MATERIAL COMBINATION

Abstract

The invention relates to a material combination comprising a first fluid comprising a liquid crystal material, and an electrically insulating second fluid substantially not miscible with the first fluid, and to an optical device using the same.

Claims

1. Material combination containing a first fluid, comprising a liquid crystal material, and an electrically insulating second fluid substantially not miscible with the first fluid, which are in contact with each other along a phase boundary.

2. Material combination according to claim 1 characterised in that the second fluid comprises one or more substantially fluorinated or perfluorinated organic compounds.

3. Material combination according to claim 2 wherein the second fluid consists of one or more perfluorinated organic compounds.

4. Material combination according to claim 1 characterised in that the first fluid comprises one or more compounds of formula I ##STR00134## wherein L.sup.11 to L.sup.15 are independently of each other H or F, R.sup.11 is alkyl, which is straight chain or branched, is unsubstituted, mono- or poly-substituted by F, Cl or CN, and in which one or more CH.sub.2 groups are optionally replaced, in each case independently from one another, by O, S, NR.sup.01, SiR.sup.01R.sup.02, CO, C(O)O, OC(O), OCOO, SCO, COS, CY.sup.01CY.sup.02 or CC in such a manner that O and/or S atoms are not linked directly to one another, Y.sup.01, Y.sup.02 are, independently of each other, F, Cl, or CN, and alternatively one of them may be H, R.sup.01, R.sup.02 are, independently of each other, H, or alkyl with 1 to 12 C-atoms, Z.sup.11 denotes C(O)O or CF.sub.2O, X.sup.11 denotes halogen, CN, SF.sub.5, a mono- or polyhalogenated alkyl-, or alkoxy having 1 to 6 C-atoms or a mono-, di- or polyhalogenated alkenyl having 2 to 6 C-atoms, ##STR00135## denotes a diradical group selected from the following groups: a) the group consisting of trans-1,4-cyclohexylene, 1,4-cyclohexenylene, 1,4-bicyclohexandiyl, in which, in addition, one or more non-adjacent CH.sub.2 groups may be replaced by O and/or S and in which, in addition, one or more H atoms may be replaced by F, b) the group consisting of 1,4-phenylene and 1,3-phenylene, in which, in addition, one or two CH groups may be replaced by N and in which, in addition, one or more H atoms may be replaced by F, and ##STR00136## denotes a diradical group selected from the group consisting of 1,4-phenylene and 1,3-phenylene, in which, in addition, one or two CH groups may be replaced by N and in which, in addition, one or more H atoms may be replaced by F, m is 0 or 1, n is 0, 1 or 2, p is 0 or 1 and m+n+p is 0, 1 or 2.

5. Material combination according to claim 4, characterised in that the first fluid comprises one more compounds of formula II ##STR00137## wherein R.sup.21 has one of the meanings given for R.sup.11 in formula I in claim 4, X.sup.21 has one of the meanings given for X.sup.11 in formula I in claim 4, A.sup.21 has one of the meanings given for A.sup.11 in formula I in claim 4, A.sup.22 has one of the meanings given for A.sup.12 in formula I in claim 4, L.sup.21, L.sup.22 are independently of each other H or F. m is 0 or 1, n is 0, 1 or 2, p is 0 or 1 and m+n+p is 1, 2 or 3.

6. Material combination according to claim 1 with the first fluid being in the isotropic state at room temperature.

7. Material combination according to claim 1 characterised in that the first fluid has a dielectric constant of 100 to 1000 or above, measured at 20 C. and 1 kHz.

8. A Optical component comprising a fluid enclosure comprising a first substrate, a second substrate placed opposite the first substrate, and a material combination according to claim 1 disposed between the first substrate and the second substrate.

9. Optical component according to claim 8 where the optical component utilises interdigitated electrodes placed on the first substrate.

10. Optical component according to claim 8 where the electrodes are covered by a polymer layer.

11. Optical component according to claim 10 where the polymer layer is a liquid crystal orientation layer.

12. Method of production of an optical component comprising a fluid enclosure comprising a first substrate, a second substrate placed opposite the first substrate, and a material combination according to claim 1 disposed between the first substrate and the second substrate said method comprising at least the steps A) dispensing a first fluid according to claim 1 onto a first substrate, B) dispensing a second fluid according to claim 1 on top of the first fluid.

13. Optical device comprising an optical component according to claim 8.

14. Display device operable in a 2D mode or 3D mode, dynamic lens element, optical shutter, beamsteerer, diffraction grating, or electronic paper display comprising an optical device according to claim 13.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0023] FIG. 1 is a cross sectional side view of an electrooptical element according to a preferred embodiment of the present invention.

[0024] FIG. 2 is a cross sectional side view of an electrooptical element according to a preferred embodiment of the present invention upon application of a voltage.

[0025] FIG. 3 shows the voltage dependence of the wrinkle amplitudes of a lens element according to a preferred embodiment of the present invention.

[0026] FIG. 4 shows the variation of the focal length with the applied voltage in a lens element with a first fluid exposed to air.

[0027] FIG. 5 shows the variation of the focal length with the applied voltage in a lens element of a biphasic system comprising a first and a second fluid according to a preferred embodiment of the present invention.

DETAILED DESCRIPTION OF THE INVENTION

[0028] As used herein, fluid refers to a continuous, amorphous substance whose molecules move freely past one another. A fluid may be a gas, liquefied gas, liquid or liquid under pressure or flowable particulate matter.

[0029] As used herein, fluid enclosure may refer to a device for physically storing a fluid.

[0030] In a preferred embodiment, the second fluid comprises one or more substantially fluorinated or perfluorinated compounds. Preferably, the second fluid entirely consists of substantially fluorinated or perfluorinated compounds, particularly preferably it consists entirely of perfluorinated compounds.

[0031] Perfluorinated means that substantially all the hydrogen atoms of the carbon materials have been replaced by fluorine atoms. While the perfluorinated materials are preferred, carbon materials which are substantially fluorinated can also be used in this invention. Substantially fluorinated indicates that most of the hydrogen atoms have been replaced by fluorine atoms, and that further replacement does not substantially decrease the miscibility with non-fluorinated materials or partially fluorinated materials. It is believed that this level is reached when about 50% of the hydrogen atoms have been replaced by fluorine atoms. Also certain of the fluorine atoms of foregoing materials may be substituted by other halogen atoms such as chlorine.

