temperature can vary depending on at least the composition of one or more layers included in the body armor composite 10, 15. The one or more layers and/or layers of additive bonding material can comprise a polymer and/or a pre-polymer or resin (or a combination thereof) that can be processed at a specified temperature and/or within a specified temperature range. As used herein, the term pre-polymer or resin can include any material composition that comprises either monomer or a mixture of monomers, and/or a partially reacted polymer or polymers that includes at least some unreacted monomer, and/or a polymer or mixture of polymers, and/or a combination thereof. Further, as used herein, the term polymer can included can include a material that comprises a polymer, a copolymer, a homopolymer, a blend of polymers, a blend of copolymers, a blend of homopolymers, or a combination thereof.
[0075] In some embodiments, one or more layers of the body armor composite 10, 15 can comprise at least one polymer. For example, in some embodiments, the body armor composite 10, 15 can include at least one strike-face reinforcement layer 130 that comprises at least one polymer. In some embodiments, the reinforcement layer 130 can include polymers that are composed of aramids (aromatic polyamides), poly(m-xylylene adipamide), poly(p-xylylene sebacamide), poly (2,2,2-trimethyl-hexamethylene terephthalamide), poly(piperazine sebacamide), poly(metaphenylene isophthalamide) (Nomex) and poly(p-phenylene terephthalamide) (Kevlar) and aliphatic and cycloaliphatic polyamides, such as the copolyamide of 30% hexamethylene diammonium isophthalate and 70% hexamethylene diammonium adipate, the copolyamide of up to 30% bis-(-amidocyclohexyl) methylene, terephthalic acid and caprolactam, polyhexamethylene adipamide (nylon 66), poly(butyrolactam) (nylon 4), poly(9-aminonanoic acid)nylon 9), poly(enantholactam) (nylon 7), poly(caprillactam) (nylon 8), polycaprolactam (nylon 6), poly(p-phenylene terephthalamide), polyhexamethylene sebacamide (nylon 6,10), polyaminoundecanamide (nylon 11), polydodecanolacatam (nylon 12), polyhexamethylene isophthalamide, polyhexamethylene terephthal amide, polycaproamide, poly(nonamethylene azelamide) (Nylon 9,9), poly(decamethylene azelamide) (nylon 10,9), poly(decamethylenesebacamide) (nylon 10,10), poly[bis-4-aminocyclohexyl)methanel, 10-decanedi-carboxamide](Qiana)(trans), or combination thereof; and aliphatic, cycloaliphatic and aromatic polyesters such as poly(1,4-cyclohexylidene dimethyl eneterephthalate) cis and trans, poly(ethylene-2,6-naphthalate), poly(1,4-cyclohexane dimethylene terephthalate) (trans), poly(decamethylene terephthalate, poly(ethylene terephthalate), poly(ethylene isophthalate), poly(ethylene oxybenzoate), poly(para-hydroxy benzoate), poly(beta,beta dimethylpropiolactone), poly(decamethylene adipate), poly(ethylene succinate) and the like.
[0076] In some other embodiments, reinforcement layer 130 can comprise at least one polymer formed of extended chain polymers by the reaction of beta-unsaturated monomers of the formula:
R.sub.1R.sub.2CCH.sub.2
where R.sub.1 and R.sub.2 are either identical or different, and are hydrogen, hydroxyl, halogen, alkylcarbonyl, carboxy, alkoyxycarbonyl, heterocycle or alkyl or aryl, where the alkyl or aryl can be substituted with one or more substituents including alkoxy, cyano, hydroxyl, akyl or aryl. In some embodiments, extended chain polymers can be composed of polystyrene, polyethylene, polypropylene, poly(1-octadecene), polyisobutylene, poly(1-pentene), poly(2-methylstyrene), poly(4-methyl styrene), poly(1-hexene), poly(1-pentene), poly(4-methoxystyrene), poly(5-methyl-1-hexene), poly(4-methylpentene), poly(1-butene), poly(3-methyl-1-butene), poly(3-phenyl-1-propene), polyvinyl chloride, polybutylene, polyacrylonitrile, poly(methyl pentene-1), poly(vinyl alcohol), poly(vinyl-acetate), poly(vinyl butyral), poly(vinyl chloride), poly(vinylidene chloride), vinyl chloride-vinyl acetate chloride copolymer, poly(vinylidene fluoride), poly(methyl acrylate, poly(methylmethacrylate), poly(methacrylonitrile), poly(acrylamide), poly(vinyl fluoride), poly(vinyl formal), poly(3-methyl-1-butene), poly(1-pentene), poly(4-methyl-1-butene), poly(1-pentene), poly(4-methyl-1-pentene), poly(1-hexane), poly(5-methyl-1-hexene), poly(1-octadecene), poly(vinyl cyclopentane), poly(vinylcyclohexane), poly(a-vinylnaphthalene), poly(vinyl methyl ether), poly(vinylethylether), poly(vinyl propylether), poly(vinyl carbazole), poly(vinyl pyrrolidone), poly(2-chlorostyrene), poly(4-chlorostyrene), poly(vinyl formate), poly(vinyl butyl ether), poly(vinyl octyl ether), poly(vinyl methyl ketone), poly(methylisopropenyl ketone), poly(4-phenylstyrene) and the like.
