VALVE CUPS AND CONTAINERS FOR USE IN FLUID MEDIUM DISPENSING SYSTEMS
20180222647 ยท 2018-08-09
Inventors
Cpc classification
B29K2067/006
PERFORMING OPERATIONS; TRANSPORTING
B29C65/02
PERFORMING OPERATIONS; TRANSPORTING
B29C65/7805
PERFORMING OPERATIONS; TRANSPORTING
B29K2067/003
PERFORMING OPERATIONS; TRANSPORTING
B29C65/06
PERFORMING OPERATIONS; TRANSPORTING
B29C66/131
PERFORMING OPERATIONS; TRANSPORTING
B29C66/73774
PERFORMING OPERATIONS; TRANSPORTING
B65D83/62
PERFORMING OPERATIONS; TRANSPORTING
B65D83/425
PERFORMING OPERATIONS; TRANSPORTING
B29K2067/006
PERFORMING OPERATIONS; TRANSPORTING
B29C66/7392
PERFORMING OPERATIONS; TRANSPORTING
B29K2067/003
PERFORMING OPERATIONS; TRANSPORTING
B29C66/12421
PERFORMING OPERATIONS; TRANSPORTING
B29C66/71
PERFORMING OPERATIONS; TRANSPORTING
B29C66/71
PERFORMING OPERATIONS; TRANSPORTING
B29C66/7422
PERFORMING OPERATIONS; TRANSPORTING
B29C66/73921
PERFORMING OPERATIONS; TRANSPORTING
B29C66/542
PERFORMING OPERATIONS; TRANSPORTING
International classification
B65D83/62
PERFORMING OPERATIONS; TRANSPORTING
Abstract
The present invention provides a valve cup (10) for use with a container (30) for dispensing a fluid medium stored under pressure. The valve cup (10) supports a valve (50) and seals an opening (32) of the container (30) and is formed from a semi-crystalline polyester. The present invention also provides a container (30), wherein at least a part of the container (30) surrounding an opening (32) is formed from a semi-crystal-line polyester. A further valve cup (10) is formed from a metal or rigid material and further includes a polyester lining (70). Dispensing systems (1) including the above containers (30) and valve cups (10) are provided, wherein welding is facilitated between the container (30) and valve cups (10).
Claims
1. A valve cup for use with a container for dispensing a fluid medium stored under pressure, the valve cup adapted to support a valve and to seal an opening of the container, wherein: the valve cup is formed from a first plastic material that is a semi-crystalline polyester.
2. The valve cup of claim 1, wherein the first plastic material has a degree of crystallinity greater than 35%, preferably greater than 38%, when measured using differential scanning calorimetry.
3. The valve cup of claim 1, wherein the first plastic material is selected from the group consisting of: crystallised PET, PBT, PEN, PEN/PET copolymers, or a blend of any of the foregoing.
4. The valve cup of claim 1, wherein the valve cup comprises a central opening that is adapted to receive and support the valve and wherein the valve cup comprises one or more enforcing members radially protruding from the central opening, the one or more enforcing members adapted to increase the rigidity of the valve cup.
5. The valve cup of claim 1, wherein the valve cup comprises an inverted U-shaped receiving portion configured to receive a lip portion of the container.
6. The valve cup of claim 1, in particular claim 5, wherein the inverted U-shaped receiving portion comprises at least one protrusion on a surface facing the container when receiving the lip portion, the protrusion adapted to frictionally engage the lip portion.
7. A fluid medium dispensing system comprising: a container for storing a fluid medium under pressure, the container comprising an opening; a valve; and the valve cup of claim 1 adapted to support the valve and seal the opening of the container, wherein the container is formed from a second plastic material, and the first plastic material is weldable to the second plastic material.
8. The system of claim 7, wherein the second plastic material is a polyester, preferably PET.
9. The system of claim 7, wherein the valve cup is weldable to the container by one of: friction welding, ultrasonic welding, and laser welding.
