SOLAR CELL FRONT SIDE SILVER PASTE DOPED WITH MODIFIED GRAPHEME AND PREPARATION METHOD THEREOF

Abstract

A solar cell front side silver paste doped with modified graphene and its preparation method are disclosed. The solar cell front side silver paste doped with modified graphene comprises by weight 0.1-5 parts of modified graphene, 88-91 parts of silver powder, 5-15 parts of organic binder, 1-5 parts of organic solvent, 1-3 parts of glass powder, wherein the modified graphene is a surface modified graphene. A solar cell front side silver paste is developed, which is screen printed on a crystalline silicon wafer, sintered at a high temperature, penetrates the SiNx passivation layer in the crystalline silicon wafer, and thus forms a good ohmic contact.

Claims

1. A solar cell front side silver paste doped with modified graphene, comprising 0.1-5 parts by weight of modified graphene, 88-91 parts by weight of silver powder, 5-15 parts by weight of organic binder, 1-5 parts by weight of organic solvent, 1-3 parts by weight of glass powder, wherein the modified graphene is a surface modified graphene.

2. A solar cell front side silver paste doped with modified graphene according to claim 1, wherein the surface modified graphene comprises graphene and surface modifier, wherein the surface modified graphene comprises 85-99 parts by weight of graphene and 1-15 parts by weight of surface modifier.

3. A solar cell front side silver paste doped with modified graphene according to claim 2, the surface modifier is one or more members of the group consisting of titanate coupling agent, aluminate coupling agent, silane coupling agent and zircoaluminate coupling agent.

4. A solar cell front side silver paste doped with modified graphene according to claim 1, wherein the silver powder is composed of 85-99 parts of micron-sized spherical silver powder and 1-15 parts of nano-sized silver powder, wherein the average particle size of the micron-sized spherical silver powder is 1.0-2.0 m, and the average particle size of the nano-sized silver powder is 20-100 nm.

5. A solar cell front side silver paste doped with modified graphene according to claim 1, wherein the organic binder is composed of 10-20 parts by weight of polymer and 80-90 parts by weight of organic solvent, wherein the polymer is one or more members of the group consisting of ethyl cellulose, acrylic resin and polyethylene resin, and the organic solvent is two or more members of the group consisting of butyl carbitol, terpineol, tributyl citrate and propylene glycol butyl ether.

6. A solar cell front side silver paste doped with modified graphene according to claim 1, wherein the glass powder comprises 1-10 parts by weight of B.sub.2O.sub.3, 0-5 parts by weight of Cr.sub.2O.sub.3, 20-60 parts by weight of PbO, 0-5 parts by weight of SiO.sub.2, 50-80 parts by weight of TeO.sub.2 and 0-20 parts by weight of Bi.sub.2O.sub.3; the glass powder is processed to a particle size D50 of 0.5-2 m; the melting point of glass powder is controlled within 250-450 C.

7. The preparation method of a solar cell front side silver paste doped with modified graphene according to claim 1, comprising: (1) preparing of modified graphene; having 85-99 parts by weight of graphene and 1-15 parts by weight of surface modifier and mixing, and ultrasonically dispersing the mixture with an ultrasonic dispersion machine for 20-60 min, filtering and drying to provide the modified graphene; (2) preparing of an organic binder having 10-20 parts by weight of polymer and 80-90 parts by weight of organic solvent and mixing, and dispersing the mixture with a dispersion machine for 50-70 min to dissolve the polymer, and such that a transparent and homogeneous organic binder is obtained; (3) preparing of a glass powder having 1-10 parts by weight of B.sub.2O.sub.3, 0-5 parts by weight of Cr.sub.2O.sub.3, 20-60 parts by weight of PbO, 0-5 parts by weight of SiO.sub.2, 50-80 parts by weight of TeO.sub.2 and 0-20 parts by weight of Bi.sub.2O.sub.3 and mixing, and heating the mixture in a high temperature muffle furnace at 800-1200 C. for 40-60 min, quenching with deionized water after being melted, ball-milling for 2.5-10 h, sieving with a 300 mesh screen, such that a glass powder with a particle size D50 less than 2 m is obtained; (4) preparing of a solar cell front side silver paste; having 0.1-5 parts by weight of modified graphene, 5-15 parts by weight of organic binder and 1-3 parts by weight of glass powder and mixing, and then dispersing with a dispersion machine at the speed of 500-800 rpm for 10-30 min; adding 88-91 parts by weight of silver powder, and dispersing the mixture with a dispersion machine at the speed of 800-1000 rpm for 30-50 min, grinding the mixture with a three-roller grinding machine 15 times, followed by adding of 1-3 parts by weight of organic solvent, which is composed of two or more members of the group consisting of butyl carbitol, terpineol, tributyl citrate and propylene glycol butyl ether, dispersing the mixture with a high speed dispersion machine for 5-20 min, such that a finished paste is obtained and packed for further use.