[0032] As indicated, perfluorinated means that substantially all the hydrogen atoms of the carbon material have been replaced by fluoride atoms. It is conceivable in the manufacture of such compounds that minor amounts of substantially fluorinated derivatives may be mixed with completely fluorinated compounds. This is permissible provided that the lack of complete replacement of all hydrogens does not affect the essential characteristics of the liquid perfluorocarbons of this invention. It is preferred that at least 95% of the hydrogen atoms havebeen replaced, more preferably at least 98% and even more preferably 100%.

[0033] Among the perfluorocarbon compounds that may be employed are perfluorodecalin (PP5), perfluoro-1-methyldecaline, perfluoro-n-undecane, perfluorododecane, perfluoro-n-octylcyclohexane, perfluoro-p-diisopropylcyclohexane, perfluoroisopropylcyclohexane, perfluoro-n-butylcyclohexane perfluoro-m-diisopropylcyclohexane, perfluoro-1,2-dimethylcyclohexane, perfluorotrimethylcyclohexane, perfluorotetramethylcyclohexane, perfluoro-1-methyl-4-isopropylcyclohexane, perfluoro-1-methyl-4-t-butylcyclohexane, perfluoropentadecane, perfluoro(methylcyclopentane), perfluorohexane, perfluoroheptane, perfluorokerosene, perfluorotetradecahydrophenanthrene, perfluorododecahydrofluorene, perfluorobicyclo[4.3.0]nonane, perfluoro-endo-tetrahydrodicyclopentadiene, perfluoroadamantane, perfluoro-ethyladamantane, perfluoro-methyladamantane, perfluoro-ethylmethyladamantane, perfluoro-ethyldimethyladamantane, perfluoro-triethyladamantane, perfluoro-trimethyldiadamantane, perfluoro-methyldiadamantane, perfluoro-1,3,5,7-tetramethyladamantane, perfluoro-1,3-dimethyladamantane, perfluoro-tetrahydrodicyclopentadiene, perfluoro-methylbicyclo[2.2.2]octane, perfluoro-dimethylbicyclo[2.2.2]octane, perfluoro-pinane, perfluoro-camphane, perfluoro-1,4,6,9-dimethanodecaline, perfluoro-bicyclo[4.3.2]undecane, perfluoro-bicyclo[5.3.0]decane, perfluoro-exo-tetrahydrodicyclopentadiene, perfluorobicyclo[5.3.0]decane, perfluorodimethylbicyclo[3.3.1.]nonane, perfluoro-2,6-dimethylbicyclo[3.3.1]nonane, perfluoro-3-methylbicyclo[3.3.1]nonane, perfluorodecahydroacenaphthene, perfluorotrimethyl-bicyclo[3.3.1.]nonane, perfluoro-7-methyl bicyclo[4.3.0.]nonane, perfluor-n-octylbromid, perfluorotributylamine (FC47), perfluoro-N,N-dialkylcyclohexylamine, perfluoroalkylmorpholine, perfluoroalkylpiperidine, perfluorotetrahydrofuran (FC80), perfluoro-2-butyltetrahydrofuran, perfluoroether (PID) [(CF.sub.3).sub.2CFOCF.sub.2(CF.sub.2).sub.2CF.sub.2OCF(CF.sub.3).sub.2], perfluoroether (PIID) [(CF.sub.3).sub.2CFOCF.sub.2(CF.sub.2).sub.6CF.sub.2OCF(CF.sub.3).sub.2], perfluoropolymer (E3) [CF.sub.3CHF(OCF.sub.2C(CF.sub.3)F).sub.2OCF.sub.2CF.sub.2CF.sub.3], perfluoropolymer (E4) [CF.sub.3CHF(OCF.sub.2C(CF.sub.3)F).sub.3OCF.sub.2CF.sub.2CF.sub.3], perfluoroetherpolymer (Fomblin Y), fluorosilicone oil

(CH.sub.3).sub.3SiOSi(CH.sub.3)(CH.sub.2CH.sub.2R.sub.f).sub.nOSi(CH.sub.3).sub.3

where R.sub.f is C.sub.nF.sub.2n+1, n being an integer from 1 to 4, p is an integer such that the average viscosity at room temperature ranges from 50 to 10000cS, preferably from 50 to 100, marketed by Dow Corning as FS 1265 when R.sub.f is CF.sub.3.

[0034] The perfluorocarbons and any derivatives thereof may be generally termed as liquids. The term liquids, as used herein, is a comprehensive designation incorporating compounds that are in a state neither solid nor gaseous such as liquids, emulsions and gels. The term perfluorocarbon means a cyclic or acyclic compound of carbon. Whereas the term substituted derivatives thereof characterizes substituted perfluorocarbons with chemical elements within their structures such as oxygen, nitrogen, chlorine and bromine

[0035] It is to be understood that perfluorocarbon liquids of this invention may be formed of neat perfluorocarbon liquids, emulsions, suspensions or solutions of perfluorocarbons in mixture with themselves or other solvents. While some of the foregoing compounds are solid at ambient temperature they are soluble in ones which are liquid at ambient temperature and such a mixture could be used. For instance, perfluoro-1,3-dimethyl adamantane is normally a solid but in mixture with perfluorotrimethyl-bicyclo[3.3.1.]nonane a liquid is formed, i.e., DAWN.

[0036] The useful substantially fluorinated or perfluorinated materials are those which are generally liquids at temperatures and pressures, including ambient temperatures and pressures. Perfluorinated C8 or lower materials and up to C18 or higher materials can be used in this invention. Mixtures of various different perfluorinated materials can also be used.

[0037] The above perfluorocarbons can be synthesized by well known chemical or electrochemical processes. The preferred perfluorinated materials are either commercially available or can be prepared following methods described in the following U.S. Pat. Nos. 4,105,798; 3,911,138 and 3,962,439 or Houben-Weyl, Methods in Organic Chemistry, Volume E10Organo-Fluorine Compounds, Volumes 1-5 (4th Edition).