10. The system of claim 7, wherein the valve cup is welded to container, thereby providing a seal between the valve cup and the opening of the container.
11. A container for dispensing a fluid medium stored under pressure and comprising an opening, the container for use with a valve cup supporting a valve sealing the opening of the container, wherein at least a part of the container adjacent the opening is formed from a first plastic material that is a semi-crystalline polyester.
12. The container of claim 11, wherein the first plastic material has a degree of crystallinity greater than 35%, preferably greater than 38%, when measured using differential scanning calorimetry.
13. The container of claim 11, wherein the first plastic material is selected from the group consisting of: crystallised PET, PBT, PEN, PEN/PET copolymers, or a blend of any of the foregoing.
14. The container of claim 11, wherein the container comprises a neck, the neck connecting the opening to a main body of the container, and wherein the entire neck of the container is formed of the first plastic material.
15. The container of claim 11, wherein the entire container is formed of the first plastic material.
16. The container of claim 11, wherein the opening of the container comprises a lip portion, the lip portion adapted to engage with an inverted U-shaped receiving portion of the valve cup.
17. A fluid medium dispensing system comprising: the container of claim 11; a valve; and a valve cup adapted to support the valve and seal the opening of the container, wherein the valve cup is formed from a second plastic material, and the first plastic material is weldable to the second plastic material.
18. The system of claim 17, wherein the second plastic material is a polyester, preferably PET.
19. The system of claim 17, wherein the valve cup is weldable to the container by one of: friction welding, ultrasonic welding, and laser welding.
20. The system of claim 17, wherein the valve cup is welded to the container, thereby providing a seal between the valve cup and the opening of the container.
21. A valve cup for use with a container for dispensing a fluid medium stored under pressure, the valve cup adapted to support a valve and to seal an opening of the container, wherein: the valve cup is formed from a metal or rigid material, and the valve cup is provided with a polyester lining at at least a part of the valve cup adapted to contact the container.
22. The valve cup according to claim 21, wherein the valve cup is formed from aluminium and the polyester lining is formed from PET.
23. The valve cup according to claim 21, wherein the polyester lining is coated or fixed by adhesive to the valve cup.
24. The valve cup according to claim 21, wherein the polyester lining is provided on an underside of the valve cup.
25. A fluid medium dispensing system comprising: a container for storing a fluid medium under pressure, the container comprising an opening; a valve; and the valve cup of claim 21 adapted to support the valve and seal the opening of the container, wherein the container is formed from a second plastic material, and the polyester lining is weldable to the second plastic material.
26. The system of claim 24, wherein the second plastic material is a polyester, preferably PET.
27. The system of claim 24, wherein the valve cup is weldable to the container by one of: friction welding, ultrasonic welding, and laser welding.
28. The system of claim 24, wherein the valve cup is welded to container, thereby providing a seal between the valve cup and the opening of the container.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0074]
[0075]
[0076]
[0077]
[0078]
[0079]
DETAILED DESCRIPTION
First Embodiment
[0080]
[0081] The valve 50 is shown in detail in
[0082] The dispensing tip 54 may have any cross-sectional shape but is preferably cylindrical. The dispensing tip 54 may also include an upper channel 55 that defines a hollow inner portion of the dispensing tip 54. A through hole 56 may be provided at a lower portion of the dispensing tip 54. In
[0083] The plunger 53 may be provided so as to slide in the direction of the common central axis. The plunger 53 may be biased to a closed position by a spring (not shown) disposed in the hollow portion of the main body 52 and communicating with receiving parts, such as perpendicular flanges, of the plunger 53.
