Apparatus for pneumatic shuttering of an aerosol particle stream

Abstract

The invention provides pneumatic shuttering of a focused or collimated aerosol particle stream. The aerosol stream can be collimated by an annular sheath of inert or non-inert gas. The apparatus propagates a sheathed aerosol stream through a series of aerodynamic lenses along the axis of a flow cell. The final lens is typically positioned above a substrate, so that direct material deposition is provided. A substantially perpendicularly-flowing gas external to the aerodynamic lens system is used to redirect the particle stream away from the flow axis and through an exhaust port, thereby shuttering the collimated aerosol stream. The pneumatic shutter enables printing of discreet structures, with on/off shuttering times of approximately 1 to 100 milliseconds.

Claims

1. An apparatus for pneumatically shuttering of an aerosol particle stream, comprising: an aerosol generator for generating an aerosol stream of particles, a print head comprising an aerodynamic lens system having at least two aerodynamic lenses with a sheath gas flow for collimating the aerosol particle stream prior to exiting through an exit nozzle, and a pneumatic shutter comprising a gas flow substantially perpendicular to the flow axis of the collimated aerosol particle stream to shutter the collimated aerosol particle stream exiting the exit nozzle away from the flow axis according to a programmed schedule.

2. The apparatus of claim 1, further comprising a decouping volume between the print head and the pneumatic shutter for decoupling the pressure in the print head from the pressure in the pneumatic shutter.

3. The apparatus of claim 1, wherein the pressure in the pneumatic shutter is a positive pressure greater than atmospheric pressure.

4. The apparatus of claim 1, wherein the pressure in the pneumatic shutter is a vacuum less than atmospheric pressure.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) The detailed description will refer to the following drawings, wherein like elements are referred to by like numbers.

(2) FIG. 1 is a schematic illustration of an aerodynamic lens system with a pneumatic aerosol shutter.

(3) FIG. 2 is a schematic illustration of a deposition apparatus that can use a pneumatic aerosol shutter.

(4) FIG. 3 is a plot of the flow cell pressure during operation of a deposition apparatus using a pneumatic shutter.

DETAILED DESCRIPTION OF THE INVENTION

(5) In direct printing, a material is deposited onto a substrate without the use of masks or lithographic techniques. An aerodynamic lens system forms a thin aerosol jet surrounded by a sheath gas for direct printing. The diameter of the collimated aerosol flow is a function of the lens system parameters, such as the individual lens element channel length and orifice diameter. The external pneumatic shutter of the present invention intermittently interrupts the collimated aerosol flow, enabling deposition of discreet structures on a substrate.

(6) The invention provides a method to interrupt the aerosol flow stream directed towards a print surface to quickly enable and disable printing of discrete features onto the print substrate. In one embodiment, the shuttering mechanism is mounted external to the aerosol print head so that the aerosol flow stream can flow through a central flow channel of the shuttering apparatus without disturbing the collimation of the aerosol flow stream. Secondary flow channels are used to: (1) redirect the collimated aerosol flow stream into a secondary channel, and (2) to collect and contain the aerosol material such that it cannot be deposited onto the print substrate. This shutter apparatus uses a positive gas flow from one channel to redirect the aerosol stream toward the collection channel and vacuum pressure on the collection side to assist with the aerosol collection process. Note that this shuttering mechanism can be made operable using either positive pressure or vacuum pressure; however, there is a minimum impact to operating pressure within the print head during the shuttering process when both positive and vacuum pressures are applied and balanced across the aerosol output orifice.

(7) The pneumatic shutter assembly of the present invention can be used to shutter a continuous stream. However, the shutter can also be used for on-demand systems. In continuous stream systems, an unbroken stream of solid or droplet aerosol particles propagates through a flow cell and is deposited on a substrate. In an on-demand system, the particles are deposited in a pulsed mode, so that a single quanta of material is deposited in response to a drive signal. Maintenance of particle production is advantageous in continuous and on-demand systems. The invention allows for constant material production during the shuttering process, so that precise and reliable deposition is provided.

