Filtration device having internal recirculation
10040030 ยท 2018-08-07
Assignee
Inventors
Cpc classification
Y02W10/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B01D2311/04
PERFORMING OPERATIONS; TRANSPORTING
B01D2313/26
PERFORMING OPERATIONS; TRANSPORTING
B01D65/08
PERFORMING OPERATIONS; TRANSPORTING
B01D2313/08
PERFORMING OPERATIONS; TRANSPORTING
International classification
B01D63/00
PERFORMING OPERATIONS; TRANSPORTING
B01D65/08
PERFORMING OPERATIONS; TRANSPORTING
B01D61/02
PERFORMING OPERATIONS; TRANSPORTING
B01D67/00
PERFORMING OPERATIONS; TRANSPORTING
B01D39/00
PERFORMING OPERATIONS; TRANSPORTING
B01D65/00
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A device for micro-, ultra-, or nanofiltration that includes one or more flat filter modules having flat filter elements arranged in parallel and at a distance from each other and gas injectors of one or more gas lifting systems for producing a circulating cross flow directed tangentially to the surface of the flat filter elements and having at least one rising area, in which the cross flow flows substantially vertically upward, and at least one falling area, in which the cross flow flows substantially vertically downward, in which the rising area flows through 10 to 100% and the falling area flows through 10 to 100% of an inlet-flow volume of the at least one flat filter module.
Claims
1. A device for micro-, ultra- or nanofiltration comprising one or more immersed flat filter modules, said modules comprising (i) flat filter elements arranged in parallel and at a distance from one another, (ii) one or more gas lifting systems comprising gas injectors having more than one gas outlets for generating a continuous circulating crossflow stream directed tangentially to the surface of the flat filter elements and (iii) at least one permeate line connected to said flat filter elements for passage of permeate into a permeate space, said module comprising at least two side walls having at least two side walls, wherein said module having a horizontal cross sectional are A.Math.F of length A and width F, and wherein the gas injectors are tubular hollow bodies, each gas injector having a longitudinal axis substantially in a horizontal plane that is oriented in a direction parallel to a lower edge of the flat filter elements wherein said gas outlets are arranged in horizontally oriented contiguous surface regions and are equally spaced from each other laterally such that the lateral distance of adjacent said gas outlets is from 0.2 to 50 mm wherein the gas injectors with gas outlets of a gas lifting system are arranged beneath said filter module for giving off a gas, gas injectors with gas outlets arranged in two equally large areas B.Math.G having a length B and a width G, wherein B extends parallel to and essentially over the full length of the flat filter elements and wherein said two equally large areas B.Math.G are separated by a space, such that vertical projections of the gas outlets pass through 10 to 80% of a horizontal cross sectional area A.Math.F of said module, and said filter module having at least one rising area in which the crossflow stream flows substantially vertically upward, and at least one falling area in which the crossflow stream flows essentially vertically downward, and said gas outlets are arranged such that the rising area passes through 30 to 60% of a flow volume of said module and the falling area passes through 40 to 70% of a flow volume of said module whereby said crossflows are substantially restricted within said module.
2. The device as claimed in claim 1, wherein the rising area passes through 45 to 55% of the flow volume of the flat filter modules and the falling area passes through 45 to 55%.
3. The device as claimed in claim 1, wherein said device comprises m flat filter modules, of which n flat filter modules are equipped with gas injectors of a gas lifting system, wherein m and n are natural numbers where m?2 and m?n?1, the gas injectors are equipped with gas outlets and vertical projections of the gas outlets pass through 10 to 80% of a horizontal cross sectional area AF of each of the n flat filter modules.
4. The device as claimed in claim 3, wherein said vertical projections of the gas outlets pass through 30 to 60% of a horizontal cross sectional area A.Math.F of each of the n flat filter modules.
5. The device as claimed in claim 3, wherein said vertical projections of the gas outlets pass through 45 to 55% of a horizontal cross sectional area A.Math.F of each of the n flat filter modules.
6. The device as claimed in claim 1, wherein said module comprises a housing having a base wall.
7. The device as claimed in claim 6, wherein the housing comprises at least one feed line for feeding feed, and at least one outlet line for conveying away retentate.
8. The device as claimed in claim 7, wherein the at least one outlet line is a siphon in which retentate flowing outward from the interior of the housing through the outlet line flows vertically upward for at least a part of a section.
9. The device as claimed in claim 7, wherein the at least one outlet line is arranged in an upper third of a side wall.
10. The device as claimed in claim 9, wherein the at least one outlet line further comprises a diaphragm for retaining solids in the interior of the housing.
11. The device as claimed in claim 10, wherein, in the interior of the housing, granules for cleaning the surfaces of the flat filter elements are present.