[0038] In a preferred embodiment of the present invention the first fluid comprises a liquid crystal medium comprising one or more mesogenic compounds of formula I,

##STR00001## [0039] wherein [0040] L.sup.11 to L.sup.15 are independently of each other H or F, [0041] R.sup.1 is alkyl, which is straight chain or branched, is unsubstituted, mono- or poly-substituted by F, Cl or CN, and in which one or more CH.sub.2 groups are optionally replaced, in each case independently from one another, by O, S, NR.sup.01, SiR.sup.01R.sup.02, CO, COO, OCO, OCOO, SCO, COS, CY.sup.01CY.sup.02 or CC in such a manner that O and/or S atoms are not linked directly to one another, [0042] Y.sup.01 and Y.sup.02 are, independently of each other, F, Cl, or CN, and alternatively one of them may be H, [0043] R.sup.01 and R.sup.02 are, independently of each other, H, or alkyl with 1 to 12 C-atoms, [0044] Z.sup.11 is COO, OCO, OCF.sub.2, or CF.sub.2O, [0045] X.sup.11 denotes halogen, CN, SF.sub.5, a mono- or polyhalogenated alkyl-, or alkoxy having 1 to 6 C-atoms or a mono-, di- or polyhalogenated alkenyl having 2 to 6 C-atoms,

##STR00002## denotes a diradical group selected from the following groups: [0046] a) the group consisting of trans-1,4-cyclohexylene, 1,4-cyclohexenylene and 1,4-bicyclohexandiyl, in which, in addition, one or more non-adjacent CH.sub.2 groups may be replaced by O and/or S and in which, in addition, one or more H atoms may be replaced by F, [0047] b) the group consisting of 1,4-phenylene and 1,3-phenylene, in which, in addition, one or two CH groups may be replaced by N and in which, in addition, one or more H atoms may be replaced by F, and

##STR00003## denotes a diradical group selected from the group consisting of 1,4-phenylene and 1,3-phenylene, in which, in addition, one or two CH groups may be replaced by N and in which, in addition, one or more H atoms may be replaced by F, [0048] m is 0 or 1, [0049] n is 0, 1 or 2, [0050] p is 0 or 1 and [0051] m+n+p is 0, 1 or 2.

[0052] In a preferred embodiment of the present invention the LC medium comprises one more compounds of formula I-1,

##STR00004##

wherein
A.sup.12, L.sup.11 to L.sup.15, R.sup.11 X.sup.11 and and Z.sup.11 have one of the meanings as indicated above in formula I.

[0053] Compounds I-1 are preferably selected from the group of compounds of its sub-formulae I-1-1 and I-1-2, preferably of formula I-1-2,

##STR00005##

wherein R.sup.11 has the meaning given under formula I above and preferably is n-alkyl, most preferably ethyl, n-propyl, n-butyl, n-pentyl, or n-hexyl.

[0054] In a preferred embodiment of the present invention, the LC medium comprises one or more compounds of formula I-2

##STR00006##

wherein
A.sup.11, L.sup.11 to L.sup.14, R.sup.11, X.sup.11 and Z.sup.11 have the meaning as indicated above in formula I.

[0055] In a preferred embodiment of the present invention, the LC medium comprises one more compounds of formula I-2 selected from the group of compounds of formulae I-2-1 to I-2-5

##STR00007##

wherein the parameters have one of the meanings as indicated under formula I.

[0056] In a preferred embodiment of the present invention the compounds of formula I-2-1 to I-2-5 are preferably selected from the group of compounds of the sub-formulae I-2-1a to I-2-1c, I-2-2a to I-2-2f, I-2-3a to I-2-3c, I-2-4a to I-2-4f and I-2-5a to I-2-5f, more preferably from the group of compounds of formula I-2-2c, I-2-3c or I-2-2f,

##STR00008## ##STR00009## ##STR00010## ##STR00011##

wherein R.sup.11 has one of the meanings as indicated above in formula II and preferably is n-alkyl, most preferably ethyl, n-propyl, n-butyl, n-pentyl or n-hexyl.

[0057] In a preferred embodiment of the present invention, the LC medium comprises one or more compounds of formula I-3,

##STR00012##

wherein A.sup.11, L.sup.11 to L.sup.16, R.sup.11, X.sup.11 and Z.sup.11 have the meanings as defined in formula I above.

[0058] The compounds of formula I-3 are preferably selected from

##STR00013##

wherein L.sup.11 to L.sup.14, R.sup.11 and X.sup.11 have one of the meanings indicated in formula I above.

[0059] In a further preferred embodiment of the present invention the compounds of formulae I-3-1, I-3-2 and I-3-3 are selected from the sub-formulae I-3-1a to I-3-1f, I-3-2a to I-3-2c and I-3-3a to I-3-3f

##STR00014## ##STR00015##

[0060] In a preferred embodiment of the present invention, the LC medium comprises one or more compounds of formula I-4,

##STR00016##

wherein [0061] L.sup.11 to L.sup.13, R.sup.11, X.sup.11 and and Z.sup.11 have one of the meanings as indicated above in formula I.

[0062] In a further preferred embodiment the compounds of formula I-4 are preferably selected from compounds of formulae I-4-1 or I-4-2 or a combination thereof.

##STR00017##

wherein the parameters R.sup.11, L.sup.11 to L.sup.13 and X.sup.11 have one of corresponding meanings given above in formula I.

[0063] Compounds of formula I-4-1 and I-4-2 are preferably selected from the group of compounds of the following sub-formulae

##STR00018## ##STR00019## ##STR00020##

wherein R.sup.11 has the meaning given under formula I above and preferably is n-alkyl, most preferably ethyl, n-propyl, n-butyl, n-pentyl or n-hexyl.

[0064] In a preferred embodiment of the present invention the LC-medium comprises one more compounds of formula II

##STR00021## [0065] wherein [0066] R.sup.21 has one of the meanings given for R.sup.11 under formula I above, [0067] X.sup.21 has one of the meanings given for X.sup.11 under formula I above, [0068] A.sup.21 has one of the meanings given for A.sup.11 under formula I above, [0069] A.sup.22 has one of the meanings given for A.sup.12 under formula I above, [0070] L.sup.21, L.sup.24 are independently of each other H or F. m is 0 or 1, [0071] n is 0, 1 or 2, [0072] p is 0 or 1 and [0073] m+n+p is 1, 2 or 3.