[0077] In some embodiments, one or more layers of body armor composite 10, 15 can be bonded to one or more layers of body armor composite 10, 15 using a thermosetting polymer. In some embodiments, thermosetting resin pre-polymer can be applied to at least one side of the at least one of the layers. In some embodiments, a thermosetting resin pre-polymer can be applied to both sides of at least one of the layers. In some embodiments, one or more layers of the body armor composite 10, 15 can be bonded to one or more other layers of body armor composite 10, 15 using an epoxy resin based polymer or pre-polymer. In some other embodiments, one or more layers of body armor composite 10, 15 can be bonded to one or more other layers of body armor composite 10, 15 using a vinyl ester based polymer. In some further embodiments, both an epoxy resin based polymer and a vinyl ester based polymer can be used.
[0078] In some embodiments of the invention, the thermosetting resin can comprise an epoxide technology. For example, in some embodiments, epoxies based on saturated or unsaturated aliphatic, cycloaliphatic, aromatic and heterocyclic epoxides can be used. For example, useful epoxides include glycidyl ethers derived from epichlorohydrin adducts and polyols, particularly polyhydric phenols. Another useful epoxide is the dlglycidyl ether of hisphenol A. Additional examples of useful polyepoxides are resorcinol diglycidyl ether, 3,4-epoxy-6-methylcyclohexylmethyl-9,10-epoxystearate, 1,2,-bis(2,3-epoxy-2-methylpropoxy)ethane, diglycidyl ether of 2,2-(p-hydroxyphenyl) propane, butadiene dioxide, dicyclopentadiene dioxide, pentaerythritol tetrakis(3,4 epoxycyclohexanecarboxylate), vinylcyclohexene dioxide, divinylbenzene dioxide, 1,5-pentadiol bis(3,4-epoxycyclohexane carboxylate), ethylene glycol bis(3,4-epoxycyclohexane carboxylate), 2,2-diethyl-1,3-propanediol bis(3,4 epoxycyclohexanecarboxylate), 1,6-hexanediol bis(3,4-epoxycyclohexanecarboxylate),2-butene-1,4-diol-bis(3,4-epoxy-6-methylcyclohexane carboxylate), 1,1,1-trimethylolpropane-tris-(3,4-epoxycyclohexane carboxylate), 1,2,3-propanetriol tris(3,4-epoxycyclohexanecarboxylate), dipropylene glycol bis(2-ethylexyl-4,5-epoxycyclohexane-1,2-dicarboxylate), diethyleneglycol-bis(3,4-epoxy-6-methylcyclohexane carboxylate), triethylene glycol bis(3,4-epoxycyclohexanecarboxylate),3,4-epoxycyclohexyl-methyl-3,4-epoxycyclohexanecarboxylate,3,4-epoxy-1-methylcyclohexyl methyl-3,4-epoxy-1-methylcyclohexane-carboxylate, bis(3,4-epoxycyclohexylmethyl) pimelate, bis(3,4-epoxy-6-methylenecyclohexylmethyl)maleate, bis(3,4-epoxy-6-methylcyclohexylmethyl) succinate, bis(3,4-epoxycyclohexylmethyl) oxalate, bis(3,4-epoxy-6-methylcyclohexylmethyl) sebacate, bis(3,4-epoxy-6-methylcyclohexylmethyl)adipate, bis(3,4-epoxycyclo-hexylmethyl) terephtalate, 2,2-sulfonyldiethanol bis(3,4-epoxycyclohexanecarboxylate), N,N-ethylene bis(4,5-epoxycyclohexane-1,2-dicarboximide), di(3,4-epoxycyclohexylmethyl)-1,3-tolylenedicarbamate,-3,4-epoxy-6-methylcyclohexane carboxaldehyde acetal, 3,9-bis(3,4-epoxycyclohexyl) spirobi-(methadioxane), and the like.
