AUDIO SYSTEM

Abstract

Speakers for locating in a vehicle exhaust system having a speaker surround that is formed from a rubber compounded using a polyacrylate polymer. Speakers having a speaker surround that is integral with a coating that covers or substantially covers at least one surface of the diaphragm.

Claims

1.-18. (canceled)

19. A speaker for locating in a vehicle exhaust system, the speaker including a basket housing a voice coil and a spider and including a diaphragm, the diaphragm being affixed to the basket by a speaker surround, characterised in that the speaker surround is formed from a rubber compounded using a polyacrylate polymer.

20. The speaker of claim 19, wherein the diaphragm is formed of an aramid fibre material or fiberglass.

21. The speaker of claim 19, speaker surround is integral with a coating that covers or substantially covers at least one surface of the diaphragm.

22. The speaker of claim 21, wherein the speaker further comprises a dust cap, wherein the dust cap conceals a portion of the diaphragm, wherein the concealed portion is substantially free of rubber coating.

23. The speaker of claim 21, wherein the speaker further comprises a dust cap, wherein the dust cap is integral with the coating that covers or substantially covers at least one surface of the diaphragm and is integral with the speaker surround.

24. The speaker of claim 19, wherein the speaker further comprises a dust cap which is integral with the diaphragm.

25. The speaker of claim 19, wherein the diaphragm is secured to the speaker surround using a heat-cure epoxy adhesive.

26. The speaker of claim 19, wherein the diaphragm is secured to the speaker surround using insert molding techniques, compression molding techniques, or a combination of inset molding and compression molding techniques.

27. The speaker of claim 19, wherein the speaker surround is secured to the basket using a heat-cure epoxy adhesive.

28. The speaker of claim 19, wherein the rubber is compounded with an alkyl mercaptobenzimidazole, optionally wherein the rubber is compounded with methyl mercaptobenzimidazole.

29. The speaker of claim 19, wherein the rubber is compounded with both carbon black and clay.

30. An audio system for generating sound in a vehicle exhaust, the audio system comprising a speaker according to any preceding claim, a detector and a processor, wherein the detector is configured to detect engine noise and generate a first signal, the processor is configured to receive the signal and send a second signal to the speaker causing sound waves to be produced by the speaker.

31. A speaker including a basket housing a voice coil and a spider and including a diaphragm, the diaphragm being affixed to the basket by a speaker surround wherein the speaker surround is integral with a coating that covers or substantially covers at least one surface of the diaphragm.

32. The speaker of claim 31, wherein the coating covers or substantially covers only one surface of the diaphragm.

33. The speaker of claim 31, wherein the coating thickness is 60% or less than the thickness of the diaphragm.

34. The speaker of claim 31, wherein the speaker further comprises a dust cap, wherein the dust cap is integral with the coating that covers or substantially covers at least one surface of the diaphragm and is integral with the speaker surround.

35. The speaker of claim 31, wherein the speaker further comprises a dust cap, wherein the dust cap is integral with the diaphragm.

Description

[0051] The invention will now be described with reference to following drawings, in which:

[0052] FIG. 1 shows a partial cut away speaker according to the invention.

[0053] FIG. 2 shows a representative partially cut away drawing of the speaker in situ in an exhaust system.

[0054] FIG. 3 shows the variation in tensile strength of the ACM rubber used in the speaker surround of the present invention and a comparison EPDM-based rubber.

[0055] FIG. 4 shows changes in E-modulus, tensile strength and elongation after heat exposure at various temperatures for various durations.

[0056] FIG. 5 shows the DMTA of the ACM rubber used in the speaker surround of the present invention in a temperature sweep from ?100? C. to +200? C. with 1 Hz frequency.

[0057] FIG. 6 shows the TGA of the ACM rubber used in the speaker surround of the present invention.

[0058] FIG. 7 shows a speaker according the invention and a comparator speaker after a high power capacity handling test at 160? C.

[0059] FIG. 8 shows an illustration of a mold that may be used to cast an integral surround and diaphragm coating as described herein.

DETAILED DESCRIPTION

[0060] The following description is provided to illustrate the invention. It is not intended to limit the invention.