[0074] In a preferred embodiment of the present invention the mesogenic media comprise one more compounds of formula II-1 or II-2 or a combination thereof.

##STR00022##

[0075] Compounds of formula II-1 are preferably selected from the group of compounds of its sub-formulae II-1-1a and II-1-1b.

##STR00023##

wherein R.sup.21 has the meaning defined above in formula I and is preferably n-butyl or n-pentyl.

[0076] Compounds of formula II-2 are preferably selected from the group of compounds of its sub-formulae II-2-1 to II-2-8, preferably of formula II-2-1 to II-2-4, most preferably of formula II-2-3,

##STR00024##

wherein R.sup.21 has the meaning given under formula II above and preferably is n-butyl or n-pentyl.

[0077] An alkyl or an alkoxy radical, i.e. an alkyl where the terminal CH.sub.2 group is replaced by O, in this application may be straight-chain or branched. It is preferably straight-chain, has 1, 2, 3, 4, 5, 6, 7 or 8 carbon atoms and accordingly is preferably methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, ethoxy, propoxy, butoxy, pentoxy, hexoxy, heptoxy, or octoxy, furthermore nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, nonoxy, decoxy, undecoxy, dodecoxy, tridecoxy or tetradecoxy, for example.

[0078] Oxaalkyl, i.e. an alkyl group in which one non-terminal CH.sub.2 group is replaced by O, is preferably straight-chain 2-oxapropyl (=methoxy-methyl), 2- (=ethoxymethyl) or 3-oxabutyl (=2-methoxyethyl), 2-, 3-, or 4-oxapentyl, 2-, 3-, 4-, or 5-oxahexyl, 2-, 3-, 4-, 5-, or 6-oxaheptyl, 2-, 3-, 4-, 5-, 6- or 7-oxaoctyl, 2-, 3-, 4-, 5-, 6-, 7- or 8-oxanonyl or 2-, 3-, 4-, 5-, 6-, 7-, 8- or 9-oxadecyl, for example.

[0079] An alkenyl group, i.e. an alkyl group wherein one or more CH.sub.2 groups are replaced by CHCH, may be straight-chain or branched. It is preferably straight-chain, has 2 to 10 C atoms and accordingly is preferably vinyl, prop-1-, or prop-2-enyl, but-1-, 2- or but-3-enyl, pent-1-, 2-, 3- or pent-4-enyl, hex-1-, 2-, 3-, 4- or hex-5-enyl, hept-1-, 2-, 3-, 4-, 5- or hept-6-enyl, oct-1-, 2-, 3-, 4-, 5-, 6- or oct-7-enyl, non-1-, 2-, 3-, 4-, 5-, 6-, 7- or non-8-enyl, dec-1-, 2-, 3-, 4-, 5-, 6-, 7-, 8- or dec-9-enyl.

[0080] Especially preferred alkenyl groups are C.sub.2-C.sub.7-1 E-alkenyl, C.sub.4-C.sub.7-3E-alkenyl, C.sub.5-C.sub.7-4-alkenyl, C.sub.6-C.sub.7-5-alkenyl and C.sub.7-6-alkenyl, in particular C.sub.2-C.sub.7-1 E-alkenyl, C.sub.4-C.sub.7-3E-alkenyl and C.sub.5-C.sub.7-4-alkenyl. Examples for particularly preferred alkenyl groups are vinyl, 1 E-propenyl, 1 E-butenyl, 1 E-pentenyl, 1 E-hexenyl, 1 E-heptenyl, 3-butenyl, 3E-pentenyl, 3E-hexenyl, 3E-heptenyl, 4-pentenyl, 4Z-hexenyl, 4E-hexenyl, 4Z-heptenyl, 5-hexenyl, 6-heptenyl and the like. Groups having up to 5 C-atoms are generally preferred.

[0081] In an alkyl group, wherein one CH.sub.2 group is replaced by O and one by CO, these radicals are preferably neighboured. Accordingly these radicals together form a carbonyloxy group COO or an oxycarbonyl group OCO. Preferably such an alkyl group is straight-chain and has 2 to 6 C atoms.

[0082] It is accordingly preferably acetyloxy, propionyloxy, butyryloxy, pentanoyloxy, hexanoyloxy, acetyloxymethyl, propionyloxymethyl, butyryloxymethyl, pentanoyloxymethyl, 2-acetyloxyethyl, 2-propionyloxy-ethyl, 2-butyryloxyethyl, 3-acetyloxypropyl, 3-propionyloxypropyl, 4-acetyloxybutyl, methoxycarbonyl, ethoxycarbonyl, propoxycarbonyl, butoxycarbonyl, pentoxycarbonyl, methoxycarbonylmethyl, ethoxy-carbonylmethyl, propoxycarbonylmethyl, butoxycarbonylmethyl, 2-(methoxycarbonyl)ethyl, 2-(ethoxycarbonyl)ethyl, 2-(propoxy-carbonyl)ethyl, 3-(methoxycarbonyl)propyl, 3-(ethoxycarbonyl)propyl, 4-(methoxycarbonyl)-butyl.

[0083] An alkyl group wherein two or more CH.sub.2 groups are replaced by O and/or COO, it can be straight-chain or branched. It is preferably straight-chain and has 3 to 12 C atoms. Accordingly it is preferably bis-carboxy-methyl, 2,2-bis-carboxy-ethyl, 3,3-bis-carboxy-propyl, 4,4-bis-carboxy-butyl, 5,5-bis-carboxy-pentyl, 6,6-bis-carboxy-hexyl, 7,7-bis-carboxy-heptyl, 8,8-bis-carboxy-octyl, 9,9-bis-carboxy-nonyl, 10,10-bis-carboxy-decyl, bis-(methoxycarbonyl)-methyl, 2,2-bis-(methoxycarbonyl)-ethyl, 3,3-bis-(methoxycarbonyl)-propyl, 4,4-bis-(methoxycarbonyl)-butyl, 5,5-bis-(methoxycarbonyl)-pentyl, 6,6-bis-(methoxycarbonyl)-hexyl, 7,7-bis-(methoxycarbonyl)-heptyl, 8,8-bis-(methoxycarbonyl)-octyl, bis-(ethoxycarbonyl)-methyl, 2,2-bis-(ethoxycarbonyl)-ethyl, 3,3-bis-(ethoxycarbonyl)-propyl, 4,4-bis-(ethoxycarbonyl)-butyl, 5,5-bis-(ethoxycarbonyl)-hexyl.