[0079] As noted above, in some further embodiments, thermosetting resins based on vinyl ester technology can be used. For example, in some embodiments, thermosetting resins based on aromatic vinyl esters can be used. These can include a condensation product of epoxide resins and unsaturated acids usually diluted in a compound having double bond unsaturation such as vinyl aromatic monomer (e.g., styrene and vinyl toluene, and diallyl phthalate). Illustrative of useful vinyl esters are diglycidyl adipate, diglycidyl isophthalate, di(2,3-epoxybutyl) adipate, di(2,3-epoxybutyl) oxalate, di(2,3-epoxyhexyl) succinate, d(3,4-epoxybutyl) maleate, d(2,3-epoxyoctyl) pimelate, di(2,3-epoxybutyl) phthalate, di(2,3-epoxyoctyl) tetrahydrophthalate, di(4,5-epoxy-dodecyl) maleate, di(2,3-epoxybutyl) terephthalate, di(2,3-epoxypentyl) thiodipropionate, di(5,6-epoxy-tetradecyl) diphenyldicarboxylate, di(3,4-epoxyheptyl) sulphonyldibutyrate, tri(2,3-epoxybutyl) 1,2,4 butanetricarboxylate, di(5,6-epoxypentadecyl) maleate, di(2,3-epoxybutyl) azelate, di(3,4-epoxybutyl) citrate, di(5,6-epoxyoctyl) cyclohexane-1,3-dicarboxylate, di(4,5-epoxyoctadecyl) malonate, bisphenol-A-fumaric acid polyester and the like.
[0080] In some embodiments, at least a portion of the body armor composite 10, 15 can include a filler material. For example, some embodiments can include a thermoplastic or thermosetting resin that includes at least some filler material dispersed through at least a portion of the body armor composite 10, 15. In some embodiments, the filler material can be dispersed substantially homogenously through at least a portion of at least one layer of the body armor composite 10. In some other embodiments, the filler material can be substantially unevenly distributed through at least a portion of the body armor composite 10, 15. For example, in some embodiments, the filler material can be dispersed substantially unevenly through at least a portion of at least one layer of the body armor composite 10, 15. In some embodiments, the filler material can be amorphous or crystalline, organic or inorganic material. In some other embodiments, the particle size of the filler material can be between 1-10 microns. In some other embodiments, at least some portion of the filler material can be sub-micron. In some in some other embodiments, the thermosetting resin can contain nano-sized particle filler material.
[0081] In some embodiments, one or more layers of the body armor composite 10, 15 can comprise an inorganic material. In some embodiments, at least a portion of the aforementioned filler material can comprise an inorganic material. For example, in some embodiments, the body armor composite 10, 15 can include at least one strike-face reinforcement layer 130 that comprises at least one inorganic material. The body armor composite 10, 15 can include at least one strike-face 120, and in some embodiments, the strike-face 120 can comprise at least one inorganic material. The inorganic material can include a ceramic material, a glass material, a metal material, or a combination thereof. In some embodiments, the inorganic material can include materials comprising S-glass, E-glass, silicon carbide, asbestos, basalt, alumina, aluminum oxynitride, spinel (such as MgAb0.sub.4), alumina-silicate, quartz, zirconia-silica, and/or sapphire. In some embodiments, the inorganic material can comprise a fibrous, whisker, and/or filament type material. For example, in some embodiments, the inorganic material can comprise a ceramic filament, boron filament, and/or carbon filaments. In some other embodiments, metallic or semi-metallic filaments composed of boron, aluminum, steel and titanium can be used.
[0082] In some embodiments, one or more layers of the body armor composite 10, 15 can comprise a polymer with an ultra-high molecular weight. For example, in some embodiments, the body armor composite 10, 15 can include at least one catchment layer 140, and in some embodiments, the catchment layer 140 can comprise ultra-high-molecular-weight polyethylene (UHMWPE), also known as high-modulus polyethylene (HMPE). In some embodiments, the molecular weight of the UHMWPE can approach 1 million. In some further embodiments, the molecular weight of the UHMWPE can be in the range 1-3 million. In some other embodiments, the molecular weight of the UHMWPE can be in the range 3-6 million. In some other embodiments, the molecular weight of the UHMWPE can exceed 6 million. In some further embodiments, one or more layers of the body armor composite 10, 15 can comprise a highly crystalline or high oriented polymer or copolymer of polypropylene.