[0061] The invention relates to a speaker, which may be as illustrated in FIG. 1. The speaker is suitable for using in vehicle exhaust systems, where it is exposed to high temperatures and extreme atmospheric conditions. The speaker depicted in FIG. 1 is a 100 W subwoofer and includes a yoke 1 (referred to as a U or T yoke) which is formed of e-coated steel. This supports a magnet 2 and a voice coil 3 which is formed of insulated aluminium (the insulation is provided by paper or aramid fiber material). The speaker has a metal basket 4 formed of e-coated steel which surrounds the voice coil 3. Between the speaker and magnet is a washer 5 of e-coated steel. The washer is glued to the yoke and magnet. Inside the basket 4 is a spider 6 formed of aramid fiber material and glued to the inner wall of the basket. A lead wire 7 is provided and attached to a connector plate with tags on the basket housing. The speaker has a diaphragm 8 (often referred to as a cone) over the opening of the basket, towards the front of the speaker. This is formed of aramid fiber material. The back of the cone is in contact with the voice coil 3 such that motive force generated by the voice coil is transmitted to the cone. The voice coil 3 is protected by a dust cap 9 of aramid fiber material to prevent ingress of exhaust fumes, condensates and particulates during use. The speaker has a speaker surround 10 around the circumference at the basket opening. This speaker surround is formed of a rubber compounded using a polyacrylate polymer. In other words, the rubber composition of the speaker is based on a polyacrylate polymerthe rubber is an ACM rubber. The cone is adhered to the speaker surround 10 at a location 11 around the entire circumference. The adhesion is achieved by a high temperature adhesive. The speaker surround is glued to the basket edge at a location 12 around the entire circumference.

[0062] In situ, the speaker is located in a vehicle exhaust system, with the front of the speaker directed into the engine emission stream. This typically includes exhaust fumes (such as CO.sub.x, NO.sub.x, SO.sub.x), extremely acidic gasoline or diesel condensate and incompletely combusted hydrocarbons. The front of the speaker may therefore be expected to experience temperatures of 160? C. during use, while the back (magnet) portion may experience temperatures of 125? C. owing to the engine system, rising to 140? C. as the magnet operation itself may generate heat. During operation, the voice coil may generate up to 65? C. of heat, in addition to that experienced as a result of the vehicle operation.

[0063] The speaker may be controlled by a processor (not shown) which in turn receives information from a detector (not shown). The interfaces and connections between the detector, processor and speaker may be wired or wireless.

[0064] Of course, it will be appreciated that other appropriate speaker arrangements may be used, either as described herein or as is apparent to a person skilled in the art. For example, and not by way of limitation, the diaphragm 8 and speaker surround 10 may be inset molded together such that no adhesive is used. The speaker shown and described is circular, however, other appropriate shapes and arrangements may be envisaged. Except where specified otherwise, for example, in the claims, other suitable materials may be used. For example, stainless steel may replace e-coated steel.

[0065] The speaker of FIG. 1 is locatable in a vehicle exhaust system. Various locations and methods for installing a speaker arrangement in an exhaust system will be apparent to the skilled person. FIG. 2 shows a non-limiting possible arrangement. FIG. 2 a portion of a vehicle exhaust system comprising a pipe 100 through with exhaust gases flow. The pipe, and therefore exhaust gases, are in fluid communication via tube 101 with a speaker unit 102 housing a speaker 103 according to the invention. To assist pressure equalization, a pressing equalising tube 104 may be provided.

[0066] Of course, it will be appreciated that the speaker may be provided in a chamber in the exhaust system, with the exhaust gasses flowing through said chamber. Advantageously, there is no need to provide a filter to protect the speaker from the exhaust gasses.

[0067] Abbreviations

[0068] ACM-polyacrylate polymer

[0069] ANC-engine noise cancellation

[0070] ASD-engine harmonics addition

[0071] DMTA-dynamic mechanical thermal analysis

[0072] EPDM-ethylene propylene diene polymer

[0073] EPHR-chemical equivalents per hundred of rubber

[0074] PHR-parts per hundred of rubber

[0075] T.sub.g-glass transition

[0076] TGA-thermogravimetrical analysis

[0077] Definitions

[0078] Aramid fiber material

[0079] This describes a class of materials formed of strong, heat-resistant fibers. These fibers are produced by spinning solid fibers from a liquid chemical blend of aromatic polyamides.