[0084] A alkyl or alkenyl group that is monosubstituted by CN or CF.sub.3 is preferably straight-chain. The substitution by CN or CF.sub.3 can be in any desired position.

[0085] An alkyl or alkenyl group that is at least monosubstituted by halogen, it is preferably straight-chain. Halogen is preferably F or Cl, in case of multiple substitution preferably F. The resulting groups include also perfluorinated groups. In case of monosubstitution the F or Cl substituent can be in any desired position, but is preferably in w-position. Examples for especially preferred straight-chain groups with a terminal F substituent are fluoromethyl, 2-fluoroethyl, 3-fluoropropyl, 4-fluorobutyl, 5-fluoropentyl, 6-fluorohexyl and 7-fluoroheptyl. Other positions of F are, however, not excluded.

[0086] Halogen means F, Cl, Br and I and is preferably F or Cl, most preferably F.

[0087] The compounds of formula I and II are accessible by the usual methods known to the expert. Starting materials are either commercially available or accessible by published methods.

[0088] Preferably the first fluid according to the instant invention comprises one or more compounds selected from the group of compounds of formulae I and II.

[0089] The concentration of the individual compounds in the first fluid according to the present invention are preferably in the range from 0.5% or more to 70% or less, more preferably in the range from 1% or more to 60% or less and most preferably in the range from 5% or more to 50% or less.

[0090] The first fluid comprises a mixture of one or more compounds selected from the group of compounds of formulae I and II, preferably in a total concentration in the range from 70% or more to 100.0% or less, preferably from 80% or more to 100.0% or less and most preferably from 90% or more to 100.0% or less.

[0091] In particular, the first fluid preferably comprises one or more compounds of formula I in a total concentration in the range from 40% or more to 100.0% or less, preferably from 60% or more to 90% or less and most preferably from 80% or more to 90% or less.

[0092] In case the first fluid comprises one or more compounds formula II, the total concentration of these compounds preferably is in the range from 1% or more to 30% or less, preferably from 5% or more to 25% or less and most preferably from 10% or more to 20% or less.

[0093] Preferred embodiments are indicated below: [0094] the first fluid comprises one, two, three, four or more compounds of formula I, preferably of formula I-1, and/or [0095] the first fluid comprises one, two or more compounds of formula II, preferably of formula II-2.

[0096] The compounds of the formulae I and II are colourless, stable and readily miscible with one another and with other liquid-crystalline materials. The optimum mixing ratio of the compounds of the formulae I and II depends substantially on the desired properties, on the choice of the components of the formulae I or II, and on the choice of any other components that may be present. Suitable mixing ratios within the range given above can easily be determined from case to case.

[0097] The total amount of compounds of the formulae I and II in the first fluid is in many cases not crucial. The mixtures can therefore comprise one or more further mesogenic compounds for the purposes of optimisation of various properties. Such compounds are known to the person skilled in the art. However, the observed effect on the operating voltage and the operating temperature range is generally greater, the higher the total concentration of compounds of the formulae I and II.

[0098] In a particularly preferred embodiment, the media according to the invention comprise one or more compounds each of the formulae I and II. A favourable synergistic effect with the compounds of the formula I results in particularly advantageous properties. In particular, mixtures comprising compounds of formula I and of formula II are distinguished by their low operating voltages.

[0099] The individual compounds of the formulae I and II, which can be used in the media according to the invention, are either known or can be prepared analogously to the known compounds.

[0100] In another preferred embodiment the first fluid comprises one or more compounds selected from the group of compounds of formula I and/or II, and additionally non-mesogenic compounds.

[0101] Said non mesogenic compounds are used to adapt the properties of the first fluid according to the needs of the optical component and are preferably high boiling organic liquids, preferably selected from 3-phenoxytoluene, butoxybenzene, benzyl methyl ether, benzyl ethyl ether, benzyl propyl ether, benzyl butyl ether, 1,4-benzodioxane, dipropoxybenzene, 2,5-dimethoxytoluene, 4-ethylphenetole, 1,2,4-trimethoxybenzene, 1,2-dimethoxybenzene, 1,3-dimethoxybenzene, dibenzyl ether, 4-tert.-butylanisole, anisole, phenetole, 2-methoxytoluene, 3-methoxytoluene, 4-methoxytoluene, 2,2-dimethyl-1,3-bonzodioxole, 1,8-cineole, 2,3-dihydro-2-methylbenzofuran, 2,3-dihydrobenzofuran, 3,5-dimethylanisole, 2,5-dimethylanisole, 4-ethylanisole, 1,2-methylenedioxybenzene.

[0102] Liquid means that the substance has a melting point below room temperature.

[0103] High boiling according to the present invention means that the boiling point of the liquid at normal pressure is above 150 C., preferably above 180 C., most preferably above 200 C.

[0104] In a preferred embodiment of the present invention the first fluid is a nematic liquid crystal.

[0105] In another preferred embodiment the first fluid is isotropic at room temperature.

[0106] Further it is preferred that the dielectric constant of the first fluid is 100 to 1000 or above, more preferably 200 to 500 or above.

[0107] The liquid-crystal mixtures which can be used in accordance with the invention are prepared in a manner conventional per se, for example by mixing one or more compounds of the formula I with one or more compounds of the formulae II or with further liquid-crystalline compounds and/or additives. In general, the desired amount of the components used in lesser amount is dissolved in the components making up the principal constituent, advantageously at elevated temperature. It is also possible to mix solutions of the components in an organic solvent, for example in acetone, chloroform or methanol, and to remove the solvent again, for example by distillation, after thorough mixing. The invention furthermore relates to the process for the preparation of the LC media according to the invention.