(8) A cross-sectional illustration of an exemplary nozzle/shutter assembly is shown in FIG. 1. In general, the nozzle comprises a series of flow orifices 11 and 12 within an aerosol print head 10. This series of flow orifices 11 and 12 forms an aerodynamic lens system that focuses and collimates an aerosol stream 15. The aerosol stream 15 is sheathed after passing from the first lens 11 and during passage through the second lens 12. The aerosol stream is shuttered using a pneumatic shuttering assembly 20. Prior to entering the pneumatic shutter 20, the combined annular flow from the aerodynamic lens system can pass through a third orifice 23. The third orifice 23 is located below a volume 16 that is open to atmosphere for the purpose of decoupling the pressure in the print head 10 from the shuttering gas pressure. Reduction of the diameter of the aerosol beam using the aerodynamic lens system 11 and 12 allows the aerosol stream to be focused and accelerated to pass through the shutter system orifices 23 and 25. The shuttering assembly 20 is downstream from the print head 10 and comprises two computer-controlled valves 21 and 22 that establish a differential pressure and gas flow in a horizontal channel 24. During shuttering, valve 21 can be used to introduce a pressurized inert gas flow that propagates along the horizontal channel 24 that runs substantially perpendicular to the flow axis of the aerosol stream 15. The cross flow through the perpendicular channel 24 enables shuttering of the aerosol stream to a collection side of the channel according to a programmed schedule. A pressure regulator can be used to set the flow rate through valve 21 to a rate greater than the flow rate of the combined sheath/aerosol flow. The decoupling volume 16 allows the shutter flow rate to be greater than the combined sheath/aerosol flow rate with minimum effect on pressure in the print head 10. Valve 22 can be connected to a vacuum source. A flow metering device can be located between valve 22 and the vacuum source to enable the vacuum-side flow rate to be matched to the flow rate of the gas from valve 21.

(9) A typical deposition apparatus is shown in FIG. 2. In the generalized case, the apparatus comprises an aerosol generator 30, print head flow cell 10, an exit nozzle 50, and a process control system (not shown) for deposition of discreet structures on a substrate. The external shutter assembly (20, not shown) can be attached to the print head nozzle 50. The apparatus can use an ultrasonic atomizer (not shown) to produce a narrow distribution of droplet diameters tuned to an aerodynamic lens system; however, a shutter assembly can be used to interrupt the flow of an aerosol stream produced by any number of means. An inert carrier gas enters the atomizer through input port 40. The flow cell 10 comprises a flow chamber housing and the aerodynamic lenses that incorporates the sheath gas flow.

Pneumatic Shuttering

(10) Programmed interruption of the aerosol stream to the substrate surface is required for maskless deposition of discreet structures. Shuttering can be accomplished by diverting a combined aerosol/sheath flow to a collection chamber using a vacuum or pressure-based actuation, or a combined pressure-based and vacuum-driven flow. In the typical case, a sheath and aerosol flow are combined to produce an annularly propagating combined flow comprising an inner aerosol-laden flow and an outer sheath flow. The combined flow pressurizes the print head flow cell volume. Constant flow cell pressure is desired for stable printing and shuttering. Accordingly, the most effective shuttering is accomplished when the print head pressure is held constant during the shutter open, flow diversion, and shutter close processes. An increase in pressure can result in a departure from laminar flow along the exhaust flow path, resulting in the accumulation of particles on the exhaust channel surfaces. A decrease in flow cell pressure can result in de-collimation or defocusing of the aerosol stream.

Shuttering of an Aerosol Stream Formed by a Multi-Lens System

(11) In a multi-lens aerodynamic system, an aerosol stream is focused and collimated while passing through a series of contractions and expansions produced by a lens assembly. The exemplary embodiment shutters the aerosol stream as it passes between the third and fourth orifice, but the shutter can divert the stream at any point along the aerosol flow axis.