12. The device as claimed in claim 11, further comprising at least one additional gas lifting system placed between said space of said two equally large areas B.Math.G, wherein gas outlets of gas injectors of said additional gas lifting system are arranged below the at least one flat filter module for giving off a gas in an alternating operation to said first set of gas outlets such that vertical projections of the gas outlets pass through 90 to 20% of a horizontal cross sectional area A.Math.F of the at least one flat filter module, thereby enabling said additional gas lifting system to reverse the direction of the circulating cross flow stream.
13. The device as claimed in claim 12, wherein said device comprises m flat filter modules, of which n flat filter modules are equipped with said gas injectors of said gas lifting system, wherein m and n are natural numbers where m?2 and m?2n?1, and wherein (m?n) flat filter modules are equipped with gas injectors of said additional gas lifting system, and the gas injectors are equipped with gas outlets such that vertical projections of the gas outlets pass through 90 to 20% of a horizontal cross sectional area AF of each of the (m?n) flat filter modules.
14. The device as claimed in claim 13, wherein the gas outlets pass through 30 to 60% of a horizontal cross sectional area AF of each of the (m?n) flat filter modules.
15. The device as claimed in claim 13, wherein the gas outlets pass through 45 to 55% of a horizontal cross sectional area AF of each of the (m?n) flat filter modules.
16. The device as claimed in claim 12, wherein the vertical projections of the gas outlets pass through 70 to 40% of a horizontal cross sectional area A.Math.F of the at least one flat filter module.
17. The device as claimed in claim 12, wherein the vertical projections of the gas outlets pass through 55 to 45% of a horizontal cross sectional area A.Math.F of the at least one flat filter module.
18. The device as claimed in claim 11, wherein the granules are made of polymeric material having a specific density of 1.0 to 1.5 kg/dm.sup.3.
19. The device as claimed in claim 7, wherein the at least one outlet line is arranged in the base wall.
20. The device as claimed in claim 19, wherein the at least one outlet line further comprises a hood for retaining solids in the interior of the housing.
21. The device as claimed in claim 7, wherein the at least one feed line is a siphon in which the feed flowing from the outside through the feed line into the interior of the housing flows downward in a vertical direction for at least a part of a section.
22. The device as claimed in claim 7, wherein said device comprises a lower frame which rests on the base of said device and determines the vertical position of said gas injectors and said flat filter module.
23. A method for the micro-, ultra- or nanofiltration of liquids through a device as claimed in claim 1 comprising one or more flat filter modules made of flat filter elements arranged in parallel and at a distance from one another, and gas injectors of one or more gas lifting systems, said method comprising directing a circulating crossflow stream tangentially toward the surface of the flat filter elements having at least one rising area in which the crossflow stream flows substantially vertically upward and at least one falling area in which the crossflow stream flows substantially vertically downward, and the rising area passes through 30 to 60% of a feed volume of the at least one flat filter module and the falling area passes through 40 to 70%.
24. The method for micro-, ultra- or nanofiltration of liquids through a device as claimed in claim 23, wherein the gas is air and vertical projections of the gas outlets pass through 30 to 60% of a horizontal cross sectional area of the at least one flat filter module.
25. The method for micro-, ultra- or nanofiltration of liquids through a device as claimed in claim 23, wherein the vertical projections of the gas outlets pass through 45 to 55% of a horizontal cross sectional area of the at least one flat filter module.
26. The device as claimed in claim 1, wherein said at least one flat filter module having a horizontal cross sectional area A.Math.F of length A and width F, and wherein the gas outlets of gas injectors of the gas lifting system are arranged beneath the at least one flat filter module for giving off a gas with gas injectors arranged in two equally large areas B.Math.G, below the right and left hand side of the flat filter module each of which having a length B and a width G, wherein B extends parallel to and essentially over the full length of the flat filter elements and wherein said two equally large areas B.Math.G are separated by a space, such that vertical projections of said first set of as outlets pass through 45 to 55% of a horizontal cross section area A.Math.F of the at least one flat filter module.