[0108] In the present invention and especially in the following examples, the structures of the mesogenic compounds are indicated by means of abbreviations, also called acronyms. In these acronyms, the chemical formulae are abbreviated as follows using Tables A to C below. All groups C.sub.nH.sub.2n+1, C.sub.mH.sub.2m+1 and C.sub.lH.sub.2l+1 or C.sub.nH.sub.2n-1, C.sub.mH.sub.2m-1 and C.sub.lH.sub.2l-1 denote straight-chain alkyl or alkenyl, preferably 1 E-alkenyl, each having n, m and I C atoms respectively. Table A lists the codes used for the ring elements of the core structures of the compounds, while Table B shows the linking groups. Table C gives the meanings of the codes for the left-hand or right-hand end groups. The acronyms are composed of the codes for the ring elements with optional linking groups, followed by a first hyphen and the codes for the left-hand end group, and a second hyphen and the codes for the right-hand end group. Table D shows illustrative structures of compounds together with their respective abbreviations.

TABLE-US-00001 TABLE A Ring elements C [00025] P [00026] D [00027] DI [00028] A [00029] AI [00030] G [00031] GI [00032] U [00033] UI [00034] Y [00035] M [00036] MI [00037] N [00038] NI [00039] Np [00040] dH [00041] N3f [00042] N3fI [00043] tH [00044] tHI [00045] tH2f [00046] tH2fI [00047] K [00048] KI [00049] L [00050] LI [00051] F [00052] FI [00053]

TABLE-US-00002 TABLE B Linking groups E CH.sub.2CH.sub.2 Z COO V CHCH ZI OCO X CFCH O CH.sub.2O XI CHCF OI OCH.sub.2 B CFCF Q CF.sub.2O T CC QI OCF.sub.2 W CF.sub.2CF.sub.2 T CC

TABLE-US-00003 TABLE C End groups Left-hand side Right-hand side Use alone -n- C.sub.nH.sub.2n+1 -n C.sub.nH.sub.2n+1 -nO- C.sub.nH.sub.2n+1O -nO OC.sub.nH.sub.2n+1 -V- CH.sub.2CH -V CHCH.sub.2 -nV- C.sub.nH.sub.2n+1CHCH -nV C.sub.nH.sub.2nCHCH.sub.2 -Vn- CH.sub.2CHC.sub.nH.sub.2n+1 -Vn CHCHC.sub.nH.sub.2n+1 -nVm- C.sub.nH.sub.2n+1CHCHC.sub.mH.sub.2m -nVm C.sub.nH.sub.2nCHCHC.sub.mH.sub.2m+1 -N- NC -N CN -S- SCN -S NCS -F- F -F F -CL- Cl -CL Cl -M- CFH.sub.2 -M CFH.sub.2 -D- CF.sub.2H -D CF.sub.2H -T- CF.sub.3 -T CF.sub.3 -MO- CFH.sub.2O -OM OCFH.sub.2 -DO- CF.sub.2HO -OD OCF.sub.2H -TO- CF.sub.3O -OT OCF.sub.3 -OXF- CF.sub.2CHO -OXF OCHCF.sub.2 -A- HCC -A CCH -nA- C.sub.nH.sub.2n+1CC -An CCC.sub.nH.sub.2n+1 -NA- NCCC -AN CCCN Use together with one another and/or with others - . . . A . . . - CC - . . . A . . . CC - . . . V . . . - CHCH - . . . V . . . CHCH - . . . Z . . . - COO - . . . Z . . . COO - . . . ZI . . . - OCO - . . . ZI . . . OCO - . . . K . . . - CO - . . . K . . . CO - . . . W . . . - CFCF - . . . W . . . CFCF
in which n and m each denote integers, and the three dots . . . are place-holders for other abbreviations from this table.

[0109] The following table shows illustrative structures together with their respective abbreviations. These are shown in order to illustrate the meaning of the rules for the abbreviations. They furthermore represent compounds which are preferably used.

TABLE-US-00004 TABLE D Illustrative structures [00054] GGP-n-F [00055] GGP-n-CL [00056] PGIGI-n-F [00057] PGIGI-n-CL [00058] GGP-n-T [00059] PGU-n-T [00060] GGU-n-T [00061] DPGU-n-F [00062] PPGU-n-F [00063] DPGU-n-T [00064] PPGU-n-T [00065] PUQU-n-N [00066] GUQU-n-N [00067] GUQU-n-F [00068] PUQGU-n-F [00069] GUQGU-n-F [00070] PUQGU-n-T [00071] GUQGU-n-T [00072] MGQU-n-F [00073] MGQU-n-T [00074] MGQU-n-N [00075] MUQU-n-F [00076] MUQU-n-T [00077] MUQU-n-N [00078] NGQU-n-F [00079] NGQU-n-T [00080] NGQU-n-N [00081] NUQU-n-F [00082] NUQU-n-T [00083] NUQU-n-N [00084] PZG-n-N [00085] PZU-n-N [00086] CPZG-n-N [00087] DGUQU-n-F [00088] DUUQU-n-F [00089] DGUQU-n-T [00090] DUUQU-n-T [00091] DGUQU-n-N [00092] DUUQU-n-N [00093] DUQGU-n-F [00094] DUQGU-n-T [00095] DUQGU-n-N
in which n preferably, independently of one another, denotes an integer from 1 to 7, preferably from 2 to 6.

[0110] The following table, Table E, shows illustrative compounds which can be used as stabiliser in the mesogenic media according to the present invention.

TABLE-US-00005 TABLE E [00096] [00097] [00098] [00099] [00100] [00101] [00102] [00103] [00104] [00105] [00106] [00107] [00108] [00109] [00110] [00111] [00112] [00113] [00114] [00115] [00116] [00117] [00118] [00119]

[0111] In a preferred embodiment of the present invention, the mesogenic media comprise one or more compounds selected from the group of the compounds from Table E.

[0112] The following table, Table F, shows illustrative compounds which can preferably be used as chiral dopants in the mesogenic media according to the present invention.

TABLE-US-00006 TABLE F [00120] C 15 [00121] CB 15 [00122] CM 21 [00123] CM 44 [00124] CM 45 [00125] CM 47 [00126] CC [00127] CN [00128] R/S-811 [00129] R/S-1011 [00130] R/S-2011 [00131] R/S-3011 [00132] R/S-4011 [00133] R/S-5011

[0113] In a preferred embodiment of the present invention, the liquid-crystal media comprise one or more compounds selected from the group of the compounds from Table F.

[0114] The mesogenic media according to the present application preferably comprise two or more, preferably four or more, compounds selected from the group consisting of the compounds from the above tables.