[0084] Optionally, a bag 100 (see
[0085] The valve 50 is supported by the valve cup 10. In the example of
[0086]
[0087] The diameter d1 is preferably larger that the diameter of the main body 52 of the valve 50. In one example configuration, the diameter d1 may be 14 mm, but the diameter d1 is not limited to this value. It should also be appreciated that the inclined portions 13 do not have to be inclined, but should at least project towards the central opening 11. The inclined portion 13 may also have a number of first inner projections 12 disposed at the sides facing central opening 11. While
[0088] The valve main body 52 may be supported by second inner projections 14 that, in
[0089] The seal member 60 is preferably sized so as to surround the outer diameter of the dispensing tip 54 and cover the through hole 56 in the closed position, as seen in
[0090] When assembling the valve 50 and valve cup 10, the seal member 60 may be inserted into the lower region of the valve cup 10 defined by the second inner projections 14, or the seal member 60 may be positioned on top of the valve main body 52. In any case, when the valve 50 is threaded into the valve cup 10 such that the dispensing tip 54 passes through the central opening 11, the second inner projections 14 may hold the valve main body 52 in place. In some embodiments, the second inner projections 14 may include raised portions 15 that snap fit into corresponding receiving portions provided in the valve main body 52.
[0091] The structure of the valve cup 10 is not particularly limited.
[0092] The inverted U-shaped receiving portions 16 may define a space wherein the inner surfaces of the inverted U-shaped receiving portions 16 may contact the lip portion 38 of the container 30 when the valve cup 10 is attached to the container 30. The innermost surface of the inner surfaces may define a diameter d3 of the valve cup 10 which may be equal to or less than the inner diameter of the opening 32. In one example configuration, the diameter d3 may be 24.8 mm, but the diameter d3 is not limited to this value. In some configurations, the outermost surface of the inner surfaces may be provided with a projection 17 extending towards the innermost surface. As seen in
[0093] The inverted U-shaped receiving portions 16 may have a height h1 than is greater than the height of the lip portion 38 such that the lip portion 38 is completely contained within the inverted U-shaped receiving portions 16. This configuration is seen in
[0094] The section may also be provided with a number of enforcing members or portions 18 that extend from the inverted U-shaped receiving portions 16 to the outer side of the inverted portions 13. This may aid in increasing the structural rigidity of the valve cup 10 while also reducing production costs and material consumption.
[0095] As mentioned above, the valve cup 10 is configured to be attached to the container 30. In
[0096] In accordance with the first embodiment of the present invention, the valve cup 10 is formed from a plastic material that is a semi-crystalline polyester. In this manner, the structural rigidity of the valve cup 10 can be ensured beyond the recommended 50? C. owing to the higher degree of crystallinity. In some cases, the degree of crystallinity may be greater than 35%, and preferably greater than 38% when measured using differential scanning calorimetry (DSC). DSC is a well-established method for measuring thermal properties of materials and is not explained further herein.
[0097] One material that can be used for the valve cup 10 of the present invention is crystallised PET (CPET). PET can either be amorphous or semi-crystalline, depending on how it is processed. Typically, PET can be injection moulded using a suitable mould (e.g., a valve cup). When a standard cycle time is used, the resulting PET product is completely amorphous. A semi-crystalline plastic is one that displays crystalline structures but also amorphous regions. When heated, the amorphous regions can transition from a hard and brittle state to a rubbery, soft, and elastic state; the temperature at which this occurs is known as the glass transition temperature. In a semi-crystalline plastic, the rigidity of the plastic is proportional to the degree of crystallinity, which essentially defines the percentage of the plastic that exhibits crystalline structures. Because the crystalline structures do not undergo the transition from hard to rubbery states, the crystalline structures keep their shape and thus can maintain the rigidity of the semi-crystalline plastic even when the amorphous regions do make the transition at the glass transition temperature.
[0098] The approximate degree of crystallinity of PET ranges from 30% to 40%, although other percentages may be possible. CPET may be formed by heating virgin PET and allowing the heated PET to cool slowly, more slowly than prescribed by a standard cycle used in injection moulding, thus forming crystalline structures. Thus, CPET has a high degree of crystallinity. In contrast, amorphous PET (APET) is cooled much more quickly preventing the crystalline structures from forming.