[0080] For example, the aramid fiber material may comprise a para-aramid such as Kevlar? or a meta-aramid such as Nomex?.

[0081] Parts Per Hundred of Rubber

[0082] This is a commonly used way of describing the relative amounts of the various components in a compounded rubber. It refers to relative amounts of starting materials that are compounded with respect to the polymer used (the ratio of which is set to 100). In other words, 5 PHR of an ingredient means that 5 kg of this ingredient is added 100 kg of polymer.

[0083] Vulcanisation/Curing

[0084] This is the chemical process of cross-linking a rubber composition to provide a more durable material. Vulcanization is typically achieved with sulfur. For example, for high temperature rubbers such as EPDM rubbers, o-toluidines such as DOTG are commonly used. However, o-toluidines have recently been added to EU REACH candidate list of substances for very high concern for authorisation owing to their carcinogenic properties. Advantageously, the rubbers of the present invention are cured without the use of o-toluidines.

[0085] Rubber Compositions

[0086] The rubber of the speaker surround is compounded using an ACM polymer.

[0087] Polyacrylate polymer, also referred to as ACM polymer, is formed from a monomer composition comprising acrylic acid ester units. It may be formed from a monomer composition comprising only acrylic acid ester units. However, small amounts of monomers other than acrylic acid ester units may be present. Suitably, the composition comprises 90 to 99.9% by weight acrylic acid ester monomer units. Suitably, the composition comprises 60-90% by weight, optionally 70-90% by weight, for example, about 80% by weight alkyl acrylate monomers. Suitably, at least half of the alkyl monomer is ethyl acrylate monomer. Suitably, the ethyl acetate is copolymerised with other acrylate esters. Suitably, the composition may comprise 40 to 70% by weight ethyl acrylate, for example 50 to 60% by weight. A representative value is around 50% by weight ethyl acrylate. Suitable other acrylate esters include n-butyl acrylate and 2-methoxyethyl acrylate.

[0088] The composition may comprise 0.1 to 10% by weight at least one carboxyl group-containing ethylenically unsaturated monomer, for example mono-n-methyl maleate or mono-n-methyl fumarate, and/or a monomer comprising a reactive halogen such as vinyl chloroacetate. This may be referred to as a functionalised monomer. For example, the composition may comprise 1 to 5% by weight functionalised monomer. More than one functionalised monomer may be present. For example, a mixture of chloro and carboxyl groups may be present in the polymer.

[0089] In some embodiments, the ACM polymer is not a dual cure-type polymer (in other words, it is substantially free of carboxyl groups). In some embodiments, the composition does not comprise a monomer comprising a reactive halogen.

[0090] The polymer may be of the HT-ACM family, which is configured for amide crosslinking technology using curatives as described herein.

[0091] Suitable ACM polymers are known in the art, and may be manufactured according to known methods (for example, as described in EP1378539, which is incorporated by reference in its entirety) or purchased from commercial suppliers, for example Hy-Temp AR12? and Hy-Temp AR12B? from Zeon Chemicals?.

[0092] In the quantities described herein, all values are given in PHR with respect to 100 parts to this ACM polymer.

[0093] It will be appreciated that the rubber is compounded with additional ingredients, including a filler as described above. The following ingredients may be included in the compounding. It will be appreciated that ingredient combinations may be selected to complement each other and/or to behave synergistically.

[0094] The rubber of the speaker surround is compounded with an antioxidant. Any suitable antioxidant may be used, and such antioxidants are known in the art. Suitably, the antioxidant is present in an amount from 0.5 to 5 PHR, for example, from 1 to 5 PHR. A representative value is around 3.5 PHR.

[0095] The antioxidant may be a diphenyl amine, for example 4,4-bis (alpha, alpha-dimethylbenzyl) diphenylamine. This is available commercially as Naugard? 445 from Chemtura?.

