Hot Melt Adhesive Film for Bonding Rubber and Ethylene-Vinyl Acetate (EVA) Foam

Abstract

A hot melt adhesive film for bonding an ethylene-vinyl acetate form and a rubber includes a hot melt adhesive film layer and a release film layer. The hot melt adhesive film layer is prepared by the following raw materials in parts by weight: a 60-90 parts by weight of polyethylene-ester copolymer, a 10-40 parts by weight of rubber, a 1-15 parts by weight of thermoplastic polyolefin, and a 5-25 parts by weight of auxiliary. The release film layer is releasably adhered to the hot melt adhesive film layer.

Claims

1. A hot melt adhesive film for bonding an ethylene-vinyl acetate (EVA) foam and a rubber comprising: a hot melt adhesive film layer prepared by the following raw materials in parts by weight: a 60-90 parts by weight of polyethylene-ester copolymer, a 10-40 parts by weight of rubber, a 1-15 parts by weight of thermoplastic polyolefin, and a 5-25 parts by weight of an auxiliary; and a release film layer releasably adhered to the hot melt adhesive film layer; wherein said auxiliary includes a rubber activator selected from the group consisting of a magnesium oxide, a calcium oxide, a stearate, or a blend thereof.

2. The hot melt adhesive film according to claim 8, wherein said polyethylene-ester copolymer is 75-90 parts by weight, said rubber is 10-30 parts by weight, and said auxiliary is 10-20 parts by weight.

3. The hot melt adhesive film according to claim 8, wherein said polyethylene-ester copolymer is at least one selected from the group consisting of a polyethylene-vinyl-acetate copolymer, a polyethylene methyl acrylate copolymer, a polyethylene ethyl acrylate copolymer, or a blend thereof.

4. The hot melt adhesive film according to claim 8, wherein said rubber is at least one selected from group consisting of natural rubber, synthetic rubber, or a blend of said natural rubber and said synthetic rubber, and wherein said synthetic rubber is one of the following kinds: a chloroprene rubber (CR), a styrene-butadiene rubber (SBR), a polybutadiene rubber (BR), a acrylonitrile butadiene rubber (NBR), a polyisoprene rubber (IR), a butyl rubber (IIR), an ethylene propylene copolymer (EPR), an ethylene propylene diene monomer (EPDM), or a blend thereof.

5. The hot melt adhesive film according to claim 8, wherein said thermoplastic polyolefin is at least one selected from the group consisting of a high density polyethylene, a linear low density polyethylene, a polypropylene homopolymer, a polypropylene copolymer, an ethylene propylene copolymer, a 1,2-polybutadiene, or a blend thereof.

6. (canceled)

7. The hot melt adhesive film according to claim 8, wherein said rubber vulcanizing accelerator is at least one selected from the group consisting of a thiazole vulcanization accelerator, a sulfonamide, a guanidine, a dithio carbamate, a thiourea, a thiurams, or a blend thereof wherein said rubber scorch retarder is at least one selected from the group consisting of a phthalic anhydride, a salicylic acid, a benzoic acid, a N-nitrosodiphenylamine, a phthalic imide sulfenamide or a blend thereof, wherein said antiozonant is at least one selected from the group consisting of a microcrystalline wax, a paraffin, a natural asphalt, or a blend thereof, wherein said initiator is an organic peroxide initiator.

8. The hot melt adhesive film according to claim 1, wherein said auxiliary is at least one selected from the group consisting of a rubber vulcanizing accelerator, a rubber vulcanizing agent, the rubber activator, a rubber scorch retarder, an initiator, an antiozonant, an antioxidant, or a blend thereof.

9. The hot melt adhesive film according to claim 2, wherein said polyethylene-ester copolymer is at least one selected from the group consisting of a polyethylene-vinyl acetate copolymer, a polyethylene methyl acrylate copolymer, a polyethylene ethyl acrylate copolymer, or a blend thereof.

10. The hot melt adhesive film according to claim 9, wherein said rubber is at least one selected from group consisting of natural rubber, synthetic rubber, or a blend of said natural rubber and said synthetic rubber, and wherein said synthetic rubber is one of the following kinds: a chloroprene rubber (CR), a styrene-butadiene rubber (SBR), a polybutadiene rubber (BR), a acrylonitrile butadiene rubber (NBR), a polyisoprene rubber (IR), a butyl rubber (IIR), an ethylene propylene copolymer (EPR), an ethylene propylene diene monomer (EPDM), or a blend thereof.

11. The hot melt adhesive film according to claim 10, wherein said thermoplastic polyolefin is at least one selected from the group consisting of a high density polyethylene, a linear low density polyethylene, a polypropylene homopolymer, a polypropylene copolymer, an ethylene propylene copolymer, a 1,2-polybutadiene, or a blend thereof.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0012] FIG. 1 is a cross-sectional view of a hot melt adhesive film for bonding an ethylene-vinyl acetate (EVA) foam and a rubber in accordance with the present invention.

[0013] FIG. 2 is cross-sectional view showing the ethylene-vinyl acetate (EVA) foam and the rubber are bonded by the hot melt adhesive film layer of the hot melt adhesive film.

DETAILED DESCRIPTION OF THE INVENTION

[0014] A hot melt adhesive film for bonding an ethylene-vinyl acetate foam A and a rubber B includes a hot melt adhesive film layer 11 and a release film layer 12.

[0015] The hot melt adhesive film layer 11 is prepared by the following raw materials in parts by weight: a 60-90 parts by weight of polyethylene-ester copolymer, a 10-40 parts by weight of rubber, a 1-15 parts by weight of thermoplastic polyolefin, and a 5-25 parts by weight of auxiliary.