8. The application of a solar cell front side silver paste doped with modified graphene according to claim 1, screen printing the solar cell front side silver paste with a 360 mesh screen on a 125 mm125 mm monocrystalline silicon wafer to form an electrode film, and then sintering the printed monocrystalline silicon wafer in a muffle furnace, the sintering peak temperature being 780 C.

Description

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0024] The present invention is described in detail with some embodiments.

[0025] Embodiment 1

[0026] A solar cell front side silver paste doped with modified graphene comprises by weight: 0.1 part of modified graphene, 88 parts of silver powder, 5 parts of organic binder, 2 parts of organic solvent and 1 part of glass powder, wherein the modified graphene is a surface modified graphene.

[0027] The surface modified graphene comprises graphene and surface modifier, and particularly, the surface modified graphene comprises 85 parts by weight of graphene and 1 part by weight of surface modifier.

[0028] The surface modifier used is one or more member of the group consisting of titanate coupling agent, aluminate coupling agent, silane coupling agent, zircoaluminate coupling agent or their mixture.

[0029] The silver powder is composed of 85 parts by weight of micron-sized spherical silver powder with an average particle size of 1.0 m and 1 part of nano-sized silver powder with an average particle size of 20 nm.

[0030] The organic binder is composed of 10 parts by weight of polymer and 80 parts by weight of organic solvent, wherein the polymer is one or more members of the group consisting of ethyl cellulose, acrylic resin and polyethylene resin, and the organic solvent is two or more members of the group consisting of butyl carbitol, terpineol, tributyl citrate and propylene glycol butyl ether.

[0031] The glass powder comprises 1 part by weight of B.sub.2O.sub.3, 20 parts by weight of PbO and 50 parts by weight of TeO.sub.2; the glass powder is processed to give glass binder with a particle size D50 of 0.5 m.

[0032] The method for preparing a solar cell front side silver paste doped with modified graphene includes the following steps:

[0033] (1) Preparation of modified graphene: 85 parts by weight of graphene and 1 part by weight of surface modifier are weighed and mixed, and the mixture is ultrasonically dispersed with an ultrasonic dispersion machine for 20 min, filtered, and dried to give a modified graphene;

[0034] (2) Preparation of an organic binder: 10 parts by weight of polymer and 80 parts by weight of organic solvent are weighed and mixed, and the mixture is dispersed with a dispersion machine for 50 min to dissolve the polymer, and then a transparent and homogeneous organic binder;

[0035] (3) Preparation of a glass powder: 1 part by weight of B.sub.2O.sub.3, 20 parts by weight of PbO and 50 parts by weight of TeO.sub.2 are weighed and well mixed, and the mixture is heated in a high temperature muffle furnace at 800 C. for 40 min, quenched with deionized water after being melted, ball-milled for 2.5 h, sieved with a 300 mesh screen, and a glass powder with a particle size D50 less than 2 m is obtained;

[0036] (4) Preparation of a solar cell front side silver paste: 0.1 part by weight of modified graphene, 5 parts by weight of organic binder and 1 part by weight of glass powder are weighed and mixed, and then dispersed with a dispersion machine at the speed of 500 rpm for 10 min; 88 parts by weight of silver powder is added, and the mixture is dispersed with at dispersion machine at the speed of 800 rpm for 30 min, the mixture is grinded with a three-roller grinding machine 15 times, followed by addition of 1 part by weight of organic solvent, which is composed of two or more members of the group consisting of butyl carbitol, terpineol, tributyl citrate and propylene glycol butyl ether, the mixture is dispersed with a high speed dispersion machine for 5 min, and a finished product, the solar cell front side silver paste doped with modified graphene, is obtained and packed for further use.