[0096] More than one antioxidant may be present. For example, an imidazole may be used. Imidazoles have well-known corrosion inhibitor properties. The imidazole may be a benzimidazole, for example an alkyl mercaptobenzimidazole. A suitable further antioxidant is methylmercaptobenzimidazole, available commercially as Rhenogran? MMBI-70 from RheinChemie Additives?. For example, a diphenylamine antioxidant and a mercaptobenzimidazole antioxidant may be used in a ratio of approximately 4:3.

[0097] The inventor has found that methylmercaptobenzimidazole is a particularly suitable anti-oxidant and it retains its properties and does not interfere in the ACM curing and vulcanising processes. Without wishing to be bound by any particular theory, the inventor attributes this to the absence of metal cations, and in particular, zinc (ZMBIzinc mercaptobenzimidazole is commonly used in the art).

[0098] The rubber of the speaker surround is compounded with stearic acid, as is known in the art. Stearic acid may help to dissolve the curatives. The stearic acid may be present in an amount from 0.5 to 3 PHR, for example, around 1 PHR.

[0099] Processing aids are normally included to improve the handling of the rubber during compounding and molding. Suitable processing aids are known in the art. The total amount of processing aids may be up to about 10 PHR, for example up to about 6 PHR. For example, the total amount of processing aids may be 0.5 to 6 PHR.

[0100] More than one processing aid may be used. For example, a processing aid may be added to improve mold release and a processing aid added to improve the mixing and compounding of the rubber product. By way of example, and not by way of limitation, long chain (for example C.sub.15-25) primary alkyl amines may be used such as octadecyl amine. This is available commercially as Ofalub? STA available from ChemSpec Ltd? and Armeen? 18D from AkzoNobel?. By way of example, and not by way of limitation phosphoric acid esters of modified fatty alcohols may be used such as commercially available Ofalub? SEO available from ChemSpec Ltd?.

[0101] Plasticizers can be used to improve processing of the compounded rubber. These plasticizers also transfer beneficial properties to the cold flexibility of the compounded rubber. By way of example, and not by way of limitation, a, plasticizer like TOTM (Trioctyl Trimellitate) may be used to improve the molding process.

[0102] Importantly, as described herein, a sulfur vulcanisation is not used. This is advantageous as it avoids the use of hazardous o-toluidene reagents. Rather, suitable curing can be achieved using appropriate curatives. Suitably, the rubber of the speaker surround is compounded with a carbamate. This may be present in an amount from 0.1 to 6 PHR. More than one carbamate may be present. Suitably, the carbamate is a carbamate of an ?,?-diaminealkane, for example hexamethylene diamine carbamate. Hexamethylene diamine carbamate is commercially available as A representative amount range for this ?,?-diaminealkane carbamate is 0.1 to 2 PHR. Without wishing to be bound to any particular theory, it is thought that the carbamate generates an ?,?-diamide cross-link between two polymer backbones of the ACM polymer (for example, through ester to amide nucleophilic amide substitution). Further curing its thought to cause these diamide cross-linkers to react with adjacent ester moieties on the polymeric backbones, leading to dehydration and imide formation.

[0103] Commercially available combinations of activated amines may be used in the curing process. Again without wishing to be bound to any particular theory, it is thought that these activated amines assist with amide/imide bond formation by generating leaving groups. This composition comprising activated amines may be present in an amount from 1 to 4 PHR, for example, a representative amount is around 2 PHR. A commercially available example is Rhenogran? XLA-60 (GE2014), available from Lanxess?.

[0104] As described above, the curing process suitably uses amide crosslinking technology. Suitably, the curing process involves the formation of carbon-nitrogen bonds. Suitably, after curing the rubber comprises cross-linked portions comprising amide and/or imide bonds. Preferably, imide bonds are present.

[0105] It will be appreciated that the present invention further relates to a rubber as described herein.