[0099] CPET may also have nucleating agents added thereto in order to enhance the formation of crystalline structures in the material. Alternatively, other additives may be introduced to PET in order to increase the stiffness and/or durability, e.g., glass particles or fibres.
[0100] Typically, PET films and bottles have a limited degree of crystallinity and usually have small crystallites leading to a clear and transparent material. This is perhaps the most common form of PET. CPET requires more careful control when forming and thus can be much more costly to produce.
[0101] CPET is much less subject to deformation under stress, especially at larger temperatures, than amorphous PET (APET). This is primarily because of the rigidity of the crystalline structures therein. Because semi-crystalline polyesters include both crystalline and amorphous regions, they can be characterised by a glass transition temperature. For PET, the glass transition temperature is between 67? C. for amorphous PET to 81? C. for semi-crystalline PET. Therefore, in the case of PET, a higher glass transition temperature correlates with a larger degree of crystallinity, and thus PET having a higher glass transition temperature is desired for use as the valve cup 10, preferably over 74? C.
[0102] In a preferential embodiment, polybutylene terephthalate (PBT) is used as the plastic material of the valve cup 10. PBT is always semi-crystalline in normal commercial settings. Typically, the degree of crystallinity is always greater than 30%, and is usually in the range of 40% to 50%. Although the glass transition temperature is approximately 66? C. for PBT, PBT is generally more rigid that amorphous PET owing to the higher degree of crystallinity. This makes PBT an excellent choice of material for use as the valve cup 10.
[0103] Yet another material that is suitable is polyethylene napthalate (PEN). PEN is very stable, particularly at higher temperatures. PEN can also form a semi-crystalline structure and has a glass transition temperature of approximately 125? C. Compared to PET, PEN has higher oxygen and water vapour barrier, tensile strength and flexural modulus. In addition, moulding and blowing cycles for PEN are much shorter than for PET leading to increased productivity. However, the cost of PEN is, at present, much higher than PET.
[0104] It should also be appreciated than many other polyesters may be used provided that they display appropriate semi-crystalline properties. Blends of polyesters may also be used. In one example, a PEN/PET copolymer may be used, wherein the percentage of PEN is relatively low in comparison to the percentage of PET, e.g., between 10-20% PEN for reasons of cost. Other copolymers may be used such as PET/PBT copolymers, or even PET/PBT/PEN copolymers. However, any of PET, PBT, or PEN may also be blended with other polyesters and/or other additives, such as nucleating agents, to form semi-crystalline structures.
[0105] Moreover, when the valve cup 10 is formed from a semi-crystalline polyester, the valve cup 10 can be welded to the container 30 when the container is formed of a second plastic material. The welding can be performed using any suitable technique to weld two plastics together, but is preferably one of friction welding, ultrasonic welding, or laser welding. In the first embodiment, the container 30 may be formed of PET with any appropriate degree of crystallinity and subsequently welded to the valve cup 10. This ensures that the valve cup 10 (e.g., the inverted U-shaped receiving portion 16) does not separate from the container 30 (e.g., the lip portion 38) even when deformation of the container 30 at high temperatures occurs.
[0106] In accordance with the first embodiment of the invention, using a semi-crystalline polyester as the material for the valve cup 10 ensures that the valve 50 is suitable held by the valve cup 10 at temperatures over 50? C. because deformation or distortion of the valve cup 10 does not occur. In addition, using a semi-crystalline polyester as the material for the valve cup 10 means that a plastic container 30 can be welded to the valve cup 10 thus ensuring that the seal between the container 30 and valve cup 10 is maintained even if deformation of the container 30 occurs. Thus, the advantageous properties of PET when used as the container 30 can be retained without compromising sealing performance at higher temperatures.
[0107] It should be appreciated, however, that the material of the container 30 is not limited to PET but may be any suitable polyester and may also be formed of any of the semi-crystalline polyesters above.
[0108] As discussed above, the rigidity of the valve cup 10 can also be improved by using the enforcing members 18. The enforcing members 18 may be formed of the same semi-crystalline polyester or may be formed of a different material, e.g., metal.