[0037] The paste obtained as above is screen printed with a 360 mesh screen on a 125mm125mm monocrystalline silicon wafer to form an electrode film, and then the printed monocrystalline silicon wafer is sintered in a muffle furnace, the sintering peak temperature being 780 C.

[0038] Embodiment 2

[0039] A solar cell front side silver paste doped with modified graphene comprises by weight: 5 parts of modified graphene, 91 parts of silver powder, 15 parts of organic binder, 2 parts of organic solvent and 3 parts of glass powder, wherein the modified graphene is a surface modified graphene.

[0040] The surface modified graphene comprises 99 parts by weight of graphene and 15 parts by weight of surface modifier.

[0041] The surface modifier used is one or more member of the group consisting of titanate coupling agent, aluminate coupling agent, silane coupling agent, zircoaluminate coupling agent or their mixture.

[0042] The silver powder is composed of 99 parts by weight of micron-sized spherical silver powder with an average particle size of 2.0 m and 15 part of nano-sized silver powder with an average particle size of 100 nm.

[0043] The organic binder is composed of 20 parts by weight of polymer and 90 parts by weight of organic solvent, wherein the polymer is one or more members of the group consisting of ethyl cellulose, acrylic resin and polyethylene resin, and the organic solvent is two or more members of the group consisting of butyl carbitol, terpineol, tributyl citrate and propylene glycol butyl ether.

[0044] The glass powder comprises 10 parts by weight of B.sub.2O.sub.3, 5 parts by weight of Cr.sub.2O.sub.3, 60 parts by weight of PbO, 5 parts by weight of SiO.sub.2, 80 parts by weight of TeO.sub.2 and 20 parts by weight of Bi.sub.2O.sub.3; the glass powder is processed to give glass binder with a particle size D50 of 2 m. The melting point of the glass powder is controlled to be about 450 C.

[0045] The method for preparing a solar cell front side silver paste doped with modified graphene includes the following steps:

[0046] (1) Preparation of modified graphene: 99 parts by weight of graphene and 15 part by weight of surface modifier are weighed and mixed, and the mixture is ultrasonically dispersed with an ultrasonic dispersion machine for 60 min, filtered, and dried to give a modified graphene;

[0047] (2) Preparation of an organic binder: 20 parts by weight of polymer and 90 parts by weight of organic solvent are weighed and mixed, and the mixture is dispersed with a dispersion machine for 70 min to dissolve the polymer, and then a transparent and homogeneous organic binder;

[0048] (3) Preparation of a glass powder: 10 parts by weight of B.sub.2O.sub.3, 5 parts by weight of Cr.sub.2O.sub.3, 60 parts by weight of PbO, 5 parts by weight of SiO.sub.2, 80 parts by weight of TeO.sub.2 and 20 parts by weight of Bi.sub.2O.sub.3 are weighed and well mixed, and the mixture is heated in a high temperature muffle furnace at 1200 C. for 60 min, quenched with deionized water after being melted, ball-milled for 10 h, sieved with a 300 mesh screen, and a glass powder with a particle size D50 less than 2 m is obtained; the melting point of the glass powder is controlled to be about 250 C.

[0049] (4) Preparation of a solar cell front side silver paste: 5 parts by weight of modified graphene, 15 parts by weight of organic binder and 3 part by weight of glass powder are weighed and mixed, and then dispersed with a dispersion machine at the speed of 800 rpm for 30 min; 91 parts by weight of silver powder is added, and the mixture is dispersed with at dispersion machine at the speed of 1000 rpm for 50 min, the mixture is grinded with a three-roller grinding machine 15 times, followed by addition of 3 part by weight of organic solvent, which is composed of two or more members of the group consisting of butyl carbitol, terpineol, tributyl citrate and propylene glycol butyl ether, the mixture is dispersed with a high speed dispersion machine for 20 min, and a finished product, the solar cell front side silver paste doped with modified graphene, is obtained and packed for further use.

[0050] The paste obtained as above is screen printed with a 360 mesh screen on a 125mm125mm monocrystalline silicon wafer to form an electrode film, and then the printed monocrystalline silicon wafer is sintered in a muffle furnace, the sintering peak temperature being 780 C.