27. A device for micro-, ultra- or nanofiltration comprising one or more immersed flat filter modules, said modules comprising (i) flat filter elements arranged in parallel and at a distance from one another, (ii) one or more gas lifting systems comprising gas injectors having more than one gas outlets for generating a continuous circulating crossflow stream directed tangentially to the surface of the flat filter elements and (iii) at least one outlet line connected to the flat filter element for conveying away permeate, said module comprising a frame that is open on one or more sides, wherein said module having a horizontal cross sectional area A.Math.F of length A and width F, and wherein the gas injectors are tubular hollow bodies, each gas injector having a longitudinal axis substantially in a horizontal plane that is oriented in a direction parallel to a lower edge of the flat filter elements wherein said gas outlets are arranged in horizontally oriented contiguous surface regions and are equally spaced from each other laterally such that the lateral distance of adjacent said gas outlets is from 0.2 to 50 mm wherein the gas injectors with gas outlets of a gas lifting system are arranged beneath said filter module for giving off a gas, gas injectors with gas outlets arranged in two equally large areas B.Math.G having a length B and a width G, wherein B extends parallel to and essentially over the full length of the flat filter elements and wherein said two equally large areas B.Math.G are separated by a space, such that vertical projections of the gas outlets pass through 10 to 80% of a horizontal cross sectional area A.Math.F of said module, and said filter module having at least one rising area in which the crossflow stream flows substantially vertically upward, and at least one falling area in which the crossflow stream flows essentially vertically downward, and said gas outlets are arranged such that the rising area passes through 30 to 60% of a flow volume of said module and the falling area passes through 40 to 70% of a flow volume of said module whereby said crossflows are substantially restricted within said module.
Description
BRIEF DESCRIPTION OF THE FIGURES
(1) The invention will be described in more detail hereinafter with reference to drawings (figures). In the drawings:
(2)
(3)
(4)
(5)
(6)
(7)
(8)
(9)
DETAILED DESCRIPTION OF ADVANTAGEOUS EMBODIMENTS OF THE INVENTION
(10)
(number of flat filter elements 5)?(area of a flat filter element 5)?(distance D between each two adjacent flat filter elements 5),
acts as rising area of the gas lifting system. The volume region enclosing the filtration device 3 accordingly acts as falling area of the gas lifting system. The falling area is marked in the plan view of
(11)
(12) The distance between each two adjacent flat filter elements 5 is indicated in
(13) In addition
(14)
(15) In
0.1.Math.A.Math.F?2.Math.B.Math.G?0.8.Math.A.Math.F; and in particular
0.3.Math.A.Math.F?2.Math.B.Math.G?0.6.Math.A.Math.F
(16) In general, the gas outlets 14 can be arranged in any desired manner such that the vertical projections 140 thereof pass through a contiguous part surface, or a plurality of about 2 to 4 part surfaces separated from one another of any desired shape. According to the invention, however, the symmetrical configuration shown in
(17) Expediently, the gas injectors 13 have a structure customary in the prior art and comprise lines or tubes, the wall of which has numerous openings, and the outside of which is encased by an elastic, liquid-impermeable membrane having fine slots. The elastic membrane is pretensioned in such a manner that the fine slots which act as gas outlets 14 behave as one-way valves. As soon as the gas pressure in the gas injector 13 and therefore on the inside of the elastic membrane exceeds the hydrostatic pressure of the surrounding liquid, gas is forced through the slots and given off into the surrounding liquid in the form of fine bubbles. If the gas pressure in the gas injectors 13 is lower than the hydrostatic pressure of the surrounding liquid, the slots in the membrane are closed, in such a manner that no gas can exit and no liquid can enter into the gas injectors 13.
(18) As indicated in
(19) According to the invention, the gas lifting system of the filtration device(s) is constructed in such a manner that it is suitable for giving off a gas stream from 0.1 to 0.5 m.sup.3 per m.sup.2 of membrane surface area of the flat filter elements and per hour to the activated sludge or feed 2. For this purpose, the pressure-generating appliance of the gas lifting system such as, for example, a fan or a compressor, is equipped with a controllable drive which permits the gas rate transported per unit time (m.sup.3/h) to be controlled and adjusted to the value required for the entire membrane surface area of one or more of the filtration devices according to the invention. In addition, the pressure-generating unit is designed in such a manner that, even at high transport rates, the pressure required at the gas injectors for gas delivery is generated in order to overcome the hydrostatic pressure of the feed 2 and the resistance to opening of the gas outlets.
(20) In operation, the volumetric flow rates of the various liquids moved in the filtration device are roughly in the following ratio:
recirculating crossflow=100? to 300?permeate flux(i)
feed flow=4? to 6?permeate flux(ii)
(21) Relation (i) states that the volume of the crossflow flowing through the flat filter modules per unit time, i.e. of the feed flowing up and downward or recirculating in the rising and falling areas, is 100- to 300-times the permeate volume removed from the flat filter modules. Analogously thereto, relation (ii) states that the volume of the (fresh) feed fed per unit time is 4- to 5-times the permeate volume. In addition, owing to the conservation of mass, the following relationship applies:
Feed volume=retentate volume+permeate volume(iii)
(22) It is necessary to take into account here that owing to the mode of construction of the flat filter modules and also of the crossflow conducted in an (open) circuit, the feed and retentate streams mix continuously and are virtually inseparable.