[0109] It should be appreciated that various modifications to the specific structure of the valve cup 10, container 30, and valve 50 may be made while still conforming to the principles of the first embodiment of the invention.
Second Embodiment
[0110] The second embodiment of the invention may be the same as the first embodiment, but vary only in the materials used for the container 30 and valve cup 10. That is, any structural features described in the first embodiment may equally be present in the second embodiment.
[0111] In the second embodiment, a part of the container 30 may be formed from any of the semi-crystalline polyesters used for the valve cup 10 of the first embodiment. Specifically, a part adjacent or in contact with the opening 32 of the container 30 is preferably formed from the semi-crystalline polyester. In contrast, the valve cup 10 may be formed from any polyester, such as PET.
[0112] In the second embodiment, the opening 32 of the container 30 maintains its rigidity at temperatures exceeding 50? C. by virtue of being formed from the semi-crystalline polyester. The valve cup 10 may maintain the seal with respect to the valve 50 due to the compressive forces acting radially inward from the opening 32 of the container 30 if the valve cup 10 begins to deform at higher temperatures.
[0113] Alternatively, the valve cup 10 may be structured in such a manner as to channel any deformation to areas away from the valve 50, i.e., away from inclined portion 13. For example, with reference to
[0114] In the second embodiment, the container 30 is preferably formed from the semi-crystalline polyester only at a portion adjacent or in contact with the opening 32. This may include only the lip portion 38. Alternatively, the entire neck portion 36 and lip portion 38 may be made from the semi-crystalline polyester. In other configurations, the entire container 30 may be formed from the semi-crystalline polyester, although this may increase the costs and/or difficulty of the manufacturing processes associated with forming the container 30.
[0115] As with the first embodiment, in accordance with the second embodiment of the invention, using a semi-crystalline polyester as the material for at least a part of the container 30 ensures that the valve cup 10 is suitably held by the container 30 at temperatures over 50? C. because deformation or distortion of the opening 32 of container 30 does not occur. This can limit or appropriately deflect any deformation of the valve cup 10 meaning that the valve 50 is stably held. In addition, using a semi-crystalline polyester as the material for a part proximate to the opening 32 of the container 30 means that a polyester valve cup 10 can be welded to the container 30 thus ensuring that the seal between the container 30 and valve cup 10 is maintained even if deformation of the valve cup 10 occurs.
[0116] The advantageous properties of using PET when used as the valve cup 10 and potentially as part of the container 30 can be retained without compromising sealing performance at higher temperatures.
[0117] It should be appreciated, however, that the material of the valve cup 10 is not limited to PET but may be any suitable polyester and may also be formed of any of the semi-crystalline polyesters above.
Third Embodiment
[0118] In the third embodiment, the primary material of the valve cup 10 may be a metal or other rigid material. Preferably, the primary material is aluminium. The structure of the valve cup 10 may be the same as in the first embodiment.
[0119]
[0120] The polyester lining 70 may be formed from any polyester, but is preferably formed from PET. When the valve cup 10 is formed of a metal, i.e., aluminium, or other rigid material, the structural rigidity of the valve cup 10 at temperatures greater than 50? C. is ensured by the structural rigidity of the metal or rigid material. In other words, the metal or rigid material does not deform at temperatures greater than 50? C. This means that the valve cup 10 may reliably hold and seal the valve 50.
[0121] Providing the polyester lining 70 on a part of the valve cup 10 means that the polyester lining 70 can be welded using any of the aforementioned techniques to a polyester based container 30, e.g., the container 30 of the first embodiment. In this way, the valve cup 10 can be reliably attached to the container 30 such that any deformation of the container 30 at temperatures greater than 50? C. does not cause the valve cup 10 and container 30 to separate, and thus the seal therebetween is maintained.