[0115] The liquid-crystal media according to the present invention preferably comprise [0116] seven or more, preferably eight or more, compounds, preferably compounds having three or more, preferably four or more, different formulae, selected from the group of the compounds from Table D.

[0117] The substrates may be made from any suitable material which allows confinement of the fluid and is preferably an optically isotropic material (i.e. one which has no birefringence), such as glass.

[0118] The thickness of the substrate is preferably 0.1 mm-3 mm, more preferably 0.5 mm-2 mm and most preferably 1.0 mm-1.5 mm. The substrate is preferably transparent in the region of visible light.

[0119] The fluid enclosure has an internal volume to receive first and second fluids, preferably in the form of immiscible liquids arranged relative to each other in separate layers. The first fluid is a liquid crystal material, and the second fluid is a non-conductive liquid, preferably a substantially fluorinated liquid. In preferred embodiments, both the liquid crystal and second fluid are substantially transparent to light and each has a different refractive index being different from the other fluid when the liquid crystal is in the isotropic state and when the liquid crystal is birefringent at least one of the uniaxial refractive indices of the liquid crystal is different from the refractive index of the second fluid.

[0120] The first and second electrodes are preferably interdigitated electrodes which comprise at least one pair of comb-shaped electrodes being arranged so as to oppose each other with their teeth interleaved. The width of the electrodes is preferably 5-240 m, more preferably 10-150 m, most preferably 25-100 m and can be the same for each electrode or different, preferably the same. The interelectrode gap is preferably 1-100 m, more preferably 5-75 m, most preferably 10-50 m and can be the same for each gap or different, preferably the same.

[0121] Preferably, the interelectrode gap is smaller than the electrode linewidth by a factor in the range of 0.9 to 0.1, more preferably 0.25 to 0.75 and most preferably 0.4 to 0.6. The electrodes are preferably transparent and may be made from any suitable transparent conductive material, preferably indium tin oxide (ITO), indium zinc oxide (IZO), antimony tin oxide (ATO), RuO.sub.2 or PEDOT, most preferably ITO. The electrodes preferably have a resistance per square below 100 /.

[0122] In a preferred refinement of the present invention the electrodes are covered with a polymer layer (30) having high transparency, preferably a polyimide or Teflon, to guard against charge injection from the electrodes (20, 21), or to promote wetting of the liquid crystal. Further, it can be preferred that said polymer layer is a liquid crystal orientation layer (rubbed polyimide) to promote preferred alignment of the liquid crystal.

[0123] Preferably the upper substrate (11) is untreated.

[0124] Further it can be preferred that the upper substrate is covered with a polymer layer (31) having high transparency, preferably a polyimide or Teflon.

[0125] References herein to transparent are to be taken as meaning that the material or substance permits most, if not all, of the light incident on the material or substance to pass therethrough without significant attenuation. Moreover, all references to light, incident light and associated terms, are to be understood as referring to in particular, visible light, but may also include other radiations from other regions of the electromagnetic spectrum, e.g. ultra-violet and infra-red.

[0126] In all embodiments of the present invention the voltage applied can be either d.c. or a.c., preferably a.c.

[0127] FIG. 2 illustrates the effect of applying a voltage to the first and second electrodes of the device of FIG. 1. When a voltage is applied, a static wrinkle is formed at the interface between the first fluid (40) and the second fluid (41), the wrinkle height being a function of the voltage.

[0128] As a result of the applied voltage, the interface between first fluid (40) and the second fluid (41) now has taken the shape of a periodic wave, thus forming a sequence of cylindrical lenses. Since the height of the wrinkles depends on the voltage the focal length of these cylindrical lenses can be controllably adjusted as a result of varying the voltage applied to the electrodes.

[0129] When the applied voltage between the first and second electrodes (20, 21) is lowered or reduced to zero the system reverts to the initial state shown in FIG. 1.

[0130] The following abbreviations and symbols are used: [0131] n.sub.e extraordinary refractive index at 20 C. and 589 nm, [0132] n.sub.o ordinary refractive index at 20 C. and 589 nm, [0133] n optical anisotropy at 20 C. and 589 nm, [0134] .sub. dielectric susceptibility perpendicular to the director at 20 C. and 1 kHz, [0135] .sub. dielectric susceptibility parallel to the director at 20 C. and 1 kHz, [0136] dielectric anisotropy at 20 C. and 1 kHz, [0137] cl.p., T(N,I) clearing point [ C.],

[0138] Unless explicitly noted otherwise, all concentrations in the present application are indicated in percent by weight and relate to the corresponding mixture as a whole without solvents.

[0139] Unless explicitly noted otherwise, all temperature values indicated in the present application, such as, for example, the melting point T(C,N), the transition from the smectic (S) to the nematic (N) phase T(S,N) and the clearing point T(N,I), are indicated in degrees Celsius ( C.). M.p. denotes melting point, cl.p.=clearing point. Furthermore, C=crystalline state, N=nematic phase, S=smectic phase and I=isotropic phase. The data between these symbols represent the transition temperatures.

[0140] All physical properties are and have been determined in accordance with Merck Liquid Crystals, Physical Properties of Liquid Crystals, Status November 1997, Merck KGaA, Darmstadt, Germany, and apply to a temperature of 20 C., and n is determined at 589 nm and at 1 kHz, unless explicitly indicated otherwise in each case.

[0141] The liquid-crystalline properties of the individual compounds are, unless indicated otherwise, determined in the nematic host mixture ZLI-4792 (commercially available from Merck KGaA, Darmstadt) at a concentration of 10%.

[0142] Room temperature means 20 C., unless indicated otherwise.

EXAMPLES

[0143] The examples below illustrate the present invention without limiting it in any way.

[0144] A liquid crystalline mixture M-1 is prepared as follows.

TABLE-US-00007 Composition and properties liquid crystal mixture M-1 Composition Compound Conc./ No. Abbreviation mass-% 1 GUQGU-3-F 8.0 2 GUQGU-4-F 6.0 3 GUQGU-5-F 4.0 4 GUUQU-3-N 6.0 5 GUQU-3-F 7.0 6 GUQU-4-F 6.0 7 GUQGU-2-T 12.0 8 GUQGU-3-T 12.0 9 GUQGU-4-T 12.0 10 GUQGU-5-T 12.0 11 DPGU-4-F 8.0 12 PGU-5-T 3.0 13 PGU-4-T 4.0 100.0 Physical Properties T(N, I) = 72.5 C. n.sub.o(20 C., 589 nm) = 1.4882 n.sub.e(20 C., 589 nm) = 1.6811 n(20 C., 589 nm) = 0.1929 .sub.(20, 1 kHz) = 11.5 .sub.||(20, 1 kHz) = 213.6 (20, 1 kHz) = 202.1

[0145] A liquid crystalline mixture M-2 is prepared as follows.