Maintenance of Constant Flow Cell Pressure

(12) Maintaining a constant pressure in the flow cell throughout shuttering and re-establishing deposition is preferred for the production of fast, clean, and efficient aerosol shuttering. The operational pressure (the pressure developed in the flow cell during deposition) is preferably maintained during the shuttering process, so that no time is required to re-establish the operational steady state pressure when the shutter valves are closed. An example of a pressure curve during shuttering is shown in FIG. 3. In this example, the sheath gas is turned on for the print head at about 20 sec. Once pressure is established, the aerosol carrier gas is turned on at about 30 sec. The shutter gas and vacuum flow rates are then adjusted to minimize pressure perturbations when the shutter is opened and to quickly return to normal operating pressure when the shutter is closed.

Multi-Nozzle Microjet Arrays

(13) The general design of invention is applicable to the manufacture of multi-nozzle arrays. In a multi-nozzle configuration, an assembly comprising several exit nozzles with sheathed flows is fabricatedusually in a linear arrayso that simultaneous deposition from each nozzle is provided.

Laser-Assisted Deposition

(14) In another embodiment, the deposition apparatus can be configured so that the aerosol stream is intercepted at the substrate by a focused laser beam. The laser focus provides preferential heating of the sample liquid. The configuration enables deposition of features with line widths less than 10 microns. The laser-jet configuration allows for controlled heating and evaporation of the deposited liquid while minimizing heating of a transparent or nearly transparent, or opaque substrate. In some cases, uncontrolled spreading of the jetted liquid can occur as the liquid strikes the substrate. Increasing the viscosity of the liquid just above the deposition zone changes the fluid dynamics so that uncontrolled spreading and even splashing is eliminated. Laser heating of the liquid just before or just after impact onto the substrate increases the viscosity of the liquid. The increased viscosity allows for deposition of structures with increased line height, and also enables printing of three-dimensional structures. The line height is then dependent on the incident laser power, the liquid deposition rate, and the substrate speed.

Direct Printing of UV Curable Inks

(15) As another example of laser-assisted liquid jet deposition, the inner liquid can be a UV curable ink. Focused or unfocused UV or visible laser radiation is directed onto the jet so that in-flight curing of the ink (core liquid) is accomplished. The laser radiation can also be focused onto the substrate deposition zone to promote real time curing of the deposited ink. A subsequent substrate heating step can remove any residual sheath liquid from the substrate surface.

Direct Printing of Films and Discreet Structures

(16) The apparatus is capable of printing continuous lines on a substrate. If the substrate is placed some distance beneath the aerosol stream such that the distance is above the point of initiation of Rayleigh instabilities, a continuous line can be written as the substrate is moved. The width of the line depends on the apparatus parameters, the fluid parameters, and the substrate speed. The apparatus is capable of operating at print speeds of approximately 1 to 5000 mm/sec.

3D Printing

(17) The invention can also be used to build three-dimensional structures using a layer-wise process, wherein simple and complex objects are printed directly from a computer-automated drawing (CAD) file. In the 3D printing process, laser-assisted deposition or a viscoelastic ink can be used to deposit a liquid filament with a viscosity sufficient to form a rigid or semi-rigid structure upon which subsequent layers are deposited. In the 3D printing technique, a digital model of an object is intersected with horizontal planes. The horizontal planes form cross sectional representations or slices of the object. Information in each slice is uploaded to a computerized motion control system, so that a solid object can be fabricated using an additive manufacturing process. The process can be used to fabricate three-dimensional objects from materials including, but not limited to, metals, ceramics, and plastics.

3-D Structures for Medical Applications

(18) In yet another embodiment, the apparatus can be used to produce structures for medical applications. The flow cell technology can be used to produce scaffolding for tissue engineering applications. The same flow cell can also be used to print living cells and nutrients for those cells in tissue engineering applications.

(19) The present invention has been described as an apparatus for pneumatic shuttering of an aerosol particle stream. It will be understood that the above description is merely illustrative of the applications of the principles of the present invention, the scope of which is to be determined by the claims viewed in light of the specification. Other variants and modifications of the invention will be apparent to those of skill in the art.