[0016] Preferably, the polyethylene-ester copolymer is 75-90 parts by weight. Preferably, the rubber is 10-30 parts by weight. Preferably, the auxiliary are 10-20 parts by weight.

[0017] The polyethylene-ester copolymer is one of the following kinds: a polyethylene-vinyl acetate copolymer, a polyethylene methyl acrylate copolymer, a polyethylene ethyl acrylate copolymer, a butyl acrylate copolymer, or a blend of two or more of said kinds.

[0018] The rubber is natural rubber, or synthetic rubber, or a blend of said natural rubber and said synthetic rubber, and wherein said synthetic rubber is one of the following kinds: a chloroprene rubber (CR), a styrene-butadiene rubber (SBR), a polybutadiene rubber (BR), a acrylonitrile butadiene rubber (NBR), a polyisoprene rubber (IR), a isobutylene isoprene butyl rubber (IIR), an ethylene propylene copolymer (EPR), an ethylene propylene diene monomer (EPDM), or a blend of two or more of said kinds.

[0019] The thermoplastic polyolefin is one of the following kinds: a high density polyethylene, a linear low density polyethylene, a polypropylene homopolymer, a polypropylene copolymer, an ethylene propylene copolymer, a 1,2-polybutadiene, or a blend of two or more of said kinds.

[0020] The auxiliary is one of the following kinds: a tackifier, a plasticizer, a filler, a rubber vulcanizing accelerator, a rubber activator, a softener, a rubber scorch retarder, an initiator, a crosslinking agent, a catalyst, an antiozonant, an antioxidant, an additive, or a blend of two or more of said kinds. The additive is vulcanizator or silane coupling agent.

[0021] The tackifiers is one of the following kinds: a rosin ester, a polymerized rosin, a terpene, a styrene terpene, a polyterpene phenolic resin, a petroleum resin, a modified petroleum resin, or a blend of two or more of said kinds.

[0022] The plasticizer is one of the following kinds: a mineral oil, a polybutylene, an isoprene rubber, or a blend of two or more of said kinds. The filler is one of the following kinds: a kaolin, a mica, a titanium dioxide, a silica, a talc, a carbon black, or a blend of two or more of said kinds.

[0023] The rubber vulcanizing accelerator is one of the following kinds: a thiazole vulcanization accelerator, a sulfonamide type, a guanidine type, a dithio carbamate type, a thiourea type, a thiurams type, or a blend of two or more of said kinds.

[0024] The rubber activator is one of the following kinds: a zinc oxide, a magnesium oxide, a calcium oxide, a stearate, or a blend of two or more of said kinds.

[0025] The softener is one of the following kinds: a mineral oil, a liquid paraffin, a linseed oil, a coco oil, a paraffin, a carnauba wax, a stearate, a palmitic acid, or a blend of two or more of said kinds.

[0026] The rubber scorch retarder is one of the following kinds: a phthalic anhydride, a salicylic acid, a benzoic acid, a N-nitrosodiphenylamine, a phthalic imide sulfenamide or a blend of two or more of said kinds.

[0027] The antiozonant is one of the following kinds: a microcrystalline wax, a paraffin, a natural asphalt, or a blend of two or more of said kinds.

[0028] The initiator is an oorganic peroxide initiator.

[0029] The crosslinking agent is a closed diisocyanate.

[0030] The catalyst is dibutyl tin dilaurate and/or stannous octoate.

[0031] The antioxidant is one of the following kinds: a N-(1,3-Dimethylbutyl), a N-phenyl-p-phenylenediamine (6PPD), a diphenyl-p-phenylenediamine (DPPD), an octylated diphenylamine (ODPA), 2-mercapto-benzimidazole (MB), a 2,6-Di-tert-butyl-4-methylphenol (BHT), or a blend of two or more of said kinds.

[0032] The vulcanizing agent is sulfur or sulfur donor vulcanizing agent for example: 4,4-dithiodimorpholine.

[0033] The silane coupling agent is one of the following kinds is n-octyltriethoxysilane, (3-glycidoxypropyl)methyldiethoxysilane or derivatives of triethoxysilane, sodium polysulphide or a blend of two or more of said kinds.

[0034] The release film layer 12 is releasably adhered to the hot melt adhesive film layer.

[0035] In the embodiment, 60 kg of polyethylene-ester copolymer, 20 kg of a natural rubber, 5 kg of a thermoplastic polyolefin, 4 kg of a tackifier, 0.7 kg of a stearic acid, 1.5 kg of a microcrystalline wax, 1 kg of a zinc oxide, 0.6 kg of sulfur, a mixture of 0.35 kg of a 2,2-dibenzothiaolyl disulfide (MBTS) and 0.2 kg of an Irganox 1010 antioxidant are kneaded by a kneader. Then a combined mixture of set forth ingredients are calendered to produce a unvulcanized hot melt adhesive film.

[0036] The procedure of using the hot melt adhesive film 1 to bond an ethylene-vinyl acetate (EVA) foam A and a rubber B includes removing the release film layer 12 from the hot melt adhesive film layer 11; positioning a first side of the hot melt adhesive film layer 11 on the rubber B; hot pressing the hot melt adhesive film layer 11 and the rubber B; positioning the ethylene-vinyl acetate (EVA) foam A on a second side of the hot melt adhesive film layer 11; and hot pressing the ethylene-vinyl acetate (EVA) foam A, the hot melt adhesive film layer 11, and the rubber B to bond them together.

[0037] With the hot melt adhesive film 1, the ethylene-vinyl acetate (EVA) foam A and the rubber B can be interconnected effortlessly, with fewer processes, economically, with fewer materials needed, and effectively than conventional adhesives.

[0038] The foregoing is merely illustrative of the principles of this invention and various modifications can be made by those skilled in the art without departing from the scope and spirit of the invention.