[0106] It will be appreciated that relative amounts of many of these ingredients may be varied. A representative compounding formulation is shown below:

TABLE-US-00001 Chemical Min Max ACM (polyacrylate rubber) polymer 100.00 100.00 Carbon black 0.00* 120.00 Silica 0.00* 60.00 Clay 0.00* 50.00 A diphenylamine such as 4,4-Bis 0.50 4.00 (?,?-dimethylbenzyl) diphenylamine (Antioxidant) Stearic acid 0.50 3.00 Octadecyl amine (process aid) 0.25 3.00 Phosphoric acid ester of modified fatty 0.25 3.00 alcohol (process aid) Combination of activated amines 1.00 4.00 Hexamethylene Diamine Carbamate 0.10 2.00 Methylmercaptobenzimidazole (antioxidant) 3.00 *Typically one or more of these filler will be present, that is there will be at least 20 PHR of carbon black, silica and/or clay.

[0107] It will be appreciated that the rubber may be compounded with additional ingredients such as plasticizers and dyes (if silica is used as filler for example).

[0108] For example, TOTM (Min 0.50; Max 5.00) may preferably be added to the above composition.

EXAMPLE 1

[0109] Example Rubber Composition

[0110] The following is a representative rubber composition according to the present invention. It is referred to as Example 1.

TABLE-US-00002 Trade name of Chemical example Amount ACM (polyacrylate rubber) polymer HyTemp AR12B 100.00 Carbon black 65.00 Antioxidant (diphenylamine) Naugard 445* 2.00 Stearic acid 1.00 Octadecyl amine Ofalub STA 1.00 Armeen 18D Phosphoric acid ester of modified Ofalub SEO 1.00 fatty alcohol Combination of activated amines Rhenogran 2.00 XLA-60 Hexamethylene Diamine Carbamate Diak-1 0.60 Antioxidant methylmercaptobenzimidazole Rhenogran 1.43 MMBI-70 *(4,4-bis (alpha, alpha-dimethylbenzyl) diphenylamine)

[0111] As elsewhere, all values mentioned are parts per hundred of rubber (PHR) with respect to a ratio of 100 parts of polymer (ACM).

[0112] The rubber was compounded using conventional rubber mixing equipment using techniques well established in the art. Where appropriate, processing to provide the rubber edge (surround) was achieved by injection molding or via thermoforming (compression moulding). These techniques are known in the art.

[0113] Comparison EPDM Rubber Composition

[0114] A comparison rubber speaker surround was prepared using the following EPDM-based formulation:

TABLE-US-00003 Chemical Trade name/Abbreviation Amount EPDM polymer JSR/EP33 100 carbon black N550 15 carbon black N774 10 calcium carbonate CACO3 20 clay KA0LINE 30 silica 1106 15 plasticizer ATBC 10 stearic acid ST 1.5 curative TBZTD 0.5 curative EZ 0.6 zinc oxide ZNO 5 sulfur S 1.5 antioxidant RD 1.5

[0115] Tensile Strength

[0116] The rubbers of the invention show excellent retention of tensile strength over a wide temperature range. Indeed, as can be seen from FIG. 2, the tensile strength hardly changes over a 125? C. window. This provides excellent mechanical stability and integrity for the applications of interest. By contrast, a compassion EPDM-based rubber marketed for high temperature use shows marked variation in tensile strength over the temperature range.

[0117] The tensile strength of the rubbers of the invention are also stable after prolonged exposure to high temperature. FIG. 3 shows the changes in E-modulus, tensile strength and elongation after heat exposure at various temperatures for various durations. Importantly, the tensile strength is virtually unchanged, even after 96 h at 170? C.

[0118] Thermal Analysis

[0119] FIG. 4 shows the DMTA of the rubber of example 1 in a temperature sweep from ?100? C. to +200? C. with 1 Hz frequency: static strain was set at 0.13% and dynamic amplitude was 0.04%. The glass transition area is between ?35? C. and +15? C.; with a T.sub.g (glass transition) of around ?10? C. This is measured in shear and is not representative for actual T.sub.g. Actual T.sub.g can be determined by DSC and is typically some 15? C. lower than on DMTA.

[0120] FIG. 5 shows the TGA of the rubber of example 1. The temperature was increased from 40? C. to 600? C. at 20? C./min under an N.sub.2 inert atmosphere. The temperature was cooled to 450? C. at 20? C./min; then the gas supply switched to an O.sub.2 atmosphere, and the temperature increased at 20? C./min up to 850? C.