TABLE-US-00008 Composition and properties liquid crystal mixture M-2 Composition Compound Conc./ No. Abbreviation mass-% 1 GUUQU-3-N 4.0 2 GUUQU-4-N 8.0 3 GUUQU-5-N 8.0 4 GUQU-3-F 6.0 5 GUQU-4-F 6.0 6 GUQGU-2-T 8.0 7 GUQGU-3-T 8.0 8 GUQGU-4-T 8.0 9 GUQGU-5-T 8.0 10 PGU-4-T 8.0 11 PGU-5-T 8.0 12 DUUQU-4-F 6.0 13 DUUQU-5-F 6.0 14 DGUQU-4-F 8.0 100.0 Physical Properties T(N, I) = 65 C. .sub.(20, 1 kHz) = 16.0 .sub.||(20, 1 kHz) = 392.8 (20, 1 kHz) = 376.8

[0146] Table 1 summarises the properties of M-1 and M-2 in comparison with isotropic liquid TTE and commercially available liquid crystal E7.

TABLE-US-00009 TABLE 1 Material .sub.|| .sub. n.sub.o n.sub.e T (N, I) Trimethylolpropane 13.5 13.5 1.477 1.477 not triglycidyl nematic ether (TIE) E7 19.5 5.2 1.65 1.50 60 M-1 213.6 11.5 1.68 1.49 73 M-2 392.8 16.0 1.44 65

[0147] From the materials shown in table 1, cylindrical lens elements were fabricated and characterised in the following manner.

[0148] Single fluid experiments were first performed to demonstrate the effect and to characterise the lens elements using a first fluid (40) without application of a second fluid (41). Single fluid experiments were performed with a borosilicate glass slide substrate. The substrate had been pre-coated with an approximately 25 nm thick layer of indium tin oxide of resistivity approximately 100 Ohm/square. This coating was provided commercially by Prazisions Glas and Optik GmbH, Iserlohn, Germany. Standard photolithographic procedures were used to etch and pattern the indium tin oxide layer to produce an array of co-planar interdigital stripe electrodes, (corresponding to 20, 21 in FIG. 1), as well as contact pads. Electrodes (20) were connected to an indium tin oxide contact pad on one side of the substrate in the positive y direction, and electrodes (21) were connected to a separate contact pad on the other side of the substrate in the negative y direction. Electrodes (20) and (21) were co-located and interleaved on a square region of the substrate which typically covered an area of 12 mm by 12 mm. The substrate and the electrodes were coated with an approximately 0.8 M thick layer of photoresist (commercial material SU8-10, MicroChem Corp., Newton, Mass., USA) which had been cured and hardened by exposure to UV radiation and heating. The SU8-10 layer was removed from above the contact pads. A droplet of liquid was dispensed onto the electrode area of the substrate using a Gilson Pipetman micropipette (Gilson, Inc., Middleton, USA). Electrical addressing of the device was performed with a sinewave voltage, typically with 10 kHz frequency, applied to alternate electrodes via a contact pad. Interposed electrodes were connected to earth potential via the other contact pad. The voltage was provided by a wave form generator connected to a PZD700A-1 amplifier (Trek Inc., Medina, New York, USA). Applying a voltage amplitude typically above 25 V (r.m.s.) for M-1 and M-2, or typically above 125 V (r.m.s.) for E7 or TTE, spread the fluid film until it formed a thin layer coating the substrate in the region on top of the co-located interleaved electrodes. Further increase in the voltage amplitude increased the amplitude of wrinkles on the fluid-air surface of the film. Side images of the liquid film under diffuse white light side illumination were taken from the y-direction using a standard USB video camera (for example, DCC1645C, ThorLabs, Ely, UK) typically fitted with a 10 objective lens allowed the wrinkle on top of the fluid to be viewed. By focusing on a region at the top of the fluid film these images allowed the peak to trough amplitude of the wrinkle to be measured as different r.m.s. amplitudes of the voltage were applied, giving the data for FIG. 3. The focal length values on the vertical axis on FIG. 4 were obtained using a top view of the substrate with a standard USB video camera typically fitted with a 10 objective lens looking down from the z direction whist the substrate was illuminated from underneath with collimated white light from an LED. The height of the USB video camera was adjusted using a micrometer operated translation stage in the z-direction. The camera was first focused onto the top of the substrate in a region where there was no fluid present. It was moved sideways until it was positioned above the region containing the fluid, spread under voltage. The height of the camera was then raised until a series of sharp parallel focused lines of light were visible. The distance of the height raised was recorded as the focal length in the positive direction, shown in FIG. 4. A similar process was used to record the focal length in the negative direction, shown in FIG. 4, except the height of the camera was lowered relative to its position when focused on the substrate.

[0149] From FIG. 3 it can be seen that for a given voltage higher wrinkle amplitudes can be achieved using the liquid materials M-1 and M-2 compared to liquid crystal E7 and polar liquid TTE.

[0150] Correspondingly, when using M-1 or M-2, the focal length can be shortened at relatively lower voltages, as shown in FIG. 4.

Application of Second Fluid

[0151] The data shown in FIG. 5 was recorded using the same experimental technique and substrate as described above for FIG. 4. The difference is that a cuvette was glued to the substrate to allow a layer of liquid perfluorodecalin (fluid 41 in FIG. 2) to remain on top of and to immerse the spread layer of liquid crystal fluid M-1 (fluid 40 in FIG. 2).

[0152] An approx. 20 m thick film of LC-mixture M-1 (Electrodes: linewidth 80 m, gaps 40 m) as the first fluid was covered with a layer of perfluorodecalin as the second fluid.

[0153] As can be seen from FIG. 5, the switching behaviour, (i.e. the change of the focal length with the applied voltage) is similar after addition of the second liquid layer.