(23) In
(24)
(25) In order to avoid discharge of solids, in particular granules for cleaning the surfaces of the flat filter elements 5, from the interior of the filtration devices 20, the outlet line 26 is equipped with a diaphragm 27. As already explained in connection with
(26)
(27) Expediently, the filtration devices 10, 20 and 30, similarly to the filtration device 10 shown in
(28) The gas injectors 13 shown in
(29) In
(30) In
(31)
(32) In
(33) In addition to the examples shown in
(34)
m?2 and(a)
m>n?1.(b)
(35) In contrast to the flat filter modules 4, the remaining (m?n) flat filter modules 4 do not have gas injectors. A gas such as air is injected via the gas injectors 13 into the flat filter modules 4, in such a manner that an upwardly directed crossflow streaming 70 develops therein which itself induces a downwardly directed crossflow streaming 71 in adjacent flat filter modules 4. The gas injectors 13 are equipped with gas outlets 14, the vertical projections of which pass through 10 to 100%, preferably 30 to 60%, and in particular 45 to 55%, of a horizontal cross sectional area AF of each of the n flat filter modules 4.
(36) In the filtration device 41 shown in
(37) In
(38) Preferably, in the filtration devices 40 and 41, in each case a flat filter module 4 and a flat filter module 4 are arranged next to one another. For this purpose, expediently, the number of flat filter modules 4 and 4 is the same, i.e. m=2.Math.n. For example, the flat filter modules 4 and 4 are arranged in respectively adjacently situated rows, wherein a row is composed of flat filter modules 4 and a row adjacent thereto of flat filter modules 4. In addition, arrangements are provided in which a flat filter module 4 or 4 is surrounded on the four sides thereof by four flat filter modules 4 or 4, respectively (chessboard-like arrangement).
(39) In further advantageous embodiments of the invention, the filtration devices 10, 20, 30, 40, 41 contain granules that circulate with the crossflow streaming 50, 60 in the interior of the filtration devices 10, 20, 30, 40, 41 and mechanically remove residues, in particular a biological fouling layer (membrane fouling), adhering to the surfaces of the flat filter elements 5.
(40) The granules consist of non-porous particles of a polymeric material having a density of 1.0 to 1.5 kg/dm.sup.3, preferably 1.0 to 1.3 kg/dm.sup.3, and in particular 1.0 to 1.1 kg/dm.sup.3. The polymeric material is selected from a group comprising mineral-particle-containing polypropylene, polycarbonate blends, thermoplastic polyurethane elastomers, polymethyl-methacrylate, polybutylene terephthalate, polyoxymethylene, polyethylene and polyvinyl chloride. The particles of the granules have a median diameter less than 5 mm, in particular from 1.5 to 3.5 mm. The particles are produced from the respective polymer material using known granulating methods. For example, a powder, optionally mixed with fillers, of the relevant polymer or copolymer is plasticized and sprayed through a die into a precipitation bath. In this case, substantially spherical, lens-shaped or cylindrical polymer particles are generated, in which fillers are optionally embedded. The polymer particles generated are then sieved and dried. The size and surface properties of the particles are adjustable in broad ranges via the diameter of the die openings, the pressure, the composition of the precipitation bath and the process temperature. According to the invention, the particles have a surface having a median roughness Rtm of less than 40?, preferably less than 30 ?m, and in particular less than 20 ?m. The median roughness Rtm of the particles is determined as specified in DIN EN ISO 4287. For carrying out the measurement, first a half-side impression is taken by means of a molding compound of at least 12 of the particles. As molding compound or impression compound, a silicone-based precision impression material, e.g. high-viscosity condensation crosslinked polysiloxane as specified in DIN 13 913 A2, ISO 4823 or Elastosil M1470 (Wacker-Chemie GmbH) is used. After curing the impression compound, a primary profile is recorded on the half-side concave impressions of the particles using a profilometer conforming to DIN EN ISO 3274 (e.g. Hommel Tester T 4000). In order to obtain a measurement section as long as possible, the measuring tip of the profilometer is placed as centrally as possible through the respective impression of a particle. The spherical, lens-shaped or cylindrical surface contour and any long-wave surface structure of the particles or the corresponding impressions present in the impression material is removed by software-supported filtering as specified in DIN EN ISO 11562 from the measured primary profile in order to obtain a roughness profile and the total height Rt thereof (maximum height between the highest peak and the lowest valley). Finally, the median roughness Rtm is determined as the median of the roughnesses Rt of the at least 12 cast particles.
(41) The concentration of the granules in the filtration devices 10, 20, 30 is, based on the liquid volume, 1 to 10 kg/m.sup.3, in particular about 3 to 5 kg/m.sup.3.