[0051] Embodiment 3

[0052] A solar cell front side silver paste doped with modified graphene comprises by weight: 3 parts of modified graphene, 89 parts of silver powder, 10 parts of organic binder, 3 parts of organic solvent and 2 parts of glass powder, wherein the modified graphene is a surface modified graphene.

[0053] The surface modified graphene comprises 90 parts by weight of graphene and 7 parts by weight of surface modifier.

[0054] The surface modifier used is one or more member of the group consisting of titanate coupling agent, aluminate coupling agent, silane coupling agent, zircoaluminate coupling agent or their mixture.

[0055] The silver powder is composed of 87 parts by weight of micron-sized spherical silver powder with an average particle size of 1.4 m and 7 parts of nano-sized silver powder with an average particle size of 70 nm.

[0056] The organic binder is composed of 15 parts by weight of polymer and 85 parts by weight of organic solvent, wherein the polymer is one or more members of the group consisting of ethyl cellulose, acrylic resin and polyethylene resin, and the organic solvent is two or more members of the group consisting of butyl carbitol, terpineol, tributyl citrate and propylene glycol butyl ether.

[0057] The glass powder comprises 6 parts by weight of B.sub.2O.sub.3, 3 parts by weight of Cr.sub.2O.sub.3, 40 parts by weight of PbO, 3 parts by weight of SiO.sub.2, 60 parts by weight of TeO.sub.2 and 10 parts by weight of Bi.sub.2O.sub.3; the glass powder is processed to give glass binder with a particle size D50 of 1 m; the melting point of the glass powder is controlled to be around 350 C.

[0058] The method for preparing a solar cell front side silver paste doped with modified graphene includes the following steps:

[0059] (1) Preparation of modified graphene: 90 parts by weight of graphene and 7 part by weight of surface modifier are weighed and mixed, and the mixture is ultrasonically dispersed with an ultrasonic dispersion machine for 40 min, filtered, and dried to give the modified graphene;

[0060] (2) Preparation of an organic binder: 15 parts by weight of polymer and 85 parts by weight of organic solvent are weighed and mixed, and the mixture is dispersed with a dispersion machine for 60 min to dissolve the polymer, and then a transparent and homogeneous organic binder;

[0061] (3) Preparation of a glass powder: 6 parts by weight of B.sub.2O.sub.3, 3 parts by weight of Cr.sub.2O.sub.3, 40 parts by weight of PbO, 3 parts by weight of SiO.sub.2, 60 parts by weight of TeO.sub.2 and 10 parts by weight of Bi.sub.2O.sub.3 are weighed and well mixed, and the mixture is heated in a high temperature muffle furnace at 1100 C. for 50 min, quenched with deionized water after being melted, ball-milled for 6 h, sieved with a 300 mesh screen, and a glass powder with a particle size D50 less than 2 m is obtained;

[0062] (4) Preparation of a solar cell front side silver paste: 3 parts by weight of modified graphene, 10 parts by weight of organic binder and 2 parts by weight of glass powder are weighed and mixed, and then dispersed with at dispersion machine at the speed of 700 rpm for 20 min; 89 parts by weight of silver powder is added, and the mixture is dispersed with at dispersion machine at the speed of 900 rpm for 40 min, the mixture is grinded with a three-roller grinding machine 15 times, followed by the addition of 2 part by weight of organic solvent, which is composed of two or more members of the group consisting of butyl carbitol, terpineol, tributyl citrate and propylene glycol butyl ether, the mixture is dispersed with a high speed dispersion machine for 12 min, and a finished product, the solar cell front side silver paste doped with modified graphene, is obtained and packed for further use.

[0063] The paste obtained as above is screen printed with a 360 mesh screen on a 125mm125mm monocrystalline silicon wafer to form an electrode film, and then the printed monocrystalline silicon wafer is sintered in a muffle furnace, the sintering peak temperature being 780 C.

[0064] The invention is not limited to the above preferred embodiments. Various other products made with the identical or similar technologies disclosed in the invention by persons skilled in the art who are enlightened from the invention, no matter any modifications or changes in shape or structure, are within the scope of the invention.