[0121] As is clear from the curve, there is no ash content (no inorganic fillers were used). The first weight loss appeared only around 300? C. This is very high and shows stable performance for this temperature range.

[0122] Structural Integrity of Speaker Surrounds

[0123] The rubber of example 1 was tested as a molded speaker surround and compared to a conventional EPDM based surround in a high power capacity handling test. A sinusoidal wave of 45 Hz was put on the speaker with a power of 7.5V (free air). These tests were performed at different temperatures. The comparison speakers fail at 160? C.: the rubber edge is completely scattered. Speakers of the invention have passed this test even at 180? C. (higher temperatures are now being tested and initial results are promising).

[0124] FIG. 6 shows the speakers before and after the test performed at 160? C.

[0125] Advantageous Properties

[0126] The rubber of example 1 has been shown to: [0127] i. Maintain dynamic behaviour over the entire temperature range of interest (?40? C. to +200? C.). Early results suggest that this upper limit is much higher. [0128] ii. Provide adhesion to the cone material. [0129] iii. Satisfy requirements for use in a vehicle exhaust (ability to withstand exhaust fumes, gas impermeability etc) [0130] iv. Be compatible with suitable high temperature resistant adhesives

[0131] Advantageously, the rubbers of the invention are compounded entirely sulfur free, meaning that o-toulidines are not used. As explained above, o-toulidines have recently been placed on the EU REACH candidate list of substances for very high concern for authorisation. The invention provides suitable rubbers for high temperature uses while avoiding the use of o-toulidines such as DOTG.

[0132] Integral Surround and Diaphragm Coating

[0133] As described herein, the inventor has found that it may be advantageous to use rubber as described herein to form both the speaker surround and to provide a coating to substantially all of at least one face of the diaphragm. This serves to improve the durability and longevity of the speaker as the connection of the surround and diaphragm is integral, and reduces both unit cost and weight (as fewer materials and process steps are used). The rubber may coat one or both faces of the diaphragm, and suitably partially or completely strikes through gaps between the fibres of the cone material. The inventor has found that the resultant speakers, once assembled, show desirable gas tightness without the need for a separate gas tightness layer or other gas tightness treatment step. In other words, suitably the speaker diaphragm is not treated with phenolic resin, acrylic polyol and (iso)cyanate hardening agent or similar.

[0134] A representative mold is shown in FIG. 8. The mold has an upper portion 200 and a lower portion 201. The upper and lower portions define a cavity 202. The diagram shows a cross section, and the cavity, for the purpose of this explanation, should be considered circular. Of course, as described herein, other speaker shapes are also envisaged. The diaphragm is placed in cavity 202 and is indicated by a dotted line. The cavity further comprises an annular 203 region into which the surround is cast. As shown, the diaphragm does not extend into the surround region, which may have a curve, as shown.

[0135] The diaphragm and mold cavity are centred on a centering portion 204 which ensures that the relevant pieces are in alignment when the rubber is molded. The upper and lower portions as shown are held together during the molding process by compression, although other means including bolts and clamps will be apparent to the skilled person.

[0136] As shown, the rubber is injected under pressure via conduit 205. Only one is shown, although typically there will be more than one spaced around the mold. The rubber may be introduced by injection molding processes, but other rubber molding processes may be used, for example thermoforming/compression molding in which thin strips of rubber are placed in the mold and cast through application of heat and/or pressure.

[0137] The neck portion of the cone is preferably protected by a seal, such that a small section of the cone at the neck (which is covered by the dust cap in the assembled speaker) is not overmolded. Keeping this section of the cone free of rubber coating improves adhesion of the cone neck to coil. The inventor has further observed that shielding the neck portion helps to prevent rubber pooling and collecting at the neck area.

[0138] The seals may be in the form of O-rings 206, and may be provided above and/or below the cone material. The inventor has observed that the use of square-cut O-rings may provide a more efficient seal against the diaphragm material. Suitable sealing materials may include, but are not limited to, Viton?, silicone, Teflon? NBR and steel.

[0139] After forming the integral surround and coating, preferably, the rubber is at least partially cured in the mold. This may prevent damage to the assembly when it is removed.

[0140] All optional features and preferences described herein are combinable to the extent that such a combination is not clearly excluded.