[0083] In some further embodiments, the body armor composite 10, 15 can include at least one enhanced protection region 25. For example, as shown in
[0084] Some embodiments can include a plate cover layer 160. For example, in some embodiments, the body armor composite 10, 15 can be fabricated with a plate cover layer 160 and/or a back cover layer 165. The use of at least one cover layer including a plate cover layer 160 and/or a back cover layer 165 can control delamination, reduce spall and provide an encapsulation of the ballistic plate, and can provide environmental protection, and reduce back-face deformation. The cover layers 160, 165 can also provide waterproofness, provide a cosmetic appearance, and provide surface for attaching labeling. In some further embodiments, functional devices can be included (e.g., embedded) in the layers 160, 165 such as for example RFID chips, and one or more sensors (e.g., impact sensors, and heath monitoring sensors). Combining the molding pressure and heat can reduce the temperature required for curing and, therefore, allows more sensitive electronics to be incorporated into the the molded part 10 and 15
[0085]
[0086] In some embodiments, the plate cover layer 160 and/or the back cover layer 165 can comprise a ballistic layer or a ballistic reinforcement layer. The plate cover layer 160 and/or the back cover layer 165 can include or comprise a monocoque structure (e.g., a monocoque truss structure). In some embodiments, the layers 160, 165 can be fabricated onto the previously formed body armor composite 10, 15 using the methods as described herein, and can include hot pressure molding, and pre-heated materials and cold pressure forming. In some embodiments, the layers 160, 165 can be fabricated and formed on a tool at a temperature between about 65 F. and about 80 F. In some embodiments, the layers 160, 165 can be formed using a resin based on an epoxide based polymer or a vinyl ester based resin. In some other embodiments, the layers 160, 165 can be formed using a resin based on any one of the epoxide based polymer or vinyl ester based resin polymers. In some embodiments, the layers 160, 165 can incorporate a bump guard 100. In some embodiments, the layers 160, 165 can be any shape, and cover any type or shape from flat to multi-curve armor. In some embodiments, the layers 160, 165 can be any combination of a top and bottom, front and back, front all sides and a two dimensional back piece for closure. Moreover, in some embodiments, the layers 160, 165 can be one piece, two pieces or any number of parts.
[0087] Ballistic plates produced by the materials and methods described herein have been tested under the 16.0 mm BFD, 124 grain 919 mm FMJ RN projectile requirement.
[0088] In some embodiments, the mold tool 1200 can be fabricated in various sizes and shapes to accommodate different armor structures. For example,
[0089]
[0090]
[0091] Fluid dispersion layer 1520 may comprise a fluid dispersion media of a material allowing fluid to flow through the media, but having a compressive strength greater than the pressure applied to body armor composite 10 formed therein. In one embodiment, fluid dispersion media is a mesh-like material or a porous material. Thermal transfer membrane 1516 and pressure bearing membrane 1518 are preferable a flexible membrane and, in one embodiment, may have elastic capabilities to stretch as necessary to conform with the shape of the molded body armor composite 10 when pressure is applied. In one embodiment, the membranes used may be made from one or more of high temperature silicone, food grade silicone, chemically resistant silicone, chemically resistant silicone, fabric reinforced silicone or any elastomer with the same properties.
[0092]
[0093]
[0094]
[0095] The application of heat and pressure may be maintained in tool 1500 until the molding of body armor composite 10 is complete or otherwise as desired. At this time, the flow of heating fluid is stopped and a cooling fluid may be introduced into the fluid dispersion layers 1520a and 1520b to reduce the temperature of the part for handling, and the pressurized fluid may be removed through inlet 1528 or 1530, which operate as an outlet, or through another stand-alone fluid drain or outlet (not shown). The locking mechanism may be disengaged and the body armor composite tool 10 may be removed from molding chamber 1503 of the molding tool 1500.
[0096] Advantages of the construction of tool 1500 are that the heat transfer fluid does not need to be pressurized, which reduces the equipment needed and increases the overall safety of the tool 1500. Further, in one embodiment, the fluid dispersion media in fluid dispersion layers 1520a and 1520b may be include one or more baffles 1537 arranged to direct the flow of fluid to create thermal flow patterns based upon the needs of the body armor composite 10 being formed. The flow pattern in the media may be combined with the location of the inlets and outlets to provide distinct thermal zones that are created and controlled independently to optimize the molding process. Moreover, the upper and lower thermal diaphragm systems described herein may also be controlled in concert or independently.
[0097] The flexible molding processes described herein can also be used to form kayaks, wing spars, vehicle body panels and a wide range of other products. Some embodiments of the invention enable better control of resin content without inducing significant localized stresses in the resulting composites. Some embodiments also enable the replacement of pre-impregnated materials with unimpregnated materials which can offer excellent structural characteristics at lower cost.
[0098] It will be appreciated by those skilled in the art that while the invention has been described above in connection with particular embodiments and examples, the invention is not necessarily so limited, and that numerous other embodiments, examples, uses, modifications and departures from the embodiments, examples and uses are intended to be encompassed by the claims attached hereto. The entire disclosure of each patent and publication cited herein is incorporated by reference, as if each such patent or publication were individually incorporated by reference herein.