[0122] The advantageous effects described in both the first and second embodiments can therefore be realised by the third embodiment; namely, that the seal between the valve 50 and valve cup 10 and the seal between the valve cup 10 and container 30 can be maintained at temperatures greater than 50? C.
[0123] As seen in
[0124] The polyester lining 70 does not have to be formed from the semi-crystalline polyesters as discussed in the first and second embodiments. However, in some cases, to prevent deformation of the polyester lining 70 that may lead to detachment from the valve cup 10, the polyester lining 70 may be formed from the semi-crystalline polyesters.
[0125] Method for Assembling Dispensing System
[0126] A method of assembling the dispensing system using valve cups 10 according to any of the first through third embodiments is now described.
[0127]
[0128] A first step, as shown in
[0129] Once the bag 100 is securely attached to the valve 50, the bag 100 may be folded to reduce the footprint thereof. As shown in
[0130] The folding may be performed in any manner so as to reduce the footprint of the BOV and allow insertion into the container 30. In one example, the flat bag 100 is rolled around the axis of the valve 50 and valve cup 10 such that the bag 100 is in a spiralled configuration centred on the axis of the valve 50. In another example, the bag 100 may be folded in a concertina. In both cases, the BOV is preferably provided with a suitable footprint.
[0131] In contrast to known methods, the BOV may not be provided with a containing sleeve or tape to retain the BOV in the folded configuration. Rather, the folded BOV is preferably inserted directly into the container 30, as is shown in
[0132] Once partially inserted, the inner region of the container 30 may be filled with gas, preferably a propellant gas. Suitable propellant gasses are known in the art and are not discussed further herein. The method used is preferably undercup gassing, which essentially means that the gas is passed under the valve cup 10 and into the region between the bag 100 and the inner volume of the container 30. In the present invention, the inner volume of the container 30 may be pressurised to a pressure between 1 to 3 bar, preferably 1.5 to 2.5 bar.
[0133] As seen in
[0134] In a preferred configuration, the valve cup 10 is provided with the inverter U-shaped receiving portion 16 and the container 30 is provided with the lip portion 38. Thus, the BOV may be inserted into the container 30 until the lip portion 38 of the container 30 abuts the inverted U-shaped receiving portion 16.
[0135] In a more preferably configuration, the inverted U-shaped receiving portion 16 comprises the projections 17, 77 which are adapted to engage in a snap-fit manner with the underside of the lip portion 38. In this way, when the valve cup 10 is pressed onto the lip portion of the container 30, the U-shaped receiving portion 16 may deform slightly to allow the projections 17, 77 to pass over the lip portion 38 and subsequently return to their resting state once the projections 17, 77 have passed over the lip portion 38. Securing the valve cup 10 in this way aids in ensuring that the welding process is performed with improved accuracy as the valve cup 10 can be reliably aligned with the container 30.
[0136] As seen in
[0137] Once the welding is completed, the dispensing system 1 is assembled. Further assembly steps may be possible, such as adding a protection overcap 120 to cover the exposed part of the valve 50 as seen in
[0138] It should be noted that some or all of the steps of the method may be performed in a sealed environment. This may aid in assembling the dispensing system 1 when the pressure is increased.
[0139] According to this method, the dispensing systems are assembled by welding the valve cup 10 to the container 30 after experiencing undercup gassing. Conventional methods rely on clinching the valve cup to the container, whereas the present assembly method utilises the welding of a specially modified valve cup 10 to a container 30. The welding may also be performed at lower pressures and without the presence of the fluid medium to the dispensed. This can ensure a more reliable weld and potentially prevent any contamination of the fluid medium to be dispensed.
[0140] The present invention therefore provides a valve cup 10 or container 30 that is modified to be rigid at temperatures exceeding 50? C., while also allowing for welding between the valve cup 10 and container 30. Primarily, this can be achieved by using either a semi-crystalline polyester with a high degree of crystallinity, or by making use of a polyester layer on a metal or rigid material valve cup. A method of assembling a dispensing system including these components is also provided.